ALSTOM - Magnus Mortberg.pdf
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Transcript of ALSTOM - Magnus Mortberg.pdf
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ALSTOM Solutions for the Syngas Industry
Istanbul, 23 - 26 February 2014
Nitrogen & Syngas 2015
Magnus Mrtberg, Gianluca Di Federico
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 2
Power generation infrastructure
Alstom supplies major equipment for 25% of the
worldwide installed power generation capacity
Power transmission infrastructure
Alstom equips more than 90%
of power utilities worldwide
Alstom holds 25% of
hydro electricity market
Rail transport infrastructure
A major player on all the
rail market segments
Three main activities, a global leader
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 3
Total sales 2013/14 = 20.3 billion
Total orders 2013/14 = 21.5 billion
Transport
5.9 bn
Thermal Power
8.8 bn
Grid
3.8 bn
Renewable Power
1.8 bn
Three main activities in four Sectors
Group sales
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 4
Orders by region and activity in 2013/14
A global footprint
Europe
36%
North America
15%
Latin America
13%
Africa and
Middle-East
21%
Asia and Pacific
15%
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 5
Environmental Control Systems
Full range of products to comply with the strictest international standards
Flue Gas Desulphurization (FGD) Wet FGD (OST,
FLOWPAC) Dry FGD (SDA & NID) Seawater FGD
Particulate Control Fabric Filter Electrostatic
Precipitators (Wet & Dry)
NOx Control SCR Systems (Selective
Catalytic Reduction) Mercury Control KNX Mer-Cure Filsorption
OST: Open Spray Tower; SDA: Sprayer Dryer Absorber; NID: Novel Integrated Desulphurization
KNX (Bromine spray)
Mer-Cure (brominated activated carbon injection) Filsorption (activated carbon injection)
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 6
ALSTOM Carbon Capture GmbH (ACC) Technology Execution for ECS/CCS Technologies
1965 Lummus GmbH founded in Munich
1969 Relocation to Wiesbaden
1989 Lummus Crest acquired by ABB
2007 Chicago Bridge & Iron Company acquired Lummus
2009 CB&I Lummus GmbH acquired by Alstom (ACC)
ALSTOM Carbon Capture GmbH acts as worldwide
technology centre and European execution centre within the
Alstom E3CS (Environmental Control and Carbon Capture
Systems) organisation.
specialists of all EPC relevant disciplines with an excellent
track record in the O&G and petrochemical industry including
an outstanding reference position in CO2 removal from natural
gas and other process streams.
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 7
Roadmap to commercialization
Test Rigs Validation Pilots Commercial Industrial Pilots Large-scale demonstration
Alstom Vaxj Sweden 0.25 MWth
We Energies Pleasant Prairie USA - 5 MWth, Coal 15ktpy CO2 EoN Karlshamn Sweden - 5 MWth, Oil 15 ktpy CO2
AEP Mountaineer USA - 58 MWth, Coal 100 ktpy CO2 TCM Mongstad Norway - gas 82 ktpy CO2
2006 2010
Chilled Ammonia Process roadmap
2020 & beyond
Industrial plants 100-200 ktpy
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 8
Chilled Ammonia Process Flow Diagram
Principle
Ammonium carbonate solution reacts with CO2 of cooled
flue gas to form ammonium Carbamate/bicarbonate
Raising the temperature reverses this reaction,
pressurized CO2 is released, the solution is recycled
Advantages
High CO2 purity
Tolerant to oxygen and flue gas impurities
Stable reagent, no degradation nor
emission of trace contaminants
Low-cost, globally available reagent
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 9
TCM Chilled Ammonia Validation Plant
Design Basis CO2 Sources:
Flue gases from natural gas CHP plant
Off-gases from the RFCC
Validation plant, designed to capture:
80 ktons CO2/year (RFCC) & 22 ktons CO2/year (CHP)
85% CO2 capture efficiency
Incorporation learning from previous pilots
Refinery environment Mongstad
Design Features
Compact and efficient layout (1300 m2)
150 tonnes of piping
62 control valves
39 Sampling Points
642 Inputs to DCS
1st on Industrial Source!
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 10
Mongstad Refinery and TCM Site
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 11
CAP Operating NH3 Emissions in flue gas
NH3 Emissions in residual flue gas leaving CAP meets the 2.5 ppm (1.7
mg/Nm) design objective. TCM Permitted level is 20 ppm (14 mg/Nm).
Ammonia emission levels constantly low
Same with RCC 5 ppm constantly
No other degradation product or harmful pollutants in flue
gas
Spikes in ammonia level occurs during change out of
sulfuric acid tote.
CONFIDENTIAL
GRAPH CHP GAS
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 12
CAP Operating CHP Gas NH3 Emissions in CO2 product
NH3 Emissions in CO2 product leaving CAP meets design objective of 10 ppm.
CO2 product purity >99,8%
Variance in ammonia level occurs when CO2 wash
temperature increases.
CONFIDENTIAL
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 13
Urea Production the role of CO2
Fertilizer Complex
Natural Gas
Reformer
CO2
Removal
Flue Gas
CO2
Removal
Ammonia
Synthesis
CO2
Urea
Synthesis
Syngas
NH3
NH3 to export
NH3
NH3 excess
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 14
CAP for CCU in industrial processes
90% capture rate with any flue gas or synthetic gas stream at ambient or high pressure (reformers, boilers, furnaces, etc.)
CO2 at battery limit is available at 99.8+ % CO2 is available at > 20 bar at battery limit (without
compression) Absorber and regenerator can operate at similar pressure CAP uses ammonia as make-up for solvent No solvent degradation (it does not react with O2) Extremely low solubility of H2, CO and CH4 in absorber
solution
KEY FEATURES
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ALSTOM 2014. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure to third parties, without express written authority, is strictly prohibited.
Nitrogen & Syngas 2014 P 15
Conclusions
Environmental Control solutions to meet current regulations, especially with regard to SOx, NOx and particulate.
CO2 Recovery technology for optimizing the production of higher value products such as urea
Case Studies can be jointly developed with interested Clients:
Technical Feasibility
Budget Cost Indication
Workshop Meeting
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www.alstom.com