Active Protection of Fiber-Reinforced Polymer Corrosion--libre

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    CORROSION SCIENCE SECTION

    CORROSIONVol. 67, No. 2 025002-1

    Submitted for publication March 19, 2009; in revised form, June24, 2010.

    Corresponding author. E-mail: [email protected]. * Department of Civil Engineering, Indian Institute of Technology

    Bombay, Mumbai 400076, India.** Indian Institute of Technology Bombay, Mumbai 400076, India.

    Present address: Thapar University, Patiala 147004, India.*** Department of Material Science and Metallurgical Engineering,

    Indian Institute of Technology Bombay, Mumbai 400076, India.

    Active Protection of Fiber-Reinforced Polymer-Wrapped Reinforced Concrete StructuresAgainst Corrosion

    S. Gadve,,* A. Mukherjee,** and S.N. Malhotra***

    ABSTRACT

    Large numbers of reinforced concrete (RC) structures that have

    been damaged from corrosion of steel reinforcements are reha-

    bilitated with fiber-reinforced polymer (FRP) composites. This

    paper investigates active protection of the steel embedded

    in concrete that is treated with surface-bonded carbon FRP.

    The electrically conductive carbon fiber is used as an anode

    while the reinforcing bar is used as a cathode. Concrete cyl-

    inder specimens with embedded steel bars are immersed in

    salt water, and anodic current is passed through the reinforce-

    ment to initiate cracking in concrete as a result of acceler-

    ated corrosion of steel. Carbon FRP sheets have been bonded

    adhesively to the cylinders. The adhesive has been modified

    to impart electrical conductivity. Specimens were exposed to

    a highly corrosive environment for a specified time. Pullout

    strength, mass loss, potentiodynamic scans, and the half-cell

    potential of steel are reported as metrics of performance of the

    samples. The proposed technique has been very effective inretarding the corrosion of steel.

    KEY WORDS: active protection, anodic current, corrosion, fiber-

    reinforced polymer, pullout strength, reinforced concrete

    INTRODUCTION

    Reinforced concrete has been developed and applied

    extensively for a century. However, there are many

    instances of premature failure of reinforced con-crete components from corrosion of reinforcement.

    The economic implications of such damage are enor-

    mous. Overall, repair and maintenance of reinforced

    concrete structures cost 1% to 2% of the yearly rate

    of new construction. In a tropical country like India,

    where approximately 80% of the annual rainfall takes

    place in the two monsoon months, corrosion-related

    problems are more alarming. India also has a very

    long coastline where marine weather prevails. Typi-

    cally, a building in the coastal region requires major

    restoration work within 15 years of its construction.

    Recent developments in the field of fiber-rein-

    forced polymer (FRP) have resulted in highly efficient

    construction materials. FRP are being used increas-

    ingly to rehabilitate corrosion-affected structures. FRP

    sheets are wrapped around beams and columns to

    rehabilitate them from the loss of shear capacity and

    confinement attributable to the corrosion of links or

    stirrups. The efficiency of FRP in the enhancement of

    bending,1shear capacities of flexure elements,2and

    enhancement of concrete confinement in compres-

    sion elements3is well established. An important spin-

    off from the FRP treatment of RC structures can be

    their resistance to corrosion. There have been vari-

    ous attempts of passive protection of steel reinforce-ments with surface-bonded FRP, both in labs and

    ISSN 0011-9312 (print), 1938-159X (online)11/000013/$5.00+$0.50/0 2011, NACE International

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    at sites.4FRP are unaffected by electromechanical/

    electrochemical deterioration and can resist aggres-

    sive corrosive effects of acids, alkalis, salts, and simi-

    lar aggregates under a wide range of temperatures.

    Therefore, unlike steel reinforcement, they are less

    susceptible to environmental degradation. Arguably,

    FRP wraps prevent the increase in the volume of rein-

    forced concrete (RC) members from rusting by apply-

    ing confinement pressure, thereby resisting dislodging

    of the concrete cover.

    The FRP wraps provide a barrier layer that should

    impede further corrosion of the steel. Site applications

    have been on structures that have been damaged by

    corrosion.5FRP has been applied primarily to com-

    pensate for the lost steel and to improve confinement

    of the concrete. However, there is near unanimity that

    FRP wraps have slowed down the rate of corrosion,

    albeit in varying degrees. The experience of the pres-

    ent authors on the performance of glass fiber-rein-

    forced polymer (GFRP) wraps on RC in coastal Gujarathas been very good. The FRP wraps in the corrosion-

    affected areas have not shown any sign of deteriora-

    tion in six years.

    The general procedure of laboratory experiments

    has been to accelerate corrosion in steel embedded in

    concrete and then apply the FRP to observe its effects

    on corrosion.6-21Corrosion has been accelerated

    through the application of impressed potential on the

    reinforcements7,10,14,16or by simulating wet and dry

    cycles in chloride-rich environments.22The main indi-

    cators of performance are mass loss of reinforcement,

    pullout strength, electric resistance, half-cell poten-tials, and potential scans. The suitability of perfor-

    mance indicators depends on the method of imparting

    corrosion. It is noted that the benefit of FRP depends

    on several factors, such as adhesive, fiber, method of

    application, and environment.

    So far, researchers have used FRP as a passive

    barrier layer that would impede ingress of moisture

    and corrosive chemicals. One class of FRP, namely

    carbon FRP (CFRP), is electrically conductive. There-

    fore, they may be used in the active protection of RC

    structures. The authors are unaware of any previ-

    ous investigation on the active protection of the steel

    using FRP. This paper investigates the use of FRP

    wraps for active protection of steel in concrete. We

    briefly introduce active protection.

    ACTIVE PROTECTION

    The corrosion of steel reinforcing bars is an elec-

    trochemical process that requires a flow of electric

    current and several chemical reactions. The three

    essential components of a galvanic corrosion cell are

    anode, cathode, and electrolyte. At the anode, iron is

    oxidized to the ferrous state and releases electrons:

    Fe e +e ++ 2 (1)

    hese electrons migrate to the cathode where they

    com ine with water and oxygen to orm hydroxyl ions:

    2e O OO

    + +++ O+ O

    (2)

    he hydroxyl ions com ine with the errous ions to

    orm errous hydroxide (Fe[OH]2):

    e e++ 2( ) (3)

    In the presence of water and oxygen, the Fe(OH)2is

    oxidized urther to orm erric oxide (Fe2O3):

    2

    2 2 2

    3 2 2

    Fe O HH

    2 2

    H

    2 2

    F4Fe

    Fe Fe O HH

    2

    H

    2

    O

    HH )O H

    HH

    + +

    2 2

    +

    2 2

    H+H

    2 2

    H

    2 2

    +

    2 2

    4H

    2 2

    O FF

    2

    2

    e ee e

    2

    e

    2

    2

    2e

    2

    HHHH

    2

    H

    2

    2

    2H

    2

    (4)

    Corrosion of steel in concrete in the presence of chlo-

    ides, but with no oxygen (at the anode), takes placen several steps. At the anode, iron reacts with chlo-

    ide ions to orm an intermediate solu le iron-chloride

    complex:

    Fe e+ +22 2 2 )Cl 2222+ 22e 2e 2 222 2 2 2 2 2 22e 2 22 2 22 2 2 (5)

    When the iron-chloride complex diffuses away from

    the ar to an area with higher pH and concentra-

    tion o oxygen, it reacts with hydroxyl ions to orm

    Fe(OH)2. This complex reacts with water to orm

    Fe(OH)2

    ( Fe Cl

    HO

    Cl+ ++ + +++222

    2 2

    Cl 2l + 2+ 2+l +l 2l +l 2 222e F 2F 2O 2O 2H2H2 2 + +2 + 22222O 2O 2 2 2 22 222 222 2O 2O 2O 2O 22 2H2H2 H 2H22 2 2 2 F 2 (6)

    he hydrogen ions then combine with electrons to

    form hydrogen gas:

    eee

    e e e (7)

    As in the case of corrosion of steel without chlorides,

    the Fe(OH)2, in the presence o water and oxygen, is

    oxidized urther to orm Fe O3:

    2

    2 2 2 3

    3 2 2

    Fe O HH

    2 2

    H

    2 2

    F4Fe

    Fe Fe O HH

    2

    H

    2

    O

    HH )O H

    HH

    + +

    2 2

    +

    2 2

    H+H

    2 2

    H

    2 2

    +

    2 2

    4H

    2 2

    O FF

    2

    2

    e ee e

    2

    e

    2

    2

    2e

    2

    HHHH

    2

    H

    2

    2

    2H

    2

    (8)

    he principle of active protection lies in connecting

    an external anode to the metal to e protected and

    the passing o an electric direct current to make all

    areas o the metal sur ace cathodic. There ore, the

    onization illustrated in Equations (1) and (5) is pre-

    vented. The external anode may e a sacri icial gal-

    vanic anode, where the current is a result of the

    otential difference between the two metals, or it may

    e an impressed current anode, where the current is

    mpressed rom an external direct current (DC) power

    source. In this paper, we investigate the impressedcurrent anode system. In the impressed current

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    system, an inert (zero or low dissolution) anode is

    used and an external source of DC power is used to

    impress a current from an external anode onto the

    cathode (reinforcing steel) surface. The issues on

    active protection of RC structures are:

    to create an anode around the structure

    to maintain adequate electric potential

    to avoid sympathetic damage as a result of

    overprotection

    There have been many alternative anode sys-

    tems developed for active protection to RC structures,

    such as highway bridge substructures, buildings, and

    marine structures.23A variety of anodes, such as tita-

    nium wire titanium strip,24titanium mesh,25and zinc

    spray,26and conductive systems, such as conductive

    concrete mortar27and carbon fiber-reinforced over-

    lay,24have been attempted by the researchers. The

    driving voltages for protection vary with the type of

    anode and environmental conditions. Typical operat-

    ing current densities range between 0.2 mA/m2and2.0 mA/m2for the cathodic prevention of new rein-

    forced concrete structures and between 2 mA/m2and

    20 mA/m2for cathodic prevention of existing salt-

    contaminated structures.28A cathodic current density

    of 5 mA/m2to 20 mA/m2to the steel reinforcement

    reduces its corrosion rate to negligible values.27Over-

    voltage or higher current densities for prolonged peri-

    ods may lead to damages such as degradation of the

    steel-concrete bond, which is associated with soften-

    ing of the cement matrix in contact with the metal.29-30

    There has been an enhanced risk of expansive alkali

    silica reaction in cathodic regions of concrete with sili-ceous aggregates. It has been reported that the risk is

    reduced considerably if the cathodic current density is

    maintained uniformly and consistently at a level lower

    than 20 mA/m2.26Although significant research has

    been done on the active protection of RC, the applica-

    tion of the technique has remained meager because

    of the requirement of special anodes that are often

    expensive.

    In a previous investigation, the authors have

    reported the efficacy of FRP wraps for passive protec-

    tion of RC structures.31In addition to passive protec-

    tion, the FRP materials that are electrically conductive

    can be designed to offer active protection as well. This

    has not been reported so far.32With the FRP wraps

    acting as anode, no other anode would be necessary.

    Therefore, the cost of active protection can be brought

    down significantly. Present work investigates active

    protection using surface-bonded CFRP sheets as the

    anode.

    Laboratory samples of RC specimens were pre-

    pared. To initiate corrosion, the specimens were

    exposed to accelerated corrosion by impressing anodic

    current into the reinforcing bar. After a specific period

    of exposure, the cracked RC specimens were treated

    with surface-bonded FRP. The samples were activelyprotected while subjecting them to a specified envi-

    ronment in a salt mist chamber for a specific period.

    Results of actively protected samples have been com-

    pared with that of unprotected and passively pro-

    tected ones.

    EXPERIMENTAL PROCEDURES

    The experimental program was carried out in the

    following steps:

    Cylindrical reinforced concrete specimens were

    cast.

    Initial corrosion was induced into the reinforced

    concrete specimens.

    Precorroded specimens were wrapped with

    CFRP and GFRP sheets.

    The wrapped specimens were subjected to fur-

    ther corrosion by exposing them to salt mist

    while applying active protection.

    Corrosion was monitored.

    Destructive tests were carried out.

    Preparation of Test SpecimensIn the present program, cylindrical specimens

    with an embedded steel bar (Figure 1) were used. The

    height and diameter of the specimen were 230 mm

    and 100 mm, respectively, with an accuracy of 1 mm.

    A standard reinforcing bar of 330 mm length and

    12 mm nominal diameter of Fe 415 grade was used.

    The bar was shot-blasted to Sa 2.5 (ISO 8501:1)33

    sur-face and immediately dipped in oil. The white shining

    FIGURE 1. Cylindrical-reinforced concrete specimen.

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    surface was maintained in the laboratory until it was

    embedded in concrete. Before placing the bar in con-

    crete, a 2-mm-diameter groove was drilled on one end

    of the bar and a copper stud was fixed in the groove.

    The plug was used for electrical connections. Polytet-

    rafluoroethylene (PTFE) tape was wound around the

    bar at two locationsthe bottom edge and at the

    interface with the concrete top face. This served as a

    bond breaker, and the embedded length of the bar in

    concrete was maintained precisely at 152 mm. The

    bar was placed in such a way that the transverse

    clear cover was 45 mm and the bottom cover was

    51 mm. Before casting of the test specimens, each

    reinforcing bar was weighed to a 0.1-gm accuracy.

    The protruded part of the steel bar was coated with

    liquid epoxy resin for corrosion protection.

    Ordinary Portland cement of nominal strength

    (43 MPa), fine aggregate (medium-sized natural/

    river sand), and crushed stone coarse aggregate with

    a maximum size of 20 mm was used in the con-crete. The ratio of cement:sand:coarse aggregate

    was 1:2.16:2.44. The water-cement ratio was 0.42and aggregate-cement ratio was 4.6. The resulting

    strength of concrete was 40 MPa.

    A special molding system (Figure 2) was fabri-

    cated for casting the specimens. The system is able to

    maintain accurately the position and inclination of the

    bar with respect to that of the cylinder.

    Inducing CorrosionThe objective of inducing corrosion to the bar is to

    simulate corrosion-damaged concrete. The commonly

    used methods of inducing corrosion in RC specimens

    are salt mist,11,14,18

    chloride diffusion,19-21

    alternatedrying and wetting in salt water,14,19and impressing

    anodic current.10,16

    In this investigation, the impressed current tech-

    nique has been used. Specimens were kept immersed

    in 3.5% sodium chloride (NaCl) solution for 24 h to

    ensure full saturation. A stainless steel mesh rolled

    into a hollow, open cylinder was used as the cathode

    (Figure 3). The cathode and the specimen were placed

    in 3.5% NaCl solution. The level of NaCl solution was

    3 cm below the top surface of the specimen to allevi-

    ate corrosion at the steel-concrete interface. The

    DC-regulated power supplier (DCRPS) used in the

    present study could supply 500 mA DC at 60 V. The

    reinforcing steel bar was connected to the positive

    terminal of the external DC source and the negative

    terminal was connected to the stainless steel mesh.

    The 100-mA direct electrical constant current (CD =

    1,740.67 A/cm2) was impressed between the rein-

    forcing bar and the stainless steel mesh. It is more

    common to maintain a constant voltage between the

    cathode and the anode.6-7,19However, in this inves-

    tigation, a constant current was preferred because

    the goal of this investigation was to examine the

    active protection through maintenance of constant

    cathodic current. A total of 12 specimens was usedin this experiment, divided into three groups. Con-

    FIGURE 2. Specimen casting system.

    FIGURE 3. Schematic representation of the device for accelerated

    corrosion.

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    stant current was impressed for 2 days, 4 days, and

    8 days into four specimens of each group, respec-

    tively. Anode-to-cathode voltage, corresponding to a

    constant current of 100 mA, was monitored every day

    for all specimens. Half-cell potential of the corroding

    reinforcement bar was also noted every day with ref-

    erence to a standard silver/silver chloride (Ag/AgCl)

    electrode. Using this method, the concrete was found

    to develop cracks within 2 days. There were brown

    stains of rust on the concrete. The crack widths were

    measured after 2 days, 4 days, and 8 days. Potentio-

    dynamic electrochemical anodic polarization scans

    were obtained for all the specimens after initial cor-

    rosion. Cracks initiated at the surface of the cylinder

    and ran along the direction of the reinforcement on

    the sides of the cylinder (Figure 4). Voltage between

    the reinforcing steel anode and stainless steel mesh

    cathode decreased with time, indicating that the resis-

    tance lessened with the progression of the crack.

    Wrapping of Precorroded SpecimensTwo fiber materials are popular in the rehabilita-

    tion of structures in Indiaglass and carbon. Because

    of the electrical conductivity of carbon fiber, only CFRP

    has been used for active protection. However, compar-

    ison has been made between the active and the pas-

    sive protection offered by both glass and carbon fiber

    sheets. The fibers are applied in the form of unidirec-

    tional sheets. Glass fiber sheets are thicker than the

    carbon fiber sheets. In this investigation, two often

    used, commercially available, unidirectional CFRP and

    GFRP sheets and compatible epoxy adhesive are used.Properties of the sheets are presented in Table 1.

    Samples were air-dried prior to the application of

    FRP wraps. Manufacturers specification was followed

    in the application of the wraps. Out of the four speci-

    mens in a group, one was kept unwrapped. One layer

    of either CFRP or GFRP sheet was wrapped around

    the test specimens with the fiber along the circumfer-

    ential direction of the cylinder. The entire length of the

    cylinder was covered. A 25-mm overlap was provided

    at the ends of the sheets. The remaining specimens

    were used for active protection. These CFRP-wrapped

    test specimens were provided with additionally adhe-

    sively bonded 25-mm to 30-mm wide, vertically ori-

    ented carbon sheet (Figure 5) to facilitate uniform

    distribution of direct current throughout the speci-

    men for effective active protection. The epoxy adhesive

    used was modified to be conductive.32

    Active ProtectionSince carbon is electrically conductive, an

    attempt was made to use this property in apply-

    ing active protection to the reinforced concrete sys-

    tem without using any external anode. In this case,

    the carbon fiber sheets that were wrapped around the

    cylindrical reinforced concrete specimen themselves

    were used as anodes and the reinforcing steel bar as

    FIGURE 4. Specimens after initial exposure.

    FIGURE 5. Schematic representation of cathodically protected

    specimen.

    TABLE 1Properties of Fibers Used in the Experiment

    Thickness Tensile Tensile Ultimate Electrical

    Material (mm) Strength (GPa) Modulus (GPa) Strain Conductivity (s/cm)

    Carbon sheet (net fiber) (CS) 0.13 3.79 230 0.015 551

    Glass sheet (net fiber) (GC) 0.35 2.30 76 0.018 Adhesive 15 4.3 0.02

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    cathode. To achieve this, the wrapping system had to

    be modified in two ways.

    One of the requirements of the system was to

    make its electric conductivity uniform. A ribbon of

    carbon fibers was stitched through the CFRP sheet in

    the perpendicular direction of the fibers. The ribbon

    was extended beyond the sheet by about 25 mm. It

    was used as the anode terminal for supplying electric-

    ity to the CFRP sheet. The ribbon pressed against the

    fibers of the sheet and ensured proper contact and

    uniform conductivity.32The only non-conductive part

    in the system was the epoxy adhesive used to bond

    carbon sheets onto the concrete. In the present study,

    the epoxy was made conductive by mixing conductive

    particulates into the epoxy. The conductive particu-

    lates that were used are commercially available graph-

    ite powder of particle size in the range from 0.1 to

    10 . An experiment was carried out to find the opti-

    mum amount of the particulate to be mixed into theepoxy, such that the epoxy became sufficiently con-

    ductive without losing the required consistency for

    proper coverage of the concrete surface. The workabil-

    ity and conductivity were studied by adding 2% to

    20% conductive particulates by weight of epoxy.32

    An external DC power supply was used to

    impress the constant current for active protection. The

    positive terminal of the DC power supplier was con-

    nected to the protruding ribbon of the carbon sheet

    and the negative terminal was connected to the rein-

    forcing bar, to be protected from corrosion. A constant

    current of 50 mA (current density = 870 A/cm2) was

    impressed between the carbon fiber, cathode and rein-

    forced steel, anode. To simulate the practical condi-

    tion of applying active protection to the reinforced

    concrete structures in a corrosive environment, the

    specimens were kept in a salt mist chamber, with all

    necessary electrical connections for active protection,

    for 60 days (Figure 6).

    Exposure of Wrapped SpecimensTo simulate corrosion-damaged structures, prior

    to the application of the wrap, an initial exposure

    was applied. In practice, the FRP wraps are applied

    on structures that are corroded to varying degrees.

    Therefore, different exposure durations were cho-

    sen prior to the application of the wrap. Three expo-

    sure durations2, 4, and 8 dayswere applied. The

    details of the samples are presented in Table 2. In two

    days, the first crack appeared in all the samples. In

    4 days and 8 days, the crack became wider and cor-

    rosion products oozed out in larger volumes. The con-

    trol samples were not wrapped. GPP and CPP indicatepassive protection with glass and carbon FRP wraps,

    respectively. CAP indicates active protection that is

    active protection applied to the RC specimens using

    carbon FRP wraps.

    All specimens with varying degrees of initial cor-

    rosion, both control and treated, then were exposed to

    a severe corrosive environment created in a salt mist

    chamber. The salt mist chamber was designed accord-

    ing to IS 1186434(Figure 6). The salt mist test was

    carried out with 5% NaCl solution at 50C. Injection

    of salt fog was put on for 8 h and put off for 16 h,

    keeping the samples in the chamber. On switching

    off, the temperature inside the chamber subsequently

    would have come down to ambient temperature

    (~27C). The total duration of exposure in the salt

    mist chamber under the specified condition was

    1,500 h, i.e., 60 days.

    Corrosion MonitoringSeveral parameters have been monitored during

    the entire process. Some of these are nondestructive,

    such as half-cell potential, cell voltages, and potentio-

    dynamic scans. These studies were carried out simul-

    taneously on all specimens. Half-cell potential was

    noted every day. Cell voltages were observed every dayduring induction of initial corrosion by impressing the

    FIGURE 6. Passive protection and active protection applied to FRC-

    wrapped specimens exposed to salt mist.

    TABLE 2Test Specimens

    Wrap Anodic Salt

    Material Current Mist Protection Nomenclature

    Unwrapped 2 60 No Control-24 60 No Control-48 60 No Control-8

    Glass 2 60 Passive GPP-24 60 Passive GPP-48 60 Passive GPP-8

    Carbon 2 60 Passive CPP-24 60 Passive CPP-48 60 Passive CPP-8

    Carbon 2 60 Active CAP-24 60 Active CAP-48 60 Active CAP-8

    Exposure in

    Days

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    Mass Loss

    TABLE 3Pullout Strength and Mass Loss

    Percent Pullout

    Difference Strength

    Specimen Percentage (Equation [9]) (MPa)

    Control-2 6.47 8.86Control-4 4.29 5.87Control-8 10.71 5.21GPP-2 2.86 55 12.99GPP-4 2.5 42 13.05GPP-8 8.57 20 11.15CPP-2 6.2 5 13CPP-4 4.6 7 10.32CPP-8 8.27 23 11.2CAP-2 1.65 75 7.81CAP-4 1.38 68 4.15CAP-8 2.87 73 5.63

    The lack of corrosion products in actively protected

    samples does not lead to the improvement in grip.However, this point should be examined before arriv-

    ing at a firm conclusion. The authors are planning

    another set of experiments by varying the protection

    current density. The microstructure of the bar-con-

    crete interface shall also be studied.

    The variations of mass loss with pullout strength

    for all the specimens are plotted in Figure 10. A lin-

    ear fit though the data of different systems has been

    carried out. Understandably, pullout strength varies

    inversely with the mass loss, i.e., corrosion reduces

    bond strength. The rate of loss of pullout strength in

    CPP and GPP samples is the lowest. This illustratesthat even with the same level of corrosion, the pas-

    sively protected specimens exhibit a better bond with

    concrete. As a result of corrosion, the bars exert a

    bursting pressure on the concrete. In absence of the

    FRP wrap, tensile stresses develop in the concrete

    that result in its cracking and spalling. The FRP-

    wrapped samples resist the expansion pressure by

    developing a hoop stress. As a result, concrete goes

    in compression. This results in better grip of concrete

    on steel. In the case of actively protected samples,

    the corrosion products did not develop. Therefore, the

    compressive force in concrete was also absent. The

    ribs on the bars, on the other hand, were lost. This

    results in the loss of bond strength. For the success

    of the active protection technique, it is imperative that

    an optimum protection current density is achieved

    such that the loss of bond strength is avoided.

    Along with the destructive tests that were car-

    ried out at the end of the exposure, each sample was

    non-destructively monitored. Potentiodynamic scans

    were obtained after induction of initial corrosion and

    then every 2 weeks during their exposure to salt mist.

    The corrosion current (Icorr) was determined. Fig-

    ure 11 shows Icorrfor different samples. Understand-

    ably, the scatter in data was very large. A linear fit ofthe data was carried out to determine the trends. It

    FIGURE 10. Variation of mass loss with pullout strength.

    is clear from the figures that the control sample had

    higher corrosion currents throughout the exposure

    time. The corrosion current increased with exposure.

    The trend was similar for all the samples, regardless

    of the length of impressed current exposure prior to

    salt mist exposure. The protected samples, both pas-

    sive and active, exhibited much lower Icorr. This dem-

    onstrates that FRP wraps are extremely effective in

    protecting the corroding reinforcements in concrete.

    Moreover, the current reduced with time. This indi-

    cates passivation of steel. Therefore, the efficacy of the

    proposed protection systems is established.The initial current was higher in passively pro-

    tected systems. However, they passivated at a fast

    rate with time. The active system exhibited a lower

    Icorrthroughout the period of exposure. It is postulated

    that the mechanisms of passivation in the active and

    passive systems are different. In the passive systems,

    the resistance offered by the FRP wrap to expansive

    pressure from corrosion does not allow the corrosion

    products to dislodge. As a result, the electrical resis-

    tance at the steel-concrete interface goes up. Thus,

    the passivation is created. In the active systems the

    passivation is from the prevention of ionization of

    iron. Therefore, the rate of decay in Icorrin the two sys-

    tems was different. The Icorrdecayed faster in the pas-

    sive systems.

    CONCLUSIONS

    v A novel system for the active protection of steel

    bars in concrete is reported. The electrical conductiv-

    ity of the carbon FRP is utilized in creating an anode

    around the steel. Thus, the proposed system elimi-

    nates any requirement of an external anode and so

    has a very favorable impact on cost.

    v The efficacy of the system was established througha set of experiments and performance metrics, both

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