1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8...

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Transcript of 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8...

Page 1: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 2: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 3: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 4: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 5: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 6: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 7: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 8: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 9: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 10: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 11: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 12: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 13: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 14: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 15: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 16: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 17: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic
Page 18: 1HNMR2013 Mary - udel.edu · Diastereotopic Protons: not just in cyclic systems 0 3.6 8.0 Hz, 4.8 Hz 3.g ppm, J 6.8, 4.8 Hz 4.5 ppm, dd. 6.8, 8.0 Still diastereotopic Diastereotopic

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Diastereotopic group selectivity and chemoselectivity of … · 2013. 8. 30. · S1 Diastereotopic group selectivity and chemoselectivity of alkylidene carbene reactions on 8-oxabicyclo[3.2.1]oct-6-ene

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