Advancing Chemistry, Innovating for Sustainabilityefficient biomass concentration in the design of...

18th Annual Green Chemistry & Engineering Conference

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American Chemical Society

Advancing Chemistry,Innovating for Sustainability

BETHESDA NORTH MARRIOTT HOTEL & CONFERENCE CENTERNORTH BETHESDA, MARYLAND, USA

JUNE 17 - 19, 2014


The ACS Green Chemistry Institute®What is green chemistry? We are glad you asked! Green chemistry and engineering is an innovation-driven approach to chemistry and chemical processes that seeks to reduce waste, conserve energy, and discover replacements for hazardous substances and nonrenewable raw materials throughout the life cycle of a product. Green chemistry and engineering benefits the economy while protecting human and environmental health.

The ACS Green Chemistry Institute® (ACS GCI) is dedicated to promoting and advancing innovation in sustainable and green chemistry for this century and beyond. We believe that such innovation holds the key to solving many environmental and human health challenges that plague our world today. Therefore, it is our mission to catalyze and enable the implementation of green chemistry and engineering throughout the global chemical enterprise.

ACS GCI welcomes you to the 18th Annual Green Chemistry & Engineering (GC&E) Conference! The conference provides a unique platform for leaders, policy makers, educators, students, and professionals from the scientific community to obtain valuable information on new progress in green research and establish meaningful collaborations and networks. This year’s theme, “Advancing Chemistry, Innovation for Sustainability” examines innovations in the science and application of greener chemistry & engineering needed for a better, brighter future.

The ACS GCI staff thanks each of you for your attendance and for bringing your enthusiasm, passion, and expertise to this conference. It is with your continued support that we can further the development of effective solutions and accomplish our mission.

FOLLOW GC&E POSTS BY JOINING ACS GREEN CHEMISTRY INSTITUTE® ON:

Conference Hashtag: #gcande

facebook.com/ACSGreenChemistryInstitute

linkedin.com/in/acsgci

twitter.com/acsgci [@ACSGCI]

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Advancing Chemistry, Innovating for Sustainability

Exhibitors

M o DRNMolecular DesignResearch Network

M o DRNMolecular DesignResearch Network

A U.S. EPA Program

GOLD

SILVER

BRONZE

TECHNICAL SESSIONS

CAREERS WORKSHOP

GENERAL

ROUNDTABLE POSTER RECEPTION

Thank you to our sponsors

®

7:00 a.m. – 5:00 p.m. Registration Open — Lower Level Registration

7:30 a.m. – 8:30 a.m. Networking Breakfast — Grand Foyer

8:00 a.m. – 5:00 p.m. Exhibition Open — Grand Foyer

8:30 a.m. – 9:30 a.m. Keynote Address: Greener quantum dot synthesis for energy efficient commercial display and lighting products. Presented by Dr. Seth Coe-Sullivan, Founder and CTO, QD Vision — Ballroom D

9:30 a.m. – 10:00 a.m. Networking Coffee Break — Grand Foyer

THEMATIC TRACKS EDUCATION GREENER PROCESSES DESIGN FOR CHEMICAL SAFETY GREENER PROCESSES NEW CHEMICAL FEEDSTOCKS

TECHNICAL SESSIONS

GREEN CHEMISTRY BEYOND THE BACHELORS DEGREE (….AND PHD) - PART I

EXPLORING GREENER APPROACHES TO HYDRAULIC FRACTURING DESIGNING SAFER CHEMICALS STUDIES IN GREEN CHEMISTRY BUILDING NEW CHEMICAL PLATFORMS

FROM BIOLOGICAL SYSTEMS

Ballroom B Ballroom C White Flint Amphitheater Brookside A Brookside B

J. Haack, Organizer, Session ChairJ. Manley, Organizer

D. Durham, D. Long, Session ChairsA. Voutchkova -Kostal, Organizer

A. Richard, Session ChairS. DeVito, Session Chair R. Wool, Organizer , Session Chair

10:00 a.m. – 10:20 a.m.

2. Lose the jargon, but don’t dumb it down: Lessons from a science communication fellowship. L. N. Vandenberg

7. Public controversy over hydraulic fracturing: The role of safer alternatives for fracturing fluids. R. Liroff

12. Bridging SAR and QSAR approaches for flagging or avoiding compounds with undesired toxicity profiles. A. Tropsha, D. Fourches, R. Politi, Y. Low, E. Muratov

19. Roots of green chemistry (1983-84) at the US Environmental Protection Agency: Investigation of substitutes for epichlorohydrin. G. E. Parris

26. Bio-renewable alternatives to petroleum-based polyesters using continuous flow. R. T. Mathers, D. Dakshinamoorthy, S. P. Lewis

10:20 a.m. – 10:40 a.m.

8. An environmentally-focused crosslinked gel system for hydraulic fracturing using chemicals sourced from the food industry. J. Holtsclaw, J. Weaver

13. Designing out toxicity by exploiting ‘Tox21’ computational approaches. G. Patlewicz, C. Kuseva, I. Popova, A. Mehmed, S. Kotov, T. Zhechev, T. Pavlov, S. Temelkov, P. Petkov, S. Dimitrov, O. Mekenyan

20. Defining the role of pollutant release and transfer (PRTR) information in global sustainability. S. C. DeVito

27. Who says monomers can’t grow on trees? The utilization of lignin bio-oil as a styrene alternative. K. H. Reno, M. G. Karavolias, D. P. Wool, D. H. Epps, III

10:40 a.m. – 11:00 a.m.

3. Beyond the PhD: Start-ups as early employee or founder. E. J. Beckman

14. Prediction of bioavailability from spectroscopic data: Quantitative spectra-property models for octanol/water partition coefficient, skin permeability and bioconcentration factors. N. An, Y. Tang, A. Voutchkova-Kostal

21. Merging automated green alternative assessments with quantitative REACH risk exposure algorithms. G. Thompson

28. Creating highly functional polyurethane dispersions with recycled raw material streams. R. Tabor, S. Mukerjee

11:00 a.m. – 11:20 a.m.

4. Sustainability is the key driver of innovation. D. R. Cooper-Hayes

9. Green solvents and microemulsions for stimulation A. Sehgal, R. Pabalan, & C. Aymes

15. Functionalized lignin-based environmentally-benign nanoparticles as replacement for antimicrobial silver nanoparticles. A. P. Richter, J. S. Brown, V. N. Paunov, S. D. Stoyanov, A. Wang, S. Gangwal, K. Houck, E. A. Cohen Hubal, O. D. Velev

22. Wealth from waste through green chemistry: GCNC contribution towards few real world cases in India. R. Sharma

29. Cellulose nanocrystals (CNCs) as supporters, reducers and chiral inducers. M. Kaushik, A. Moores

11:20 a.m. – 11:40 a.m.

5. Continuing education through the alternatives assessment community of practice. C. Baier-Anderson

16. Comparative external validation of common aquatic toxicity prediction tools: Informing selection and development of tools for alternatives assessment. F. Melnikov, A. Voutchkova-Kostal, J. Kostal, J. L. Tunkel, J. Zimmerman, P. T. Anastas

23. Bio-derived solvents in enzymatic catalysis. G. Paggiola, J. H. Clark, A. J. Hunt, C. R. McElroy, J. Sherwood

30. Chemical modification of sophorolipids for the synthesis of novel biomaterials. M. H. Schofield, M. L. Dahle, G. M. Sapienza

11:40 a.m. – 12:00 p.m.

10. Alternative to traditional biocidal chemicals in the oil and gas industry. D. Maley, B. O’Neil

17. Integrating informatics, SAR, QSAR, and decision theory to tease out undesired properties of molecules in chemical design. C. Yang, J. F. Rathman, C. H. Schwab, B. Bienfait

24. Advanced Silanes: Exploring sustainable and greener options for coatings applications. M. Singh, A. Maddox, H. Kiester, J. Matisons, J. Zazyczny, B. Arkles

31. High speed reactive extrusion processing for renewable polymer blends. M. S. Sobkowicz, J. Gug, X. Chen

12:00 p.m. – 12:20 p.m.

6. Driving innovations in green chemistry and educating on sustainability through life cycle assessment tools. B. W. Uhlman

11. Improved health, safety and environmental performance of a new field proven stimulation fluid in oilfield application. C. D. Wolf, B. Daigle, E. Bisinger, J. LePage, W. Braun

18. Mining the ToxCast chemical-data landscape for green chemical design: A SAR-Chem-Informed approach. A. M. Richard, P. Volarath, K. Mansouri, R. Judson

25. MoDRN: Rational design and development of the next generation chemicals. K. E. Mellor, E. Beach, F. Melnikov, L. Q. Shen, J. B. Zimmerman, J. Corrales, L. Kristofco, M. Mullins, G. Saari, E. Williams, J. Kostal, C. Schaupp, M. Mills, T. Kavanagh, N. Simcox, A. Voutchkova-Kostal, E. Gallagher, B. Brooks, P. Anastas

32. Shear-enhanced membrane processes for efficient biomass concentration in the design of biorefineries. C. Slater, M. J. Savelski, P. Kostetskyy, M. Johnson

SCHEDULE / Tuesday, June 17, 2014Seth Coe-Sullivan, PhDFounder and CTOQD Vision

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Advancing Chemistry, Innovating for Sustainability 17

SCHEDULE / Tuesday, June 17, 2014

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18th Annual Green Chemistry & Engineering Conference18

12:20 p.m. – 1:30 p.m. Lunch (on your own)

THEMATIC TRACKS EDUCATION ORGANIC CHEMISTRY DESIGN FOR CHEMICAL SAFETY GREENER PROCESSES NEW CHEMICAL FEEDSTOCKS

TECHNICAL SESSIONS

GREEN CHEMISTRY BEYOND THE BACHELORS DEGREE (….AND PHD) - PART II

SAFER AND MORE EFFICIENT APPROACHES TO HIGHLY REACTIVE CHEMISTRY KNOWLEDGE AND TOOLS TO EVALUATE ALTERNATIVES SUSTAINABLE PRACTICES IN BIOPHARMACEUTICALS ABUNDANT INNOVATION: PATHWAYS TO FEEDSTOCKS

FROM CO2 AND NATURAL GAS

Ballroom B Ballroom C White Flint Amphitheater Brookside A Brookside B

J. Haack, Organizer, Session ChairA. Marteel Parrish, Session Chair

J. Manley, OrganizerJ. Tucker, Session Chair

A. Voutchkova -Kostal, OrganizerE. Cohen Hubal, Session Chair

J. Manley, OrganizerK. Budzinski, Session Chair

J. Jackson, Organizer, Session Chair

1:30 p.m. – 1:50 p.m.

33. Connecting students with real-world applications of chemistry through project-based courses, outreach, and a focus on science communication. M. J. Mulvihill, M. Schwarzman, M. Douskey

40. A method for aromatic nitration which demonstrates remarkable thermal stability. L. Desai, G. Beutner, D. Fanfair, P. Lobben, M. Eastgate

44. Cheminformatic approaches for toxicity prediction. G. Daston

51. Greener biopharmaceuticals production: Evaluating ancillary substances using spatially explicit environmental risk assessment methods. J. Straub, R. Shearer, J. Klemmer, M. Studer

86. From waste to wealth using green chemistry. J. Clark

1:50 p.m. – 2:10 p.m.

34. Network of Early-Career Sustainable Scientists and Engineers (NESSE): An initiative from the ACS Summer School on Green Chemistry and Sustainable Energy 2013. C. Coss, J. Dodson, O. Zaskoka, M. Mastronardi, L. Hoch

45. Rapid in silico methods to characterize and predict ADME properties for chemical toxicity and exposure prioritization. D. T. Chang, C. M. Grulke, Y. Yin, R. Tornero-Velez, M. A. Pasquinelli, M. Goldsmith

57. (1:55 p.m.) Greenhouse gas and energy life cycle assessment of pine chemicals derived from crude tall oil: Benefits of material versus biofuel use. S. Cashman, K. Moran

2:10 p.m. – 2:30 p.m.

35. Project GreenLab: A regional student-faculty collaboration in green chemistry curriculum development, research and outreach education. E. J. Brush

41. A green ozonolysis/oxidation process to produce multi kilograms of drug substance. B. M. Cochran

46. Showcase of ChemView: EPA’s online database to access information under the Toxic Substances Control Act. D. Parsons, E. Lavoie, M. Doa, M. Leopard, S. Canavan, Y. Gonzalez, T. Klosterman, P. Lewis

52. EMD Millipore’s biopharmaceutical product recycling program. J. Ignacio

59. (2:15 p.m.) The acid-base chemistry of CO2 capture with liquid amines. S. Calabro, L.S. Baugh, P. Kortunov, M. Siskin.

2:30 p.m. – 2:50 p.m.36. Impact of active student participation on driving the

green chemistry conversation. L. B. Hoch47. Functional use: An underappreciated foundational

concept in advancing safer chemistry. J. A. Tickner, J. N. Schifano

2:50 p.m. – 3:20 p.m. Networking Break — Grand Foyer 42. From batch to flow processing: Benzimidazole ring formation via catalytic heterogeneous hydrogenation. J. Chen, K. Przyuski, R. Roemmele, R. P. Bakale

Networking Break — Grand Foyer (3:00 p.m.) Networking Break — Grand Foyer

3:20 p.m. – 3:40 p.m.

37. Mentoring graduate students in research and teaching by utilizing research as a template. M. N. Jackson Jr, C. C. Knutson, M. Beekman, M. E. Carnes, D. W. Johnson, D. A. Kezler

48. Incorporating SAR and high-throughput screening data into alternatives assessment: Challenges and opportunities. C. Baier-Anderson, E. T. Lavoie

53. Ultra low temperature freezer evaluations: NIH main campus. L. Gumapas

58. (3:30 p.m.) Nitrogen heterocycles as a hydrogen alternative in polymer electrolyte membrane fuel cells. L. K. Rubin, E. Deunf, K. T. Clark, S. Gottis, D. Faulkner, C. D. Vulpe, J. B. Kerr, J. Arnold 43. Making bonds safely in water @ RT. B. H. Lipshutz

3:40 p.m. – 4:00 p.m.38. Green chemistry high school professional

development: For teachers, by teachers. A. S. Cannon, K. Anderson

49. Developing systematic review approaches for mechanistic data and the relevance to chemical alternatives assessment. J. A. McPartland, J. A. Lam

54. Bioinspired technologies for sustainability: From fully compostable bioplastics to human organs-on-chips. D. E. Ingber

55. (3:50 p.m.) New materials for solar fuels from CO2. A. Bocarsly

4:00 p.m. – 4:20 p.m.39. Learn to see green with GREEN. D. E. Hogan, C. Coss,

R. Eismin50. Using Chemical Hazard Assessment for Informed

Substitution: Applications of GreenScreen for Safer Chemicals. L. Heine

4:20 p.m. – 4:40 p.m.

4:40 p.m. – 5:00 p.m.

56. (4:40 p.m.) Biodiesel production via transesterification using carbon dioxide-methanol mixtures in the presence of a heterogeneous catalyst. L. Soh, C. Chen, E. Beckman, J. Zimmerman

5:30 p.m. – 7:30 p.m. Welcome Reception – Kenneth G. Hancock Award Winners Announcement — Ballroom D

SCHEDULE / Wednesday, June 18, 2014

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8:00 a.m. – 5:00 p.m. Exhibition Open — Grand Foyer

8:30 a.m. – 9:35 a.m. Keynote Address: Sustainability challenges of the apparel & footwear industry and opportunities for innovation. Presented by Dr. Richard Blackburn, Professor, University of Leeds; Head, Sustainable Materials Research Group — Ballroom D


THEMATIC TRACKS ORGANIC CHEMISTRY NEW CHEMICAL FEEDSTOCKS EDUCATION DESIGN FOR CHEMICAL SAFETY CONSUMER PRODUCTS

TECHNICAL SESSIONS

COMMERCIALIZING RESEARCH ADVANCES - PART I

FROM WASTE TO WEALTH: CHEMICALS FROM DISCARDED FOOD AND TRASH

GREEN CHEMISTRY EDUCATION: CHARTING THE COURSE AHEAD

WORKSHOP - MAKING TOOLS FOR SAFER CHEMICAL DESIGN WORK FOR YOU

INNOVATIVE AND SUSTAINABLE SOLUTIONS IN APPAREL AND FOOTWEAR - PART I BUSINESS PLAN COMPETITION

Ballroom B Ballroom C White Flint Amphitheater Brookside A Brookside B Linden Oak

J. Manley, OrganizerD. Leahy, Session Chair

J. Clark, Organizer, Session ChairJ. Haack, Organizer

E. Brush, Session ChairJ. Kostal, Organizer, Session Chair J. Frazier, Organizer, Session Chair

D. Daly, M. Lefenfeld, R. Resendes, Organizers, Session Chairs

10:00 a.m. – 10:20 a.m.

62. The academic side of industrial collaborations aimed at advancing catalytic C–H borylations. R. E. Maleczka, Jr, M. R. Smith III

66. 5-(Chloromethyl)furfural (CMF) is the new HMF: Functionally equivalent but more practical in terms of its production from biomass. M. Mascal, E. B. Nikitin, S. Dutta, I. Gandarias, F. Chang

73. Integrating LCA into an introductory engineering course on material and energy balances. M. J. Savelski, C. Slater, G. Brereton, M. Oakley, S. Schanck

19. Making tools for safer chemical design work for you. L. Heine, K. Houck, J. Wang. This workshop will arm toxicologists and chemists with practical approaches for the rational design of safer industrial chemicals. Participants will learn the basics of computational theory and how computations can be paired with experimental findings to design chemicals with minimal biological activity. Specifically, tutorials will demonstrate how property-based design guidelines can be applied to maximize probability that chemicals will not exert acute or chronic toxicity to aquatic species and mammals. In learning about model development, the presenters will also outline sources of experimental data, which can be used to train computational models, as well as future strategies for secure data-sharing. Finally, participants will learn how data from models can be used for chemical hazard assessment, and drive development of decision-making frameworks that translate scientific progress to action items for the user or the regulator.

80. Applications of scCO2 as a “green” solvent in the textile industry. A. Lutz, R. Schlake, R. May, M. Anand, P. Hobbs

Semi-Finalists will be presenting their business plans:

SioTeX. L. Taylor & A. KotwalCirca Group. S. CaddeduCell-Free Bioinnovation. Z. ZhuU.S. Bioplastics. S. MillerHydroCoat. T. Shultz10:20 a.m. – 10:40 a.m.

63. C-H Borylation: Gateway to molecular diversity. S. W. Krska, T. Cernak, R. Dermenjian, K. Dykstra, B. Ghaffari, Y. Liu, P. Maligres, K. Moore, C. Parish, D. Perera, D. Plattner, S. Preshlock, M. Reibarkh, F. Shen, E. Streckfuss, S. Tyagarajan, P. Vachal, R. Maleczka, M. Smith

67. Biomass valorisation, sustainable materials and the methanol economy. R. J. White

74. Adapting a one-semester Green and Sustainable Chemistry course to the demands of the 21st century. A. Marteel-Parrish

81. Extend your cotton knits lifetime with biopolishing, develop consumer loyalty and achieve significant sustainability benefits. G. A. Screws

10:40 a.m. – 11:00 a.m.

68. A high-power and high-energy-density biobattery running on renewable sugars. Z. Zhu, Y. Zhang, J. Rollin

75. EPA-sponsored model program in sustainability: The Institute for Green and Sustainable Science summer program. C. S. Lecher

82. Pure solutions chemical line for industrial laundries. L. Boyd

11:00 a.m. – 11:20 a.m.

69. Alginic acid derived mesoporous carbonaceous materials as super-adsorbents for the removal of bulky dyes from waste waters. H. J. Abdoul, V. L. Budarin, M. De bruyn, J. H. Clark

76. Student-driven and teacher-supported, design-thinking approach toward the integration of STEAM activities into, and augmentation of, an existing high school curriculum. R. L. Broadrup, K. Umunna, M. Pereira, S. Lee

83. Waterborne polyurethane: A strong lever towards improved performance and sustainability in apparel and footwear materials. N. Smith

11:20 a.m. – 11:40 a.m.

64. Selective C-H activation borylation ortho to fluorine on fluoroaromatic systems. J. Oppenheimer, M. R. Smith, III, R. E. Maleczka, Jr, H. Li, D. Shabashov, C. Jayasundara

70. Valorization of rice bran and other agro-industry wastes by extraction of oil and esterification over solid catalysts. N. Ravasio, F. Zaccheria, M. Mariani, R. Psaro

77. The Green Chemistry Commitment: Resources for implementing green chemistry student learning objectives. A. S. Cannon

84. Biobased composites for applications in footware and apparel. R. Wool, S. Gong, X. Su, H. Cao

11:40 a.m. – 12:00 p.m.

71. Bioprocess development for the production of ethyl lactate from dairy waste. M. Koutinas, M. Menelaou, E. N. Nicolaou

78. A green chemistry experiment for undergraduates: Eugenol titration. P. Chen, H. Barcena

85. Where did my ZnO go? T. Wilson III

12:00 p.m. – 12:20 p.m.65. The NSF SusChEM Initiative. T. Li 79. Detection of ethidium bromide residues in

a teaching laboratory. H. Barcena, A. Gorbenko, P. Chen

12:20 p.m. – 1:30 p.m. Networking Lunch and Dedicated Exhibitor Time - Announcement of the Business Plan Competition Winners — Ballrom D and Grand Foyer

R ichard Blackburn, PhDProfessor, University of Leeds; Head, Sustainable Materials Research Group University of Leeds

SCHEDULE / Wednesday, June 18, 2014

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18th Annual Green Chemistry & Engineering Conference20

1:30 p.m. – 2:30 p.m. Poster Session – Even Numbers Only — White Oak

2:30 p.m. – 3:30 p.m. Poster Session – Odd Numbers Only — White Oak

THEMATIC TRACKS ORGANIC CHEMISTRY CRITICAL MATERIALS EDUCATION NEW CHEMICAL FEEDSTOCKS CONSUMER PRODUCTS

TECHNICAL SESSIONS

COMMERCIALIZING RESEARCH ADVANCES - PART II

FROM WASTE TO WEALTH: CHEMICALS FROM E-WASTE

ADVANCING SUSTAINABILITY THROUGH THE ACS SUMMER SCHOOL ON GREEN CHEMISTRY

AND SUSTAINABLE ENERGY

GREENING THE SUPPLY CHAIN USING BIOBASED CHEMICALS - PART I

INNOVATIVE AND SUSTAINABLE SOLUTIONS IN APPAREL AND FOOTWEAR - PART II BUSINESS PLAN COMPETITION

Ballroom B Ballroom C White Flint Amphitheater Brookside A Brookside B Linden Oak

J. Manley, OrganizerD. Leahy, Session Chair

A. Matharu, Organizer, Session ChairM. Kirchhoff, Organizer

J. F. Stanzione, Session Chair

J. Manley, OrganizerP. Williams , B. Comanita, Session Chairs

A. Phillips, Session ModeratorJ. Frazier, Organizer, Session Chair

D. Daly, E. Beckman, R. Resendes, Organizers, Session Chairs

3:30 p.m. – 3:50 p.m.

157. Bicyclic nitroxyl (co)catalyzed aerobic alcohol and amine oxidation. J. E. Steves, K. Miles, J. Kim, M. Lauber, J. Hawkins, S. S. Stahl

161. Rare metals recovery and recycling in the context of an integrated critical materials strategy. A. H. King

Introductory Remarks. 172. Composites from plant oil-based resin. A. Campanella

176. Chemicals management and green chemistry. S. Echols, J. Frazier

Panel Discussion: Innovating with Science, Technology, & Entrepreneurship

Panelists:D. DalyE. BeckmanR. Resendes Grand Prize Winner

165. (3:35 p.m.) Teaching green chemistry to undergraduate students and advances in green synthesis of nanomaterials. A. H. Moores, M. J. Rak

3:50 p.m. – 4:10 p.m.

166. (3:55 p.m.) Covalent tethering of earth-abundant metal corrole catalysts with applications to oxygen reduction in a PEM fuel cell. H. L. Buckley, D. T. Gryko, J. Arnold

177 Beyond the RSL: Taking an attributes-based approach to preferred chemicals. J. Rinkevich162. (4:00 p.m.) Development of a

thermodynamic database for rare metal recovery and recycling. I. Jung, M. Van Ende, Y. Kim, T. Kim

4:10 p.m. – 4:30 p.m.

158. Flow oxidations and reductions with heterogeneous catalysts. J. M. Hawkins

167. (4:15 p.m.) Lignin-based plastics and a hands-on biodiesel project for first-year engineering students. J. F. Stanzione, III, S. Farrell, R. P. Wool

173. Growing with Ingeo lactide derivatives. M. Natal

178. Hazard and risk assessment for process chemicals in textile factories: Practical considerations of process and utility. S. B. Moore

4:30 p.m. – 4:50 p.m.

163. (4:30 p.m.) Green technologies for Elemental Recovery and Sustainability. A. J. Hunt, H. L. Parker, A. Muñoz García, V. L. Budarin, L. Rylott, N. Bruce, J. H. Clark

168. (4:35 p.m.) 1,1-Dimethyl-2,3,4,5-tetraphenylsilole as a molecular rotor probe to investigate the microviscosity of imidazolium ionic liquids. R. E. Scalise, P. A. Caradonna, H. J. Tracy, J. L. Mullin, A. E. Keirstead

179. Is ‘blue’ the new green? P. Johnson

4:50 p.m. – 5:10 p.m.

159. Transforming organic synthesis from chemistry in organic media to chemistry in water: Suzuki-Miyaura cross-couplings. B. H. Lipshutz

169. (4:55 p.m.) Metal oxide nanostructures for CO2 photoreduction. L. B. Hoch, T. E. Wood, P. G. O’Brien, L. M. Reyes, K. Liao, G. A. Ozin

174. A pine-based solution for increasing recycled asphalt pavement content in new road construction. P. Williams, R. Severance

180. Archroma One Way sustainability tool. P. Cowell

164. (5:00 p.m.) Critical elements in electronic applications. N. T. Nassar

5:10 p.m. – 5:30 p.m.

170. (5:15 p.m.) Transforming from a student seminar series into an interdisciplinary campus center with help from the green chemistry community and the ACS Summer School. M. J. Mulvihill

181. Green chemistry challenge. L. Adams

5:30 p.m. – 5:50 p.m.

160. The development of new enzymatic platforms for accessing chiral amines. G. Hughes

Panel Discussion on e-waste and rare metals. 171. (5:35 p.m.) Effects of PFOS and other perfluorinated compounds on the permeability of a black lipid membrane model system. C. Martinez, S. Ferguson, D. Scoville, P. Novak, N. Mohapp

175. Use of soy and bio-based materials in industrial applications. L. Kim-Habermehl

182. EcoChem: Where the new value chains meet. N. Hawker

(5:55 p.m.) Concluding Remarks.

6:00 p.m. – 10:00 p.m. ACS Careers Workshop (Advanced registration required) - Glen Echo

7:00 p.m. – 9:30 p.m. 4th Annual ACS GCI Roundtable Poster Reception (Advanced registration required) - Ballroom D

SCHEDULE / Thursday, June 19, 2014

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7:30 a.m. – 3:00 p.m. Exhibitions Open — Grand Foyer

8:30 a.m. – 8:45 a.m. Welcome Remarks and Announcement of Student Poster Awards.

8:45 a.m. – 9:45 a.m. Keynote Address: “Innovation and the Green Chemistry Enterprise” Presented by Dr. Eric Beckman, George M. Bevier Professor of Engineering, University of Pittsburgh; Co-Director, Mascaro Center for Sustainable Innovation — Ballroom D


THEMATIC TRACKS ORGANIC CHEMISTRY NEW CHEMICAL FEEDSTOCKS CRITICAL MATERIALS CONSUMER PRODUCTS POLICY AND INNOVATION

TECHNICAL SESSIONS CATALYSIS IN GREEN CHEMISTRY

GREENING THE SUPPLY CHAIN USING BIOBASED CHEMICALS

PART II

USING EARTH ABUNDANT ELEMENTS TO REPLACE CRITICAL MATERIALS

GREENING THE SUPPLY CHAIN: DEFINING GREENER AND MORE SUSTAINABLE CONSUMER PRODUCTS

PART ITRENDS IN GREEN CHEMISTRY INNOVATION

Ballroom B Ballroom C White Flint Amphitheater Brookside A Ballroom A

J. Manley, OrganizerN. Strotman, Session Chair

J. Manley, OrganizerP. Williams , B. Comanita, Session Chairs

A. Phillips, Session Moderator

L. Sommer, OrganizerJ. Hutchison, Session Chair

J. Manley, OrganizerP. Sliva, Session Chair

M. Spitzer, K. Weber, K. Clansky, K. Roberts, J. Jackson, Organizers M. Spitzer, Session Chair

10:15 a.m. – 10:35 a.m.

184. Evolution of dirhodium(II) catalyzed oxidations by tert-butyl hydroperoxide for practical applications. M. P. Doyle, M. O. Ratnikov

189. Transforming waste gases to low carbon fuels and chemicals. M. Koepke

193. Investing in the future of materials innovation. C. Wadia

199. Johnson & Johnson’s Earthward process: Moving toward a healthy future. M. Chung, R. Predale

Introductory Remarks.

203. (10:20 a.m.) Economic benefits of green chemistry process innovations. R. P. Wool

10:35 a.m. – 10:55 a.m. 204. (10:40 a.m.) Lessons from the PureBond experience. T. Vogelsinger

10:55 a.m. – 11:15 a.m.

185. Asymmetric alkene hydrogenation with cobalt catalysts: Moving away from precious metals. M. R. Friedfeld, M. Shevlin, J. M. Hoyt, S. W. Krska, M. T. Tudge, P. J. Chirik

190. Solvent elimination from large scale processing of plant materials for purification of low abundance enzymes. R. Mehigh

194. Critical material alternatives energy applications: R&D at DOE. E. Rohlfing

200. Green products, green commerce, and life cycle assessment. M. H. Wolf

205. (11:00 a.m.) NGO trends driving innovation in green chemistry. E. Simon

11:15 a.m. – 11:35 a.m.

186. Effect of CO2 pressure and water on the Suzuki coupling of basic nitrogen containing substrates. C. Senter, A. Rumple, W. Medin-Ramos, D. Houle, L. Cheng, J. Fisk, B. Holden, P. Pollet, C. A. Eckert, C. L. Liotta

198. Fe(0) Nanoparticles as sustainable catalysts for the hydrogenation reaction and catalysts supports for the Huisgen condensation. A. H. Moores, R. Hudson, S. Ishikawa, M. Masnadi Khiabani, A. Castonguay, M. Bateman

Discussion

11:35 a.m. – 11:55 a.m.

187. Base metal catalysts for the synthesis of organoboron compounds. J. V. Obligacion

191. Green chemistry in the agrochemical industry: Chiral bio-based building blocks as starting material for crop protection compounds. M. P. Fleer, B. J. Verkuijl

195. Reductive disassembly of lignin and lignocellulose using earth-abundant catalysts. P. C. Ford, K. Barta, A. V. Iretskii, S. L. Scott

201. Execution, performance, and benefits of sustainable cleaning programs. N. B. Green, II

206. (11:30 a.m.) Turing greem chemistry into commercial reality: The Coca-Cola Company’s Global PlanBottle® Program. M. Schultheis

207. (11:45 a.m.) Constrained resources, sustainability, performance: Key drivers for innovation. J. Frazier

11:55 a.m. – 12:15 p.m.

188. Aggressive use of green technologies in the development of a benign manufacturing process for the potent PARP inhibitor, niraparib. K. M. Belyk, C. K. Chung, P. Bulger, B. Kosjek, N. Rivera, M. Scott, G. R. Humphrey, J. Limanto, D. C. Bachert, K. M. Emerson

196. Earth-abundant materials in energy sustainability: Encapsulation of iron pyrite (FeS2) nanoparticles in an elastic carbon matrix for Li-ion battery cathodes. T. S. Yoder, M. Tussing, J. E. Cloud, Y. Yang

(12:00 p.m.) Breakout discussion.

12:15 p.m. – 12:35 p.m.

231. Delivering performance and sustainability with polymers of itaconic acid into a market of changing trends, labels and laws. Y. Durant

197. Heterogeneous 1st row metal C-H oxidation catalyst derived from dicobalt octacarbonyl and 1,2-bis(diphenylphosphino)ethane. S. L. Collom, R. H. Crabtree, P. T. Anastas

202. The challenges involved in formulating green products for the I&I market. M. Gottardi

12:35 p.m. – 1:35 p.m. Lunch (on your own)

Eric J. Beckman, PhDGeorge M. Bevier Professor of EngineeringCo-Director, Mascaro Center for Sustainable InnovationUniversity of Pittsburgh

SCHEDULE / Thursday, June 19, 2014


gcande.org

22

THEMATIC TRACKS ORGANIC CHEMISTRY GREENER PROCESSES CRITICAL MATERIALS CONSUMER PRODUCTS POLICY AND INNOVATION

TECHNICAL SESSIONS

GREENER CHEMISTRY THROUGH KINETICS AND MECHANISTIC UNDERSTANDING

TOOLS AND METRICS FOR INDUSTRIAL IMPLEMENTATION OF GREEN CHEMISTRY

ENDANGERED ELEMENTS: CRITICAL MATERIALS IN THE SUPPLY CHAIN

GREENING THE SUPPLY CHAIN: DEFINING GREENER AND MORE SUSTAINABLE CONSUMER PRODUCTS

PART II

REGULATORY LANDSCAPE AND IMPLICATIONS FOR INNOVATION

Ballroom B Ballroom C White Flint Amphitheater Brookside A Ballroom A

J. Manley, OrganizerL. Desai, Session Chair

J. Manley, OrganizerR. Giraud, Session Chair

D. Constable, Organizer, Session ChairJ. Manley, OrganizerP. Sliva, Session Chair

M. Spitzer, K. Weber, K. Clansky, K. Roberts, J. Jackson, OrganizersL. Bergeson, Session Chair

1:35 p.m. – 1:55 p.m.

213. Understanding the pharmaceutically relevant maillard reaction. M. E. Kopach, S. W. Baertschi, M. E. Kobierski, M. Hawk, A. Dion, M. L. Williamson, C. H. Hyzer, P. J. Jansen

217. Coatings with improved eco-footprint through the use of polymer pigment composites. J. Bohling, D. Fasano

227. Transparency in cleaning product formulation: What do we know about ingredients and available hazard data? P. C. DeLeo, E. S. Williams, M. Ciarlo, C. Horne, B. Greggs

Introductory Remarks.

208. (1:40 p.m.) Setting up a new trend in EPA PMNs: Using the P2 page to your company’s advantage. L. Bergeson

1:55 p.m. – 2:15 p.m.218. Innovating with intent: Science and sustainability

at Eastman. D. Kossor (2:00 p.m.) Introductory Remarks.

224. (2:05 p.m.) R. Eggert 209. (2:00 p.m.) State chemical management initiatives’ undercurrent of green chemistry. E. Tipaldo

2:15 p.m. – 2:35 p.m.214. Mechanistic studies on the synthesis of sulfilimines

with Chloramine. T. G. Beutner, J. Nye, A. Ortiz, B. Remy, C. Sfouggatakis

219. Eco-footprint : A new tool for the Made in CHIMEXTM considered approach. S. Duprat de Paule

225. (2:25 p.m.) P. Chirik 228. Green chemistry alternatives: An industry perspective. J. T. Gannon 210. (2:20 p.m.) REACH: From Europe to Asia. S. Hong

2:35 p.m. – 2:55 p.m. 220. Program for assisting the replacement of industrial solvents (PARIS III). P. F. Harten

226. (2:45 p.m.) A. Matharu (2:40 p.m.) Q&A and Discussion.

2:55 p.m. – 3:15 p.m.

215. A few of my favorite rings: Catalysis inspired by macrocycles. V. M. Dong

221. Sustainability assessment and feedback model for development of pyrolysis processes to produce biofuels from waste pinewood chips: Framework and results. A. D. Patel, M. Zabeti, K. Seshan, M. Patel

(3:05 p.m.) Panel Discussion. 229. A review of the FTC’s guides for the use of environmental marketing claims (the ‘Green Guides’). L. Koss, L. Kim

211. (3:00 p.m.) Regulatory Approvals: The gatekeepers to commercialization. A. L. Shafer

3:15 p.m. – 3:35 p.m.

222. TRI’s pollution prevention search tool: New metrics for assessing progress in green chemistry and sustainability. D. Teitelbaum

212. (3:20 p.m.) Moving California towards flame retardant-free furniture and baby products. M. Green, C. Cox, J. Levin

(3:40 p.m.) Discussion and Brainstorm.

3:35 p.m. – 3:55 p.m. 216. Ru-catalyzed 1,4-dynamic kinetic resolution involving vinylogous enolates. N. A. Strotman, J. Deerberg, O. Soltani, D. Treitler

223. Tracking green chemistry advances using EPA’s Toxics Release Inventory. C. Keenan

230. Valuing natural capital in your supply chain. L. Bernick

3:55 p.m. – 4:15 p.m.

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