1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl
Transcript of 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl
![Page 1: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/1.jpg)
1�
Copies spectra
1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl3
��
N
O
Copies of spectra
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry.This journal is © The Royal Society of Chemistry 2014
![Page 2: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/2.jpg)
2�
�
13C NMR spectrum (Varian, 100 MHz) of compound 3a in CDCl3
��
�
�
�
�
�
�
�
�
N
O
![Page 3: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/3.jpg)
3�
�
N
O
![Page 4: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/4.jpg)
4�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3b in CDCl3
�
13C NMR spectrum (Varian, 100 MHz) of compound 3b in CDCl3
�
����
N
O Cl
N
O Cl
![Page 5: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/5.jpg)
5�
�
�
�
�
N
O Cl
![Page 6: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/6.jpg)
6�
�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3c in CDCl3 + rotamers
�
�
N
O
I
![Page 7: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/7.jpg)
7�
������������������������������13C NMR spectrum (Varian, 100 MHz) of compound 3c in CDCl3�
�
�
�
�
�
�
�
�
�
�
�
N
O
I
![Page 8: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/8.jpg)
8�
�
�
�
�
�
N
O
I
![Page 9: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/9.jpg)
9�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3d in CDCl3
�
�
��
N
O
Cl
Br
![Page 10: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/10.jpg)
10�
�
������������������������13C NMR spectrum (Varian, 100 MHz) of compound 3d in CDCl3 �
�
�
�
�
�
�
�
�
�
N
O
Cl
Br
![Page 11: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/11.jpg)
11�
�
�
�
�
�
�
N
O
Cl
Br
![Page 12: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/12.jpg)
12�
�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3e in CDCl3
�
�
��
N
O
Br
![Page 13: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/13.jpg)
13�
�
13C NMR spectrum (Varian, 100 MHz) of compound 3e in CDCl3�
�
�
� �
�
�
�
�
�
�
N
O
Br
![Page 14: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/14.jpg)
14�
�
�
�
�
�
N
O
Br
![Page 15: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/15.jpg)
15�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3f in CDCl3 �
�
�
�
�
�
�
�
�
�
N
O
Cl
![Page 16: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/16.jpg)
16�
�
�
����������� 13C NMR spectrum (Varian, 100 MHz) of compound 3f in CDCl3�
�
�
�
�
�
�
�
�
N
O
Cl
![Page 17: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/17.jpg)
17�
�
�
�
�
�
N
O
Cl
![Page 18: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/18.jpg)
18�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3g in CDCl3 �
���
�
�
�
�
�
�
�
N
O
Cl
![Page 19: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/19.jpg)
19�
�
�������������������������������13C NMR spectrum (Varian, 100 MHz) of compound 3g in CDCl3�
�
�
�
�
�
�
�
�
�
N
O
Cl
![Page 20: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/20.jpg)
20�
�
�
�
�
�
�
N
O
Cl
![Page 21: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/21.jpg)
21�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3h in CDCl3 ���
�
N
O
H3C
![Page 22: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/22.jpg)
22�
�
13C NMR spectrum (Varian, 100 MHz) of compound 3h in CDCl3�
��
�
�
�
�
�
�
�
N
O
H3C
![Page 23: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/23.jpg)
23�
�
�
�
�
�
N
O
H3C
![Page 24: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/24.jpg)
24�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3i in CDCl3 ����
�
�
�
�
�
N
O CH3
![Page 25: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/25.jpg)
25�
�
�����������������������������������13C NMR spectrum (Varian, 100 MHz) of compound 3i in CDCl3 �
��
�
�
�
�
�
�
�
�
N
O CH3
![Page 26: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/26.jpg)
26�
�
�
�
�
�
N
O CH3
![Page 27: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/27.jpg)
27�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3j in CDCl3 ���
�
�
�
�
�
�
�
�
�
�
�
�
�
�
N
O I
![Page 28: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/28.jpg)
28�
�
�
�
�
�
�
�
13C NMR spectrum (Varian, 100 MHz) of compound 3j in CDCl3 �
�
�
�
N
O I
![Page 29: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/29.jpg)
29�
�
N
O I
![Page 30: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/30.jpg)
30�
�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3k in CDCl3 ��
��
�
�
�
�
�
�
�
�
�
�
N
O
Cl
Cl
![Page 31: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/31.jpg)
31�
�
13C NMR spectrum (Varian, 100 MHz) of compound 3k in CDCl3 �
��
�
�
�
�
�
�
�
�
�
N
O
Cl
Cl
![Page 32: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/32.jpg)
32�
�
�
N
O
Cl
Cl
![Page 33: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/33.jpg)
33�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3l in CDCl3 ����
��
�
�
�
�
�
N
O
Cl
Cl
![Page 34: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/34.jpg)
34�
�
13C NMR spectrum (Varian, 100 MHz) of compound 3l in CDCl3 �
��
�
�
�
�
�
�
N
O
Cl
Cl
![Page 35: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/35.jpg)
35�
�
N
O
Cl
Cl
![Page 36: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/36.jpg)
36�
�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3m in CDCl3 ���
�
�
�
�
�
�
�
�
N
O
ClCl
![Page 37: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/37.jpg)
37�
�
�
�
�
13C NMR spectrum (Varian, 100 MHz) of compound 3m in CDCl3��
�
�
�
�
�
N
O
ClCl
![Page 38: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/38.jpg)
38�
�
�
�
N
O
ClCl
![Page 39: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/39.jpg)
39�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3n in CDCl3 ���
�
�
�
�
N
O
Cl
Cl
![Page 40: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/40.jpg)
40�
�
13C NMR spectrum (Varian, 100 MHz) of compound 3n in CDCl3��
�
�
�
�
�
�
�
�
N
O
Cl
Cl
![Page 41: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/41.jpg)
41�
�
N
O
Cl
Cl
![Page 42: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/42.jpg)
42�
1H NMR (Varian, 400 MHz) spectrum of compound 3o in CDCl3 ���
�
�
�
�
�
�
�
�
�
�
�
�
�
N
O
Cl
Cl
![Page 43: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/43.jpg)
43�
�
13C NMR spectrum (Varian, 100 MHz) of compound 3o in CDCl3��
��
�
�
�
�
�
�
N
O
Cl
Cl
![Page 44: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/44.jpg)
44�
�
�
�
N
O
Cl
Cl
![Page 45: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/45.jpg)
�
�
�
1H NMR (Varian, 400 MHz) spectrum of compound 3p in CDCl3��
N
O
![Page 46: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/46.jpg)
�
13C NMR spectrum (Varian, 100 MHz) of compound 3p in CDCl3
�
�
N
O
![Page 47: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/47.jpg)
�
1H NMR (Varian, 400 MHz) spectrum of compound 3q in CDCl3��
![Page 48: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/48.jpg)
�
13C NMR spectrum (Varian, 100 MHz) of compound 3q in CDCl3
![Page 49: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/49.jpg)
1H NMR (Varian, 400 MHz) spectrum of compound 3r in CDCl3
� 13C NMR spectrum (Varian, 100 MHz) of compound 3r in CDCl3
![Page 50: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/50.jpg)
45�
�
1H NMR (Varian, 400 MHz) spectrum of compound 4a in CDCl3 ���
��
�
�
�
�
�
�
�
�
�
�
�
�
�
N
O Ph
PhO
![Page 51: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/51.jpg)
46�
�
�
13C NMR spectrum (Varian, 100 MHz) of compound 4a in CDCl3��
���
�
�
�
�
�
�
�
�
�
�
�
N
O Ph
PhO
![Page 52: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/52.jpg)
47�
�
�
�
�
�
N
O Ph
PhO
![Page 53: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/53.jpg)
48�
�
1H NMR (Varian, 400 MHz) spectrum of compound 4b in CDCl3 ���
�
�
�
�
�
�
�
�
�
�
�
�
�
N
O Ph
OCH3
![Page 54: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/54.jpg)
49�
13C NMR spectrum (Varian, 100 MHz) of compound 4b in CDCl3��
��
�
�
�
�
�
�
�
�
�
�
�
N
O Ph
OCH3
![Page 55: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/55.jpg)
50�
�
�
��
�
N
O Ph
OCH3
![Page 56: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/56.jpg)
�
1H NMR (Varian, 400 MHz) spectrum of compound 5a in CDCl3��
NH
PhO
5a
![Page 57: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/57.jpg)
51�
�
�
1H NMR (Varian, 400 MHz) spectrum of compound 5a in CDCl3 ���5b
![Page 58: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/58.jpg)
52�
13C NMR spectrum (Varian, 100 MHz) of compound 5a in CDCl3�
�
��
�
�
�
�
�
�
�
�
�
5b
![Page 59: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/59.jpg)
53�
�
�
�
�
�
1H NMR (Varian, 400 MHz) spectrum of compound 6 in CDCl3 ����
��
�
�
�
�
N
7
![Page 60: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/60.jpg)
54�
13C NMR spectrum (Varian, 100 MHz) of compound 6 in CDCl3��
�
�
�
�
�
�
�
�
�
N
7
![Page 61: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/61.jpg)
55�
IH NMR (Varian, 400 MHz) spectrum of compound 7 in CDCl3 ���
�
�
�
�
�
�
�
�
�
�
�
�
�
N
O
8
![Page 62: 1H NMR (Varian, 400 MHz) spectrum of compound 3a in CDCl](https://reader031.fdocuments.us/reader031/viewer/2022021522/620a6b05624a9d2d5a02ea8f/html5/thumbnails/62.jpg)
56�
�
�
13C NMR spectrum (Varian, 100 MHz) of compound 7 in CDCl3��
�
N
O
8