4-7 Recovery Boiler Deposits and Plugging Prevention · 2008. 1. 4. · 6200 KPa (900 psi) Deposit...
Transcript of 4-7 Recovery Boiler Deposits and Plugging Prevention · 2008. 1. 4. · 6200 KPa (900 psi) Deposit...
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Recovery Boiler Deposit Formation Recovery Boiler Deposit Formation andand Plugging PreventionPlugging Prevention
Honghi TranPulp & Paper Centre University of Toronto
Toronto, Canada
Tappi Kraft Recovery CourseSt. Petersburg, Florida, January 7-10, 2008
Problems with DepositsProblems with DepositsReduce boiler thermal efficiencyCreate a corrosive environment at tube surfacesLead to unscheduled boiler shutdowns for deposit removal or tube repair
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Presentation OutlinePresentation OutlineEntrained ParticlesDeposit PropertiesPlugging in Different RegionsDeposit CleaningPlugging Prevention
Entrained ParticlesEntrained Particles
Particles
Deposits
Dust
Black Liquor
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Particle TypesParticle Types
Carryover500 μm
(100 μm - 3 mm)
ISP20 μm
(1 - 100 μm)
Fume0.5 μm
(0.1 - 1 μm)
CarryoverCarryover FumeFume
ISPISPDeposits onDeposits onAir Cooled ProbeAir Cooled Probe
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EconomizerEconomizer
SuperheaterSuperheater
Boiler BankBoiler Bank
Presentation OutlinePresentation OutlineEntrained ParticlesDeposit PropertiesPlugging in Different RegionsDeposit CleaningPlugging Prevention
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Particle Composition (Wt%)Particle Composition (Wt%)
Carryover
NaCl 2%K-salts 2.5% Other 1%
Na2SO445%
Na2CO350%
NaCl 4.0%K-salts 3.5%
Other 0.2%
Na2SO487%
Na2CO3 6%
Fume
Superheater
Precipitator DustEconomizer
Deposit CompositionDeposit Composition
Na2CO3
Na2SO4
NaCl
K-saltsOther
Boiler Bank
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Appearance of a Deposit ConeAppearance of a Deposit Cone
1200
1400
1600
800
1000Tem
pera
ture
(oF)
600 700 800 900500
Firstmelting
Flowing
Completemelting
Temperature (oC)
Sticky0%
70%15%
~1%
100%
LiquidPhase
First melting temperature is important for corrosionSticky and flowing (slagging) temperatures are important for fouling/pluggingThese temperatures are related to liquid content, which is a function of:
deposit composition (mainly chloride)temperature
Melting TemperaturesMelting Temperatures
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Deposit Sticky TemperatureDeposit Sticky Temperature
0 mole% K/(Na+K)
mole% Cl/(Na+K)0 102 124 146 168 18 20
850
700750800
500550600650
Tem
pera
ture
(oC
)
0 mole% Cl/(Na+K)
1
5
10
20
ChlorideChloride
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Deposit Sticky TemperatureDeposit Sticky Temperature
mole% K/(Na+K)
mole% Cl/(Na+K)0 102 124 146 168 18 20
0
10 20
5
850
700750800
500550600650
Tem
pera
ture
(oC
)
SurfaceDiffusion
BulkDiffusion
Materialtransfer
Particle SinteringParticle Sintering
Temperature
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Dust Sintering Dust Sintering Test (1 hour)Test (1 hour)
Before After 480oC (900oF)
Vol. Shrinkage 58%
After380oC (720oF)
Vol. Shrinkage 18%
Compressive Strength Compressive Strength ComparisonComparison
GlassFired brickCementSintered dustInsulating brickUnsintered dust
MPa800 - 2000
7030 - 60
507
<2
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Presentation OutlinePresentation OutlineEntrained ParticlesDeposit PropertiesPlugging in Different RegionsDeposit CleaningPlugging Prevention
Plugging at the Superheater InletPlugging at the Superheater Inlet
Screen
Superheater
Screen
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Deposit Accumulation PatternDeposit Accumulation Pattern
ScreenSuperheater
FurnaceWall
Carryover
Plugging in the SuperheaterPlugging in the SuperheaterCaused by carryover deposition
High gas temperatureLarge amount of sticky carryover
Not by fume depositionSmall amount of fume
Deposits
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Plugging at the GB InletPlugging at the GB Inlet
Plugging at the GB inletPlugging at the GB inletNarrow tube spacing (2”)Carryover deposition upstream (superheater)
High gas temperatureSticky carryover
Fume deposition and sintering
High gas temperatureLarge amount of fume
Deposits
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Cause of Plugging at the GB InletCause of Plugging at the GB Inlet
TimeMassive depositbuildup zone
Clean PluggedFouled
Plugging in the Generating BankPlugging in the Generating Bank
Fume deposition and sintering
High gas temperatureLarge amount of fume
Inadequate sootblowing
DepositsDeposits
Deposits
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Flue Gas
Steam6200 KPa(900 psi)
Deposit
Tube
550oC
450oC (Hard)
270300oC (Soft)
Temperature across a GB Tube and Temperature across a GB Tube and Deposit LayerDeposit Layer
Deposits sinter rapidly if they are:Deposits sinter rapidly if they are:jammed between tubeson stabilizing bars and baffleson sealed tubes (no steam inside)on mud drum (for bi-drum boilers)
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Plugging in the Generating BankPlugging in the Generating Bank
Plugging in the Generating Bank of a Plugging in the Generating Bank of a Single Drum BoilerSingle Drum Boiler
Flue Gas
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Plugging in the EconomizerPlugging in the Economizer
Fume deposition and sinteringSticky fume (acidic sulphate formation)
Low bed temperatureHigh sulphidity
Inadequate sootblowing
Na2SO4 + SO2 +½ O2 +H2O = 2 NaHSO4
Deposits
Baffle
Deposits
Baffle
Presentation OutlinePresentation OutlineEntrained ParticlesDeposit PropertiesPlugging in Different RegionsDeposit CleaningPlugging Prevention
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Nozzle Throat JetPIP
Lance Tube
Sootblower LanceSootblower Lance
350 psig steam60 to 100 sootblowers per boilerConsume 3 to 12% total boiler stream production
Factors Affecting SootblowingFactors Affecting SootblowingEfficiency Efficiency -- Jet Jet
Peak Impact Pressure (PIP)
Nozzle designSteam flow rate and pressure
Distance to depositBlowing angleBlowing sequence and frequency
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Factors Affecting SootblowingFactors Affecting SootblowingEfficiency Efficiency -- DepositDeposit
Deposit adhesion strengthDeposit composition (Cl, K)Deposit temperature
Deposit size and thicknessDeposit and tube temperature
Tube Temperature and PIP Tube Temperature and PIP RequirementRequirement
Economizer160-270oC: LOW(320-520oF)
Superheater300-500oC: HIGH(570-930oF)
Generating Bank270-300oC: MEDIUM(520-570oF)
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Presentation OutlinePresentation OutlineEntrained ParticlesDeposit PropertiesPlugging in Different RegionsDeposit CleaningPlugging Prevention
Plugging due to Sticky CarryoverPlugging due to Sticky Carryover
Main CausesExcessive carryoverHigh flue gas temperature
Preventive MeasuresMinimizing carryover quantityReducing carryover stickinessLowering flue gas temperaturesIncreasing sootblowing efficiency
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Plugging due to Fume SinteringPlugging due to Fume Sintering
Main CausesExcessive fume High flue gas temperatureIneffective sootblowing
Preventive MeasuresMinimizing fume quantity (low bed temperature, coarse spray)Lowering flue gas temperaturesIncreasing sootblowing efficiency
Plugging due to Sticky FumePlugging due to Sticky FumeMain Causes
Low carbonate content in the fumeHigh SO2/SO3 conc. in the flue gasIneffective sootblowing
Preventive MeasuresIncreasing bed temperatureLowering liquor sulphidityIncreasing sootblowing efficiency
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SummarySummaryDeposit formation and characteristics vary greatly with location within a boiler, and differ from boiler to boiler.It is important to identify the exact cause in order to devise appropriate solutions