Acidic foam cleaner-descaler · 2013-07-25 · 3 Hazards identification 0 Classification: Xi...

Draft version - For internal use only

JohnsonDiversey a - -

JohnsonDiversey Acifoam Acidic foam cleaner-descaler

The information contained in this document bulletin is to our best knowledge. true and accurate, but all recommendations or suggestions are made without guarantee, since the conditions of use are beyond our control. JohnsonDiversey disclaims any liability incurred in connection with the use of these data or suggestions.

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JohnsonDiversey Acifoam Draft version - For internal use only

Test method Reagents:

Procedure:

Calculation:

O.IN Sodium hydroxide solution Phenolphthalein indicator Add IOOml of water and 2 - 3 drops of indicator solution to 5ml of the test solution.Titrate with the sodium hydroxide to a permanent pink end point. % v/v Acifoam = titre (ml) x 0.18 % w/v Acifoam = titre (ml) x 0.23 % w/w Acifoam = titre (mi) x 0.23

Registration National Poisons Centre, Beaumont Hospital, Ireland. Tel:00353 1 8379964.

Available pack sizes Article code 7509884 5600021 5600078 7509873

JohnsonDiversey (IRL) Jamestown Ro Finglas Dublin 11 Tel. 01 808 1808 www.johnsondiversey.com . WO141 IEEN-OJ

Pack site Bulk 20L

200L 900L

2

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http://www.johnsondiversey.com

Material Safety Data Sheet According to 911155 EC

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Printing Date 27.03.2001

1 Product and company identification

Brandname: ACIFOAM VFlO

Clearance code: R57153

ManufacturerISupplier: DiverseyLever

Information department: DiverseyLever (Ireland) Limited, Jamestown Road, Finglas, Dublin 11, Ireland Tel 01-8081808. Emergency information: National Poisons Centre, Beaumont Hospital, Dublin 9.Tel: 00-353-1-8379964

Reviewed on 20.03.2001

2

Chemical characterization Description:

Composition / Information on ingredients

Mixture in water of non-dangerous ingredients and the substances listed below.

Hazardous ingredients: anionic surfactants

7664-38-2 phosphoric acid

C; R 22-34

C; R 34

< 5 %

>= 30 %

Ingredients according to EC 89/542 phosphates >= 30% anionic surfactants c 5%

3 Hazards identification

Classification: C Corrosive Risk phrases: R 3 4 Causes burns. Classification system The classification complies with current EC regulations on dangerous substances and preparations.

4 Firet aid measures

General information Remove contaminated clothing immediately. Inhalation In case of unconsciousness bring patient into stable side position for transport. Skin contact Wash skin immediately and thoroughly with water. Remove contaminated clothing. Obtain medical attention if symptoms develop. Eye contact Wash immediately with copious amounts of water and obtain medical attention.

Remove material from mouth. Drink one or two glasses of water or milk and (Continued on page 2)

Ingestion

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Page 2/5

Material Safety Data Sheet According to 91/155 EC

Printing Date 27.03.2001 Reviewed on 20.03.2001


(Continued from page 1) obtain medical attention without delay.

Fire fighting measures I * Suitable extinguishing media C02, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Protective equipment: No special measures required.

6 Accidental release measures

Protection of personnel:

Environmental precautions: Dilute with plenty of water. Method of disposal:

Wear suitable protective clothing, gloves and eye/face protection.

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of the collected material according to the regulations. Use neutralizing agent.

7 Handling and storage

Handling (see also sections 8 and 15) Information for safe handling:

Information about protection against explosions and fires: Use common rules for working with chemicals.

No special measures required.

Storage Requirements for storage rooms and containers:

Storage in one common storage facility: According to local legislation. Further information about storage conditions:

According to local legislation.

Keep container tightly sealed. _____~

8 ^Exposure controls and personal protection

Additional information about design of technical systems: No further data; see section 7. Components with limit values that require monitoring at the workplace: 7664-38-2 phosphoric acid (>= 3 0 % ) OEL: Short-term value: 2 mg/m3

The lists that were valid during the compilation were used as basis. Additional information:

Personal protective equipment General protective and hygienic measures Keep away from foodstuffs, beverages and food.

(Continued on page 3)

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(Continued from page 2) Take off immediately all contaminated clothing. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. Breathing equipment: Personal protection is not normally required. Protection of hands: Protective gloves. Eye protection: Tightly fitting safety glasses.

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Physical and chemical properties

Form: Liquid Colour : Clear Pale brown Odour: Characteristic

Change in condition Melting point/Melting range: Not determined

Value/Range Unit Method

Boiling point/Boiling range: 100 O c Flash point: Not applicable

Spontaneous combustion: Product is not self igniting.

Danger of explosion: Product is not explosive.

Density at 20 C 1.29 g/cm3

Solubility in / Miscibility with Water: Fully miscible

pH-value : pH e = 2.0

10 Stability and reactivity

Thermal decomposition / conditions to be avoided:

Dangerous reactions Reacts with alkali and metals Hazardous decomposition products:

No decomposition if used according to specifications.

No dangerous decomposition products known ~ ~

11 Toxicological information

Acute toxicity: Primary irritant effect: on the skin: Caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. Sensitization: No sensitizing effect known. Additional toxicological information: EC classification:

(Continued on page 4 )

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(Continued from page 3 ) Corrosive Ingestion will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach.

12 Ecoloqical information

General notes: Must not reach sewage water or drainage ditch undiluted or unneutralized. The surfactants used in this product are biodegradable in compliance with the requirements of EC Directives 73/404/EEC and 73/405/EEC and their subsequent amendments.

13 Disposal considerations

Product: Recommendation Must not be disposed of together with domestic waste. Do not allow undiluted product to reach sewage system.

Uncleaned packagings: Recommendation: Dispose of observing official regulations. Recommended cleaning agent: Water, if necessary with cleaning agent.

14 Transport information

Land transport ADR/RID (cross-border) ADR/RID-GGVS/E Class: 8 Corrosive substances. Item number / Sub-group:

UN-Number: 1805 Label 8 Proper Shipping Name: Phosphoric acid, solution Comments:

17c

According to ADR/RID marginal 2801a, combined packages of small quantities can be transported with an exemption from ADR/RID.

15 Requlatory information

Classification according to EC guidelines: The product has been classified and labelled in accordance with current EC Directives.

Symbol and hazard designation of product: C Corrosive

Ingredients responsible for the classification: phosphoric acid

Risk phrases: 34 Causes burns.

Safety phrases: (Continued on page 5 )

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Material Safety Data Sheet According to 9 1 / 1 5 5 EC

Printing Date 2 7 . 0 3 . 2 0 0 1 Reviewed on 2 0 . 0 3 . 2 0 0 1


(Continued from page 4 ) 26 In case of contact with eyes, rinse immediately with plenty of

2 8 After contact with skin, wash immediately with plenty of

3 6 / 3 7 / 3 9 Wear suitable protective clothing, gloves and eye/face

4 s In case of accident or if you feel unwell, seek medical advice

water and seek medical advice.

water.

protection.

immediately (show the label where possible). ~~~ ~ ~~ ~

16 Other information

The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product features and does not establish a legally binding contract.

Department issuing material safety data sheet:

Contact: DLI Regulatory Group, Maarssen, The Netherlands

DLI Regulatory Group, Maarssen, The Netherlands, for information to DiverseyLever operating companies.

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TASKI clonet Heavy-duty toilet cleaner

Description Ready-to-use cleaner for the effective removal of lime scale and other deposits from toilet bowls and urinals.

Key properties * Effective combination of three different acids 0 Fast acting

Ideal viscosity for optimal adhesion to sloped / vertical surfaces

Benefits Quickly dissolves calcium/lime deposits Long-lasting action on vertical/sloped surfaces Safe for use on intact porcelain and glazed sanitary installations

Use instructions Dosage: TASK1 clonet is ready to use, apply undiluted.

Application: Flush the toilethrinal and squirt the product under the rim, around the bowl, onto waterlflush paths and water outlets.. Allow the product to act for 5-10 mins., then scrub with a brush and flush to rinse. Increase the acting time (1 - 2) hours in case of heavy calcium/lime build-up.

Important: Do not mix the,product with chlorinated products and do not use on acid- sensitive surfaces (e.g. marble, enamel, grouting). Immediately remove any drops or splashes from acid-sensitive surfaces and rinse thoroughly with water.

Technical data Appearance: clear, red coloured liquid Relative density [2O"C]: 1.06 pH-value neat: pH I 2.0

w4

The above data is typical of normal production and should not be taken as a specification.

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TASK1 clonet

Safe handling and storage information Safe handling: Full guidance on the handling and disposal of this product is provided in a separate Material Safety Data Sheet. Only for professional users / specialists.

Storage Information: Store in original closed containers away from extremes of temperature.

Environmental information The surfactants used in this product are biodegradable in compliance with the requirement of E C Directives 7314041EEC and 73/405/EEC and their subsequent amendments.

Available pack sizes Article code Pack size 7508695 2x5L

n DiverseyLever (IRL) I

Jamestown Road Finglas Dublin 11 Tel. 01 808 1808 w www.diverseylever.com

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P005?61EEN-01 f-7

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EPA Export 25-07-2013:19:58:15

http://www.diverseylever.com

Material Safety Data Sheet According to 91/155 E C

Printing Date 17.04.2001 Reviewed on 12.04.2003.


* Brandname: TASK1 CLONET W4

Clearance code: R 5 8 1 2 1

Manufacturer/Supplier: DiverseyLever

Information department: DiverseyLever (Ireland ) Limited,Jamestown

* Emergency information:As above 9am-Spm (Mon -Fri). After hours emergency: Road, Finglas. Tel: 00353 ( 0 ) 1 8081808.

National Poisons Centre,Beaumont Hospital, Dublin 9. Tel: 00353 ( 0 1 1 8379964.

2 Composition / Information on ingredients

Chemical characterization Description: Mixture in water of non-dangerous ingredients and the substances listed below.


C; R 22-34

5329-14-6 sulphamic acid Xi; R 36/38-52/53

Xi; R 36 77-92-9 citric acid

Ingredients according to EC 89/542 anionic surfactants

< S %

5 - 1 5 %

c 5 %

< 5%


0 Classification: Xi Irritant Risk phrases: R 36/38 Irritating t o eyes and skin.

* Classification system The classification complies with current EC regulations on dangerous substances and preparations.

4 First aid measures

Inhalation In case of unconsciousness bring patient into stable side position for transport.

* Skin contact Wash skin immediately and thoroughly with water. Remove contaminated clothing. Obtain medical attention if symptoms develop. Eye contact Wash immediately with copious amounts of water. Obtain medical attention if symptoms develop.


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/ 5

Material Safety Data Sheet According to S1/155 EC


Brandname: TASK1 CLONET W4

(Continued from page 1) * Ingestion In case of persistent symptoms obtain medical attention.

5 Fire fighting measures

* Suitable extinguishing media C02, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Protective equipment: No special measures required.

~ ~~ ~

6 Accidental release measures

Protection of personnel: Not required. Environmental precautions: Dilute with plenty of water. Method of disposal: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of the collected material according to the regulations. Use neutralizing agent.

7 Handling and storage

Handling (se? also sections 8 and 15) Information for safe handling:

Information about protection against explosions and fires: Use common rules for working with chemicals.


Storage Requirements €or storage rooms and containers:

Storage in one common storage facility: According to local legislation. Further information about storage conditions:

According to local legislation.

Keep container tightly sealed. ~ ~ ~

8 Exposure controls and personal protection

Additional information about design of technical systems: No further data; see section 7.

Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.

The lists that were valid during the compilation were used as basis. Additional information:

Personal protective equipment . General protective and hygienic measures Keep away from foodstuffs, beverages and food. Take off immediately all contaminated clothing.


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Printing Date 1 7 . 0 4 . 2 0 0 1 Reviewed on 12.04.2001

Recommendation C .

undiluted product to reach sewage system.


(Continued f r o m page 2 ) Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. Breathing equipment: Personal protection is not normally required. Protection of hands: Protective gloves. Eye protection: Safety glasses recommended during refilling.

9 Physical and chemical properties

Form: Liquid .Colour: Clear Red Odour: Slightly perfumed

Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined

Flash point: Not applicable

Spontaneous combustion: Product is not self igniting


Density at 20 O C 1.06 g/cm3

Solubility in / Miscibility with 0 Water: . Fully miscible

0 Value/Range Unit Method

* pH-value: pH < = 2.0


* Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.

* Dangerous reactions Reacts with alkali (lyes) * Hazardous decomposition products:

No dangerous decomposition products known

11 Toxicological information

I (Continued on page 4 )

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Material Safety Data Sheet According to 9 1 / 1 5 5 E C

Printing Date 17 04.2001 Reviewed on 12.04.2001

Brandname: TASK1 CLONET W4

(Continued from page 3 )

* Acute toxicity: Primary irritant effect : on the skin: Irritant to skin and mucous membranes. on the eye: Irritant effect. Sensitization: No sensitizing effect known. Additional toxicological information: EC classification: Irritant

12 Ecological information

General notes: The surfactants used in this product are biodegradable in compliance with the requirements of EC Directives 73/404/EEC and 73/405/EEC and their subsequent amendments.

13 Disposal considerations

Product: Recommendation Must not be disposed of together with domestic waste. Do not allow undilurred product to reach sewage system.


14 Transport information

Land transport ADR/RID (cross-border) ADR/RID-GGVS/E Class: 8 Corrosive substances.

e Item number / Sub-group: 66c

* UN-Number: 1760 Label 8 Proper Shipping Name: Corrosive liquid, n.0.s. (sulphamic acid,

Comments: alkylsulphonic acids)

According to ADR/RID marginal 2801a, combined packages of small quantities can be transported with an exemption from ADR/RID.

~~

15 Regulatory information

Classification according to EC guidelines: The product has been classified and labelled in accordance with Current EC Directives.


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Brandname: TASK1 CLONET W 4

(Continued from page 4 ) Symbol and hazard designation of product: Xi Irritant

* Risk phrases: 36/38 Irritating to eyes and skin.

Safety phrases: 2 6 In case of contact with eyes, rinse immediately with plenty of

37 Wear suitable gloves. water and seek medical advice.

16 ' Other information


. ...

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JohnsanDiversey * ?!s

Jo hnsonDiverse y Mu lticlean Liquid hard surface cleaner

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The information contained in this document bulletin is to our best knowledge, true and accurate. but all recommendations or suggestions are msde without guarantee. since the conditions of use ere beyond our control. JohnsonDiversey disclaims any liability incurred in connection wlth the use of these data or suggestlons.

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Jo h nfonDiversey Mu#iclean

te s t met hod Rea.gents:

Procedure:

Calculation:

0.1 N Hydrochloric or sulphuric acid Phenolphthalein indicator Add 2-3 drops of indicator solution to 50ml of the test solution. Titrate with the acid to a colourless end point. % vfv Multiclean = titre (mi) x 0.73 % w/v Multiclean = titre (ml) x 0.76 % w/w Multiclean = titre (rnl) x 0.76

Registration National Poisons Centre, Beaumont Hospital, Ireland. Tel:00353 1 8379964.

Available pack sires Article code 7509881 7509290 7SO929 1 7509876

JohnsonDiversey (IRL) Jamestown Ro Finglas Dublin 11 Tel. 01 808 1808 www,johnsondiversey,com PW2831EEN-03

Pack size B& 20L 200L 950L

0 Copyright 2003 JohnsonDlvaney 2

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Brandname: MULTICLEAN VK7

Clearance code: R58979

.r Wanufacturer/Supplier: DiverseyLever Ireland ..

Information department: DiverseyLever (Ireland) Limited, Jamestown Road,

Emergency information: National Poisons Centre, Beaumont Hospital, Dublin

- Finglas, Dublin 11, Ireland. Tel: 01-8081808.

9. Tel.: (00-353) 1-8379964.

2 Composition / Information on ingredients

Chemical characterization Description: Mixture in water of non-dangerous ingredients and the substances listed b e l o w .


Xn; R 22-38-41

111-76-2 2-butoxyethanol Xn; R 20/21/22-37

13870-28-5 disodium disilicate Xi; R 38-41

c 5 %

< 5 %

< 5 %

Ingredients according to EC 89/542 anionic'sutfactants, nitrilotriacetic acid c 5%


Classification:

Risk phrases: void 5 Classification system

w i d

The classification complies with current EC regulations on dangerous substances and preparations.

4 First aid measures

General information No special measures required. inhalation Remove from source of exposure. Obtain medical attention if symptoms develop. Skin contact Not applicable. Eye contact wash immediately with copious amounts of water. Ingestion In case of persistent symptoms obtain medical attention.

5 Fire fighting measures

(Continued on page 2) I

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Brandname: MULTICLW VK7

(Continued from page 1) I Suitable extinguishing media C02, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Protective equipment: No special measures required.

Accidental release measures l 6 Protection of personnel: Not required. Environmental precautions: Dilute with plenty of water. Method of disposal: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust) . Dispose of the collected material according to the regulations. Additional information: No dangerous materials are released.

Handling and storaqe

I 7 Handling (see also sections 8 and 15) Information for safe handling:

Information about protection against explosions and fires:

Storage Requirements for storage rooms and containers: No special requirements. Storage in one common storage facility: Not required. Further information about storage conditions: None.

8 Exposure controls and personal protection

Additional information about design of technical systems:

Use common rules for working with chemicals.


No further data; see section 7 .

Components with limit values that require monitoring at the workplace: 111-76-2 2-butoxyethanol ( c 5 8 ) OES: Long-term value: 123 mg/ma, 25 ppm

Sk, Bmgv Additional information: The lists that were valid during the compilation were used as basis.

I Personal protective equipment ? General protective and hygienic measures

The usual precautionary measures for handling chemicals should be complied with. Breathing equipment: Personal protection is not normally required. Protection of hands: Not required. Eye protection: Safety glasses recommended during refilling.


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Material Safety Data Sheet According to 911155 EC

Printing Date 2 7 . 0 3 . 2 0 0 1 Reviewed on 20.03.2001

Brandname: MULTICLEAN VK7

9

e

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e

0

0

0

e

e


Form: Liquid eo 1 our : Colourless Clear Odour: Characteristic

Change in condition Melting point/Melting range: Not determined


Boiling point/Boiling range: 100 O C

Flash point: Not applicable

Spontaneous combustion: Product is not self igniting.


Density at 20 O C 1.04 g/cm2

Solubility in / Miscibility with water: Fully miscible

pH-value : pH > 12.5


Thermal decomposition / conditions to be avoided:

Dangerous reactions No dangerous reactions known f Hazardous decomposition products:

No decomposition if used according to specifications.

No dangerous decomposition products known

11 Toxicoloqical information

Acute toxicity: Primary irritant effect: on the skin: Unlikely to be irritant on the eye: Unlikely to be irritant

6 Sensitization: No sensitizing effect Additional toxicological information

in normal use.

n normal use. known.

The product is not subject to classification under the EC Dangerous Substances and Preparations Directives. When used and handled according to instructions, the product is unlikely to have any harmful effects.


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Printing Date 27.03.2001 Rsviewed on 20.03.2001

Brandname: ldULTICL&AN VK7


The surfactants used in this product are biodegradable in compliance with the requirements of EC Directives 73/404/EEC and 73/405/EEC and their subsequent amendments.

General notes:

13 Disposal considerations I Product: Recommendation Must not be disposed of together with domestic waste. Do not allow undiluted product to reach sewage system. Uncleaned packagings: Recommendation: Dispose of observing official regulations. Recommended cleaning agent: Water, if necessary with cleaning agent.

3 4 Transport information

Land transport ADR/RID (cross-border) ADR/RID-GGVS/E Class:

15 Requlatory information

Classification according to EC guidelines : Non-dangerous according to the guidelines of the relevant EC Directives.

I -

16 Other information


Department issuing material safety data sheet:

contact: DLI Regulatory Group, Maarssen, The Netherlands

DLI Regulatory Group, Maarssen, The Netherlands, for information to DiverseyLever operating companies.

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3Al-tTY DA I A SHt t I

7 . IIYENTlFlCATlON OF THE SUBSTANCE/PREPARATION AND OF THE COMPANYlUNDERTAKlNG

Diversey Lever Limited

Weston Favell Centre Northampton NN3 8PD TelOl604 40531 1 Fax 01604 406809 Out of hours emergencies 01604 401273

t) I verseyhl’er

DOMESTOS CHANNEL BLOCKS Toilet Channel Blocks Product Code 65 1695

~ ~~ ~~ ~

TO : THE COMPANY SECRETARY DIVERSEYLEVER (EIRE) LTD JAMESTOWN ROAD FINGLAS

EIRE 000 000

n DUBLIN 1 1

2. HAZARDS IDENTIFICATION

Irritant - irritating to eyes and skin.

r-l 3. FIRST AID MEASURES

Eyes : Inhalation : Q Inb. ,cion :

Rinse immediately with plenty of water, holding the eyelids open and seek medical advice. Remove from source of dust, vapour or spray mist and seek medical attention. Wash thoroughly with soap and water. Remove product from mouth, give plenty of water or milk to drink and seek medical advice.

4. HANDLING & STORAGE

Avoid contact with skin and eyes. Store upright in original closed containers away from extremes of temperature.

n

1 5. EXPOSURE CONTROL/PERSONAL PROTECTION

Hand : Eyes : Skin :

Use rubber gloves resistant to detergents. When handling neat product or use solutions wear eyelface protection to prEN 166 3 (chemical liquids). Personal protection is not normally required unless a risk assessment indicates the need for it. Personal protection is not normally required unless a risk assessment indicates the need for it. iJ Respiration :

6. FIRE FIGHTING MEASURES

NON FLAMMABLE - In the event of a fire due to other causes the product is compatible with water, foam, carbon dioxide and dry powder extinguishers. May evolve toxic fumes if involved in a fire. Firefighters should wear self contained breathing apparatus.

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U,. ACCIDENTAL RELEASE MEASURES

Near suitable gloves and eyelface protection. Sweep up and dispose of safely as solid waste. Hose down area with plenty of water, diluting to at least 2.5% w/w (25 gllitre).

8. DISPOSAL CONSIDERATIONS

This product does not contain any prescribed substance under the Environmental Protection Act (Prescribed Processes and Substances) Regulations 1991 but is classified as special waste under the Control of Substances (Special Waste) Regulations 1996. For disposal of both large and small quantities contact a licensed waste management company.

1 9 . STABILITY 81 REACTIVITY

Keep sway from stropg oxidising agents.

n U1 0. COMPOSITION/INFORMATION ON INGREDIENTS

Preparation containing : ( 1 5-30%) Sodium Alkylbenzene Sulphonate Xn R22 Harmful if swallowed

R36/38 Irritating to eyes and skin P 1 I . PHYSICAL & CHEMICAL PROPERTIES

Page: 1 of 2 CSZ.C)T rii

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EPA Export 25-07-2013:19:58:16

D P U

P

Product Name DOMESTOS CHANNEL BLOCKS Product Code 651695

Appearance :

Fl-Tmability :

Green block

Non flammable Solubility : Slowly soluble in water

12. TOXICOLOGICAL INFORMATION

Eyes : Skin : Irritant. Inhalation : Ingestion :

Can be severely irritant.

May be capable of causing irritation. May be capable of causing irritation.

13. ECOLOGICAL INFORMATION

The product is not known to pose any significant threat to the environment.

14. TRANSPORT INFORMATION

EEC Regulation : Not regulated. IMDGlUN : Not regulated. RlDlADR : Not regulated. ICAOllATA : Not regulated.

15. REGULATORY INFORMATION

hGLard symbol : . Xi, IRRITANT. Risk phrases : Safety phrases :

Irritating to eyes and skin. Keep out of reach of children. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. If swallowed, seek medical advice immediately and show this container or label.

16. OTHER INFORMATION

Date: 11/09/1998 Revision Number: - Page: 2 of 2

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EPA Export 25-07-2013:19:58:16

Suma Sol Detergent sanitiser 0

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Diversey Lever

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Suma Sol

Technical data Appearance pH (1 % solution) Available chlorine (%w/w)

pink powder 8.4 3.3

These figures are typical values and should not be interpreted as specificatigns;

Safe handling and storage information Full guidance on the handling and disposal of this product is provided in a separate Material Safety Data Sheet.

Store in original container. Avoid extremes of temperature and humidity.

Product compatibility Under recommended conditions of use, Suma Sol D4.8 is suitable for use on most matefils commonly encountered in the kitchen.

Available pack sizes Article code 7508256

Dhrerseylever (IRL) Jamestown Road

DuMln 11 Tel. Dl 803 1808 w.diversieylever.com

Fibs

WW741EEN41

Pack size 1Qkg

2

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http://w.diversieylever.com

/4

Material S a f e t y Data Sheet According to 91/155 6%


* Brandname: SUMA SOL D4.8 * Hanufacturer/Supplier: Diverseylever Information department: DiverseyLever (Ireland ) Ltd, Jamestown Road, Finglas, Dublin 11. Tel : 01 8081808.

contact : National Poisons Centre, Beaumont Hospital, Dub1 in 9 . Tel : 01 * Ehergency information: As above, 9am-5pm (Mon-Fri ) . After hours emergency

Chemical charac t eri za t ion

Powder mixture of non-dangerous ingredients and substances listed below.

Hazardous ingredients:

* Description:

51580-86-0 sodium dichloroisocyanurate, dihydrate 5-15 3 Xn, N; R 22-31-36/37-50/53

Ingredients according to BC 89/542 phosphates 15 - 30% chlorine-based bleaching aqents c 5%

.Risk phrases: R 31 Contact with acids liberates toxic gas. Classification system TIie classification complies with current EC regulations on dangerous substances and preparations. I

. Inhalation Remove from source of exposure. Obtain medical attention if symptoms develop.

a Skin contact Not applicable. - - Eye contact Wash immediately with copious amounts of water. - Ingestion In case of persistent symptoms obtain medical attention.

. Suitable extinguishing media C02, extinguishing powder or water jet. Fight larger fires with water jet or alcohol -resistant foam.

. Protective equipment: Put on breathing apparatus.

*Protection of personnel: Put on breathing apparatus. . Environmental precautions: No special measures required. . Method of df sposal: Collect mechanically. Dispme of the collected material according to the regulations.


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/4

Material S a f e t y Data Sheet According to 91/155 BC

la

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Brandname: SUMA SOL 0 4 . 8

(Continued from page 1)

*Handling (see a l s o sections 8 and 15) . Information for safe handling: Prevent formation o f dust. . Information about protection against explosions and fires: NO special measures required.

- Storage . Requirements for storage roams and containers:

astorage in one common storage facflity: According to local legislation.

Do not store together with acids. According to 1 oca1 1 egis1 at ion. Further information about storage conditions: store under dry conditions.

-Additional information about design of technical systems: No further data; see section 7 .

Components with limit values that require monitoring at the workplace: 51 58 0 - 86 - 0 sodium di chloroi socyanura te , dihydrate (5 -1 5 %I MEL: Short-term value: 0.07 m9/m3

Long-term value: 0.02 mg/m3 Sen; as -NCO

Additional information: The lists that were valid during the compilation were used as basis.

a Personal protective equipment *Qeneral protective and hygienic measures

. Breathing equipment: Wash hands during breaks and at the end of the work.

Personal protection is not normally required. In case of low levels of exposure use breathing filter.

. Protection of hands: R i n s e and dry hands after use. For prolonged contact protection for the skin may be necessary.

. Eye protection: Not required. .

.Form: Solid * Colour: Pink . Odour: Chlorine-like

* Change in condition Melting point/MeZ ting range: Not determined

. oiling point/Boiling range: Not de termined * Pla6h point : Not applicable . Spontaneous combustion: Prduct is not s e l f igniting.


I (Continued on page 3 ) I

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/ 4

Material S a f e t y Data Sheet According t o 91/155 EC


Brandname: SUMA SOL 0 4 . 8 1 (Continued from page 2)

* Danger of explosion: Product is not explosive.

* Solubility in / Miscibility with - water: Sol u b l e

* Daneity at 20 c 1.00 g/cmJ

- pH-value: 8.0 < pH (1%) <= 8.5

-Thentml decomposition / conditions to be avoided: No decomposition if used according to specifications. Dangerous reactions Reacts with acids releasing chlorine *Hazardous deconmosition products: Chlorine

. Acute toxicity:

. Primary irritant effect: ;a13 the skin: Unlikely to be irritant in normal use. -on the eye: Unlikely to be irritant in normal use. * Sensitization: No sensitizing effect known.

Ueneral notes: Must not reach sewage water or drainage ditch undiluted or unneutralized.

Product :

Must not be disposed of together with domestic waste. Do not allow undiluted product to reach sewage system.

. Becmmenda tion

. Uncleaned packagings: *Recommendation: Dispose of observing official regulations. Recammended cleaning agent: Water, if necessary with cleaning agent.

. Land transport ADR/RID (cross-border) ADR/RID-GGVS/B Class: -

I I

* Classification according to BC guidelines: The product has been classified and labelled in accordance with current EC Directives .

'Ritrk phrases: 31 Contact with acids liberates toxic gas.


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/ 4

D

Material S a f e t y Data Sheet According to 91/155 EC

Printing Date 18.08.2001 R e v i e w e d on 13 .08 .2001

Brandname: SUMA SOL D4.8


S a f e t y phrases : 8 Keep container dry. 22 Do not breathe dust. Specia l designa t i o n of c e r t a i n prepera tions: Rinse and dry hands a f t e r use . For prolonged contact p r o t e c t i o n for the s k i n may be necessary.

The information i n this document i s based on our best pre s ent knowledge. H o w e v e r , i t d o e s not c o n s t i t u t e a guarantse for any specific product f e a t u r e s and does not e s t a b l i s h a l e g a l l y binding contract .

U

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EPA Export 25-07-2013:19:58:17

DiverseyLever Super Dilac Heavy duty acidic CIP detergent descaler

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5iverseyLever Super Dilac

Technical data Appearance clear, colourless liquid Relative density at 20°C I .28

1 Chemical Oxygen Demand (COD) none Nitrogen Content (N) 85 glkg Phosphorous Content (P) 21 glkg

pH (1 % solution at 20°C)

Super Dilac [%wlw] [mS/cm] 0.5 12.8 1 25.1 2 46 3 66 4 85

Specific conductivity at 25°C

The above data is typical of normal production and should not be taken as a specification.

Safe handling and storage information Store in original closed containers or (where applicable) in an approved bulk tank, away from extreme temperatures. Full guidance on the handling and disposal of this product is provided in a separate Material Safety Data Sheet.

Product corn pa ti b i I i ty Super Dilac is safe for use on all type of materials commonly found in CIP circuits when applied under the recommended conditions. In the event of uncertainty it is advisable to evaluate individual materials before any prolonged use.

Test method Reagents:

Procedure:

Calculation:

Available pack sizes Article code 7509816 5600014 750981 5 7508849 7508848

DiverseyLever US 3560 East Kemper Road Sharonville Cincinnati Ohio 45241 Tel 1 -80@-6?6-5@1 www.diverseylever.com

POfl323-02

0.1 N Sodium hydroxide solution Phenolphthalein Indicator Add 2-3 drops of the Indicator solution to 10 mls of the test solution. Titrate with the caustic to a red end point. %w/w Super Dilac = titre (mls) x 0.14 %vlv Super Dilac = titre (mls) x 0.1 1

Pack size 200L

20L 2x5L 900L Bulk

DiverseyLever Canada 2401 Bristol Circle Oakville Ontario L6H 6P1 Tel 1-800-668-71 7 1 "",'V""A :I &'E :;cy!, " c I ; >,-*

ID Copynghl 2001 DtverseyLevei

DiverseyLever Puerto Rico 16-6 Street Sabana Abajo Industrial Park Carolina Puerto RICO 00983

www diverseylever corn

T _ I 1 -i 3P QE;n 16?7

7

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http://www.diverseylever.com

R

5

W U R P 0 :o U 61 B

'-l

Page 11'4

Materia4 Safety Data Sheet According to 91/155 EC


. Brandname: SUPER DILAC VA4

. Manufacturer/Supplier: DiverseyLever

. Information department: DiverseyLever ( I r e l and ) Ltd, Jarnestohm Road, F inglas , Dublin 11. T e l : 01 8081808. Emergency information: As above, 9am-5pm (Mon-Fri ) .df tei- hours emergency contact : National Poisons Centre,Beaumont Hospita1,Dublin 9 . T e l : 0 1 83 79964.

Chemical characterization Des crip t i on : M i x t u r e i n water o f non-dangerous ingred i en t s and t h e substances 1 i s t e d below. ,

Hazardous ingred i en t s : 7697-37-2 n i t r i c a c i d >= 30 %

C , 0 ; R 8-35

7664-38-2 phosphoric a c i d 5 - 1 5 8 C; R 3 4

Ingredients according to EC 89/542 phosphates 5 - 15% --

. Classification: C Corrosive 'Risk phrases: R 3 5 Causes s e v e r e burns. ' Classification system The c l a s s i f i c a t i o n c o m p l i e s with current EC r egu la t i ons on dangerous substances and preparat ions .

General in f orma ti on Remove contaminated clothing immediately . Inhalption In c a s e of unconsciousness br ing p a t i e n t i n t o s t a b l e s i d e p o s i t i o n for t ransport . Skin contact Wash sk in immediately and thoroughly with water. R e m o v e contaminated c l o th ing . Obtain medical a t t en t i on i f s y m p t o m s deve lop . Eye contact Wash immediately with copious amounts of water and ob ta in medical a t t ent ion . Xnges t i on K e m o v e mat e r i a l f r o m mouth. Drink one or t w o g l a s s e s o f water or mi l k and obta in medical a t t en t i on without de l ay .

Su i tab le extinguishing media CO2, extinguishing powder or water j e t . Fight l a r g e r f i r es with water j e t or

(Continued on page 2 ) - ~ -- - --

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R P

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Page 2 /4


Printing Date 26.06.2001 Reviewed on 3 0 . 06.2001

Brandname: SUPER DILAC VA4

(Continued from page 1)

a lcoho l - r e s i s t a n t f o a m . . Protective equipment: N o s p e c i a l measures r e q u i r e d .

Protection of personnel: Wear s u i table p r o t e c t i v e c lo th ing , gloves and e y e / f a c e p r o t e c t i o n . Environmental precautions: D i l u t e with p l e n t y o f water. Method of disposal: Absorb with l iquid-binding material (sand, d ia tomite , a c i d b inders , uni versa1 b i n d e r s , s a w d u s t ) . Dispose o f t h e collected m a t e r i a l according t o t h e regulat ions . U s e n e u t r a l i z i n a aaent .

~ - ~~ ~~

'Handling (see also sections 8 and 151 Information for safe handling: Ensure good ven t i l a t i on/exhaus ti on a t t h e workplace. Information about protection against explosions and fires: No s p e c i a l measures required.

. Storage 'Requirements for storage rooms and containers: According t o local l e g i s l a t i o n . Storage in one common storage facility: According t o l oca l l e g i s l a t i o n . Further information about storage conditions: None.

Additional information about design of technical systems: No f u r t h e r d a t a ; see s e c t i o n 7 .

Components with l i m i t values that require monitoring a t t h e workplace: 7697- 37-2 n i t r i c a c i d (>= 30%) O E S : Short-term v a l u e : 10 m g / m 3 , 4 p p m

Long-term v a l u e : 5 .2 m g / m 3 , 2 ppm

7664-38-2 phosphoric a c i d (5-15%) OES: Short-term value: 2 m g / m 3 Additional information: T h e l ists that w e r e v a l i d during t h e compilat ion w e r e used a s b a s i s .

Personal protective equipment General protective and hygienic measures K e e p away from f o a d s t u f f s , L ~ v i r a j s s and f o o d . Take o f f immediately a l l contaminated c l o t h i n g . Wash hands during b r e a k s and a t t h e end o f t h e work. Do not i n h a l e gases / f u m e s / a e r o s o l s . Avoid contact with t h e eyes and s k i n . Breathing equipment: In c a s e of low levels o f exposure u s e breath ing f i l t er Protection of hands: Protect ive g l o v e s .


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I ' Fage 3 / 4


P r i n t i n g Date 2 6 . 0 6 . 2 0 0 1 Reviewed on 2 0 . 0 6 . 2 0 0 1


(Continued from page 2 ) . I . Eye protection: T i g h t l y f i t t i n g s a f e t y g l a s s e s .

Form: L i q u i d Col our: Uncol oured C1 e a r Odour: Charac t er is t i c

Value/Range Unit Method Change in condition Melting point/Melting range: Boiling point/Boiling range: Flash point: Spontaneous combustion: Danger of explosion: Density at 20 * Solubility in / Miscibility with Water: gH-value:

Not de termined ,

Not de termined N o t appl i cab1 e Product i s n o t s e l f i g n i t i n g Product i s not e x p l o s i v e .

C 1.28 g/cm3

F u l l y miscible DH <= 2 . 0

Thermal decomposition / conditions to be avoided: No d e c o m p o s i t i o n i f u s e d a c c o r d i n g t o s p e c i f i c a t i o n s . Dangerous reactions Reacts with alkali and metals Hazardous decomposition products: No dangerous d e c o m p o s i t i o n p r o d u c t s known

Acute toxicity: Primary irritant effect: on the skin: S t r o n g c a u s t i c e f f e c t on skin and mucous membranes. on the eye: S t r o n g c a u s t i c e f f e c t . Sensitization: N o s e n s i t i z i n g e f f e c t known. Additional toxicological information: EC c l a s s i f i c a t i o n : C o r r o s i v e I n g e s t i o n w i l l l e a d t o a s t r o n g c a u s t i c e f f e c t on mouth and t h r o a t and t o t h e danger o f p e r f o r a t i o n o f esophagus and s tomach.

I

. General notes : Must n o t r e a c h sewage w a t e r o r dra inage d i t c h u n d i l u t e d o r u n n e u t r a l i z e d .


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P a g e 4 / 4


P r i n t i n g D a t e 36.06.2002 R e v i e w e d on 2 0 . 0 6 . 2 0 0 1


( C o n t i n u e d from page 3 )

' Product: Recommendation M u s t not be disposed o f together w i t h d o m e s t i c w a s t e . Do n o t a l l o w u n d i l u t e d p r o d u c t to reach s e w a g e s y s t e m .

Uncleaned packagings: Recommendation: D i s p o s e o f observing o f f i c i a l r e g u l a t i o n s . Recommended cleaning agent: W a t e r , i f necessary w i t h c leaning agent.

' Land transport ADR/RID (cross-border) ADR/RID-GGVS/E Class : 8 C o r r o s i v e s u b s t a n c e s . Item number / Sub-group:

2b ' UN-Number: 2 0 3 1 Label 8 Proper Shipping Name: N i t r i c a c id s o l u t i o n Connnen t s : According to ADR/RID m a r g i n a l 2 8 0 1 a , combined packages o f s m a l l q u a n t i t i e s can be transported w i t h an e x e m p t i o n f r o m ADR/RID.

. Classification according to EC guidelines: T h e p r o d u c t has been c l a s s i f i e d and labe l l ed i n accordance w i t h curr ent EC D i r e c t i v e s .

Symbol and hazard designation of product: C C o r r o s i v e

Risk phrases: 3 5 C a u s e s severe b u r n s .

23 Do not breathe vapour. 26 .. In case o f contact w i t h e y e s , rinse i m m e d i a t e l y w i t h plenty o f

28 A f t e r contact w i t h s k i n , w a s h i m m e d i a t e l y w i t h p l e n t y o f

36/37/39 Wear s u i table protective c l o t h i n g , gloves and e y e / f a c e

a 5 In case o f acc ident or i f y o u f e e l u n w e l l , seek m e d i c a l advice

. Ingredients responsible for the classification: n i t r i c ac id

. Safety phrases:

wa t er and seek m e d i c a l advice .

w a t e r .

protection.

i m m e d i a t e l y ( s h o w the labe l w h e r e p o s s i b l e ) . ~ .

I

T h e i n f o r m a t i o n i n t h i s d o c u m e n t i s based on o u r best present k n o w l e d g e . H o w e v e r , i t does not c o n s t i t u t e a g u a r a n t e e f o r any s p e c i f i c p r o d u c t f e a t u r e s and does not es tab l i sh a l e g a l l y b ind ing contract.

I 1 I i I . Clearance code: D L 1 0 4 5 7

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