400 ps
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-25 0 25 50 500 5000
-2
-1.5
-1
-0.5
0
383 nm (35)
O
D (
mO
D)
-25 0 25 50 500 5000-4
-2
0
467 nm (105)
O
D (
mO
D)
-25 0 25 50 500 5000-1
0
1
509 nm (140)
O
D (
mO
D)
-25 0 25 50 500 5000
0
0.5
1
552 nm (175)
O
D (
mO
D)
-25 0 25 50 500 5000
0
0.5
1
594 nm (210)
O
D (
mO
D)
Time (ps) -25 0 25 50 500 5000-2
-1
0
1
636 nm (245)
O
D (
mO
D)
Time (ps)
03 RoomT bCar hex.raw (1) (Not Dispersion Adjusted)05 RoomT bCar iodohex.raw (1) (Not Dispersion Adjusted)09 RoomT bCar chlorohex.raw (1) (Not Dispersion Adjusted)
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300 400 500 600-6
-4
-2
0
22 ps (31): Pump Probe
OD
(m
OD
)
300 400 500 600-3
-2
-1
0
115 ps (57): Pump Probe
OD
(m
OD
)
300 400 500 600
-3
-2-10
24 ps (71): Pump Probe
OD
(m
OD
)
300 400 500 600
-3-2-101
37 ps (84): Pump Probe
OD
(m
OD
)300 400 500 600
-4
-2
0
200 ps (112): Pump Probe
OD
(m
OD
)
300 400 500 600-4
-2
0
470 ps (139): Pump Probe
OD
(m
OD
)
300 400 500 600
-4
-2
0
3000.3 ps (167): Pump Probe
OD
(m
OD
)
Wavelength (nm)300 400 500 600
-4
-2
0
5000.8 ps (194): Pump Probe O
D (
mO
D)
Wavelength (nm)03 RoomT bCar hex.raw (1) (Not Dispersion Adjusted)05 RoomT bCar iodohex.raw (1) (Not Dispersion Adjusted)09 RoomT bCar chlorohex.raw (1) (Not Dispersion Adjusted)
![Page 3: 400 ps](https://reader035.fdocuments.us/reader035/viewer/2022072013/56812c7e550346895d912b96/html5/thumbnails/3.jpg)
350 400 450 500 550 600 650
-6
-5
-4
-3
-2
-1
0
1
2
M1: hexane
Ab
sorp
tion
(sc
ale
d)
Wavelength (nm)
1 10 100 1000
0.0
0.2
0.4
0.6
0.8
1.0
M1: hexane
Co
nc
ps
400 ps
ps
7 ps
S1
S*
T Chi square:
4.0E-0002
1 10 100 1000
0.0
0.2
0.4
0.6
0.8
1.0
M1: Chlorohexane
Abs
orpt
ion
(sca
led)
ps
350 400 450 500 550 600 650-5
-4
-3
-2
-1
0
1
2
M1: Chlorohexane
Ab
sorp
tion
(sc
ale
d)
Wavelength (nm)
2.9E-0002
300 ps
ps
7 ps
S1
S*
T400 ps
ps
14 ps
S1
S*
T
350 400 450 500 550 600 650
-5
-4
-3
-2
-1
0
1
2
M1: Iodohex
Ab
sorp
tion
(sc
ale
d)
Wavelength (nm)
1 10 100 1000
0.0
0.2
0.4
0.6
0.8
1.0
M1: Iodohex
Ab
sorp
tion
(sc
ale
d)
ps
hexane chlorohex Iodohex
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400 ps ps
7 ps
S1
S*T
350 400 450 500 550 600 650
-9
-8
-7
-6
-5
-4
-3
-2
-1
0
1
2
3
Abs
orpt
ion
(sca
led)
Wavelength (nm)
chlorohex
1 10 100 1000
0.0
0.2
0.4
0.6
0.8
1.0
Abs
orpt
ion
(sca
led)
ps
MODEL doesn’t work: EADS beating
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4.0E-00023.4E-0002
hexane chlorohex Iodohex1000 ps
ps
7 ps
S1
S*
T1000 ps
600 ps
ps
7 ps
S1
S*
T600 ps
800 ps
ps
14 ps
S1
S*
T800 ps
350 400 450 500 550 600 650
-6
-5
-4
-3
-2
-1
0
1
2
3
4
Ab
sorp
tion
(sc
ale
d)
Wavelength (nm)
1 10 100 1000
0.0
0.2
0.4
0.6
0.8
1.0
Abs
orpt
ion
(sca
led)
ps
2.9E-0002
1 10 100 1000
0.0
0.2
0.4
0.6
0.8
1.0
Ab
sorp
tion
(sc
ale
d)
ps
350 400 450 500 550 600 650-9
-8
-7
-6
-5
-4
-3
-2
-1
0
1
Ab
sorp
tion
(sc
ale
d)
Wavelength (nm)
1 10 100 1000
0.0
0.2
0.4
0.6
0.8
1.0
Abs
orpt
ion
(sca
led)
Wavelength (nm)
350 400 450 500 550 600 650
-10
-9
-8
-7
-6
-5
-4
-3
-2
-1
0
1
2
3
Ab
sorp
tion
(sc
ale
d)
Wavelength (nm)