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    MACHINING SCIENCE AND TECHNOLOGY, 1 1 , 3 52 1997

    mVIEW

    ARTICLE

    M CHINING OF FIBER REINFORCED

    COMPOSITES

    Ranga Komanduri

    Mechanical and Aerospace Engineering,

    Oklahoma State University, Stillwater, Oklahoma

    Received

    pril

    18, 1996;

    epted

    January 30 1997

    ABSTRACT

    Since the introduction of glass fiber-reinforced polymer composites

    in the early 1940s, composite materials development was driven by the

    needs of space, defense, and aircraft industries where performance rather

    than cost was the prime consideration. At the beginning, conventional

    machining techniques were adopted to machine glass fiber-reinforced

    composites for convenience as well as to keep the capital costs down.

    This was followed by significant advancements in tool materials and tool

    ing design. With the development of new and more challenging metal

    matrix and ceramic-matrix composites, conventional manufacturing pro

    cesses proved to be inadequate or even inappropriate to process them.

    Need and opportunity, therefore, exists for alternate nontraditional ma

    chining operations, such as laser machining, water jet WJ and abrasive

    water jet AWJ cutting, electrical discharge machining, ultrasonic-as

    sisted machining, and electrochemical spark machining. When composites

    become more popular and are used in large volume in the civilian sector,

    such as auto and other consumer industries, material and processing costs

    will be the driving factors. A high degree of automation for the mass

    manufacturing of composite parts will be required to bring the costs down

    and compete with other materials. Advancements in the nontraditional

    machining processes offer an opportunity to process these materials ec

    onomically, thus realizing the full potential of the composite materials.

    This paper gives a broad overview on the various issues involved in

    machining conventional and nonconventional of fiber-reinforced com

    posites. The field of composites, in general, and machining

    of composites,

    in particular, are so broad that it would not be possible to do justice by

    Copyright 1997 by Marcel Dekker, Inc.

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    KOMANDURI

    discussing each aspect of composite material machining without ending

    up with a voluminous document This

    review

    therefore has to be limited

    to a few aspects of composite materials and their machining techniques.

    may also be pointed out that in this reviewcertain areas are dealt more

    in-depth than others. Personal preferences and availability of material in

    the open literature are some of the reasons for this nonuniformity in

    coverage. Also, some areas are more actively pursued than others.

    An

    attempt is made to highlight some of the issues and opportunities in the

    area of machining of composites.

    INTRODUCTION

    Our technologically advancing society is continually challenging the

    limits of conventional materials and newer demands on performance. Extreme

    and sometimes conflicting requirements are forcing us to engineer materials

    not possible by conventional alloying methods. Composite materials come

    under one class of engineered material developed specifically to meet this

    challenge. Glass-reinforced resin matrix composites were first introduced in

    the early 1940s. Since then, the use of composites is growing steadily in

    various industries including aerospace, aircraft, automobile, sporting goods,

    marine, off-shore drilling platforms, appliances, etc.

    Composite materials form a material system composed of a mixture or

    a combination

    of

    two or more macroconstituents that differ in form and chem

    ical composition and are insoluble in each other 1). The matrix or the re

    inforcing fibers can be inorganic e.g., ceramic or glass), organic polymers),

    or metallic aluminum, titanium, etc.). While the term composite materials

    could apply to any duplex alloy depending on the scale

    of

    reference), it is

    commonly used to describe a material whose components do not form to

    gether as an alloy during processing but have been separately manufactured

    prior to the combining process

    2-5).

    This definition is extended today to

    composites that can be directly cast from the melt by unidirectional solidifi

    cation

    of

    certain alloys

    of

    eutectic compositions 6). However, for this ma

    terial to be classified as a composite material it must be capable of supporting

    higher stress levels than the matrix material, undergo larger strains than the

    fibers, and the fibers have to be adequately bonded to the matrix. Professor

    Dietz of MIT, a pioneer in the composites field, summed up the subject 7):

    Science and technology, like literature and fine arts, have their fashionable

    phrases and catchwords. One very much to the fore these days is

    composite

    materials

    which has been coined to give dignity and renewed impetus to a

    very old yet simple idea: putting dissimilar materials to work in concert so

    as to achieve a new material whose properties are different in scale and kind

    from those

    of

    any of the constituents. The objective here is to take advan

    tage

    of

    the superior properties of both materials without compromising on

    the weaknesses of either. In a sense, composites epitomize the art of com

    promise at its best. These compromises are sought from the acceptable levels

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    MACHINING OF FIBERREINFORCED COMPOSITES us

    strength, ductility, fracture toughness, oxidation and corrosion resistance,

    modulus, density, creep, fatigue, weight, and cost. Neither the composite ma

    terials per se nor the concept of engineering composites are new 8). Wood

    is a natural composite consisting of cellulose fibers in a matrix lignin.

    Cellulose fibers are strong in tension but flexible; lignin cements the fibers

    and endows the material with stiffness. Bone is a composite of strong but

    soft protein collagen and the hard but mineral apatite. The introduction

    straw in bricks by the Egyptians in the days

    the Pharaohs, or the incor

    poration plant fibers into pottery in the days the Inca and Maya to

    prevent their premature cracking are classical examples engineered com

    posites 9). Many other materials such as paper, concrete, etc., have been in

    existence for some time.

    The successful development glass-reinforced plastics in the 1940s

    gave yet another approach for the development new materials. The concept

    of incorporating high-strength close to theoretical strength) fibers or whiskers

    in a tough or ductile matrix to form a very high-strength composite has

    opened up an exciting possibility 2,5). For example, it was discovered that

    glass fibers have significantly more strength than that of the bulk by an order

    magnitude), because the absence of defects. By combining strong glass

    fibers in an epoxy matrix, a new composite material with the strength glass

    fibers and ductility an epoxy is obtained. The main outcomes such a

    combination include savings in weight, improvement in strength, and a de

    crease in the cost of materials and fabrication.

    In the fiber-reinforced composite, the fibers carry the bulk the load

    and the matrix serves as a medium for the transfer load to the fibers. The

    matrix can be a metal, polymer, or ceramic. The fibers likewise can be metal,

    ceramic, glass, or polymers.

    Some of the advantages of composites include high specific strength;

    high specific stiffness or modulus; good dimensional stability; unusual com

    bination of properties not easily obtainable with alloys; higher fracture tough

    ness; higher oxidation and corrosion resistance; directional properties; good

    resistance to heat, cold, and moisture; ease fabrication; and low cost.

    Some the properties of com mon matrix materials and reinforcing

    fibers and comparative metals are given in Table 1 10). Endowed with some

    these features, composites are ideal candidates for a range applications

    involving extreme conditions not possible with conventional alloying. Ex

    amples include high-strength, lightweight applications space launchers and

    vehicles), high operating temperatures gas-turbine engine parts), and resis

    tance to severe destructive) conditions over a limited period

    time rockets

    and protection devices for vehicles and missiles re-entering the earth s at

    mosphere). However, composites are not limited to extreme conditions as one

    finds their applications under more conventional conditions because their

    superior performance and/or affordable cost. Conventional machining prac

    tices, such as turning, drilling are widely applied to the machining com

    posites in view the availability equipment and experience in conven-

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    Table 1

    Properties of Various Fibers, Composites, and Comparative Metals (10)

    SPECIFIC SPECIFIC

    DENSITY, MODULUS, MODULUS,

    STRENGTH,

    STRENGTH,

    gjcm

    GPa GPa cm /g GPa GPa cm /g

    Group I Ceramic Whiskers

    Graphite 2.2

    700 320 20

    9.1

    Silicon nitride

    3.2

    400

    125 7 2.2

    Silicon carbide

    3.2 500 155 7 2.2

    Alumina

    4.0 420

    105

    14

    3.5

    Group II: Glass, Ceramic, or Polymer Fibers

    Carbon

    RAE (type I)

    2.0 460

    230

    1.7 0.9

    RAE (type II)

    2.0 260 130 2.9 1.5

    Boron

    2.5

    420

    170 2.5 1.0

    Asbestos

    2.5 190 76 6

    2.4

    Mica

    2.7 230

    85

    3

    1.1

    Nylon-6,6 I.1

    5

    4.5 0.8

    0.7

    E-glass as drawn 2.5

    60

    24

    3 1.2

    Group III: Hard-Drawn Metal Wires

    Piano (0.9

    C

    7.8 210

    27

    4 0.5

    Stainless steel

    7.9

    200

    25 2.4 0.3

    Molybdenum 10.3 365 35

    2.1

    0.2

    Tungsten 19.3 345 18 2.9 0.1

    Group IV: Composites and Other Higher Strength Materials

    Steel alloy-current 7.8 200 25 1.3 0.17

    Al alloy

    2.8

    70

    25 0.6 0.21

    Ti alloy 4.5

    115

    26 1.0 0.22

    Beryllium 1.8 300 170

    0.5

    0.28

    0

    Steel alloy-future 8

    200

    25 5

    0.65

    0 glass

    I l

    Fiber epoxy

    c

    Type 1

    2

    350

    175

    1.3 1.5

    0.6 2.5

    l

    Type 2 2 200

    100 2 . 3 5 1.2 2.5

    Current and projected values for uniaxial layup.

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    MACHINING OF FIBER-REINFORCED COMPOSITES

    117

    tional machining. Although some of the fibers used in composites such as

    glass, graphite, boron, alumina, and silicon carbide are hard sometimes equal

    to or harder than the tool material and abrasive, conventional machining is

    considered for these materials because these fibers are very brittle and ma

    terial separation in machining is accomplished by brittle fracture rather than

    plastic deformation ahead of the tool. However, the cutting tool materials are

    chosen to minimize wear due to the hard abrasive constituents

    of

    the fibers

    in many cases.

    FIBER

    REINFORCED COMPOSITES

    Machining

    of

    a fiber-reinforced composite depends on the properties of

    the fibers and the matrix as well as its response to the machining process. In

    addition, the choice of the specific process depends upon the following fac

    tors: type

    of

    machining operation, part geometry and size, finish and accuracy

    requirements, number of parts, diversity

    of

    parts including the materials

    of

    the parts, availability

    of

    appropriate machine and cutting tools, availabilityof

    in-house technology, current machining practice, manufacturing schedule,

    capital requirements and justification for new equipment, and overall costs.

    Certain machining operations may not be possible at all with some com

    posite materials. For example, it is not possible to machine SiC whisker

    reinforced alumina with a single-point cutting tool, even with a diamond tool.

    may, however, be possible to shape it by diamond grinding or by some

    of

    the nonconventional machining processes, such as laser machining or ultra

    sonic-assisted machining. In other cases more than one process may be can

    didate processes and the specific process chosen depends on the factors out

    lined earlier. Of course, the general tendency is to use current machining

    practices by adopting existing equipment for this application. This is partic

    ularly true of composite machining in small manufacturing shops in view of

    capital limitations for procuring new machinery or new technology. This may

    not be the case with large companies, such as Boeing, Lockheed, or General

    Dynamics, where resources are normally available, if justified. Even a par

    ticular process chosen now for machining composites may have to be aban

    doned at a later date because

    of

    changes in the factors outlined earlier. For

    example, the lot size may be increased significantly, necessitating a review

    of alternate manufacturing processes, or new technology or a technology not

    currently practiced in the plant may become available or be economically

    attractive.

    In the following text, some common fiber materials used in composites

    are briefly discussed. Table 2 gives some of the mechanical properties of

    these fibers. Table 3 gives the mechanical properties

    of

    resin matrix materials.

    This will be followed by a brief description of the three types

    of

    composites,

    namely, organic-matrix, metal-matrix, and inorganic-matrix composites. Ta

    bles

    6

    give some

    of

    the mechanical properties of representative composite

    materials.

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    KOMANDURI

    able Z Mechanical Properties of Fibers

    SPECIFIC

    SPECIFIC

    TENSILE TENSILE ELASTIC ELASTIC

    DENSITY, STRENGTH, STRENGTH,

    MODULUS, MODULUS,

    FIBER g/cm ksi X 10

    6

    in.

    X10

    6

    psi

    10

    K

    in.

    Kevlar-29 1.44 525 10.1

    12

    2.3

    Kevlar-45

    1.44 525 10.1 18

    3.5

    HT graphite

    1.75 450 7.1 32

    5.1

    E-glass

    2.55 350 3.8

    10 1.1

    S-glass

    2.49 575 6.4 12.4

    1.4

    Boron

    2.60 350

    4.2

    65 7.8

    Boron

    Filaments

    Boron filaments cannot be formed exclusively. Instead they have to be

    formed on a tungsten or carbon core using the chemical vapor deposition

    CVD) technique. For example, BCI, and tungsten are reacted at

    -2000F

    resulting in the tungsten core transforming into tungsten boride on which

    amorphous boron deposits. A typical 0.004-in.-diameter boron fiber contains

    -0.0005-in.

    tungsten boride core 11). To make a usable product, the fibers

    are generally placed on a glass gauge tape preimpregnated with resin and

    cured. Boron composites are also made in a metal matrix, generally aluminum

    or titanium, to reduce weight, yet maintain high strength at room aluminum)

    or elevated temperature titanium).

    Glass

    Fibers

    Glass fiber-reinforced plastics GFRP) developed in the 1940s were the

    first lightweight, high-strength, relatively inexpensive engineering compos

    ites. The most comm on types

    of

    glass fibers are the E-glass electrical) and

    the S-glass high strength). E-glass is a calcium alumina borosilicate with low

    levels of sodium or potassium. Typical composition

    of

    an E-glass is

    52-56

    Si0

    2

    ,

    12-16 Al

    20

    3

    ,

    16-25 CaO, and

    8-13

    B

    20

    E-glass has a tensile

    strength of 500 ksi and a modulus of elasticity of 10.5 X 10

    6

    psi. S-glass has

    higher specific strength and is more expensive than E-glass see Table 2).

    Consequently, it is used primarily in military and aerospace applications for

    able

    3.

    Mechanical Properties Polyester and Epoxy Resin Matrix 1)

    PROPERTIES

    Tensile strength, ksi

    Tensile modulus of elasticity, psi X 10

    6

    Flexural yield strength, ksi

    Impact strength notched-bar Izod test), ft

    -Ib/in,

    of notch

    Density, g/cm

    POLYESTER

    6-13

    0.30-0.64

    8.5-23

    0.2-0.4

    1.10-1.46

    EPOXY

    8-19

    0.41-0.61

    18.1

    0.1-1.0.

    1.2-1.3

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    MACHINING OF FIBERREINFORCED COMPOSITES 119

    reinforcing metals or ceramics. The inherently high cost of processing metal

    or ceramic matrix composites makes it unattractive to use glass as a rein

    forcing material; instead the choice is for the use of more expens ive high

    performance fibers such as boron in the case of metal matrix composites

    MMCs) and SiC in the case

    of

    ceramic matrix composites CMCs).

    Aramid Fibers

    Aramid is the generic name for aromatic polyamide. Aramid fibers were

    introduced by du Pont in 1972 under the trade name

    Kevlar

    There are two

    commercial types: Kevlar-29 and Kevlar-49. Kevlar-29 is a low-density, high

    strength, low modulus fiber designed for such applications as ropes, cables,

    armor shield, etc. Kevlar-49 is characterized by low density, high strength,

    and high modulus.

    is used in such applications as aerospace, space shuttle,

    marine, automotive, and other industrial applications. The chemical structural

    unit of aramid is shown in Fig. 1. The pol ymer chains are bonded together

    by hydrogen bonding in the transverse direction. The fibers have high strength

    in the longitudinal direction and low strength in the transverse direction. The

    aromatic ring structures give high rigidity to the polymer chains, causing them

    to have a rod-like structure.

    Carbon Fibers

    Carbon fibers have a combination of lightweight, very high-specific

    strength and stiffness. Carbon fibers are produced mainly from two sources:

    polyacrylonitrile PAN) and pitch. The tensile strength ranges from

    450 650

    ksi and the modulus

    of

    elasticity ranges from

    28 35

    X

    10

    6

    psi. In general,

    the higher modulus fibers have lower strengths and vice versa. The density

    of

    the fibers ranges from

    1 7 2 1

    g /cm . In view of the relatively high cost

    of

    carbon fibers, they are used mainly for high-tech applications where light

    weight, specific modulus both at room and elevated temperatures are required.

    They are also used in high value added products, such as tennis racquets,

    golf clubs, and fishing rods.

    Silicon Carbide Fibers

    Silicon carbide fibers are produced by a vapor-phase decomposition pro

    cess in which the fiber component is deposited from the vapor phase on a

    o

    0

    11 0

    0

    C N

    N

    I I

    H H

    igur

    1. Chemical structurat unit of an aromatic polyamide 1).

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    120

    KOMANDURI

    carbon substrate. They can also be formed by the decomposition

    of

    naturally

    occurring substances such as rice hulls.

    Modern composite materials, depending on the matrix material used, can

    be classified as follows:

    1.

    Polymer organic) matrix composites PMC).

    2. Metal matrix compo sit es MMC).

    3. Ceramic in org anic) matrix compo sites CMC).

    Theoretically, a multitude of materials can come under these categories.

    In the following text a bri ef description of some of the composites used

    industrially of the three previous categories are given.

    PMC

    The common types of fibers used to reinforce plastic materials are glass,

    graph ite, aramid, and boron. Glass fiber reinforced plastics GFRP) are by

    far the most commonly used materials in view of their relatively high specific

    stren gth and low cost. The o th er materials p ro vide higher specific stren gth,

    higher specific stiffness, and light weight. They are, however, expensive and

    are used only for those applications w her e performance and not cost is the

    major consideration. Aramid is used instead of graphite where strength, light

    ness, and flexibility are major considerations, and stiffness and high-temper

    ature p erforman ce are not. The commo n matrix materials used are p olyester

    and epoxy resins. Polyester resins are lower in cost and are not as st ro ng as

    the epoxy. Their use as co mp os ites include boat hulls, structural panels for

    automobiles and aircraft, building panels, appliances, etc. Epoxy, in addition,

    has a lower sh rink ag e after cure. is used co mmon ly in carbon and aramid

    fiber composites. Tables 3 and 4 give some mechanical properties

    of

    polyester

    and epoxy resins, GFRP polyester composites, respectively. Maximum-use

    temperatures of polymeric matrix composites are relatively low, as the matrix

    material is prone to softening or chemical decomposition or degradation) at

    moderate temperatures. The same conditions apply for machining these ma

    terials.

    ble

    4. Mec hanica l P roperties of GFRP Com posite s 1)

    WOVEN CHOPPED SHEET-MOLDING

    CLOTH

    ROVING COMPOUND

    Tensile strength, ksi 30 50 15 30 8 20

    Tensile modulus

    of

    elasticity, Msi

    1 5 4 5

    0 80 2 0

    Impact strength notched bar, Izod

    5 0 30 2 0 20 0

    7 0 22 0

    Ib/in. of notch

    Density, g/crrr

    1 5 2 1 1 35 2 30 1 65 2 0

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    MACHINING OF FIBERREINFORCED COMPOSITES

    MMC

    121

    MMCs are used for applications requiring higher operating temperatures

    than are possible with PMCs. Most of these alloys are developed for the

    aerospace industry, but new applications are found in the auto industry such

    as in automobile engine parts. There are three types of MMCs depending on

    the nature of the fibers used, namely, continuous, discontinuous, or particu

    late.

    Continuous fibers provide the highest stiffness and strength for MMCs.

    Boron-aluminum composites are one of the earliest developed MMC mate

    rials. is made by hot pressing layers of boron fibers between aluminum

    foils, so that the foil deforms around the fibers and bond to each other 11).

    By reinforcing with boron, the tensile strength can be increased by a factor

    of 3-5 while the elastic modulus can be tripled. Silicon carbide, graphite,

    alumina, and tungsten fibers are some

    of

    the fibers used in MMCs. To keep

    the weight low, aluminum, magnesium, and titanium are the most commonly

    used metal matrix materials. Table 5 gives some of the mechanical properties

    of the MMCs. Applications of MMCs include use of boron-aluminum for the

    fuselage of the space shuttle orbiter, SiC-AI for the vertical tail section of

    advanced fighter planes, and SiC-titanium aluminide for hypersonic aircraft.

    The discontinuous and particulate MMCs are low-cost MMCs that pro

    vide higher strength and stiffness and better dimensional stability over rein

    forced alloys. Small additions of the reinforcement -20 ) moderately in

    crease the strength and stiffness.

    They also increase the wear resistance and contribute toward the diffi

    culty in machining these materials. These alloys are used for sporting equip

    ment, automobile engine parts e.g., pistons), missile guidance parts, etc.

    Table Mechanical Properties of MMC Materials 1)

    TENSILE

    ELASTIC

    STRAIN

    TO

    STRENGTH, MODULUS, FAILURE,

    ksi

    psi X 10

    6

    Continuous-fiber MMCs:

    AI 2124-T6 45 B) axial)

    211

    32 0.810

    AI 6061-T6 51 B) axial)

    205

    33.6

    0.735

    Al6061-T6

    45 SiC) axial) 212 29.6

    0.89

    Discontinuous-fiber MMCs:

    AI 2124-T6 20 SiC) 94 18.4 2.4

    AI 6061-T6 20 SiC)

    70 17.7

    5

    Particulate MMCs:

    AI 2124 20 SiC)

    80 15

    7.0

    AI 6061 20 SiC)

    72 15

    5.5

    No reinforcement:

    AI 2124-F

    66

    103

    9

    AI 6061-F

    45 10

    12

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    122

    CMC

    KOMANDURI

    CMCs are being developed mainly to improve fracture toughness. They

    already possess higher specific modulus and elevated temperature mechanical

    properties superior to metals. Continuous fibers, discontinuous fibers, or par

    ticulates can be used as reinforcing materials. The common fiber materials

    used are alumina and silicon carbide. Oak Ridge National Laboratories re

    cently developed a SiC whisker-reinforced alumina. A 20 wt% of SiC whisk

    ers to alumina can increase the fracture toughness from 4 to 8 ksi/in. . Such

    an increase in toughness of a ceramic cutting tool will enable it to take heavy

    cuts or to perform without fracture in interrupted cutting. Conventional

    hot isostatic pressing (HIP) techniques can be used to consolidate the CMCs.

    Table 6 gives some of the mechanical properties of CMCs. Other CMCs

    include carbon/carbon composite in which high-strength carbon fibers are

    embedded in a graphite matrix. The low density of carbon in combination

    with the extraordinary strength of carbon fibers offers potential for the de

    velopment of high specific-strength materials.

    Figure 2 is the stress-strain behavior of various types of reinforcing

    fibers with the slope giving the modulus of elasticity. Figure 3 is a plot of

    specific strengths versus specific modulus for various types of reinforcing

    fibers.

    can be seen that aramid (Kevlar-49), graphite, and boron fibers have

    outstanding specific strength/specific modulus compared to steel or aluminum.

    Figure 4 is a plot of specific strength versus specific stiffness of various

    composites with conventional metallic-matrix materials.

    can be seen that

    composites, in general, have higher specific strength/specific modulus over

    conventional steel, AI, Ti, and Mg, and the MMCs have properties superior

    to polymer-reinforced composites. Figure 5 shows the variation of specific

    strength with temperature for various composites (12). Fiber-reinforced plas

    tic have higher specific strength (tensile strength/density) at low temperatures.

    For high-temperature applications, one needs to move from PMCs to MMCs

    to CMCs.

    ble 6. Mechanical Properties of SiC Whisker-Reinforced Ceramic-Matrix Composites at

    Room Temperature (1)

    FLEXURAL

    FRACTIJRE

    MATRIX

    SiC WHISKER STRENGTIl, TOUGHNESS,

    MATERIAL

    ol % CONTENT ksi

    s ~

    Si,N.

    0

    60 95

    4 6 6 4

    10

    60 75

    5 9 8 6

    30

    50 65

    6 8 9 1

    Al

    O

    0

    4.1

    10

    57 73 6.5

    20

    75 115

    6 8 8 2

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    MACillNINGOF FIBERREINFORCED

    OMPOSIT S

    3

    4137

    600)

    3447

    500)

    2758

    400)

    s 2068

    [ 300)

    il

    1379

    (200)

    689

    100)

    Nomex

    2

    T U strain,

    4

    Figure 2. Stress-strain characteristics of various types of reinforcing fibers (from Kevlar 9

    Data Manual

    E.

    I.

    du Pont de Nemours).

    8M

    graphite

    (hlg/l modulus)

    lIqfon

    lIT graphite

    (hlg/l tensue)

    K '1l 49

    resin-Impregnated

    str n s

    1 2 3 4 5

    Sped/Ie tensU. modulus, Ill In.

    = _

    Sgl. . . .

    p

    5

    i

    c

    '

    c

    u

    '

    0

    Figure 3. Specific tensile strength versus specific tensile modulus of various types of reo

    inforcing fibers (courtesy E. I. du Pont de Nemours).

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    4

    KOM NDURI

    0.34GrlMg

    e

    6

    GrlEpo.y

    0.37GrlAI

    .37Gr/AI

    4SB I

    iCffi

    onventional

    Steel.AI.T Mg

    O 25SiC IAI

    @o.SOGrlEpo,y

    0.25

    t

    e se

    z

    ~

    Figure

    4. Specific strength versus specific stiffness for various metal matrix composites.

    Number in front of the composite represents the volume fraction

    of

    the reinforcement 12).

    MACHINING OF

    FI R

    REINFORCED COMPOSITES

    Machining of fiber-reinforced composites differs significantly in many

    aspects from machining of conventional metals and their alloys 13). In the

    machining of fiber-reinforced composites, the material behavior is not only

    inhomogeneous, but it also depends on diverse fiber and matrix properties,

    fiber orientation, and the relative volume of matrix and fibers. The tool en

    counters continuously alternate matrix and fiber materials, whose response to

    machining can be entirely different. For example, in an aluminum-boron com

    posite, the tool continuously encounters a soft aluminum matrix and hard

    boron fibers. Similarly, in a glass-epoxy composite, the tool encounters a low-

    T l l q e r a ~ u r e F

    Figure

    5. Variation of specific strength with temperature 12).

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    MACIllNING OF FIBERREINFORCED COMPOSITES

    125

    temperature soft epoxy matrix and brittle glass fibers. is this diverse re

    quirement

    o

    a cutting tool that makes composites somewhat unique and at

    the same time difficult to machine. Therefore, machining

    o

    fiber-reinforced

    composites impose special demands on the geometry and abrasion resistance

    o the tool materials.

    Conventional machining practices are generally applied to the machining

    o composites in view o the availability of equipment and experience, in

    spite of the fact that the response o composites to machining is entirely

    different from metal machining. However, in some applications conventional

    machining with a tool harder than the work material may not even be an

    economical proposition. For example, in the machining o glass reinforced

    with continuous fibers o SiC composite, no conventional cutting tool mate

    rial, including polycrystalline diamond PCD , would last longer than another

    14 . The need, therefore, arises for alternate material removal processes or

    nonconventional machining processes, such as laser cutting, ultrasonic ma

    chining, water jet or abrasive water jet cutting, or electrical discharge ma

    chining. Of course, all of these processes have their own limitations. The

    objective would be to choose a process that takes advantage o its unique

    capabilities while exploiting the weaknesses o the work material, enabling

    to be processed economically and yet meet the requirements

    o

    the part.

    Since most fibers used in composites e.g., glass, boron, and carbon are

    hard and abrasive, the tool materials recommended for use include cemented

    carbides coated and uncoated , ceramics, cubic boron nitride cBN , and

    diamond single crystal or polycrystalline . However, cemented carbide and

    diamond are the commonly used materials. High speed steel HSS tools are

    also used in some cases, but at the expense o rapid tool wear. In view o

    high tool wear and the high costs

    o

    tooling that are experienced with con

    ventional machining, noncontact material removal processes offer an attrac

    tive alternative. This will also minimize the dust and noise problems. In

    addition, extensive plastic deformation and consequent heat generation as

    sociated with conventional machining

    o

    fiber-reinforced composites espe

    cially with an epoxy matrix can be minimized. These processes include laser

    machining, water j t with or without an abrasive , ultrasonic machining, and

    electrical discharge machining. Each o these processes offers certain advan

    tages and shortcomings compared to conventional machining and even com

    pared among themselves. For example, electrical discharge machining EDM

    requires that the composite material be electrically conductive. Laser ma

    chining depends on the optical absorption and thermal properties o compos

    ite. In the following text some o the issues involved in the conventional

    machining o representative composite materials are discussed.

    Conventional Machining

    As pointed out earlier, conventional machining o composites is some

    what difficult in view o the diverse fiber and matrix properties, fiber orien-

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    6

    KOMANDURI

    tation, inhomogeneous nature of the material, and the presence of high vol

    ume fraction of hard, abrasive fibers in the matrix. Glass-, graphite-, and

    boron-reinforced composites even polymer based are difficult to machine

    because of rapid tool wear. Even cemented carbide tools wear rapidly and

    one may have to resort to the use of diamond-impregnated tools. Several

    advances have been made in the tool materials development including poly

    crystalline diamond tools, diamond-plated tools, and diamond-impregnated

    tools in various forms such as core drills, milling cutters, drills, and grinding

    wheels. In the following text various issues involved in the machining of

    some of these materials are presented as examples.

    Machining of Boron-Titanium Composites

    Boron is hard and abrasive, whereas titanium is chemically reactive with

    most tool materials. The dissimilar and difficult machining characteristics of

    boron-titanium composites makes the task of machining even more challeng

    ing than other composites. Doron and Maikish 15 conducted tests on a

    boron-epoxy/titanium laminate in a variety of machining operations including

    drilling, reaming, countersinking, routing, milling, and sawing. They used

    diamond-impregnated tools as well as plated tools. The following are typical

    drilling condition recommendations: cutting speed from 2 6 SFPM sur

    face feet per minute and a feed rate of 0.0005-0.005 in./rev. A tool life of

    up to 400 holes with a 1/4 in. diameter drill was reported. The use of cutting

    fluids was recommended to reduce heat buildup both in the tool and the part.

    Protecting the machinery to prevent wear of machine elements by abrasive

    boron dust was also highly recommended. Diamond-impregnated tools were

    found to perform better than diamond-plated tools.

    Machining of Aramid-Reinforced Plastic Composites

    Aramid-reinforced plastic composite is an inherently tough material;

    therefore, cutting tools should be sharp and clean. Tools should be cleaned

    frequently to remove buildup of partially cured resins that can cause a loss

    in cutting action. The requirements of tools for machining aramid-reinforced

    plastics are different from those of glass or carbon fibers. In many respects

    aramid-reinforced polymer resembles wood. The structure is characterized by

    the presence of highly oriented fibrous material embedded in a matrix. The

    best results are obtained when machining is processed in such a way that the

    fibers are preloaded in tension and then cut with a shearing action.

    Special cutters were specifically developed to address this problem 16 .

    For example, Paige 17 developed a four-fluted spiral rotary carbide milling

    cutter Fig. 6a with a unidirectional helix throughout much of its length, and

    a reverse directional helix adjacent to the cutting edge. Chip breakers are

    arranged along the lands with the notches at alternate lands aligned and the

    notches of the other lands intermediately aligned. The notches are cut at an

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    MACHINING OF FIBER.REINFORCED COMPOSITES

    a

    b

    127

    d

    igur

    6. New tool designs specially made for the machining of aramid fiber reinforcing

    polymers 17- 20 .

    angle of about 20 deg from a line perpendicular to the axis of the cutting

    tool. These cullers with angled chip breakers were designed to cut cleanly

    the aramid fiber-reinforced plastic composites. They operate at production

    speeds with minimal overheating. Figures

    6b-6d

    show some of the other

    designs or cutters specifically made for drilling aramid fiber-reinforced resin

    composites 18-20 .

    Since aramid-reinforced polymers are not particularly hard, HSS tools

    should give a reasonable tool life if care is taken to avoid overheating the

    tool. Coated TiN HSS tools should prolong the life further and minimize

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    128

    KOMANDURI

    buildup on the tool. Cemented carbide tools provide longer tool life and

    maintain sharper cutting action. These tools could easily handle single ar

    amid reinforcing fiber composites. When

    hybrid

    composites containing

    glass or graphite in addition to aramid have to be machined, tool wear will

    be high. Diamond impregnated or plated tools are not recommended for ma

    chining aramid-reinforced polymer composites 13 . Backup support is rec

    ommended on both entrance and exit sides to avoid fuzz and delamination.

    E. du Pont de Nemours and Co., that developed aramid Kelvar fibers, has

    conducted extensive machining tests on this material in collaboration withlor

    in support of its customers. The guidelines for machining Kevlar aramid

    composites and should be consulted for details on the recommended cutting

    conditions for various machining operations 21 .

    Machining

    of

    GFRP Composites

    In view of the high hardness and abrasiveness

    of

    glass fibers in GFRP

    composites, cemented carbide and preferably diamond tools single crystal

    and polycrystalline are recommended for machining these materials. While

    HSS tools can be used to machine GFRP, they wear rapidly and cutting speeds

    should be kept low enough not to overheat the tool. Maintaining the sharpness

    of

    the tool will be a real problem for both HSS and cemented carbide tools

    because of the abrasive action on the cutting tool by the glass fibers. Some

    consider the machining

    of

    GFRP to be similar to drilling a hole in a resin

    bonded grinding wheel 22 . A dull tool can dissipate considerable heat into

    the workpiece and damage the resin-based composites. Although alumina

    based tools can be used because

    of

    their higher hardness, the possibility

    of

    a

    chemical reaction between alumina and glass should not be overlooked.

    Polycrystalline diamond tools are preferred, particularly in the case of GFRP

    components with a high glass fiber content (-60 ) that have to be machined

    to tight tolerances and with a good surface finish 23 . Of course, rigid ma

    chine tools are preferred when machining GFRP with PCD to take advantage

    of

    PCD's

    superior cutting performance capability. To prevent wear of ma

    chine elements in relative motion because of the abrasive action of the glass

    fibers, protective covers have to be incorporated in the machine tool. Some

    times it is necessary to dedicate a machine tool for machining this material

    if enough parts are to be fabricated on a continuing basis. When using PCD

    it is preferable to clamp rather than braze the insert on the tool holder to

    avoid softening the braze material. The final choice

    of

    the tool material, say,

    between cemented carbide and PCD, depends on the economics

    of

    the ma

    chining operation as well as the part requirements. Appropriate dust collection

    and extraction systems should be in place when machining GFRP. Operator

    safety should be a prime consideration and the use

    of

    masks, hand gloves,

    an apron or lab coat are required to minimize the risks involved in the health

    and safety of operating personnel because of loose glass fibers and dust.

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    MACHINING OF FIBER-REINFORCED COMPOSITES

    129

    Cutting speeds ranged from

    100-150

    SFPM for carbides and

    500-1500

    SFPM for PCD.

    Machining of Carbon Fiber-Reinforced Plastic CFRP Composites

    Although CFRP are generally fabricated to near-set-shape, there often

    is a need to conduct some additional machining operations such as drilling

    of holes, trimming of the edges, etc. High tool wear and delamination of the

    composites are some of the concerns in machining. Koplev et al. 24 con

    ducted orthogonal machining tests using a quick stop device to freeze the

    cutting process and obtain the chip root. They conducted cutting experiments

    parallel and perpendicular to the fibers. When cutting parallel to the fibers,

    they found the surface to have visible fibers. They also found that nearly all

    fibers were fractured perpendicular to their longitudinal direction. When the

    composite was machined perpendicular to the fibers, they did not find the

    surface with visible fibers; instead they found the whole surface to be coated

    with a thin layer of the matrix material. They also found a layer of disturbed

    material with cracks below the surface layer. Koplev et al. observed a rather

    sharp notch with no cracks in front when machining perpendicular to the fiber

    direction. In contrast, a crack was found in front

    of

    the notch when machining

    parallel to the fibers. Based on these observations Kop1ev et al. pointed out

    that during machining of CFRP perpendicular to the fibers, two separate ef

    fects occur near the tool tip. As the tool moves forward, it presses on the

    composite in front of it causing the composite to fracture and create a chip.

    At the same time a downward pressure on the composite below the tool

    produces fine cracks =0.01 in. deep into the specimen. When the composite

    is machined parallel to the fibers, the tool applies pressure on the specimen,

    resulting in chips; but a crack is often seen in front of the tool tip indicating

    that this crack seems further or deeper than the current chip. At the surface

    there are cracks that reach depths

    of only one or two fiber diameters.

    Friend et al. 25 conducted machining tests using conventional and

    nonconventional machining methods. To reduce tool wear, the authors rec

    ommended diamond tooling. For producing intricate shapes of high accuracy,

    the authors recommended ultrasonic machining.

    Fundamental Studies on Chip Formation Mechanics

    Several fundamental studies were conducted to obtain insights into the

    mechanisms of material removal in machining composite materials. For ex

    ample, Bhatnagar et al. 26 investigated orthogonal machining of unidirec

    tional CFRP composites. They studied the effect

    of

    fiber orientation with

    respect to the cutting direction on the machining response. When the fibers

    were oriented at + 10 deg in the

    e

    direction, the fibers were found to bend

    to the underside of the tool edge and not get cut e is measured counter

    clockwise from the machined surface . The resulting surface was full of fibers

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    130

    KOMANDURI

    not being cut and delaminated 27 . In contrast, when the fibers were oriented

    at the

    1

    deg direction, they were found to break in tension, with the ma

    chining surface produced as a consequence. Chips were produced ahead of the

    cutting edge of the tool by the shearing of the matrix in a plane along the fiber

    orientation. A model for predicting the cutting forces for composites with fibers

    oriented in different directions to the cutting direction was also proposed.

    Wern et al. 28 investigated the stress fields in the machining

    of

    fiber

    reinforced plastics using a model material and photoelastic analysis. They

    used polyester matrix with embedded copper wire, which is a ductile rein

    forcement in a brittle matrix and the opposite of conventional fiber-reinforced

    plastic where the matrix is ductile and the fibers brittle. For this particular

    case, Wern et al. found that in the case of fibers oriented away from the

    cutting direction, the fibers were machined by shearing and tensile fracture;

    and in the case of fibers oriented toward the cutting tool, the fibers failed by

    shearing and bending. They also found the fiber matrix debonding to be

    maximum for fibers oriented at 45 deg to the tool path.

    Arola et al. 29 investigated the chip formation mechanism in the or

    thogonal trimming of a graphite-epoxy composite using polycrystalline cut

    ting tools. Similar to Bhatnager et al. 26 , Arola et al. found the character

    istics of chip formation to be primarily dependent on the fiber orientation. In

    the O-deg fiber orientation they found that the chip formation mechanism

    included failure along the fiber-matrix interface through cantilever bending

    and fracture perpendicular to the fiber direction. In positive fiber orientations

    up to 75 deg, chip formation involved compressive-loading-induced shear at

    the tool nose. In the 90 deg and negative fiber orientations, the chip formation

    mechanism was composed of out-of-plane shear with severe compressive

    loading-induced intralaminar deformation.

    Di IIio et al. 30 investigated the effect of drilling parameters on specific

    energy when drilling various composites thermoset and thermoplastic matri

    ces with aramid and glass fibers . They found that specific energy can be

    expressed as a function of the feed rate and diameter of the drill, similar to

    the relationship obtained when drilling metals. The coefficients for the func

    tional relationship varies with the particular type of composite and the twist

    drill used. They also found that the thrust force or feed force , which is a

    critical parameter in the drilling of composites, is related to the cutting torque,

    which in turn, is related to the specific energy. Since, when drilling compos

    ites, one of the main concerns is the delamination which does not exist in

    the case of metals , the correlation between torque and thrust force represents

    an important finding that affects not only the machinability, but also the in

    tegrity of the composite after drilling. With this relationship, it may be pos

    sible to determine a value of thrust force low enough to avoid delamination.

    Since the temperature during drilling of composites is a concern, both from

    the point of drill life and the workpiece quality, Bella et al. 31 evaluated

    the temperature generated in drilling composites both analytically and exper

    imentally.

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    MACHINING OF FIBER-REINFORCED COMPOSITES 131

    is well known that delamination is a major concern during drilling of

    composites because it reduces the structural integrity and results in poor as

    sembly tolerance.

    can thus cause long-term performance deterioration. Ho

    Cheng and Dharan 32 investigated the delamination during drilling in com

    posite laminates. was found that drilling-induced delamination occurs both

    at the entrance and exit during drilling. Ho-Cheng and Dharan analyzed this

    problem using fracture mechanics and found an optimal thrust force as a

    function of drilled hole depth. They proposed that optimum thrust force for

    no delamination can be used for feedback control to maximize productivity.

    Wear of Cutting Tools in Machining of Composites

    In view of the hard, abrasive reinforcing fibers such as glass, carbon,

    and boron used in most PMCs, tool wear in conventional machining is gen

    erally a serious problem with most tool materials. Hasegawa et al. 33 con

    ducted extensive studies on the characteristics of tool wear when machining

    GFRPs. They found the tool wear to be predominantly abrasive in nature and

    proportional to the contact pressure between a glass fiber and the tool under

    a constant cutting length. They divided the tool wear with cutting speed into

    three regions. At very low speeds Region I they found the tool wear to be

    negligible and independent of cutting speed and dependent only on the length

    of cut; the wear increasing linearly with the length of the cut. At intermediate

    speeds Region II the tool wear was found to increase with cutting speed.

    At higher speeds Region III tool wear was found to increase rapidly and

    independently of speed. Hasegawa et al. developed a rheological model of

    tool wear to explain the observed wear phenomenon in machining GFRP.

    Ramulu et al. 34 investigated the machining

    of

    a graphite-epoxy com

    posite with PCD tools. The wear behavior was characterized by small cracks,

    rounded edges, and flank wear. was also found that the larger the diamond

    grain size the coarser the PCD grade the better the wear resistance.,

    Ho-Cheng and Puw 35 investigated the machinability of carbon fiber

    reinforced thermoplastics ABS in contrast to the thermosetting epoxy in

    drilling. They found the machinability to be good, wear on the HSS drills to

    be minimal, and the quality of finished surface to be good.

    Nonconventional chining

    To overcome the rapid tool wear experienced in conventional machining

    of some composites containing hard, abrasive, or refractive constituents, al

    ternate material removal operations have been adopted. These include laser

    machining, electrical discharge machining,

    W

    and

    Wl

    cutting, ultrasonic

    machining, and electrochemical spark machining.

    These are basically noncontact machining operations involving no cut

    ting tools, and consequently, no cutting forces. In the following text some of

    the issues involved in the processing of composites are outlined.

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    3

    KOM N URI

    Laser Machining

    Laser machining is based on the interaction

    the work material with

    an intense, highly directional coherent monochromatic beam

    light, from

    which material is removed predominantly by melting and/or vaporization. In

    the case resin matrix material it is removed by chemical degradation. The

    type

    laser to be used for the machining of a given composite depends upon

    the following characteristics the beam and the work material properties

    5,36): power density, wavelength

    emission type

    laser), interaction

    time [continuous wave cw) versus pulse], polarization the beam, absorp

    tion coefficient at the given wavelength, melting and vaporization tempera

    ture, thermal conductivity, heat capacity, diffusivity, and heat of vaporization.

    Several types of lasers are available for machining composites including

    solid-state lasers and gas lasers. Fiber-reinforced plastics generally exhibit a

    high absorption of infrared rays typical those produced by a CO

    2

    laser.

    Since polymers do not generally exhibit a fusion reaction, the vapor column

    is not surrounded by molten material as in metals. This together with the

    thermal properties

    the plastics are such that the vaporization process occurs

    at much lower specific powers 10-

    3 1 5

    W/cm

    2

    ) .

    As previously noted, laser-beam machining is based on the interaction

    an intense, highly directional coherent monochromatic beam of light laser

    beam) with a work material from which material is removed by melting and

    vaporization or chemical degradation. The physical processes involved in

    laser machining are basically thermal in origin. When a laser beam impinges

    on a work material several effects arise, including, reflection, absorption, and

    conduction the laser beam. The amount by which the beam is reflected

    depends on the wavelength of the laser radiation, and on the condition and

    properties of the work material, such as roughness, degree oxidation, and

    its temperature. The amount

    laser energy absorbed by the surface

    the

    composite material depends on the optical as well as the thermochemical

    properties

    the material. Figure 7 shows the variation

    reflectance for

    several metals as a function of the wavelength of several laser lines 37). For

    efficient lasing action, absorption should be as high as possible or

    reflection as low as possible. Most metals absorb more readily at shorter

    wavelengths, and hence, less power is required to machine these materials at

    these wavelengths. Therefore, Nd:YAG with a wavelength

    1.06 l m would

    be more suitable for machining MMCs than CO

    2

    In contrast, some of the

    organic resins and other compounds have a higher absorption at higher

    wavelengths close to that

    the CO

    2

    laser 10.6 urn), and hence, CO

    2

    would

    be more appropriate for machining such materials e.g., aramid-resin com

    posites). It should be noted that as melting begins or the material begins to

    interact with its atmosphere, the absorption may change. Thus, the

    absorption in drilling may change as the process continues. For example, the

    absorption in part of the hole drilled could be different from its initial

    value at the surface.

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    MACmNING OF FIBER-REINFORCEDCOMPOSITES

    133

    ,

    LEAD GLASS

    , I TRAN SMIT TANC E)

    \

    \

    \

    I I

    ARGON 48

    52/ nl \

    Nd Y G

    2nd

    I

    / HARMONIC

    .53

    \

    C02

    10.6

    He-Nef.6]

    1

    I

    UBY ,694

    ... Nd:GLASS Nd:YAG

    11.061

    0.5 1.0 2.0 5.0

    W V

    l N TH

    J

    m I

    0.2

    O L _

    --lL-...lL_-- - _ J. J

    0.1

    w

    1

    0 0 1 - r - - i - ; : = = : : : : : : : : ~ = = = = ; ; ; ; ; ; ~ ~ ; 1

    u

    z

    2

    Z

    0:

    0:

    o

    u

    Z

    U

    0:

    igur 7. % Reflectance of several metals as a function of wavelength, with the wavelengths

    of several laser lines indicated 41).

    Generally, the longer the wavelength of the laser beam, the higher the

    reflectivity of the metal workpieces. Similarly, the higher the thermal con

    ductivity thermal diffusivity), the higher the reflectivity. The higher reflec

    tivity of some materials [especially high conductivity even better high dif

    fusivity) metals such as aluminum and copper] at higher laser wavelengths

    .g., 10.6 u.m for CO

    2

    ) renders them unsuitable or uneconomical for ma

    chining. For wavelengths greater than 5 urn, most metals reflect over 90

    of the incident radiation at low power densities. Consequently, low wave

    length lasers e.g., Nd:YAG with a wavelength

    of

    1.06 urn) would be pref

    erable for laser machining of high conductivity metals, provided there is

    adequate power available for lasing. In contrast, nonmetals e.g., plastics,

    glass, and ceramics) with low thermal conductivity are ideal candidates for

    CO

    2

    laser machining reflectivity is inversely proportional to the thermal con

    ductivity). The amount of reflectivity can, however, be reduced substantially

    by modification of the surface conditions on the work materials. For example,

    the reflectivity of copper at a wavelength of 694.3 nm Ruby laser) can be

    reduced from 95 to less than 20 by oxidizing the surface. Similarly, re

    flectivity can be reduced significantly once the material begins to melt.

    Energy transfer from a laser to the work material may occur in two

    ways. At low values

    of

    specific power i.e., below a threshold value), the

    laser energy is absorbed in a superficial zone

    of

    the work material and heat

    is transmitted into the material by conduction. Above the threshold power,

    which is high enought to melt and/or vaporize the material, a vapor column

    surrounded by molten material forms and energy is absorbed through the

    entire thickness of the workpiece. The temperature reached by the material

    produces changes in the mechanical and physical properties near the inter

    action of the work material and the laser. The nature

    of

    these changes as well

    as the magnitude

    of

    the heat affected zone HAZ) depends on the temperature

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    4

    KOMANDURI

    Table 7.

    Typical Thermal Properties of Fiber-Reinforced Material Constituents

    p, K C,

    K,

    T., H

    MATERIAL

    g em :

    W

    m K

    J kg

    K

    (em s- )lO-

    C

    J g

    Resin 1.25 0.20 1200

    1.30 450 1000

    Aramid Fibers 1.44 0.05 1420

    0.24

    950

    4000

    Carbon Fibers 1.85

    50 710 380

    3300

    43000

    Glass 2.55 1.0 850 4.6

    2300 31000

    reached in the vapor column and the thermal exchange coefficient between

    vaporized and solid zones.

    Tables 7 and 8 give some of the thermal properties of resin and various

    reinforcing fibers, and various unidirectional composites, respectively. Note

    the poor thermal properties of polymer resin that constitutes 50-60 of a

    fiber reinforced plastic (FRP). The properties

    of

    aramid fibers are somewhat

    similar to that of resin with minor differences in magnitudes. In contrast, the

    properties of carbon and glass fibers are different from that of the resin matrix

    material. As a result large differences exist between the thermal properties of

    resin matrix and glass or graphite fibers while the difference are negligible

    with aramid. The energy needed for vaporization for glass or graphite is also

    very high compared to the matrix. The laser power requirements, therefore,

    will be strongly dependent on the fibers used and their volume fraction and

    not the matrix. However, too high a laser power may vaporize or chemically

    degrade the polymer matrix.

    The vapor column generation mechanism is strongly influenced by the

    nature

    of

    the constituent materials

    of

    the composite (fibers and matrix), which

    may exhibit very different properties. At high specific powers, the time to

    vaporize the constituents of the composite is very short, but because of their

    different thermal properties, fibers and matrix can exhibit very different values

    of vaporization times. Theoretically, the time t that will elapse before the

    vaporization condition is reached on the work material surface under a laser

    beam source can be calculated (38) as follows:

    K

    t

    v

    -

    where K is the thermal conductivity, is the vaporization temperature, F

    o

    is

    Table 8. Typical Thermal Propert ies of Unidirectional Composites

    COMPOSITE

    Aramid/resin

    Graphite/resin

    Glass/resin

    1.35

    1.55

    1.90

    0.13

    25

    0.60

    1300

    950

    1000

    0.74

    170

    3.2

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    MACHINING OF FIBERREINFORCED COMPOSITES

    135

    the specific power, and is the thermal diffusivity. Using this equation, it is

    possible to calculate the minimum values of times needed to vaporize the

    materials at a given specific power. Figure 8 shows these values for a typical

    matrix material and three types

    of

    fibers 39 . is possible to observe two

    limit conditions at constant specific power.

    can be seen that both the fibers

    and the matrix exhibit different vaporization times. However, they are closer

    than glass or graphite fibers for aramid fibers in a resin matrix. is evident

    that FRP with aramid fibers respond better with a laser, and hence, would be

    a candidate for this material. This is fortuitous since difficulties such as sur

    face delamination and fuzziness are experienced in conventional machining

    of aramid fiber-reinforced resin matrix composites.

    Laser-Cut Quality Parameters

    Some of the defects observed in laser cutting include fiber pullout from

    the matrix surrounded by large zones with a loss

    of

    matrix material, the

    presence of craters and delamination, uneven kerf width and taper in the cut

    surface, the presence

    of

    charred material, and thermal cracks. Tagliaferri 40

    identified principal quality criteria for laser-cut surfaces as shown in Fig. 9.

    The quality parameters include the kerf width at inlet Wi and outlet W

    o

    of the

    laser beam; the size of the heat affected zone HAZ

    W

    d

    which is character

    ized by the presence of fiber debonding from the matrix or matrix recession;

    and thermal degradation

    of

    the fibers, matrix, and slope

    of

    the cut surface

    tan a from inlet Wi to outlet

    o

    for a given thickness s .

    Influence Cutting Parameters

    The quality of laser cutting depends only on the interaction time between

    the beam and the material, and therefore, on the translation speed

    of

    the beam.

    s the cutting speed increases the kerf width

    Wi

    and

    W

    o

    the slope

    of

    the

    cut surface tends to decrease and reaches a steady-state value Fig. 10 . The

    lB

    t.

    5

    igur

    8. Limit conditions for the vaporization of some composite constituents versus spe

    cific power of the beam,

    F

    o

    and interaction time t

    40 .

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    136

    KOMANDURI

    ut 41 12 11

    t

    h t 2 i ~

    X-Z

    x-z

    DO

    Slope

    o f the

    Hatl ix

    cu t

    surface

    [ j

    fJ

    ccession

    H

    W

    o

    te

    -25 -

    H

    y-z

    W

    o

    I

    V

    I

    raters

    < >

    l Z

    W

    d

    x-z

    Hcat

    L

    b

    afrected

    el ln t ion

    tone

    -

    Figure

    9. Terminology for quality of laser beam cut surfaces of FRP 40 .

    limiting width

    W;

    is close to the laser beam spot diameter. In contrast, the

    slope

    of the cut surface decreases with speed reaching a minimum value and

    the slope increases with a further increase in speed Fig. 11 . The minimum

    value depends on the thickness of the sample, the thinner the sample the

    higher the

    minimum

    value. The HAZ, similar to the kerf width, decreases

    with increasing speed Fig. 12 . This may be explained in terms of the in

    teraction time and thermal properties of the work material. The damage di

    minishes when the energy input is lower, resulting in a shorter interaction

    time.

    Caprino and Tagliaferri 41 developed a one-dimensional thermal model

    to correlate maximum cutting speed V

    ma x

    ,

    power P , material thickness r ,

    and focal spot diameter

    d . The maximum cutting speed is given by

    P

    V

    ax t

    1 5

    .. S=2.0mm

    c S=3.3mm

    o

    S=4.5mrT

    E

    V Vo

    ..

    1.

    e

    0

    :

    I

    ~

    0

    0

    0

    8 5

    0

    0

    i

    0

    8

    e

    00

    0

    8 8

    8

    2

    4

    6 8 10

    V (mlmin\

    Figure 10.

    Width of the kerf at the inlet

    W,

    and outlet

    W

    o

    of the laser versus cutting

    speed;

    P

    =

    800 W

    40 .

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    MACHINING

    O

    FIBERREINFORCED COMPOSITES

    B

    137

    o S=2.0mm

    o S=3.3mm

    S=4.5mm

    6

    :

    x

    4

    T

    B

    2

    o

    \

    a 0 00

    \

    / 0

    0

    ~

    8

    a A a

    0_ 10

    0-

    A A

    .-6._.

    8

    8 2

    4 6 B

    V m/min)

    10

    12

    igure

    11. Slope of the cut surfaces versus cutting speed;

    P

    =

    800 W (40).

    Figure 13 shows a linear vanatton

    of

    V

    na x

    d versus Pit for various

    composites (AFRP, GFRP, and CFRP). The slope

    of

    the curve gives the value

    of

    the material constant

    K

    which is 3730 Jzcrrr for AFRP, 40,000 J/crrr for

    CFRP, and 11,100 Jzcrrr for GFRP.

    The performance of the lasers in machining can also be changed by the

    introduction of a gas jet. For example, the efficiency

    of

    metal machining can

    often be increased by oxygen-assisted cutting. The technique takes advantage

    of

    the additional energy released due to the exothermic chemical reaction

    of

    the work material with oxygen. Depending on the type

    of

    work material, laser

    0.8

    S=2.0mm

    o S=3.3mm

    E

    B.6

    S= 5mm

    J

    B.4

    e

    0

    0

    c

    0

    0

    e

    0.2

    c

    0

    e

    s

    e

    e

    a

    22

    a

    e

    e

    B.B

    8

    2

    4

    6 8

    18

    V m/min)

    igure

    12. Heat-affected zone size at the inlet of the beam versus cutt ing speed;

    P

    = 800

    W

    (40).

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    l> AFRP

    o

    GFRP

    o CFRP

    138

    6

    /

    i

    6

    ,

    / /

    i e

    0

    0-

    _

    I I

    4 8

    p-

    ...

    .lWtYnml

    KOM N URI

    Figure 13. Experimental values V

    m

    ex d are reported as a function of Pit. V

    m

    is the maxi

    mum cutting speed above which a through cut cannot be obtained rnm/s ; d is the focal spot

    diameter 11m ; I is the thickness of the machine material 11m ;

    is the material parameter

    (J/cm ).

    For AFRP

    =

    3730

    J/cm ,

    for CFRP

    =

    40,000

    Jlcm ,

    and for GFRP

    =

    11,100

    lcm

    40 .

    machining may be assisted by oxygen, inert gas N

    2

    or Ar , or air. For ex

    ample, oxygen assist air and not nitrogen would be preferable for laser

    assisted machining of titanium alloys from energy considerations. However,

    to avoid oxidation of titanium, inert atmosphere may be preferred. In contrast,

    nitrogen assist is preferable for machining nickel-based superalloys.

    Several types of lasers are used for machining. The most commonly

    used are gas

    C

    2

    and Excimer lasers and solid-state Nd:YAG and Nd:

    Glass lasers. These lasers can be operated either in a cw mode or a pulse

    mode for machining. The important requirements of lasers for machining

    include the following:

    1. Adequate power available cw or pulsed .

    2. Controlled focal intensity profile.

    3. Reproducibility of power, mode, polarization, and stability.

    4. Reliability.

    5. Initial and scanning costs.

    Table 9 gives characteristics

    of

    various lasers for manufacturing appli

    cations 41 . Excimer lasers, such as xenon chloride and argon fluoride, are

    currently being developed and should soon find exciting applications for the

    machining of composites.

    Important characteristics of laser beams:

    1. Spatial profile.

    2. Beam divergence.

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    C l

    =

    z

    Ii

    Table 9

    Lasers Commonly Used for Materials Processing 41)

    C l

    0

    WAVE-

    l

    LASER

    LENGTH,

    MODE OF PULSE REP. PULSE

    :l

    =

    YPE

    I om

    OPERATION POWER, W RATE, pps

    LENGTH APPLICATIONS COMMENTS

    t l

    p

    Ruby 0.6943 Normal pulse

    2

    X 10 peak

    Low

    0.2 5

    ms Large material removal

    Often uneconomical for

    in one pulse, drilling

    multipulse applications

    Z

    diamond dies, spot

    l

    0

    welding

    =

    Nd:Glass

    1.06

    Normal pulse

    2

    X

    10

    6

    peak Low 0.5 10 ms Large material removal

    Often uneconomical

    C l

    t l

    in o ne p ulse

    I:l

    C l

    Nd:YAG

    1.06 Continuous 200

    Welding

    Compact; economical at

    0

    low powers

    Nd:YAG

    1.06 Repetitively 10

    4

    peak

    5000

    200 ns Resistor trimming elec-

    Compact and economical

    0

    Q switched

    10

    average tronic circuit fabrica-

    en

    tion

    CO, 10.6

    Continuous 375 Cutting organic materials, Bulky at high powers,

    en

    oxygen-assisted metal very eco nomi ca l at

    cutting, s cri bing brittle low powers

    materials

    CO,

    10.6

    Repetitively

    75000

    peak

    400

    50 200

    ns Resistor tri mming

    Bulky but economical

    Q -s wi tc hed 1.5 average

    CO, 10.6 Superpulsed 100 average

    500

    10-1001 -5

    Welding, hole produc- Bulky but econom ical

    tion, scribing

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    140 KOMANDURI

    3. Focusing.

    4. Temporal behavior.

    5. Power continuous and peak .

    Benefits of laser machining:

    1.

    Material waste kerf width is minimum.

    2. Minimum set-up time.

    3. No tools, hence, no wear or replacement.

    4. Smooth edge cuts can be obtained.

    5. Low total heat input, hence, low overall distortion or damage of the

    part.

    6. Parallel sided cuts possible.

    7. Sharp contoured surfaces can be generated.

    8. Independent of workpiece hardness or strength.

    9. Cuts can be made without a starter or sloping.

    Limitations of laser beam machining:

    1. HAZ. High temperatures imparted to the workpiece by laser ma

    chining at or near the last cut can cause metallurgical changes. This

    can reduce the fatigue properties of the work material.

    2. Quality of holes in deep hole drilling is poor.

    3. Unable to drill blind holes to precise depth.

    4. Lasers not efficient with highly reflective or highly thermal con

    ducting materials.

    5. Lasers not recommended for thick workpieces.

    6. Lasers tend to char thick nonmetals with reradiation from decom

    position products.

    Water-Jet and Abrasive Water-Jet Cutting

    High-pressure water-jet cutting either in unison or in consort with fine

    abrasives is a candidate process for machining inhomogeneous materials that

    are hard and abrasive, such as most polymer-matrix composite materials.

    Water cools the workpiece, and hence, minimizes the thermal deformation

    problems commonly experienced in the conventional machining of compos

    ites. A narrow kerf, a minimum amount of dust and toxic fumes, and prac

    tically no delamination effects are some of the salient features of this system

    42 . Rapid tool wear commonly experienced in conventional machining of

    composites is also not an issue in water jet or AWJ cutting. AWJ cutting,

    however, is not without its limitations. Some of the shortcomings of this

    process are high noise levels

    80 100

    dB , and consequently, the need for a

    catcher at the exit; safety; low removal rates; inability to machine blind holes

    or pockets; abrasive particles or high-pressure water jet that can damage the

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    MACHINING OF FIBERREINFORCED COMPOSITES

    machine elements; and the size of the AWl cutting system and associated

    equipment. Removal rates, dimensional accuracy, and finish can still be lim

    itations

    of

    AWl

    cutting, depending on the material and its thickness. When

    machining thick materials the jet stream tends to angle away from the direc

    tion of the cutting, resulting in a tapered surface. This effect becomes more

    pronounced as the thickness and/or feed rate increases.

    Boron-epoxy, boron-polyester, fiberglass-epoxy, graphite-epoxy, and ar

    amid-epoxy composites are some of the candidate materials for water-jet cut

    ting. Some of the metal matrix and ceramic matrix composites can also be

    machined by AWls but at reduced cutting rates. AWl cutting of composites

    depends more on the matrix material than on the reinforcement. Straight

    water-jet cutting, with no abrasives, is recommended for materials with a low

    yield strength =10 15 ksi).

    Korican 43) reported using an AWl t 35-ksi pressure, 100-grit Garnet

    abrasive, 20 hp) to cut resin-impregnated graphite, aramid, and glass fibers.

    The cutting rates changed from 63 to 5 in./min as the thickness increases

    from 1/8 to 1 in. Of course, the optimum value depends on the composite

    material, its thickness, abrasive type, size used, jet pressure, etc. Table 10

    gives the AWl cutting traverse rates for some composites materials of interest

    after Hashish 44).

    Ramulu and Arola 45) investigated the cutting of unidirectional graph

    ite-epoxy composite by Wl and AWl They repored the principal material

    removal mechanism with Wl to be the failure associated with microbending

    induced fracture and out-of-plane shear. In

    AWl

    the material-removal

    mechanism included shearing, micromachining, and erosion. They found

    AWl

    to be more feasible because

    of

    its material-removal mechanism, higher

    removal rates, and superior surface finish.

    Table 1

    Traverse CUlling Rates in/min) using AWl P: 50 ksi, abrasive: 80 mesh garnet)

    46)

    THICKNESS, in.

    1/16

    1/8

    1/4

    1/2 3/4

    Organic matrix composites

    Glass-epoxy 225

    180

    100

    40 28.0

    Graphite-epoxy 150

    125 95 35 26.0

    Carbon/carbon 75 52 31

    18 9.5

    Metal matrix composites

    B.C-Mg 15 B.C)

    71 35 24

    9.5

    SiC-Al 15 SiC)

    40 24 12

    SiC Al 25 SiC)

    22 12

    Al,O,-Al 15 Al,O,)

    22 12

    Ceramic Matrix Composites

    TiB,-SiC 15 TiB,)

    0.68

    0.35

    SiC-Al,O, 7.5 SiC)

    6.4

    3.30

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    142

    KOMANDURI

    Hashish 46 presented a technique for precision drilling

    of

    small di

    ameter holes in composites with an Wl The technique involves computer

    control of the jet pressure-time profile and the abrasive flow rate that in tum

    controls the hole size, shape, and quality. On a ceramic matrix composite

    Hashish reported drilling a hole 0.043 in diameter with an accuracy of 0.001

    in.

    EDM of Composites

    The principles of EDM are well known and will not be discussed in this

    paper. Only opportunities in machining composites will be explored. EDM

    can make complex shapes with high precision.

    t

    is, however, a slow process,

    but automation of the process can bring the cost of manufacturing down. The

    prerequisite for the EDM process is that the work material be electrically

    conductive. The electrical resistivity of the work material should be lower

    than 100 O-cm; organic matrix composites are, therefore, not candidate ma

    terials for EDM. These composites can, however, be made conductive by

    impregnating them with metallic fillers Cu, AI, or Ag powders , but that can

    defeat the purpose of composites for high strength, lightweight applications.

    MMCs will be ideal candidates for EDM, especially where complicated

    shapes and high accuracy are required. Only a few ceramic matrix composites

    that are electrically conductive can be shaped by EDM. However, recent

    improvements in mechanical properties, especially the fracture toughness and

    strength of whisker-reinforced ceramics by improved processing technology

    and starting materials, makes them ideally suited for high-temperature and

    fatigue-resistant applications. Silicon carbide whisker-reinforced alumina. is

    one example. The fracture toughness is nearly double that of the material

    without the fibers. t is the same with silicon-nitride-based composites. These

    materials are very hard but extremely difficult as well as costly to machine

    or grind. f however, these materials can be made electrically conductive by

    adding conductive refractory materials such as TiC or TiN without compro

    mising on other properties, processing these components by EDM can be

    come an economic proposition. The particle size and percentage of TiC or

    TiN to be added to the matrix can be adjusted to make it sufficiently electri

    cally conductive to carry out the EDM process, without compromising sig

    nificantly on the ultimate properties and performance requirements of the

    material.

    Silicon-nitride-based composites can be made electrically conductive by

    adding TiN and alumina-based composites by adding TiC. Martin et al. 47

    found that for Si

    3N

    4 -ba se d

    composites with TiN additions, EDM cannot be

    performed at a conductivity lower than 2 10

    2

    o

    cm

    since no electrical

    arc is produced between the workpiece and the tool Fig. 14 . However, a

    preferred value of conductivity for good EDM practice is found to be 5 X

    10

    3

    0 -

    1

    m

    I

    In contrast, for wire EDM of SiC whisker-reinforced, zirconia-

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    MACHINING OF FIBER-REINFORCED COMPOSITES

    143

    EDM LImit

    ..J

    10

    U

    IE

    1

    B

    U

    W

    ..J

    W

    10

    30

    0

    6

    70

    8

    9

    100

    owl TIN

    >

    t

    >

    10

    t

    U

    ::I

    C 10

    z

    o

    o

    igur 14. Variation of electrical conductivity of a Si,N

    4

    TiN composite versus the TiN

    content for two grades of TiN 47 .

    1

    . .

    800

    M

    LIMIT

    Z

    IE

    l

    600

    III

    ..J

    IE

    Conducllvllr

    40 0

    ::I

    2 St,

    enlllh

    III

    ..J

    200

    2

    I

    S

    i

    i

    10r---....,

    JL

    .......

    ;

    o

    z

    8

    ;i

    IE

    U

    10

    III

    10 20

    30

    40 00

    .1 TIC

    igur 15. Influence of TiC content on electrical conductivity and on three-point-bend test

    of alumina-based composites 47 .

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    KOMANDURI

    toughened alumina with the addition of TiC, the minimum conductivity value

    was reported as 1 0

    1

    cm Fig. 15). With a

    30

    vol

    TiC addition to the

    alumina-based composite the bend strength was reported to be 125 ksi Fig.

    16), while up to 50 vol of TiN particles could be added to the Si

    3N

    matrix

    without reducing its fracture toughness. This is one example where difficult

    to-machine materials such as ceramic composites can be tamed by making

    them electrically conducting and processing them by EDM. Typical EDM

    removal rates for Si

    3N

    TiN composites, steel, and cemented tungsten carbide

    are given in Table 11.

    Gadalla and Cheng 48) investigated wire EDM of various ceramic com

    posites. By combining a nonconducting ceramic with a more conducting ce

    ramic it was possible to lower the electrical resistivity. For example, by com

    bining TiC to alumina, it could be made more conductive for EDM cutting.

    Table 12 shows various composite materials along with relevant properties)

    that were successfully cut by wire EDM by Gadalla and Cheng. The addition

    of a more conducting phase may in many cases not be detrimental to its

    performance and may actually facilitate it. For example, by combining

    30

    TiC to alumina, the strength, hardness, wear resistance, and fracture strength

    of the cutting tool material will increase. At the same time, EDM can be used

    for processing this material. A similar situation exists for SWON with TiN,

    Si

    3N

    with TiN, and SiC with TiB

    2

    as shown in Table 12.

    1000

    900

    II

    l:

    I:

    800

    e

    Z

    W

    II:

    70 0

    II I

    J

    II

    : l

    600

    x

    W

    J

    L

    50 0

    0 10

    20

    30

    40

    50 6 0

    70

    l w I T iN

    igur

    16. Effect of TiN ratio on the three-point bend strength of a Si

    3N

    4

    ,

    TiN composite

    47).

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    MACIDNING OF FIBER-REINFORCED COMPOSITES

    145

    Si,N.-TiN

    COMPOSITE STEEL

    190 140 190

    0.28 0.5 0.16 0.14

    24 64 16 24

    ve v e

    ve

    10 10

    5

    5

    20

    0.0037 0.0043 0.0019

    4 6 0

    6 6 20

    0.0011 0.0013 0.0007

    ble 11. Comparative Performance of Si,N. Composite, Steel, and WC in Wire EDM (47)

    Wire EDM (0.010 in. brass wire)

    Wire speed, in./min

    Cutting rate, in./min

    Finish (Ra), l in

    Die Sink EDM

    (Copper die and oil dielectric)

    Roughing operation

    Die polarization, 80 V

    Intensity, A

    Die consumption,

    Removal rate, in. /min

    Finishing operation

    Intensity

    Die consumption,

    emoval rate in. /min

    Ultrasonic-Assisted Machining of Composites

    Ultrasonic-assisted drilling involves the use of a rotary tool where an

    axial vibratory motion at high frequency is superimposed. A special adaptor

    is required to transmit the vibration from a piezoelectric transducer to the

    tool. Ultrasonic vibration can reduce friction, break chips, and reduce tool

    wear. is a particularly useful technique when the matrix or the reinforcing

    fibers are hard, brittle materials. Use of a core drill permits cutting fluids to

    be passed through its center. Ultrasonic machining through a slow operation

    can result in high finish and accuracy of intricate parts.

    Garlasco (11) of Grumman conducted ultrasonic machining experiments

    on boron fiber composites. Based on the analysis of costs, he found the

    technique to be more expensive than diamond-abrasive cutting. He, however,

    recommended this process as a potential for applications when intricate

    shapes

    of

    high accuracy and finish are to be produced.

    ble

    12.

    Ceramic Composites Cut by Wire EDM (48)

    MATERIAL

    A1,O,-TiC

    Si-SiC

    SiAlON-TiN

    Si.,N.-TiN

    SiC-TiB,

    COMPOSITION

    70/30

    5/95

    80/20

    75/25

    80/20

    DENSITY,

    g/cm

    4.23

    3.09

    4.0

    3.75

    3.3

    ELEcrRICAL

    RESISTIVITY,

    fl-cm

    3.5e-3

    1.43e-4

    7.0e-4

    1.5e-3

    1.0

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    t

    KOM NDURI

    Doran and Maikish 14 conducted rotary ultrasonic machining. They

    used a core drill at speeds up to 6000 rpm while simultaneously vibrating

    the tool axially at

    20

    kHz with a peak-to-peak amplitude of approximately

    0.001 in. They found a slight improvement of tool life ~ 1 O - 2 0 ) . However,

    the savings resulting from the tool life improvement was much less than the

    additional costs involved in the use of ullrasonic machining of the boron

    epoxy composite. Therefore, this process was not recommended unless com

    plex shapes of high finish and accuracy are needed.

    Electrochemical Spark Machining

    Jain et al. 49 proposed electrochemical spark machining as a plausible

    solution for the cutting of fiber-reinforced plastics. They investigated Kevlar

    fiber-reinforced epoxy and glass fiber-reinforced epoxy as work materials,

    copper as the tool, and an aqueous solution of NaCI as the electrolyte. They

    established the feasibility for specific machining operations and the optimi

    zation of process conditions. Subsequently, Jain et al. 50 extended this con

    cept to traveling wire electrochemical spark machining TW-ECSM of com

    posites. Glass-epoxy and Kevlar-epoxy composites were used as the work

    materials, copper wire as the traveling wire electrode, and NaOH as the elec

    trolyte. Jain et al. showed that higher accuracy was feasible with this tech

    nique.

    S FETY ONSIDER TIONS

    Composites contain fibers, which when machined, can release finer frac

    tions of the fibers into the atmosphere. Also, in the case of polymer-based

    composites, some of the chemicals released because of heat and thermal dam

    age du