ALCOHOL PRODUCTION AND IT’S CONCENTRATION
Transcript of ALCOHOL PRODUCTION AND IT’S CONCENTRATION
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ALCOHOL PRODUCTION AND ITS CONCENTRATION
1*Hiwrale Shubham Dnyaneshwar (B. Pharm), Rokade V. G.(M. Pharm)
2 and
Hingane L. D. (Ph. D Scholar)3
1Shendra MIDC, Kumbhepal Aurangabad.
2Aditya Pharmacy Collage, Nalwandi Naka, Beed.
3Ph.D Scholar At. Post Kumbhephal Tq Aurangabad Dist: Aurangabad.
1. ABSTRACT
World ethanol production rose to nearly 13.5 billion gallon in 2006.
Ethanol has been part of alcoholicbeverages for long time, but its
application has expanded much beyond that during the 20th Century.
Much ofthe recent interest is in the use of ethanol as fuel. In this paper,
we have reviewed published literature oncurrent ethanol production
and separation methods, and chemical and sensory analysis techniques.
Ethanolproduced by fermentation, called bioethanol, accounts for
approximately 95% of the ethanol production. It isrecently widely used
as an additive to gasoline. Corn in the Unites States and sugarcane in
Brazil are widelyused as raw materials to produce bioethanol. Cellulosic materials are
expected to be the ultimate major sourceof ethanol and also represent a value-technology for
agricultural coproducts. While bioethanol isconsidered as a sustainable energy source.
2. INTRODUCTION
Alcohol is both a beverage providing some sustenance and a drug.
For thousands of years, alcohol has been consumed in a medicinal, celebratory, and ritualistic
manner.
Alcohol is a psychoactive drug.
A psychoactive drug is any substance that crosses the blood-brain barrier primarily affecting
the functioning of the brain, be it altering mood, thinking, memory, motor control, or
behavior.
Alcohol which is best defined by the National Council on Alcohol and Drug Dependence
WORLD JOURNAL OF PHARMACY AND PHARMACEUTICAL SCIENCES
SJIF Impact Factor 7.632
Volume 10, Issue 3, 884-906 Review Article ISSN 2278 – 4357
*Corresponding Author
Hiwrale Shubham
Dnyaneshwar (B. Pharm)
Shendra MIDC, Kumbhepal
Aurangabad.
Article Received on
09 Jan. 2021,
Revised on 29 Jan. 2021,
Accepted on 19 Feb. 2021
DOI: 10.20959/wjpps20213-18503
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(NCADD) and the American Society of Addiction Medicine (1992) as ―a primary, chronic
disease with genetic, psychosocial and environmental factors influencing its development and
manifestations. The disease is often progressive and fetal. It is characterized by continuous or
periodic: impaired control over drinking, preoccupation with the drug alcohol, use of alcohol
despite adverse consequences, and distortion in thinking, most notably denied‖
(www.ncadd.org) was not to be recognized as health- related problem and confirmed as a
disease until the mid of nineteenth century. This paper attempts to investigate the evolution of
the alcoholism concept through out the different ages. Alcoholism which considered the most
recurrent brain depressant through out the different cultures and the cause of remarkable
number of diseases and deaths (DSM-IV, 1998) has gone through different level of
conceptual development before being recognized as a disease-related concept. Alcoholism,
regardless to the different definitions, linked to the consumption of the substance ―alcohol‖
which is one of the 11 substances classes named by the American Psychiatric Association as
a substance related disorders (DSM-IV, 1998). The public and historians’ interest in alcohol
as subject was evoked through the cultural historians’ interest in studying the food and
drinking. According to Sournia (1990), the historian interest in food and nutrition goes back
to ―the perennial Malthusian battles between the man and a hostile environment‖ (p ix).
Thisconcern in food and nutrition did not address what people dink or what kind of cultural
drinking habits that are existed at theses times (Sournia, 1990). This paper intends to show
how the concept of alcoholism changed through time, and what was the impact of a selected
cultures and religions on the alcohol drinking’s habits and abstinence. This historical review
of the alcoholism evolution is much concerned about the alcoholism as a disease; therefore,
an emphasis is put in discussing the alcoholism as been recognized as a problem. Besides, the
efforts of prominent scholars are also discussed.
3. Raw material
Raw Material Selection Criteria
Availability & Cost of Raw Material
Storage, Handling & Transportation Cost
Pre-Processing & Capital Cost
Utility Cost
Technology Availability
Plant Location
Plant Capacity & Annual Operation
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Revenue from Co-products
Effluent Treatment & Discharge
2Saccharine – containing Sugar
Starchy - Containing Starch
Cellulosic - Containing Cellulose
The feed stocks raw materials are of 3 types
Saccharine
All saccharine material can be converted to ethanol after their conversion to glucose.
Sucrose + H2O Glucose + fructose
Lactose + H2O Glucose + Galactose
Maltose + H2O 2Glucose
Cellobiose + H2O 2Glucose
Classes of carbohydrates
Monosaccharides contain a single polyhydroxy aldehyde or ketone unit (e.g., glucose,
fructose).
Disaccharides consist of two monosaccharide units linked together by a covalent bond (e.g.,
sucrose).
Oligosaccharides contain from 3 to 10 monosaccharide units (e.g., raffinose).
Polysaccharides contain very long chains of hundreds or thousands of monosaccharide units,
which may be either in Straight or branched chains (e.g., cellulose, glycogen, starch).
Plant part used for ethanol production
Cassava: Root
Sweet potato: Root
Sugar beet: Root (Juice/ molasses)
Sugar cane: Stalk (Juice/Molasses/Bagasse)
Sweet sorghum: Stalk
Paddy: Grain (Husk/Rice Bran Cake)
Corn: Grain/Residue
Sorghum: Grain
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Wheat: Grain/Straw
Millets: Grain
Barley: Grain
Rice: Grain/Husk
Mahua: Flowers
Cashewapple: Juice
Forest plants: Wood waste
Biosynthesis of ethanol
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Grain quality
Starch is present as granules which are embedded in a protein matrix. This matrix
issurrounded by cell walls containing a gum called -glucan. The starch granules aretherefore
inaccessible and protected from attack by the amylase enzymes that are produced during
germination During the process however, the cell walls and the protein will be dissolved by
other enzymes which are produced naturally as the seed grows. It must have a low proportion
of protein. The lower the protein, the higher the amountof carbohydrate. (Protein levels are
measured by measuring nitrogen content, a typicalspec being less than 1.8%.) The grains
should be of an even size. That way they are more likely to grow evenly.
The grains should be consistent colour, helping indicate the same variety and lack of damage
due to for instance moisture. The grains should be large. Large are easier to process.
They must be undamaged, free of split or pre-germinated grains and free of disease of pests
such as beetles or moths. They must be free of other cereals or other varieties. The moisture
level must be suitable. If freshly harvested, not more than 18%, andsuitable for drying to 12%
prior to storage.
4. Molasses
Composition and classification
The third boiling of the sugar syrup yields dark, viscous fluid known asmolasses.
The majority of sucrose from the original juice has crystallized and beenremoved.
The quality of Indian molasses is inferior as compared to the molasses available in
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countries such as Brazil and Australia and also varies widely within the country. The
quality of Indian molasses is inferior as in India8sugar is produced by double sulphitation
method that involves three and half boiling and use of SO2 for sulphitation.
Sugarcane molasses is agreeable in taste and aroma, and is primarily usedfor sweetening
and flavoring foods.
It is a defining component of fine commercial brown sugar.
Unlike highly refined sugars, it contains significant amounts of vitaminB6and minerals,
including calcium, magnesium, iron, and manganese.
It is a major raw material for the production of ethyl alcohol, bakers’ yeast and citricacid.
Composition
Particulars. %
Total solids. 83 to 85
Invert/Reducing sugar. 12 to 18
Sucrose. 30 to 40
Fermentable sugar. 50 to 55
Non-sugar organic compounds. * 20 to 25
Process and product
Cane sugar is obtained by successive evaporation, cristallization andcentrifugation. Both the
sugar.extraction process andthe sugar refining process yield molasses, and each step of these
processes. Outputspecific. types of molasses. Pérez, 1995 has described the different
molasses as follows:
Integral high-test molasses is produced from unclarifiedsugarcane juice. Because it is
concentrated from unclarified sugarcane juice, heavy incrustations and scum deposits lead to
frequent mill interruptions and, therefore, to increased factory maintenance costs.
High-test molasses is basically the same as integral high-test molasses. However, it does not
raise as many problems in manufacture as integral high-test molasses does.
A molasses (first molasses) is an intermediate by-product resulting from first sugar crystal
extraction (A sugar), from initial processing at the sugar factory. A molasses contains 80-
85% DM. If it has to be stored, it should be inverted in order to prevent crystallization.
B molasses (second molasses). It has approximately the same DM content as A molasses but
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contains less sugar and does not spontaneously crystallize.
C molasses (final molasses, blackstrap molasses, treacle) is the end by-product of the
processing in the sugar factory. It still contains considerable amounts of sucrose
(approximately 32 to 42%). C molasses does not crystallize and can be found in liquid or
dried form as a commercial feed ingredient.
Syrup-off (liquor-off, jett) is the end by-product from the centrifugation of the final refined
masecuite in a raw sugar refinery. Normally, syrup-off is sent to the raw sugar section of the
refinery where it is further processed in order to recover more sucrose. Due to its high content
of sucrose (90-92% DM), it is an excellent energy source for monogastrics but can be an
expensive ingredient.
Refinery final molasses is the by-product of refined sugar extraction. It has a very similar
composition to that of C molasses produced in a raw sugar factory and it is stored in the same
tanks.
In some countries the juice is extracted in a simple animal or mechanically driven press, then
boiled in open vats. In this rudimentary process, pan (uncrystallized) sugar is produced and
the by-product molasses is called "melote". It contains only 50% DM.
5. Fermentation
Fermentation is carried out in the fermentation vessels under controlled conditions
oftemperature and pH. The propagated yeast biomass is transferred to the mainfermenters
keeping volume at 10 to 15% of the total fermenter volume. The rest isfilled with diluted
molasses. After filling the fermenter, it is left for fermentation. Thisprocess occurs under
anaerobic condition. Under these conditions, the glucosemolecule breaks down to produce
ethyl alcohol and carbon dioxide. The time requiredfor completion of the fermentation
process is 15 – 20 hours. The fermentation processis understood to be completed when the
effervescence stops. Other measurementlike specific gravity etc., are also taken to assess the
completion of fermentationprocess. Fermentation is an exothermic reaction. Hence, the
temperature rises during the fermentation process. To maintain the temperature at 36 degree
C., the fermentervessels are required to be cooled with fresh water, through plate type heat
exchanger. The yeast sludge along with solids present in molasses is collected at the bottom
of the fermenter vessels. These solids need to be removed to make the fermentervessels ready
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for another batch of fermentation process. The sludge is washed off bywater. The washed
sludge called fermenter washing constitutes a waste along withsome alcohol.
The fermenter washing is centrifuged in a high speed centrifuge machine, whichseparates
solid and liquid the liquid containing some alcohol is sent for distillationwhile the solid
contained biomass and other solid is sent for bio-composting.
Type of fermentation
Fermentation
A) Batch B) Fed. barch C) Continuous
1) Alcon and Tate & Lyle
2) Melle Bionet
3) Semi-continuous
4) Biostil
5) Cascade
6) Encillium
Batch fermentation
All necessary medium components and the inoculum are added at thebeginning.
The products of fermentation, whether intracellular or extracellular, areharvested only at
the end of the run.
The concentration of medium components are not controlled during theprocess.
As the living cells consume nutrients and yield product(s), theirconcentrations in the
medium vary along the process.
The affecting factors, such as pH and temperature, are normally keptconstant during the
process.
The optimum concentration of raw materials can be decided only accordingto the initial
concentration.
Continuous fermentation
One or more feed streams containing the necessary nutrients are fed continuously.
The output stream containing the cells, products and residues is continuouslywithdrawn.
A steady state is established for the process.
The culture volume is kept continuous by maintaining an equal volumetric flow rateof
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feed and output.
Need for cleaning is minimized as a continuous culture concentration is maintainedin the
fermenter.
Continuous fermentation systems require good quality of molasses and aresusceptible to
contamination.
Fed-batch fermentation
Nutrient or raw material is fed intermittently.
After the first filling, the inoculum is added.
After a small retention time, filling is continued.
Fermentation starts right after the first filling and continues alone the process.
At the end of the process, fermenter is emptied and the product isobtained.
It is currently the most popular mode of fermentation amongst thedistilleries in India.
Commercial fermentation processes
Alcon process and Tate & Lyle process
Both the processes are nearly the same and in these processes feed issterilized only once
during the first filling in the fermenter.
Feed is given without sterilization.
The contents of the fermenter are mixed by pumped recirculation.
The settled yeast is recycled and supernatant is sent for distillation.
6. Alcohol and bioproduct technology
Alcohol & Biofuel
Tomsa Destil is the leading company in distillation technology for alcohol production. Our
history date back to the 1850s and through all this years we have developed our own
distillation technology to produce the best quality alcohoiinall its variants and from any
sources. We provide full project life cycle services, starting from the conecption of the plant,
to the engineering, construction all the way to plant operation and product comercialization.
Tomsa Destil provide full EPC projects both for edible and biofuel alcohol Tomsa Destil
supplies plants with capacities ranging from pilot plants up to industrial plants with
production rates of more than 1,000,000 litres/day.
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Diffussion
Must preparation
Fermentation
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Distillation
Vinasses Concentration
Alcohol storage
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Energy
Cogeneration, energy efficiency, power generation and recovery.
Manufacturing
With over 43,000 sqft in two locations, we manufacture our own equipment to make sure
everything is builtto the highest european standards.
Tomsa Destil builds its own technological equipment Skid plants.
Ready for startup with practically zero installation required except for interconnection
Motor Cabinets and Control Cabinets design, engineering and manufacturing Handcrafted
equipment.
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Industry
R&D, chemical, pharmaceutical, food & beverage, waste treatment and process control
systems.
Construction
Architecture, land scaping, civil works, steel structures, HVAC.
Construction
We take care of the full project including site construction. Our team of architects and
engineers manage foundation, roads, metal structures, fire protection and all the rest of
constructiondisciplines.
NTomsa Destil has built in seismic and high wind areas.
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7. Ethanol production
Substrates
Ethanol is produced from various kinds of substrates. The substrate used forethanol
production is chosen based on the regional availability and economical efficiency. In this
section, the substrate for ethanol fermentation is discussed.
Sucrose containing materials
Ethanol is produced by fermentation. Fermentation process is a process to convert sugar to
ethanol. Sucrose containing materials could simplify the ethanol production process.
Sugarcane: Brazil is the world second biggest ethanol producer. In Brazil, sugarcane is
the major substrate for ethanol (Goldemberg et al., 2008). Countries in Central America
and Caribbean are suitable for sugarcane cultivation, and their ethanol production is
increasing recently. Sugar beet is mainly cultivated in European countries (Power et al.,
2008) since it grows under cold climate.
Sugar sorghum Sugar sorghum is also a sucrose containing crop. It yields large amount of
biomass and sugar due to its high photosynthetic efficiency (Giorgis et al, 1997).
*Ethanol purification
Fermentation by-products
Ethanol is produced by yeast fermentation. Although yeast mainly produces ethanol, it also
produces by-products. These by-products need to be removed to obtain pure ethanol. There
are mainly two kinds of by-product sources, starch and lignin. Starch derived by-products
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include esters, organic acids, and higher alcohols. Lignin derived by-products include cyclic
and heterocyclic compounds.
Purification techniques
Fermentation by-products are mostly removed by distillation. However, volatile by-products
tend to lodge more in ethanol. Also, especially for drinking or pharmaceutical purpose, high
concentration of ethanol is not required. In this case, further distillation is just waste of
energy and money. Many studies have done to find a new purification technique of ethanol
which can take place of distillation.
Distillation
Distillation is the most dominant and recognized industrial purification technique of ethanol.
It utilizes the differences of volatilities of components in a mixture. The basic principle is that
by heating a mixture, low boiling point components are concentrated in the vapor phase. By
condensing this vapor, more concentrated less volatile compounds is obtained in liquid phase.
Distillation is one of the most efficient separation techniques. However, itcontains several
problems. One is separation of volatile compounds. In ethanol production, a distillation tower
is designed to separate water and ethanol effectively. Water is obtained from the bottom of
the tower and ethanol is obtained from the top of the tower. It is expected that impurities with
similar boiling points to ethanol lodges in ethanol even after distillation. Second is its cost.
Distillation is a repetition of vaporization and condensation. Therefore, it costs a lot.
Adsorption
Adsorption is a separation technique utilizing a large surface area of adsorbent. Compounds
are simply adsorbed on the adsorbent depending on their physical and chemical properties. In
general, bigger particles tend to be adsorbed more due to their low diffusivities. Also,
compounds with the similar polarity to the adsorbent surface tend to be adsorbed more. When
purification of ethanol is considered, non-polar surface and wide ranging pore distribution are
favorable since ethanol is polar compounds and various sizes of particles could be contained
in ethanol as impurities. From water treatment, activated carbon (Demirbas et al., 2008) and
activated alumina (Tripathy and Raichur, 2008) are the most expectable adsorbents.
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8. Alcoholic beverages
Alcoholic beverage, any fermented liquor, such as wine, beer, or distilled spirit, that
contains ethyl alcohol, or ethanol (CH3CH2OH), as an intoxicating agent. Abrief treatment of
alcoholic beverages follows. For full treatment, see alcohol consumption.
Alcoholic beverages are fermented from the sugars in fruits, berries, grains, and such other
ingredients as plant saps, tubers, honey, and milk and may be distilledto reduce the original
watery liquid to a liquid of much greater alcoholicstrength. Beer is the best-known member
of the malt family of alcoholic beverages, which also includes ale, stout, porter, and malt
liquor. It is made from malt, corn, rice, and hops. Beers range in alcoholic content from about
2 percent to about 8 percent. Wine is made by fermenting the juices of grapes or other fruits
such as apples (cider), cherries, berries, or plums. Winemaking begins with the harvest of
the fruit, the juice of which isfermented in large vats under rigorous temperature control.
When fermentation is complete, the mixture is filtered, aged, and bottled. Natural, or
unfortified, grape wines generally contain from 8 to 14 percent alcohol; these include such
wines as Bordeaux, Burgundy, Chianti, and Sauterne. Fortified wines, to which alcohol
or brandy has been added, contain 18 to 21 percent alcohol; such wines include sherry, port,
and muscatel.
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The making of distilled spirits begins with the mashes of grains, fruits, or other ingredients.
The resultant fermented liquid is heated until the alcohol and flavourings vaporize and can be
drawn off, cooled, and condensed back into a liquid. Water remains behind and is discarded.
The concentrated liquid, called a distilled beverage, includes such liquors
as whiskey, gin, vodka, rum, brandy, and liqueurs, or cordials. They range in alcoholic
content usually from 40 to 50 percent, though higher or lower concentrations are found.
In the ingestion of an alcoholic beverage, the alcohol is rapidly absorbed in
the gastrointestinal tract (stomach and intestines) because it does not undergo any digestive
processes; thus, alcohol rises to high levels in the blood in a relatively short time. From the
blood the alcohol is distributed to all parts of the body and has an especially pronounced
effect on the brain, on which it exerts a depressant action. Under the influence of alcohol the
functions of the brain are depressed in a characteristic pattern. The most complex actions of
the brain—judgment, self-criticism, the inhibitions learned from earliest childhood—are
depressed first, and the loss of this control results in a feeling of excitement in the early
stages. For this reason, alcohol is sometimes thought of, erroneously, as a stimulant. Under
the influence of increasing amounts of alcohol, the drinker gradually becomes less alert,
awareness of his environment becomes dim and hazy, muscular coordination deteriorates,
and sleep is facilitated. See also alcoholism
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9. The three types of alcohol
The only type of alcohol that humans can safely drink is ethanol. We use the other two types
of alcohol for cleaning and manufacturing, not for making drinks. For example, methanol (or
methyl alcohol) is a component in fuel for cars and boats. It’s also used to manufacture
antifreeze, paint remover, windshield wiper fluid, and many other products. Isopropanol (or
isopropyl alcohol) is the chemical name for rubbing alcohol, which we use for cleaning and
disinfecting. Both methanol and isopropanol are poisonous to humans because our bodies
metabolize them as toxic substances which cause liver failure. Drinking even a small amount
of methanol or rubbing alcohol can be fatal.
Ethanol (or ethyl alcohol) is the type of alcohol that over two billion people drink every day.
This type of alcohol is produced by the fermentation of yeast, sugars, and starches. For
centuries, people have consumed ethanol-based drinks, such as beer and wine, to change the
way that they feel. However, ethanol also has harmful effects on the body. The human liver
can metabolize ethanol, but only in limited quantities.
Ethanol is toxic, so it damages the liver, the brain, and other organs over time. Ethanol also
inhibits the central nervous system, thereby impairing coordination and judgment.
Additionally, binge drinking and other forms of alcohol abuse can cause a person to develop
debilitating alcohol addiction.
Distilled and Undistilled alcohol
There are two categories of alcoholic beverages: distilled and undistilled. Undistilled drinks
are also called fermented drinks. Fermentation is the process by which bacteria or yeast
chemically converts sugar into ethanol. Wine and beer are both fermented, undistilled
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alcoholic beverages. Wineries ferment grapes to make wine and breweries ferment barley,
wheat, and other grains to make beer.
Distillation is a process which follows fermentation. The process converts a fermented
substance into one with an even higher concentration of alcohol. Distillation concentrates
alcohol by separating it from the water and other components of a fermented substance.
Liquors and spirits are distilled alcoholic beverages. They contain more alcohol by volume
than undistilled drinks. In general, a distilled alcoholic beverage will have a higher alcohol
proof.
Alcohol by volume (ABV) and alcohol proof are two measures of alcohol content, or the
concentration of alcohol in a drink. Alcohol by volume is the number of milliliters of ethanol
per 100 milliliters (or 3.4 fl.oz.) in a solution, while alcohol proof is twice the percentage of
alcohol by volume. For example, a drink which has 50% ABV will be 100 proof
10. Different Types of Alcoholic Drinks By Alcohol Content
There are many different kinds of alcoholic drinks, and some of them contain more alcohol
than others. The types of alcoholic drinks with higher concentrations of alcohol are able to
cause drunkenness and alcohol poisoning more quickly and in smaller doses.
Undistilled drinks
Beer
Beer is the most popular alcoholic beverage worldwide. In fact, after water and tea, beer is
the most commonly-consumed drink in the world. Beer is also most likely the oldest
alcoholic drink in history. A standard beer, whether it be a lager or an ale, has between 4% to
6% ABV, although some beers have higher or lower concentrations of alcohol. For example,
―light beers‖ only have between 2% to 4% ABV while ―malt liquors‖ have between 6% to
8%.
Wine
Wine is another popular and ancient alcoholic beverage. Standard wine has less than 14%
ABV. Champagne, the most well-known sparkling wine, has an alcohol concentration of
about 10% to 12%. Some wines are ―fortified‖ with distilled alcohol. Port, Madeira, Marsala,
Vermouth, and Sherry are examples of fortified wines. They usually have about 20% ABV.
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Hard Cider
Hard cider is fermented apple juice. It usually has about 5% ABV.
Mead
Mead, a blend of water and fermented honey, has between 10% to 14% ABV.
Saké
Saké, a well-known Japanese drink made from fermented rice, has an alcohol concentration
of about 16% ABV.
Distilled drinks (Liquors and Spirits) gin
sugarcane is a spirit made from juniper berries. It can have anywhere from 35% to 55% ABV.
Brandy
Brandy is distilled wine. The concentration of alcohol in brandy ranges from 35% to 60%.
For example, one famous brandy, Cognac, has 40% ABV.
Whiskey
Whiskey is a spirit made from fermented grain. The ABV of whiskey ranges from 40% to
50%.
Rum
Rum, a distilled drink made from fermented sugarcane or molasses, has a typical alcohol
concentration of 40% ABV. Some rum is ―overproof,‖ meaning that it has alcohol
concentration of at least 57.5% ABV. Most overproof rum exceeds this minimum, usually
reaching 75.5% ABV, which is equivalent to 151 proof.
Tequila
Tequila is a type of liquor. The main ingredient of tequila is the Mexican agave plant. The
alcohol concentration of tequila is typically about 40% ABV.
Vodka
Vodka, a liquor usually made from fermented grains and potatoes, has a standard alcohol
concentration of 40% ABV in the United States.
Absinthe
Absinthe is a spirit made from a variety of leaves and herbs. There is no evidence for the idea
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that absinthe is a hallucinogen, but it does have a high alcohol concentration. Some forms of
absinthe have about 40%, while others have as much as 90% ABV.
Everclear
Everclear, a grain-based spirit, is another drink with a heavy concentration of alcohol. The
minimum ABV of Everclear is 60%, but Everclear can also have 75.5% and 95% ABV.
Get Help for Alcohol Addiction Today
Any type of alcoholic beverage can be the source of an alcohol use disorder. If you or
someone you know is struggling with alcoholism, please contact a dedicated treatment
professional to learn more about recovery and find the treatment center that’s right for you.
11. Uses of alcohol
Alcoholic drinks
The word "alcohol" in alcoholic drinks refers to ethanol (CH3CH2OH).
Industrial methylated spirits
Ethanol is usually sold as industrial methylated spirits, which is ethanol with a small quantity
of methanol and possibly some color added. Because methanol is poisonous, industrial
methylated spirits are unfit to drink, allowing purchasers to avoid the high taxes levied on
alcoholic drinks.
Use of ethanol as a fuel
Ethanol burns to produce carbon dioxide and water, as shown in the equation below, and can
be used as a fuel in its own right or in mixtures with petrol (gasoline). "Gasohol" is a
petrol/ethanol mixture containing approximately 10–20% ethanol. Because ethanol can be
produced by fermentation, this is a useful method for countries without an oil industry to
reduce the amount of petrol imports.
H3CH2OH+3O2→2CO2+3H2O(1)(1)CH3CH2OH+3O2→2CO2+3H2O
Ethanol as a solvent
Ethanol is widely used as a solvent. It is relatively safe and can be used to dissolve many
organic compounds that are insoluble in water. It is used, for example, in many perfumes and
cosmetics.
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Methanol as a fuel
Methanol also burns to form carbon dioxide and water:
2CH3OH+3O2→2CO2+4H2O(2)(2)2CH3OH+3O2→2CO2+4H2O
It can be used a a petrol additive to improve combustion, and its use as a fuel in its own right
is under investigation.
Methanol as an industrial feedstock
Most methanol is used to make other compounds, for example, methanal (formaldehyde),
ethanoic acid, and methyl esters of various acids. In most cases, these are then converted into
further products.
12. CONCLUSION
In this paper, the current ethanol production, purification, and analysis techniques have been
reviewed. Ethanol is produced from various kinds of substrates. The substrates used for
ethanol production vary by different countries due to their different farming conditions. In the
United States, corn is the dominant substrate of ethanol, and in Brazil, sugarcane is used for
ethanol production. Also, from the environmental stand point, utilization of ethanol
production is being studied more intentionally.
Ethanol is purified almost only by distillation in the industry. Although distillation is one of
the most effective liquid-liquid separation techniques, it contains some critical disadvantage,
cost and limitation on separation of volatile organic compounds. Many purification
techniques of water and wastewater are expected to be applied to ethanol purification as well.
Ozonation could degrade impurities. Activated carbon could remove impurities without
adsorbing ethanol, and gas stripping could simply remove high volatile compounds without
any heating. Ethanol analysis is done with different kinds of analytical techniques. While,
currently, GC has advantages on the resolution of analysis, HPLC could be used for heat
sensitive analytes. IR is convenient for routine quality assurance or classification of ethanol.
Also, olfactometry is utilized for flavor analysis of alcoholic beverages.
13. REFERENCES
1. Alcázar, A., J. M. Jurado, F. Pablos, A. G. González, and M. J. Martín, 2006.
2. HPLC determination of 2-furaldehyde and 5-hydroxymethyl-2-furaldehyde in alcoholic
beverages. Microchemical Journal, 2006; 82(1): 22-28.
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3. Alley, E. R, 2007.
4. Water quality control handbook. New York, N.Y.: McGraw-Hill. Bailey, P. S. 1982.
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