A Practical and Mild Method for the Highly Selective Conversion of Terminal Alkenes into Aldehydes...
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2005 Aldehyde derivatives Q 0340 A Practical and Mild Method for the Highly Selective Conversion of Terminal Alkenes into Aldehydes Through Epoxidation—Isomerization with Rutheni- um(IV)—Porphyrin Catalysts. — A ruthenium(IV)—porphyrin catalyst is used for the highly regioselective formation of aldehydes from terminal alkenes without C=C bond cleavage. The new method supplements the Wacker process for the oxidation of terminal alkenes to ketones or aldehydes. The reactions occur at room temperature to afford isolable β,γ-unsaturated aldehydes. — (CHEN, J.; CHE*, C.-M.; Angew. Chem., Int. Ed. 43 (2004) 37, 4950-4954; Shanghai-Hong Kong Jt. Lab. Chem. Synth., Shanghai Inst. Org. Chem., Chin. Acad. Sci., Shanghai 200032, Peop. Rep. China; Eng.) — S. Adam 01- 077
Transcript of A Practical and Mild Method for the Highly Selective Conversion of Terminal Alkenes into Aldehydes...
2005
Aldehyde derivativesQ 0340 A Practical and Mild Method for the Highly Selective Conversion of Terminal
Alkenes into Aldehydes Through Epoxidation—Isomerization with Rutheni-um(IV)—Porphyrin Catalysts. — A ruthenium(IV)—porphyrin catalyst is used for the highly regioselective formation of aldehydes from terminal alkenes without C=C bond cleavage. The new method supplements the Wacker process for the oxidation of terminal alkenes to ketones or aldehydes. The reactions occur at room temperature to afford isolable β,γ-unsaturated aldehydes. — (CHEN, J.; CHE*, C.-M.; Angew. Chem., Int. Ed. 43 (2004) 37, 4950-4954; Shanghai-Hong Kong Jt. Lab. Chem. Synth., Shanghai Inst. Org. Chem., Chin. Acad. Sci., Shanghai 200032, Peop. Rep. China; Eng.) — S. Adam
01- 077
