A Mass-Balance, Watershed-Scale Analysis of the Chemistry of Adirondack Lakes Discussion - Day 5.
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Transcript of A Mass-Balance, Watershed-Scale Analysis of the Chemistry of Adirondack Lakes Discussion - Day 5.
![Page 1: A Mass-Balance, Watershed-Scale Analysis of the Chemistry of Adirondack Lakes Discussion - Day 5.](https://reader036.fdocuments.us/reader036/viewer/2022062519/5697bfbb1a28abf838ca0f31/html5/thumbnails/1.jpg)
A Mass-Balance, Watershed-Scale Analysis of
the Chemistry of Adirondack Lakes
Discussion - Day 5
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Patterns and Consequences of Variation in Lake DOC
DOC in 1470 lakes sampled by the Adirondack Lake Survey Corporation (ALSC) in the 1980’s ranged from 0.2 - 35 mg/L.
• Lakes within a given region can vary dramatically in dissolved organic carbon (DOC) concentrations.
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Patterns and Consequences of Variation in Lake DOC
Low DOC lakes typically have- high light penetration,
- higher pH (unless acidified by mineral acids), and
- richer oxygen conditions
Low DOC lakes are also more susceptible to - acidification,
- eutrophication, and
- UV-light effects
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Acid deposition has reduced DOC in many north temperature lakes, with attendant increases in UV light penetration.
High DOC lakes appear to have higher levels of contamination with mercury
Patterns and Consequences of Variation in Lake DOC
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Sources and Fates of Lake DOC
The bulk of the DOC in lakes originates from decomposition in wetland and upland ecosystems within the watershed.
As it moves from uplands to lakes, DOC links terrestrial, wetland, littoral, and open water habitats.
Lakes export far less DOC than they import. Fates of DOC in lakes include photolysis, decomposition, flocculation and sedimentation.
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Objectives
Most previous studies of variation in lake DOC have relied on multiple regression models.
We developed an alternative approach, based on mass balance principles, that focuses on the inputs and losses of DOC.
Our most basic objective was to understand how the composition and spatial configuration of the upland and wetland vegetation within a watershed influences DOC concentrations within each lake.
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Approach
Our approach takes advantage of data sets available for the watersheds of over 600 lakes in the Adirondack Mountains of New York.
The approach is spatially-explicit, and divides each watershed into 10 x 10 m grid cells.
Our analysis estimates the loading of DOC to the lakes as a function of:- the type of vegetation in each grid cell, and- the flow-path distance from the cell to the
lakeshore.
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Map of the roads and boundary of the Adirondack Park. Upland vegetation types of the 610 sampled watersheds are indicated in shades of green. Sampled lakes are shown in blue.
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Within Individual Watersheds
Vegetation Cover Type
Relative Cover over all
Watersheds (%)Median
Cover (%)Minimum
Cover (%)Maximum Cover (%)
Upland Vegetation
Deciduous Forest 30.20 25.9 0.0 84.5
Mixed Forest 41.67 39.2 0.0 94.2
Conifer Forest 12.13 7.4 0.0 93.0
Deciduous / Open 1.73 0.0 0.0 56.0
Open Uplands 4.36 1.4 0.0 67.7
Wetlands
Open Water 0.08 0.0 0.0 7.6
Emergent Marsh 0.67 0.0 0.0 22.0
Deciduous Forest Swamp 1.01 0.0 0.0 17.1
Conifer Forest Swamp 4.43 2.4 0.0 79.9
Dead Tree Swamp 0.16 0.0 0.0 15.1
Deciduous Shrub Swamp 1.99 0.4 0.0 58.8
Broadleaved Evergreen Shrub Swamp 0.70 0.0 0.0 56.5
Needle-leaved Evergreen Shrub Swamp 0.85 0.0 0.0 96.9
Total Area (ha) 42,172.75
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A Mass Balance Model of Variation in Lake DOC
•We assume that lake DOC is in approximate steady state from year-to year. Thus, inputs to a lake should approximately equal outputs.
•Inputs:
• Within-lake annual net production (assumed to be a linear function of lake area)
•Input from wetlands and upland vegetation within the watershed
•Outputs:
• Lake discharge
• Within-lake degradation
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At Steady State:
)))
1-33
(yr k) Rate (Flushing * (m Volume Lake
(g/yr) Loading (g/m DOC
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Inputs to Headwater Lakes
for j = 1..n pixels (100 m2) of i = 1..c vegetation types, where Dij is the flowpath distance from pixelij to the lakeshore LakeArea is lake surface area (in m2), p1 is the estimated within-lake DOC production (g/m2), Ei is the estimated DOC export (g/100 m2) of vegetation type i,
and i, and i are estimated parameters that
determine the decline in DOC loadingof vegetation type i with distance from the lake
iijiD
c
i
n
ji e*E)LakeArea*p(Inputs
1 1
1
0
20
40
60
80
100
120
0 50 100 150 200
Distance from Lake (m)
Lo
adin
g (
kg/h
a)
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Lake DOC Outputs
• Lake Discharge• Discharge = DOC concentration * lake volume * flushing
rate
• Within-Lake Degradation• Degradation = DOC concentration * lake volume * k
• Also allow k to vary as a function of
•ANC: k = a + b*ANC
•Depth: k = a * exp(-b*depth)
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Adding Upstream Lakes – a recursive model
Include watersheds that have embedded ponds within the watershed
For sampled ponds that have other ponds immediately upstream, add inputs from the immediately upstream pond to the loading term (number of immediately upstream ponds is as high as 8, along a branching stream)
Add a term to the model to estimate the percentage of upstream inputs that actually make it to the lake
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Parameters Estimated by the Analysis
• 3 parameters for each vegetation type
• 1 parameter for within-lake production
• 1-2 parameter(s) for within-lake decay (k)
• 3 parameters to account for interannual variation in total loading
• = total of 41-42 parameters when using 12 cover types
• Solve for the parameter values that provide the best fit to the observed variation in lake DOC (i.e. maximize the likelihood of observing the dataset) using simulated annealing (a global optimization procedure)
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Model comparison
Model # Lakes # Parameters Likelihood AICcorr R2 SlopeHEADWATER LAKESBasic Model: Total Distance 355 41 -818.67 1730.34 0.551 1.012
Basic Model: Ground Distance 355 41 -823.13 1739.26 0.538 0.999
Basic Model: Stream Distance 355 41 -832.52 1758.05 0.509 1.005
Basic Model + Depth 355 42 -814.92 1725.41 0.555 0.994
Basic Model + Wetland Loading 355 42 -816.11 1727.79 0.551 1.001
Basic Model + ANC1 348 42 -782.53 0.542 1.003
Reduced Model: No Distance Decay 355 17 -838.26 1712.33 0.498 0.997
Reduced Model: 5 Types Vary 355 22 -824.60 1696.26 0.530 1.011
ALL LAKESBasic Model: Total Distance 428 29 -1040.21 2142.79 0.477 0.995
Reduced Model: No Distance Decay 428 18 -1046.16 2129.99 0.461 0.996
1 ANC model compared against basic model with just 348 lakes
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Headwater Lakes - Reduced Model
0
100
200
300
400
500
0 50 100 150 200 250
Distance from Lake (m)
DO
C L
oadi
ng (
kg/h
a/yr
)
Deciduous Forest
Mixed Forest
Conifer Forest
Deciduous / Open
Open Vegetation
Emergent Marsh
Deciduous Forest Swamp
Conifer Forest Swamp
Dead Tree Swamp
Deciduous Shrub Swamp
Broadleaved Evergreen ShrubSwamp
Needle-leaved EvergreenShrub Swamp
Predicted loading as a function of distance
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Headwater Lakes (n=355)
y = 1.0122x
R2 = 0.5459
0
5
10
15
20
25
30
0 5 10 15 20
Predicted DOC
Ob
serv
ed D
OC
Goodness of fit
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0
50
100
150
200
250
300
350
400
DF MF CF
DO OVEM
DFSCFS
DTSDSS
BESS
NESS
Cover Type
DO
C L
oa
din
g (
kg/h
a/y
r)
532.1
Upland cover types wetlands
Estimated loading from different cover types (all lakes)
Error bars are 2-unit support limits
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Results from Alternative Models
• Significantly worse fits produced when:
• assuming no decline in loading with distance for all cover types
• Using a “topographic index” to identify and limit inputs to areas likely to have saturated soils
• Limiting distance to specified distances from the lake
• Calculating distance to nearest open water (stream or lakeshore) rather than all the way to the lakeshore
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Effects of In-Lake Processes
Net In-Lake DOC Production:
- basic model estimate: 12.4 kg/ha (95% S.I. = 0 – 26.9)
In-Lake Decay
- basic model estimate: 0.82 (95% S.I. = 0.69 – 1.00)
- declines significantly with depth
- marginal increase with fraction of loading from wetlands
- hint of increase with ANC
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Effect of Lake Depth on K
0.0
0.5
1.0
1.5
2.0
0 5 10 15 20
Mean Lake Depth (m)
In-L
ake D
ecay C
oeff
icie
nt
(k)
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Effect of Wetland Loading on In-Lake Decay
0.6
0.7
0.8
0.9
1.0
1.1
1.2
0 20 40 60 80 100
% of DOC Loading from Wetlands
k (
/yr)
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CONCLUSIONS
• Loading of DOC from upland vegetation types associated with disturbance (logging, beech bark disease, and limited lakeshore development)
•was very high when the disturbance was immediately adjacent to the lake,
•but declined dramatically with distance from the lake
• Similar patterns for wetlands dominated by dead trees (beaver ponds)
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CONCLUSIONS
• However, these small headwater watersheds (most with thin, glacial till soils) are very well “plumbed”. Inputs do not decline significantly with distance from the lake for the major wetland and forest types
• There was significant variation in DOC loading from different vegetation types, however:• The main closed forest types (deciduous, mixed, conifer)
had approximately equal predicted loading of ~ 50 kg/ha/yr, and
• 4 of the most common wetland types also had approximately equal predicted loading of ~ 200 kg/ha/yr
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• Thus, as expected, wetlands generally export much more DOC per unit area than uplands
• However, as a result of the much larger area of uplands (~ 90% of drainage area), upland forests are the dominant source of DOC in these lakes
CONCLUSIONS