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a2organicreactions-130110030254-phpapp01
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Transcript of a2organicreactions-130110030254-phpapp01
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7/26/2019 a2organicreactions-130110030254-phpapp01
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A2 Organic Reactions / Reagents & Conditions
1. GRIGNARD REAGENTS Preparation:
i. HALOALKANE + Mg GRIGNARD
Reagents and Conditions:
1) Heat under re!u"
#) Dr$ Et%er
&) 'ing!e Cr$sta! o Iodine (ata!$st i needed
Reactions:
i. GRIGNARD + CO#(cold/solid) +1C)CAR*O,LIC ACID + Mg*rC!(+1C = the addition of one Carbon molecule to the chain)
ii. GRIGNARD + ME-HANAL +1C) 1 ALCOHOL + Mg*rC!
iii. GRIGNARD + Ot%er ALDEH,DE' +1C) # ALCOHOL +Mg*rC!
i/. GRIGNARD + KE-ONE +1C)& ALCOHOL + Mg*rC!
Reagents and Conditions:
1) Dr$ Reagents
#) 0it% HC!
2. CARO!"#IC ACIDS Preparation:
i. 1 ALCOHOL' + #O2 CAR*O,LIC ACID + 0A-ER
Reagents and Conditions:
1) Heat under Re!u"
#) 3otassiu4 Di(%ro4ate 5 H#'O6ii. H$dro!$sis o Nitri!es
NI-RILE + #H#O + HC! CAR*O,LIC ACID + NH6C!
Reagents and Conditions:
1) Heat under re!u"
#) 0it% di!ute HC! Reactions:
i. CAR*O,LIC ACID + NaOH CAR*O,LA-E 'AL- + H#O
ii. CAR*O,LIC ACID + Na#CO&5NaHCO& CAR*O,LA-E 'AL- + H#O + CO#iii. CAR*O,LIC ACID + ALCOHOL 7 E'-ER + H#O
Reagents and Conditions:
1) 0ar4ed under re!u"
#) 0it% (on(entrated H#'O6i/. CAR*O,LIC ACID + 3C!8 ACID CHLORIDE + 3OC!&+ HC!
Reagents and Conditions:
1) Dr$ 5 roo4 te49erature
/. CAR*O,LIC ACID + 6H2 ALCOHOL + H#O
Reagents and Conditions:
1) LiA!H6in dr$ et%er
#) 0it% HC!
$. ACID C%#ORIDES: Preparation:
i. CAR*O,LIC ACID + 3C!8 ACID CHLORIDE + HC! + 3OC!& Reactions:
i. ACID CHLORIDE + H#O CAR*O,LIC ACID + HC!
ii. ACID CHLORIDE + ALCOHOL E'-ER + HC!
iii. ACID CHLORIDE + (concentrated)AMMONIA AMIDE + NH6C!
i/. ACID CHLORIDE + AMINE '*'-I--ED AMIDE + HC!
1 o &
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. ESTERS: Preparation:
i. CAR*O,LIC ACID + ALCOHOL 7 E'-ER + H#O
Reagents and Conditions:
1) 0ar4ed under re!u"
#) 0it% (on(entrated H#'O6
ii. ACID CHLORIDE + ALCOHOL E'-ER + HC! Reactions:
i. E'-ER + NaOH ALCOHOL + CAR*O,LA-E 'AL-
Reagents and Conditions:
1) Heat under re!u"
ii. E'-ER + H#O 7 CAR*O,LIC ACID + ALCOHOL
Reagents and Conditions:
1) 0ar4ed under re!u"
#) 0it% (on(entrated H#'O6
'. CARON"# CO(PO)NDS:
Preparation * A+de,-des:i. 1 ALCOHOL + O2 ALDEH,DE + H#O
Reagents and Conditions:
1) Heat under DI'-ILLA-ION
#) 3otassiu4 Di(%ro4ate 5 H#'O6 Preparation * etones:
i. # ALCOHOL + O2 KE-ONE + H#O
Reagents and Conditions:
1) Heat under re!u"
#) 3otassiu4 Di(%ro4ate 5 H#'O6 Reactions * ot, A+de,-des and etones:
i. CAR*ON,L + #;6
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4. 15 A(INES Preparation:
i. NI-RILE + 6H2 AMINE
Reagents and Conditions:
1) LiA!H6in dr$ et%er
ii. HALOALKANE + NH& AMINE + H Reagents and Conditions:
1) Heated in a sea!ed tu>e
#) Con(entrated NH& Reactions * 6it, ACIDS
i. AMINE + HC! ALK,L AMMONIM+CHLORIDE