2008 CropProtection Newsroom Brochures CropProtectionProductRange

Functional Chemicals Division

Product RangeCrop ProtectionEdition 2008

Auxiliaries for Crop Protection Formulations

Product range

Introduction 4

emulsifiers

Fatty alcohol ethoxylates 6Special emulsifiers 10Tristyrylphenol (TSP) ethoxylates 10Castor oil ethoxylates 12 EO/PO block copolymers 12EO/PO alkoxylation products 14 Nonylphenol ethoxylates 16 Tributylphenol ethoxylates 18

disPersing agents

Anionic condensation products 20Other dispersing agents 20Tristyrylphenol (TSP) ethoxylates, phosphated 22

anionic emulsifiers

Alkylbenzene sulfonates 24

adjuvants

Amine ethoxylates 26 Special adjuvants 28

blends

Emulsifier blends 30Performance blends 30Clariant matched pairs 30

other Products

Sulfosuccinates 32Solvents, crystallization inhibitors 32Glymes – glycol diethers 34 Polyethylene glycols 34

ProDuCt grouP

EC SC SE EW ME OD SL WG, WG,SP WP

Fatty alcohol ethoxylates

tristyrylphenol ethoxylates

Castor oil ethoxylates

Eo/Po block copolymers

Eo/Po alcohol alkoxylates

Nonylphenol ethoxylates

tributylphenol ethoxylates

Dispersing agents

tSP ethoxylates, phosphated

Alkylbenzene sulfonates

Fatty amine ethoxylates

Nonionic / anionic blends

Sulfosuccinates

Solvents / Crystallization inhibitors

ProDuCt rANgE

Description Page

genapol® C Coconut fatty alcohol ethoxylates 6

genapol® LA Lauryl fatty alcohol ethoxylates 6

genapol® o Oleyl alcohol ethoxylates 6

genapol® oX Alcohol ethoxylates based on C12/C15 oxo alcohol 6

genapol® t C16/C18 fatty alcohol ethoxylates 8

genapol® uD Alcohol ethoxylates based on C11 oxo alcohol 8

genapol® X Iso-tridecyl alcohol ethoxylates 8

genapol® XM Iso-tridecyl alcohol ethoxylates methyl ethers 10

Emulsogen® tS Tristyryl phenol ethoxylates 10

Emulsogen® EL Castor oil ethoxylates 12

genapol® PF, ED EO/PO block copolymers 12

genapol® EP Alcohol alkoxylates 14

Arkopal® N Nonylphenol ethoxylates 16

Sapogenat® t Tri-sec.-butylphenol ethoxylates 18

Dispersogen® Dispersing agents of different types 20 / 22

Phenylsulfonat, Calsogen® Anionic emulsifiers (Ca alkylbenzene sulfonates) 24

genamin® C Coconut fatty amine ethoxylates 26

genamin® o Oleyl amine ethoxylates 26

genamin® t Tallow amine ethoxylates 26

Synergen® Adjuvants and bio-enhancers 28

genagen® Fatty acid dimethylamides 32

the aim of this publication is to support our customers in selecting the most suitable clariant product for their formulation needs. it contains the basic information, brand name, composition, active substance content, appearance, hlb value, basic specification, important physical data, and registration information. this information is not intended to replace technical data sheets or safety data sheets.

sYstematic overvieW of the most imPortant Product grouPs and their trade names

Nonylphenol / nonylphenol ethoxylate Directive 2003/53/EC

in general all products mentioned in the brochure are free of nonylphenols and nonylphenol ethoxylates. exceptions are marked as nPe-containing in the „comments“ column and their use is restricted according to directive 2003/53/ec effective from 17th january 2005.see also: http://eur-lex.europa.eu/pri/en/oj/dat/2003/l_178/l_17820030717en00240027.pdfNPE = nonylphenol ethoxylate, APE = alkylphenol ethoxylate

rEACH

according to regulation (ec) no. 1907/2006 (reach), the manufacture or import of chemical substances in volumes exceeding 1 ton per year must be registered at the european chemicals agency (echa) in helsinki. reach registra-tion is related to substances and not products, e.g. preparations/formulations of substances. Production, import and marketing of a reach-substance will be restricted to those uses evaluated in its registration dossier. the reach process starts with preregistration (1st june 2008 until 1st december 2008), which ensures the availability of preregistered substances to the registration date. the date of registration depends on the production volume of the substance and lies between 2010 and 2018. We confirm that we will, pursuant to reach requirements, pre-register all substances manufactured by clariant functional chemicals division in the eu or imported in the eu, that are relevant for the products listed in this bro-chure. however, no guarantee can be given that clariant will offer all listed products in the future, particularly over the 11 year phase of the reach implementation. if reach registration requirements lead to unacceptable costs, clariant will contact its customers to find an appropriate solution.

genapol®, emulsogen®, arkopal®, sapogenat®, dispersogen®, calsogen®, genamin®, synergen®, genagen® are registered trademarks of clariant.

introduction

clariant is a market leader in formulation inerts, serving the agrochemical industry for several decades. our goal is to make agrochemical formulations more efficient and safe for the mutual benefit of manufacturers, consumers and the environment. We are continuously expanding our product range with new surfactants, focusing on safe and sustainable chemistry.clariant offers a complete range of additives for each formulation type and problem.this comprehensive brochure gives an overview of the various products by function. the following table shows the different product groups and their main applications by formulation type.

EC = Emulsifiable concentrate

SC = Suspension concentrate

SE = Suspo-emulsion

EW = Emulsion (oil-in-water)

ME = Microemulsion

OD = Oil dispersion

SL = Soluble concentrate

WG, SP = Water-soluble granules, powder

WG, WP = Water-dispersible granules, powder

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Composition Active cont. (%); Cloud Point Method HLB EPA * Comments Appearance (°C) A B C (calc.)

genapol® C 050 Coconut fatty alcohol polyglycol ether with 5 EO 100; liquid ca. 73,0 10 910, 930 Genapol C 100 also shows adjuvant properties and enhances cuticular penetration (for details see “Pesticide Formulations and Application Systems: 20th volume, ASTM STP 1400”).

genapol® C 070 Coconut fatty alcohol polyglycol ether with 7 EO 100; liquid ca. 50,5 12 910, 930

genapol® C 100 Coconut fatty alcohol polyglycol ether with 10 EO 100; pasty, wax-like ca. 90,5 14 910, 930

genapol® C 120 Coconut fatty alcohol polyglycol ether with 12 EO 100; pasty ca. 67,0 14,5 910, 930

genapol® C 200 Coconut fatty alcohol polyglycol ether with 20 EO 100; pasty, wax-like ca. 77,0 16,5 910, 930

genapol® C 250 Coconut fatty alcohol polyglycol ether with 25 EO 100; pasty, wax-like ca. 60,0 mPas (50°C)

17 910, 930 Product specified by viscosity.

genapol® LA 030 C12/14 fatty alcohol polyglycol ether with 3 EO 100; liquid ca. 54,0 8 910, 930




genapol® LA 100 C12/14 fatty alcohol polyglycol ether with 10 EO 100; pasty ca. 86,0 14 910, 930

genapol® LA 230 C12/14 fatty alcohol polyglycol ether with 23 EO 100; waxy solid ca. 48,5 mg KOH/g

17 910, 930 Product specified by OH number.

genapol® o 050 Oleyl alcohol polyglycol ether with 5 EO 100; liquid ca. 68,5 9 910, 930

genapol® o 080 Oleyl alcohol polyglycol ether with 8 EO 100; liquid-pasty ca. 80,5 11 910, 930

genapol® o 100 Oleyl alcohol polyglycol ether with 10 EO 100; pasty, wax-like ca. 50,0 12 910, 930

genapol® o 120 Oleyl alcohol polyglycol ether with 12 EO 100; pasty ca. 58,0 13 910, 930

genapol® o 150 Oleyl alcohol polyglycol ether with 15 EO 100; wax-like ca. 72,0 14 910, 930

genapol® o 200 Oleyl alcohol polyglycol ether with 20 EO 100; wax-like ca. 75,0 15,5 910, 930

genapol® oX 050 C12/C15 oxo alcohol polyglycol ether with 5 EO 100; liquid ca. 64,0 10 910, 930

genapol® oX 070 C12/C15 oxo alcohol polyglycol ether with 7 EO 100; liquid-pasty ca. 73,0 12 910, 930

genapol® oX 080 C12/C15 oxo alcohol polyglycol ether with 8 EO 100; liquid-pasty ca. 77,0 13 910, 930

genapol® oX 100 C12/C15 oxo alcohol polyglycol ether with 10 EO 100; pasty ca. 63,5 14 910, 930

A: 1% a.i. in water

B: 5g / 25g / 25% BDG

C: 1g / 100ml / 10% NaCl

* EPA: Exempted from tolerance under EPA regulation

40 CFR § 180.xxx

in this brochure a selection of clariant’s most important alkoxylates for crop Protection applications is shown. other types which are not mentioned here may be available locally or on request as well as aqueous emulsifier solutions of certain products (typically 80% or 90% active content) with improved handling properties.

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FAttY ALCoHoL EtHoXYLAtES


genapol® t 250 Powder C16/C18 fatty alcohol polyglycol ether with 25 EO 100; powder ca. 60,0 mPas (70°C)

16 910, 930 Product specified by viscosity.

genapol® t 500 Powder C16/C18 fatty alcohol polyglycol ether with 50 EO 100; powder ca. 105,0 mPas (70°C)

18 910, 930

genapol® t 800 Powder C16/C18 fatty alcohol polyglycol ether with 80 EO 100; powder ca. 60,0 19 910, 930 Product specified by dropping point.

genapol® uD 050 C11 oxo alcohol polyglycol ether with 5 EO 100; liquid ca. 68,0 11 910, 930




genapol® uD 110 C11 oxo alcohol polyglycol ether with 11 EO 100; pasty ca. 63,5 15 910, 930

genapol® X 030 Iso-tridecyl alcohol polyglycol ether with 3 EO 100; liquid ca. 40,0 7 910, 930 Besides their high emulsifying performance, the iso-tridecanol based Genapol X types are also excellent wetting agents.genapol® X 050 Iso-tridecyl alcohol polyglycol ether with 5 EO 100; liquid ca. 60,5 10 910, 930

genapol® X 060 Iso-tridecyl alcohol polyglycol ether with 6 EO 100; liquid ca. 65,5 11 910, 930




genapol® X 150 Iso-tridecyl alcohol polyglycol ether with 15 EO 100; wax-like ca. 70,0 15 910, 930

A: 1% a.i. in water

B: 5g / 25g / 25% BDG

C: 1g / 100ml / 10% NaCl


40 CFR § 180.xxx

FAttY ALKoHoL EtHoXYLAtES


Emulsogen® LP Oleyl alcohol polyglycol ether ca. 100; liquid ca. 70,5 9 910, 930 Emulsogen LP and Emulsogen M are preferred emulsifiers for mineral oils. Both are characterized by a low pour point (ca. 0°C) and remain homogeneous down to ca. 12°C.Emulsogen MC is mainly used as an emulsifier for vegetable oils and leads to improved low temperature stability of the formulation.

Emulsogen® M Oleyl alcohol polyglycol ether ca. 100; liquid ca. 67,0 9 910, 930

Emulsogen® MC Oleyl alcohol polyglycol ether ca. 100; liquid ca. 86,0 11 910, 930

A: 1% a.i. in water

B: 5g / 25g / 25% BDG

C: 1g / 100ml / 10% NaCl

EPA: Exempted from tolerance under EPA regulation

40 CFR § 180.xxx

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tSP-EtHoXYLAtES


Emulsogen® tS 100 2,4,6-Tri(1-phenylethyl)-phenol polyglycol ether with 10 EO

100; liquid

ca. 67,0 10 920


100; liquid

ca. 60,0 13 920


100; liquid-pasty

ca. 57,5 13,5 920


100; wax-like

ca. 68,0 15 920


100; wax-like

ca. 71,0 17 920


100; wax

ca. 73,0 17 920


100; wax

ca. 19 mg KOH/g

17,5 920 Product specified by OH number.

A: 1% a.i. in water

B: 5g / 25g / 25% BDG

C: 1g / 100ml / 10% NaCl


40 CFR § 180.xxx

SPECIAL EMuLSIFIErS

Composition Active cont. (%); OH number HLB EPA * Comments Appearance (mg KOH/g) (calc.)

genapol® XM 060 Iso-tridecyl alcohol ethoxylate methyl ether with 6 EO 100; liquid

max. 11 11 not r. Methylation of iso-tridecanol ethoxylates leads to the Genapol XM types which combine emulsifying as well as wetting power and chemical inertness, e.g. for hydrolytically sensitive active ingredients.

genapol® XM 150 Iso-tridecyl alcohol ethoxylate methyl ether with 15 EO 100; wax-like

max. 7 15 not r.


40 CFR § 180.xxx

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Eo / Po BLoCK CoPoLYMErS

Composition Active cont. (%); Cloud Point Method HLB EPA* Comments Appearance (°C) A B C (calc.)

Emulsogen® V 1816 EO/PO block copolymer 100; pasty ca. 72,9 6 960 Low molecular weight EO/POs typically have a molecular weight below 1000 g/mol. These surfactant molecules are small and flexible and can quickly adhere to newly formed surfaces. Medium molecular weight EO/POs typically cover molecular weights from about 1000 – 3000 g/mol. As a consequence of the increased molecular weight, these products tend to exhibit higher viscosity and/or waxier consistency. Their main application fields are as emulsifiers and dispersants in EC and SC formulations. High molecular weight EO/POs have molecular weights typically above 3000 g/mol and are mostly waxy, only a few being liquid. They are used as co-emulsifiers or dispersants in EC or SC formulations.

Emulsogen® 4084 EO/PO block copolymer 100; wax-like ca. 69,0 17,5 960

genapol® V 5008 EO/PO/EO block polymer 100; wax-like ca. 775 mPas (70°C)*

17,5 960

genapol® PF 10 Block copolymer of EO/PO containing 10% EO 100; liquid ca. 35,4 13,5 960

genapol® PF 20 Block copolymer of EO/PO containing 20% EO 100; liquid ca. 56,8 14 960

genapol® PF 40 Block copolymer of EO/PO containing 40% EO 100; liquid ca. 67,8 16 960

genapol® PF 80 Powder Block copolymer of EO/PO containing 80% EO 100; powder ca. 1200 mPas (70°C)*

19 960

genapol® PF 80 Block copolymer of EO/PO containing 80% EO 100; wax-like ca. 1200 mPas (70°C)*

19 960

genapol® PF 80 FP Block copolymer of EO/PO containing 80% EO 100; powder ca. 1200 mPas (70°C)*

19 960 Genapol PF 80 FP is a finely powdered version of Genapol PF 80.

genapol® ED 1616 Ethylene diamine EO/PO block copolymer 100; liquid ca. 73,0 (10% a.m. in water)

16 960

genapol® ED 3030 Ethylene diamine EO/PO block copolymer 100; viscous liquid ca. 53,6 16 960

genapol® ED 3060 Ethylene diamine EO/PO block copolymer 100; viscous liquid ca. 28,6 15 960

A: 1% a.i. in water

B: 5g / 25g / 25% BDG

C: 1g / 100ml / 10% NaCl


40 CFR § 180.xxx

* Product specified by viscosity.

CAStor oIL EtHoXYLAtES

Composition Active cont. (%); Saponification HLB EPA * Appearance number (mg KOH/g) (calc.)

Emulsogen® EL 200 Castor oil ethoxylate with 20 EO 100; liquid 87,0 – 97,0 10,5 960

Emulsogen® EL 300 Castor oil ethoxylate with 30 EO 100; liquid Cloud point ca. 72,5°C (1% in 20% acetic acid) 12,5 960

Emulsogen® EL 360 Castor oil ethoxylate with 36 EO 100; liquid 64,0 – 69,0 13,5 960

Emulsogen® EL 400 Castor oil ethoxylate with 40 EO 100; pasty 60,0 – 64,0 14 960

Emulsogen® EL 540 Castor oil ethoxylate with 54 EO 100; pasty 49,0 – 53,0 15 960


40 CFR § 180.xxx

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Eo / Po ALKoXYLAtIoN ProDuCtS


Emulsogen® V 2436 Fatty alcohol alkoxylate 100; wax-like ca. 67,0 11 not reg.

Emulsogen® 3510 n-Butanol alkoxylate 100; wax-like ca. 85,0 11 960

Emulsogen® EP 4901 n-Butanol alkoxylate 100; liquid ca. 73,5 16,5 960 Emulsogen EP 4901 is a liquefied alternative to Emulsogen 3510 for easier handling.

genapol® EP 4103 n-Butanol alkoxylate 100; liquid ca. 29,0 14 960

Emulsogen® NPA 200 Nonylphenol alkoxylate 100; viscous liquid

ca. 72,5 16 not reg. NPE-containing.

Emulsogen® ItA 200 Iso-tridecyl alcohol alkoxylate 100; viscous liquid

ca. 72,5 16 960 Emulsogen ITA 200 is an APE-free alternative to Emulsogen NPA 200 and Emulsogen TBA 200.

Emulsogen® tBA 200 Tributylphenol alkoxylate 100; viscous liquid

ca. 72,5 15,5 not reg.

genapol® EP 0244 Fatty alcohol alkoxylate 100; liquid ca. 36,5 11 not reg.

genapol® EP 0858 Fatty alcohol alkoxylate 100; liquid ca. 51,0 12,5 not reg.

genapol® EP 1182 Fatty alcohol alkoxylate 100; liquid ca. 59,0 13,5 910 Genapol EP 1182 exhibits excellent spreading/wetting properties and a very good cold water solubility.

genapol® EP 2424 Fatty alcohol alkoxylate 100; liquid ca. 26,0 9 not reg.

genapol® EP 2464 Fatty alcohol alkoxylate 100; liquid ca. 44,0 12 910, 930

genapol® EP 2544 Fatty alcohol alkoxylate 100; liquid ca. 32,0 10 920

genapol® EP 2552 Fatty alcohol alkoxylate 100; liquid ca. 40,0 10,5 not reg.



A: 1% a.i. in water

B: 5g / 25g / 25% BDG

C: 1g / 100ml / 10% NaCl


40 CFR § 180.xxx

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NoNYLPHENoL EtHoXYLAtES

Composition Active cont. (%); Cloud Point Method HLB EPA* NPE- Comments Appearance (°C) A B C (calc.) containing

Arkopal® N 040 Nonylphenol polyglycol ether with 4 EO 100; liquid

ca. 37,0 9 910 – 930


ca. 62,0 11 910 – 930


ca. 33,0 12,5 910 – 930


ca. 53,0 13 910 – 930 NPE replacements: As substitutes for Arkopal N 090 and N 100 we recommend ethoxylates based on synthetic alcohols, e.g. Genapol OX 070, 080, 100 – Genapol UD 070, 080 – Genapol X 080.


ca. 63,5 13,5 910 – 930


ca. 72,5 14 910 – 930


ca. 84,5 15 910 – 930

Arkopal® N 150 Nonylphenol polyglycol ether with 15 EO 100; liquid-pasty

ca. 62,0 15,5 930

Arkopal® N 200 Nonylphenol polyglycol ether with 20 EO 100; pasty

ca. 71,5 16,5 not reg.


ca. 74,0 17,0 not reg.


ca. 76,5 18 910 – 930

A: 1% a.i. in water

B: 5g / 25g / 25% BDG

C: 1g / 100ml / 10% NaCl


40 CFR § 180.xxx

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trIButYLPHENoL EtHoXYLAtES


Sapogenat® t 040 Tri-sec-butylphenol polyglycol ether with 4 EO 100; liquid

ca. 27,5 8 not reg. 4-Nonylphenol ethoxylates (NPEs) and 4-Octylphenol ethoxylates (OPEs) as well as the underlying phenols are listed in the EU SEC (2004) Document as substances with evidence of endocrine- disrupting effects (Category 1) whereas 2,4,6-Tri-sec.-butylphenol as well as its ethoxylated derivatives (Sapogenat T types) are not listed.Based on the structural elements of known endocrine disrupters (EDs), it is likely that the endocrine-disrupting effect of alkylphenols and derived ethoxylates is associated with

- a para-substituted alkyl group on the aromatic ring with at least 3 carbon atoms- no polyalkylation on the aromatic ring Supporting evidence was obtained using three different in vitro receptor binding tests with Sapogenat T 130 and 2,4,6-Tri-sec.- butylphenol in which both molecules did NOT show endocrine- disrupting effects in any of these tests. In these test models the known EDs estradiol and 4-Octylphenol clearly showed endocrine-disrupting effects demonstrating the suitability of the test models.

Based on available scientific facts published in literature as well as on the results from 3 different in vitro tests it can be concluded in a weight of evidence approach that it is unlikely that 2,4,6-Tri-sec.-butylphenol and the ethoxylated derivatives (Sapogenat T types) exhibit endocrine-disrupting effects.


ca. 54,7 10 not reg.





Sapogenat® t 130 Tri-sec-butylphenol polyglycol ether with 13 EO 100; liquid-pasty


Sapogenat® t 180 Tri-sec-butylphenol polyglycol ether with 18 EO 100; wax-like



ca.70 mPas (70°C)*

17 not reg.


ca. 140 mPas (70°C)*

18 not reg.

A: 1% a.i. in water

B: 5g / 25g / 25% BDG

C: 1g / 100ml / 10% NaCl


40 CFR § 180.xxx

* Product specified by viscosity.

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ANIoNIC CoNDENSAtIoN ProDuCtS

Composition Active cont. (%); Type Water solubility EPA* Comments Appearance

Dispersogen® 1494 Sodium salt of a cresol-formaldehyde condensation product

ca. 80; powder

anionic yes not reg.

Dispersogen® 1494 liq. Sodium salt of a cresol-formaldehyde condensation product

ca. 35; liquid


rapidaminreserve CL Sodium salt of a cresol-formaldehyde condensation product

ca. 35; liquid


Dispersogen® SI Combination of anionic surfactants mixed with a carrier

ca. 62; powder

anionic no 910, (920), 930


40 CFR § 180.xxx

otHEr DISPErSINg AgENtS


Hostapon® tPHC Fatty acid methyl tauride sodium salt ca. 60-65; powder

anionic yes 910, 930, (950) All products displayed under Other dispersing agents are APE-free. Clariant has recently extended its range of dispersing agents for agro formulations with new and environmentally friendly products. These dispersing agents are polymers and are available as highly concentrated products.

Dispersogen® PSL 100 Polyacrylate graft copolymer ca. 100; pasty

non-ionic yes not reg.

Dispersogen® 4387 Anionic polymeric ester ca. 80; liquid


Dispersogen® S-r Nonionic polyester ca. 70; liquid

non-ionic yes not reg.

Dispersogen® S-rA Anionic modified polyester ca. 100; powder


Dispersing Agent 3618 Phosphate ester of EO-PO-EO blockpolymer ca. 97; wax

anionic yes 920, 960


40 CFR § 180.xxx

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tSP-EtHoXYLAtES, PHoSPHAtED


Dispersogen® LFH 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester

ca. 97; liquid

anionic yes 920 Phosphated TSP ethoxylates are anionic emulsifiers and dispersing agents.Dispersogen TP and LF types differ in their degree of ethoxylation (TP: 16 moles EO, LF: 20 moles EO) and their mono-/diester ratio.The LF types are stand-alone products that offer better electrolyte stability compared to the TP types as well as higher dispersing power at low dispersion viscosity.

Dispersogen® LFS 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester triethanolamine salt

ca. 96; viscous liquid


Dispersogen® LFA * 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester ammonium salt


anionic yes 920

Dispersogen® tP 160 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester

ca. 97,5; viscous liquid

anionic yes 920

Dispersogen® tP 160 t 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester triethanolamine salt

ca. 97,5; viscous liquid


Dispersogen® tP 166 t * 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester triethanolamine salt

ca. 60; liquid


Dispersogen® tP 169 A * 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester ammonium salt


anionic yes 920

* Development product; samples available * EPA: Exempted from tolerance under EPA regulation

40 CFR § 180.xxx

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ALKYLBENzENE SuLFoNAtES

Composition Solvent Type Active content (%); Flash point EPA* Water content Comments Appearance (°C) K.F. (%)

Phenylsulfonat CA iso-C12 alkyl benzene sulfonate calcium salt Isobutanol branched ca. 70; viscous liquid

33°C 910, (920), 930

max. 0,5 The ND types (“Naphthalene Depleted”) are alkylbenzene sulfonates in a solvent with a low content of naphthalene (max. 0,9 %).

Phenylsulfonat CA 62 iso-C12 alkyl benzene sulfonate calcium salt Isobutanol branched ca. 62; viscous liquid

33°C 910, (920), 930

max. 0,5

Phenylsulfonat CAL n-C12 alkyl benzene sulfonate calcium salt Isobutanol linear ca. 70; viscous liquid

33°C 910, (920), 930

max. 0,5

Calsogen® Ar 100 iso-C12 alkyl benzene sulfonate calcium salt Solvesso® 200 branched ca. 40+10; liquid

> 100°C 910, 930 max. 0,5

Calsogen® Ar 100 ND iso-C12 alkyl benzene sulfonate calcium salt Solvesso® 200 ND branched ca. 40+10; liquid

> 100°C 910, 930 max. 0,5

Calsogen® Ar 62 ND iso-C12 alkyl benzene sulfonate calcium salt Solvesso® 150 branched ca. 40+10; liquid

ca. 62°C 910, 930 max. 0,5

Calsogen® ArL 100 ND n-C12 alkyl benzene sulfonate calcium salt Solvesso® 200 ND linear ca. 40+10; liquid

> 100°C 910, 930 max. 0,5

Calsogen® ArL 48 n-C12 alkyl benzene sulfonate calcium salt Solvesso® 100 linear ca. 50+7; liquid

ca. 48°C 910, 930 max. 0,5

Calsogen® EH iso-C12 alkyl benzene sulfonate calcium salt 2-Ethylhexanol branched ca. 58; viscous liquid

> 60°C 910, (920), 930

max. 0,5

Calsogen® 4814 n-C12 alkyl benzene sulfonate calcium salt 2-Ethylhexanol linear ca. 58; viscous liquid

> 60°C 910, (920), 930

max. 0,5

Solvesso ® is a registered trademark of Exxon. * EPA: Exempted from tolerance under EPA regulation

40 CFR § 180.xxx

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AMINE EtHoXYLAtES

Composition Appearance Alkaline number EPA* Comments (mg KOH/g)

genamin® C 020 Cocos fatty amine ethoxylate with 2 EO liquid 190 – 205 920 Clariant offers a broad range of fatty amine ethoxylates based on different fatty amines and with different degrees of ethoxylation.For amine ethoxylates containing a solubilizer, refer to Special Adjuvants.

genamin® C 050 Cocos fatty amine ethoxylate with 5 EO liquid 129 – 137 920




genamin® o 050 Oleyl amine ethoxylate with 5 EO liquid 111 – 117 920

genamin® o 200 Oleyl amine ethoxylate with 20 EO liquid 47 – 57 920

genamin® t 050 Tallow fatty amine ethoxylate with 5 EO liquid 110 – 118 920




genamin® t 250 Tallow fatty amine ethoxylate with 25 EO pasty, wax-like 39 – 42 920


40 CFR § 180.xxx

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SPECIAL ADJuVANtS

Composition Appearance EPA* Application Comments

genamin® 267 Amine ethoxylate containing a solubilizer liquid 910, 920, 930

Formulated adjuvant for Glyphosate SL formulations, easily dissolves in water without gelation.

Special Adjuvants are tailor-made products for dedicated types of active ingredients with a proven performance as bio-enhancers.Benefits are formulations with the highest efficacy, minimizing the usage level of pesticides – saving costs and increasing environmental compatibility. Please enquire for additional information about our Special Adjuvants range or guide recipes.

genamin® 700 Amine ethoxylate containing a solubilizer liquid 910, 920, 930

Formulated adjuvant for Glyphosate SL formulations.

Synergen® gL 5 Copolymer of glycerol, esterified viscous liquid 910, 930 Proprietary polyglycerol-based adjuvant which is derived from natural starting materials, showing excellent performance with Glyphosate. Environmentally friendly; very favorable tox / ecotox properties, no hazard labeling required. Due to its structure, it also has excellent dispersing properties.

Synergen® g2D Aqueous solution of an amphoteric adjuvant liquid not reg. Adjuvant for Glyphosate.

Synergen® 9903 Aqueous solution of an amphoteric adjuvant liquid not reg. Adjuvant for Glyphosate.

Synergen® HY Aqueous solution of a quaternary ammonium salt

liquid not reg. Adjuvant for Glyphosate.

Synergen® SW-100 Specialty silicone liquid 910 Silicone-based superwetter, enhances spreading and penetration. Suitable as tank-mix or in-can adjuvant.

Synergen® BB Copolymer of glycerol, esterified liquid 910, 930 Proprietary polyglycerol-based adjuvant for bentazone with very favorable tox / ecotox properties, no hazard labeling required. For further information see our Newsletter on Bentazone.

Synergen® IB 775 Copolymer of glycerol, esterified liquid 910, 930 Proprietary polyglycerol-based adjuvant with increased hydropho-bic character and very good dispersing properties. Suitable as tank-mix or in-can adjuvant.

Synergen® KN Adjuvant blend liquid 910, 920, 930

Efficient adjuvant blend for fungicides (e.g. Tebuconazole and Azoxystrobin). Proven performance as tank-mix or in-can adjuvant.

Synergen® g-HL Amine alkoxylates containing a solubilizer liquid not reg. Proprietary high performance adjuvant blend for Glyphosate high-load formulations, efficient at low dosages. Suitable as tank-mix or in-can adjuvant.

Synergen® g-S Amine alkoxylate solid not reg. Proprietary adjuvant for Glyphosate solid formulations.


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EMuLSIFIEr BLENDS

Description Active content (%); EPA* APE-free Comments Appearance

Emulsogen® IC Blend of anionic and nonionic surfactants ca. 70,5; viscous liquid

910, (920), 930

Emulsogen® ICL Blend of anionic and nonionic surfactants ca. 78,0; viscous liquid

910, (920), 930

Emulsogen® It Blend of anionic and nonionic surfactants ca. 85; liquid 910, (920), 930, 960

Emulsogen® ItL Blend of anionic and nonionic surfactants ca. 80; liquid 910, (920), 930, 960

Emulsogen® t Blend of anionic and nonionic surfactants ca. 100; liquid 910, (920), 930

Emulsogen T is an excellent emulsifier for natural oils.

Emulsogen® PSI 100 Blend of anionic and nonionic surfactants ca. 100; liquid not reg.

Emulsogen® PSI B Blend of anionic and nonionic surfactants ca. 80; liquid not reg.

PErForMANCE BLENDS

Description Active content (%); EPA* NPE-free Comments Appearance

Emulsogen® B 350 Blend of anionic and nonionic surfactants in organic solvent for Endosulfan EC

ca. 90; liquid not reg. Clariant’s Performance Blends include everything which is needed for easy and successful formulation: A well balanced combination of emulsifiers and adjuvants. Performance Blends are available for specific formulations of major active ingredients. Please enquire for Performance Blends for additional formulations. Emulsogen® tB 200 Blend of anionic and nonionic surfactants

in organic solvent for Tebuconazole ECca. 25; liquid 920

Emulsogen® P 250 Blend of anionic and nonionic surfactants in organic solvent for Propiconazole EC

ca. 52; liquid 920

Emulsogen® MPB Blend of anionic and nonionic surfactants in organic solvent for Methyl-Parathion

ca. 74; liquid 910, (920), 930, 960

Synergen® PW Blend of anionic and nonionic surfactants for Paraquat

ca. 46; liquid 910 – 930

CLArIANt MAtCHED PAIrS

Description Active content (%); EPA* APE-free Comments Appearance

Emulsogen® MP 1 Blend of anionic and nonionic surfactants ca. 100; liquid 910, (920), 930, 960

The matched pairs emulsifiers are a versatile, APE-free system containing only a few components for multiple active ingredient solutions. Matched pairs are emulsifier blends with optimized performance. So numerous active ingredients can be formulated with only a few (up to three) blends, saving space and time. Guide recipes for formulations are available on request.Emulsogen® MP 2 Blend of anionic and nonionic surfactants ca. 100; liquid 910, (920),

930, 960

Emulsogen® MP 3 Blend of anionic and nonionic surfactants ca. 100; liquid 910, (920), 930


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SuLFoSuCCINAtES

Composition Active content (%); EPA* Water content Flash point Comments Appearance K.F. (% ) (°C)

Emulsogen® SF 8 Aqueous solution of sodium dioctyl sulfosuccinate

ca. 50; liquid

910, 930 ca. 48,5 > 100 Dioctyl sulfosuccinates are versatile surfactants, having outstanding wetting power (fast wetters) and dispersing properties.The broad choice of different solvents makes it possible to find a grade which is suitable for many different formulation types. Synergen W 02 and W 03 are very suitable for hydrolytically unstable active ingredients due to their very low water content.

Synergen® W 02 Sodium dioctyl sulfosuccinate in aromatic solvent, naphthalene-depleted

ca. 60; liquid

910, 930 < 0,1 > 100

Synergen® W 03 Sodium dioctyl sulfosuccinate in aromatic solvent

ca. 64; liquid

910, 930 < 0,1 ca. 63

Synergen® W 09* Sodium dioctyl sulfosuccinate in white oil ca. 58; liquid

910, 930 < 0,1 > 100

* Development product; samples available

SoLVENtS, CrYStALLIzAtIoN INHIBItorS

Composition Active content (%); EPA* Water content Comments Appearance K.F. (% )

genagen® 4166 Dimethylamide of C8/C10 fatty acid ca. 100; liquid

920 < 0,5 Genagen types are versatile solvents, co-solvents and crystallization inhibitors.

genagen® 4231 Dimethylamide of C8/C10 fatty acid ca. 100; liquid

920 < 0,5

genagen® 4296 Dimethylamide of C10 fatty acid ca. 100; liquid

920 < 0,5


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gLYMES – gLYCoL DIEtHErS

Composition Active content (%) Water content EPA* Flash point Kinematic viscosity Water solubility Comments K.F. (% ) (°C) at 20°C (mm 2/s) at 20°C (% w/w)

tetraglyme Tetraethylene glycol dimethyl ether > 99 max. 0,2 not reg. 141 4,1 100 Glymes are versatile solvents with varying properties, depending on the degree of condensation and type of alkyl groups.

Dipropylene glycol DME can also be used as an NMP replacement.

All products selected here are non-toxic and require no hazard labeling. For more glymes and further information see also Clariant’s brochure “Your functional fluid, Glymes – Glycol Diethers”.

Dipropylene glycol DME Dipropylene glycol dimethyl ether > 99 max. 0,05 not reg. 65 1,1 35

Polyglycol DME 500 Polyethylene glycol dimethyl ether > 98 max. 0,3 not reg. 220 29 100

Butyldiglyme Diethylene glycol dibutyl ether > 99 max. 0,05 not reg. 120 2,4 0,3

Polyglycol BB 300 Polyethylene glycol dibutyl ether > 99 max. 0,2 not reg. 151 4 – 5 2

PoLYEtHYLENE gLYCoLS

Composition Appearance Water content EPA* OH number Viscosity Comments K.F. (%) (mg KOH/g) at 20°C (mPas)

Polyglykol 300 Polyethylene glycol with MM 300, PEG-6 liquid max. 0,5 910, 930 356 – 394 88 – 96 Polyethylene glycols are used in agrochemical formulations as humectants, compatibilizers, and to increase low temperature stability. Additionally, certain PEGs also increase the bio-availability of active ingredients.For more polyethylene glycols and further information see also Clariant’s Polyalkylene / polyethylene glycols brochure.

Polyglykol 400 Polyethylene glycol with MM 400, PEG-8 liquid max. 0,5 910, 930 267 – 295 112 – 124

Polyglykol 600 Polyethylene glycol with MM 600, PEG-12 wax max. 0,5 910, 930 178 – 197 17 –18 (50% in water)

Polyglykol 1000 Polyethylene glycol with MM 1000, PEG-20 wax / melt max. 0,5 910, 930 107 – 118 24 – 28 (50% in water)

Polyglykol 2000 S Polyethylene glycol with MM 2000, PEG-40 flakes max. 0,5 910, 930 51 – 62 50 – 58 (50% in water)

Polyglykol 4000 S Polyethylene glycol with MM 4000, PEG-90 flakes max. 0,5 910, 930 25 – 30 114 – 142 (50% in water)

Polyglykol 6000 S Polyethylene glycol with MM 6000, PEG-150 flakes max. 0,5 910, 930 17 – 20 210 – 262(50% in water)


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this information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. it should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. any existing industrial property rights must be observed. the quality of our products is guaranteed under our general conditions of sale.

® trademark of clariant registered in numerous countries.© 2008 clariant international ag, rothausstrasse 61, 4132 muttenz, switzerland

Clariant International Ltd.

Functional Chemicals Division

marketing crop Protection4132 muttenz switzerland Phone +41 61 46 977 67 fax +41 61 46 975 12

Clariant Produkte (Deutschland) gmbH

functional chemicals divisionresearch & development crop Protection65926 frankfurt am main germany Phone +49 69 305 80 234 fax +49 69 318 435

Internet or Email:

http://[email protected]

2008 CropProtection Newsroom Brochures CropProtectionProductRange

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