3-25-2020 Supersedes: All Previous Issues SAFETY DATA ...

SDS Date: 3-25-2020 Revision: 03 Supersedes: All Previous Issues

SAFETY DATA SHEET

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SECTION 1. IDENTIFICATION

Product Name: Applicable Product Code(s): CAS #:Tariff Code: Product Type: Recommended Use: Restrictions for Use:

Company Name: Company Address:

Telephone Emergency Phone Number INFOTRAC (Domestic) INFOTRAC (International) Website Email

Manufacturer Name: Manufacturer Address:

Gunk Glass Cleaner- Streak Free GC33 Mixture 3402.90.5030 Finished Product – Consumer (Retail) Use Only.

Cleaning Use only as directed on label

Blumenthal Brand Integrated, LLC 600 Radiator Road Indian Trail, NC 28079 (704) 821-7643

(800)-535-5053(352)[email protected]

RGA Enterprises INC.4001 Performance Rd. Charlotte, NC, 28208

RGA Contact: Customer Service Department: (704)-398-0487 (8 A.M. to 5:00 P.M. EST, Monday-Friday),[email protected] or National Poison Control Center: (800)-222-1222 or Local Poison Control Center or your physician or Chem Tel: (800)-255-2924

SECTION 2. HARZARDS IDENTIFICATION. See Section 11 for additional information

NOTE: This product is a consumer product and is labeled in accordance with the US Consumer Product Safety Commission

regulations which take precedence over OSHA Hazard Communication labeling. The container label may not include the

OSHA label elements listed in this document. Always carefully review the entire SDS and the product label prior to use in

the workplace.

Hazard Category:

Acute toxicity, oral Acute toxicity, dermal

Category 4 Category 4

Acute toxicity, inhalation Category 4 Skin corrosion, irritation Serious eye damage/ eye irritation

Category 2 Category 2

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Specific target organ toxicity, sing exposure Hazardous to the aquatic environment, acute hazard

Category 3 respiratory track irritation Category 3

Signal Word Warning

Hazard Statements Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. Harmful to aquatic life.

Hazard pictograms

Precautionary Statements- Prevention Use as directed. Keep out of reach of children.

Avoid release to the environment. Wear eye protection/ face protection.

Physical appearance: Liquid

Precautionary Statements- Store in original container. Storage

Precautionary Statements - Dispose of contents/container in accordance with local regulations. Disposal:

Hazardous not otherwise classified None(HNOC)

SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Name Trade Secret CAS-No Wt% Tripropylene Glycol Methyl Ether No 20324-33-8 1-5

Isopropyl Alcohol No 67-63-0 1-3Ammonium Hydroxide No 1336-21-6 < 1

Ammonium Lauryl Ether Sulfate No 32612-48-9 < 1 Tetrasodium EDTA No 64-02-08 < 1

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Precise concentration of ingredients is not used due to protect confidentiality and due to batch variation. Other components are below reportable levels.

SECTION 4. FIRST AID MEASURES

First aid measures for different exposure routes:

Eye contact: Rinse with plenty of water. Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately.

Skin contact: Rinse with plenty of water. Remove contaminated clothing promptly and launder before reuse. Get medical attention immediately if irritation develops or persists.

Inhalation: Move to fresh air. If symptoms persist, call a physician.

Ingestion: Do NOT induce vomiting. Seek medical attention immediately. Contact local Poison Control Center.

Most Important symptoms/effects: Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurredAcute and delayed. vision. Permanent eye damage including blindness could result.

Indication of immediate medical attention and special treatment, if necessary: Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed

Notes to Physician: Treat symptomatically. Keep victim under observation. Symptoms may be delayed.

SECITON 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media: Dry chemical, CO₂, alcohol-resistant foam, or water fog.

Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread fire.

Special hazard: During fire, gases hazardous to health may be formed.

Special protective equipment for As in any fire, wear self-contained breathing apparatus pressure demand. MSHA/NIOSH Fire-fighters (approved or equivalent) and full protective gear.

Specific hazards arising from the None chemical

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures:

Personal precautions: Keep unnecessary personnel away. Keep people away from upwind spill/leak. Use personal protective equipment. Do not get in eyes, on skin, or on clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

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Advice to emergency responders: Use personal protective equipment as required.

Methods and materials for containment and cleaning up:

Methods of Containment: Adsorb with earth, sand or other non-combustible material and transfer to containers for later disposal.

Methods for cleaning up: This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Floor and surfaces may be slippery. Mop up small spills. Dike area with sand or other inert material for large spills. Use absorbent material and disposal according to local / national regulations (see section 13). Following product recovery, flush area with water.

SECTION 7. HANDING AND STORAGE

Precautions for safe handling:

Advice on safe handing: Do not get this material in contact with eyes. Avoid prolonged exposure. Provide adequateventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Use personal protective equipment as required. Keep out of reach of children.

Conditions for safe storage, including any incompatibilities:

Storage Conditions: Store in original tightly closed container. Keep out of the reach of children. Store away from incompatible materials (see Section 10 of the SDS).

Incompatible products: Strong oxidizing agents.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters:

Exposure Guidelines:

Chemical Name CAS-No ACGIH TLV OSHA PEL Ammonium Hydroxide 1336-21-6 25 ppm 18 mg/m3

Isopropyl Alcohol 67-63-0 400 ppm 980 mg/m3

Exposure controls:

Engineering Measures: Distribution, Workplace and Household Settings: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station.

Personal Protective Equipment:

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Eye Protection: Distribution, Workplace and Household Settings: Wear safety glasses with side shields (or goggles) or a face shield.

Hand Protection: Distribution, Workplace and Household Settings: For sensitive skin or prolonged exposure, wear gloves.

Skin and Body Protection: Distribution, Workplace and Household Settings: Wear appropriate chemical resistant gloves. Wear suitable protective clothing.

Respiratory Protection: Distribution, Workplace and Household Settings: Chemical respirator with organic vapor cartridge and full facepiece if threshold limits is exceeded. Dust mask.

Thermal Hazard Distribution, Workplace and Household Settings: Wear appropriate thermal protective clothing, when necessary.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

liquid Clear liquid. Ammonia no information available

Values Note

9-10No information available212 °F (100 °C)No information available< 1 BuAcNo information available

Physical State @ 20°C: Appearance: Odor: Odor threshold:

Property

pH Value Melting/freezing point: Boiling point/boiling range: Flash point: Evaporation rate: Flammability (solid, gas): Flammability Limits in Air: Upper flammability limit: Lower flammability limit: Vapor pressure: Vapor density: Specific Gravity: Water solubility: Solubility in other solvents: Partition coefficient: n-octanol/water: Auto ignition temperature: Decomposition temperature: Viscosity of Product: Percent volatile: VOC Content (%):

No information availableNo information availableNo information available0.00001 hPa estimatedNo information available1.01 g/mLSolubleNo information availableNo information available442 °F (227.78 °C) estimatedNo information availableNo information available98.573 % w/w

SECTION 10. STABILITY AND REACTIVITY

Reactivity: None under normal use conditions

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Stability: Stable under normal conditions.

Hazardous polymerization: Hazardous polymerization does not occur.

Conditions to Avoid: Contact with incompatible materials

Materials to Avoid: Strong oxidizing agents..

Hazardous Decomposition Products: None in particular.

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information: Information on likely routes of exposure.

Inhalation: Prolonged inhalation may be harmful. Skin contact: No adverse effects due to skin contact are expected.Ingestion: Expected to be a low ingestion hazard.Eye contact: Causes serious eye damage.

Delayed and immediate effects as well as chronic effects form short and long-term exposure:

Acute toxicity No known effect. Skin corrosion/irritation Causes skin irritationSerious eye damage/eye irritation Causes serious eye irritation.Skin sensitization No known effect.Respiratory sensitization No known effect.Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are

mutagenic or genotoxic. Neurological Effects No known effect.Reproductive toxicity This product is not expected to cause reproductive effects.Developmental toxicity This product is not expected to cause developmental effects.Teratogenicity No known effect.STOT – single exposure May cause respiratory irritationSTOT – repeated exposure Not Classified.Target Organ Effects No known effect.Aspiration hazard No known effect.Carcinogenicity Not classifiable as to carcinogenicity to humans.

Component Information:

Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation Tripropylene Glycol

Methyl Ether 20324-33-8 Rat- 3500 mg/kg Rabbit- 15440 mg/kg -

Ammonium Hydroxide 1336-21-6 Rat- 350 mg/kg - 5131 mg/m3

Isopropyl Alcohol 67-63-0 Dog 4797 mg/kg Mouse 3600 mg/kg

Rabbit 5.03 g/kg Rat 4.7 g/kg

Rabbit 12800 mg/kg -

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Ammonium Lauryl Ether Sulfate

32612-48-9 Rabbit: >2000 mg/kg Rat- >5000 mg/kg -

Tetrasodium EDTA 64-02-08 Rat- 2000 mg/kg ATE US 2000 mg/kg -

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity:

Harmful to aquatic life

Chemical Name CAS-No Species Test Results Ammonium Hydroxide 1336-21-6 Western mosquitofish

(Gambusia affinis) LC50: 15 mg/l, 96 hours

Isopropyl Alcohol 67-63-0 Bluegill (Lepomis macrochirus) LC50: >1400 mg/l, 96 hours

Persistence and degradability: No information available.

Bioaccumulative potential: Partition coefficient n-octanol / water (log Kow) Isopropyl Alcohol 0.05

Mobility: No information available.

Other adverse effects: No information available.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste Treatment:

Waste from Residues / Unused Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Products regulations. Do not allow this material to drain into sewers/water supplies. Do not

contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Contaminated packaging: Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

General information: DOT Regulated marine pollutant.

Ground Transport (US DOT): Not regulated

IMDG: Not regulated

Air Transport (IATA): Not regulated

SECTION 15. REGULATORY INFORMAITION

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U.S. Federal Regulations

SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations Part 372.

SARA 311/312 Hazardous Categorization: Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactivity Hazard No

U.S, State Regulations (Right-to-know):

Ingredient CAS# CA RTK

CT RTK

FK RTK

IL RTK

LA RTK

MA RTK

MI RTK

NJ RTK

PA RTK

RI RTK

Tetrasodium EDTA 64-02-8 X X X Ammonium Hydroxide 1336-21-6 X X X X

Isopropyl Alcohol 67-63-0 X X X X Tripropylene Glycol Methyl

Ether 25498-49-1 X X

International Inventories:

Country(s) or region Inventory Name On inventory (Yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical No

Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes

(PICCS) United States Toxic Substances Control Act (TSCA) Inventory Yes and Puerto Rico

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governingcountry(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventoryadministered by the governing country(s).

Gunk Glass Cleaner

2-(2-butoxyethoxy) Ethanol (CAS 112-34-5) Soda, Caustic (CAS 1310-73-2)

California Proposition 65: California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov.

US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))


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SECTION 16. OTHER INFORMATION

Other Information:

NFPA HMIS

This SDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. The information contained here has been compiled from sources considered by RGA Enterprises to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an all-inclusive document on worldwide hazard communication regulations.

This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. RGA Enterprises assumed no responsibility for injury to the recipient or third person or for any damage to any property resulting from misuse of the product.

HEALTH

FLAMMABILITY

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PERSONAL PROTECTION

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Revision information This document has undergone significant changes and should be reviewed in its entirety.

3-25-2020 Supersedes: All Previous Issues SAFETY DATA ...

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