Agilent GC Solutions · Agilent GC Solutions A Convenient Deans Switch Method for the Analysis of...
Transcript of Agilent GC Solutions · Agilent GC Solutions A Convenient Deans Switch Method for the Analysis of...
Agilent GC Solutions A Convenient Deans Switch
Method for the Analysis of
Permanent Gases in Various
Matrices by Gas
Chromatography
CAG
Shannon Coleman
GC Applications
October 17, 2012
1
• Simplified design
• Easier setup
• Easier maintenance
• Capillary columns
• Faster chromatography
Advantages to Using Micro-fluidics for Analysis of
Permanent Gases in Various Matrices
2
Deans Switch Heart-cutting 2-D GC provides extremely high chromatograpic
resolution
7
Cut
Deans
Switch
Auto- sampler
7890A GC
FID1 FID2
Column 1 Column 2
.
Back
Front
PCM
Front
TCD
(220)
TCD
(220)
(112)
CAP
Molesieve
HP PLOT Q
Restrictor
P
S
R1
3
PCM X
Ch 1
Ch 2 2
13
Deans Switch
8
Deans Switch
9
.
Back
Front
PCM
Front
TCD
(220)
TCD
(220)
(112)
CAP
Molesieve
HP PLOT Q
Restrictor
P
S
R1
3
2
13
PCM X
Ch 1
Ch 2
Deans Switch
10
.
Back
Front
PCM
Front
TCD
(220)
TCD
(220)
(112)
CAP
Molesieve
HP PLOT Q
Restrictor
P
S
R1
3
2
13
PCM X
Ch 1
Ch 2
• System designed for analysis of
permanent gases and organics
• Gas sample valve for sample
introduction
• Split inlet for injection volume
control and alternative injection
source
• Deans switch allows for heart
cutting permanent gases to
Molsieve column
• Dual detectors for simultaneous
analysis from two columns
System Design
11
.
Order No :
Date : 03-08-2012
Remarks
FLOW
SOURCE
INJECTION
PORT
VALVE COMPARTMENT
BLOCK 2 BLOCK 1DETECTOR
S/N :
Item :
Options
OVEN LEFT SIDE
Valve System
SP1 options
Back
Front
PCM
Front Inl Front
1/XXX
2/XXX3/XXX
4/XXX5/861/
6/861/
= #87X
TCD(220)
TCD
(220)
(112)
CAPEPC
12
3
4
5
6
IN
OUT
SAMPLE
LOOP
CH 1
Column 2
Column 1
Restrictor
0.37m x 0.1mm Blank FSD
Restrictor Tubing
Col 1: 190091P-QO3, HP-PLOT Q, 15m x 0.32mm x 20um
Col 2: 19091P-MS4, HP-PLOT Molsieve, 30m x 0.32mm x 12 um
Restrictor: 160-2255-30, Deactivated Fused Silica Tubing, 0.37m x 0.1 mm
888P
S
R1
3
21
3
112, 2x220, 305, 306, 309, 701, 751, 860, 888 Bio-ethanol fermentation analysis.
System Operation: Sample Load
18
.
Order No :
Date : 03-08-2012
Remarks
FLOW
SOURCE
INJECTION
PORT
VALVE COMPARTMENT
BLOCK 2 BLOCK 1DETECTOR
S/N :
Item :
Options
OVEN LEFT SIDE
Valve System
SP1 options
Back
Front
PCM
Front Inl Front
1/XXX
2/XXX3/XXX
4/XXX5/861/
6/861/
= #87X
TCD(220)
TCD
(220)
(112)
CAPEPC
12
3
4
5
6
IN
OUT
SAMPLE
LOOP
CH 1
Column 2
Column 1
Restrictor
0.37m x 0.1mm Blank FSD
Restrictor Tubing
Col 1: 190091P-QO3, HP-PLOT Q, 15m x 0.32mm x 20um
Col 2: 19091P-MS4, HP-PLOT Molsieve, 30m x 0.32mm x 12 um
Restrictor: 160-2255-30, Deactivated Fused Silica Tubing, 0.37m x 0.1 mm
888P
S
R1
3
21
3
112, 2x220, 305, 306, 309, 701, 751, 860, 888 Bio-ethanol fermentation analysis.
.
Order No :
Date : 03-08-2012
Remarks
FLOW
SOURCE
INJECTION
PORT
VALVE COMPARTMENT
BLOCK 2 BLOCK 1DETECTOR
S/N :
Item :
Options
OVEN LEFT SIDE
Valve System
SP1 options
Back
Front
PCM
Front Inl Front
1/XXX
2/XXX3/XXX
4/XXX5/861/
6/861/
= #87X
TCD(220)
TCD
(220)
(112)
CAPEPC
12
3
4
5
6
IN
OUT
SAMPLE
LOOP
CH 1
Column 2
Column 1
Restrictor
0.37m x 0.1mm Blank FSD
Restrictor Tubing
Col 1: 190091P-QO3, HP-PLOT Q, 15m x 0.32mm x 20um
Col 2: 19091P-MS4, HP-PLOT Molsieve, 30m x 0.32mm x 12 um
Restrictor: 160-2255-30, Deactivated Fused Silica Tubing, 0.37m x 0.1 mm
888P
S
R1
3
21
3
112, 2x220, 305, 306, 309, 701, 751, 860, 888 Bio-ethanol fermentation analysis.
System Operation: Sample Inject
19
H2, O2, N2, CH4,
CO, CO2, HC’s
.
Order No :
Date : 03-08-2012
Remarks
FLOW
SOURCE
INJECTION
PORT
VALVE COMPARTMENT
BLOCK 2 BLOCK 1DETECTOR
S/N :
Item :
Options
OVEN LEFT SIDE
Valve System
SP1 options
Back
Front
PCM
Front Inl Front
1/XXX
2/XXX3/XXX
4/XXX5/861/
6/861/
= #87X
TCD(220)
TCD
(220)
(112)
CAPEPC
12
3
4
5
6
IN
OUT
SAMPLE
LOOP
CH 1
Column 2
Column 1
Restrictor
0.37m x 0.1mm Blank FSD
Restrictor Tubing
Col 1: 190091P-QO3, HP-PLOT Q, 15m x 0.32mm x 20um
Col 2: 19091P-MS4, HP-PLOT Molsieve, 30m x 0.32mm x 12 um
Restrictor: 160-2255-30, Deactivated Fused Silica Tubing, 0.37m x 0.1 mm
888P
S
R1
3
21
3
112, 2x220, 305, 306, 309, 701, 751, 860, 888 Bio-ethanol fermentation analysis.
System Operation:
20
H2, O2, N2, CH4, CO,
CO2, HC’s
Valve 1 OFF
System Operation: Sample Load
23
.
Order No :
Date : 03-08-2012
Remarks
FLOW
SOURCE
INJECTION
PORT
VALVE COMPARTMENT
BLOCK 2 BLOCK 1DETECTOR
S/N :
Item :
Options
OVEN LEFT SIDE
Valve System
SP1 options
Back
Front
PCM
Front Inl Front
1/XXX
2/XXX3/XXX
4/XXX5/861/
6/861/
= #87X
TCD(220)
TCD
(220)
(112)
CAPEPC
12
3
4
5
6
IN
OUT
SAMPLE
LOOP
CH 1
Column 2
Column 1
Restrictor
0.37m x 0.1mm Blank FSD
Restrictor Tubing
Col 1: 190091P-QO3, HP-PLOT Q, 15m x 0.32mm x 20um
Col 2: 19091P-MS4, HP-PLOT Molsieve, 30m x 0.32mm x 12 um
Restrictor: 160-2255-30, Deactivated Fused Silica Tubing, 0.37m x 0.1 mm
888P
S
R1
3
21
3
112, 2x220, 305, 306, 309, 701, 751, 860, 888 Bio-ethanol fermentation analysis.
System Operation: Sample Inject
24
H2, O2, N2, CH4,
CO, CO2, HC’s
.
Order No :
Date : 03-08-2012
Remarks
FLOW
SOURCE
INJECTION
PORT
VALVE COMPARTMENT
BLOCK 2 BLOCK 1DETECTOR
S/N :
Item :
Options
OVEN LEFT SIDE
Valve System
SP1 options
Back
Front
PCM
Front Inl Front
1/XXX
2/XXX3/XXX
4/XXX5/861/
6/861/
= #87X
TCD(220)
TCD
(220)
(112)
CAPEPC
12
3
4
5
6
IN
OUT
SAMPLE
LOOP
CH 1
Column 2
Column 1
Restrictor
0.37m x 0.1mm Blank FSD
Restrictor Tubing
Col 1: 190091P-QO3, HP-PLOT Q, 15m x 0.32mm x 20um
Col 2: 19091P-MS4, HP-PLOT Molsieve, 30m x 0.32mm x 12 um
Restrictor: 160-2255-30, Deactivated Fused Silica Tubing, 0.37m x 0.1 mm
888P
S
R1
3
21
3
112, 2x220, 305, 306, 309, 701, 751, 860, 888 Bio-ethanol fermentation analysis.
.
Order No :
Date : 03-08-2012
Remarks
FLOW
SOURCE
INJECTION
PORT
VALVE COMPARTMENT
BLOCK 2 BLOCK 1DETECTOR
S/N :
Item :
Options
OVEN LEFT SIDE
Valve System
SP1 options
Back
Front
PCM
Front Inl Front
1/XXX
2/XXX3/XXX
4/XXX5/861/
6/861/
= #87X
TCD(220)
TCD
(220)
(112)
CAPEPC
12
3
4
5
6
IN
OUT
SAMPLE
LOOP
CH 1
Column 2
Column 1
Restrictor
0.37m x 0.1mm Blank FSD
Restrictor Tubing
Col 1: 190091P-QO3, HP-PLOT Q, 15m x 0.32mm x 20um
Col 2: 19091P-MS4, HP-PLOT Molsieve, 30m x 0.32mm x 12 um
Restrictor: 160-2255-30, Deactivated Fused Silica Tubing, 0.37m x 0.1 mm
888P
S
R1
3
21
3
112, 2x220, 305, 306, 309, 701, 751, 860, 888 Bio-ethanol fermentation analysis.
System Operation, Valve 1 ON @ 0.8 min
25
CO2, HC’s
H2, O2, N2, CH4,CO,
System Operation: Valve 1 OFF @ 1.2 min
26
CO2, HC’s
H2, O2, N2, CH4,CO,
.
Order No :
Date : 03-08-2012
Remarks
FLOW
SOURCE
INJECTION
PORT
VALVE COMPARTMENT
BLOCK 2 BLOCK 1DETECTOR
S/N :
Item :
Options
OVEN LEFT SIDE
Valve System
SP1 options
Back
Front
PCM
Front Inl Front
1/XXX
2/XXX3/XXX
4/XXX5/861/
6/861/
= #87X
TCD(220)
TCD
(220)
(112)
CAPEPC
12
3
4
5
6
IN
OUT
SAMPLE
LOOP
CH 1
Column 2
Column 1
Restrictor
0.37m x 0.1mm Blank FSD
Restrictor Tubing
Col 1: 190091P-QO3, HP-PLOT Q, 15m x 0.32mm x 20um
Col 2: 19091P-MS4, HP-PLOT Molsieve, 30m x 0.32mm x 12 um
Restrictor: 160-2255-30, Deactivated Fused Silica Tubing, 0.37m x 0.1 mm
888P
S
R1
3
21
3
112, 2x220, 305, 306, 309, 701, 751, 860, 888 Bio-ethanol fermentation analysis.
Results PPQ Channel: CO2, ethylene, ethane, H2S, water, propane, and ethanol
Molsieve Channel: H2, O2, N2, CH4, CO
27
Flexible Configuration
31
.
Order No :
Date :
Remarks
FLOW
SOURCE
INJECTION
PORT
VALVE COMPARTMENT
BLOCK 2 BLOCK 1DETECTOR
S/N :
Item :
Options
OVEN LEFT SIDE
Valve System
SP1 options
Side
Back
Front Front Inl
Back Inl
Back Aux
Back
1/XXX
2/XXX3/XXX
4/XXX5/861/
6/861/
= #87X
TCD
FID
(220)
(210)
TCD
(221)
Front
(112)
CAP
(112)
CAPEPC
EPC
AUX 2
3
1
888P
S
R1
3
12
3
4
5
6
LOOP
12
3
4
5
6
LOOP
21
3
Column 1
Column 4a Column 4b
Column 2
Column 3
2x112, 210, 220, 221, 301, 305, 306, 2x701, 752, 2x860,
880, 888, 4xG2855-20530, 2x5188-5363, G2855-60200,
160-2255-30, 160-2325-30, 160-2615-10, CP7554, 19095P-
MS0E, 123-1036, 115-3352, 4xG2855-20590
7890-0990, 7890-0999
Column Info:
Column 1: CP7554, PoraPLOT Q, 25m x0.53mm x 20um
Column 2: 19095P-MS0E, 30m x 0.53mm x 50um
Column 3: Restrictor, fused silica deactivated tubing
Column 4a: 123-1036, (5m cut), 60m x 0.25mm x 1.0 um
Column 4b: 123-1036, (55m cut), 60m x 0.25mm x 1.0 um
Sample In
Sample Out
• Easily modified to include additional channels and detectors
Flexible
Detector
Choices:
FID
MSD
ECD
FPD
SCD
NCD
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