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    Basin Volume V 2400 m3

    Dry sludge [A] 4 Kg/m3

    Cell death rat Kd 0.06 l/day

    Substract utili A 0.6

    Input stream V 10 m3/min

    0.166666667 m3/sInput stream1[BOD] 135 mg/l

    1.35E+11 Kg/m3

    Input stream2[BOD] 200 mg/l

    0.2 Kg/m3

    out put strrea [BOD] 15 mg/l

    0.015 Kg/m3

    out put strrea [BOD] 20 mg/l

    0.02 Kg/m3

    b)

    [B]T1 0.015 kg/m3

    [B]1 0.135 kg/m3

    [B]T2 0.020 kg/m3 Solver

    [B]2 0.200 kg/m3 Left -0.0018

    [B]eq 0.005 kg/m3 Right -0.0018

    V 2400 m3V 0.1667 m3/s

    TB 14400 s 4 h

    vB -1

    [A] 4 kg/m3

    k 0.000208333 m3/kgs

    vA 0.6

    vad -1

    kd 0.06 1/day

    kd 6.94444E-07 1/s

    TA1 1800000 s 500 h

    TA2 847059 s 235 h AA

    BBK

    1

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    c) [A] 6.167 kg/m3

    TA 500 h

    d) V 1200 m3

    TB 7200 s 2

    [B]T1 0.02357143

    TB 7200

    TA1 614634 171

    [B]T2 0.00765306

    TB 7200

    TA2 -2756250 -766

    dAdeq k

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    eq

    B BB

    BB

    Ak ][][

    ][][

    ][

    1 0

    0

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    Given data:

    Basin Volume

    CSTR 1 VB1 4000 m

    CSTR 2 VB2 2000 m

    initial input stream Vdotini 250 m/h

    Concentration of biomass [A] 4 kg/m

    Cell death rate per day kd 0.025 1 /day

    Substrate utilisation vA 0.6

    vad -1

    vB -1

    Biological Oxigen Demand [B] 600 mg/l

    BOD of CSTR 1 [B] t1 35 mg/l

    BOD of CSTR 1+2 [B] t2 27 mg/l

    b) residence time CSTR 1 B1 16 [h]

    residence time CSTR 1+2 B2 24 [h]

    [B]eq 1.0301E-02 Kg/m

    [B]eq 10.301 mg/l

    K 0.357 m/(kg*h)

    h s

    c) For CSTR 1 4000m A 235.0 8.46E+05

    For CSTR 1+2 6000m A 393.8 1.42E+06

    d) Big ==>Small

    initial input stream Vdot

    ini 250 m/h

    Volume of 1st

    Reactor VR1 4000 m

    Volume of 2nd

    Reactor VR2 2000 m

    Small ==>Big

    initial input stream Vot

    ini 250 m/h

    Volume of 1st

    Reactor VR1 2000 m

    Volume of 2nd

    Reactor VR2 4000 m

    There is no different if stream passes the small basin first, the outlet BOD

    refer cre levenspiel

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    0212

    B

    BBB

    100

    Beq

    10

    1

    BCSTR

    q

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    [A] 4 kg/m

    vb -1

    vadd 0

    vA 0.6

    vad -1

    kd 0.025 1/d

    B) V flow V flow V [B] [B] [B]T [B]T

    m/h m/s m mg/l kg/m mg/l kg/m

    250 0.069444 4000 600 0.6 35 0.035

    250 0.069444 6000 600 0.6 27 0.027

    1/K 10072.13115

    K 9.92839E-05

    0.010300546

    C)

    V TA TB

    m3 s s

    4000 846022 57600

    6000 1417555 86400

    D) If it Passed through in series

    First 4000 then 2000 First

    As before the outlet of the first basin is the same so For

    [B]1 0.035 kg/m TB1

    TA1 846022 s [B]1

    TB1 57600 s TA1

    For 2000 m3 For

    TB2 28800 s [B]2

    [B]2 0.012286 kg/m TA2

    TA2 -5846175 s TB2

    No difference space time remains the same in total

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    TB x axis values

    s -

    57600 2.45226E-06

    86400 1.65799E-06

    2000 then 4000

    2000 m3

    28800 s

    0.057713568 kg/m

    394468.5025 s

    4000 m3

    0.012286432 kg/m-5846174.77 s

    57600

    0

    0.005

    0.01

    0.015

    0.02

    0.025

    0.03

    0.035

    0.04

    1.0E-06 1.5E-06 2.0E-06 2.5E-06

    [B]T

    Chart Title

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    3.0E-06

    Series1

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    Given Data

    V,react = 4000 m

    T = constant

    [A] = 4 kg / m

    kd = 0.025 1 / d

    0.00104 1 / hv,A = 0.6 substrate utilisation

    v,B = -1

    Permitted limit = [BOD] 40 mg / l

    0.04 kg / m

    a)

    b)

    V, m / h [B]o(mg/l) [B]mg/l [B]

    okg/m

    1996 162 680 26 0.68

    1999 168 608 25 0.608

    2000 228 612 31 0.612

    2001 267 604 34 0.604

    slope = 1 / k = 2.7245

    intercept = [BOD]eq = 0.0082

    k = 0.3670 m / (kg * h)

    [BOD]eq = 0.0082 kg / m

    c)

    volume basin 4000 m

    [B]o

    600 mg / L

    0.6 kg / m

    [B] 40 mg / L

    0.04 kg / mB 12.00 h

    V 333.46 m/h

    d)

    V

    VB

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    [B]o

    600 mg / L

    0.6 kg / m

    for [B] 40 mg / L

    Volume basin 2000 m

    B 2.26 h

    Required

    [B]1, kg/m [B]2, kg/m [B]2, kg / m Diff V (m / h)

    0.15 0.04 0.04 1.9791E-09 886.01

    V

    VB

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    [B]kg/m B (h)([BOD] - [BOD]

    o)/

    vB*[A]*B

    0.026 24.69 0.0066

    0.025 23.81 0.0061

    0.031 17.54 0.0083

    0.034 14.98 0.0095y = 2.724

    R =

    0

    0.005

    0.01

    0.015

    0.02

    0.025

    0.03

    0.035

    0.04

    0.0000 0.0020 0.0040

    V

    V

    B

    eq

    BB

    o

    B

    B BOD

    A

    BODBOD

    k

    BOD

    1

    eq

    B

    BBB

    BB

    Ak ][][

    ][][

    ][

    1 0

    0

    oB BODBOD 1

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    eqBBB

    Ak

    1][

    ][][][][

    Ak

    BBAkB

    BB

    eq

    BB

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    x + 0.0082

    0.9973

    0.0060 0.0080 0.0100

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    V,react = 4000 m

    T = constant

    [A] = 4 kg / m

    kd = 0.025 1 / d

    0.001041667 1 / h

    v,A = 0.6substrate

    utilisation

    v,B = -1

    Permitted limit = 40 mg / l0.04 kg / m

    V, m / h [B]o, mg/l [B]t, mg/l [B]o, kg/m [B]t, kg/m

    1996 162 680 26 0.68 0.026

    1999 168 608 25 0.608 0.025

    2000 228 612 31 0.612 0.031

    2001 267 604 34 0.604 0.034

    Slope 2.7245265980.0100

    Improvement of an activated sludge system

    Into an industrial activated sludge system of 4000m (CSTR basin) the volume flow of

    concentration has decreased (long duration average values):

    volume flow inlet concentration outlet concentra

    1996 162m/h 680mg/l 2

    1999 168m/h 608mg/l 2

    2000 228m/h 612mg/l 3

    2001 267m/h 604mg/l 3

    Your task is to predict the maximum volume flow related to the permitted limit of 40mg/l

    a) without any change in the process and

    b) when the basins will be divided in two parts of 2000m each and passed in ser

    Assume a multi-component substrate and ideal CSTR conditions in all basins. The conce

    basins is to be estimated to 4kg/m and the normal cell death rate to 2,5% per day (kd= 0,

    = 0,6). The temperature in the system is constant!

    b) Calculate the equilibrium concentration of BOD [BOD]eqand the rate constant k

    (graphical solution possible)! The linearized form of the equation for residence ti

    eq

    BB

    o

    B

    B BOD

    A

    BODBOD

    k

    BOD

    1

    Draw an adequate diagram!

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    Intercept 0.008202071

    K 0.3670 m / (kg h)

    [BOD]eq 0.0082 kg/m3

    Inlet [ ] 600 mg/l

    0.6 kg/m3

    Outlet [ ] 40 mg/l

    0.04 kg/m3

    12.00 h

    Max volume 333.46 m3/h

    Volume Basis 2000 m3

    4000 m3

    Inlet [ ] 600 mg/l

    0.6 kg/m3

    Outlet [ ] 40 mg/l

    0.04 kg/m3

    2.26 h

    Volume flow 886.00 m3/h

    y = 0.366x -

    R = 0.99

    0.0000

    0.0010

    0.0020

    0.0030

    0.0040

    0.0050

    0.0060

    0.0070

    0.0080

    0.0090

    .

    0 0.01

    c) Calculate for the 4000m basin the maximum volume flow for an estimated inlet

    limit of 40mg/l using the two coefficients from b) or take the value from the dia

    d) Calculate (iteration) for the two 2000m basins in series the maximum volume f

    600mg/l and an outlet limit of 40mg/l using the two coefficients from b)!

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    Outlet

    concentration B1

    [kg/m3]

    Outlet

    concentration B2

    [kg/m3]

    Final

    concentration

    required [kg/m3]

    Difference

    0.145379 0.040 0.04 0.000

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    Residence

    timeBig Equation

    24.69 0.0066

    23.81 0.0061

    17.54 0.0083

    14.98 0.0095

    astewater has increased, while the outlet

    tion

    6mg/l

    5mg/l

    1mg/l

    4mg/l

    in the outlet

    ies.

    tration of biomass (dry sludge [A]) in the

    25d-1

    ). The substrate utilisation is 60% (A

    from the given data by linear regression

    me is

    11 points

    eq

    BB

    o

    B

    B BOD

    A

    BODBOD

    k

    BOD

    1

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    0.003

    73

    0.02 0.03 0.04

    Big Equation

    Linear (Big Equation)

    concentration of 600mg/l and an outlet

    ram!

    4 points

    eq

    B

    BBB

    BB

    Ak ][][

    ][][

    ][

    10

    0

    low for an estimated inlet concentration of

    6 points

    eq

    B

    BBB

    BB

    Ak ][][

    ][][

    ][

    10

    0

    1][

    ][][][][

    Ak

    BBAkB

    BB

    eq

    BB

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    V,react 4000 m

    T constant

    [A] 4 kg / m

    kd 0.025 1 / d

    0.00104 1 / h

    v,A 0.6 substrate utilisation

    v,B -1

    Permitted limit 40 mg / l

    0.04 kg / m

    a)

    b)

    V, m / h [B]o(mg/l) [B]mg/l [B]

    okg/m [B]kg/m

    1996 162 680 26 0.68 0.026

    2001 267 604 34 0.604 0.034

    Slope = 1/K 2.76804636

    [B]eq 0.007671 kg / mk 0.3613 m / (kg * h)

    c)

    [B]omg/l [B]

    okg/m tB (h) V (m/h)

    580 0.58 11.56 346.06

    600 0.6 11.99 333.70

    620 0.62 12.41 322.19640 0.64 12.84 311.45

    d)

    BB

    B

    B

    A

    BODBOD

    k

    BOD

    1

    eq

    B

    BBB

    BB

    Ak ][][

    ][][

    ][

    1 0

    0

    V

    VB

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    V,each 1330 m

    V,total 3990 m

    [B]t 0.04 kg / m

    V, m / h t,B, h [B]2, kg/m [B]1, kg/m [B]0, kg/m

    800 1.66 0.1177 0.3819 1.2811

    1000 1.33 0.1021 0.2837 0.8142

    1200 1.11 0.0918 0.2265 0.5769

    V

    VB

    kBB ][][ 0

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    600

    700

    800

    900

    1000

    1100

    1200

    1300

    0.0000 0.5000 1.0000 1.5000

    Volumeflow,m/h

    Inlet concentration, kg/m

    Volume flow vs. Inlet concentration

    First Basin

    Second Basin

    Third Basin

    eqBB BBA ][][][ 0

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    T constant

    [A] 4 kg / m

    kd 0.025 1 / d

    0.00104 1 / hv,A 0.6

    v,B -1

    [BOD] 20 mg / l

    0.02 kg / m

    a)

    b)

    V, m / h [B]o(mg/l) [B]mg/l [B]

    okg/m [B]kg/m B (h)

    ([BOD] -

    [BOD]o)/

    vB*[A]*B

    160 680 20 0.68 0.020 0.00 #DIV/0!

    180 600 20 0.6 0.02 0.00 #DIV/0!

    220 580 20 0.58 0.02 0.00 #DIV/0!

    slope = 1 / k = #DIV/0!

    intercept = [BOD]eq = #DIV/0!

    k = #DIV/0! m / (kg * h)

    [BOD]eq = #DIV/0! kg / m

    substrate utilisation

    eq

    BB

    o

    BB BOD

    A

    BODBOD

    kBOD

    1

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    Given Data

    V,react 5000 m

    T constant

    [A] 4 kg / m

    kd 0.025 1 / d

    0.00104 1 / h

    v,A 0.6

    v,B -1

    Permitted limit = [BOD] 20 mg / l

    0.02 kg / m

    a)

    b)

    V, m / h [B]o(mg/l) [B]mg/l [B]

    okg/m

    1995 220 580 30 0.58

    1998 250 520 32 0.52

    2001 270 510 33 0.51

    2004 300 470 35 0.47

    slope = 1 / k = 7.9484

    intercept = [BOD]eq = -0.0174

    k = 0.1258 m / (kg * h)

    [BOD]eq = -0.0174 kg / m

    c)

    Total

    volume basin 5000 m V

    [B]o

    400 mg / L volume basin

    0.4 kg / m B

    [B]2 20.00 mg / L [B]o

    0.02 kg / m

    B 20.19 h [B]1 = [B]o2

    V 247.68 m/h

    substrate utilisation

    0

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    d)

    V 272.68 m/h

    volume basin 2500 m

    B 9.17 h

    [B]o

    400.00 mg / L

    0.40 kg / m

    [B]2 0.05695 kg / m

    56.95 mg / L

    diff [B]2 0.00570 kg / m

    5.70 mg / L

    with additionally flow

    influence of the bypass flow on the outlet concentration

    eq

    B

    BBBAk ][][][ 0

    ][ k

    B

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    [B]kg/m B (h)([BOD] - [BOD]

    o)/

    vB*[A]*B

    0.030 22.73 6.05E-03

    0.032 20.00 6.10E-03

    0.033 18.52 6.44E-03

    0.035 16.67 6.53E-03

    First

    247.68 m/h

    2500 m

    10.09 h

    400 mg / L

    0.4 kg / m

    0.05125 kg / m

    51.25 mg / L

    y = 7.9484x - 0.

    R = 0.829

    0.029

    0.030

    0.031

    0.032

    0.033

    0.034

    0.035

    0.036

    6.00E-03 6.10E-03 6.20E-03 6.30E

    V

    V

    B

    eq

    BB

    o

    B

    B

    BOD

    A

    BODBOD

    k

    BOD

    1

    101

    00

    1

    AK

    BBAKB

    BB

    eqBB

    V

    V

    B

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    1][

    ][][][

    Ak

    BBA

    BB

    eq

    BB

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    0174

    -03 6.40E-03 6.50E-03 6.60E-03

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    Given Data

    input stram 15.6 m3/min 0.26 m3/sec

    T constant

    [A] 4 kg / m

    kd 0.025 1 / d

    0.00104 1 / h 2.89352E-07 1/sv,A 0.6 substrate utilisation

    v,B -1

    [BOD] 25 mg / l

    0.025 kg / m

    [BOD] 500 mg/l

    0.5 kg/m3

    lab

    [A] 1000 mg/l

    1 kg/m3

    y axis x axis

    time in minseconds [BOD] in mg/l in kg/m3

    30 1800 135 0.135 0.000203 slope 634.17 1/K

    60 3600 40 0.04 0.000128 int 0.0064 BOD EQ

    120 7200 12 0.012 6.78E-05 K 0.001577 1/s

    1440 86400 10 0.01 5.67E-06

    Tau A 2142.636312 sTau B 4048.800403 s

    Volume of basiin 1052.688 m3

    BBOD

    dAdeqA

    AkBBK

    1

    eqB

    BBB

    BB

    AKV

    V

    0

    0

    1

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    0.135

    0.01

    y = 634.17x + 0.0064

    R = 1

    0

    0.02

    0.04

    0.06

    0.08

    0.1

    0.12

    0.14

    0.16

    0 0.00005 0.0001 0.00015 0.0002 0.00025

    Series1

    Linear (Series1)

    eq

    BB

    o

    BBOD

    A

    BODBOD