911-3551-6 Sample Data PackageVinyl Chloride 881129 lOiOO SUB 62 "H~^1 44 50 ' 1 ' '!' 64 / 69 81...

$: 911-3551-6 Sample Data PackageVinyl Chloride 881129 lOiOO SUB 62 "H~^1 44 50 ' 1 ' '!' 64 / 69 81 94,1. / .\ / 50 60 70 80 90 100 Scan 66 2.68 »in. 11N9 rlOO kid ' "•O SflMPLE SPECTRUM$
911-3551-6 Sample Data Package

AR202966

*- ±

QUANT REPORT

Operator ID: MALOS Quant Rev: 6 Quant Time: 911126 18:42Output File: AA3741::D4 Injected at: 911126 17:57Data File: >A3741::D2 Dilution Factor: 5.00000Name: 91L-3551-6Misc: 1ML/5ML

ID Fi le: IDJJCA: : D2Title: HP UOA Standards for 5 Point Calibration Curve Rev. ELast Calibration: 911113 16:18

Compound R.T. Scan* Area Cone Units q

1) *Bromochloromethane 9.02 221 24831 50.00 ug/L 844) Uinyl Chloride 2.70 58 5078 53.86 ug/L 9114) Trans-l,2-Dichloroethene 10.61 262 13019 87.06 ug/L 9215) Chloroform 11.19 277 2214 5-. 00 ug/L 9116) l,2-Dichloroethane-d4 11.81 293 67235 229.76 ug/L 8023) »l,4-0ifluorobenzene 19.36 488 106531 50.00 ug/L 6926) Trichloroethene 16.30 409 5013 25.43 ug/L 8933) *Chlorobenzene-d5 24.20 613 89645 50.00 ug/L 9836) Tetrachloroethene 21.92 554 26936 142.07 ug/L39) Toluene-d8 23.00 582 112764 237.12 ug/L40) Chlorobenzene 24.32 616 518181 1437.35 ug/L45) Bromofluorobenzene 28.39 721 98773 232.25 ug/L

* Compound is ISTD

88202967

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Id File: ID_YCA::D2Title: HP UOA Standards for 5 Point Calibration Curve Rev. ELast Calibration: 911113 16:18

Operator ID: MALOSQuant Time: 911126 18:42Injected at: 911126 17:57

SR202968

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Compound No: 1 (ISTD)Compound Name: BromochloromethaneScan Number: 221Retention Time: 9.02 min.Quant Ion: 128.0Area: 24831Concentration: 50.00 ug/Lq-value: 84

AR202969

REFERENCE STRNDRRD SPECTRUMFile >R0078Bpk flb 2728.

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Data File: >A3741::D2 Quant Output File: /NA3741::D4Name: 91L-3551-6Misc: 1ML/5MLQuant Time: 911126 18:42 Quant ID File: ID_yCA::D2Injected at: 911126 17:57 Last Calibration: 911113 16:18

Compound No: 4Compound Name: Uinyl ChlorideScan Number: 58Retention Time: 2.70 min.Quant Ion: 62.0Area: 5078Concentration: 53.86 ug/Lq-value: 91

AR202970

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Compound No: 14Compound Name: Trans-1,2-DichloroetheneScan Number: 262Retention Time: 10.61 min.Quant Ion: 96.0Area: 13019Concentration: 87.06 ug/Lq-value: 92

AR20297I

REFERENCE STRNDRRD SPECTRUMFile "BIGDB Chlorofor* Scan 67663Bpk flb 9999. CLP FLT 0.00 min.

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Compound No: 15Compound Name: ChloroformScan Number: 277Retention Time: 11.19 min.Quant Ion: 83.0Area: 2214Concentration: 5.00 ug/Lq-value: 91

&R202972

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Compound No: 16Compound Name: 1,2-DichIoroethane-d4Scan Number: 293Retention Time: 11.81 min.Quant Ion: 69.0Area: 67239Concentration: 229.76 ug/Lq-value: 80

AR202973

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Data File: >A3741::D2 Quant Output File: ~A3741::D4Name: 91L-3551-6Misc: 1ML/5MLQuant Time: 911126 18:42 Quant ID File: ID_UCA::D2Injected at: 911126 17:57 Last, Ca 1 ibrat ion: 911113 16:18

Compound No: 23 (ISTD)Compound Name: 1,4-DifluorobenzeneScan Number: 488Retention Time: 19.36 min.Quant Ion: 114.0Area: 106931Concentration: 50.00 ug/Lq-value: 69

AR202971*

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Data File: >A3741::D2 Quant Output File: ~A374l::D4Name: 91L-3551-6Misc: 1ML/5MLQuant Time: 911126 18:42 Quant ID File: ID_UCA::D2Injected at: 911126 17:57 Last Calibration: 911113 16:18

Compound No: 26Compound Name: TrichloroetheneScan Number: 409Retention Time: 16.30 min.Quant Ion: 130.0Area: 5013Concentration: 25.43 ug/Lq-value: 89

AR202975

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Compound No: 33 (ISTD)Compound Name: ChIorobenzene-d5Scan Number: 613Retention Time: 24.20 min.Quant Ion: 117.0Area: 89649Concentration: 50.00 ug/Lq-value: 98

AR202976

REFERENCE STANDARD SPECTRUMFile "BI&DB Ethene, tetrachloro- Scan 127184Bpk flb 100. FLT NRM NOM 0.00 win.

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SRMPLE SPECTRUM (BACK8ROUNO SUBTRACTED)File >R3741 91L-3551-6 1ML/5ML Scan 554Bpk Rb 2838. SUB 21.92 Bin.

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Data File:. >A3741::D2 Quant Output File: ~A3741::D4Name: 91L-3551-6Misc: 1ML/5MLQuant Time: 911126 18:42 Quant ID File: IDJJCA::D2Injected at: 911126 17:57 Last Calibration: 911113 16:18

Compound No: 36Compound Name: TetrachloroetheneScan Number: 554Retention Time: 21.92 min.Quant Ion: 164.0Area: 26936Concentration: 142.07 ug/Lq-value: 99

AR202977

REFERENCE STRNDRRD SPECTRUMFile >VXNSP HP VOR No Spike Internal Standards and 3u Scan 625Bpk Rb 100.

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Data File: >A3741::D2 Quant Output File: ~A3741::D4Name: 91L-3551-6Misc: 1ML/5MLQuant Time: 911126 18:42 Quant ID File: ID_UCA::D2Injected at: 911126 17:57 Last Calibration: 911113 16:18

Compound No: 39Compound Name: Toluene-d8Scan Number! 582Retention Time: 23.00 min.Quant Ion: 98.0Area: 112764Concentration: 237.12 ug/Lq-vaiue: 96

AR202978

REFERENCE STRNDRRD SPECTRUMFile "Bl&DBBpk flb 100.

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Data File: >A3741::D2 Quant Output File: /XA3741::D4Name: 91L-3551-6Misc: 1ML/5MLQuant Time: 911126 18:42 Quant ID File: ID_v"CA::D2Injected at: 911126 17:57 Last Calibration: 911113 16:18

Compound No: 40Compound Name: ChlorobenzeneScan Number: 616Retention Time: 24.32 min.Quant Ion: 112.0Area: 518181Concentration: 1437.35 ug/Lq-value: 97

AR202979

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Data File: >A3741::D2 Quant Output File: 'NA3741::D4Name: 91L-3551-6Misc: 1ML/5MLQuant Time: 911126 18:42 Quant ID File: ID_UCA::D2Injected at: 911126 17:57 Last Calibration: 911113 16:18

Compound No: 45Compound Name: BromofluorobenzeneScan Number: 721Retention Time: 28.39 min.Quant Ion: 95.0Area: 98773Concentration: 232.25 ug/Lq-value: 90

AR202980

SAMPLE INTEGRATION SUMMARY

SAMPLE NAME AND AMT: 91L-3551-6 1ML/5MLSAMPLE DATA FILE: >A3741

PEAK NO. RET. TIME SCAN AREA IDENTIFICATION1 9.02 221 207473 IS2 10.61 262 64026 TC3 11.81 293 159238 SS

4 16.30 409 32290 TC5 19.36 488 307404 IS6 21.92 554 247744 TC7 23.00 582 350288 SS8 24.32 616 2446752. TC9 28.42 722 641658 SS10 34.86 888 824279 UK

IS = INTERNAL STANDARDSS = SURROGATETC = TARGET COMPOUNDUK = UNKNOWN<10% = UNKNOWN LESS THEN 10% OF INTERNAL STANDARD

AR20298I

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AR202982

File >fl3741 91L-3551-6 1ML/5ML Scan 888Bpk flb 3935. SUB

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File >BIGDB Benzene, 1 ,4-dichloro- <9CI) ScanBpk flb 9999.

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File >BIGDB Benzene, 1 ,3-dichloro- <9CI> ScanBpk flb 9999.

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1. Benzene, 1,4-dichloro- (9CI) 146 C6H4C122. Benzene, 1,2-dichloro- (9CI) 146 C6H4C123. Benzene, 1,3-dichloro- (9CI) 146 C6H4C124. Peroxide, bis(dichlorobenzoyl) (9CI) 378 C14H6C1404

Sample file: >A3741 Spectrum #: 888Search speed: 1 Tilting option: S No. of ion ranges searched: 60

Prob. GAS # CON # ROOT K DK #FLG TILT % CON C_I R_IV

1. 96* 106467 16705 "BIGDB 102 6 0 2 89 0 72 942. 83* 95501 16704 "BIGDB 68 43 0 0 100 21 47 833. 81* 541731 16706 "BIGDB 60 48 0 0 100 20 45 734. 79 28604902 16707 "BIGDB 103 44 1 0 187 14 43 63

CORRECTED TOTAL ION AREA OF UNKNOWN = 82427920RRECTED TOTAL ION AREA OF INTERNAL STANDARD ~ 307404CONCENTRATION OF INTERNAL STD = 50 ug/L DILUTION FACTORSEMI QUANTITATION OF UNKNOWN = 670 ug/L

QUANT REPORT

perator ID: LUELLA Quant Rev: 6 Quant Time: 911127 20:21tput File: AB8538::D1 Injected at: 911127 19:19ta File: >B8538::A4 Dilution Factor: 10.00000

Name:. 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)

ID File: ID_BAA::QTTitle: HP BNA Standards for 5 point Calibration Curve Rev. ELast Calibration: 911125 14:56

Compound R.T. Scant Area Cone Units q

1) *d4-l,4-Dichlorobenzene 11.10 722 69567 40.00 ug/1 993) 2-Fluorophenpl 7.67 392 7750 32.54 ug/1 915) Phenol-d6 10.43 658 13644 38.19 ug/1 866) Phenol 10.47 661 4429 12.67 ug/1 8510) 1,4-Dichlorobenzene 11.14 726 14162 53.63 ug/1 9512) 1,2-Dichlorobenzene 11.68 778 54535 212.53 ug/1 9718) *d8-Naphthalene 14.97 1094 283939 40.00 ug/1 8819) Nitrobenzene-d5 12.87 892 11474 30.36 ug/1 9529) 4-Chloroaniline 15.37 1133 51983 141.96 ug/1 9632) 2-Methylnaphthalene 17.52 1340 5316 10.64 ug/1 9133) *dlO-Acenaphthene 20.52 1628 156945 40.00 ug/1 9238) 2-Fluorobiphenyl 18.50 1434 24250 41.87 ug/1 9454) *dlO-Phenanthrene 25.11 2070 275764 40.00 ug/1 9858) 2,4,6-Tribromophenol 23.01 1868 4488 43.08 ug/1 9666) *d!2-Chrysene 33.48 2875 239864 40.00 ug/1 93.9) Terphenyl-dl4 30.29 2568 25471 33.49 ug/1 90) *d!2-Perylene 37.62 3274 186818 40.00 ug/1 93* Compound is ISTD

TOTflL ION CHROMflTOGRflMFile >B8538 35.0-500.0 amu. 9113551-6 1000/10ML

TIC1000 | 2000 t 3000

600000-

550000-

500000-

450000-

400000-

350000-'

300000-

250000-

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150000"

100000-

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12 ' 16 ' 28 ' 24 ' 28 ' 32 ' 36 48 ' 44

Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)

Id File: ID_BAA::QTTitle: HP BNA Standards for 5 point Calibration Curve Rev. ELast Calibration: 911125 14:56Operator ID: LUELLAQuant Time: 911127 20:21Injected at: 911127 19:19

AR202985

REFERENCE STflNDflRD SPECTRUMFile >B7941 d4-l ,4-Dichlorobenzene 910925 09:20 Scan 752Bpk flb 44024.

40000-•

•

SUB 10.89 min.150

52 56 <i*i 78 00 ,48

..i.i . . ...i.40

' / S<\')\ |TIVi ||M'

68

/ 87 " 122. L .(. N . .. ,i. / ...

t

il.

-100

.a80 100 120 140

SflMPLE SPECTRUM <BflCK8ROUND SUBTRflCTED)File >BBpk flb

40000--0-

8538 9113551-6 leee/lOML EXT:1 Sc49456. SUB 11.1

1I

52 ^ 78 QQ 1f538 *. 56 ** / 87 *?

. t^i. . i i.i \f , .f ill. . { ^ .1.49 ' 68 ' 80 ' 100 ' 120 ' 140

an9 m50

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SflMPLE SPECTRUM (UNflLTERED)File >B8538Bpk flb 49456

.48088-.

- 40

e-rl'fi i40

9113551-6.

52 6^ 56 ^.,..1.1,1. ,....£... l .... i ....

68

188e/"18ML

1 1^4 99 // 87 v 11 / \...il.l.. . i , > . . I.I.' 88 ' 188 ' 128

EXT:1 Scan 72211.18 min.

1587 h!80

.

.i il. .g

' 148

Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56Compound No: 1 (ISTD)Compound Name: d4-l,4-DichlorobenzeneScan Number: 722Retention Time: 11.10 min.Quant Ion: 152.0Area: 69567Concentration: 40.00 ug/1q-value: 99

(JR202986

REFERENCE STflNDflRD SPECTRUMFile >B7941 2-Fluorophenol 910925 09:20 Scan 426Bpk flb 46568. SUB 7.50 min.

112

40000-

0-

64

3* 45 50 /? 68 7/ B /2' / / f / ^

l l l l | m i | l i l l | l l l l | l h | l 1 • |li/f| h l l | i l i l | I I l | i i i i | i H I M I I | i n i | i i i i | l . ,

/•

1 140 50 68 70 88 90 100 110

-100

-0

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >B8538 9113551-6Bpk flb 3865.

4000-

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0-J

1000X10ML EXT:1 Scan 392SUB 7.67 min.

11264

S3 K7~o OJ or? \ ' 1M \ .11 I I 1 I I I I I I I I48 58 68

73 83 ?2

/ "1 1

f

\

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La78 ' 88 ' 98 ' • 100 ' li0

SflMPLE SPECTRUM <UNOLTERED)File >B8538 9113551-6Bpk flb 3865.

4000-.

0-

1000X10ML EXT:1 Scan 3927 .67 min .

11264

38 53 57/ \ f 1i ii i , . , 1 1 ,il40 50 60

73 83 2

. / 71 1

/

i

-100

-0

' 70 ' 80 ' 90 ' 100 ' 110

Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56

Compound No: 3Compound Name: 2-FluorophenolScan Number: 392Retention Time: 7.67 min.Quant Ion: 112.0Area: 7750Concentration: 32.54 ug/1q-value: 91

flR20298

REFERENCE STRNDflRD SPECTRUMFile >B7941 Phenol-d6Bpk flb 41968. . SUB

40000-

-Q_

40 . 49 54 SQ 66 -- 72. i i l i It . . i . i . i , . . i . . i . . i 1 . , l 1 1 r . .40 50 60 70

910925 09:20

81 82

Minim mi HI30 90

Scan 69210.26 min.

99

94

i J | r I I -pi «

f

l ,

-100

.

.a100

SflMPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)File >B8538Bpk flb 5668.

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1 1 140

9113551-6 1000/10MLSUB

7*

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SflMPLE SPECTRUM (UNflLTERED)File >B8538Bpk flb 5668.

-4000-: 40

0- , ,' , { I40

9113551-6

42- 49 54

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1000X10ML

71 ?0

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Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56Compound No: 5Compound Name: Phenol-d6Scan Number: 658Retention Time: 10.43 min.Quant Ion: 99.0Area: 13644Concentration: 38.19 ug/1q-value: 86

AR202988

REFERENCE STflNDflRD SPECTRUMFilBpk

e >B7941flb 58848.

-40000-

-39• 40

. . i l l . .40

Phenol

43

l l 1 l45

47 50 55 6i ... i f

50 55

62\

rH+60

SUB

65 66j f 70 74

1 1 1 1 1 if h 1 1 ( \ i65 70 75

910925

79\Ml IM i80

09:20 Scan 69610.31 min.94

92\

f

9£

-100

-a85 90 95

SflMPLE SPECTRUM (BflCKGROUND SUBTRflCTED)File >BBpk flb

2000-

0-

8538 9113551-61949.

39""j 40

40 45

50 55i 150 55

1000/10ML EXT:1 ScanSUB 10.47 n

94/

65 66

If95

i60' 65 70 75 88 85' 98 95

661in .

-100

,SflMPLE SPECTRUM <UNflLTERED>File >B8538 9113551-6Bpk flb 1949.

2000Hi 39 40\/

* ————40 45

50 55r (50 55

1000/10ML

ft* 6665 _„V| 71i l , r60 65 70 75

EXT:1 Scan 66110.47 min.94' 1-100

99 ;

,,,,..,,,..,,.,! ,' , , , ! -080 85 90 95

Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56Compound No: 6Compound Name: PhenolScan Number: 661Retention Time: 10.47 min.Quant Ion: 94.0Area: 4429Concentration: 12.67 ug/1q-value: 85

AR202989

REFERENCE STflNDflRD SPECTRUMFile >B7941 1,4-DichlorobenzeneBpk flb 61248. SUB

-40000- 37 50 J5 " 75 97 99

fS* S S^^ \ X s*J_u —— ..di 1 .. ..ill ,11. l f ..i40 60 80 100

910925 09:20 Scan 75610.93 min.

146

11' 120. /

L^ 1 1 | 1 1 1 1 | 1 1 1 1 | 1 1 -rr. -

f

i

-100

-a120 140

SflMPLE SPECTRUM (BflCKSROUND SUBTRRCTED)File >BBpk flb

5800-

^

8538 9113551-6 1000/10ML7417. SUB

1/ 51 55 73 84/ V iT f (.40 60 80 100

EXT:1 S11.1

11

120 140

c14/

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an4 rr6

726nn .

,-100

•

SflMPLE SPECTRUM <UNflLTERED>File >BBpk flb

5000-

g.

8538 9113551-6 1000/10ML EXT:1 S<7417. 11.

1

50 75 1113 7 / 5 5 f 85 |

fTT . ,L <f . .ill, . .,<. ..I.I ,40 ' 60 ' 80 ' 100 ' 128 ' 140

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Data File: >B8538::A4 Quant Output File: *B8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56

Compound No: 10Compound Name: 1,4-DichlorobenzeneScan Number: 726Retention Time: 11.14 min.Quant Ion: 146.0Area: 14162Concentration: 53.63 ug/1q-value: 95

AR202990

REFERENCE STflNDflRD SPECTRUMFile >B7941 1,2-Dichlorobenzene 910925 09:20 ScanBpk flb 52632.

.

40000-

•50 f.i

37 / 55 ..0 * P jr

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/ / \ i /I'f'f'f I'l'l'i'l'i i *'i'| i I'f'J'i1'1' i i | 1 i i i 1 i ii i ! i i i .

l80 100 120 140

807mm .

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SflMPLE SPECTRUM <BflCK6ROUND SUBTRfiCTED)File >BBpk flb

.

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8538 9113551-6 1000/10ML EXT:1 Sc26248. SUB 11*6

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7C HI50 63 / Q4 97 /3f ; 00 ., - 84 v

.11. ..id i, n.r ..lilt ii., ^ ..,.1.1,40 ' 60 ' 80 ' 100 ' 120 ' 140

a84/

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nit6

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778in .

r-100

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SfiMPLE SPECTRUM <UNflLTERED>File >B8538 9113551-6 1000/10ML EXT:1 Scan 778Bpk flb 26248. 11.68 min.

146.

20000-

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75 I*-*37 J 55 y f 84 97

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Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56Compound No: 12Compound Name: 1,2-DichlorobenzeneScan Number: 778Retention Time: 11.68 min.Quant Ion: 146.0Area: 54535Concentration: 212.53 ug/1q-value: 97

AR20299I

O -u DREFERENCE STflNDflRD SPECTRUMFile >B7941Bpk flb 35872

50600-42

40

d8-Naphthalene•

52\

54 68 7*

68

SUB

82 88

80

910925 89:20

X wO * ft rt94 108

i 1 i 1 I M 1 1 i i i i i | i i100 120

Scan 112014 .72 min .

136

128i'1'i I'l' -i ~

/ -100

-a

SflMPLE SPECTRUM (BflCKGROUND SUBTRflCTED)File >B8538 9113551-6Bpk flb 115952.

100000-

: 42 52. ./ ^40

54 68r" M

60

1000/18MLSUB

76 78 99 106

80 100


136f -100

108 130 !f" ^ , 1, 1 '«

120

SflMPLE SPECTRUM <UNflLTERED)File >B8538 9113551-6Bpk flb 115952.

100000

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40 ' 68

1000/10ML

76 78 90i.x- .r80

106 y

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136' -180

g 130 ;N.I.I, i. .9

120


Compound No: 18 (ISTD)Compound Name: d8-NaphthaleneScan Number: 1094Retention Time: 14.97 min.Quant Ion: 136.0Area: 283939Concentration: 40.00 ug/1q-value: 88

AR202992

REFERENCE STflNDflRD SPECTRUMFile >B7941 Ni trobenzene-d5 910925 89:20 Scan 923Bpk flb 40856. SUB 12.67 min.

8240000-

*42 5|

I'/ .' 1 1 i ' 1 ' l '40

54

66 70 7?

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SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >B8538 9113551-6 1000/10ML EXT:1 Scan 892Bpk flb 5139. SUB 12.87

82.

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1

9.9 112( f

40 60 80 100 120

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SflMPLE SPECTRUM (UNflLTERED)File >B8538 9113551-6 1000/10ML EXT:1 Scan 892Bpk flb 5139.

.

4000*-

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12.8782

id

42 5, ( .140

70 761 {

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98 1121 f

60 ' 80 ' 100 ' 120

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2i

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Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML . EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56

Compound No: 19Compound Name: Nitrobenzene-d5Scan Number: 892Retention Time: 12.87 min.Quant Ion: 82.0Area: 11474Concentration: 30.36 ug/1q-value: 95

AR202993

REFERENCE STflNDflRD SPECTRUM ________ ^u OFile >B7941 4-Chloroaniline 910925 09:28 Scan 1168Bpk flb 58528. SUB 15.13 min.

127.

40080-' "

-rt.

6539 52 " i 73 7,6 92 100 IIP' / ^ X ' { ,1 1 1 Iti. 1 1 .. .1 1 1 . . i i i l l l i i ..in. . • . . i ii i . ..ilti. i. ,

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162

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40 60 80 100 120 . 140 160

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >B8538Bpk flb 12807

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130

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hl00•

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SflMPLE SPECTRUM <UNflLTERED>File >B8538 9113551-6 1000/10ML EXT:1Bpk flb 12S87.

18000-

0-

6539 52

ill.. .1 ,..i nil'40 ' " ' " ' '6'0' r

127'

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130Ji "

80 ' 100 ' 120 ' 140

Scan 113315.37 min.

hl001

L-a160


Compound No: 29Compound Name: 4-ChloroanilineScan Number: 1133Retention Time: 15.37 min.Quant Ion: 127.0Area: 51983Concentration: 141.96 ug/1q-value: 96

AR20299.4

REFERENCE STflNDflRD SPECTRUMFile >B7941Bpk flb 75993.

50000- 39

gJ'l'l'i i i40

2-Me thy 1 naphthaleneSUB

51 57 63 71 87 *?

i'1'l I ' l 1 . I'l'l'i i If'i'l'l'i | i I'l'^'l'i i i60 88

918925 09:20

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142' -180

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60 80 100


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SflMPLE SPECTRUM CUNflLTERED)File >B8538Bpk flb 2311

2000-•- 40. /

0- , ! , ,40

9H3551-6 isee/

51 57 78 71/ / ~m*~-- ~ *^i t 1 l l

68 88

18ML EXT:1 Scan 134817.52 min.

142

115

'I

-188,

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1 -0180 ' 128 ' 148

Data File: >B8538::A4 Quant Output File: *B8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56Compound No: 32Compound Name: 2-MethylnaphthaleneScan Number: 1340Retention Time: 17.52 min.Quant Ion: 142.0Area: 5316Concentration: 10.64 ug/1q-value: 91

RR202995

REFERENCE STflNDflRD SPECTRUMFile >B7941 d!0-flcenaphthene 910925 09:20 Scan 1651Bpk flb 44088. SUB 20.24 min.

16440000-

0-1

42 54 66^ ^S / 9g 106 108 igg ±3g ±3Q 156

i'1'i1 1 1 1 i-l'l'i 1 1 i'1'l 1 11 i'i I'l1/1! 1 1 1 H'l 1 1 si 1 1 1 \ 1 1 1 1 \ \ 1 1 1 1'l'i'v'i'i 1 1 1 1 1 i'i"i'l'

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SflMPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)File >BBpk flb

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8538 9113551-6 1000/18ML EXT:1 Sc*55288. SUB 20. S

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8042 54 66 68 / 90 "6 1" 1£2 138 1« 156

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SflMPLE SPECTRUM <UNflLTERED>File >BBpk flb

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8538 9113551-6 1000/10ML EXT:1 Sea55288. 20. S

1

pa42 54 6 .. , ,. 186 1.. 146 IB.

...- ..if. . i .<. ...L .../.. .\/ . / ./... N >.i.. | .... | .... | .... | i ... | .... | ......... | .... | .............. , . . . . ,40 60 80 100 120 140 1£

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Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56Compound No: 33 (ISTD)Compound Name: dlO-AcenaphtheneScan Number: 1628Retention Time: 20.52 min.Quant Ion: 164.0Area: 156945Concentration: 40.00 ug/1q-value: 92

ftR202996

REFERENCE STflNDflRD SPECTRUM <"""File >B7941Bpk flb 93144

100809-

39

0- i |i i i i40

2-Flu.orobipheny 1

51-t-H-

63•iM'l'l'il'l60

76 85

I'l'l'l'l I'l'i'l'l'i80

SUB

94I'VI I'l'l i100

120107 \

910925 09:20

125

'I'l'l'i'i'il'hn'l120

133 m*s 146/ /•I'M i-i ii'h'/'h140

Scan 145918.24 min.

172^

157 ,' ...11.

-100

-ai'l | 1 1 I'l'l'l l v160


39

9- •40

9113551-6

51 63 73 85I. . .1 in, i Ii.

60 80

1000/10MLSUB

12094 vf i100 120


172" -100

133 151 153 ;

1 t I ill* t i l l 1 _Q

140 ' 160

SflMPLE SPECTRUM <UNflLTERED)File >B8538Bpk flb 7913

5000- 39

^j " ^ __ __

40

9113551-6

51/

63

60 '

1000/10ML

73 85 94/ { /

80 100

120\

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120


172"x*

133 151 153

/ \/ lli

-100

•

1 ' ' -j- '-'•'-' i i i i . i i •'" 'i -V140 160


Compound No: 38Compound Name: 2-FluorobiphenylScan Number: 1434Retention Time: 18.50 min.Quant Ion: 172.0Area: 24250Concentration: 41.87 ug/1q-value: 94

AR202997

REFERENCE STRNDflRD SPECTRUMFile >B7941Bpk flb 74056.

50000-

042

• 1 ' M ' 1 140

d!0-Phenanthrene

/ 661 1 1 1 I'l'l i 1 1 160

80 94• • ?J

80

SUB

100 H? 13*/ \ \1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 |

100 120

910925

132 146

-W 1 1 1 1 1 1 11 I140

09:20 Scan 289124.82 min.

188V>"

160 178/

1 1 1 1 1 1 . i160

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-100

-0180

SflMPLE SPECTRUM (BflCKGROUND SUBTRflCTED)File >B8538Bpk flb 8933(

50000-42

40

_9113551-6s .

*? 66 80 94

60 80

1000/10MLSUB

118 130/ \ \,100 120

EXT:

132 146 lfie

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1 Scan 207025.11 min.

188^ -100

170/ ....!.,! 1. 19

188

SflMPLE SPECTRUM CUNflLTERED)File >B8538Bpk flb 89336

50000-42

40

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2 66{,.. ... { ..... i .... , ..

60

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EXT:

132 146 168

140 160

i Scan 207025.11 min.

188***•

1701.

-100

-a180

Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTinjected at: 911127 19:19 Last Calibration: 911125 14:56Compound No: 54 (ISTD)Compound Name: dlO-PhenanthreneScan Number: 2070Retention Time: 25.11 min.Quant Ion: 188.0Area: 275764Concentration: 40.00 ug/1q-value: 98

flR202998

REFERENCE STflNDflRD SPECTRUMFile >B7941 2,4,6-Tribromophenol 910925 09:20 Scan 1892Bpk flb 21200. SUB 22.75 min.

33020008-

0-1

6237 -"" 91 111 / 172 1tT 220 J22 250

J'l Il''i fv Mi Vfh | 7 1*>*| V fi ft f M 'M*. | i . I"! i • . ft . . | i'fti |

-188

L040 80 120 160 280 240 280 320

SflMPLE SPECTRUM (BflCKGROUND SUBTRflCTED)File >B8538Bpk flb 1648

1088- 5/

48

9113551-6•

623f" 91 111II , ( (

88 128

1880/10ML.SUB

141/ 170II T

160 200


330

""Ti "100222 250 '.

240 ' 288 ' 328

SflMPLE SPECTRUM <UNflLTERED)File >B8538Bpk flb 1648.

1800" o%/• t

48

9113551-6

62j<*5| 91 111

1 ' 'II l 1 l88 128

1888/18ML

141/ 178II T' 160 ' 288

222 258ih 1' 248


338•>x

• I;L288 ' 328

Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56Compound No: 58Compound Name: 2,4,6-TribromophenolScan Number: 1868Retention Time: 23.01 min.Quant Ion: 330.0Area: 4488Concentration: 43.08 ug/1q-value: 96

RR202999

REFERENCE STflNDflRD SPECTRUMFile >B7941Bpk flb 75899

50000-

: 52(i! ^40

d!2-Chrysene.

ftfi 90 106 120"v. ^ _ >s_

t i i i i i i \ | i . r | i80 120

SUB

126 154 170/ \ \

160

910925 09:20 Scan 289533 .18 min .

240"*"""•

182 4 212../. .,/.....,/,... ..,.,. nlii

-100

241 ;

L Jj. la200 240


•

40000

9113551-6,

1 cue.J 52 66 78 "X _0 j •,.,/', •'• ••"•-•-'• -.»'48

I ' ' ' 1 ' ' ' 180

1000/10MLSUB

120 156 158k ^ 132 \ / 180I.....JI .. f . . X.< .. S..

120 160


248"""

194 288

/ ./.. . ...,.L

-108

241 '

. -a¥00' r "~ ' 240 ""

SOMPLE SPECTRUM <UNflLTERED>File >B8538 9113551-6 1000/10ML EXT:Bpk flb 69664.

•

40000-

g]

40

52 66.f.

-,0 106 120 156 15878 L s. 132 x s./......,.....,!....., Jl .. / . . X./T ..80 ' 120 ' 160

194 208180 / v

200

1 Scan 287533.48 min.

240"

. ..i Jul

241

i

r!08r

-0240

Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56Compound No: 66 (ISTD)Compound Name: d!2-ChryseneScan Number: 2875Retention Time: 33.48 min.Quant Ion: 240.0Area: 239864Concentration: 40.00 ug/1q-value: 93

&R203000


100000

54\r-T-r-T-r

40

Terpheny l-d!4.

66 88V"l 'i""[""""

81 — p-0

SUB

106 ±sp 136r / "V120

910925 09:20

198 212160 174 v \•i-'-h'!-"! 1' T . Wi'l-'-T160 200

Scan 259130.02 min.

244*""

226

-100

n

240

SflMPLE SPECTRUM (BflCKGROUND SUBTRflCTED)File >B8538Bpk flb 9420

10000-

'. 54

0" * * *40

9113551-6•

66 80 94\ / / /1 i i l l I I I

80

1000X10MLSUB

06 122 136ill 1 1 i

128

160..i.160

EXT:1

198 212\ \

i 1

200

Scan 256830.29 min.

244j -108

226/ , J| '1 1 i lilll* _fl

248

SflMPLE SPECTRUM (UNflLTERED)File >B8538Bpk flb 9420.

10000-

' 54

40

9113551-6

66 80 94. . . .Q.0. . . .

1000/10ML

106 3,22 136 ±60

120 160

EXT:1

198 212

N \200

Scan 256830.29 min.

244"""I -100

226f ..tllfl

240

Data File: >B8538::A4 Quant Output File: AB8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56Compound No: 69Compound Name: Terphenyl-dl4Scan Number: 2568Retention Time: 30.29 min.Quant Ion: 244.0Area: 25471Concentration: 33.49 ug/1q-value: 90

AR20300I

REFERENCE STflNDflRD SPECTRUM _______________________________________ 0 ,. File >B7941 d!2-PeryleneBpk flb 72040.

80000-

40000-

0-1

42 ff n 114 132/ 66 90 x -^.

1 1 II II . . I.I 11 in 1 |J I ill 1

40 80 120

SUB

156 180i l i i i' l i i i 1 i i

160

910925

284 208\ /

'i 1 V"i i '|200

09:20 Scan 329337 .32 min .

264"*" -100

232 2t _i 'l"l' | i i 1" '4 i i | L0

248 288

SflMPLE SPECTRUM (BflCKGROUNO SUBTRflCTED)File >B8538 9113551-6Bpk flb 50312.

.40008-

- 5c

40

76' \

13288 184 ""-j

... .A .. J. . ...,l . J88 128

1088/18MLSUB

±t 156 180

160

204 288\/200

£XT

232. u.it

:1 Scan 327437.62 min.

264f**1

260

KL00

-0240 280

SflMPLE SPECTRUM <UNflLTERED)FileBpk

>B8538flb 50312

.40000-

0-, ...

40

40

9113551-69

76X 88

80

1000/10ML

132104 >.,/....„ J|

120

149\

• i • •156 180 * ?

160 208

EXT:1 Scan37.62

264~""

y7 232 ati< ..L ..J,

240L

3274mm .

hl00

-o280

Data File: >B8538::A4 Quant Output File: *B8538::D1Name: 9113551-6Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 20:21 Quant ID File: ID_BAA::QTInjected at: 911127 19:19 Last Calibration: 911125 14:56Compound No: 75 (ISTD)Compound Name: d!2-PeryleneScan Number: 3274Retention Time: 37.62 min.Quant Ion: 264.0Area: 186818Concentration: 40.00 ug/1q-value: 93

/JR203002


SAMPLE NAME AND AMT: 9113551-6 1000/10MLSAMPLE DATA FILE: >B8538

PEAK. NO. RET. TIME SCAN AREA IDENTIFICATION1 5.68 - 2 0 1 70238 UK2 6.73 302 421778 UK3 7.67 392 24900 SS4 10.32 647 100744 UK5 10.43 658 48880 SS6 11.10 722 469047 IS7 11.14 726 28366 TC8 11.68 778 218926 TC9 12.87 892 31419 SS

10 13.82 984 64532 UK11 14.97 1094 633445 IS12 15.38 1134 169382 TC

13 18.50 1434 59113 SS14 18.80 1463 2664618 UK15 19.25 1506 4360193 UK16 20.52 1628 706396 IS17 21.05 1679 31241

18 25.11 2070 732181 IS19 27.91 2339 186492 UK

20 30.29 2568 52327 SS21 30.39 2578 66840 <105<22 33.48 2875 707459 IS

23 37.62 3274 • 512655 IS

IS - INTERNAL STANDARDSS =- SURROGATETC - TARGET COMPOUNDUK - UNKNOWN<10S = UNKNOWN LESS THEN 10X OF INTERNAL STANDARD

AR203003

File >B

600000-

60000-

20000-

480000-

440000-

400000-

360000-

320000-

280000-

240000-

200000-

160000-

120000-

80000-

40000-

0-

8538 35.0-500.0 amu. 9113551-61000 £000. . . . i . . . . i . . . . i . . . . i . . .

2 6

1

i

4: i4 ' ' ' 8 ' ' '

1

1

4 <4XX

8

910i l

.2i :,

^

16 18

.7

1000/-10ML

3000

22

19

T

23

i • i • i • i • i • i l i • i • f • ( • i ' i • I •12 16 20 24 28 32 36 ' '40' ' '44

EXT

-100

-90

-80

':7Q

-60

-50

-40

:30

:£0

-0

FiU >B8538 9113551-6 1000/10MLBpk flb 6048. SUB

1 4-?-O9 ? « "nJi II 1 i i,i 1 i

EXT!llx£2 Scan 2015.68 min.166

•^ i?1 ' f t

Li ,L40 SO 80 100 120 140 160

Fila >8I60B Ethane, tetrachloro- <9Bpk flb 9999.

-\ ]| 4-L J.9 ,59 32 /4 "• 117

Cn Scan 198480 .00 min .

Ib6i29 131 ' L.

, .1.. . ,1, L40 ' 60 ' so ' "ibb" ' ' " 'iab" '" "iVo" ''"ieb

Fila >BIGDB Quinazoline, 4-chloro- <8CBpk fib 9999.

J 7 , 1 0 275 82 /

../, .' ' ...L

I9CI) Scan 194800.00 min.

L29•-~. 164 ,/ r

130 . \. i. . il. Ln

40 ' 60 ' 80 ' 100 ' 120 ' 140 ' 160

File >BI6DB Benzene, t <2-chloro-2-propeny 1 )oxy ]- C9CI> Scan 1»*81Bok flb 9999. 0.00 mm.

1331 39 51 65 77 ^ 94 105 f 168 tf" / / > 2? { H5 119 141 151 -•„ fJ.,l..........i...........,.i.... ....i.l.rT.......,.........J.,........<...-rrr... ..III,. ..s.. ..«?. ....i. L40 ' 60 ' 80 ' 100 ' 120 ' 140 ' 160

1. Ethene, tetrachloro- (9CI) 164 C2C142. Quinazoline, 4-chloro- (8CI9CI) 164C8H5C1N23. Benzene, C(2-chloro-2-propeny1)oxy]- (9CI) 168 C9H9C10

Sample file: >B8538 Spectrum #: 201Search speed: 1 Tilting option: S No. of ion ranges searched: 56

Prob. CAS # CON # ROOT K DK #FLG TILT % CON C_I R_IU

1. 89» 127184 19848 "BIGDB 104 18 2 2 87 0 66 692. 11* 5190681 19480 "BIGDB 23 78 ^ Q 72 65 2 123. 11* 53299539 14421 "BIGDB 22 104 3 0 79 63 2 12

CORRECTED TOTAL ION AREA OF UNKNOWN - 70238CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 469047CONCENTRATION OF INTERNAL STD = 40 ug/1 DILUTION FACTOR - 10SEMI QUANTITATION OF UNKNOWN = 60 ug/1

AR203005

File >B8538 9113551-6 IQOO/IOMLBpk flb

-

1 ^

55523. SUB77

•u38 48 "i 56 61 72 84

1 1 1 1 1 i i i i 1 iTi 1 1 1 M i ( 1 1 i i | i l 1 i | i i i i i7"i 1 1 | 'I'-i 1 i | iTTi-f40 50 60 7Q 80

EXT: 11/22 Scan 3026.73 mm.

1' *

85 ' 97HI i |i n i|i IM'II i i i | u i i | i l

90 100 110

File >BISDB Banzene , chloro- (SCI SCI) ScanBpk flb

-

:

9999.

ISf

4-1 -

"~

-0

108830 .00 min ,112

7738 48 51 56 61 ?2 ' 84

40 ' 50 '' ' 60 "'"'V6 ' '" "80

J.5 J? 1W

90 100 110

t [-

File >BIGDB Benzoyl chloride <DOT> <8C I 9CI ) Scan 458Bpk flb

:

3999.

<• <51

3? 43 / 57 62 72 79

40 ' 50 ' 60 ' 70 ' 80

0.00 min.105/

36 96 97 111

i i i i | i • • i j i ! • • | < • ! • | ! i i i j ! ' "90 100 110

1. Benzene, chloro- C8CI9CI) 112 C6H5CI2. Benzoyl chloride (DOT)(8CI9CI) 140 C7H5C10


Prob. CAS * CON # ROOT K DK #FLG TILT \ CON C_I R_IU

1. 82* 108907 10883 "BIGDB 65 29 0 0 92 23 41 782. 31 98884 458 "BIGDB 62 33 2 0 81 45 12 22

CORRECTED TOTAL ION AREA OF UNKNOWN = 421778CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 469047CONCENTRATION OF INTERNAL, STD = 40 ug/1 DILUTION FACTOR - 10SEMI QUANT I TAT ION OF UNKNOWN = 360 ug/1

AR2G3006

File >B8538 9113551-6Bpk flb 14903.

" 3,940 45 46 51 52;' --- / •-x /

1QOO/-10ML EXT:ll.--22 Scan 647SUB 10.32 mm.

9366

6Z°' 74 7673 91

/I ' ' 1 ^ 1 -\ 1

Y[

U-|L.n40 44 43 52 56 60 64 68 72 76 80 84 88 ?2

File ./BISOB ' flniline CflCN)C8CI> Scan £785Bpk flb 9999.

j 5,940 43 46 51 52 5

0 .00 mm .93

.65 665 6 ST.. .-"' 74 7678 86 91/ r , 1 i "> / , f ^ "^ 1

40 44 43 52 56 60 64 63 72 76 30 34 SS 92

File .--BIGDB Si lanediamine , 1 , 1-di me thy 1 -N , N '-diphenv 1- (8CI9C Scan 2796Bpk flb 9999. ' 0.00 min.

J3941 43 47 51 52 R,1,,'.-'...'' . ,,>

fi^ 665 62°, --- 74 77 78 88 91

93

T--1 °40 44 48 52 56 60 64 63 72 76 80 84 88 92

File >BIGDB Benzenamine , hydrochlor ide (9CI> Scan 2789Bpk flb 9999. 0.00 min.

j 40 45 46 50540-^ ^ • ^ ' ^r [-T j-r-

62s5 74 75 78 91/ > ^ ^ . . f. ~^,

93

'\

'Ln40 44 48 52 56 60 64 68 72 76 80 84 88 92

<•»,-» j

1. Aniline (ACNH8CI) 93 C6H7N2. Silanediamine, 1,1-dimethy1-N,N'-dipheny1- C8CI9CI) 242 C14H18N2Si3. Benzenamine, hydrochloride (9CI) 129 C6H8C1N4. 3-Penten-l-yne (8CI9CI) 66 C5H65. lH-Pyrazole-4-carbonitrile C9CI) 93 C4H3N3



1. 96* 62533 2785 "BIGDB 84 6 1 0 97 5 72 962. 89 13435091 2796 "BIGDB 102 17 1 0 80 1 66 613. 63 142041 2789 "BIGDB 64 22 1 0 100 20 30 304. 58* 2206237 2771 "BIGDB 59 40 2 -2 43 17 25 235. 43* 31108573 2797 "BIGDB 29 52 2 0 90 23 17 14

CORRECTED TOTAL ION AREA OF UNKNOWN = 100744 AR2Q3007CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 469047CONCENTRATION OF INTERNAL STD - 40 ug/1 DILUTION FACTOR - 10SEMI QUANT ITAT ION OF UNKNOWN - 86 ug/1

File >B8538 9113551-6 lOOO-'lOML EXTsll-£2 Scan 984Bpk flb 8023.

: 39 4K - / ^

fl_ \ | J | i • 1

40

F i l e :-8I6DBBpk Ob 9999.

SUB 13.82 min.127

65 q«

5 52 ~-~_ 66 73 , 100 102

50 60 70 90 90 100 110 120

o-Ch 1 or oan i 1 i ne Scan

,il130

134720 .00 min .

127

1 ' '39 50 52 *5 66 73 86 92 99 102 130

i /oJ-t.'H - i,.-40

File >BIGDBBpk flb 9999.

- ^ " ^ -~~ — '"""* "" / , rff -*'i' • i . t i r I ! " . . i i . . . " r . . 1 i . f i , T . ' , T

50 60 i7 0 °C* on -in it H'"1 1°0

p-Chloroani 1 ine <PCN> Scan

,lln130

134850.00 min.

12/

1 39

40

File >BI6DBBpk flb 9999.

52 6-P 66 73 9£ 100 log '

50 60 70 SO 90 100 110 120

m-Chloroani 1 ins Scan

',,1130

134730 .00 min .

127

1 39 SJ /

( H i ' j ' i - i - i - i40

i 52 b- . 66 73 84 9S 1°° 102 110

50 60 70 80 90 100 110 120

,-jJU H)130

I. o-Chloroani1ine 127 C6H6C1N2. p-Chloroani1ine CACN) 127C6H6C1N3. m-Ch'loroani 1 ine 127 C6H6C1N4. Pyridine, 2-chloro-6-methy1- C9CI) 127 C6H6C1N5. Pyridine, 2-chloro-4-methy 1- (9CI) 127 C6H6C1N

Sample file: >B8538 Spectrum #: 984-Search speed: 1 Tilting option: S No. of ion ranges searched: 56

Prob. CAS * CON * ROOT K DK #FLG TILT % CON C_I R__IU

1. 87* 95512 13472 "BIGDB 67 31 2 0 100 3 63 482. 86* 106478 13485 "BIGDB 61 37 2 3 80 4 60 373. 76* 108429 13473 "BIGDB 57 47 3 0 100 6 45 224. 70* 13368633 13478 "BIGDB 35 73 3 0 100 10 42 135. 60* 3678624 13476 "BIGDB 37 67 3 0 100 13 30 13

CORRECTED TOTAL ION AREA OF UNKNOWN = 64532CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 633445CONCENTRATION OF INTERNAL STD = 40 ug/1 DILUTION FACTOR = 10SEMI QUANTITATION OF UNKNOWN - 41 ug/1

FileBpk

Fi laBpk

FileBpk

FileBpk

>B8538 9113551-6flb 164161.

ij 39 51 63 651 x" / '•--. ^

O-M'i'i , ! ,i|i|., ,i | ,.|.i|ir; ,i, ,.p40 60

1000/10ML EXTtll/22 ScanSUB 18.80

15<<

* 39 98 102 115 128 129 139'l | i I ' l ' l ' l ' l l I'Mf'f'i l I'l'l'f'i' i | I'l'H'^ i i i ' 1 ' l i i 1 I'f'l'l , -

mm .

i.tn80 100 120 140

>BIGDB 1 ,1 '-Bipheny 1 C9CI) Scanflb 9999. O.OQ

| ?9 ^ *? 65 /6 37 98 102 115 126129 139,

40 60

17935mm .54^ l

30 100 120 140

••BIGDB Naphthalene, 2-ethenyl- <9CI> Scanflb 9999. 0.00

1

j 40 51 63 . 6g ?6 Q7 1Q1 102 ilg 128 129 139

• i ' ' • • i • • • • ( . • • • i •' -40 60

17944min .

.54

130 100 120 140

>BI6DB flcenaphthene <8CI) Scanflb 9999. 0.00

]

j 39 51 63^ 73 ™ 97 99 102 115 126129 139 .

40 ' 60 '

17933min .

.54

l.Lo80 ' 100 ' 120 ' 140

1. l,l'-Biphenyl (9CI) 154C12H102. Naphthalene, 2-ethenyl- (9CI) 154 C12H103. Acenaphthene (8CI) "154C12H104. 1,4-Ethenonaphthalene, 1,4-dihydro- (8CI9CI) 154C12H105. 1-Isoquinolinecarbonitri le C9CI) 154C10H6N2


Prob. CAS # CON # ROOT K DK #FL6 TILT % CON C_I R_IU

1.' 68* 92524 17935 "BIGDB 65 40 0 0 60 50 20 782. 59* 827543 17944 "BIGDB 59 42 1 1 53 32 22 443. 41* 83329 17933 "BIGDB 50 40 1 2' 34 45 14 344. 35* 7322476 17956 "BIGDB 49 43 1 1 38 46 11 315. 28* 1198307 17946 "BIGDB 28 78 2 0 69 40 10 14

CORRECTED TOTAL ION AREA OF UNKNOWN - 2664618CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - • 706396CONCENTRATION OF INTERNAL STD - 40 ug/1 DILUTION FACTOR =SEMI QUANT ITAT ION OF UNKNOWN = 1500 ug/1

File >88538 9113551-6 1000/10ML EXT:ll.--22 Scan 1506Bpk flb 95496. SUB 19.25 mm.

9 / 77 -'•-'•'• ""--6_5 "~1 35 94 102 1,15 128 139 |, 155

40 £0 80 100 120

File >BIGOB Benzene, l.l'-oxybis- <9CI) Scan 20296Bpk flb 9999. ' ' ' 0.00 mm.

170

1 OQ 51 77 141] 3,9 / 65 - 35 94 102 i15 129 139 •-" 154

.1 . / .. I / / / i -"-. "- I.40 60 30 100 120 140 160

File >BIGDB Quinaldonitrile, 3-hydroxy- (SCI) Scan 20312Bpk flb 9999. 0.00 min.

170

50fn

64 70/ ^

il. i .1.88•*-*.

1J.3

J? \M. lit 1,

i ' ' i ' ' ' t ' • ' • i ' ' ' • i • • * ' i • ' ' • i ' ' • • i ' ' • ' i ' ' ' • i • ' ' ' rr40 60 80 100 120 140 160

File >BISDB l,3-Benzoxazepine-2-carbonitrile (8CI9CI) Scan 203138ok flb 9999. 0.00 min.

118^ 170 ,

51/ii..

63/

.il,74/

9036--->. I ,.

141i i.

I • I I I ' ' I ' ' ' ' I ' * ' ' I ' ' ' ' I ' ' ' ' I ' ' ' 1 ' ' ' [ - * T r . . . f I-T-.-T j

40 60 80 100 120 140 160

1. Benzene, l,l'-oxybis- (9CI) 170 C12H1002. Quinaldonitrile, 3-hydroxy- C8CI) 170 C10H6N203. l,3-Benzoxazepine-2-carbonitrile (8CI9CI) 170 C10H6N204. 1,4-Methanonaphthalene, 1,4-dihydro- (8CI9CI) 142 C11H105. [l,l'-Biphenyl]-3-ol (9CI) 170 C12H100


Prob. CAS # CON # ROOT K DK #FLG TILT % CON C_I R__IU


CORRECTED TOTAL ION AREA OF UNKNOWN = 4360193CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 706396CONCENTRATION OF INTERNAL STD = 40 ug/1 DILUTION FACTOR = 10SEMI QUANT I TAT ION OF UNKNOWN = 2500 ug/1

Fila >B8538 9113551-6 1000/lOML EXT:ll/22 ScanBpk flb 14173.

-1 « 631 b3J.,, ,1.. /, .,40

File .'BIGDBBpk flb 9999.

-: si 63

r ' • . L ,40

File ,>BIGDBBpk flb 9999.

: si 63, oi, ,>, /, —

40

File >BI6D8Bpk flb 9999.

J51 63••f-r ?- r ,-' , •40

SUB 27.91.

15277 101 115 1£7 151 .--• 169 189 £02 ^ ~ --w " / ~~~~ «•"""* f **** "11. • M.I • i \, . , i. , , H, 1,1,, ill i, iii t, , . 1 . ij .i.ii, ilmi. ip n 1 20 i •••• £* •''"'C1 240

2339mm .

j

_

i.n

l,l'-Biphenvl , 2-phenoxv- <9CI) Scan 291200.00246

15277 101 115 127 151 .--• 169. 139 2Q£ 2291- . »i.t. :...."T: . r,!i • .M..i '.'. , " !t.. t. (!*:. i...... 't.i. (f. '.-(H. (Hlifi

SO' ' 120 ' 160 ' 200 ' 240

mm .

l.

-

0

Cl,l' s3' ,1 ' '-Terphenyl 3-2 '-ol <9CI) Scan 291140.00246•--,

77 101 11123 139 165 168 189 £02 217

80 120 160 200 240

mm .

I.LCl,l':3',l"-Terphenyl]-4'-ol C9CI) Scan 29119

0 .00 min .246^

77 101 11123 139 165 169 139 202 217'

80 ' 120 ' 160 ' 200 ' 240I,r.

1. l,l'-Biphenyl, 2-phenoxy- (9CI) 246 C18H1402. Cl,I1:3' ,I1 '-Terphenyl]-2'-ol (9CI) 246 C18H1403. Cl,l ' :3' ,1' '-TerPhenyl]-4'-ol <9CI) 246 C18H1404. BicycloC3.1.0]hex-3-en-2-one, 6,6-dipheny1- C8CI9CI) 246 C18H1405. l,l'-Biphenyl, phenoxy- (9CI) 246 C18H140

Sample file : >B8538 Spectrum #: 2339Search speed: 1 Tilting option: S No. of ion ranges searched: 57


1. 95* 6738041 29120 "BIGDB 108 29 1 0 86 15 64 9'2. 76* 2432113 29114 "BIGDB 67 58 0 0 70 40 37 8u3. 58* 6093034 29119 "BIGDB 64 56 1 0 84 45 18 634. 47* 13304079 29121 "BIGDB 58 63 1 0 88 42 16 495. 35* 28984896 29133 "BIGDB 49 79 2 0 94 38 14 22

CORRECTED TOTAL ION AREA OF UNKNOWN - 186492 ,CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 732181CONCENTRATION OF INTERNAL STD = 40 ug/1 DILUTION FACTOR = 10SEMI QUANT ITATION OF UNKNOWN = 100 ug/1

91L-3551-7 Sample Data Package

AR2030I2

7

QUANT REPORT

Operator ID: MALOS .Quant Rev: 6 Quant Time: 911126 18:16Output File: ^C1618::D4 Injected at: 911126 17:30Data File: >C1618::D1 Dilution Factor: 2.00000Name: 911-3551-7Misc: 2.5ML/5ML

ID File: IDJJCC::QTTitle: HP UOA Standards for 5 Point Calibration Curve Rev. ELast Calibration: 911119 13:18

Compound R.T. Scan* Area Cone Units q

1) *Bromochloromethane 8.50 104 26302 50.00 ug/L 754) Uinyl Chloride 2.40 25 2945 9.95 ug/L 8814) Trans-l,2-Dichloroethene 10.12 125 4936 11.64 ug/L 9016) l,2-Dichloroethane-d4 11.43 142 51573 102.46 ug/L 9823) *l,4-Difluorobenzene 19.07 241 111261 50.00 ug/L 6729) Benzene 16.45 207 43683 37.86 ug/L 9233) *Chlorobenzene-d5 24.09 306 83814 50.00 ug/L 9639) Toluene-d8 22.85 290 136642 110.66 ug/L 8740) Chlorobenzene 24.24 308 497255 571.41 ug/L41) Ethylbenzene 26.10 332 1023 2.36 ug/L45) Bromofluorobenzene 28.41 362 87810 102.73 ug/L

* Compound is ISTD

AR2030I3

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Id File: ID_UCC::QTTitle: HP VOA Standards for 5 Point Calibration Curve Rev. ELast Calibration: 911119 13:18

Operator ID: MALOSQuant Time: 911126 18:16Injected at: 911126 17:30

8R2030U

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Compound No: 1 (ISTD)Compound Name: BromochloromethaneScan Number: 104Retention Time: 8.50 min.Quant Ion: 128.0Area: 26302Concentration:' 50.00 ug/Lq-value: 75

AR2030I5

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Data File: >C1618::D1 Quant Output File: 01618::04Name: 911-3551-7Misc: 2.5ML/5MLQuant Time: 911126 18:16 Quant ID File: ID_UCC::QTInjected at: 911126 17:30 Last Calibration: 911119 13:18

Compound No: 4Compound Name: Uinyl ChlorideScan Number: 29Retention Time: 2.40 min.Quant Ion: 62.0Area: 2945Concentration: 9.95 ug/Lq-value: 88

48203016

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SflMPLE SPECTRUM <UNflLTERED>File >C1618 911-3551-7 2.5ML^6ML Scan 125Bpk flb 1063. 10.12 min.

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Data File: >C1618::D1 Quant Output File: /SC1618::D4Name: 911-3551-7Misc: 2.5ML/5MLQuant Time: 911126 18:16 Quant ID File: ID_UCC::QTInjected at: 911126 17:30 Last Calibration: 911119 13:18

Compound No: 14Compound Name: Trans-1,2-DichloroetheneScan Number: 125Retention Time: 10.12 min.Quant Ion: 96.0Area: 4936Concentration: 11.64 ug/Lq-value: 90

AR2030I7

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Data File: >C1618::D1 Quant Output File: /XC1618::D4Name: 911-3551-7Misc: 2.5ML/5MLQuant Time: 911126 18:16 Quant ID File: ID_UCC::QTInjected at: 911126 17:30 Last Calibration: 911119 13:18

Compound No: 16Compound Name: 1,2-DichIoroethane-d4Scan Number: 142Retention Time: 11.43 min.Quant Ion: 65.0Area: 51573Concentration: 102.46 ug/Lq-value: 98

AR2030I8

REFERENCE STflNDflRD SPECTRUMFile >VXNSPBpk flb 100.

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SflMPLE SPECTRUM (BflCKSROUNO SUBTRflCTED>File >C1618 , 911-3551-7 2.5ML/5ML Scan 241Bpk Rb 9053. SUB10000-

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Data File: >C1618::D1 Quant Output File: /SC1618::D4Name: 911-3551-7Misc: 2.5ML/5MLQuant Time: 911126 18:16 Quant ID File: ID_UCC::QTInjected at: 911126 17:30 Last Calibration: 911119 13:18

Compound No: 23 (ISTD)Compound Name: 1,4-DifluorobenzeneScan Number: 241Retention Time: 19.07 min.Quant Ion: 114.0Area: 111261Concentration* 50.00 ug/Lq-value: 67

AR2030I9

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REFERENCE STflNDflRD SPECTRUMFile "BI6DB Benzene Scan 71432Bpk flb 100. CLP FLT NRM NOM 0.00 min.

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SflMPLE SPECTRUM <8flCK6ROUNO SUBTRflCTED)File >C1618Bpk flb 3530.

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78

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SflMPLE SPECTRUM <UNflLTEREO>File >C1618Bpk flb 3530.

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LData File: >C1618::D1 Quant Output File: 1618::D4Name: 911-3551-7Misc: 2.5ML/5MLQuant Time: 911126 18:16 Quant ID File: ID_UCC::QTInjected at: 911126 17:30 Last Calibration: 911119 13:18

Compound No: 29Compound Name: BenzeneScan Number: 207Retention Time: 16.45 min.Quant Ion: 78.0Area: 43683Concentration: 37.86 ug/Lq-value: 92

AR203020

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Compound No: 33 (ISTD)Compound Name: ChIorobenzene-d5Scan Number: 306Retention Time: 24.09 min.Quant Ion: 117.0Area: 83814Concentration: 50.00 ug/Lq-value: 96

RR2Q3021

o * oREFERENCE STflNDflRD SPECTRUMFilBpk

e >VXNSPflb 100.

100-

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42

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^Data File: >C1618::D1 Quant Output File: /SC1618::D4Name: 911-3551-7Misc: 2.5ML/5MLQuant Time: 911126 18:16 Quant ID File: ID_VCC::QTInjected at: 911126 17:30 Last Calibration: 911119 13:18

Compound No: 39Compound Name: Toluene-d8Scan Number: 290Retention Time: 22.85 min.Quant Ion: 98.0Area: 136642Concentration: 110.66 ug/Lq-value: 87

AR203022

i I

REFERENCE STBNDflRD SPECTRUMFile "BISDB Benzene, chloro- Scan 108907Bpk flb 100. CLP FLT NRM NOM 0.00 min.

112100-

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80 90 100 110

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SflMPLE SPECTRUM <BflCK8ROUND SUBTRflCTED)File >CBpk Rb

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Data File: >C1618::D1 Quant Output File: ~C,1618::D4Name: 911-3551-7Misc: 2.5ML/5MLQuant Time: 911126 18:16 Quant ID File: ID_UCC::QTInjected at: 911126 17:30 Last Calibration: 911119 13:18

Compound No: 41Compound Name: EthylbenzeneScan Number: 332Retention Time: 26.10 min.Quant Ion: 106.0Area: 1023Concentration: 2.36 ug/Lq-value: 86

SR203021*

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Data File: >C1618::D1 Quant Output File: /SC1618::D4Name: 911-3551-7Misc: 2.5ML/5MLQuant Time: 911126 18:16 Quant ID File: IDJJCC::QTInjected at: 911126 17:30 Last Calibration: 911119 13:18


AR203025


0SAMPLE NAME AND AMT: 911-3551-7 2.5ML/5MLSAMPLE DATA FILE: >C1618


4 16.45 207 113595 TC5 19.07 241 297673 IS6 22.85 290 • 394460 SS7 24.24 308 2128633 TC8 28.41 362 423702 SS9 33.51 428 27021 <10%10 34.97 447 88307 UK


- ^

AR203026

File >C

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AR203027

File >C1618 911-3551-7Bpk flb 461. SUB

1 75; 4_4 50 55 70 , 84 89

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Scan 44734.97 min.

146^ u.

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Sample file: >C1618 Spectrum #: 447

No data base entries were retrieved.

CORRECTED TOTAL ION AREA OF UNKNOWN = 88307CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 297673CONCENTRATION OF INTERNAL STD =50 ug/L DILUTION FACTOR =SEMI QUANTITATION OF UNKNOWN = 30 ug/L

flR203028

QUANT REPORT

aerator ID: MIKE Quant Rev: 6 Quant Time: 911127 21:00(tput File: AD7748::D2 Injected at: 911127 20:12ta File: >D7748::D3 Dilution Factor: 10.00000

Name:. 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)

ID File: ID_BAD::QTTitle: HP BNA Standards for 5 point Calibration Curve Rev. ELast Calibration: 911122 08:43

Compound R.T. Scan# Area Cone Units q

1) *d4-l,4-Dichlorobenzene 10.19 683 81680 40.00 UG/L 953) 2-Fluorophenol 6.86 363 5130 20.24 UG/L 945) Phenol-d6 9.64 630 8352 23.60 UG/L 956) Phenol 9.67 633 3476 10.15 UG/L 9218) *d8-Naphthalene 14.02 1051 329836 40.00 UG/L 9319) Nitrobenzene-d5 12.03 860 7960 21.28 UG/L 8529) 4-Chloroaniline 14.48 1095 133288 337.85 UG/L 9633) *dlO-Acenaphthene 19.51 1579 183023M 40.00 UG/L38) 2-FlUOrobiphenyl 17.56 1391 25928 42.95 UG/L 9454) *dlO-Phenanthrene 24.08 2018 299745 40.00 UG/L 9858) 2,4,6-Tribromophenol 22.06 1824 1172M 14.97 UG/L66) *d!2-Chrysene 32.40 2818 147817 40.00 UG/L 9169) Terphenyl-dl4 29.28 2518 17115 34.96 UG/L 9475) *d!2-Perylene 36.55 3217 73782 40.00 UG/L 95

_* Compound is ISTD

AR203029

TOTfiL ION CHROMfiTOGRflflFile >D7748 35.0-500.0 amu. 91L3551-7 1000/10ML E

TIC1000 2000 3000 4000

900000

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700000

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Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)

Id File: ID_BAD::QTTitle: HP BNA Standards for 5 point Calibration Curve Rev. ELast Calibration: 911122 08:43Operator ID: MIKEQuant Time: 911127 21:00Injected at: 911127 20:12

AR203030

,-x f • ——

REFERENCE STflNDflRO SPECTRUM ~File >B7941 d4-l ,4-Dichlorobenzene 910925 09:20 Scan 752Bpk flb 44024. SUB 10.89 min.

,40000-

0- I l l l

150

52 56 ft4 78 qo -1-?-5*9 ' / / ' B? \ f 122, . ...i.l. i.i. ...., ...il.l.. . i . N . ..I.i. / . ..

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SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7748 91L3551-7 1000/10ML EXT:11 Scan 683Bpk flb 45760. SUB 10.19 min.

150

40000-

0-

52 7g 115

.. " ...I/../ ,,.L .7. N1"..!, i

-100

-a40 60 80 100 120 140

SflMPLE SPECTRUM (UNOLTERED)File >D7748 91L3551-7 1000/10ML EXT:11 Scan 683Bpk flb 45760. 10.19 min.

150•i

40000-

0-

52 7S 115-aa / 56 64 . __ 99 108 '3- \ / s \ 87 v \..,<. ...,.L<r..,,.< ...i.l.. .f. > N .. .1.

f

ii.

.•1 dCk

•a1 ' 1 ' ' ' • 1 ' ' ' • 1 • ' • ' 1 • • ' ' 1 ' ' ' ' 1 ' ' • • 1 ' ' • • 1 • ' ' ' 1 • • • • 1 ' ' • • 1 • ' • ' 1 • ' -40 60 80 100 120 140

Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 21:00 Quant ID File: ID_BAD::QTInjected at: 911127 20:12 Last Calibration: 911122 08:43Compound No: 1 (ISTD)Compound Name: d4-1,4-DichlorobenzeneScan Number: 683Retention Time: 10.19 min.Quant Ion: 152.0Area: 81680Concentration: 40.00 UG/Lq-value: 95

flR20303l

REFERENCE STRNDflRD SPECTRUMFile >BBpk flb

40000-

0-

7941 2-Fluorophenol46568. SUI

64

38 45 50 / 68

1 1 1 1 1 M 1 1 M 1 1 1 1 1 1 1 r 1 1 1 1 1 1 1 1 1 |h^|li40 50 60 70

910925 09:20 Sea3 7.50

1

y 83^ ™

l l | l l l l | I I l | l l l l | l l l | l l l l | I I I I | I M l | l80 90 100 110

nn

12/

-h

426un .

-100

-0

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7748 91L3551-7Bpk flb 1301.

£.A

1000

0-

'r J(, \ \\,40 50 60

1000X10MLSUB


112•

' 100

83 92

170 80 90

!,.,,,.. | .... | I I I . | 1 '. 1 -0

100 110

SflMPLE SPECTRUM <UNflLTEREO)File >D7748 91L3551-7 1000/10ML EXTsll Scan 363Bpk flb 1301. 6.86 min.

112

100040 f

/? I 8 /2

/

40 ' 50 ' 60 '70 ' 80 ' 90 ' 100 ' 110

-100

-0

Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 21:00 Quant ID File: ID_BAD::QTInjected at: 911127 20:12 Last Calibration: 911122 08:43Compound No: 3Compound Name: 2-FluorophenolScan Number: 363Retention Time: 6.86 min.Quant Ion: 112.0Area: 5130Concentration: 20.24 UG/Lq-value: 94

AR203032


40000-

40/ r0- )' 1 1 /• N

40

Phenol-d6SUB

42 71 7^ 49 54 58 66 - . </ / f "*""""•*. 1 S

h i , 1 1 ,'i tii \ i M J 1 1 1 1 1 1 /Ji i III \ 1 150 60 70

910925 09:20 Scan 69210.26 min.

99

2 81 82 94

' Yf7 ', .'

' -100•(

-L. .a80 90 100

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7748 91L3551-7 1000/10MLBpk flb 2565. SUB

.

2000-

-

0-

40 42 7/ *~~ 52 66 1

i 1 1 i, r^ "^ ii 140 50 60 70

EXTsll Scan 6309 .64 min .

99*

94i

h!00(

•

-a80 90 100

SflMPLE SPECTRUM CUNflLTERED)File >D7748 91L3551-7 1000/10ML EXT:11 Scan 630Bpk flb 2565.

.

2000--

0-

40 42 7 L/ *** 52 66 ^

, hln r" > ii40 ' s'0 ' 60 ' 70

9.64 min.99f

94{

(-100••-0

80 90 100

Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 21:00 Quant ID File: ID_BAD::QTInjected at: 911127 20:12 Last Calibration: 911122 08:43Compound No: 5Compound Name: Phenol-d6Scan Number: 630Retention Time: 9.64 min.Quant Ion: 99.0Area: 8352Concentration: 23.60 UG/Lq-value: 95

AR203033


e >B7941flb 58848.

-40000-

a-

39^ 40

. . i l l . .40

Phenol

4,3 47 50/ / /l l l l 1 i i'l 1 l 145 50

5?*-h-h-n-i55

62\

60

SUB

65 66

11 71 ; ) 1 ni ft .65 70

910925 09:20 Scan 69610.31 min.94

74 79 92

r

9$i . f

-100

,

1 1 | 1 I1 1 1 | 1 1 1 1 | 1 1 1 1 | 1 M rrr. , -75 80 85 90 95

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7748 91L3551-7 1000/10ML EXT:11 Scan 633Bpk flb 999

1000H•

0-

39>v

11

SUB 9.67 min.94'

40 44 °f . 'hi I

^ 71/1

1-100

L040 45 50 55 60 65 70 75 80 85 90 95

SflMPLE SPECTRUM <UNflLTERED>File >D7748 91L3551-7 1000/10ML EXT:11 Scan 633Bpk flb 1079.

1000-

0-

40

9.67 min.94'

39 / AA 6S6.6 7.1^ 1 /1 1 1 l 1 1 149 45 50 55 60 65

^ f

-100

•

•a70 75 80 85 90 95

Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 21:00 Quant ID File: ID_BAD::QTInjected at: 911127 20:12 Last Calibration: 911122 08:43Compound No: 6Compound Name: PhenolScan Number: 633Retention Time: 9.67 min.Quant Ion: 94.0Area: 3476Concentration: 10.15 UG/Lq-value: 92.

AR20303ii


50000-42

al f

40

d8-Naphthalene

5\J4 ^

60

L(\

SUB

82 88

I'l'H • M80

910925 09:20

106 iao94 x 08i t M ^ I I I i | i i i i | i i

100 120

Scan 112014.72 min.

136' -100

128 ;.... i . 1 1 1 . _n


100000-

i 42 52

40

J54 68

60

1000/10MLSUB

76 78 90 106\/ \ r \80 100

EXT:11 Scan 105114.02 min.

136' -100

i08 118 ±3* :1. f >...!, I..0' 120

SflMPLE SPECTRUM CUNOLTERED)File >D7748 91L3551-7Bpk flb 121280.

100000-

.42 52 54 68 7,

• i • • • • i • • • • i • • • • i •40 66

1000/10ML

6 78

s'e

90\

106r \100

EXT:11 Scan 105114.02 min.

136^

y* us 13i. / N...I,' ' ' ' • 120 '

l.

[-100

-a

Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 21:00 Quant ID File: ID_BAD::QTInjected at: 911127 20:12 Last Calibration: 911122 08:43

Compound No: 18 (ISTD)Compound Name: dS-NaphthaleneScan Number: 1051Retention Time: 14.02 min.Quant Ion: 136.0Area: 329836Concentration: 40.00 UG/Lq-value: 93

O

flR203035

°- L>REFERENCE STflNDflRD SPECTRUMFile >B7941 Ni trobenzene-d5 910925 09:20 Scan 923Bpk flb 40856.

40000-

- 42 5!. .1 I . . . . i .40

SUB 12.67 min.82

54

66 70 77

I ' l l 1 1 I'l I'l1' I'l'l I1 ... | ... l | . TT-r T-T-i-r . | . . r , -

x-"

12!

9\ 98 112\ ... S ,. .

tj-100

.

60 80 100 120

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >DBpk flb

1000-

0

7748 91L3551-7 1001663. SUB

5442 52 '

l( ^1

0/10ML EXT:11 Sea12.03

82^

198(

40 60 80 100 120

nIT

2«/

860tin.

-100

-0

SflMPLE SPECTRUM <UNflLTERED>File >D7748 91L3551-7 1000/10ML EXT:11 Scan 860Bpk flb 1663. 12.03 min.

82

1000

f

42 52. \ \40 '

54/ 1

98i l

60 ' 8*0 ' 100 ' 120

2£-100

-0

Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 21:00 Quant ID File: ID_BAD::QTInjected at: 911127 20:12 Last Calibration: 911122 08:43Compound No: 19Compound Name: Nitrobenzene-d5Scan Number: 860Retention Time: 12.03 min.Quant Ion: 82.0Area: 7960Concentration: 21.28 UG/Lq-value: 85

RR20303

REFERENCE STflNOflRD SPECTRUMFile >B7941Bpk flb 50520.

.40000-

- 39

0-|'l'|'l i'1-'!40

4-Chloroani 1 ine

6552 ^ 73 .6

'I'l'l i i I'l'lU i-l'l'H i | i ''60 80

910SSUB

1

/8 T 11*......i. ..ii.i. ./ .100 120

>25 09:20

27f

ill ,140

Scan 116015.13 min.

[-100

162 ;-0

160

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7748Bpk flb 41973

40000-

- 39g..ill,i .

40

91L3551-7.

6552 ^ 73

...in.. .iillli, ,i.60

1000/10ML EXTrll Scan 1095SUB 14.48 min.

127

;6 »,* «• lie,.<: ......,il. .ii.. L

^130

\\i***

-100'

•L0

80 ' 100 ' 120 ' 140 ' 160

SflMPLE SPECTRUM <UNflLTERED)File >D7748Bpk flb 42312

40000-

- 39

0- j '}!}.!,,/40

91L3551-7,

6552 j 73 76

...n'. ..iiili. .i T .... i .... i .... i .... i ...60 80

1000/10ML

o<&92 i 00/ , 110

.....L .il.. t..100 120

EXT:11

127^

138

\f "•'••-140"

Scan 109514 .48 min .

hl00

•.a

160

Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 21:00 Quant ID File: ID_BAD::QTInjected at: 911127 20:12 Last Calibration: 911122 08:43Compound No: 29Compound Name: 4-ChloroanilineScan Number: 1095Retention Time: 14.48 min.Quant Ion: 127.0Area: 133288Concentration: 337.85 UG/Lq-value: 96

AR203037

REFERENCE STflNDflRD SPECTRUMFile >B7941 d!0-flcenaph thene 910925 09:20 Scan 1651Bpk flb 44088. SUB 20.24 mm.

16440000-

-

0J

42 54 66/ / ^T: Xi'1'Ji 1 1 i'1'l'i i ! Mi'l l f iM i-i'i

f 92 1^f ^8 122 132 138 x'1 1 1 1 ("I'l i i H 1 1 1 f i i i i 1 i 1 i i i I'l'J'l'l'i i i 1 i i I'l'l1

1i j I

^

|1 ' 1*

-100

•

L040 60 80 100 120 140 160


_

4000042 54 66 7

1000/10ML EXT:11 Scan 1579SUB 19.51 min.

" 98 10 08 122 132 14 156

162/

1 1.

-100

-a40 ' 60 ' 80 ' 100 ' 120 ' 140 ' 160

SflMPLE SPECTRUM (UNflLTERED)File >D7748 91L3551-7 1000/10ML EXT:11 Scan 1579Bpk flb 66920. 19.51 min.

162_

40000 42 54 66 76 ** 90 106 108 146...(.. .,.(... i...\J.,.../... ...\/ . / ./,.. N .l.l,

I

\ 1.

-100

-ft

40 ' 60 ' 80 ' 100 ' 120 ' 140 ' 160


Compound No: 33 (ISTD)Compound Name: dlO-AcenaphtheneScan Number: 1579Retention Time: 19.51 min.Quant Ion: 164.0Area: 183023MConcentration: 40.00 UG/L

AR203038

REFERENCE STflNOflRD SPECTRUMFile >B7941Bpk flb 93144

100000-

• 39

0- i |i i i i40

2-Fluorobipheny 1i

51 63|'l i i'1'l'l'l'i I'

60

76 85/ /

[•I'l'l'l I'l'i 'I't'i80

SUB

94I'VI I'l'l i100

910925 09:20

120107 v 125•I'l'l'.'.-! I'l'l'. 'IV,

120

133X /

•I'l M'I . I'hfl'l140

Scan 145918.24 min.

172^

157 ,* 1 1

-100

rtl'l|.l 1 I'l'l1 1-0

160


10000-

"

0-" .,. ,,

39

t

40

91L3551-7

50/

631

60

1000/10MLSUB

76 85 9Ittti > i lit ii

80 100

^ 125\ /

I 1 1

120

EXT :11 Scan 139117

/ 146 157S t t, i140

,i . '160

.56 min.172

J-100

•

-0

SflMPLE SPECTRUM (UNflLTERED)File >07748 91L3551-7Bpk flb 9485.

10000-

; 39 50

40 ' 68 '

1000/10ML

76 85 ^ 125

89 100 120

EXTrll Scan 139117.56 min.

172> -100

>33 146 187 :/ .r,,, f Jlii*140 160


Compound No: 38Compound Name: 2-FluorobiphenylScan Number: 1391Retention Time: 17.56 min.Quant Ion: 172.0Area: 25928Concentration: 42.95 UG/Lq-value: 94

flR203039


50000-

_42

40

d!0-Phenanthrene 910925 09:20 ScSUB

^ 66, ,f

60

80

•m- 1 1 i'i'f80

94 100/ /

1 1 1 . \\ 1 1 1100

118 132\ \

|l I' l l " ' i | l120

136 x•Mi| \ \ t \ I'll'140

160

K rn-160

24.

178*x.

an 209182 min .188/

.In l

KL00

•*

180

SflMPLE SPECTRUM CBflCKGROUND SUBTRflCTED)FileBpk

>D7748 91L3551-7flb 100496.

100000-

42

40

52/

60

66..I . .

1000/10MLSUB

80 94 100 118 132/ / / \ V

. l i m l - l l l . . p.m. .i.i, imp80 100 120

EXT

156 1A,136 \™..'. ... ....i.l.140 160

:11 Scan 201824

3 180

1£

.08 min .188

..l.il

f

1..

-100

-a

SflMPLE SPECTRUM <UNflLTERED>File >D7748 91L3551-7Bpk flb 100496

100000-

0-1,. ...,.42

40

•

f 6/6

60

86

4™80

1000X10ML

94 100

108

118\

132

120

EXT:

156136 X

140

168/

160

11 Scan 201824.08 min.

188

180

. N..u

/

L.

-100

-a180

Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 21:00 Quant ID File: ID_BAD::QTInjected at: 911127 20:12 Last Calibration: 911122 08:43Compound No: 54 (ISTD)Compound Name: dlO-PhenanthreneScan Number: 2018Retention Time: 24.08 min.Quant Ion: 188.0Area: 299745Concentration: 40.00 UG/Lq-value: 98

AR2030i*Q


50080-: 52

/40

d!2-ChryseneSUB

~ " 106 120 I26 154 170>6 \ -^ / \ \

80 120 160

910925

182 '• T"' '''* "I"'1

200

09:20 Scan 289533 .18 min .

240""- -100

212 J-41 :,i,riV, .,,,.,,...,11., ,Jil,'-0

240


•40000-

- 54\

40

91L3551-7

66 "/ Xj, /j

80

1000/10MLSUB

120 156 170\ 132 v^ >....ji . y. . X .S120 160

180 /Af /

EXT:

^ 212

200 ^

11 Scan 281832 .40 min .

240"""••x.

241

-1 CtCt

-ct240

SflMPLE SPECTRUM <UNflLTERED>File >D7748 91L3551-7Bpk flb 46216.

40000-- 54 90 196

\ >sv. - -

40 ' 80

1000/10ML

12 132 15 1?x0 180...j| . y. . >>. .S /..120 160

EXT:11 Scan 281832.40 min.

240" -100

V94 212 Lt41 :/ ..J. . ..Jl 10200 240

Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 21:00 Quant ID File: ID_BAD::QTInjected at: 911127 20:12 Last Calibration: 911122 08:43Compound No: 66 (ISTD)Compound Name: d!2-ChryseneScan Number: 2818Retention Time: 32.40 min.Quant Ion: 240.0Area: 147817Concentration: 40.00 UG/Lq-value: 91

HR2030M

REFERENCE STflNDRRD SPECTRUMFile >B7941Bpk flb 110832

100000-

0Jn-r~n

54\

40

Terphenyl-dl4.

66 80

80

SUB

'/ /' "*/*120

910925 09:20

198 £12160 174 x V

160 200

Scan 259130.02 min.

244^

226

-100

-0240

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7748Bpk flb 4954.

.4000-

• 54- \

40

91L3551-7

66 80 92/ / /. i. , .

' ' • -8'0' ' ' '

1000/10MLSUB

106 \. ,•r j r120

160 174/ /.1 r160

EXTrll

212i.

200

Scan 251829.28 min.

244" i 1-100•

226

•• • •"lll'!'-0240

SflMPLE SPECTRUM <UNRLTERED>File >07748Bpk flb 4954.

4000-' 54

»A40

91L3551-7

66 80 92. i. . .

80 '

1000X10ML

186 «8^36 160 174i. J i <i !

120 160

EXT 811

212i,

200

Scan 251829.28 min.

244" 1-100•

226/,...,'-<|1' .-0

240

Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 21:00 Quant ID File: ID_BAD::QTInjected at: 911127 20:12 Last Calibration: 911122 08:43Compound No: 69Compound Name: Terphenyl-dl4Scan Number: 2518Retention Time: 29.28 min.Quant Ion: 244.0Area: 17115Concentration: 34.96 UG/Lq-value: 94

AR2030if2

REFERENCE STflNOflRD SPECTRUMFile >B7941Bpk flb 72040,

80000-

40000-'

42

40

d!2-PeryleneSUB

90 H H o 13266 \ 104 H8 / 156./ .. \ ./ / ,jl /

80 ' 120 ' 160

910925

180X 204

200

09:20 Scan 329337 .32 min .

264^

228 232. \ X iI

-100

•

-ct' 240

SflMPLE SPECTRUM (BflCKGROUND SUBTRflCTED)File >D7748 91L3551-7Bpk flb 18720.

20000-

: 66 76y S ...

40 80

1000/10MLSUB

132102 118 / 156.L ..n ...ill f

120 160

EXT:11 Scan 321736 .55 min .

264"- -100

y9 888858 /* '•S /NX ..!..:«200 ' 240


20000-

" 66 J6 102» —— f.f{.-r,fi40 80

1000X10ML

132118 /nil ...Jl

120

156

160

EXT:11 Scan 321736.55 min.

264^ -100

180 228 232,-<. . , r. ,\< . , ,f,i.200 240

Data File: >D7748::D3 Quant Output File: AD7748::D2Name: 91L3551-7Misc: 1000/10ML EXT:11/22/91 (RS0377)Quant Time: 911127 21:00 Quant ID File: ID_BAD::QTInjected at: 911127 20:12 Last Calibration: 911122 08:43Compound No: 75 (ISTD)Compound Name: d!2-PeryleneScan Number: 3217Retention Time: 36.55 min.Quant Ion: 264.0Area: 73782Concentration: 40.00 UG/Lq-value: 95

AR2030U3


SAMPLE NAME AND AMT: 91L3551-7 1000/10MLSAMPLE DATA FILE: >D7748

PEAK NO. RET. TIME SCAN AREA IDENTIFICATION1 5.81 262 302350 UK2 10.19 683 5298-20 IS

3 12.94 947 465524 14.02 1051 729968 IS5 14.48 1095 536654 TC

6 17.56 1391 65267 SS7 18.22 1455 3179121 UK8 19.51 1579 848791 IS

24.08 2018 801289 IS

10 29.28 2518 34659 SS11 32.40 2818 455298 IS

12 34.52 3022 35218 UK13 35.80 3145 43312 UK14 36.55 3217 216112 IS15 37.00 3260 38874 UK

IS - INTERNAL STANDARDSS - SURROGATETC ^ TARGET COMPOUNDUK = UNKNOWN

= UNKNOWN LESS THEN 10X OF INTERNAL STANDARD

AR2Q301+U

File >0

900000

fe :r i700000-

600000-

500000

400000

300000-

200000-

1QOOQQ-

Q-

7748 35.0-500.0 amu. 91L3551-7 1000./10ML Lx'f:'TIC

1000 £000 3000 4000. . , . i . . . . i . . . . i . . . . i . . . . i . . . . i . . . . t . . . , i ,

1

4 8

7

4

3

5

6

L

39

11

1014

121315i i Ji i i

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780

:70

;60

-60

;40

:30

ii.* 1 ' 1 ' 1 ' 1 ' I ' 1 - ' I * I ' I ' t ' 1 ' 1 " J ' I ' ! ' 1 '12 16 20 24 28 32 36 40 44

flR2030i»5

Fil« /O"Bpk flb S

jFile >BBpk fib '

7743 91L3551-7 1000/1^1563. SUB

38 47 / 56 61/ -^ i ' *•"

i l I ' l u M i ' l i i l l ' M i i l i . l i l l n i . n l M M |40 50 60 70

Ot1L EXT:ll/22x Sea5.3111

7? /

86 97

80 90 100 110

[SOB Benzene, chloro- <8CI9CI> Scan3999. 0.00

1177

'38 48 ^ 56 61 72 ' . 34 35 • 97 108

40 ' 50 ' 'SO ' " ' 70 SO 90 100 110

ri 262ra i n .

I10883min.2

J-:o

u - J

1. Benzene, chloro- C8CI9CI) 112 C6H5C1

Sample file: >D7748 Spectrum #: 262Search speed: 1 Tilting option: S No. of ion ranges searched: 55

Prob. CAS # CON * ROOT K DK #FL6 TILT % CON C_I R_IU

1. 95* 108907 10883 "BIGDB 89 5 1 4 72 1 72 93

CORRECTED TOTAL ION AREA OF UNKNOWN - 302350CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 529820CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR - 10SEMI QUANT I TAT ION OF UNKNOWN = 230UG/L

ftR2030i*6

File >07748 91L3551-7 1000--10t1L EXT:ll/22/ Scar, 1455Bpk fib 164161. SUB

, ?q 51 7? ^ , J>U•j .-

toltW«File >BI6DBBpk fib 9999.

65 '< , 35 94 102 128 139 1. . . . . . ' ,. , ... , ' /. ... L .'. . . 1 . ~-. , >i II,

6.0 80 100 120 140

.Benzene, l,l'-oxvbis- ';9CI)

1 ,Q 51 77 141j Ji* / 5 ~ - 85 94 102 115 129 139 ,--"

r J T .40 '

'File >BISDBBok flb 9999.

-j5

C- ,. , , , r, ''

40

File >B I SOBBok Bb 9999.

j

, / -•' / / i '•--. '-- I),SO ' 80 ' 100 ' 120 ' 140

duinaldoni tri le , 3-hydroxy- <.'8CI>

115 1420 64 70 88 39 / -^

lit 1 . 1 . .in. 1 i 1.60 80 100 120 - 140

IH-Indene, 1-e thy 1 idene- (9CI)141

115| 39 50 63 71 37 89 ( 13_9

i-J f* :'40

,! . ..1 .. > r~ .1 i. r —60 80 100 120 140

18.22 min.170

"""• j-155 ft / I | Ln160

Scan 202960 .00 mm.

"-. .

154 E..;''. ,1 I Ln

160

Scan 203120.00 min.170" u[

i Ln160

Scan 160960 .00 min .

h-i-43 F

Ln160

1. Benzene, l,l'-oxybis- (9CI) 170 C12H1002. Quinaldonitri le, 3-hydroxy- (8CI) 170 C10H6N203. IH-Indene, 1-ethy 1idene- (9CI) 142 C11H104. lH,3H-NaphthoCl,8-cd]pyran (8CI9CI) 170 C12H1005. Cl,l'-Biphenyl]-3-ol (9CI) 170 C12H100

Sample file: >D7748 Spectrum tt: 1455-Search speed: 1 Tilting option: S No. of ion ranges searched: 56


1. 74* 101848 20296 "BIGDB 70 36 2 1 83 12 39 432. 25* 15462438 20312 "BIGDB 25 87 3 0 70 42 Q 133. 21* 2471832 16096 "BIGDB 50 35 2 0 46 58 5 314. 20* 203849 15988 "BIGDB 39 69 2 0 50 55 5 145. 18* 580518 20298 "BIGDB 39 51 1 0 71 56 4 22

CORRECTED TOTAL ION AREA OF UNKNOWN - 3179121 __ -CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 848791flR 2 0 3 0 4 7CONCENTRATION OF INTERNAL STD = 40UG/L DILUTION FACTOR = 10SEMI QUANT I TAT I ON OF UNKNOWN - 1500UG/L

Fila ,>D7748 91L3551-7Bpk fib 6120.

•3 "1J. , , ,M:e°147

[•' 'l20 ' 150

1000/lOML EXT:ll/22/ Scan 3022SUB

£lf 222 267 £81 355.1 r- :•• r~: . (200 24Q gsn ''SO ''ftQ

34.52 mm.

,..,!-400

Sample file: >D7748 Spectrum #: 3022


CORRECTED TOTAL ION AREA OF UNKNOWN - 35218CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 216112CONCENTRATION OF INTERNAL STD = 40UG/L DILUTION FACTOR * 10SEMI QUANT I TAT I ON OF UNKNOWN =• 65UG/L

ftR2030U8

File >07748 91L3551-7 lOOQ/lOML EXT:ll/2£/ Scan 3145Bpk fib 6S70. SUB 35.80 min.

-

^ 0-

147 • ' f,' "i i81 295 355 f.1. ,. 1. ' (. r'". '~-±n

H SO 120 160 20C1 240 280 320



CORRECTED TOTAL ION AREA OF UNKNOWN = 43312CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 216112CONCENTRATION OF INTERNAL STD =• 40UG/L DILUTION FACTOR = 10SEMI QUANT I TAT ION OF UNKNOWN = 80UG/L

File >D7748 91L3551-7 1000/lOML EXTsll/22/ Scan 3260Bpk flb 5826. SUB 37.00 min.

j; 133 ' 191 °^_ 367 £'f1 295 355~ i * • • . • • ' i • • ' i ' • • i • • * i • ' 1 1 ' • • i ' • • . > ' ' i • * » i ' ' ' i • ' • i ' * • i * * •SO 120 160 200 240 280 320

-0

File '.BI6DB Cvc lopropanamine . N-ms thy 1 -1-phenvl - <9CI> Scan 16819Bpk flfa 9999. ' ' 0.00 min.

147

77 105

rJ<W- , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , ,I32 150' _^— —

SO . 1,20 160 200 240 230 320-C

1. Cyclopropanamine, N-methy1-1-pheny1- C9CI) 147 C10H13N



1. 11* 56771483 16819 "BIGDB 23 58 3 0 48 65 2 12

CORRECTED TOTAL ION AREA OF UNKNOWN - 38874CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 216112CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR - 10SEMI QUANT ITAT ION OF UNKNOWN - 72UG/L

AR203050

Xv. (J


SR2Q305I

UUAN I KtHUK I

LJoerator ID: HRLUb LJuant Kev: 6 Uuant lime: V1112/ 1)4:26Uutput h i l e : /NU16W: : UA Injected at: V1112/ U.V.4ULJat-a H i l e : >L16'2y::u^ U i l u t i o n r a c t o r : l . U U U U UName: V1L- _?•?•? 1-8

1 u r i I e : 1 UJJCC : : U I'. \ t 1 e : MH UUA Standards for •? Hoint Lalibration Curve Kev. tLast Calibration: V1111V l^:ib

Compound K.I. Scan* Area Cone Units

1) *Bromochloromethane U.t/ IU1? y^^Û Û.UU ug/L 's*4) Umyl Chloride 2 . 4U 21? B'?6a 14. 6/ ug/L VV

14) i rans-l,2-Uichloroethene 1U.11 121? l'?U4Uy IHV.^4 ug/L VII1?) Chloroform lU./.> 13^ 4"? ^ 2.66 ug/L W16) 1 ,2-Uichloroethane-d4 11. It 141 b/141 'y/.b^ ug/L V/2. ) *1 ,4-LUf luorobenzene IV. U/ 241 12.J/V6 t>U.UU ug/L 6b26) I richloroethene l^.Vb 2U1 3B41?! >/.3/ ug/L V22V) tlenzene 16.44 2U/ IB/1? 2 /.û ug/L VU5^) *Uh lorobenzene-d1? 24.0V Û6 bV5*>6 bU.UU ug/L.) letrachloroethene 21. // 2/6 bV/3V /«?.41 ug/L

.'V) 'oluene-dd 22 . U^? '2VU 144>6 ? ^>4.8^ ug/L4u ) Uh lorobenzene 24.24 3UU 2UVU44 Ibb . /B ug/L V241? .) Bromof luorobenzene 2B.41 ^62 V4UU.J bl.^>B ug/L BV

* Compound is IblU

AR203052

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Data r i l e : > C162V : : LJ2 Ujuant Uutput rile: /"C162V::U4Name:Hisc:

1 d I- i 1 e : 1 U_UUU : : U 1i i t l e : HH UUA Standards for ^ Point Calibration Curve Kev. LLast Calibration: VllllV 1^ : IB

Uperator 1U: HALUSUluant lime: V1112/ U4:'26Injected at: V1112/ 0 :4U

AR203053

i MtioHnu or cy_ i r*.u11>VXN5r HP VUH Ho Spike Internal Standards and 5u Scan

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I 70 01 931 4.4 I, 64 y^1 /rJ__Il_lLL! ______ L ______ I.I ..I.I L0

40 ft'O ' fl'O ' tOO ' 1PO

SOMPI F sprnrpiiMri 1 • M-1 APC O1 I —OKHl _O KMI ^r an 105 'Bok Rb 5859. • fillR 8.57 Min.' 49

-\ { M 00/jonnJ

1 *°nJt f*

40

1 13*j 6- fi 79 91 93 116 / t

. . itiii t . f I*!* itiii ^ . i t i t t60 80 100 120

-0

SflMPLE SPECTRUM CUNflLTEREO)Fil« >C1629 91L-3551-8 "' ~~ 5HL ~ Sc*n 105 1Bpk flb 5859. 8.57 Min.

-

4C

JXi .'.to

4?

13<£o ,1 79 81 93 116 /

1 . 71 / "~ ' \ II...;;.! f. f ;.rr ..!.! \ .!.!.'. . ! , ... . _,_. . . . , ... •_;_'•• -i • • • •.!.;•• • i • • r •. i, ; • • • i 'eu au luu xeu

-1001

-0

Uata rile: >C16'2V::U^ Uuant Uutput I- lie: "•C161^V::U4Name:

Uluant Time: V1112/' 04:26 Uuant ID File: 1U_VCC::U|IInjected at: V1112/ U^:4U Last Calibration: Vllliy 13: IB

Compound No: 1 IIS'IU)Compound Name: bromoch loromethanebean Number: lUbKetention lime: B.1?/ mm.Uuant Ion: 12H.UArea: 2-?V^UConcentration: ^U.OU ug/Lq-va lue : "?y

o i iinunrui F i i « /H0078 Vinyi Chloride SSiic? 10:00 Scan 66I * ™ •I

I

.. »L. * <-/ W HI -.

cGOC-j-j

iv!__

A . 47r / O/4| 69 81 \' 119.!. ( . ( \ I

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;onpi r RprnTuiiM (•Rori^RRniiNn siiRTPorTFn1)

ouu-

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3 f MOO

A* 48 I 164 fr / \\ \ Ii CM-, , i', 11,',, .•HIM ,, i,,,.,,,,. i,,,.,.,.,,.,,. i.,,, i . . . . , , , , . , , , . . , , y-<*I 40 60 90 100 130 140 160|_____________________________________________________,______SflMPLE SPECTRUM <UNflLTERED>Fil« >C16£9 " ~ 91L-3551-8 5ML " Sc*n 25Bpk flb 1056. 2.40 Min.

1000-1 \ -1001 IMl4.* I Xb4J I ,l / ..II X

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\ I I ^ ^1 ' ' ' • I ' ' • • I • ' ' • J ' • • • I ' * ' ' L' ' ' " I ' ' ' " I ' ' I ' * ' 1 ! ' '40 60 SO ivO icO 140 160

Uata t-ile: >L,16•-!v : : U2 Uuant Uutput rile: 'XC162V::U4Name:Hisc:Uuant lime: V1112/ U4:26 Uuant ID rile: 1 U__VUL: : UIinjected at: V1112/ U^:4U Last Calibration: V1111V 13:IB

Compound No: 4Compound Name: Umyi ChlorideScan Number: 21?Ketention lime: 2.4U mm.Uuant Ion: 62.0area: B*?6BConcentration: 14.6/ ug/Lq-value: VV

AR203055

REFERENCC oiHi-iur-mD orm-tixunr i i « .'H06i'o HSL CHU -CHK . voOuq'L^Oj' i4'39 13:30r™i _ i. i"« i.ui_- r- nu

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SfiMPI F SPFrTRIIM CRflr^fiRnilNfl SIIRTRflrTFmFii* 'C1629 91L-3551-2 5t1L

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37 _„ °/ 72j/ ""* 1 i sv yr . n • • • . . . . i i i i i i , m i . i i i i i i , i , . ; , r . - , , . , , , , . , ,40 50 60 70 80

Scar? 12510.11 Min.

oc M 00*•£___ qfl (•/ ri i

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SRMPLE SPECTRUM <UNflLTERED>Film >C1629 91L-3551-8 5HLBpk Rb

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40 50 60 70 30

ScAn 12510.11 Min.

96 -100-- 98 '

1 . :.50 100

Uata I-lie: >C162V::U2 Uuant Uutput rile: ~C162V'.:U4Name:Hisc:Uuant Time: V1112/ 04:26 Uuant 1U rile: 1 L^VCC::UIInjected at: V1112/ U^:4U Last Calibration: V1111V 1^:1

Compound No: 14Compound Name: Irans—1,2-UichloroetheneScan Number: 121?Retention lime: 10.11 mm.Uuant ion: V6.0ttrea: I'jBAOyConcentration: 1BV._>4 ug/Lq-value: VI

AR203056

'* A JLRcr"£RcN'CE STfiNufiRu or cCTRuflFiia "BI6D5 Chloroformu< p *. n w J s s

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SCMPI F SPFflTPIIM (Rflrk'fiPnilNn ftllRTPQrTFmFi'ls Cl££? O1L~3551— 2 5MLBpii~flb~367

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1SflMPLE SPECTRUM <UNflLTERED)File >C1629 91L-3551-8 5«LBpk flb 1052.

Scan 13310.73 Min.

40looo-i r""*

11

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3347 61 --. °5 ^ **

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Data rile: >C162V::U2 Uuant Uutput rile: 'NC162V::U4Name:nisc:Uuant lime: V1112/ 04:26 Uuant 1U File: 1U_UCC::UIInjected at: V1112"/ U>:40 Last Calibration: V1111V 13:

Compound No: lt>Compound Name: ChloroformScan Number: 1»Ketent ion lime: 10./> mm.Uuant Ion: B3.0Area: t&HConcentration: 2.66 ug/Lq-value: VV

AR203057

o t m*uttff.u or e.i_, i n.u11« Fi lm >VXN5P HP VOfl No 5pi ke Internal Standards and Su Scan 33c tI n », i , r~i v •* i™i <-> * ~it_tpr\ni-'j.*i/v

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SfiMPI F SPFHTPIIMF-,l« C1629Bpk Bb 4346.

tvuu-

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5147 >\ 1 ,-

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91L-3551-S 5KLRIIR

65/

53 go. . ( , i J?, i . i60 70 80

Scan 14111.35 Min.

MOO

100 102 f\ f. \"•• • i i i -M?

90 100

SflMPLE SPECTRUM CUNflLTERED)|Fil« >C1629 " 91L-3551-Q " 5ML ~ " Scan 1411 Bpk flb 4346. 11.35 Min.11 400O-11 J

j 45! 1 / 441 .1 1 /I i 1 1 jj i ..,.,.| HWi

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i

Data t - i l e : >C162V::U2 Uuant Uutput rile: ^C162V::U4Name: VlL-.J'^l-BHisc: ^HLUuant lime: V1112/ 04:26 Uuant 1U rile: lU_VCL:::urInjected at: V1112/ 0 :40 Last Calibration: V1111V 1_>:1B

Compound No: 16Compound Name: 1,2-UichIoroethane-d4Scan Number: 141Ketention lime: 11. !? mm.Uuant Ion: 6b.UHrea: /14'iConcentration: 'y/.'yj ug/Lq-value: V/

AR20305

STfiN'OfiRB SPECTRUMFiia >VXNSF h'P VUH No

J. VS "lJ^ 44 A31 \ °,U /

<-J ,_, , ml' ,-'! "I- j

40 AO

SflMPI F SPFr.TPIIM (RRr.KRF' le X--C1629Bok flb 9847.

10000H

1 38 RO ^J•I / / I

nJ-'M ,, (t . ..1, .nli i40 60

Spika Internal Standards and Suci_r NRM114

17R oo QO 1

,, .>, f. 1 .„ / ..\f~~~SO 100 i?0 140

pniiNn siiRTRflrTFn>O1 I _OKK1 _O KMI

SIIR114f

88 99 |'^ °/ < / 1

30 100 120 140

ScanCl .52

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168\

160

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SflMPLE SPECTRUM <UNflLTERED>Fil* >C1629Bpk flb 9847.

10000}\ 40 50 ~/~

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91L-3551-8 5ML

1141

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Data rile: >C162V::U2 Uuant Uutput rile: "C16'/:V::U4Name:Hiac:Uuant lime: V1112/ 04:26 Uuant iU File: 1 U_<v>U_:: : UIInjected at: V1112/ U^:4U Last Calibration: VI11IV 1>:IB

Compound No: 2^ US ID)Compound Name: 1,4-LHf luorobenzenebean Number: 241Ketention lime: IV.O/ mm.Uuant Ion: 114.0Area: 12>/"y6Concentration: ^>0.00 ug/Lq-value: 6B

AR203059

3F ECTRui"jFiii "3I6G6 Eth*n«, trichioro- 5can_750i6

I *'i j__ \/%_

I 60

1

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40 AO RO " 100

•=toMP! Fa i a • n e.pqBpk "flb "3522.

4

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ISflMPLE SPECTRUMFilm >C1629Bpk flb 3522.

£00J 4s

.1 \ }40

O1 I --OKK1 _O

C

60?Q f" 82 84

KMI Qr an pni 115.98 Min.

?5 igg

1 f :«.<, II '

^ ' III •11,1 M.l.iLn

60 80 100 120

<UNflLTERED>91L-3551-8 "" *

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can 20198 Min.13?/ -100i :

Data I-lie: >C162V::U2 Uuant Uutput I-lie: '"C162V::U4Name: VlL-^-p^l-8nisc: "7HLUuant Time: V1112/ 04:26 Uuant ID File: 1U_VCC::UIInjected at: V1112/ 0>:40 Last Calibration: V1111V 1>:1B

Compound No: 26Compound Name: Irichloroethenebean Number: 201Ketention lime: 1"?.VB mm.Uuant Ion: 1_*U.Ottrea: ^B4^?lConcentration: 3/.3/ ug/Lq-value: V2

AR203060

CJ

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SQMPI F SPFTTRIIM (RQr.k-fiP.ni IMP. SIIRTPQr.TFmFi 1 a >i~1629 •?••' -OKKI_OBok Ob 1590. SIIR

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SflMPLE SPECTRUM <UNflLTEREO>Fil« >C1629 91L-3551-8Bpk flb 1590.

i100C"

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,i i "ur" /a n40 60 50

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[

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Uata File: >C162V::U2 Uuant Uutput File: "C162V::U4Name: VlL-.J^l-B

Uuant lime: V1112/ 04:26 Uuant ID File: 1U_UCC::UIinjected at: V1112/ 0^:40 Last Calibration: V1111V 1^:

Compound No: 2VCompound Name: Benzenebean Number: 20/Ketenticn lime: 16.44 mm.Uuant ion: /B . 0«rea: lb/*?2Concentration: /._>0 ug/Lq-va lue : VO

AR203061

E r c 3 T fi N u|i-ii« 'V'XNSr HP VUH Wo Spik* Internal Standards and 5u 5can 660ICpk fib 10C. CLP NRH CC.C4 Kin.' 11?

1 82 I t1CC•i 54 7* i""' oo I I-1 ny 44 , 59 66 '^ 76 \ V j , \

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i- an **r\e,09 min.117' MOOI I- I

I . l120

SflMPLE 3PECTRUM_<UNOLTERED) _ . __|Fil« >C1629 '' 91L-3551-8 "5ML Scan 306! Bpk flb 7403. 24.09 i»in.I iie 117

1 77 82.. .. «?d ( r"4,U V >• BR b* 74 | | ».

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Data I- lie: >C162V::U2 Uuant Output rile: "•L162V : : U4Name:

Uuant lime: V1112/ 04:26 . Uuant ID rile: 1U_UCC::UIInjected at: V1112'/ 0 :44J Last Calibration: V1111V 1^:

Compound No: 15 tlblU)Compound Name: Ch lorobenzene-dbbean Number: >06Retention lime: 24. UV mm.Uuant Ion: ll/.Ottrea: BV>^6Concentration: bO.OO ug/Lq- value: VV

6R20306

,rn..e. 9 \ wKOHr. u or c.t, t nvti __. ._. . . i| r i i«^" site IJB c-tnene, ter.racnioro- ocanxd^xatj

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4000- 4J "" 1 49

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SO 100 ieO 140 160

Data r i l e : >C162V::U2 Uuant Uutput rile: 'VC162V::U4Name:disc:Uuant lime: V1112/ 04:26 Uuant 1U File: 1U_VCC::U!Injected at: V1112/ 0 :40 Last Calibration: V1111V 1>:1B

Compound No: ^6Compound Name: I etrach loroetheneScan Number: 2/6We tent ion lime: 21.// mm.Uuant Ion: 164.0ftrea: 'yV/' VConcentration: /*?.41 ug/Lq-value: VB

ftR203063

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Fi la >vXNSr HP VUH No 5pi k« In ». «rnmi Standards and 5u. Sc an 6co< - t _ t , r » u - « . - » . - . . i n M -i _r ^i rt — J ..l _ i p f v r » l - » - t W « l*f\tt L. \_> • -_ III A t 1 *

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^^ _ . A^ ^^% OO 1 '-^ 44 Oci 3t " bb '^ ™ gg 94 j

j , .1 .r'. ,>, r' .. ^ .'>.„!. / / / ., ii.:«40 KO AO 70 RO 90 100

SOMPI F SPFCTRIIM f RQr.KfiRniINn SIIRTRflCTFn^I F J J * >C1699 OII-IKKI—O

Bpk'flb 11117. ' '*" "silR

ICOCO-i•1 42 44 52 154 62 ££

40 50 60

KMI ^<- aw 2^^ '22.85 ruin.

98i7 M OO

70 76 78 82 . . If

• iMM,^.if.|.f..,i.f'.,i..MHlMlLQ 170 80 90 100 1

SflMPLE SPECTRUMFilm >C1629Bpk flb 11117.

1 nnnnJ•j] 4S *•*

Vo '

<UNflLTERED>

52

,->-\ f'r-j50

91L-3551-8

54 *>? 66 70/ \ -v {

60 70

5ML Scan 29022.85 Bin.

56ri .

'.* 7.8 SS oo o* i I\ / x r >• i.i

[-100

•Gi | i i i i i i i i i | i i 1 i j i i i i j i i i I | i -60 90 100

Data Hie: >C162V::U2 Uuant Output rile: 'HJ162V::U4Name:Hisc:Uuant lime: V1112/ 04:26 Quant ID Pile: 1U_JJCC::UIInjected at: V1112/ U_»:40 Last Calibration: V1111V 13: IB

Compound No: 3VCompound Name: loluene-dBbean Number: 2VOKatention lime: 22. b1?, mm.Uuant Ion: Vb.0Area: 144361?Concentration: 4.83 ug/Lq-value: VI

4.3

RErLRCN'CE STm't'DriRO SPECTRUM_________________________________________________Fiia 'BISC'S Benzena, chloro- Scan 105907'Dpk fib ICO. CLP TLT NRM MOM 0.00 »ir,.

.-,, "4.ICv-i i-I 77 I\ „ ' V \

40 50 AO 70 RO 90 100 110

SDHPI F SPFTTBIIM CRflHKRPnilNn ftFi i*Bpk"'flb~20568.

-1 3fl 48

rvi-jl., , ,1.

91L-3551-SSIIR

51 ^ 3, _., 62 74i 2* / '--—.i..,.f. ..,:,, . . j i i i i

40 50 60 70

KMt

'7

r.-. 88... ..x y80 90 100

24112

1

1

110

<s<- an "snal.24 min.

MOO-i <* * r

r" [

SflMPLE SPECTRUM <UNOLTERED> _ _ _File >C1629 "' " " 91L-3551-8 "" """"5ML ' " 'Scan 308Bpk flb 20568. 24.24 Min.

lie20000-1

l"c1 •=*» <.^ / KA b^ 74 I 82 88.1Y. /' II -^ / ..1 S / .

' ! 'J ' l'' i ' I ' .' j' I ' i l i J'_ i ' i '.' ' i J^ .'' I ' i ' i' [ i i i ' i ' [ i'i i i - j i ' >

(-100

60 70 ' 50 50 100 110

Data rile: >C162V::LJ2 Uuant Uutput rile: "C162V::L>4Name: VlL

Uuant Time: V1112/ 04:26 Uuant 1U h i l e : ILJ_<JCC::UIInjected at: V1112/ 0>:40 Last Calibration: V1111V l_i:lB

Compound No: 40Compound Name: Ch lorobenzeneScan Number: .JOBKetention lime: 24.24 mm.Uuant ion: 112.0ftrea: 2BVU44Concentration: l!?b.7B ug/Lq-va lue : V2

ftR203065

. . -1r i i e "/*N^r Mr VUH rup N nw ILvC •

1C01 7544 50 ""-

10 spik« internal Standards and Su ScanHIM 1 w». . W U

95 176

1 U.U 1J7illi 1 1 ^i 1 1 i \~~~

" 40 ' 'AO' ' 'R'O' ' '160' ' 'i?o' ' 'i4o' ' 'IAO' ' 'IRQ' ' '?6o'

SOMPI F SPFP.TRIIM (RQP.krfitfnillMn SIIRTROHTFn^Fila .'C1629Bpk~flb~4ii3.

4000-) ''O

j J7 r5°40 60

01 I -ORK1 _0 KMI "nr »nRIIR 28.41 N

95

176i 87 105 11? 141 156 if 193 207J \ 1 / X \ / II \ \.ijkip i. ..Jh < < ^ f M ^. \.80 100 120 140 160 130 200

OiJi i'l .

"100

-0

!?APlin .

MOO•'

'-0

SflMPLEFilaBpk

SPECTRUM <UMflLTERED>>C1629

Rb 4853

40CO-- 40

/. i <40

.

jj

i.'"-f-?

750 ^

'!" T60

1

91L-3551-8 5ML28

5o

RR

176105 11'' 141 156 ij' 193

MI'V-.l.1 l M.- l -.I..- l -.I..- l -.L." i •aw j.uv xew JL«»U xou J.BU

Scan 362.41 Min.

207X

f-100

-,-.ado

i

Uata hile: >C162V::U2 Uuant Uutput rile: ~C162V::U4Name: VlL

Uuan.t lime: V1112/ 04:26 Uuant ID rile: 1U_ULC::UIInjected at: V1112/ o_>:40 Last Calibration: V1111V i_J:

Compound No: 41?Compound Name: Uromof luorobenzenebean Number: >62Ketention lime: 2B.41 mm.Uuant Ion: V? . 0ftrea: V4003Concentration! ' l.'sB ug/Lq-value: BV

AR203066


SAMPLE NAME AND AMT: 91L-3551-8 5MLSAMPLE DATA FILE: >C1629


4 15.98 201 237427 TC5 16.44 207 46549 TC6 19.07 241 324957 IS7 21.77 276 483971 TC8 22.85 290 414374 SS9 24.24 308 1369725 TC10 28.41 362 450132 SS11 34.89 446 3574787 UK


fiR203067

File >C1629 35.0-260.0 amu. 91L-3551-8 5MLTIC

90000•

80008

7000*

•

50000-

48808-

38888-

20000-

18888-

0-

2

1

— - — !.LJ8

(

4

1 I1 .._ Hii i i • i • i •

12 16

1119 1

7»

8

110

1 J1

20 24 28 32 36 ' 49 ' 44

-100

^

-s a

;7e-68

-40

:30-28

-0

AR203068

File >C1629 91L-3551-8 5ML Scan 446Bpk flb 19960. SUB

^ :" 8-£

34.89 min.146

37 50 55 72 / 84 97 107, , , . i l l '. .'I | 'l'1'i i . i-l'-Ut-'i i I'l 'I'l i-i-MM1 ~~~~"'\-40 60 80 100

Lll Xf 128 131' i l l , , M ,, ,/,',, . , ,, ,

128 148


-.

0- '•

0.0e

l*

16705min .

146

75 11:L38 50 55 72 ^ 35 9? 107... ,. .rTT ,... "s !iii.. .,{,,. ":. ~~~~~~...

48 68 88 108

/ 128Li. ./.. i

120 148


-.

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3.86

-1

i\i -a

167861 min .

146

7K Hi-38 58 55 ?2 ™ 85 9? 197

48 60 88 188

/ 128.1.1. .... i

128 148


fc X

0.8C

-!

if -0

16784i min .

146

75 13L138 50 55 72 / 85 97 187 / 128

W 48 ' 68 ' 88 ' 188

/

128 148

•

1. Benzene, 1,4-dichloro- (9CI) 146 C6H4C122. Benzene, 1,3-dichloro- (9CI) 146 C6H4C123. Benzene, 1,2-dichloro- (9CI) 146 C6H4C124. Peroxide, bis(dichlorobenzoyl) (9CI) 378 C14H6C1404

Sample file: >C1629 Spectrum #: 446Search speed: 1 Tilting option: S No. of ion ranges searched: 61

Prob. CAS # CON # ROOT K DK #FLG TILT % CON C_I R_IV


CORRECTED TOTAL ION AREA OF UNKNOWN = 3574787 AR203069i CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 324957CONCENTRATION OF INTERNAL STD = 50 ug/L DILUTION FACTOR = 1SEMI QUANTITATION OF UNKNOWN = 550 ug/L

flR2Q3070

QUANT REPORT

^perator ID: LUELLA Quant Rev: 6 Quant Time: 911127 17:49atput File: AD7745::D2 Injected at: 911127 17:01

Data File: >D7745::D3 Dilution Factor: 1.00000Name: 91L3551-8Misc: 1000/1ML EXT:11/22/91 (RS0377)

ID File: ID_BAD::QTTitle: HP BNA Standards for 5 point Calibration Curve Rev. ELast Calibration: 911122 08:43

Compound R.T. Scan# Area Cone Units q

1) *d4-l,4-Dichlorobenzene 10.19 680 70563 40.00 UG/L 993) 2-Fluorophenol 6.85 359 5545M 2.53 UG/L5) Phenol-d6 9.64 627 9618 3.15 UG/L 979) 1,3-Dichlorobenzene 10.08 669 11901 4.29 UG/L 9410) 1,4-Dichlorobenzene 10.25 685 81617 29.60 UG/L 9612) 1,2-Dichlorobenzene 10.79 737 419364 147.39 UG/L 9618) *d8-Naphthalene 14.03 1048 278007 - 40.00 UG/L 9119) Nitrobenzene-d5 11.99 852 128901 40.88 UG/L 9524) Benzoic Acid 13.79 1025 3685 1.85 UG/L 8829) 4-Chloroaniline 14.48 1092 318201 95.69 UG/L 9333) *dlO-Acenaphthene 19.52 1575 157697 40,00 UG/L 8838) 2-Fluorobiphenyl 17.55 1386 222201 42.72 UG/L 9454) *dlO-Phenanthrene 24.08 2013 290248 40.00 UG/L 9858) 2,4,6-Tribromophenol 22.03 1816 2372M 3.13 UG/L66) *d!2-Chrysene 32.40 2811 172754 40.00 UG/L 9869) Terphenyl-dl4 29.28 2512 232431 40.62 UG/L3) Bis(2-Ethylhexyl)Phthalate 33.06 2874 21467 4.02 UG/L•5) *d!2-Perylene 36.57 3210 90770 40.00 UG/L

* Compound is ISTD

ye

*

TOTflL ION CHROMflTOGRflMFile >D

120000&:

1100000

1000000:•

'.900000-

•800009-

.

700000;

600000-

500000

400000

300008-

200000-

100000-

7745 35.0-580.0 amu. 91L3551-8 1800/1ML ETIC

1000 2000 3000 4000i i . i i i i . i i , . , i i . i i i i . i . . i i . . . i i . . i i i , i i i

mCvMCID

1__

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J~~ .=4!C.

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f 1s 1C v1 J=1 N F1 - J ikCiLg-

4 8

1 -g. S §J • -1 | | ? «

ID W "§ « 6 n' "5

I «' § i* -B f "^#g j c : l l ° 1 &5 DC n- "° !p S ®-g "° E *" Is ^

1 ._ ,| tr M ^. 1 1 V> V "aM e l & m lJ IIP i T _LJ 1 , .._, i JA. L_L ._-, . ___H_-.I - * — -• J... i. .A* . .u-. —— ^^

1 i • i • i • i • i • i • i • i • i • i • i • i • i • i • i • i • i •12 16 28 24 28 32 36 48 44

Data File: >D7745::D3 Quant Output File: D7745::D2Name: 91L3551-8Misc: 1000/1ML EXT:11/22/91 (RS0377)

Id File: ID_BAD::QTTitle: HP BNA Standards for 5 point Calibration Curve Rev. ELast Calibration: 911122 08:43

Operator ID: LUELLAQuant Time: 911127 17:49Injected at: 911127 17:01

AR20307J

REFERENCE STflNDflRD SPECTRUMFile >BBpk flb

40000-•

0-

7941 d4-l,4-Dichlorobenzene44024. SUB

52 56 64 7Q 9«4/e f / X ,' 8/7 <

I'll 1 l.'l'l'l'Hl I'l'l'f i ! I'l'l' -| . I'I'I'M . .40 68 88

910925 09:28 Sc18.8

1

115' r 122I'M M i i'i'1 l ' l » Mi i |i • i M i '1 1'188 128 148

a95/

mn8

4

752in .

-188.

-8

SflMPLE SPECTRUM (BRCKGROUND SUBTRflCTED)File >D7745 91L3551-8 1880X1ML EXT:11 Scan 688Bpk flb 45728. SUB 18.19 min.

158

48808-._

8-

Kp 70 11538 « 56 64 7 8? 99 ±03 /

.iCT.. ....,.!., /..... / . ...I.!.. Y. N / ...I.I.

/

i40 ' 60' ' 80' ' 100 ' 120 ' 140

J.

-108

-a

SflMPLE SPECTRUM <UNflLTERED>File >D7745 91L3551-8 1000X1MLBpk fib 45728.

48888-

"

a.

EXTrll Scan 68010.19 min.

150

ep 70 llSOC K£ fA ' " j» . v

s3O ^ y . ' 87 10*3

.r.. ,...J.,. {....../ ..,,1,1,, .f. N /40 68 80 108

.1.

^

, il.

-188•

-a128 ' 148

Data File: >D7745::D3 Quant Output File: AD7745::D2Name: 91L3551-8Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 17:49 Quant ID File: ID_BAD::QTInjected at: 911127 17:01 Last Calibration: 911122 08:43Compound No: 1 (ISTD)Compound Name: d4-l,4-DichlorobenzeneScan Number: 680Retention Time: 10.19 min.Quant Ion: 152.0Area: 70563Concentration: 40.00 UG/Lq-value: 99

AR203072

REFERENCE STflNDflRD SPECTRUMFile >B7941 2-Fluorophenol 910925 89:28 Scan 426Bpk flb 46568. SUB 7.50 min.

112

40880-

8-

64y

ia =« 5? 73 ' 83 9,233 45 58 / 68 y -^ /

1 1 1 1 1 11 II 1 1 1 1 1 1 1 1 1 li 1 1 1 1 1 II • 1 1 1 11 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 . 1 1 1 1 1 1 1 1 1 1 1 1 ! 1 1 -T-.

/

1 140 50 60 70 80 90 . 108 110

-108

-0


641000- 57 t• 41 J*3 / j

o_ ^Tl \\ 1 II48 50 60

1000/1MLSUB

70

83

180

EXT:11 Scan 3596 .85 min .

112

f l"10092

„, J,,,,,,,,, „„„„,„„-*90 100 110


1000-

0-

i\a< 43 ?

1 fT 148 ' 50 ' 60

1000/1ML EXT:11 Scan 3596 .85 min .

112

64{ 83 92

1 1 1

-100

-a70 ' 80 90 ' 100 ' 110


Compound No: 3Compound Name: 2-FluorophenolScan Number: 359Retention Time: 6.85 min.Quant Ion: 112.0Area: 5545MConcentration: 2.53 UG/L

AR203073


40000-

- 40/ r~0- hM-f -I4J

40

Phenol-d6

2? 49 54 58

/ l i l l i ' i t l t \ \ t \ l i \ \ \50 68

918925 09:20SUB

66 ?i. ?2 81 82"•. I S \v /

l l | J l i J / J l l l | f M i l l 1 . U M M | l l70 80 90

Scan 69210.26 min.

99' -100

94i

. ) | . ll --1L0100

SflMPLE SPECTRUM <BflCKGROUND SUBTRACTED)File >D7745Bpk flb 3502.

.~

2008- 40

a. i 1 148

91L3551-8

42" 49 54 58

1 i / / /III i i 158 68

1000/1MLSUB

7166 * »

...... _ .....


99' 1-188

••

, i la88 98 188

SflMPLE SPECTRUM <UNRLTERED>File >D7745Bpk fib 3582.

.•*

2080- 48

fr i " 1 140

91L3551-8

42-" 49 54

ll, f f50

1800X1ML

7158 66 i\ T*\ . il 160 ' 70

EXT: 11 Scan 6279.64 min.

99' (-180

•93' ' ' -^

80 ' 90 ' 188


Compound No: 5Compound Name: Phenol-d6Scan Number: 627Retention Time: 9.64 min.Quant Ion: 99.0Area: 9618Concentration: 3.15 UG/Lq-value: 97

AR20307U

REFERENCE STflNOfiRD SPECTRUMFile >B7941 1 ,3-Dichlorobenzene 910925 09:20 Scan 740Bpk flb 54840. SUB 10.76 min.

146

40000-

0-

,-, 50 63 7,5 „ 97 /37 / 5 v .' 85 vf 120

I'l't . i i ' l ' l ' l i'l i I ' l ' i i i I'l'l'f'i | i - I M ' i | i , 1', | . i .'I'] I'M i M i i u i ii i i i i40 60 80 100 120 140

Ltf -0

SflMPLE SPECTRUM <BflCKGRQUND SUBTRflCTED)File >DBpk flb

-4008-

0-

7745 91L3551-85547.

07 50 5537 / ,n ill i n .il48 ' 68

1808/1ML EXT:11 ScSUB 10.0

1

,5 111/ 85 f, / . I.I88 100 120 148

a84I

i

in«6

,

669in .

-100

-0

SflMPLE SPECTRUM <UNflLTERED)File >DBpk flb

-4888-

-0J

7745 91L3551-8 1888/1ML EXT:11 Sc5547. 10. C

1

7g 11137 / *? f 85 '

rT ,1, / .. .,il. / . .140 ' 60 ' 80 ' 100 ' 120 ' 148

a84/

i

nn6

i

669in .

-100

p

L8


Compound No: 9Compound Name: 1,3-DichlorobenzeneScan Number: 669Retention Time: 10.08 min.Quant Ion: 146.0Area: 11901Concentration: 4.29 UG/Lq-value: 94

AR203075

'Jt •REFERENCE STflNDflRD SPECTRUMFile >BBpk flb

-40000-

8-

7941 1,4-Dichlorobenzene 910925 09:20 S61248. SUB 10

-_ 50 55 72 75 __ 108 /J / / \ / 84 97 x! | 120if i -I'!1 M IT M1!1 'P. ^ l-l'l ' l f40 60 80 100 120 140

5<.<j~

i

:an?3 rr.46

756in .

-100

-Q

SflMPLE SPECTRUM (BflCKGROUND SUBTRfiCTED)File >D7745Bpk flb 31176

_

2000037

.1.40

91L3551-8

50 55 72

60

1008'1ML EXT:11 Scan 685SUB 18.25 min.

146-""

7_ 111

r 84 97±v f1 (.. ( XL.

-100

-080 100 120 140

SflMPLE SPECTRUM <UNflLTERED>File >D7745 91L3551-8 1000/1MLBpk flb 31176.

_,

20008

0- ........... . , , ... i ........... . . .,....,

37 50 55 72 /5 ._ 188 *J- ( y ^ ii 85 97 x.rT ..,.,!,, .r ..... NilL /. / X.40 60 80 188


146

11/

,-"'

i ,1.,..

-100

-fl

120 140

Data File: >D7745::D3 Quant Output File: AD7745::D2Name: 91L3551-8Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 17:49 Quant ID File: ID_BAD::QTInjected at: 911127 17:01 Last Calibration: 911122 08:43Compound No: 10Compound Name: 1,4-DichlorobenzeneScan Number: 685Retention Time: 10.25 min.Quant Ion: 146.0Area: 81617Concentration: 29.60 UG/Lq-value: 96

AR203076

REFERENCE STfiNDflRD SPECTRUMFile >B7941 1Bpk flb 52632.

,

40000--

0-

,2-Dichlorobenzene 918925 89:28 Scan 807SUB 11.46 min.

146f

37 ^o __ 63 f- -. 91 105 '37 / 55 x / 84 f N 120.n, ,.i40

i.. i, ii.rfT ..llln.i. .in. ..r .. . i.iiu .1. f. 1 tl.

kL88

.

.a'f','1 i I ' l ' l 1 , i I'l'l'f'r'l T'l'rr'f'r-r^'r'rT r'rHI'l'li i | 1 i i i \ri i r i i r t- r w60 80 100 120 148

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >DBpk flb

100000-

7745 91L3551-8 ISOBxlML EXT:11 Sc140673. SUB 10.7

1

75 ^37 5.0 55 63 / o,- 97 99 'J- { / / \ ** \. S 128.rT ..,!,. ,< „/ ...ill,. ./. X/ ...,,i. ../.

a94

inIT6

ii.48 ' 60 ' 88 ' 100 ' 128 ' 140

737in .

-100

-0

SflMPLE SPECTRUM (UNflLTERED)File >DBpk fib

100000-

7745 91L3551-8 1000/1ML EXT:11 Sc140673. 10.7

1

75 "37 5/ 55 « ( 85 " 99 '

.rf.. ..L tf....s ...ill,. ..,<.. \./ ...,,i. ./.40 ' 60 ' 80 ' 100 ' 120 ' 148

a94/

I

nm6

.1.

737in .

-100

-0


Compound No: 12Compound Name: 1,2-DichlorobenzeneScan Number: 737Retention Time: 10.79 min.Quant Ion: 146.0Area: 419364Concentration: 147.39 UG/Lq-value: 96

AR203077


5000042

r-t-k-r40

dS-Naphthalene•

5\J4 . i i-rTi i . \+i60

SUB

v. 82 88 9'f i l l I ' i ' l ' i i \ | i \

88

918925 89:28

'„"",„„100 120

Scan 112814.72 min.

136f -100

128,-ri 1 - 1 ' ^-8


1000001

: 42 52

40

54 68.1 .. . ...TTTi

60

1000/1MLSUB

76 106 10x 80 9094 v ^$

. .,. ,.' ,.,... f. t ... .N.i.80 ' 188

EXT:11 Scan 184814.03 min.

136' -100

s 130 :>.i.h l.lg

' ' isg • • - . • • • •

SflMPLE SPECTRUM CUNfiLTERED)File >D7745 91L3551-8Bpk flb 108448.

100000-

0

42 52 54 68

40 ' 60

1000/1ML

^ 88 9094

80 ' 188

EXT:11 Scan 104814.03 min.

136' -100

108 130 :.\^ X.,.1, i.i0..... ifei . . . . . . . .


Compound No: 18 (ISTD)Compound Name: d8-NaphthaleneScan Number: 1048Retention Time: 14.03 min.Quant Ion: 136.0Area: 278007Concentration: 40.00 UG/Lq-value: 91

AR203078

REFERENCE STflNDfiRD SPECTRUMFile >B7941 Ni trobenzene-d5 910925 09:28 Scan 923Bpk flb 40856.

40000-.

0-

54/

42 52/ i

1 •! } i i • I ' • 'i f t i i i i i i i

SUB 12.67 min.82

66 70 77X ' '1 I I'l 1- 'I I'l'l I'J

*r12!

93 Qp\ / 112\ . . { ,, .i i i i i t i i I r i i i i i i i i i i i i h

r!00

'•0

40 68 88 100 120

SflMPLE SPECTRUM <BflCKGROUND SUBTRACTED)File >D7745 91L3551-8 1000X1ML . EXT:11 Scan 852Bpk flb 47376. SUB 11.99

82Ji

48080-

-

f _J

54 -/

, , T 5^ \ T 7i

9>8 112• i ^i . . i . .

40 60 80 100 120

mm .

2!

1

"10011

-a

SfiMPLE SPECTRUM <UNfiLTERED)File >D7745 91L3551-8 1000X1ML EXT:11 Scan 852Bpk fib 47376.

4

40000-

0-v . . . .

11.9982

min .

•S4 -""/

42 5|__

48

66 78 ,,

X...L f...

12!

/8 "2.1. /

68 80 100 120

-180{

-a

Data File: >D7745::D3 Quant Output File: AD7745::D2Name: 91L3551-8Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 17:49 Quant ID File: ID_BAD::QTInjected at: 911127 17:01 Last Calibration: 911122 08:43Compound No: 19Compound Name: Nitrobenzene-d5Scan Number: 852Retention Time: 11.99 min.Quant Ion: 82.0Area: 128901Concentration: 40.88 UG/Lq-value: 95

AR203079

REFERENCE STflNDflRD SPECTRUMFile >DBpk fib

2000-•

0-

7273 Benzoic flcid1983.

77^

51/

, , , , , ! , , , , , , , , , , , , ,60

cSUB

1

94i i80 100

?10926 11 :«

05 122' ^

l126

*8 Scan 114.53 n

123r

866in .

-180

-0

SflMPLE SPECTRUM (BflCKGROUND SUBTRfiCTED)File >DBpk flb

1000-

0-

7745 91L3551-81020.

77A* 51 ^J:1 / 57i il ir i.

60

1888/1MLSUB

1

851

EXT:

f5

1

11 Scan 113.79 if

22/

188 108 120

025tin .

-100

-0

SflMPLE SPECTRUM <UNRLTERED>File >D7745 91L3551-8 1000/1ML EXT:11 Scan 1025Bpk fib 1020. 13.79 min.

77 "5 1221000-

•:0-

"X.*+ 51

J> < 57r il ir i.85 1

/

1 1

-1881

,

-060 ' 80 ' 188 ' 128

Data File: >D7745::D3 Quant Output File: AD7745::D2Name: 91L3551-8Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 17:49 Quant ID File: ID_BAD::QTInjected at: 911127 17:01 Last Calibration: 911122 08:43Compound No: 24Compound Name: Benzoic AcidScan Number: 1025Retention Time: 13.79 min.Quant Ion: 105.0Area: 3685Concentration: 1.85 UG/Lq-value: 88

AR203080


.40080-

'39

40

4-Chloroani

65S? ^ - 7

60

1 ine

76

l'» i | i I'V80

910925 09:20 Scan 1168SUB 15.13 min.

127'

,f L 1/18Ifl'l I'l' 'I'M 1 |'(l IM II I1. M.-n-r. .. .,.. ..,.. -

162

J. Y

-100

-a100 120 140 160

SflMPLE SPECTRUM (BflCKGROUND SUBTRfiCTED)File >D7745 91L3551-8Bpk fib 92000.

108008-1

•

&

39

.•ihi.40

52.1 ...in..

65

"1 73 x6.iiiih. ,,.<: ...60 80

1088/1ML EXT illSUB

127-""

92 100

...il, ...L. ..!130

\f f"^ 100 r iFa ' 148

Scan 109214.48 min.

-180

B

-C

168

SflMPLE SPECTRUM <UNRLTERED>File >D7745 91L3551-8Bpk fib 92800.

100008-1'.

»...••••!•••

39 52< t.ill.,. .1 ...i.i..40

65

^ 73 76,,1,1, ""i/

60 88

1000/1ML EXT:11

127•s1

/2 100J iL /

138, f ^

188 ' 128 ' 148

Scan 189214.48 min.

-180•.

-a168

Data File: >D7745::D3 Quant Output File: AD7745::D2Name: 91L3551-8Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 17:49 Quant ID File: ID_BAD::QTInjected at: 911127 17:01 Last Calibration: 911122 08:43Compound No: 29Compound Name: 4-ChloroanilineScan Number: 1092Retention Time: 14.48 min.Quant Ion: 127.0Area: 318201Concentration: 95.69 UG/Lq-value: 93

AR20308I

REFERENCE STflNDfiRD SPECTRUMFile >B7941 d!0-flcenaphthene 910925 09:28 Scan 1651Bpk fib 44888. SUB 28.24 min.

40000-

-

0J

164

« .« « ? f V y* ». 132 133

IT*' .1 I ' l ' l48

' .\ S 1 i ' N/ / ' -^ >l'1 i | I'l'l 1 { i'l I'l'l1 1 1 1 1 f'l'l ! t\ 1 1 \i ' | i i i 1 ! 1 i i i I'l'i"!'!1! ulu I'l'l'l1|

s.

1 1»

-188•

L868 80 188 128 148 168

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7745Bpk fib 64192

91L3551-8.

1000/1MLSUB

EXT: 11 Scan 157519.52 min.

164_

40000-

0J42

. ..{..48

54i i..

66 68Tl f*' i

60

80/

nil30

90 100 y8 122/ / / /

108 128

146 156132 ;f vf, ^ , 1,

•*>

1

^

1.

-188

,

-a148 168

SflMPLE SPECTRUM <UNRLTEREO>File >D7745 91L3551-8 1000/1ML EXT:11 Scan 1575Bpk fib 64192. 19.52 min.

164.

40888-

8-

8842 54 66 68 / 90 100 / 122 132 ^ X

...... i ,.. . ..i.l.i. .. i.iilil . . . ;;. .. f . . ,.<\ , . .... .1..... . ^ ..i.l.

^

, 1 1.

-100

,

-0

48 60 80 100 120 140 160

Data File: >D7745::D3 Quant Output File: AD7745::D2Name: 91L3551-8Misc: 1000/1ML . EXT:11/22/91 (RS0377)Quant Time: 911127 17:49 Quant ID File: ID_BAD::QTInjected at: 911127 17:01 Last Calibration: 911122 08:43

Compound No: 33 (ISTD)Compound Name: dlO-AcenaphtheneScan Number: 1575Retention Time: 19.52 min.Quant Ion: 164.0'Area: 157697Concentration: 40.00 UG/Lq-value: 88

AR203082

<-*.-./


100000-

39

8- i| M i i40

2-Fluorobipheny 1

51 63

I'ln'iri'rH'l"68

76 85

88

SUB

94s 107

'fl l'|'l i'1'i'l'i1100

120

'i'i IT'1'1120

918925

133\

146X

l l ' l . l ' l140

09:20 Scan 145918

H _? 4 i o y151 v.

160

.24 mm .172t

4

t-100

a

SflMPLE SPECTRUM <BfiCKGROUND SUBTRflCTED)File >D7745Bpk flb 84936

50088- 39

48

91L3551-8.

51 63 75 85

68 88

1000/1MLSUB

99 106 120

188 128

133\

EXT:11 Scan 138617.55 min.

172

146 151 -l8 ,.. ,,;.., X.||

f KL88

-a148 160

SflMPLE SPECTRUM <UNfiLTERED>File >D7745Bpk flb 84936

50008- 39

40

91L3551-8•

51 63 75 85,....,....,....,....,..

60 88

1000/1ML

99106Ti'yi i'l'VjV100

133120 N

f .. 120

EXT: 11 Scan 138617.55 min.

172• -100

146 151 16^ - :.**Zi. ..n.. ... Xlll. .10140 160

Data File: >D7745::D3 Quant Output File: AD7745::D2Name: 91L3551-8Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 17:49 Quant ID File: ID_BAD::QTInjected at: 911127 17:01 Last Calibration: 911122 08:43Compound No: 38Compound Name: 2-FluorobiphenylScan Number: 1386Retention Time: 17.55 min.Quant Ion: 172.0Area: 222201Concentration: 42.72 UG/Lq-value: 94

AR203083

REFERENCE STflNDflRO SPECTRUMFile >B7941Bpk flb 74056.

50000-

420. 1 1 1 1 1 1 140

d!8-Phenanthrene 910925 09:20 Scan 2091SUB

/* 6,6l f i | l ' l ' f i | i i60

S30

80

94 188

•I'l1 1 1 1 1 1 1 1 1 1100

118 132\ X

|l III |ll M|l

120

136 x

140

160/

160

24.82 min.188

178i ini'i'n'l'i1. H w

/

1.

-100

.a180

.SflMPLE SPECTRUM <BfiCKGROUND SUBTRflCTED)File >D7745 91L3551-8Bpk fib 105152.

100000-

42 x 66

40 ' 68

88., 1 .....80

1000X1MLSUB

94 y* H4 ,_,'. /......./.....

100 120

EXT:11 Scan 201324.88 min.

188f -100

* 136 "v? 1" 18* :.../ ..... .u. .. X.i.,i i. . Ig

140 160 180

SflMPLE SPECTRUM <UNfiLTERED>File >07745 91L3551-8Bpk fib 105152

100888-

J^42

•

/2 56ir. !•!•!•!••. •.•.••••60

80

4***i80

1000XlhL

94 100

180

114/ x1/36 1!128 148

EXT:

5* 160

160

11 Scan 201324.08 min.

188

180

. . N..,.,,

f

\..

-100

-aI'p-TTT' " ' T1 "

180


Compound No: 54 (ISTD)Compound Name: dlO-PhenanthreneScan Number: 2013Retention Time: 24.08 min.Quant Ion: 188.0Area: 290248Concentration: 40.00 UG/Lq-value: 98

REFERENCE STRNOflRD SPECTRUMFile >B7941 2, 4, 6-TribromophenolBpk flb 21200.

£0000-.

~ 37

40 JC62"" 91

/

38

111

120

141

i,i i i i

918925SUB

172

160

197 22

'Mi '"1 ' ' ' 1208

222 250

240

09:20 Scan22.75

330

1303 i../ 1

280 328

1892mm .

I

-1001

-a

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7745Bpk flb 1073.

1000-

5C

± ,. II.40

91L3551-8

62

98 106

n I I I88 120

1000/1MLSUB

141{ 223

II f160 200 240

EXT:11 Scan 181622.83 min.

332**"• -108

1 1 lg288 328

SflMPLE SPECTRUM <UNflLTERED>File >D7745 9Bpk flb 1073.

10001

'•'\c. 11 Illl48

1L3551-8 " 1000/1ML

62""" 141

90 106 / 223mi (H r"i 1 r813 120 160 200 240

EXT:11 Scan 322.03 n

332

ill280 ' 320

.816lin .

-100

-0

Data File: >D7745::D3 Quant Output File: AD7745::D2Name: 91L3551-8Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 17:49 Quant ID File: ID_BAD::QTInjected at: 911127 17:01 Last Calibration: 911122 08:43Compound No: 58Compound Name: 2,4,6-TribromophenolScan Number: 1816Retention Time: 22.03 min.Quant Ion: 330.0Area: 2372MConcentration: 3.13 UG/L

AR203085

REFERENCE STflNOflRD SPECTRUMFile >B7941Bpk flb 75899

50000-52

^ /

48

d!2-Chrysene

66 9 186 120.„./, ,,„,,,;>,, ,,,51..,,,1 1 1 1 1 1 1 1 1 1 1 .

88 1<

SUB

126 154 178/ \ \

"'"I'l | . i'"l"| VI20 • 160

910925 89:28 Scan 289533.18 min.

248j -100

182 ^4 212 L341 •,. ,,1 , ,,/„,, v,, rvr,T Jill, , ,J,I,10

200 240

SflMPLE SPECTRUM (BflCKGROUND SUBTRfiCTED)File >D7745 91L3551-8Bpk flb 53120.

40000-- 54 90 i

N* 66 x 1

40 ' 80

1000X1MLSUB

06 120 124 156 160 ±Q0Ti "jl S X / /

120 160

EXT:11 Scan 281132.40 min.

240"" -

194 208 241

Ii

-100•

-a200 240

SRMPLE SPECTRUM <UNflLTERED)File >D7745 91L3551-8Bpk fib 53120.

40000-

- 41 66 9? 10

40 80

1000/1ML

120 124 156 160 ...•^. S \ / 180....ji... .X/. /..128 ' 168

EXT:11 Scan 281132.48 min.

248"*""* j-100

194 208 241 '/,. i.,,.j,,c;.-*200 240


Compound No: 66 (ISTD)Compound Name: d!2-ChryseneScan Number: 2811Retention Time: 32.40 min.Quant Ion: 240.0Area: 172754Concentration: 40.00 UG/Lq-value: 98

AR203086

REFERENCE STfiNDflRD SPECTRUM '•* -File >B7941Bpk flb 118832

100000-

; 54

40

Terphenyl-dl4SUB

106 1Pp 13666 80 94 / J>22 x 1

80 120 1(

910925 09:20 Scan 259130.02 min.

244^ -100

68 174 "s* & '•Pv n-X.TW U»0 200 240

SflMPLE SPECTRUM <BflCKGROUND SUBTRfiCTED)Fila >D7745Bpk fib 79240

50000- KA

\

48

91L3551-8.

66 80 94

v-X-r.-rT-f-v-r80

1000X1ML •

106

120

SUB

>/

168 174..,/....../ ...168

EXT:11

- «288

Scan 251229.28 min.

244" s.

226/ .......1,1.

-188,

-a. . r- T^

248

SflMPLE SPECTRUM <UNRLTERED>File >D7745 91L3551-8Bpk fib 79240.

5000fr 54

n- ^

40

66 80 94/ / /

80

1000/1ML

106 3- / 160 174f^ 1 ^ >\ f

120 160

EXT:11

QQ^ 212N 208

Scan 251229.28 min.

244"*"• -100

,

226./... j-le

240


Compound No: 69Compound Name: Terphenyl-dl4Scan Number: 2512Retention Time: 29.28 min.Quant Ion: 244.0Area: 232431Concentration: 40.62 UG/Lq-value: 90

AR203087

REFERENCE STflNDfiRD SPECTRUMFile >B7941Bpk flb 66584.

—

40000-j

&•57

,1,1 ,,,J,L40

Bis<2-E

71 83/ °3ll

r 's's' '

thylhexyDPhthalateSUB

149"""""•

11-3 132i. \

. 1. il .. >.

167

i .. I.128 168

910925 09:28 Scan 2952• 33 .77 min .

261 279

. \ ^1.

-100

-a208 248 280

SflMPLE SPECTRUM (BflCKGROUNO SUBTRfiCTED)File >D7745Bpk flb 8466

•

5088-

fr

57_

ill40

91L3551-8.

±

1 ' ?3il t.ill •..<!. i .80

1000/1MLSUB

149" t

113 1£1ii . il .1.

167"x>:

1. I120 160

EXT:11 Scan 287433.86 min.

207~]r 279. i

rl00,

-0280 240 280

SflMPLE SPECTRUM <UNflLTERED>FilBpk

e >D7745fib 8466

5008:

8-

57~v.

,11.48

91L3551-8 1000/1ML•

ll

149""K-

/ 83 113 ipi,il / ^ . /

.till l.lih I,J. 1, Mil .M ...

167

EXT:11 Scan33.06

2874mm .

\ 287 S7Q

./88 ' 120 ' 160 ' 288

- .

-188'

-a248 ' 288

Data File: >D7745::D3 Quant Output File: AD7745::D2Name: 91L3551-8Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 17:49 Quant ID File: ID_BAD::QTInjected at: 911127 17:01 Last Calibration: 911122 08:43Compound No: 73Compound Name: Bis(2-Ethylhexyl)PhthalateScan Number: 2874Retention Time: 33.06 min.Quant Ion: 149.0Area: 21467Concentration: 4.02 UG/Lq-value: 83

AR203088

REFERENCE STflNDfiRD SPECTRUMFile >B7941 d!2-PeryleneBpk fib 72040.

80000-,

40000- 42 ff 114 132y 66 " \ "^

40 80 120

SUB

156

168

918925 09:28 Scan 329337.32 min.

180 £!4 2X08/ \ X' 1 ' 1 * 1 'l"l ''1

288

232 2 .^ —— -I

240

264+*** _• ,«._»

1

-low

.ai • |

280

SflMPLE SPECTRUM <BRCKGROUND SUBTRflCTED)File >D7745Bpk fib 24592

.20000-

- 42

40

91L3551-8.

\ ?80

132104 .JC.JJ.-J

120

1888/-1MLSUB

191 i156 180 // / / /168 280

EXT:11

'09 2s 232^ /

• i fett

240

Scan 321836.57 min.

264"""

38

1,l .

h!00

•a288

SflMPLE SPECTRUM (UNfiLTERED)File >D7745 91L3551-8Bpk fib 24592.

.28888-

»,.......,...\ f \

48 88

184 "..<....J.I....j,ll, ... i ...

120

1000/1ML

156 180

160

191/ X

200

EXT:11 Scan 321836.57 min.

264

y7 232 / i.. b.t .. Ij.ln

248

" hl80

-n288

Data File: >D7745::D3 Quant Output File: AD7745::D2Name: 91L3551-8Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 17:49 Quant ID File: IDJBAD::QTInjected at: 911127 17:01 Last Calibration: 911122 08:43Compound No: 75 (ISTD)Compound Name: d!2-PeryleneScan Number: 3210Retention Time: 36.57 min.Quant Ion: 264.0Area: 90770Concentration: 40.00 UG/Lq-value: 95

AR203089

'•*•*•SAMPLE NAME AND AMT: 91L3551-8 1000/1MLSAMPLE DATA FILE: >D7745

AREA IDENTIFICATION1 ' 4.78 160 257126 UK2 5.81 259 858283 UK3 7.92 462 777163 UK4 8.15 484 43367 <10%5 8.34 502 45706 <10%6 8.59 526 39344 <10«7 8.93 559 76872 UK8 9.46 610 83152 UK9 9.64 627 44087 SS10 10.08 669 46056 TC11 10.19 680 481684 IS12 10.25 685 314457 TC13 10.70 729 56480 UK14 10.79 737 1803620 ' TC15 10.94 752 52215 UK16 11.57 812 41910 <10%17 11.73 827 51854 UK18 11.99 852 418206 SS

19 12.93 94320 14.03 1048 610720 IS21 14.48 1092 1181648 TC22 14.63 1106 3649223 16.18 1255 38539 <109<24 16.27 1263 41243 <10«

25 17.11 1344 6693726 17.56 1387 730669 SS27 17.79 1409 33319 <10X28 18.18 1447 313052 UK29 18.48 1475 838611 UK30 18.57 1484 43224 <10X31 19.52 1575 717994 IS32 20.21 1641 174409 UK33 21.72 1786 347299 UK

34 23.66 1973 3208935 23.76 1982 5607236 24.08 2013 809301 IS37 26.33 2229 3387638 27.39 2330 34709 <10?<39 27.71 2361 46884 <10H

40 29.10 2494 181202 <-,, '-41 29.28 2512 692851 SS42 29.70 2552 177691 UK43 32.41 2812 557557 IS44 33.06 2874' 91576 TC

ARZ03090

IS = INTERNAL STANDARDS3 = SURROGATETC = TARGET COMPOUNDUK = UNKNOWN<10% = UNKNOWN LESS THEN 10% OF INTERNAL STANDARD

AR20309I

Fila ,>0?745

650000-•

600000-

50000-

500000-

450000-

400000-•

350000-

300000-.

250000-•

£00000-'

150000-

100000-.

50000-J

__I --';.SM

4L

35.0-500.0 arnu. 91L3551-8 1000/1ML EXT:TIC

1000 SOOO 3000 4000. 1 . . . . : . . . . 1 . . . . 1 . . . . 1 . . . . l . . . . 1 . . . . f

14

3

. .. >

1]

1

rtluk.

' 8 ' '

21

2<.

18

^

4i

19

.

=2

2926 31

***\

5

3

36

33

32

_L^

16 20

3'

41

4

43

,245

U 1

uJL_

-100

-90

r80

r70

J-60

;50

-40

:30

:£0'

.1 ' 1 ' ' • i • i • i • i • i • i • i • i •24 28 32 36 40 44

AR203092

Fila >07745 91L3551-8 lOOO-'irtL EXT:ll'-22^ Scan 160Bpk flb 7379. SUB 4. 7,3. jn in.

12947 „ 94-_ 49 59 . 92

%;

-f-r40 60 80 100 120 140 160

i l e > B I G D B E t h e n e , tatrachloro- < 9 C I ) S c a n 19848Bpk flb 9999. 0.00 min.

166

j L2947 49 59 82 9,4 99 117 119

i ^ ^ -'^ / i i •"' -•--. <~-- L040 60 80 100 120 140 ISO

File >BIGDB Ethene, tetrachloro- <9CI> Scan 19848Bpk fib 9999. 0.00 min.

166-i 129 / L.

47 49 59 82 9,4/ 99 117 119 I j

40 60 80 100 120 140 160

File >BI6DB Benzene, £<2-chloro-2-prop@nyl>oxy3- <9CI> Scan 14421Bpk Bb 9999. 0.00 min.

133

.39 « f7:J,........,!.,.......,!.....

4 105

]Z.....,I........,.L,.. 115 1191

141 151168

"140 60 80 100 120 140 160

1. Ethene, tetrach loro- C9CI) 164 C2C142. Ethene, tetrachloro- (9CI) 164 C2C14J. Benzene, [C2-chloro-2-propeny1)oxy]- (9CI) .168 C9H9C10


Prob. CAS # CON # ROOT K DK #FLG TILT H CON C_I R_IU

1. 83* 127184 19848 "BIGDB 72 50 1 0 87 13 51 712. 83* 127184 19848 "BIGDB 72 50 1 0 87 13 51 717. 11* 53299539 14421 "BIGDB 32 94 3 0 90 63 2 13

CORRECTED TOTAL ION AREA OF UNKNOWN = 257126CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 481684CONCENTRATION OF INTERNAL STD = 40UG/L DILUTION FACTOR =• 1SEMI QUANT I TAT I ON OF UNKNOWN =• 21UG/L

AR203093

Fil« ^07745 91L3551-8 lOOQxltlL EXT:llx22/- Scan 259Bpk flb 57488. SUB

1 '3J.,f,

40

Fila VBIGDBBpk flb 9999

-: ss

0-,; !•!., ,40

File ,>BIGDBBpk flb 9999

5148 / 56 61 72" "" i 1 i • n i"TT "~: I'll

50 60 7 n

Benzene, chloro-

5.

•34 35 971 1 i iTn fm 1 1 i i i 1 1 1 l"iT| i 1 1 . i u n i80 90 100 11

31 rain.112bt

-r On

<SCI9CI> Scan 108830 .00 min ,

7748 ^ 56 61 72

~~- , ii . . , ' , . .<' . """--: , , , ,50 60 70

84 35 97 108I . ~~" f*l : . *-" . ^"" - -

'' L.

|• ' i Ln

SO 90 100 110

Benzoyl chloride <DOTX8CI9CI> Scan 4580.

10500 min.

, 77 /

j 3740

5143 '' 57 62 72

50 60 70

/79 86 96 97 :1/11 L

80 90 100 110

f/7

1. Benzene, chloro- C8CI9CI) 112 C6H5C12. Benzoyl chloride (DOT)C8CI9CI) 140 C7H5C10

Sample file: >D7745 Spectrum #: 259Search speed: 1 Tilting option: S No. 'of ion ranges searched: 55

Prob. CAS # CON # .ROOT K DK #FLG TILT % CON C_I R_IU

1. 86* 108907 10883 "BIGDB 75 19 1 2 36 9 59 722. 24 98884 458 "BIGDB 67 28 2 0 86 55 7 23

CORRECTED TOTAL ION AREA OF UNKNOWN = 858283CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 481684CONCENTRATION OF INTERNAL STD = 40UG/L DILUTION FACTOR - 1SEMI QUANT ITAT I ON OF UNKNOWN = 71UG/L

File >07745 91LCBpk flb 66512.

j 37 50o iTT,.,,, ,*;

^ 40

Mle VBISDBBpk flb 9999 .

; 37 50

O ^ i ' i ' i ' i - i - , ,40


I ? 5°nJ.,.i,i.|. ...

40

File >BI3DBBpk flb 9999.

39

1 ' ™J...

40

551-8 lOOOxlML EXT ill/SUB

54/ 10S

82 ^61 70 72 / 98 IOO

H-4-- 'i'i i'1-i i rV'i i' i ' -^ 'i i i i i i i~n fTi i TI i i i i i • i -

22.' Scan 4627 .92 rain .

,

i2<;/.Ln

50 60 70 SO 90 100 110 120

2,5-Cyclohexadiene-l,4-dione < 9C I )

5,4 - 10S32

61 69 73 / 98~"i . 1 ! ,..,{,,. > . . ? . . . .. ""- , :"-

Scan 8110 .00 min .

.

110 f-—— Ln

50 60 70 ' 30 90' ' ' 100 ' ' ii6 ' ' 120

1 ,4-Benzenediamine <9CI.'>

30 • 52 // 63 65 78 91 93 105

^,111,... . .rrT...... , 1 .. ... .>.. .... ,! ,50 60 70 80 90 100 110

1,3-Butadiana <8CI9CI>54/

^ 56.Hi .,— -

Scan 50460 .00 min .

i

127 [, , , ,. ,..>0

120

Scan 7210 .00 min .

In50 60 -70 ' 'SO 90 100 110 120

1. 2,5-Cyclohexadiene-l,4-dione C9CI) 108 C6H4022. 1,4-Benzenediamine C9CI) 108 C6H8N23. 1,3-Butadiene (8CI9CI) 54 C4H6



1. 97* 106514 811 "BIGDB 96 17 0 0 82 0 72 . 972. 25* 106503 5046 "BIGDB 39 75 3 0 68 46 7 133. 25* 106990 721 "BIGDB 32 ' 71 3 0 100 48 7 13

CORRECTED TOTAL ION AREA OF UNKNOWN = 777163CORRECTED TOTAL ION AREA OF .INTERNAL STANDARD = 481684CONCENTRATION OF INTERNAL" STD = 40UG/L DILUTION FACTOR = 1SEMI QUANT ITAT ION OF UNKNOWN - 65UG/L

AR203095

File >D7745 91L3551-8 10QQ/:Bpk flb 5438. SUB

1 ?' « ? 6i_ " »"4 iii-iii' "'T 7i l i •'40 50 60 70

LML EXT ill/as/ Scar•3.93119

91 """"•

sn an 100 110 1

File >BI6DB Benzene, isocvanato- <9CI) S'c an ]Bpk flb 9999. ' 0.00

119

1 64 91] J38 44 51 62 ^ 74 77 88 / 103

40 ' 50 60 ' 70 ' ' "

i Si9mm.

t

20

L2128mm.

1SO 90 100 110 120

Fila >BIGDB IH-Benzo tr i azo 1 e tVflN8CI9CI> ScanBok flb 9999. 0.00

119_, 91 -~,

64 /; 38 52 62 --' 76

40 ' 50 ' 60 ' 70

File >BI5DB Benzene, azidBpk flb 9999.

64J38 ,, = , ,_ ^., 46 51 62 74 7r~ / ^ ^^ i

1 1 , 1 . . 1 . I I I . ^1 1 1 . >!...'

40 ' 50 ' 60 ' 70 '

2606min .

L80 90 100 110 120

o- <3C!9CI) Scan0.00

91119

7 83 .

2609min .

r. . j .... | .... | .... j ,...,.,. . | . . . . j . . . . |- . T 1 . ,

80 90 100 110 120

1. Benzene, isocyanato- (9CI) 119 C7H5NO2. IH-Benzotriazole (UAN8CI9CI) 119 C6H5N33. Benzene, azido- C8CI9CI) 119 C6H5N34. 2,1-Benzisoxazole (8CI9CI) 119 C7H5NO5. Benzoxazole (8CI9CI) 119 C7H5NO

Sample file: >D7745 Spectrum #: 559Search speed: 1 Tilting option: S No.of ion ranges searched: 56



CORRECTED TOTAL ION AREA OF UNKNOWN = 76872CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 481684CONCENTRATION OF INTERNAL STD = 40UG/L DILUTION FACTOR =flR 203 0 9*6SEMI QUANT I TAT ION OF UNKNOWN = 6UG/L

File >07745 91L3551-8 lOOO.-'lML EXT : 11/22.' Scan 610Bpk flb 3520.

1 39j }'41 43 46 51 54 6c

^ . 4 1 1 i l| M . /. M M M u . i M |SA 40 44 48 52 56 60

_File >BIQDB flnilineBpk flb 9999.

SUB 9.46 min.9366

6 '' 781 ' ' l" i64 68 72 76 80 84 88 92

CflCNXSCO Scan0.00

12785mm .

93J ' ' '

3 4 43 46 51 52 55 62 6.5 S 74 7673 86 91, , 'rT, .< --. .>,{..<

40 44 48 5£ 56 60, , 1 , . ^. , f, f . < . .>-, \

' '&* r'6s ' '72 r W r s'd ' 'sV ' 'ss ' 7sFile >BI6DB Si 1 anediamine . 1 ,1-dimethyl-N ,N '-diphenvl- <8CI9C ScanBck flb 9999. 0.00

F-i Q

2796mm .

93J _

^Q f,K b^5.941 43 4751 52 55 62 b° / 74 7678 83 91

,1 . ' : . . f . T^i { , 1 .' >

40 44 48 52 56 60! , . ! , . >..f.f ^..~>.l

64 68 72 76 80 34 88 92

File >BIGDB lH-Pyrazole-4-carboni tr i le <9CI) ScanBok flb 9999. 0.00

'fn °

£797min .

93

J^940 43 5052; iiV.r;,,,,,,',,', ,,,, , , , ,40 44 48 52 56 60

66

/.64 68 72 76 80 34 88 92

f

•to

1. Aniline (ACNXSCI) 93 C6H7N2. Silanediamine, 1/1-dimethy1-N,N'-dipheny1- CSCI9CI) 242 C14H18N2Si3. lH-Pyrazole-4-carbonitrile (9CI) 93 C4H3N34. Benzenamine, hydrochloride (9CI) 129 C6H8C1N5. Pyridine, 4-methyl- (9CI) 93 C6H7N

Sample file: >D7745 Spectrum #: 610Search speed: 1 Tilting option! S No. of ion ranges searched: 56

Prob. CAS # CON # ROOT K DK #FLG TILT % CON C_J ,R_IU

1. 86* 62533 2785 "BIGDB 74 16 1 0 100 19 50 832. 83 13435091 2796 "BIGDB 86 33 2 0 99 1 57 253. 63* 31108573 2797 "BIGDB 39 42 0 0 81 32 22 484. 43 142041 2789 "BIGDB 37 49 1 0 89 24 17 145. 41* 108894 2786 "BIGDB 62 47 1 -2 51 42 14 39

CORRECTED TOTAL ION AREA OF UNKNOWN - 83152 M&onr»rt«-,CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 481684 An__.Q3097CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR = 1SEMI QUANT I TATION OF UNKNOWN - 7UG/L

File >D7745 91LBpk flb 9057.

451000 Q-j

4 f

40

3551-8 1000/1ML EXT:ll/22/SUB

- - ? • * 3 ?V ",' / 127 156r '• """ii^n an 100 120 140 160

Scan10.70

185•— _180

729min.



CORRECTED TOTAL ION AREA OF UNKNOWN - 56480CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 481684CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR •SEMI QUANT I TAT ION OF UNKNOWN - 5UG/L

AR203098

FileBpk

t

>D7745 91L3551-8 1000/itlL EXT:ll/£2/flb 7071.

45

inJj t_.53X.

40

SUB

•5757 V 75 ^/ > /

'I'l'l i i i i 1 ! 1 ! I'i i ! i i r60 80

111 127

100 120

Scan10 .94

14/

140

752min.

£6L\ o



CORRECTED TOTAL ION AREA OF UNKNOWN = 52215CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 481684CONCENTRATION OF INTERNAL STD » 40UG/L DILUTION FACTOR •SEMI QUANT I TAT I ON OF UNKNOWN =- 4UG/L

&R203099

Fila >D7Bpk flb t

F ile .VBBpk flb '

'745 91L3551-S lOOO.'ltIL=937. SUB

39 43 53 54 63 66

1 1 l 1 i '1 i 1 i i i i | 1 1 i ir"i i i i i 1 i 1 ( i 1 i' i ! i 1 i i i i 1 i1 140 50 60 70

EXT: 11/22.' Scan 32711 .73 min .

106i

79 81 91 t

,1 .,.,, , , , , , , , , , , , , , , ^SO ?0 100

SDB Benzenamine, 4-methvl- <9CI) Scan 99253999. ' ' 0.00 min.

106

' t39 51 54 63 65 ' 7 39 t/ / s" i \. / \n...,- > -r i . i . , , Ln40 50 60 70

' • t ' ' • • 1 • * ' ' 1 ' ' ' • t • ' ' * 1 ' ' ' *,l ' • ' ~on an s nn 'WW - W J. W W

File ">BIi3DB Benzanamine, N-fnethvl- <9CI> Scan 10033Bpk flb 9999. ' 0.00 win.

106

1 - ' Fj 39 44 51 54 63 65 74 7/ 81 91 92 101 f

File >BBpk flb

J

40 50 60 70 80 90 100

IGDB Benzenamine, 3-methyl- (9CI> Scan 100399999. 0.00 min.

1061 b

39 44 53 63 65 74 77 81 89 92 [

40 ' 50 60 ' ' ' ' ' ' ' 70 ' ' ' ' '80 90 100

1. Benzenamine, 4-methyl- (9CI) 107 C7H9N2. Benzenamine, N-methyl- C9CI) 107 C7H9N3. Benzenamine, 3-methyl- C9CI) • 107 C7H9N4. Pyridine, 2-ethyl- (8CI9CI) 107 C7H9N5. Benzenamine, 2-methyl- (9CI) 107 C7H9N




CORRECTED TOTAL ION AREA OF UNKNOWN = 51854CORRECTED TOTAL ION AREA OF INTERNAL STANDARD =• 481684CONCENTRATION OF INTERNAL STD = 40UG/L DILUTION FACTOR =SEMI QUANT I TAT ION OF UNKNOWN = 4UG/L

File ..Q7745 91US551-3 lOOO.-'lML EXT:11'22' Scan 543Bpk Sb 26333. SUB . 12.93_nun.

LC t

•„ *5 go I t" I45 52 "4 .--• 73 >" 100 103 It

-,"rl),,C,r-,, M i l l , , , ,_^__, -in R n £.0 T n| .. ... .. ..I ' l ' l i | i l I ' l ' l 1 'I l il|''""i"' ' T-'-i i i | • i H,Q o Q n inn i i_ n 1 s n

_^i 1 e >BIGDB o-Chl oroan i 1 me ScanBpk flb. 9999 .. . 0 .0.0.

H1 39 50 52 64 £5

nJ.,_"' .. ,.,'T"1: -iC-, , l;+nC',.-,40 50 60 70

1C

73 36 ;2 99 102 110

SO 90 100 110 120

File xBISDB Pyridine, 2-chloro-3-me thvl - (9C!> ScanBok flb 9999. 0 .00

,Ln

mm.'u.

13480min .

91 1&7_i . _. J 3? 50 51 64 __-J,,l . . "~-,r . • ,/Til,

40 50 60 70

y J

73 1 97 120.•<" . 1 1 .'' { ,

30 90 100 110 120

File .^BI6DB Pyridine, 2-chloro-5-me thyl - C9CI> ScanBok flb 9999. 0.00

•5Q 65, 50 51 63_ -

„!. . ./.l.40 50 60 70

Is92 /

7^ <a«^ 1 . ../.

80 90 100 110 120

i_

r-^O

13479mm.7rr-U

1. o-Chloroani1ine 127C6H6C1N2. Pyridine, 2-chloro-3-methy 1- C9CI) 127 C6H6C1N3. Pyridine, 2-chloro-5-methy1- (9CI) 127 C6H6C1N4. m-Chloroani1ine 127 C6H6C1N5. Pyridine, 2-chloro-4-methy 1- C9CI) 127C6H6C1N

Sample f i l e : >D7745 Spectrum #:. 943Search speed: 1 Tilting option: S No. of ion ranges searched: 55


1. 83* 95512 13472 "BIGDB 74 24 2 2 92 7 54 542. 70* 18368768 13480 "BIGDB 34 79 3 0 95 6 42 133. 70* 18368644 13479 "BIGDB 70 39 2 0 79 19 32 504. 63* 108429 13473 "BIGDB 55 49 2 0 ' 85 19 30 325. 60* 3678624 13476 "BIGDB 46 58 3 0 84 11 30 13

CORRECTED TOTAL ION AREA OF UNKNOWN - 285564CORRECTED TOTAL ION AREA OF INTERNAL STANDARD =« 610720ZONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR =*SEMI QUANT I TAT I ON OF UNKNOWN - 19UG/L

File -D7745 91L3551-3 1QOQ''1I1L EXT:ll'-22/ ScanBpk flb 23560. SUB IS .18

_1 51 77 t411 J9 j' 65 -- 34 94 102 5 139 f" 152

40

File -BIGGBBpk Pb 9999.

~ e• ^ >.-j, r i.40

60 30 100 120 140 160

Banzena , l.l'-oxvbis- C9CO Scan c0.00If 0

1. 77 14165 -- 35 94 102 115 12<, 139 --- 154

. . ,,' .,. .... •',.•' . :' .,'. .. >Jl. '. ,1c n on -* r» n ion -i _i o •* -i 6'j «• 'j v a. •_< •*." __ i_ •' _, tr -J -u >-i W

File >BI'3DB Cl ,1 '-BiphenyU-3-ol <9CI> Scan iBok flb 9999 . 0.00

170

1\ 39 51 63 76 85 89 102 H5 122 139 ^41 152

-j --' •' / / ' -' l { '' "*-- • "-" i40 60 ' 30 ' 100 ' 120 ' 140 ' 160

File >BI6DB Quinaldon i tr i le , 3-hydroxy- C3CI) Scan c.Bpk Bb 9999. 0.00

170J U S 1 4 2 ^

50 64 70 38 89 * ""i. . ii. i"",. ..liT" ll. I,

40 60 ' 30 ' 100 ' 120 ' 140 ' 160

1447mm.

^MJ

0296mm.

-,MJ

.0298min .

i,'-Q

!0312min .

i, -0

1. Benzene, l,l'-oxybis- (9CI) 170 C12H1002. Cl,l'-Biphenyl]-3-ol (9CI) 170 C12H100J. Quinaldonitri le, 3-hydroxy- (8CI) 170 C10H6N204. Cl,l'-Biphenyl]-2-ol (9CI) '170 C12H100

Sample file: >D7745 Spectrum #'• 1447Search speed: 1 Tilting option: S No. of ion ranges searched: 56

Prob. CAS * CON # ROOT K DK #FLG TILT \ CON C_I R_IU

1. 71* 101848 20296 "BIGDB 59 47 2 0 96 13 38 362. 20* 580518 20298 "BIGDB 28 62 2 0 91 54 5 143. 20* 15462438 20312 "BIGDB 22 90 3 0 100 54 5 124. 15* 90437 20293 "BIGDB 42 49 1 1 33 56 3 17

CORRECTED TOTAL ION AREA-OF UNKNOWN - 313052CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 717994CONCENTRATION OF INTERNAL STD » 40UG/L DILUTION FACTOR - 1SEMI QUANT I TAT ION OF UNKNOWN - 17UG/L

AR203I02

File ?07745 91L3551-8 . 10Bpk Pb 59112.

-1 -q 65| / 51 \ •' ' 79

nJ.,1..,.,. ,.{.. ,,,l|. T"1' " I'

OOxlML EXTj 11/22.-- ScanSUB 13.4333' 106 165

107 120 _37 _33 _go

k 49 in an 10Q 120 140 1^0

FFile /BIGDB Carbamic acid, pheBpk flb 9999.

] 39 51 6^5 77 7g

nvl-, athvl ester OCl'J Scan 10 . Op_

?3 1t'.• 106

^ 120 137

1475mm.

9555mm.

!

1 n £ n o .-> -inri ion ^d.n ninTV Gw 0^ — wj ' J.llrf iTW — Orf

File >BIGDB Benzoic acid, 3-amBok flb 9999.

9_. 65 /

j 3? 5'2 " 74 30nj.,i...... ,.,-:. ...III. .',....'

ino-, ethyl ester <9CI> Scan 10.00

2 120/ ' 165

137106 109 " -.138 150

. --.,.-<" ..1. 1.-- f.

9557mm.

40 60 80 100 120 140 160

File '>BISDB flnilin«Bpk flb 9999.

J,o 662? 52 -_ 76 73

5 <flCNX3CI> 5can0.00

33

95

40 ' 60 ' 80 ' 100 ' 120 ' 140 ' 160

2785min.

r-0

1. Carbamic acid, phenyl-, ethyl ester C9CI) 165 C9H11N022. Benzoic acid, 3-amino-, ethyl ester (9CI) 165 C9H11N02J. A n i l i n e (ACNXSCI) 93 C6H7N4. Urea, N-nitroso-N-pheny1- (9CI) 165 C7H7N3025. Pyridine, 2-methyl- (9CI) 93 C6H7N

Sample file: >D7745 Spectrum #: 1475Search speed: 1 Tiltin g option: S No. of ion ranges searched: 56

Prob. CAS # CON # ROOT K DK #FLG TILT % CON C_I.R_IU

1. 93* 101995 19555 "BIGDB 101 11 1 4 66 0 68 892. 25* 582332 19557 "BIGDB 38 83 3 0 60 42 8 133. 21* 62533 2785 "BIGDB 55 35 1 -2 79 56 5 334. 20* 6268322 2954 "BIGDB 36 77 3 0 40 53 5 135. 20* 109068 2788 "BIGDB 28 79 3 0 100 55 5 13

CORRECTED TOTAL ION AREA OF UNKNOWN - 838611CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 717994 i D On o i n «CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR - H n & U ° ' ¥ «SEMI QUANT I TAT ION OF UNKNOWN - 47UG/L

File >07745 91L3551-8 1000.-Bpk flb 12577. SUE

• 1 39 51 65 ' ' 91 104i-JrrTT iTT ,.i'. . il. . '\,. ~~~~.l1 1 1 1 140

File .-8 I GOBBpk flb 9999

40

File >BI*DBBok flb 9999

rdr""40

File >BI6DBBpk flb 9999

t"o*iC--40

ItlL EXT !ll/-22/ Scan 1641) £0.21 mm.106^ . . 1 70

I . . ,i'i i. __. liLni . . . | . . . . i . . . . i . . . . | i . i i | . . i . | . i . i i . i i | i i . . | i i . i | . . . . | . . . . i . . . . |60 30 100 120 140 1-C' 130

Pyridme, 2-eU

I.1 65 ', 92 104"" / .' v_ ^___^

iyl- OCISCI) Scan 99170 .00 mm .

106--"

108 Cto

60 30 100 120 140 160 180

Benzenemetha

51 65 '/' 91 104

lamme ( CO Scan 100370 .00 mm.

106

108 fr — ^~~ . Ln

60 ' 30 ' 100 ' 120 ' 140 ' 160 ' 130

Bensenamma, 4

51 63 77 89 104

-methyl- <9CI> Scan 99250 .00 min .

106

108 [

60 80 100 120 140 160 180

1. Pyridine, 2-ethyl- C8CI9CI) 107 C7H9N2. Benzenemethanamine (9CI) 107 C7H9N3. Benzenamine, 4-methyl- (9CI) 107 C7H9N4. Benzenemethanamine, .aIpha.-me thy 1- (9CI) . 121 C8H11N5. Ethanol, 2-Cphenylamino)- (9CI) 137 C8H11NO


Prob. CAS # CON # ROOT K DK #FLG TILT H CON C_I R_IU

1. 40* 100710 9917 "BIGDB 58 36 2 0 82 46 12 412, 30* 100469 10037 "BIGDB 51 50 2 0 70 46 10 253. 25* 106490 9925 "BIGDB 34 52 1 0 71 48 7 184. 15* 98840 9935 "BIGDB 39 56 2 0 100 59 3 175. 15 122985 9961 "BIGDB 46 46 2 0 100 60 3 13

CORRECTED TOTAL ION AREA OF UNKNOWN - 174409 mono I nCORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 717994 AR CUJ I UCONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR * 1SEMI QUANT ITAT I ON OF UNKNOWN « 10UG/L

File >07745 91L3551-3 1000/lttLBpk flb £2534. SUB

J - - , Q < 339 62 ___.J 77 '<-_ 101 125

4'frrr •!•!• r l'l'r • ViV'tT • V" • • V <T- 'n • T'^ 40 60 80 100 120

"lie >BISOB Carbamic acid, < 4-ch 1 oroohenvBpk flb. 9999.

j 45 50 63 77 99^ 101 1£0

EXT:ll/22/ Scan 178621.72 mm.

127""" 1-*0 199 [-

153 171 "-- h

1^0 l^C1 ion 200

!>-, ethyl ester <9C Scan 242680 .00 min .

127 ^.-- 140 " k-

^ 153 171 tll il, r.'T" f,, • ,\ Ln

40 ' 60 ' SO ' 100 ' 120 ' 140

File >BI6DB Carbamic acid, <3-ch lorophenyBok flb 9999.

j 39 J? ^63 37 9_9 m 129

160 130 200

!>-, ethyl ester C9C Scan 243600 .00 min .

127 200"" 140 . -v. i.

"" 153 171 | f,1. . ,1. £ L JIlL

40 60 80 100 120 140

File >BISDB l-Naph thalenecarboxamide , NBpk flb 9999.

j 42 51 75 77 99 , ipl 125

,N-dimethyl1

139i. *"""

40 ' 60 ' " 30 " ' 100 ' 120 ' 140

160 ' ISO ' 200

- <9CO Scan 242520 .00 min .

55199 t"-. t

i. il. L)160 180 200

O'

1. Carbamic acid, (4-chloropheny1)-, ethyl ester (9CI) 199 C9H10C1N022. Carbamic acid, (3-chloropheny1)-, ethyl ester C9CI) 199 C9H10C1N023. 1-Naphthalenecarboxamide, N,N-dimethy 1- (9CI) .199 C13H13NO4. o-ChloroaniIine 127 C6H6C1N5. Acetamide, N-(4-chloropheny1)- C9CI) 169 C8H8C1NO

Sample file: >D7745 Spectrum #: 1786Search speed: 1 Til t i n g option: S No. of ion ranges searched: 56

Prob. CAS # CON * ROOT K DK #FLG TILT \ CON C_I R_IU

1. 86* 2621809 24268 "BIGDB 100 35 1 3 78 6 59 772. 79* 2150892 24360 "BIGDB 93 52 2 2 36 12 43 613. 26* 3815245 24252 "BIGDB 23 95 3 0 134 39 10 124. 21* 95512 13472 "BIGDB 56 42 1 -1 71 60 5 315. 20 539037 13548 "BIGDB 60 43 2 2 84 51 5 13

CORRECTED TOTAL ION AREA OF UNKNOWN = 347299 • d o ft n A c-CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 717994 AR £ U 3 I U 5:ONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR = 1SEMI QUANTITATION OF UNKNOWN - 19UG/L

File >07745 91L3551-8 1000/lttL EXT:11'"22-- Scan 2494m i

t

Bpk flb 3319. SUB c9 .10 mm.

65 77 91 ill 123139 154 147 ^' \ £44l i ' i t i f / s" i .1 --^

Illlj' ,,111,111, i| ll.| ,,1,11111.11111,1,1 ,, ,,,,11, | ,i|, L |iil|"|'''"i , , r l i , p, , i | , tl|h | , i |"

Fila >BIGDB 1-0ibenzofuranamin§ <9CIi Scan 22069Bpk flb 9999. 0.00 mm.

101 102 ll27 140 \54 166 135.—-, . , , . , , , , L Q

40 30 120 160 200 240

Fila >BIGDB Benzenamine, 4-iodo- <9CI> Scan 26713Bok flb 9999. 0.00 min.

21965 92

39 / 74 / 109 127 145 157 171 191 199, / . ./ -f / / / / s-

40 80 120 160 200 240

File >BISDB 2-Naphthilenamine, N-phenyl- (9CI> Scan 26712Bok flb 9999. 0.00 min.

219

63 77 89 115 127 140 153 165 191 204

80 120 160 200 ' 240

1. l-Dibenzofuranamine C9CI) 183 C12H9NO2. Benzenamine, 4-iodo- (9CI) 219 C6H6IN3. 2-Naphthalenamine, N-phenyl- (9CI) 219 C16H13N4. Benzenamine, 3-iodo- (9CI) 219 C6H6IN5. Quinoline, 6-methy1-2-pheny1- (8CI9CI) 219 C16H13N


Prob. CAS * CON * ROOT K DK #FLG TILT H CON C_I R_IU


CORRECTED TOTAL ION AREA OF UNKNOWN -' 181202CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 557557 ftR20 3 I 0CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR - 1SEMI QUANT I TAT ION OF UNKNOWN = 13UG/L

FFila .'07745 911.3551-8 IQOOxltIL EXT : 1.L-'Zc.-' Scan 2552| Bpk flb 21398. SUB 29.70 min.i 93

"i 1Bpk

F i lBok

Fi 1Bpk

Hj 39 51 i5 92_

O-J-C-"", ih ,1 • ••'['• • • i-l" - ~~~

119 120

40 rrO 80 100

s .-BIGD8 Uraflb 9999.

-jj 39 51 J»5 91

a, N ,N

93

1

40 SO. SO 100

a >BIbOB Urea, N,N'-diflb 9999 .

J39 51 65 92

120

137

140

'-diphanyl- \

-I9 120 135

120 1 Cl— TV

phenyl-N-< tri methyl

93

119 120 135y_.-i ,— ;; pi'- "i ••-,•'• |-"-i • j-' , , ,40 60 80 100

« >B1GDB fleeflb 9999.

1 43j / 51 ^56 92

120 140

tamide, N-phenyl- <93

135106 120

40 ' 60 ' 80 ' 100 '120 ' 140

167 £

i • i • t ' t ' t ' i ' t160 130 200

i,9CI; Scan 25917

0 .00 mm .

167 194 ^^

-i — ' — i — i — i — i — i — ' — i — ' — i — ' — r' ~ ni c n ^ o n '5 n n_ W V J. w V l_ ..' <S

s i l v l > - <9CI) Scan0.00

149 167 185 2^ / /

160 130 200

9CO Scan0.00

137- *•

160 ' 180 ' 200

25922min .

7780min .

1. Urea, N,N'-dipheny1- (9CI) 212 C13H12N202. Urea, N,N'-dipheny1-N-CtrimethyIsilyl)- (9CI) 284 C16H20N20Si3." Acetamide, N-phenyl- (9CI) 135 C8H9NO4. 2-Furancarbonitrile (9CI) 93 C5H3NO5. lH-Pyrazole-4-carbonitrile C9CI) 93C4H3N3


Prob. CAS # CON # ROOT K DK #FLG TILT H CON C__I R_IU

1. 88* 102078 25917 "BIGDB 70 39 2 0 92 5 65 502. 78 1154843 25922 "BIGDB 73 44 2 0 89 3 55 183. 52 103844 7780 "BIGDB 43 39 2 0 100 16 20 144. 43* 617903 2593 "BIGDB 25 32 2 0 81 25 17 145. 37* 31108573 2797 "BIGDB 35 46 3 0 100 29 14 14

CORRECTED TOTAL ION AREA OF UNKNOWN - 177691CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 557557 AR203I07CONCENTRATION OF INTERNAL STD = 40UG/L DILUTION FACTOR => 1SEMI QUANTITATION OF UNKNOWN =« 13UG/L


AR203I080

UUAN I Kt-KUK I

Uperator iu: HALUb Uuant Kev: 6 Uuant li m e : V11126 2U:23Uutput I - l i e : "C162U: : U2 Injected at: V11126 1V:^BUata l - i l e : >L162U::Ui D i l u t i o n I-act or: 2U.UUUUUName: y IL-.*1?1?!-*Mioc: 2I?UUL/'?"1L

1 U F i 1 e : 1UJJLL: : U Il i t i e : HH UUA Standards for ^ Point Calibration Curve Kev. hLast Calibration: V1111V 13:ia

Compound K.I. Scan* Area Cone Units q

1) *bromochloromethane B. 4V 1U4 2 61 ! "bU.OU ug/L //14) I rans-1 ,2-Uich 1 oroethene 1U.11 121? 11^83 2/b./l ug/L Vdlb ) Chloroform ' lU./"-5 133 4/"?6 b6.62 ug/L VU16J 1//-Uich Ioroethane-d4 11.42 142 ' 'J /U lUbb.b6 ug/L VV2U) Carbon I e t rach lor ide 1^.12 164 2-iUab 3/"_:.U4 ug/L y/2>J *l,4-Ui f luorobenzene IV. U6 241 ll1? !'? ^U.UU ug/L 6d26J I r ichloroethene 1^?.9/ 2U1 1-?UU 31.3D ug/L HB») *Lh lorobenzene-d^ 24.ua ^U6 VUa^?4 'JU.UU ug/L V336) let rach loroethene 21./6 2^6 91?29U 2366. la ug/L VV

) loluene-da 22. a4 2VU 134iy4 1UU2.1?/ ug/L avLhlorobenzene 24.23 30b 2242b 237.76 ug/L Vb

) bromof luorobenzene 2b.4U 362 b66/l V3^?.3/ ug/L V2

* Compound is IblO

AR203109

' ""'

TDTQI TON nF i 1 s C

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AR203I 100

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Data File: >C1620::D1 Quant Output File: C1620::02Name: 91L-3551-9flisc: 250UL/5MLQuant Time: 911126 20:23 Quant ID File: ID_UCC::QTInjected at: 911126 19:38 Last Calibration: 911119 13:18

Compound No: 1 (ISTD)Compound Name: BromochloromethaneScan Number: 104Retention Time: 8.49 min.Quant Ion: 128.0Area: 29612Concentrationf 50.00 ug/Lq-value: 77

AR203I!I

REFERENCE STflNOflRO SPECTRUMFilm >flBpk flb

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Data File: >C1620::D1 Quant Output File: /SC1620::02Name: 91L-3551-9Misc: 250UL/5MLQuant Time: 911126 20:23 Quant ID File: ID_VCC::QTInjected at: 911126 19:38 Last Calibration: 911119 13:18

Compound No: 14Compound Name: Trana-1,2-DichloroetheneScan Number: 125Retention Time: 10.11 min.Quant Ion: 96.0Area: 11383Concentration: 275.71 ug/Lq-value: 98

AR203I12

REFERENCE STBNDBRD SPECTRUMFilm "Bl&DB cniorofor* Scan 67663Bpk flb 9999. CLP FLT 0.00 »in.

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Data File: >C1620::01 Quant Output File: /NC1620::D2Name: 91L-3551-9disc: 250UL/5MLQuant Time: 911126 20:23 Quant ID File: IDJJCC::QTInjected at: 911126 19:38 Last Calibration: 911119 13:18

Compound No: 15Compound Name: ChloroformScan Number: 133Retention Time: 10.72 min.Quant Ion: 83.0Area: 4756Concentration: 56.62 ug/Lq-value: 90

AR203I13

REFERENCE STflNOflRD SPECTRUMFila >VXHSP HP VOfl No Spik* Internal Standards and Su Scan 332Bpk flb 100

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Data File: >C1620::D1 Quant Output File: AC1620::D2Name: 91L-3551-9Misc: 250UL/5MLQuant Time: 911126 20:23 Quant ID File: ID_yCC::QTInjected at: 911126 19:38 Last Calibration: 911119 13:18

Compound No: 16Compound Name: 1,2-OichIoroethane-d4Scan Number: 142Retention Time: 11.42 min.Quant Ion: 65.0Area: 53370Concentration: 1088.86 ug/Lq-value: 99

AR2031IU

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Data File: >C1620::01 Quant Output File: C1620::D2Name: 91L-3551-9Misc: 250UL/5MLQuant Time: 911126 20:23 Quant ID File: ID_UCC::QTInjected at: 911126 19:38 Last Calibration: 911119 13:18

Compound No: 20 'Compound Name: Carbon TotrachlorideScan Number: 164Retention Time: 13.12 min.Quant Ion: 117.0Area: 23088Concentrations 372.04 ug/Lq-value: 97

flR2Q3115

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^Data File: >C1620::D1 Quant Output File: /SC1620::D2Name: 91L-3551-9Misc: 250UL/5MLQuant Time: 911126 20:23 Quant ID File: ID_UCC::QTInjected at: 911126 19:38 Last Calibration: 911119 13:18

Compound No: 23 (ISTD)Compound Name: 1,4-DifluorobenzeneScan Number: 241Retention Time: 19.06 min.Quant Ion: 114.0Area: 115315Concentration: 50.00 ug/Lq-value: 68

AR203116

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Data File: >C1620::D1 Quant Output File: XSC1620::D2Name: 91L-3551-9Misc: 250UL/5MLQuant Time: 911126 20:23 Quant ID File: ID__UCC::QTInjected at: 911126 19:38 Last Calibration: 911119 13:18

Compound No: 26Compound Name: TrichloroetheneScan Number: 201Retention Time: 15.97 min.Quant Ion: 130.0Area: 1500Concentration: 31.30 ug/Lq-valua: 88

AR203I17

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Compound No: 33 (ISTD)Compound Name: Chlorobenzene-d5Scan Number: 306Retention Time: 24.08 min.Quant Ion: 117.0Area: 90854Concentration: 50.00 ug/Lq-value: 93

AR203I18

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REFERENCE STBNDflRO SPECTRUMFila "BISOB Ethana, tatrachloro-Bpk flb 100. FLT NRM NOM

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Data File: >C1620::D1 Quant Output File: /NC1620::D2Name: 91L-3551-9Misc: 250UL/5MLQuant Time: 911126 20:23 Quant ID File: ID_UCC::QTInjected at: 911126 19:38 Last Calibration: 911119 13:18

Compound No: 36Compound Name: TetrachloroathaneScan Number: 276Retention Time: 21.76 min.Quant Ion: 164.0Area: 95290Concentration: 2366.18 ug/Lq-value: 99

AR203I19

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Compound No: 39Compound Name: Toluen0-d8Scan Number: 290Retention Time: 22.84 min.Quant Ion: 98.0Area: 134194Concentration: 1002.57 ug/Lq-value: 89

AR203I20


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AR203I2I

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Data File: >C162Q::D1 Quant Output File: /NC1620::D2Name: 91L-3551-9Misc: 250UL/5MLQuant Time: 911126 20:23 Quant ID File: IDJJCC::QTInjected at: 911126 19:38 Last Calibration: 911119 13:18


AR203I22


SAMPLE NAME AND AMT: 91L-3551-9 250UL/5MLSAMPLE DATA FILE: >C1620

PEAK NO. RET. TIME SCAN AREA IDENTIFICATION1 8.56 105 224789 IS2 10.18 126 54235 TC3 10.72 133 13378 TC4 11.42 142 164318 SS5 13.12 164 79566 TC

6 15.97 201 9836 TC7 19.06 241 311561 IS

8 21.76 276 770297 TC9 22.84 290 390485 SS

10 24.08 306 415868 IS11 28.40 362 412591 SS12 34.88 446 1596790 UK


AR203I23

File >C1620 35.0-260.0 amu. 91L-3551-9 250UL/5MLTIC

60000-

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File >C1620 91L-3551-9 250UL/5ML ScBpk flb 9244. SUB 34.8

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File >BIGBpk flb 9S

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128 148

^ » o

1. Benzene, 1,4-dichloro- (9CI) 146C6H4C122. Benzene, 1,2-dichloro- (9CI) 146 C6H4C123. Benzene, 1,3-dichloro- (9CI) 146 C6H4C124. Peroxide, bis(dichlorobenzoyl) (9CI) 378 C14H6C1404

Sample file: >C1620 Spectrum #: 446Search speed: 1 Tilting option: S No. of ion ranges searched: 60

Prob. CAS # CON # ROOT K DK #FLG TILT % CON C_I R_IV


CORRECTED TOTAL ION AREA OF UNKNOWN = 1596790CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = . 415868JONCENTRATION OF INTERNAL STD = 50 ug/L DILUTION FACTOR - •p O?PQ I 95SEMI QUANTITATION OF UNKNOWN = 3800 ug/L MR£UU I c *

QUANT REPORT

Operator ID: LUELLA Quant Rev: 6 Quant Time: 911127 18:44'utput File: ~D7746::D2 Injected at: 911127 17:54ita File: >D7746::D3 Dilution Factor: 1.00000

Name: 91L3551-9Misc: 1000/1ML EXT:11/22/91 (RS0377)

ID File: ID__BAD::QTTitle: HP BNA Standards for 5 point Calibration Curve Rev. ELast Calibration: 911122 08:43

Compound R.T. Scan# Area Cone Units1) *d4-l,4-Dichlorobenzene 10.23 680 66246 40.00 UG/L5) Phenol-d6 9.69 628 3692 1.29 UG/L9) 1,3-Dichlorobenzene 10.10 668 61896 23.77 UG/L10) 1,4-Dichlorobenzene 10.28 685 360760 139.35 UG/L12) 1,2-Dichlorobenzene 10,85 740 1875629M 702.17 UG/L18) *d8-Naphthalene 14.05 1047 277806 40.00 UG/L19) Nitrobenzene-d5 12.02 852 140642 44.64 UG/L24) Benzoic Acid 13.83 1026 5328 2.68 UG/L27) 1,2,4-Trichlorobenzene 13.98 1040 11910 4.79 UG/L29) 4-Chloroaniline 14.51 1091 93478 28.13 UG/L33) *dlO-Acenaphthene 19.55 1575 '166346 40.00 UG/L38) 2-Fluorobiphenyl 17.59 1387 248259 45.25 UG/L54) *dlO-Phenanthrene 24.11 2013 291556 40.00 UG/L58) 2,4,6-Tribromophenol 22.07 1817 653M .86 UG/L66) *d!2-Chrysene 32.44 2813 165888 40.00 UG/L69) Terphenyl-dl4 29.32 2513 256131 46.62 UG/L73) Bis(2-Ethylhexyl)Phthalate 33.09 2875 21253 4.15 UG/Li) *d!2-Perylene 36.60 3212 99880 40.00 UG/L* Compound is ISTD

<Jt _ I /TOTflL ION CHROMflTOGRflMFile >07746

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400000-

200000-

0- 1 '4

35.0-508.0 amu. 91L3551-9 1300/1ML ETIC

, 1300 ( 2000 t 3800 ( _ | 4000

SM

4>

|

O

-P

a

I

!'

j

5i-1£

1" 1 s» jS.

-_{•=: 2

|| 11 pJJLj

f" 1 ? 1O TJ P

1 |1| }f|

| P ?

. _P , .. , If I . .' i • • i • i • i • i • i • i • i • i • i • i • i ' i • i • i • i • i • t •3 12 16 20 24 28 32 36 48 44

Data File: >D7746::D3 Quant Output File: AD7746::D2Name: 91L3551-9Misc: 1000/1ML EXT:11/22/91 (RS0377)

Id File: ID_BAD::QTTitle: HP BNA Standards for 5 point Calibration Curve Rev. ELast Calibration: 911122 08:43

Operator ID: LUELLAQuant Time: 911127 18:44Injected at: 911127 17:54

AR203I27

• - -

REFERENCE STflNDflRD SPECTRUMFiU >B7941 d4-l,4-Dichlorobenzene 910925 09:28 Scan 752Bpk flb 44024.

40000-•

' 40

0- I'l'l 1 |i'|'|40

52 56 64f / X ,Tl'h I'l'l'* i ! I ' l 1 J

60

SUB 10.89 min.150

78 115; .?7 \ ..,80 100

' -100

Ijli -flTl | 1 i i i | i i i i | i l 1 I' . -120 140

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7746 91L3551-9 1000/1MLBpk flb 36075. SUB40000-

'20000-

-


150

52 56 78 I15OQ f w^ / Q^ 99Jj8 ' / / f / V40 60 88 188

/.1

'

i il.

-188

:•a

128 148

SflMPLE SPECTRUM CUNRLTERED)File >D7746 91L3551-9 1000/1ML EXT:11 Scan 688Bpk flb 36296. 18.23 min.

15840008-

20008-.

0-

52 56 64 78 99 1«/ _x 87 v i.\z i .1 . ..^ .ii.'.. . ( . ^ . . I.i i .

/

i .1.

-190

'

L-a40 ' 60 ' 88 ' 108 ' 120 ' 148

Data File: >D7746::D3 Quant Output File: AD7746::D2Name: 91L3551-9Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 18:44 Quant ID File: ID_BAD::QTInjected at: 911127 17:54 Last Calibration: 911122 08:43Compound No: 1 (ISTD)Compound Name: d4-l,4-DichlorobenzeneScan Number: 680Retention Time: 10.23 min.Quant Ion: 152.0Area: 66246Concentration: 40.00 UG/Lq-value: 94

AR203I28


40000-

: 4/r0-1 1 1 j I /40

Phenol-d6

-- 49 54i . . i , i . i ] .i . . i i i . . i i i . i

50

910925 09:20SUB

58 66 ? ?2 81 82

1 ' i - i , M*i , | 1 1 1 {, • C' \60 70 80 90

Scan 69210.26 min.

99' -100

94

i 1 | i U +1-0108

SflMPLE SPECTRUM <BflCKGROUND SUBTRflCTED)File >D7746 91L3551-9 1000X1ML EXT:11 Scan 628Bpk flb 1243. SUB

100*.

g.41 ~ 54 66 ^X, | / ^

i 1 l 1 1 1

9.69 min.99

94,i

-100

•

f

. .L-a48 ' 58 ' 68 ' 78 ' 88 ' 98 ' 188

SflMPLE SPECTRUM <UNP,LTERED>File >DBpk flb

1000-

0

7746 91L3551-9 1000X1ML EXT:11 Sc<1243. 9.6<c

T"T 5/4 6 i "1 448 ' 58 ' 68 ' 78 ' 88 ' 98 ' 3

\!f\) n>9/

.ee

628in.

-100

•

Data File: >D7746::D3 Quant Output File: AD7746::D2Name: 91L3551-9Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 18:44 Quant ID File: ID_BAD::QTInjected at: 911127 17:54 Last Calibration: 911122 08:43Compound No: 5Compound Name: Phenol-d6Scan Number: 628Retention Time: 9.69 min.Quant Ion: 99.0Area: 3692Concentration: 1.29 UG/Lq-value: 75

AR203I29

REFERENCE STP.NDP.RD SPECTRUMFile >BBpk flb

"40000-

0-

7941 154340.

37

40

, 3-Dichlorobenzene 910925 09:20 ScSUB 10.7

1

75 lli

'| i'| i I'l'i i i i1!1 T. i HMV-n-r 1" i-TT'H-'l1! hrrr68 88 188 128 148

a64/

1

nn6

740in .

-100

•

SflMPLE SPECTRUM (BfiCKSROUND SUBTRflCTED)File >D7746Bpk flb 20688

20000-

• 37

frl'l i , .40

91L3551-9

50 55 63

Ji n .. r...... 6,Q. .....

1888X1MLSUB

f 85ill. id

80 108


146

111

...L.f -108

i •'• -0120 148

SflMPLE SPECTRUM CUNRLTERED)File >07746 91L3551-9 1888xlML EXT:11 Scan 668Bpk flb 28688. 18.18 min.

14628088-.

0-

75 1113? ? 55 « { 85 f.<r ..i, if .. / .a!. / ...L.

'

48 ' 60 ' 88 ' 188 ' 128 ' 148-i:

-188

-0' 1


AR203I30


"40000-

0-

7941 161248.

37

l'1'l i i i'l'40

,4-Dichlorobenzene 910925 09:20 SSUB 10

7* 11150 55 72 75 _, 108 / 128/ ./ x / 84 97 ^v /

60 ' 80 ' 108 ' 120 ' 140

Scan.93 m146*

756in .

-100•

.0

SflMPLE SPECTRUM (BflCKGROUND SUBTRflCTED)File >D7746 91L3551-9 1000/1MLBpk flb 101330. SUB

100000-

1 50 72 /5 109 137 / 55 7= f 95 9-188.rr: ..,..,!• ,<.,.. \iil,. .„<... ./. X,40' ' 68 ' 88 ' 188


146

11/ 128

" ^

i

-180

-a128 ' 148

SflMPLE SPECTRUM <UNP.LTERED>File >07746 91L3551-9Bpk flb 101568

100880-1••

8-. . , , , , ,37

.11. . ..i ..48

i

50/14

55 ?2^ N68

1000/1ML

75/ gg 18i

ill,. .,,<... ./. .>

88 ' 188


146"""

1111 f 128

i il.,.

-1081

••a

128 ' 148


AR203I3I

REFERENCE STflNDflRO SPECTRUMFile >BBpk flb

40000-

0-

7941 1,2-Dichlorobenzene52632. SUB

75 1J? ?8 5 « , 34 91 105

[ I I I . | . . i l l l . i i . l i , i l i i p . . . i l l Ullll i'1'l'i'n i i|i,i,.-.r ijljll40 60 80 100

910925 89:20 Sc11.4

1

11/

120

I'M. f i . . . , . ......120 140

a64f

r6m807in .

[-108•

.a

SflMPLE SPECTRUM <BflCKGROUNO SUBTRflCTED)File >D7746 91L3551-9 1888/1ML EXT:11 Scan 748Bpk flb 175873.

100009-

0-

i37

.It, . ..i40

SUB 10.85 min.146

53 63 7 97 99 V1/ 55 " < 84 _J9 128127.. ^ .i/ ....ill,. ..,<.,. />..r ...,,l, .L f.

t

\ ii.

rl00,•

•a68 ' 80' ' 100 ' 128 ' 148

SflMPLE SPECTRUM (UNflLTERED)File >07746 91L3551-9 1000/1ML EXT-.ll Scan 740Bpk flb 175873.

100000-

g.

18.85 min.146!

7« HI

*? 7 « 53 T M \7 J» ' iaai27.It. ... ..1

40,. i?T..../ ....ill.. ./,... .>../ .... ,1. ./.. / ,

68 ' 88 ' 188 ' 128 ' 148,.

-100

•

-a

Data File: >D7746::D3 Quant Output File: AD7746::D2Name: 91L3551-9Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 18:44 Quant ID File: ID_BAD::QTInjected at: 911127 17:54 Last Calibration: 911122 08:43Compound No: 12Compound Name: 1,2-DichlorobenzeneScan Number: 740Retention Time: 10.85 min.Quant Ion: 146.0Area: 1875629MConcentration: 702.17 UG/Lq-value: 94

AR203I32

REFERENCE STONDORD SPECTRUM - '* „File >B7941 d8-NaphthaleneBpk flb 35872. SUB

910925 09:20 Scan 112014.72 min.

136^

50080- gg: 42 54 68 v 38 100108

„' f / / \ r / '0-1. | I'i i . ! I'l40

i h ii i'Hf i ih'i'h ii H h ni n60 80 100

, , n 1 . 1 1

-188

138 ;Ir -«

128 148 168 188

SflMPLE SPECTRUM (BflCKSROUND SUBTRflCTED)File >D7746 91L3551-9 1888X1ML EXT:11 Scan 1847Bpk flb 112192. SUB 14.05 min.

136

100000

j42 54 68 78 y4 100 188

.../ .... .. ....i.i ,.,'. ,..<;.... . . /....i. ..,.1,

138 188

S \40 68 88 188 120 148 168 18C

-100

-8J


100000-

0-42 54 68

40 68

1000/1ML EXT: 11 Scan 1847

78 84,/•/88

iee«8100

14.05 min.136"

122/ ..,.1.

138 188,/ \.

-188

-a128 ' 140 ' 168 ' 188


Compound No: 18 (ISTD)Compound Name: d8-NaphthaleneScan Number: 1047Retention Time: 14.05 min.Quant Ion: 136.0Area: 277806Concentration: 40.00 UG/Lq-value: 86

UR203I33

REFERENCE STflNDflRD SPECTRUMFile >87941 Ni trobenzene-d5 910925 09:20 Scan 923Bpk flb 40856.

40000-

"

SUB82

54/

A *5 w VX

..I i . , , 1 1 L40

64 70 77

'l 1 | 1 I'l f'l'l I'l1! 1' - r rr-p-r-r . f . . . . - |-n- r- r -p-r r r r -, w

t

93 <, \ :12 .67 min .

181

/8 112{ i .

•100

-a60 30 108 120

SflMPLE SPECTRUM CBRCKGROUND SUBTRflCTED)File >D7746 91L3551-9 1088'IML EXT:11 Scan 852Bpk flb 52528.

40000-

0-4| 5*

. 1 , 1 . . . .40

SUB 12.0282

54 '

64 70 7g

min .

12S

8 112..1. f

68 ' 88 ' 188 ' 128

/

1

h!001

-0

SflMPLE SPECTRUM CUNP.LTERED)File >DBpk flb

40900-

0

7746 91L3551-9 100«52528.

S54

42 58 64 78 ?6

' !•!•!•" • |-l' -i . , i i i r|-. i-i-i p, . . . , . . . . , . . . . , . . . . , . . . ,

ixlML EXT:11 Sea12.82

32/

1

7 112i .. 1. f

48 68 88 188 128

n«

2!/

852tin .

hieei

-8

Data File: >D7746::D3 Quant Output File: AD7746::D2Name: 91L3551-9Misc: 1000/lML EXT:11/22/91 (RS0377)Quant Time: 911127 18:44 Quant ID File: ID_BAD::QTInjected at: 911127 17:54 Last Calibration: 911122 08:43

Compound No: 19Compound Name: Nitrobenzene-d5Scan Number: 852Retention Time: 12.02 min.Quant Ion: 82.0Area: 140642Concentration: 44.64 UG/Lq-value: 96

HR203I3U

REFERENCE STONDflRO SPECTRUMFile >DBpk flb

2000-

0-

7273 Benzoic flcid 9109261983. SUB

10577 "">•

5^- ™ ?

40 50 68 78 88 98 108

11:48 Sc14.1

118 126

an 153 m22/

lI

866in .

-100

-0

SflMPLE SPECTRUM (BflCKSROUND SUBTRflCTED)File >D7746 91L3551-9 1000/1ML EXT:11 Scan 1826Bpk flb 1230. SUB 13.83 min.

77 105j

1000-

gj

/ "51

38 jn , ll i

122/

i

-100

.

-a40 58 60 70 80 90 100 110 120

SflMPLE SPECTRUM <UNflLTERED>File >0Bpk flb

1308-

j

7746 91L3551-9 11230.

51

n33, ll

888X1ML'7 105( ^

i

EXT: 11 Scan 113.83 n

122

i48 58 68 78 88 98 188 118 128

026in .

•108

•8


Compound No: 24Compound Name: Benzoic AcidScan Number: 1026Retention Time: 13.83 min.Quant Ion: 105.0Area: 5328Concentration: 2.68 UG/Lq-value: 86

AR203I35

REFERENCE STflNOflRD SPECTRUMFile >B7941 1,2,4-Trichlorobenzene 918925 09:20 Scan 1112Bpk flb 40064. SUB 14.63 min.

13040000-

0-

37 J30 61 74

/

QA 105 109 I.45J^4 x / 122 ±33 i

-100

in -a40 60 30 100 120 140 160 180

SflMPLE SPECTRUM <BflCK8ROUND SUBTRflCTED)File >D7746 91L3551-9 1000X1MLBpk flb 4961. SUB

.4000-

0-

EXT:11 Scan 104813.98 min.

188f

A-I 74 109 14537 50 6/ / 84 97 /-** _ * / 1 j

.In Id n , ill) It i { . In48 68 88 188 128 148

,1, 1 1

rl88.,

•a168 188

SflMPLE SPECTRUM (UNflLTERED)File >D7746Bpk flb 4961

.

4008-- 37

>4I0I

91L3551-9

£.1 745* 61n,,, r .ili, ir ,

60 ' 80 '

1000X1ML

109 197 / 122f ..Li /100 ' 120 ' 140

• EXT:11 Scan 184013.98 min.

180' [-100

45

,1, nl .g' 160 ' 188


Compound No: 27Compound Name: 1,2,4-TrichlorobenzeneScan Number: 1040Retention Time: 13.98 min.Quant Ion: 180.0Area: 11910Concentration: 4.79 UG/Lq-value: 95

AR203I36


'40000-

0-

7941 4-Chloroaniline 910550520. SUB

1

65

' /2 l 7i / ' * ^} 2''I'l'l j'l'irl'lM I'l'l'j-l |'.'l'l I l l l ' V l f ' 1 .'I'M', M p. M| Ml'40 60 88 108 120

>25 09:28 Scan 115.13 «

27/

162

il,,,,,,,,,,,,,,,\140 160

168in .

L100

.a

SflMPLE SPECTRUM (BflCKGROUNO SUBTRflCTED)File >D7746 91L3551-9Bpk flb 25176.

.20000- 6g

-39 52 ^| 7pi_ nlii .1 . ,ni . .nllli,

40 68

'3 7S,X

30

1000/1MLSUB

/2r in. ...i, ,i,, *100 128

EXT:11 Scan 109114.51 min.

127'"" H1001

136 !

1 • • -a140 168

SflMPLE SPECTRUM (UNflLTERED)File >D7746 91L3551-9 1888/1ML EXT:11Bpk flb 25176.

.

20000-

-g_

39/

40

6552 ^ 73

l. ,,n, .illlli. ^

68

76 92s /

I,,./ . .,,1..._...,..

127-*'

1/00 111,1,, /

136

i . f188 ' 128 ' 148

Scan 189114.51 min.

-188

•-a

r 168


Compound No: 29Compound Name: 4-ChloroanilineScan Number: 1091Retention Time: 14.51 min.Quant Ion: 127.0Area: 93478Concentration: 28.13 U6/Lq-value: 98

AR203I37

'.t x

REFERENCE STflNDflRD SPECTRUMFile >B7941 d!0-flcenaphthene 910925 09:20 Scan 1651Bpk flb 44088. SUB 28.24 min.

16440000-

.

GW

42 54 66 { 92 10 1 12g 132 138 s.1

•

1 1,

-100

.a40 60 80 100 120 148 168

SflMPLE SPECTRUM (BflCKSROUND SUBTRflCTED)File >D7746 91L3551-9 1000/1ML EXT:11 Scan 1575Bpk flb 66552. SUB 19.55 min.

164_

40000- 42 54 66 7* */* ,90 100 I08 Ig8 13g 146 1M...<.. ...L. .7l.,.. A,,,l. ' . L .::.<.. . . (.. ./,., X >!.!,

"V*

1 1 1.

-188

-a8-,-,..,.,.,,,, | , , , , | , , , , , , , , , , , , , , , , , , , , , , , , , , , , , | ,. , -r-r-rr-r-i r, r, , , n ,•,----,48 68 88 188 128 148 168

SflMPLE SPECTRUM <UNflLTERED)File >D7746 91L3551-9 1000/1ML EXT:11 Scan 1575Bpk flb 66552. 19.55 min.

164—

40809- _. .,_. 76 80 log 14642 54 66 . / 90 10e i?e 122 133 i^» 156 1

s

1 1,

-188

-a8J, , , , , , | , , , , | , , , , , , , , , | , , , , | , , , , | , , , , | , , , , , . , , , , . . . , | , , , . | . . . . , . . . -40 68 88 188 128 148 168

Data File: >D7746::D3 Quant Output File: AD7746::D2Name: 91L3551-9Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 18:44 Quant ID File: ID_BAD::QTInjected at: 911127 17:54 Last Calibration: 911122 08:43Compound No: 33 (ISTD)Compound Name: dlO-AcenaphtheneScan Number: 1575Retention Time: 19.55 min.Quant Ion: 164.0Area: 166346Concentration: 40.00 UG/Lq-value: 90

AR203I38


100000-

; 39^ /a-1'!'! i h i'40

2-Fluor ob ipheny 1.

51 63 76 85/ / / /

'|'i i I'l'i'i'i'i I'l'i'i'i'i yi'i'l'i'i i'60 30

SUB

94, 187 128

I'l iM'i .'v.'iv.'.i-i'ivi100 120

910925 09:20

133 146\ X1/51

140 1

Scan 145918 .24 min .

172/

168 ;1 ii I'l'PPt'ir L060

SflMPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)File >D7746 91L3551-9Bpk flb 102808.

100000-

J 7 "48

63 75 85

68 """ 38 '

1888/1MLSUB

13399 187 128 N

•irnvrriTiv.T|rr»v,Vi188 128

EXT :11 Scan 138717.59 min.

172' -180

"' 1=1 "• . :.\ .„•;. .. N.ll,. ._,148 160

SflMPLE SPECTRUM <UNflLTERED)File >D7746 91L3551-9Bpk flb 182888.

188888-

: ™ 5148

63 75 85. ....i. ...... .UK....... i>...68 ' 80 '

1000^1ML

13399 187 120 v

188 128

EXT:11 Scan 138717.59 min.

172' -188

146 168

..•X..>if -148 168


Compound No: 38Compound Name: 2-FluorobiphenylScan Number: 1387Retention Time: 17.59 min.Quant Ion: 172.0Area: 248259Concentration: 45.25 UG/Lq-value: 93

AR203I39


50000-

42/

40

dl0-Phenant.hr ene

52 66 80 94

1 M | I'l'f 1 | 1 I'l'l | 1 1 I'l'f 1 1 i l ( i i i i ! ,

SUB

100 118 1

60 80 100 120

910925 09:20 Scan 209124.82 min.

183/

ii | I'M i | 1 i ii |'l I'l'f '['i 1 1 1 |iil'l'fl'Wl|i-»1.

-1881

-i-a148 168 180

SflMPLE SPECTRUM (BflCKGROUNO SUBTRflCTED)FileBpk

>D7746flb 99300

100000-

•

•42/

48"'

91L3551-9•

52/

60

66/

88/

,1,80

1888/-1MLSUB

94 188 118 132 I'y x_ 1 .X

if1, l i . i . 1 iTij.-i.i-i i i lijiTi i | i i V i108 128 140

EXT:11 Scan 201324 .11 min .

5? 160X \\168

188X. |188

188

,|

/

!..

-188

'

SflMPLE SPECTRUM CUNflLTERED)File >D7746 91L3551-9Bpk flb 99800.

100880-

. 42 6,6

48 68 88

1000/1ML

94 188 118 132 , 156„' / \ X136'^

. 1 . . . . | . . . . | . , . . | , , . . j , , . . | . . . . | ,

188 128 148

EXT:11

' 168 1'

168

Scan 281324.11 min.

188

38

/ -188

.

188

Data File: >D7746::D3 Quant Output File: AD7746::D2Name: 91L3551-9Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 18:44 Quant ID File: ID_BAD::QTInjected at: 911127 17:54 Last Calibration: 911122 08:43Compound No: 54 (ISTD)Compound Name: dlO-PhenanthreneScan Number: 2013Retention Time: 24.11 min.Quant Ion: 188.0Area: 291556Concentration: 40.00 UG/Lq-value: 99"

HB2031UO


20000-

;,-: (u^ Y * "* r *40

2, 4, 6-TribromophenolSUB

-2 91 111 VS72 19X7 220/ / y ^. \ -*•'M v t +• •• ikf v •• '*' • f " ri i | i . i | . i . | . ii | i . i | 1 1 1 | M 1 | 1 1

80 120 160 230

910925

222 250

nd | ,'K |240

09:20 Scan 189222.75 min.

330

""ll ~190

303 | L '...'• Ipl :3280 320

SflMPLE SPECTRUM (BflCKGROUNO SUBTRflCTED)FiBp

le >D7746 91L3551-9k flb 483.

62

400- 1sd "nil. , rlli i

40 ' 80

1008/1MLSUB

106 141

I120 168 200 240

EXT:11 Scan 181722.07 min.

332*->. -100

iU280 320

SflMPLE SPECTRUM <UNflLTERED)File >D7746 91L3551-9 1000/1ML EXT:11 Scan 1817Bpk flb 483. 22.07 min.

41 3?2

400-

J

y

\93 186 141ii 1 1 fi i i

40 ' 80 128 ' 168 ' 208 ' 248 ' 288 ' 328

•

uData File: >D7746::D3 Quant Output File: AD7746::D2Name: 91L3551-9Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 18:44 Quant ID File: ID_BAD::QTinjected at: 911127 17:54 Last Calibration: 911122 08:43Compound No: 58Compound Name: 2,4,6-TribromophenolScan Number: 1817Retention Time: 22.07 min.Quant Ion: 330.0Area: 653MConcentration: .86 UG/L

AR203IU

'Jtw JREFERENCE STflNDflRO SPECTRUMFile >B7941Bpk flb 75899.

50000-52

Q"1!'' f"' 140

d!2-Chrysene

66 78 10..,. | v"|' ,-f"l"H'

80

SUB

120 126 154 170

^ / \ \120 160

910925

182 ?4

200

09:20 Scan 289533.18 min.

240"" -100

212 J41 :H|in |ii, 1 1 niiniiuni ii , ,1.11 1 •-_!

240

SflMPLE SPECTRUM <BflCK6ROUND SUBTRACTED)File >D7746Bpk flb 58688

.

40000-- 42

40

91L3551-9.

«6 V-Ll IJ

80

120

..ji. .128

1888/1MLSUB

138 "X1" 188168

EXT:11 Scan 281332.44 min.

248* *

/4 212241

-100•

-a200 240

SflMPLE SPECTRUM <UNflLTERED>File >D7746Bpk flb 50688

.

40888-J 42

48

91L3551-99

/' \,18i ... i ... i .

128

..Jl. .128

1008/1ML

156 1?8.LOG NV V 4.OO

168

EXT:11 Scan 281332.44 min.

2481 T108•

i*4 2i2 h41 :.r. ...../ . .jJiilL .288 248


Compound No: 66 (ISTD)Compound Name: d!2-ChryseneScan Number: 2813Retention Time: 32.44 min.Quant Ion: 240.0Area: 165888Concentration: 40.00 UG/Lq-value: 89

AR203IU2


100000-

• 54

•40

Terpheny l-d!4SUB

910925 09:20 Scan 259130.02 min.

244^

66 88 94 2* ?*™ ^198^18 ^yi. [ i|i.ii|mi|i.i|iii|iii[if ii|iH|. i l , |i.yl| ,,. , ,|M|, .......... ...... ..... ....l... ..... .......l.il

III •'••! V"| 1 f 1 FT1 I"I"T"

-100

"080 120 160 200 240

SflMPLE SPECTRUM <BflCK6ROUNO SUBTRflCTED)File >D7746Bpk flb 89091

50000- 54\

40

91L3551-9

66 88 94

88

1808/1ML EXT illSUB

4 90 -i <oc •) qo186 J 22 "6 168 174 1;" 212

128 160 200

Scan 251329.32 min.

244"-X

226.{. . ..,,1.1-1.

-100

.a240

SflMPLE SPECTRUM <UNflLTERED)File >D7746 91L3551-9 1000/1MLBpk flb 89272.

5900* 5 66 80 94 86 "6 160 i?4 :fr . .. ..,.. . ..f. . . ...L... .. ../... . J ...... . _ 1 ..... .... . ....!_. ...f. ....

48 88 128 160

EXT:11

O O^ 1288

Scan 251329.32 min.

244"""I -188

226 ;

248

Data File: >D7746::D3 Quant Output File: AD7746::D2Name: 91L3551-9Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 18:44 Quant ID File: ID_BAD::QTInjected at: 911127 17:54 Last Calibration: 911122 08:43Compound No: 69Compound Name: Terphenyl-d!4Scan Number: 2513Retention Time: 29.32 min.Quant Ion: 244.0Area: 256131Concentration: 46.62 UG/Lq-value: 91

AR203U3


—

40000 57

i ,1.1, rjil.i ' ' ' i40

B is<2-E thy lhexyl>Ph thai ateSUB

149^

71 fi- 113 132o o .LAO

..JL .. ..J.. ... 1. ,L -i.. ,u, ,,,„, „.,

167

L ,. I.f 1 1 } 1 t 1 | t 1 1 | 1 1 1 | 1 i r [ . i i |80 128 168

910925 09:20 Scan 295233.77 min.

-100

261 279 :, \ 1. ' g

200 240 280


10000-

5000-

0- r -, .

57--_JJ48

91L3551-9

71*• /J ..ill ,.

8

83 113/ "*-.i, i.

1211 (128

1800/1MLSUB

149^

167

, 1160

EXT:11 Scan 287533.89 min.

279i

-180

,

-a208 240 280

SflMPLE SPECTRUM <UNflLTERED>File >D7746Bpk flb 982118888-,

5888-

0.

57

JJ48

91L3551-9 1888/1ML.149^

_. ^ 83 113 121,,i ..i.._r r^i / .167

, |. | ... | ... | ... | ... | ... | ... g

88 128 168

EXTsll Scan 287533.89 min.

279^

-188

,

-0200 ' 248 ' 288

Data File: >D7746::D3 Quant Output File: AD7746::D2Name: 91L3551-9Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 18:44 Quant ID File: ID__BAD::QTInjected at: 911127 17:54 Last Calibration: 911122 08:43

Compound No: 73Compound Name: Bis(2-Ethylhexyl)PhthalateScan Number: 2875Retention Time: 33.09 min.Quant Ion: 149.0Area: 21253Concentration: 4.15 UG/Lq-value: 97

AR203UU


80000-1

40000- 42

40

d!2-Perylene

114 13266 90 v •--_

80 120

SUB

156

160

910925

188 20^

' 1 ' i * 1 ''"' i'l280

09:28 Scan 329337.32 min.

264" -108

232 -i 'I'M" | i i i'"|" S-I-T -0240 280


-20000- •1 -53

? M ••"<. |

40 30 120

1000/'1MLSUB

156 188

168

„

204 208\x200

EXT:11

232 2</240

Scan 321236.68 min.

264

50

"il

*<*•

i .

-100'

-a" ' 280"


-20008-

0.

1 'ao55 114 x fv 66 88 < ^

48 88 128

1000/1ML

156 188 20N4 ;

' 168 ' 288

EXT:11 Scan 321236 .68 min .

264•""* (-188

•

07 232 2tt :•lt'i'v ,,,,'+ '., f-8

248 288

Data File: >D7746::D3 Quant Output File: AD7746::D2Name: 91L3551-9Misc: 1000/1ML EXT:11/22/91 (RS0377)Quant Time: 911127 18:44 Quant ID File: ID_BAD::QTInjected at: 911127 17:54 Last Calibration: 911122 08:43Compound No: 75 (ISTD)Compound Name: d!2-PeryleneScan Number: 3212Retention Time: 36.60 min.Quant Ion: 264.0Area: 99880Concentration: 40.00 UG/Lq-value: 86

AR203U5

SAMPLE INTEGRATION SUMMARY•x <_• ..

SAMPLE NAME AND AMT: 91L3551-9 1000/1MLSAMPLE DATA FILE: >07746

PEAK NO. RET. TIME SCRN nPEA I DENT IFICttTI ON1 4.77 156 2006516 UK2 5.92 ' 257 1653470 UK3 7.98 464 1449877 UK4 8.18 483 63922 , UK5 8.36 501 65565 UK6 3.61 525 82071 UK7 a.97 559 77081 UK8 9.50 610 80081 UK9 10.11 669 257120 TC10 10.28 685 2018561 TC11 10.35 740 4189212 TC12 10.98 752 454767 UK13 11.01 755 120646 UK14 12.02 852 464377 SS15 12.97 943 113947 UK16 13.98 1040 52808 TC17 14.05 1047 628578 IS18 14.51 1091 393051 ' TC

19 17.14 1344 328519 UK20 17.59 1387 811730 SS21 17.82 1409 435593 UK22 18.24 1449 1804589 UK23 18.51 1475 631375 UK24 19.55 1575 787769 IS25 20.25 1642 83803 UK26 20.56 1672 94387 UK27 21.75 1786 213591 UK

28 23.79 1982 7750829 24.11 2013 793509 IS30 27.18 2307 57957

31 29.13 2495 161789 UK32 29.32 2513 751610 SS33 29.74 2553 145126 UK34 32.44 2813 523284 IS35 33.10 2876 78135 TC

36 36.60 3212 286206 IS

IS =• INTERNAL STANDARDSS - SURROGATETC - 'TARGET COMPOUNDUK - UNKNOWN

=• UNKNOWN LESS THEN 10JS' OF INTERNAL ST it 6

File . 07746 35.0-500.0 amu. 31L3551-9 IQOO.-'IML EXTsTIC

. . . . . . . . 100°11

300000-

.•

k '00000-1 ;'6 00 0,0 0-

•

c n n n n ri

"

400000

.

SOOOOfr•

.200000

100000-

3

11C

3O

1

1

:

*«UtLi

2

,

221

cC

17

14

3X1I

14 8 12

C

11.8

1

£4

3

2000. i . . . . i . . .

29 32i

27

26|

• i • i ' f •16 20

8«__*

30 3

i J i i

3000 4000. i . . . . i . . . . itt"100

34

3

| ,' I ' f ' ! ' I T 1

36

f5 11 1.

-90

-80

-70*

;60

'-5Q

-40

-30

:£0

-10

In' i ' 1 ' t ' I ' 1 ' i '

24 28 32 36 40 44

:o

AR203U7

FiU ,'07746 91L3551-? 1000/lflL EXT :li/-22/ Sea.;-, 156Bpk fib 84963. SUB 4.77 min.

166129 131

! ~ " \ ,'•'" ,j-° /1 i i'i i . I I I , i i i |l|l| I'V i 1 S i i i i I'l". . i .

ii*

117I'M , , i , . - , , - , . , , , J.U

40 60 90 100 120 140

File VBIGOB Ethen«, tetrachloro- <9CI> Scan 19848Bpk Rb 9999. 0.00 min.

166

1 47 49 59 82 9.4 117 " ^

40 60 30 ICO 150 140 160

File 'BIGDB Benzene, C <2-t:hloro-2-propeny 1 >o.xy]- <9CI) Scan 14421Bpk flb 9999. 0.00 min.

133

39

.ill.....

51

..„(...,...

65

i l l

77

ll.r79

^— "

7 1......,.i,

05

M...ilS 125 1 141 153

16S

...L40 60 80 100 120 140 160

1. Ethene, tetrachloro- (9CI) 164 C2C142. Benzene, C(2-chloro-2-propeny1)oxy]- C9CI) 168 C9H9C10



1. 93* 127184 19848 "BIGDB 77 45 0' 0 91 11 64 932. 11* 53299539 14421 "BIGDB 22 104 3 0 80 63 2 12

CORRECTED TOTAL ION AREA OF UNKNOWN - 2006516CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 628578CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR - 1SEMI QUANT I TAT ION OF UNKNOWN = 130UG/L

AR203U8

File >07746 91L3551-9 lOOO^ltlL EXTillxSa/' Scan 257 IBpk fib 98264. SUB 5.32 'nin.|

77 11£ I51 ^ I

\ J8 43 '/ ?6 62 72o4 1 1 1 | i i i l | iTi 1 1 1 1 1 i f 1 1 i i 1 1 1 1 i p'i i i Ti"1' 1 1 \{

k 40 50 60 70

P^le >BIGDB Benzen*. chloro-Bpk flb 9999.

! '38 48 51 56 61 ?2

40 50 ' SO '' 70'"''

Fil« >BIGDB Banzovl chloride (Bpk flb 9999.

1 51j 37 43 / 57 ,52 72

40 50 60 70

34 86 97i • i iTn i m 1 1 , M n T^I . 1 1 1 ! i , i , 1 1 4an cin 100 110

CSCI9CI) Scan0 .00

11->7

34 35 97 108

on QQ 100 110

DOTX8CI9CI> Sea0.00

10577 • //

79 86 96 97 113

30 90 100 110

•Ifo

10833mm.£

t

' 0

n 458min .

i :r-n'OI

1. Benzene, chloro- (8CI9CI) 112 C6H5C12. Benzoyl chloride (DOT)(8CI9CI) 140 C7H5C10



1. 95* 108907 10883 "BIGDB 89 5 1 4 84 1 72 932. 31 98884 458 "BIGDB 62 33 2 0 87 45 12 22

CORRECTED TOTAL ION AREA OF UNKNOUN - 1653470. CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 628578CONCENTRATION OF INTERNAL STD ' 40UG/L DILUTION FACTOR * ISEMI QUANT ITAT ION OF UNKNOUN - 110UG/L

AR203U9

FiU /07746 91L3551-Bpk flb 111752.

J37 49- .M^v, ,'>!!

40 50


: 37 49^.rrT. --,,11

40 50

F i l a >8IGDBBok flb 9999.

39

J' «nJ.., .. ^ 1,40 50

FiU >B!GDBBpk flb 9999.

1 - 43 ',J...,,.'. ...,!40 50

-9 1000/1ML ESUB

54

82ol 70 72 / 97' ~-~ \ ~--~

• ' I ' l I ' l ' l 1 1 ' | ' 1 • 1 1 ' 1 ' \ - ' 1 1 1 | . ! I'l |

60 70 SO 90 10r

2,5-Cyclohexadien@-l,4-dione <9C54

3361 64 73 / 98

60 70 SO 90 10C

1,3-Butadiene <!8CI9CI>54

56

60 70 30 90 1Q<

1 ,4-Benzenediamine <9CI>

80

63 65 76 1 91 92 11 >..< -- , 1 '>-"• ' • ! i ' i ' i ' i ' i - i - i - i - i - i ' ! ' i ' i i - i - i ' i ' i i - i r

60 70 30 90 10

XT:ll/-£2/ Scan 4647 .98 mm ,

103 u126 \

—— Iri ———— L<>i 110 120

•) Scan 3110.00 mm .

103

JjLO f, , , - i-T ',-,-r---r-..'10? 110 120

Scan 7210.00 min.

———————— r^o3 110 120

Sc»n 50460 .00 min .

108

35 110 E

J 110 120

1. 2,5-Cyclohexadiene-l,4-dione (9CI) 108 C6H4022. 1,3-Butadiene (8CI9CI) 54 C4H6J. 1,4-Benzenediamine (9CI) 108 C6H8N24. 2-Butyne C8CI9CI) '54 C4H6


Prob. CAS # CON * ROOT K DK #FLG TILT K CON C_I R_IU

1. 89* 106514 811 "BIGDB 69 44 0 0 71 10 62 862. 25* 106990 721 "BIGDB 39 64 3 0 100 48 7 133. 25* 106503 5046 "BIGDB 39 75 3 0 59 46 7 134. 15* 503173 725 "BIGDB 30 36 2 0 68 57 3 15

CORRECTED TOTAL ION AREA OF UNKNOWN * 1449877CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 628578CONCENTRATION OF INTERNAL STD =» 40UG/L DILUTION FACTOR - 1SEMI QUANT ITATION OF UNKNOWN « 92UG/L

ftR203!50

F i l « ;-07746 91L3551-9 1000/lflL EXT : 11 '-££.•• Scan 483Bpk Ob 3091. SUB 3.13 min.

\ 41 54 55- / "--. .--' 77 32

I-LJ 1 1 ,il| 1 , ii """•; i .i'i_ 40 'T'O aO

FF i 1 e /BIGDB C » c 1 o o c t an e ,Bpk flb 9999. .

1 41 35 "-] ••' 53 •" 71 31

Ji.l.l. "v. ., ,, .-"- . . /.,,40 60 SO

.„„ Ill , f...o ,

1 ,-o100 120 140

eth'/l- v 9 C I > Scan 106340 .00 mm .i

111

38 97 104 118 128 140t / ' -"* / **"-»

t t 1 , "^

1

-n100 ' 120 ' 140

File '•'BIGDB Cyclohexane, 1-ethvl-l ,3-dims thvl- , cis- <9C!.'> Scan 10654Bpk flb 9999.

69

~ 41 _-•• / 53 77 3• \ '-- "-~. /,-Jl . 1 . 1 . . . . . . . . , i . : . . . . i . l . , . . . . . , .

40 .60 30

0.00 min.

Ill3 91 '?5 ' 125 126

f _.**' -.-•_ - - ———

t-•.

100 120 140

File ^BISDB Cyclohaxane, 1-a thy 1-2 ,3-dimethyl- <8CI> Scan 10693Bok flb 9999. 0.00 min.

69J 5 5 - • -

V- 53 71 *1 III ~""T 1 1 l 1 "^ . . [ I

40 60 80

111

3 91 97. 103 123 125 11°/...,/.. S? _ , , Ss-. . - " , {

:-o

100 120 140

1. Cyclooctane, ethyl- (9CI) 140 C10H202. Cyclohexane, 1-ethy 1-1,3-dimethyI-, cis- (9CI) 140 C10H203. Cyclohexane, 1-ethy 1-2,3-dimethy1- (SCI) 140 C10H204. Cyclohexane, 1-ethy 1-2,4-dimethy1- (9CI) 140 C10H205. Cyclohexane, 2-ethy 1-1,3-dimethy1- (8CI) 140 C10H20

Sample file: >D7746 Spectrum ft: 483Search speed: 1 Tilting option: S No. of ion ranges searched: 58

Prob. CAS # CON * ROOT K DK #FL6 TILT % CON C_I. R_IU

1. 27* 13152028 10694 "BIGDB 45 50 3 0 72 43 8 152. 26 62238317 10654 "BIGDB 44 45 2 0 77 44 8 143. 15* 7058051 10693 "BIGDB 34 67 3 0 57 59 3 134. 15* 61142696 10651 "BIGDB 25 65 3 0 ' 65 60 3 135. 15* 7045672 10692 "BIGDB 27 73 3 0 60 60 3 13

\CORRECTED TOTAL ION AREA OF UNKNOUN » 63922CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 628578CONCENTRATION OF INTERNAL STD = 40UG/L DILUTION FACTOR - A D OH^ i tSEMI QUANTISATION OF UNKNOWN =• 4UG/L A it t U 0 I 3 I

File ,-07746 91L3551-9 100Q/1ML EXT : llx££.' Scan 50llBpk flb 3482. SUB 3.36 m:n.'

55 07J4,1 6* M / t' 53

1 , " 11

~ .

l l . l , , , , . ,

S3

, , , ,,,,,l| , , , , , ,

/ 1111- ,., , , ! , , , ,..-, , , , , , , , , iO-JL

40 ' 60 ' fl'o ' 100 1£00

File .BIG08 Cy c 1 opan t»n« , 1 -rne thy 1 -3 — •: S-me thy 1 propy 1 > - <9CI.'< 'Scan 8350Spk Qb 9999. ' ' ' 0.00 mm.

• .551 '3,U-

53I I . , "M

- ""69

7 11 1 . . . , , i . 1 1 ;-^

83 9791

. n i,. . ' ,1' 105

/-i —— ,-w ——

112 123,', ""--

135 140--- -"-.

40

File >BI5DB 4-Nonene , 3-methyl-, <Z>- (9CI> Scan 3640Bok fib 9999. 0.00 min.

55

' ^1 l "i h •

"1 ?1ilir

/ 111f 140I:f:-n

40 60 ' SO 100 ' 120 ' 140

File :>BI6DB Cyclohexane, 1-raethy 1-2-propyI- <8CI9Cn Scan 8341Bpk flb 9999. 0.00 min.

55 97/

t1 53I.i >:.

6 71"

111/•

125 140

40 60 80 100 120 140

1. Cyclopentane, 1-methy1-3-C2-methyIpropy1)- C9CI) 140 C10H202. 4-Nonene, 3-methyl-, (Z)- (9CI) 140 C10H203. Cyclohexane, 1-methy1-2-propy1- (8CI9CD 140 C10H204. Cyclohexane, 1-methy1-3-(1-methylathy 1)- C9CI) ' 140 C10H205. Cyclopentane, 2-isopropy1-1,3-dimethy1- (SCI) 140 C10H20


Prob. CAS * CON # ROOT K DK #FLG TILT S CON C_I R_IU

1. 42* 29053041 8350 "BIGDB 28 84 3 0 100 21 17 132. 33* 63830693 3640 "BIGDB 57 44 2 -1 81 43 12 243. 27* 4291796' 8341 "BIGDB 27 62 3 0 80 37 10 134. 27* 16580248 8346 "BIGDB 26 61 3 0 100 39 10 135. 27* 32281859 8299 "BIGDB 29 81 3 0 100 37 10 13

CORRECTED TOTAL ION AREA OF UNKNOWN = 65565CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 628578CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTORSEMI QUANT I TAT I ON OF UNKNOUN =• 4UG/L - AR203IS20

File /07746 91L3551-9 10CX --ir!L EXT:11''2£/ ScanBpk flb 3273.

55-( i .-••1 V

525SUB 3.61 min.03

*9 1 9771 / HI 140

i i r" . i . i i i f ~~~~i~

-0__^ **• 0 60 Q0 100 120 140

W\ le ' BIGDB 5-Hepten-2-one , 4,6-dimethvl- -'3CI3CI ) Scan 5452repk Pb 9$99. Q.QO min.

4 Ji =3 y~UjI ' ' • . ' • ' T .

33*7 77 '/ qi 97 10 .11 122 125 140

, 1 , ' ~~"~ , , 1 , 1 , . , . . . , . . , i , ' 1.1 ~~~~~:

:-o

40 ' 60 ' SO ' 100 ' 120 ' ' 140

File >BH3DB 5-Hep ten-2-one , 4 , 6-diroe thvl - (8CI9CI) Scan 5452Bpk flb 9999.

43

1 ' „ '".J. l ' ^

0.00 min.

67 77 'J/ Ql 97 1071 11 122l£5 140( . -^ i . / f f "l { ---f.

40 60 30 100 120 140

File >9!@DB 3-Hexena, 2 ,2 ,5 ,5- ta trame thy 1- , (Z>- (3CI9CI) Scan 3700Bok flb 9999. 0.00 min.

71 55

1 53 "J, i,-,,,^, ,,.,,,,.,,,,,,,,,.,,,,,,,,,.,,,,,..,,..,,, .72 83

}- 91 9/ 109 110 123 __3-25 140 L40 60 80 100 120 140

1. 5-Hepten-2-one, 4,6-dimethy1- (8CI9CI) 140 C9H1602. 5-Hepten-2-one, 4,6-dimethy 1- (8CI9CI) 140 C9H160J. 3-Hexene, 2,2,5,5-1etramethy I-, (Z)- C8CI9CI) 140 C10H204. Cyclopentane, 2-isopropy1-1,3-dimethy1- C8CI) 140 C10H205. Cyclohexane, <2-methyIpropy1)- C9CI) 140 C10H20


Prob. CAS # CON # ROOT K DK #FL6 TILT S CON C_I R_IU

1. 15* 31162488 5452 "BIGDB 23 67 3 0 167 59 3 122. 15* 31162488 5452 "BIGDB 23 67 3 0 167 59 3 123. 15* 692477 3700 "BIGDB 30 75 J 0 47 60 3 134. 15* 32281859 8299 "BIGDB 32 78 3 0 60 58 3 135. 15* 1678984 5636 "BIGDB 28 75 2 0 62 59 3 14

CORRECTED TOTAL ION AREA OF UNKNOWN » 82071CORRECTED TOTAL ION AREA OF INTERNAL STANDARD =• 628578CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR - HR203I§3SEMI QUANT I TAT ION OF UNKNOWN - 5UG/L

FiUBpk

>07746 91L3551-9 1000/1111flb 4215. SUB

1 6439 44 J51 62 ' 71 76

nJll 1 i . .-^ \ i_._... i 1 , .-*•"*

EXT:ll/22/ Scan 5598 .97 ruin .119

91 x--. .

,Ln40 50 60 70 80 90 100 110

r i l *Bpk

>BISDB B«nzen«, isocyanato- <9CI; Scan 12128flb 9999. 0.00 mm.

119' 1 64 91 ^r: 3S 44 51 62 -^ 74 77 38 f 103 \

ru i'i ii . .<" . . "^ i ,', . . "> , , {. . T: , , , . '' Ln40 ' so ' s'o ' 70 ' s'o ' 9'6'"'"i6o '' 'iio

FilaBok

>BISDB • IH-Benzo tr iazolaflb 9999.

1 64j 38 52 62 S 76nJ i i . i . . i 7i I i ^

<VflN8CI9CI) Scan 26060 .00 min .119

91 '•-.,L40 ' 50 ' 60 70 ' 80 ' 90 ' 100 ' iio

File >BI5DB 2 ,1-BanzisoxazolBpk flb 9999.

-\ 64f 49 52 62 f 76

,-J 1 1 , , **-: . . '. "T; 1 1 , r^

a <SCI9CI) Scan 26070.00 min.

92 H^ L/ r

38 [T-. , . Ln

40 ' 50 ' 60 ' 70 ' 80 ' 90 ' 100 ' 110

.,*,- 7

1. Benzene, isocyanato- (9CI) 119 C7H5NO2. IH-Benzotriazole (UAN8CI9CI) 119 C6H5N33. 2,1-Benzisoxazole (8CI9CI) 119 C7H5NO4. Benzene, azido- (8CI9CI) 119 C6H5N35. Benzonitrile, 4-hydroxy- C9CI> 119 C7H5NO


Prob. CAS # CON # ROOT K DK #FLG TILT X CON C_I R_IU


CORRECTED TOTAL ION AREA OF UNKNOWN - 77081CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 628578CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR » AR 9fl T I 5 USEMI QUANT I TAT ION OF UNKNOWN - 5UG/L " ^

Fila ,>07746 91L3551-9Bpk Ab 6923.

J ,,j -/41 43 46 51 52

ol ( -- •' '-• '^' 1 1 1 1 1 1 | 'M'i M 1 1 1 •<in _t_i 43 R£" •

1000/-1ML EXT :ll'-22.'/ Scan 610SUB 9 .50 mm .

93

59 62''-? "' 37/ / i /

. | . i V | . \ I 1 | . ( . j i | . t , | i j , | , , , , 1 | i ] ,

rt~\ "

1, lie >8IGDB Si lanediaminc ,"Bpk flb 9999.

•

Jf,'941 _3 47 51 52:„;. • ; i-,:',,.' ,,,,•"";.„; ,

40 44 43 52

Fila >BISDBBpk flb 9999.

1 ,1-dimethvl-N , N ' -d i phenv 1 - C3CI9C Scan0.00

, _ & O

5R 62 °V -^ 74 7678 «8 91> , . ! . . > / .'' x- >

56 60 64 63 72 76 SO 34 SS- 92

fin i line < flCN> <3CI > Scan0.00

2796min.

-

1 -0

2785min.

93,

3940 43 46 51 52

'^! i ' i < i • 1 ' 1 • i • i ' i '40 44 48 52

55 62 6,5 s 74 7678 36 91/ ..>..!. > . .-'. ./. s. ..---.' I ' l ' i '•?-' rir~ "r"T' i ""-i ' F' rir i ' i ' i * i ' i ' i ' i '56 60 64 68 72 76 80 84 88 92

Fila >B!SOB lH-Pyrazole-4-carboni trile <9CI> ScanBpk flb 9999. 0.00

/ ,

f'-G

2797min .

93

: /940 43 5052

40 44 48 52

6664.

56 60 64 68 72 76 80 84 88 921

1. Silanediamine, 1,1-dimethy 1-N,N'-dipheny1- (8CI9CI) 242 C14H18N2Si2. Aniline (ACNH8CI) 93 C6H7N3. lH-Pyrazole-4-carbonitrile C9CI) 9J C4H3N34. Pyridine, 2-methyl- (9CI) • 93 C6H7N5. Pyridine, 3-methyl- (9CI) 93 C6H7N


Prob. CAS * CON # ROOT K DK #FLG TILT % CON C_I R_IU

1. 83 13435091 2796 "BIGDB 80 39 2 0 100 4 57 212. 73* 62533 2785 "BIGDB 69 21 2 0 100 21 32 603. 49* 31108573 2797 "BIGDB 34 47 0 0 72 33 20 334. 43* 109068 2788 "BIGDB 41 66 2 0. 69 22 17 145. 41* 108996 2787 "BIGDB 55 42 2 0 45 43 14 32

CORRECTED TOTAL ION AREA OF UNKNOWN =• 80081CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 628578CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR •SEMI QUANT ITAT I ON OF UNKNOWN = 5UG/L

EXT: 11/22'' Scan 755' 11.01 mm.

Fi 1Bpk

J..AI.57 *9 °/ ill 127 146 172/ [" 1 / t -""" - -.uiiyn., ., — , —— ! — , — ! — ,., T , ._! — , — ( — , — — , —— ! — , —— ! — , — ! — , — { — , — ; —— , — , — , —— j ,

40 6Q SO 100 120 1 d 0 1s- 0 180

e BI60B Butane, 1-rnathoxv- C9CI)flb 9999.

45r '^6 71 S3 39

_1O ^Q 'SO 1'in 1 3 n H.IO «£n ^ o n '•TV WW <_*«•• J. V V X L, V J. "f V J. O -f J. '-J W

.L200

Scan 3320 .00 rain .

L200

1. Butane, 1-methoxy- (9CI) 88 C5H120

Sample file : >D7746 . Spectrum #: 755Search speed: 1 T i l t i n g option: S No. of ion ranges searched: 55

Prob. CAS #. CON # ROOT K DK #FLG TILT % CON C_I R_IU

1. 37* 628284 332 "BIGDB 26 55 2 0 100 30 14 14

CORRECTED TOTAL ION AREA OF UNKNOWN - 120646CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 628578CONCENTRATION OF. INTERNAL STD - 40UG/L DILUTION FACTOR - 1SEMI QUANT I TAT ION OF UNKNOUN - 8UG/L

ftR203!56

Fila >07746 31L3551-1? 1000/inL EXT: 11/22.-- Scan 5431Bpk flb 11571. SUB 12.97 40 in. j

*: 39 45 52 -X_ 66

nJ , i ( , ,•"" . r"" , 1 1 i ,-""40 50 60 70

73 *,*• 100 X02rrT' .1 T . :*"~ J-j -O

SO ?0 100 110 120

Fila >BIGDB o-Ch loroani 1 i ne Scan 13472Bpk flb 9999. Q.00__mm.

-jj 39 50 52 *5^ 66

rJ. i (• • • .^ . '*"" , , . i i ••""""40 50 60 70

73 86 f.2 99 102 110' " , , 1 . {, . f** ''

' fr_tn

30 90 100 110 120

Fila .--BIGDB m-Chloroani 1 ine Scan 13473Bpk flb 9999.

39 5. 52 ° 66. i ' i i i 1 •**"' 1 1 1 -~"~

0.00 min .127S

73 84 ' 2 100 102 110. .TTT. . ' ,i , li..**^" ^ ' In

40 50 60 70 '80 Vo ' ' 100 ' 110 ' 120

File >BISDB Pyridine, S-chloro-5-wathyl- <9CI) Scan 13479Bok flb 9999. 0.00 mm.

.1 39 65f 51 52 ^> 66

,jj. 1 1 . """n .- ,.M! r~*

12792 / ,

73 99,""" 1 . {. i -iL

40 50 60 70' 30 90 100 110 120

1. o-Chloroaniline 127C6H6C1N2. m-Chloroaniline 127C6H6C1N3. Pyridine, 2-chloro-5-methy 1- (9CI) 127C6H6C1N4. p-Chloroani1ine (ACN) 127 C6H6C1N5. Pyridine, 2-chloro-6-methyi- (9CI) 127 C6H6C1N


Prob. CAS * CON # ROOT K DK #FLG TILT H CON C_I. R_IU


CORRECTED TOTAL ION AREA OF UNKNOWN - 113947CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 628578CONCENTRATION OF INTERNAL STD ^ 40UG/L DILUTION FACTOR -SEMI QUANT I TAT ION OF UNKNOWN - 7UG/L

Fil« .>07746 91L3551-9 1000/1MLBpk flb 14956. SUB

65 10,61 39 -- 77 92 "-•] " 5,1 67 JJ , w

nJi+ ,.,.,,, ,,,!,,, J^ll iv7i'i'J|l|i MI|' 'I', . i i i 4yrT-40 60 80 100

Fila >BIGDB Carbamic acid, phenvl-. rnethvBpk flb 9999.

" 1 65 10^39 51 "-. 76 JJ .« ' i07

O-J ..... 1, 1 ,1 .. ..""""-III... . . . ll.. . . . , . , .

Aft ' i'n ' on ' 1 nn 'TV w V W V _ V V

F i l « >BIGDB Benzoni tri le , 3-hydroxyBpk flb 9999.

j 39 52 *4 75 80 ^ 102 116.d,.. ...„<„... ,.,ll,.... >,..../ ,, ../. -

40 ' 60 ' 80 ' 100

File >BI6DB Banzoni tr i Is , 4-hydroxyBpk flb 9999.

j 39 50 6* 69 81 9> 102J,.,<... ../...... ..L..S-........f ..(.. ../,•»-]— r . . . , , . . , ( ... i , .... j .... ( .... ( . . . . j . .

40 60 30 100

EXT:ll/22.-' 3ca17.1

151119 '/

135 li J|'... .M'>" i ————— t+^-rrr... -

n 13444 mm .

= 6 [~~-iLn

120 140 160

1 «ster C9CI) Scan0.0151

119135 l

., ,. "•>. ,.- —— ~

174510 mm .

53 :In

120 140 160

- C9CI> ScarO.C

119/

121

121370 min .

Ln120 140 160

- C9CI) Scan 121360 .00 min .

119/ ,

121 E

120 140 160

1. Carbamic acid, phenyl-, methyl ester (9CI) 151 C8H9N022. Benzonitrile, 3-hydroxy- (9CI) . 119 C7H5NO3. Benzonitrile, 4-hydroxy- (9CI) 119 C7H5NO4. Benzoic acid, 4-amino-, methyl ester (9CI) 151 C8H9NQ25. Benzoic acid, 2-amino-, methyl ester (9CI) 151 C8H9N02

Sample file: >D7746 Spectrum #:,. 1344Search speed: 1 Tilting option: S No. of ion ranges searched: 56

Prob. CAS # CON # ' ROOT K DK #FLG TILT % CON C_I R_IU


CORRECTED TOTAL ION AREA OF UNKNOWN - 328519CORRECTED TOTAL ION AREA OF INTERNAL STANDARD - 787769CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR -• D O nO J ClOSEMI QUANT I TAT I ON OF UNKNOWN =» 17UG/L H R C. U O 1 U U

File ,>D7746 91L3551-9 IQQQ.'ltILBpk flb 54392.

: 39 51n_!. ,'. . ,i

40

Bile >BIGOB|Bpk flb 9999.

J40 51, id . ,!';•, , , , , , , , , , , . . , , . , , , , , , , , , , , , , , , , , , , ,

SUB

63 ^6 39 102 109 115I'l'l'i'i) i-P-'l'i" I'lVi'i'iviri'i i'/| i V i i | i"i'SO SO 100 120

Naphthalene, 2-ethenyl-

63 7* 37 102 113 115, i .. . ( j i . . . . , , ...... /"?: . i . ...

40 60 SO 100 120


j 39 51J.,". ..L...

Rcenaphthene CSCI)

63 / 87 98 113 115\t ..It '' •' "~~- -~"

40 60 30 100 120

File >B!3DBBok flb 9999.

H1 39 511 1rJ jfj,... ''4-, ,. ,

l,l'-Biphenyl C9CI)

63 6 37 102 103 115

40 ' 60 ' 80 ' 100 ' 120

EXT:ll/22x Scan 140917.32 min.

154

126 139~" ' *i|I

130 [""""-: Ln

140 160 190

<9CI) Scan 179440 .00 min .

154

123 139ili , , ; . . . ! \

156 [I.-""" Ln

140 160 ISO

Scan 179330 .00 min .

154

126 139 ,rrrT" .. ../ .....il

f,.- L140 160 180

Scan 179350 .00 min .

154

126 139if? f ...,ll

j \-156 [

140 160 180

1. Naphthalene, 2-ethenyl- C9CI) 154C12H102. Acenaphthene C8CI) 154 C12H103. l,l'-Biphenyl (9CI) 154C12H104. Benzene, (.2 ,4-cyc lopen t ad ien-l-y 1 ideneme thy 1 ) - C9CH 154 C12H105. 1,4-Ethenonaphthalene, 1,4-dihydro- (8CI9CI) 154C12H10



1. 79* 827543 17944 "BIGDB 62 39 2 -1 89 6 48 312. 59* 83329 17933 "BIGDB 47 43 0 0 45 36 21 55J. 43* 92524 17935 "BIGDB 59 46 1 0 58 46 13 534. 30* 7338503 17817 "BIGDB 44 45 2 0 43 49 10 235. 25* 7322476 17956 "BIGDB 35 57 2 0 43 49 7 17

CORRECTED TOTAL ION AREA OF UNKNOWN - 435593CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 787769CONCENTRATION OF INTERNAL STD =• 40UG/L DILUTION FACTORSEMI QUANTITATION OF UNKNOWN - 22UG/L

Fila >07746 91L35Bpk flb 127243.

J -,«, 51J /' '

0-l"|l|i|., , rijtvi1i i i • . . ..I40

File >BISDBBpk flb 9999.

1 3,9 "nJ ..i. .. .1 ,. ..•^ i i i ' ' • i ' ' '

40

Fila >BI6DBBpk flb 9999.

J 5 0

, , , , , , f , , ,40

File >BISDBBpk flb 9999.

J39 51-A-ni-^-n40

51-9 1QOO/1ML EXT:ll/22/ ScanSUB 13.2,4

H .. « •>.77 . ._ i^65 "•-- 73 94 102 ^ 128 139 j 155

1449rn i n .

i60 80 100 ISO 140 160

Benzene, l,l'-oxvbis~ ''9CI> Scan <0.00170

77 14165 -~_ 35 94 102 I-5 139 139 -" 154

...../...........I.. .'......./ .. ../ £.... r--, --.Ii,. ..r:.

20296mm .

i, Ini | l 1 l l j 1 j i | l l l . . . , , | , . 1 r-p -r-i-.r- ) i i i i | i l i . | l i r i-| i i i i { .1 i i i i "SO SO 100 120 140 160

aui nal don i tri le, 3-hvdroxy- <8CI> Scan0.00170

115 14264 7Q 83 89 ' f^

: III. ' .1, .III. ill II.

20312min .

' -0. 1 . . . . , , . . . j . . , , j ... , t . . , , ( , . . , j , , . • a . • • ' i • • - • | • • • .[ill ' ) >60 80 100 120 140 160

Cl,l'-8iphanyn-3-ol (9CI) Scan0 .00170-»>

63 76 85 39 102 115 _£2 139 141 15g... ..s.........>... j... f ( ,-••' . rT" .. . .,

£0298min .

I.L,-,60 ' 80 ' 100 ' 120 ' 140 ' 160

r ovJ j_ J

1. Benzene, l,l'-oxybis- (9CI) 170 C12H1002. Quinaldonitrile, 3-hydroxy- (SCI) 170 C10H6N203. [l,l'-Biphenyl]-3-ol C9CI) 170 C12H1004. [1,1'-Biphenyl]-2-ol C9CI) '170 C12H1005. !H,3H-NaphthoCl,8-cd3pyran (8CI9CI) 170 C12H100


Prob. CAS * CON * ROOT K DK #FL6 TILT % CON C_I R_IU

1. 79* 101848 20296 "BIGDB 59 47 2 1 84 10 48 302. 20* 15462438 20312 "BIGDB 22 90 3 0 100 51 5 123. 18* 580518 20298 "BIGDB 39 51 1 0 68 59 4 224. 11* 90437 20293 "BIGDB 42 49 1 1' 31 62 2 175. 11* 203849 15988 "BIGDB 34 59 2 0 47 65 2 15

CORRECTED TOTAL ION AREA OF UNKNOWN = 1804589CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 787769CONCENTRATION OF INTERNAL STD = 40UG/L DILUTION FACTOR sftR203I60SEMI QUANT ITAT ION OF UNKNOWN - 92UG/L

File >07746 91L3551-9 1Bpk flb 48534.

~ 39 65: jy 5i - •• ' 79- I / Ii "~~-j ^~

^ 40 60 80

Vile ..-BIGQB Carbamic acid, phe'Bpk Ob 9999.

: 39 51 65 77 -,9

;> ,'j- .', ; i'' ,-, , , , i1! , , , riVf, . , , i40 60 SO

File --BI8DB Pyridine.Bpk flb 9999.

J39 66l"" 51 ""-j 76 78

'I'j'iTi-i'j':1!-, , ,•!':'!'! | . TVf7 , , i-j40 60 SO

File >BIGDB Benzanamina,Bpk fib 9999.

66: 46 50 -- 74 73

40 ' 60 ' 80

QQQ/1ML EXTzllxaS/ ScanSUB 18.5193x 106 165

" 103 12° 137

\\ 1 1 1 l't"'iVl 1 1 I1 '1 1 1 1 I 1 1 I'1 1 1 1 M | II 1 1 | ' ''I'100 120 140 160

>nvl-, ethvl ester <9CO Scan 10 .0.0

f 106" 120 137

100 120 140 160

4-methvl- <9CI> Scan0 .00

93

95

• • • T f • • • • i • • • • i • • * • i • • • • i • • ' • i • • • • i ' • •100 120 140 160

hydrochloride (9CI) Scan0 .00

93

94i ,

100 120 140 160

1475nin .

-0

3555min .

-0

2786min .

-Q

2789min.

1. Carbamic acid, phenyl-, ethyl ester (9CI) 165 C9H11N022. Pyridine, 4-methyl- (9CI) 93 C6H7N3. Benzenamine, hydrochloride C9CI) 129 C6H8C1N4. Anili n e CACNH8CI) ' 93 C6H7N5. lH-Pyrazole-4-carbonitrile (9CI) 93 C4H3N3


Prob. CAS # CON # ROOT K DK #FL6 TILT H CON C_I R_IU

1. 30* 101995 19555 "BIGDB 40 72 1 0 58 43 12 212. 27* 108894 2786 "BIGDB 55 54 .2 -2 84 45 8 153. 25 142041 2789 "BIGDB 38 48 1 0 90 50 7 144. 25* 62533 2785 "BIGDB 34 56 2 0' 90 50 7 175. 20* 31108573 2797 "BIGDB 28 53 2 0 81 55 5 14

CORRECTED TOTAL ION AREA OF UNKNOWN = 631375CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 787769CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR =SEMI QUANT I TAT ION OF UNKNOWN = 32UG/L

FiU >D7746 91L3551-9 1QOQ.'Bpk flb 6245. SUE

1 7739 52 65 f 91 104i--~~~ --' / • i i ^-- ~-_nJi. i in ,,.i , 1 U h. , "•;,40 SO 30 1 nn

File >BIGDB Pvridine, 2-etfBpk flb 9999.

1ML EXT:ll/22/ Scan 1642i £0.25 min.106

'' 133 151 "" ;./ /, i i i i . n

120 140 160 180

lyl- <8CI9Cn Scan 99170 .00 min .

106

103 i.~~ -n

40 ' 60 ' SO '''lOO ' 120 ' 140 ' 160 ' ISO

Fil* >BISD6 Benzenemethanamine <9CI> Scan 10037Bpk flb 9999. 0.00 min.

106J - * ^ " _

7939 51 65 / 9.1 104 1 108 ;

40 ' 60 ' 80 ' 100 ' 120 ' 140 ' 160 ' 180

File >B1GPB Benzenamine, 4Bpk flb 9999.

| 39 51 63 7/ 39 104

40 ' 60 ' 80 ' 100

-methyl- <9CI> Scan 99250 .00 min .

106

108 f

120 ' 140 ' 160 ' 180

1. Pyridine, 2-ethyl- (8CI9CI) 107 C7H9N2. Benzenemethanamine C9CI) 107 C7H9N3. Benzenamine, 4-methyl- (9CI) 107 C7H9N4. 1-Triazene, 1-methy 1-3-(4-methyIpheny1)- C9CI) 149 C8H11N35. Benzenemethanamine, .aIpha.-me thy 1-, (.+-.)- <9CI) 121 C8H11N



1. 41* 100710 9917 "BIGDB 55 39 1 -3 100 45 14 332. 41* 100469 10037 "BIGDB 56 45 2 0 68 45 14 333. 25* 106490 9925 "BIGDB 30 56 1 0 76 47 7 164. 25 21124130 9929 "BIGDB 53 42 2 0 71 47 7 165. 15* 618360 9936 "BIGDB 33 60 3 0 100 58 3 13

CORRECTED TOTAL ION AREA OF UNKNOWN - 83803CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 787769 •n on O I r OCONCENTRATION OF INTERNAL STD = 40UG/L DILUTION FACTOR =An_;Uj|(}__SEMI QUANT I TAT I ON OF UNKNOWN = 4UG/L

File' ',-07746 91L35S1-9 1000/1ML EX"Bpk flb 2773. SUB

99 , 14°

n_i|l ll iM| , 1 !|i i 1 1 l i , ,1 , Li ,,, , i' , lj,|i ,40 60 30 100 120 140

• lie >BIGDB Benzoic acid, 2-amino-5-chloro- , methyl <*<fipk flb 9999.

1 ••* Qa 12639 52 *3 ?3 90 99 110 / 135 142n-L ........i'.,.. 1,,. .,. .r , ...... .,(„.. ..,,[,,, ....... f.. ....„....„ !).. .J......f...

40 ' 60 ' SO ' 100 ' 1£Q ' 140

File >BIGDB Benzoxazole, 2-chloro~ <8CI9CI)Bpk flb 9999.

1 631 38 51 / -.Q 90 1251~"~ -"' 11 / ' ^ ^C.

r t T T - - t • ' • • i * • ' ' i • • • ' i • ' • • i • • • • i • • • • i • • • • i • • • • i • • • - i • • • •40 60 80 100 120 140

File >BI6DB Naphthalene, 1-iso thiocyanato- C9CIBpk flb 9999.

J _44 51 69 77 93 _QI 113 ^ _4fl 152

...!.. S.. ... .J, .. ...f. L .il. .. ^40 ' 60 ' 80 ' 100 ' 120 ' 140

r s 11x22." Scan20.56

153 135." ">..

160 130

;ter C9C Scan 30.00

153185

1 169

ISO ISO

Scan :0.00

153

157

r r'isoirTT iso) Scan <

0.00185

153 -

*-.. i i i .160 130

1672m i h .

jjLn

i7S62min.

4n

L7813min .

T.LO

22293min .

\J-Q

1*0.6

1. Benzoic acid, 2-amino-5-chloro-, methyl ester C9CI) 185 C8H8C1N022. Benzoxazole, 2-chloro- (8CI9CI) 153 C7H4C1NO3. Naphthalene, 1-isothiocyanato- C9CI) 185 C11H7NS4. Benzene, chloroisocyanato- (9CI) 153 C7H4C1NO5. Benzene, 1-chloro-3-isocyanato- (9CI) 153 C7H4C1NO

Sample f i l e : >D7746 Spectrum #: 1672Search speed: 1 Tilting option: S No. of ion ranges searched: 56

Prob. CAS # CON * ROOT K DK #FLG TILT % CON C_I R_IU


CORRECTED TOTAL ION AREA OF UNKNOWN - 94387CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 787769CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTORSEMI QUANTITATION OF UNKNOWN - 5UG/L

'FT. I«"7£f7;?46 31L35B1-9Spk flb' 12623.

J ,, a^j 39 62 77 '-^

40 60 SO • 1

1000/1MLSUB

1

101 125

00 120

. i l e >BI6DB Carbamic acid, < 3-chloroph«nv 1Bpk flb 9999.

EXT:li i£- -.car1736cl.75 mm.

£7_ j *+i-+U

" 153 171L9£

J,lo140 160 laQ 300

J-. ethvl ester <9C Scan 243600 .00 mm .

icif 200~! =039 ._ ° 63 87 99nJ,,'.. ,,i 1,1, . iT>! ..,.,,, ""*": .in,

«~-111 125

i.,,.,. ~""1!,., ,7""1i il,40 60 SO 100 120

Fila >BI6DB Carbamic acid, ( 4-chloropheny 1Bpk flb 9999.

140-"' 153 17i

.... ,i, ;"^ L^>ll-| ^£n HonO.-TV J.WW ±^J * L

i-. ethyl ester <'9C Scan

___ i_FLU

:oo24268

0.00 mm.127 •L"

J45 50 63 77 1 -""' i"f" , " ,,,

^101 120

1 f"~~"" ' il40 60 30 100 120

140-*" 153 171

.. .. ,1. .C' .;'.

/ ,

,lln140 160 180 200

File *>BIGD8 2-Naphthilenecarboxarnide , N ,N-dimethyl- <9CI> Scan 24253Bpk flb 9999. 0.00 min.

155H *F •{ 1Q*T3 4£ 51 75 77 _QQ

nj /. r 'T;.,'"*' "" ~101 125

•tr""* "" i i.40 ' 60 ' 80 ' 100 ' 120

^ _!•*-1 .1,. / f:U,

140 ' 160 ' 180 ' 200

1. Carbamic acid, (3-chloropheny1)-, ethyl ester (9CI) 199 C9H10C1N022. Carbamic acid, C4-chloropheny1)-, ethyl ester C9CI) 199 C9H10C1N023. 2-Naphthalenecarboxamide, N,N-dimethy1- C9CI) 199 C13H13NQ4. 1-Naphthalenecarboxamide, N,N-dimethy1- (9CI) 199 C13H13NO5. o-Chloroani1ine 127 C6H6C1N

• Sample file: >D7746 Spectrum #s 1786Search speed: 1 Tilting option: S No. of ion ranges searched: 56

Prob. CAS # CON t ROOT K DK #FLG TILT % CON C_I R_IU


CORRECTED TOTAL ION AREA OF UNKNOWN = 213591CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 787769 mn nn^CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR =ft R 2 U 3 ISEMI QUANT I TAT ION OF UNKNOWN = 11UG/L

File >D7746 91L3551-9Bpk flb 10131.

1j 39 63 77J -^- / /

0-H i |iH'i |'ll ,-"|l|"-i^ 40 SO

Vile >BIGOB'Bpk flb 9999.

1 65] 39 .' 74

40 SO

File >BH30BBpk flb 9999.

i 39 f 74nJii T ...... .,.,... „•'i • • • i • • • i40 30

1000."1ML EXT :ll--22."SUB

c.

91 108 " 123139 ri54" i£6 ^J2f / / / ' .-'- f"

3 c z.n i -. '• -:29.13 mm.19•

t£44 t--Ln'(•Hr-y i-'V i | r'"i i "'r'T -i-"l" | T1 i -i — |'"i 1 i — [—>""> — i'l i i '•*• "I— -

120 160 200 540

Benzenamine, 4-iodo- <9CI>^

92' 109 127 143 157 171 191 199

/ ,' ;{ ..-f! / / •""

Scan 267130.00 mm.

19'

_220 ti Ln

120 160 200 240

Bettzenamine , 3-iodo- <9CI>2

/2 109 -p 152 171 191. i. - ,. /

Scan 267150.00 min.

19/ ,

221 [•r~ ~"~ Ln. ( . . , ( , . , | ... | , , . , . , , | , . , , . . i |

120 160 200 240

File >8I6DB flee tarn ide, N-C6-pheny Ihexy 1 >- C9CI)Bok flb 9999.

2

1 43 55 73 / 104 12814fiJ. ( . f f'. A , if ,,. f "^140 30

Scan 267300 .00 min .

19/ ,

£20 [i Ln. j ... ! . . . ( ... j ... ( . . . ( . . . ( . . . ,

120 160 200 240

1. Benzenamine, 4-iodo- C9CI) 219 C6H6IN2. Benzenamine, 3-iodo- C9CI) 219 C6H6IN3. Acetamide, N-(6-phenyIhexy1)- (9CI) 219 C14H21NO


Prob. CAS * CON * ROOT K DK #FL6 TILT % CON C_I R_IU

1. 26* 540374 26713 "BIGDB 35 80 2 0 100 42 8 142. 26* 626017 26715 "BIGDB 26 81 2 0 100 43 8 143. 25* 53429177 26730 "BIGDB 25 109 3 0 100 43 8 13

CORRECTED TOTAL ION AREA OF UNKNOWN = 161739CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 523284CONCENTRATION OF INTERNAL STD - 40UG/L DILUTION FACTOR - 1SEMI QUANT I TAT ION OF UNKNOWN = 12UG/L

ftR203!65

File >07746 91L3551-9Bpk flb 15521.

J39 51 *5 92,.i"jT". \fT ...fiT" ii i * ' t p i ' i '40 60 80

lOOO.'lHL EXT:11."22SUB

93

119

r^ — 1 — l — I — r— 'l — l — | — l — | —— i — | — l — | — i — | — l — | — l — [—100 120 140 160 180

, i l e >8IGDB Urea, N ,N ' -dipheny 1-N-C trims thy Isi Ivl )- <9CI)Bpk flb 9999.

j 39 51 *5 92TJ r"'. ,7~"T ,. .. mT . >,..,. ...""""

40 SO SO

93

119 129 135 149 167 1357- 1....... .. .. ... ~~ ,. . ....;•'' .:r " , /. /100 120 140 160 ISO

File -BIGDB Urea, N ,N '-dipheny 1- <9CI>Bpk flb 9999.

j 39 51 65 91n-I.fiTT'. . ...TT" ...iiT. ...i... ""!"

40 60 30

93

Xf9 121 135 167In. " j.r-" -""" ./

100 120 140 160 130

File >BIGDB Pyridine, £-methyl- <9CI>Bpk flb 9999.

J 39 51 3 92j " _•-•' I --

ijJ.il ...... ...ill,.. ,.,.lli. ....1.40 60 80

93

941,- — — ——

1 ' 1 ' 1 ' 1 ' 1 ' I ' I ' ! • 1 • 1 ' 1100 120 140 160 180

" Scan 255329.74 min.

212{. :

200-0

Scan 259220 .00 min .

212L

200-0

Scan 259170 .00 min .

104 212> L200

r-0

Scan 27880.00 min .

200

:-0

1. Urea, N,N'-dipheny1-N-(trimethy Isilyl)- (9CI) 284 C16H20N20Si2. Urea, N,N'-dipheny1- C9CI) 212 C13H12N203. Pyridine, 2-methyl- C9CI) 93 C6H7N4. Acetamide, N-phenyl- C9CI) 135 C8H9NQ5. lH-Pyrazole-4-carbonitrile (9CI) 93 C4H3N3

Sample fil e : >D7746 Spectrum ft: 2553Search speed: 1 Tilting option: S No. of ion ranges searched: 56

Prob. CAS ft CON ft ROOT K DK ftFLG TILT % CON C_I R_IU

1. 78 1154843 25922 "BIGDB 77 40 2 1 100 5 55 142. 76* 102078 25917 "BIGDB 83 26 1 0 59 36 37 803. 52* 109068 2788 "BIGDB 26 81 3 0 100 17 20 134. 42 103844 7780 "BIGDB 38 44 2 0 100 25 17 135. 30* 31108573 2797 "BIGDB 27 54 3 0 100 32 12 13

CORRECTED TOTAL ION AREA OF UNKNOWN = 145126CORRECTED TOTAL ION AREA OF INTERNAL STANDARD = 523284CONCENTRATION OF INTERNAL STD = 40UG/L DILUTION FACTOR =SEMI QUANT I TAT I ON OF UNKNOWN - 11UG/L AR203I&6

911-3551-6 Sample Data PackageVinyl Chloride 881129 lOiOO SUB 62 "H~^1 44 50 ' 1 ' '!' 64 / 69 81...

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Transcript of 911-3551-6 Sample Data PackageVinyl Chloride 881129 lOiOO SUB 62 "H~^1 44 50 ' 1 ' '!' 64 / 69 81...