A solution for seawater transportation and use in marine ...

A solution for sea water transportation

and use in marine environment

N. DUFAURE

2013-06-14

Arkema proprietary – Confidential – Do not duplicate

The information contained in this document is based on trials carried out by our Research Centres and data selected from the

literature, but shall in no event be held to constitute or imply any warranty, undertaking, express or implied commitment from our part. The trials were carried out on samples coated according to Arkema recommendations or following EN 10310 standard

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The Rilsan® system for fluid application

Rilsan® coatingSteel

chemical

pretreated or

mechanical

grit blasted

Primer for optimum Adhesion

and to prevent corrosion propagation

in case of damage




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Rilsan® Fine PowdersBIOMASS VALORIZATION

Castor

Plants

Castor

Seeds

Castor

Oil

FeedstockIndia, China, Brazil

IntermediatesFrance

Technical PolymersFrance, USA

Food

Cosmetics

Pharmaceuticals

C3

Jet lub, Fridge lub

Butter tracer

Fragrance, Flavors

C7

Cosmetics

Perfumes

Pharmaceuticals

C11

Concrete demolder

Metal working

Lubricants

Road building

Esters

Amino

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100% based on

renewable

resources

Integrated

Production

Metal Protection

Paint, coating




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Reduce risk of

damage during

storage and handling

Improve flow-ability

Versatile usage

environment

Contact Approval

Maintain designed performance

and durability

Main Properties �� Benefits

Rilsan® Fine Powders

Low frictionLow friction

Smoothsurface

Smoothsurface

AbrasionresistanceAbrasion

resistance

ImpactresistanceImpact

resistanceCorrosionresistanceCorrosionresistance

Chemicalresistance

Chemicalresistance

Weatheringresistance

Weatheringresistance

Cavitationresistance

Cavitationresistance

Potable Water Contact

Certificate

Potable Water Contact

Certificate




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Certifications and Approvals Worldwide for contact with potable

water (homologated grades available upon request)

� USA : NSF 61

� UK : WRC – BS6920 and DWI

� GERMANY : DVGW KTW and W270

� HOLLAND : ATA

� FRANCE : DGS VS4

� JAPAN : Ministry of Health

� Australia: AS4020

Complies with different coating performance standards for piping

systems

� Holland—KIWA K-759

� USA—AWWA C-224

� Japan—JWWA WSP-067

� Australia—AS/NZS 4158

� Europe—EN 10310

Rilsan® in potable water application




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Resists more than 10 years in sea water while even

very expensive stainless steel grades corrode in sea

water

● From 1973 to 1983, 5 RFP coated plates (1 white, 1

black, 1 green, 1 red and 1 blue) have been

immersion in seawater in a Normandy harbor.

Immersion depth : 0.2 to 1 mm below seawater

● The products were applied by dipping with a primer

(Rilsan® thickness >250µ)

● Regular inspection of the samples

● Results after 10 years :

� No rust point

� No blistering

� Adhesion between 2.5 and 4 according to NFT 58-112

(good to very good)

Durability (sea water)

St-Valery-en-Caux harbor




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Ageing of coated carbon steel plates in seawater at 80°°°°C for 6 months (accelerated ageing).

� After 6 months, Rilsan® coating exhibits no point of rust or blistering, on the contrary to usual marine paints

� Rilsan® can be used for years at 20°°°°C without any point of rust

Durability (sea water)

Rilsan® coating IMO PSPC approvedcoating




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Polyester Rilsan®:

Highly corroded plateSand has induced damages, resulting in high corrosion

Very good abrasion + corrosion resistance

Galvanization

Durability (marine environment)

1 min grit blast followed by 10,000 h salt spray test (to model sand + seawater on seaside




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Corrosion resistance to NaCl (10%, pH=3, 40°C)

No change in inherent viscosity �� No degradation

No loss of adhesion after 2000 hours

Very limited propagation from the damages area

Durability (sea water + acidity)

0

1

2

3

4

0 500 1000 1500 2000

time (h)

0

2

4

6

8

10

adhesion NFT 58 112 (0-4 rating)

corrosion propagation from ascribe (mm)




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Simulation of usage conditions (10 days in autoclav e)

Medium: 2/3: salt water (3%) with 10% gas oil, the whole saturated with CO2,

1/3: methane with 10%CO2 + 10%H2S

Evaluation: Blistering, change of colour and cracking

Conclusion on usage conditions:Temperature: up to 70 °CPressure: up to 150bar (the highest pressure tested)Decompression rate: withstand instantaneous decompress ion

Durability (oil&gas)




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0 20 40 60 80 100

epoxy

GRP

Rilsan®

Loss (mg) - 1000 cycles

Wear resistance

Abrasion resistance (Taber test ISO 9352, 1Kg, 1000 cycles)

Silicate mud wear resistance (ASTM G6)

The coated sample are placed during 200h in a barrel containing a mix of silicates (13.6 Kg) and water (5.6 liter) and rotating at a 30.5 m/min speed.

� Thickness loss after 200 hours < 1 micron

� No porosity of the coating after 200 hours

Rilsan®Rilsan®




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Properties - Impact

Rilsan® coating limits chipping during handling and storage

0 0.5 1 1.5 2 2.5 3 3.5

Polyester

Epoxy

Polyolefinic copolymer

Rilsan®

Impact energy (J)Standard: ASTM G14

Rilsan®Rilsan®




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Much more flexible than GRP and thermosetting

4 80% elongation at break

4 Bending of the coated pipes is up to a curvature of 30 D withoutcracking the coating

Properties - Flexibility




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Looksbroek Potable Water Production

Owner Waterleidingmaatschappij Oost-Brabant N.V.‘s-Hertogenbosch

Engineering Veolia Rossmark Waterbehandeling B.V., Oldenzaal

Year of construction 1967

Expansion 1997

Reference-Water treatment

Water Treatment Piping System – 50 years of experiences




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Date 1990

Country Bocholt, Germany

Products Flanged pipes and fittings

End Use Waste water treatment plant piping system

Customers Afvalwater zuiveringsinstallatie

Reference-Waste water

Waste Water Treatment Plant




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Reference – Accessories

Main reasons for choosing Rilsan®:

• Corrosion resistance to many fluids (including

seawater)

• Potable water approvals

• Abrasion resistance

• Low Friction

• Impact resistance

• Ease of the coating process

• …

Rilsan® is used to protect many accessories :

-Fittings

-Pumps

-Flow meter

-Valves

Waterflux (Krohne)

Impeller for submersible pumps

Fitting (Viking Johnson)




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Reference – seaside furniture

Lamposts in Spanish seaside

(Almeria)

Manufacturer : Simon Lightning

Bench on seafront

(Barcelona)

Manufacturer : Santa & Cole

Rilsan® coated furniture show no corrosion after 5 years,

while polyester coated parts are heavily corroded




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Date January 1997

Country Japan

Owner Prefecture of Okinawa

Products Piping system

End Use See water reverse osmosis desalination

Capacity 40 000 m3/day

Reference-SWRO

Chatan desalination plant




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Reference-SWRO

Case file formatFinal customer:FabricatorApplication: De-Salination plant for on board

shipsConsumption:Job Coaters:Leyfos Plastics UKGrade: Dip coated in T Green 7529 MAC

A little story about the case so that we can eventually put it into megazine

PhotosPhotos

Photos

Photos

Photos

Photos

Country: UK

Fabricator: Salt separation Services

End use: Reverse osmosis De-Salination plant for on board ships (aircraft carriers)

Capacity: 100m3 per day




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Date 2007

Country Israel

Products Sand filter for seawater

End Use SWRO plant

Customers Veolia/Askelon municipality

Exterior Rilsan® coating Interior Rilsan® coating

Reference-SWRO




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Owner Blue Star Ferries cruise ship

Year 2000

Engineering Van der Giessen de Noord

Application Pumping of sea water for cooling of the engine through heat exchanger and discharge of hot seawater up to 70°C

Reference-sea water

Seawater Cooling System Pipeline




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Reference-Naval & Offshore Applications

Main reasons for choosing Rilsan®:

• Salt Water Resistance

• Corrosion Protection

• Low Friction

• Prevents Biofilm development

Specified for: Marine HVAC - Air conditioning for Oil platforms Tubing System for Condensers and Chillers

Reference: T black 7450 AC, T gris 49 AC2

T blue 7443 MAC, T blue 7174 MAC




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Cable attachments for off-shore and ships

Country: Finland

Grade: Rilsan T black 7450 ACRilsan T red 7424 AC

Main reasons for choosing Rilsan ®:

• Resistance to weather ability

• Withstand outdoor exposure

• Resistance to corrosion

• Resists the temperatures from the hot tubing

• Resistance to impacts and abrasion at both high and low temperatures

Reference-Naval & Offshore Applications




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Reference – oil & gas

On site trial of 5 years ½ in Anemas (Algeria) in water pipe-line used

for the water injection assisted extractions of crude oil2

Medium:

salt water (41g/l of NaCl, 4.6g/l of SO4, 2.4g/l of Ca2, 0.7g/l of Sr2)Dissolved gases: 150ppm of CO2, 6ppm of H2S, 0.4ppm of O2

Pressure: 15kg/cm2

Temperature: -6 to 45°C

Conclusion:

No degradation of the coating, no blistering

and no loss of adhesion.

2. Report DSI 489 013/A by Bureau Veritas in 1989: Evaluation after 5 and half years of service in Anemas (Algeria) in water pipe-line

used for the water injection assisted extractions of crude oil




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Reference – oil & gas

Coated tubing produced by Tuboscope

End Use: Production and Injection tubings as well as flowlinesfor oil & gas production

Service conditions: CO2, fresh and salt water, oil, and gas serviceto 107°C




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Reference list

Installation Customer Capacity, m3/day Country Prefecture(Japan)

Original water Use

2006 Higashi Hiroshima City 12 Japan Hiroshima Well water Drinking water2006 A certain plant 25 Japan Okinawa Sea water Concentrated salt water2006 Japan Water Agency 35 Japan Tokushima Sea water Drinking water2006 A certain cosmetic company 220 Japan Shizuoka Sea water Deep sea water2006 Biomass plant 350 Sri Lanka Sea water Industrial water2006 Rubbish inc inerat ion plant 30 Japan Kagoshima Concentrated sewage water Concentrated salt water, desalinated water2006 Rubbish inc inerat ion plant 3 Japan Fukushima Concentrated sewage water Concentrated salt water, desalinated water2006 A certain mineral water company 300 Japan Nagano Well water Mineral water2006 The Tuvaluan Government 65 Tuvalu Sea water Drinking water2006 Deep sea water plant 2400 Taiwan Deep sea water Fish farming water2006 LNG plant 2000 Yemen Sea water Industrial water2006 Likuliku Lagoon Resort 100 Fiji Sea water Industrial water2006 Deep sea water plant 4 Japan Mie Deep sea water Mineral water2006 Thermal powder stat ion 2000 Thailand Sea water Industrial water2005 Djibout i Hotel 110 Djibouti Sea water Water to make concrete2005 Thermal powder stat ion 2000 Thailand Sea water Industrial water2005 Treatment of the spring water during digging tunnel 1600 Japan Ehime Brackish spring water Industrial water2005 A certain sake-brewery 6 Japan Kagoshima Well water Water to make sake2005 Yakuin Shiroyama no Yu (Spa) 200 Japan Fukuoka Well water Drinking water2005 A certain old-people's home 20 Japan Fukuoka Well water Drinking water2005 Hotel New Otani 100 Japan Saga Well water Industrial water2005 Iki Sogyo 16 Japan Nagasaki Sea water Mineral water2005 Deep sea water plant 13 Japan Ishikawa Deep sea water Mineral water2005 LNG plant 1060 Indonesia Sea water Industrial water2005 Investigating ship 8 Japan Sea water Drinking water2005 Wajima City 12 Japan Ishikawa Well water Tap water2005 A certain resort hotel 50 Philippines Sea water Industrial water2005 Air Force 60 Japan Sea water Water for emergency2004 Kobe City Brewery 60 Japan Hyogo Sea water Water for brewery2004 Okinawa Kanucha Resort 800 Japan Okinawa Well water Desalinated water2004 MSF Desalination Plant 300 Algeria Well water Drinking water2004 Rubbish inc inerat ion plant 160 Japan Ishikawa Concentrated sewage water Concentrated salt water, desalinated water2004 LNG plant 60 Indonesia Well water Industrial water2004 A certain saltworks 120 Japan Okinawa Sea water Concentrated salt water to make salt




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Installation Customer Capacity, m3/day Country Prefecture(Japan)

Original water Use

2004 Yorigami Marine Construct ion (shipbuilding) 200 Japan shimane Sea water Industrial water2004 Deep sea water plant 480 Japan Kagoshima Sea water Deep sea water2004 TEC Iran 5200 Iran Sea water Industrial water2004 Malolo Island Resort 50 Fiji Sea water Industrial water2004 Fishery Institution 200 Maldives Sea water Drinking water2004 A certain mineral water plant 840 China Sea water Mineral water2004 A certain institute 6 Japan Hokkaido Sea water Drinking water2004 Plantat ion Island 100 Fiji Sea water Industrial water2004 Uchinoura Kishira Onsen (Spa) 12 Japan Kagoshima Well water Drinking water2004 Deep sea water plant 200 Hawaii Deep sea water Mineral water2004 Safari Beach Resort 100 Sri Lanka Sea water Industrial water2004 Abu Dahbi Oil 500 UAE Sea water Industrial water2003 A certain food company 50 Japan Well water Industrial water2003 A certain plant 200 Mexico Sea water Industrial water2003 Yasawa Island Resort 50 Fiji Sea water Industrial water2003 Villa Hotel 200 Maldives Sea water Industrial water2003 JGC Oman 800 Oman Sea water Industrial water2003 Reach Resort 440 Maldives Sea water Industrial water2003 Toa Corporat ion 12 Japan Tokyo Deep sea water Mineral water2003 NGM Corporat ion 12 Japan Saga Well water Industrial water2003 A certain processed marine products plant 72 Japan Well water Industrial water2003 Mana Island Resort 220 Fiji Sea water Drinking water2003 Mitsumi Electric 300 Philippines Well water Industrial water2003 Wakachiku Corporat ion 60 Maldives Sea water Water to make concrete2003 Nishi Nippon Wire & Cable 315 Japan Oita Sea water Industrial water2003 Ground Force - Takematsu Garrison Town 20 Japan Nagasaki Well water Water for boiler2003 A certain brewery plant 6 Japan Kagoshima Well water Water to make sake2003 Uojima Town 55 Japan Ehime Sea water Tap water2002 The Chugoku Electric Power 800 Japan Yamaguchi Sea water Drinking water2002 Shimokari Town Office 11 Japan Hiroshima Sea water Concentrated salt water to make salt

Reference list

A solution for seawater transportation and use in marine ...

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