§172.102 49 CFR Ch. I (10–1–14 Edition) · PP Sodium copper cyanide solution PP Sodium...

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49 CFR Ch. I (10–1–14 Edition) § 172.102

LIST OF MARINE POLLUTANTS—Continued

S.M.P. (1)

Marine pollutant (2)

Silver cyanide Silver orthoarsenite

PP Sodium copper cyanide, solid PP Sodium copper cyanide solution PP Sodium cuprocyanide, solid PP Sodium cuprocyanide, solution

Sodium cyanide, solid Sodium cyanide, solution Sodium dinitro-o-cresolate, dry or wetted with less

than 15 per cent water, by mass Sodium dinitro-ortho-cresolate, wetted with not less

than 15 per cent water, by mass PP Sodium pentachlorophenate

Strychnine or Strychnine salts Sulfotep

PP Sulprophos Tallow nitrile Temephos TEPP

PP Terbufos Tetrabromoethane Tetrabromomethane 1,1,2,2-Tetrachloroethane Tetrachloroethylene Tetrachloromethane Tetraethyl dithiopyrophosphate

PP Tetraethyl lead, liquid Tetramethrin Tetramethyllead Thallium chlorate Thallium compounds, n.o.s. Thallium compounds (pesticides) Thallium nitrate Thallium sulfate Thallous chlorate Thiocarbonyl tetrachloride Triaryl phosphates, isopropylated

PP Triaryl phosphates, n.o.s. Triazophos Tribromomethane

PP Tributyltin compounds Trichlorfon

PP 1,2,3—Trichlorobenzene Trichlorobenzenes, liquid Trichlorobutene Trichlorobutylene Trichloromethane sulphuryl chloride Trichloromethyl sulphochloride Trichloronat Tricresyl phosphate (less than 1% ortho-isomer)

PP Tricresyl phosphate, not less than 1% ortho-isomer but not more than 3% orthoisomer

PP Tricresyl phosphate with more than 3 per cent ortho isomer

Triethylbenzene Triisopropylated phenyl phosphates Trimethylene dichloride

PP Triphenylphosphate Triphenyl phosphate/tert-butylated triphenyl

phosphates mixtures containing 5% to 10% triphenyl phosphates

PP Triphenyl phosphate/tert-butylated triphenyl phosphates mixtures containing 10% to 48% triphenyl phosphates

PP Triphenyltin compounds Tritolyl phosphate (less than 1% ortho-isomer)

PP Tritolyl phosphate (not less than 1% ortho-isomer) Trixylenyl phosphate Vinylidene chloride, stabilized Warfarin (and salts of)

PP White phosphorus, dry

LIST OF MARINE POLLUTANTS—Continued

S.M.P. (1)

Marine pollutant (2)

PP White phosphorus, wet White spirit, low (15-20%) aromatic

PP Yellow phosphorus, dry PP Yellow phosphorus, wet

Zinc bromide Zinc cyanide

[Amdt. 172–173, 55 FR 52474, Dec. 21, 1990]

EDITORIAL NOTE: For FEDERAL REGISTER ci-tations affecting § 172.101, see the List of CFR Sections Affected, which appears in the Finding Aids section of the printed volume and at www.fdsys.gov.

§ 172.102 Special provisions.

(a) General. When column 7 of the § 172.101 table refers to a special provi-sion for a hazardous material, the meaning and requirements of that pro-vision are as set forth in this section. When a special provision specifies packaging or packaging require-ments—

(1) The special provision is in addi-tion to the standard requirements for all packagings prescribed in § 173.24 of this subchapter and any other applica-ble packaging requirements in subparts A and B of part 173 of this subchapter; and

(2) To the extent a special provision imposes limitations or additional re-quirements on the packaging provi-sions set forth in column 8 of the § 172.101 table, packagings must con-form to the requirements of the special provision.

(b) Description of codes for special pro-visions. Special provisions contain packaging provisions, prohibitions, ex-ceptions from requirements for par-ticular quantities or forms of materials and requirements or prohibitions appli-cable to specific modes of transpor-tation, as follows:

(1) A code consisting only of numbers (for example, ‘‘11’’) is multi-modal in application and may apply to bulk and non-bulk packagings.

(2) A code containing the letter ‘‘A’’ refers to a special provision which ap-plies only to transportation by air-craft.

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Pipeline and Haz. Matls. Safety Admin., DOT § 172.102

(3) A code containing the letter ‘‘B’’ refers to a special provision that ap-plies only to bulk packaging require-ments. Unless otherwise provided in this subchapter, these special provi-sions do not apply to UN, IM Specifica-tion portable tanks or IBCs.

(4) A code containing the letters ‘‘IB’’ or ‘‘IP’’ refers to a special provision that applies only to transportation in IBCs.

(5) A code containing the letter ‘‘N’’ refers to a special provision which ap-plies only to non-bulk packaging re-quirements.

(6) A code containing the letter ‘‘R’’ refers to a special provision which ap-plies only to transportation by rail.

(7) A code containing the letter ‘‘T’’ refers to a special provision which ap-plies only to transportation in UN or IM Specification portable tanks.

(8) A code containing the letters ‘‘TP’’ refers to a portable tank special provision for UN or IM Specification portable tanks that is in addition to those provided by the portable tank in-structions or the requirements in part 178 of this subchapter.

(9) A code containing the letter ‘‘W’’ refers to a special provision that ap-plies only to transportation by water.

(c) Tables of special provisions. The fol-lowing tables list, and set forth the re-quirements of, the special provisions referred to in column 7 of the § 172.101 table.

(1) Numeric provisions. These provi-sions are multi-modal and apply to bulk and non-bulk packagings:

Code/Special Provisions

1 This material is poisonous by inhalation (see § 171.8 of this subchapter) in Hazard Zone A (see § 173.116(a) or § 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter.

2 This material is poisonous by inhalation (see § 171.8 of this subchapter) in Hazard Zone B (see § 173.116(a) or § 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter.

3 This material is poisonous by inhalation (see § 171.8 of this subchapter) in Hazard Zone C (see § 173.116(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this sub-chapter.

4 This material is poisonous by inhalation (see § 171.8 of this subchapter) in Hazard

Zone D (see § 173.116(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this sub-chapter.

5 If this material meets the definition for a material poisonous by inhalation (see § 171.8 of this subchapter), a shipping name must be selected which identifies the inha-lation hazard, in Division 2.3 or Division 6.1, as appropriate.

6 This material is poisonous-by-inhalation and must be described as an inhalation hazard under the provisions of this sub-chapter.

8 A hazardous substance that is not a haz-ardous waste may be shipped under the shipping description ‘‘Other regulated sub-stances, liquid or solid, n.o.s.’’, as appro-priate. In addition, for solid materials, spe-cial provision B54 applies.

9 Packaging for certain PCBs for disposal and storage is prescribed by EPA in 40 CFR 761.60 and 761.65.

11 The hazardous material must be pack-aged as either a liquid or a solid, as appro-priate, depending on its physical form at 55 °C (131 °F) at atmospheric pressure.

12 In concentrations greater than 40 per-cent, this material has strong oxidizing properties and is capable of starting fires in contact with combustible materials. If appropriate, a package containing this ma-terial must conform to the additional la-beling requirements of § 172.402 of this sub-chapter.

13 The words ‘‘Inhalation Hazard’’ shall be entered on each shipping paper in associa-tion with the shipping description, shall be marked on each non-bulk package in asso-ciation with the proper shipping name and identification number, and shall be marked on two opposing sides of each bulk pack-age. Size of marking on bulk package must conform to § 172.302(b) of this subchapter. The requirements of §§ 172.203(m) and 172.505 of this subchapter do not apply.

14 Motor fuel antiknock mixtures are: a. Mixtures of one or more organic lead

mixtures (such as tetraethyl lead, triethylmethyl lead, diethyldimethyl lead, ethyltrimethyl lead, and tetramethyl lead) with one or more halo-gen compounds (such as ethylene dibromide and ethylene dichloride), hy-drocarbon solvents or other equally effi-cient stabilizers; or

b. tetraethyl lead. 15 This entry applies to ‘‘Chemical kits’’

and ‘‘First aid kits’’ containing one or more compatible items of hazardous mate-rials in boxes, cases, etc. that, for example, are used for medical, analytical, diag-nostic, testing, or repair purposes. Kits that are carried on board transport vehi-cles for first aid or operating purposes are not subject to the requirements of this subchapter.


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49 CFR Ch. I (10–1–14 Edition) § 172.102

16 This description applies to smokeless powder and other solid propellants that are used as powder for small arms and have been classed as Division 1.3C, 1.4C and Divi-sion 4.1 in accordance with § 173.56 of this subchapter.

19 For domestic transportation only, the identification number ‘‘UN1075’’ may be used in place of the identification number specified in column (4) of the § 172.101 table. The identification number used must be consistent on package markings, shipping papers and emergency response informa-tion.

21 This material must be stabilized by ap-propriate means (e.g., addition of chemical inhibitor, purging to remove oxygen) to prevent dangerous polymerization (see § 173.21(f) of this subchapter).

22 If the hazardous material is in dispersion in organic liquid, the organic liquid must have a flash point above 50 °C (122 °F).

23 This material may be transported under the provisions of Division 4.1 only if it is so packed that the percentage of diluent will not fall below that stated in the shipping description at any time during transport. Quantities of not more than 500 g per pack-age with not less than 10 percent water by mass may also be classed in Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter).

24 Alcoholic beverages containing more than 70 percent alcohol by volume must be transported as materials in Packing Group II. Alcoholic beverages containing more than 24 percent but not more than 70 per-cent alcohol by volume must be trans-ported as materials in Packing Group III.

26 This entry does not include ammonium permanganate, the transport of which is prohibited except when approved by the Associate Administrator.

28 The dihydrated sodium salt of dichloroisocyanuric acid is not subject to the requirements of this subchapter.

30 Sulfur is not subject to the requirements of this subchapter if transported in a non- bulk packaging or if formed to a specific shape (for example, prills, granules, pel-lets, pastilles, or flakes). A bulk packaging containing sulfur is not subject to the placarding requirements of subpart F of this part, if it is marked with the appro-priate identification number as required by subpart D of this part. Molten sulfur must be marked as required by § 172.325 of this subchapter.

31 Materials which have undergone suffi-cient heat treatment to render them non- hazardous are not subject to the require-ments of this subchapter.

32 Polymeric beads and molding compounds may be made from polystyrene,

poly(methyl methacrylate) or other poly-meric material.

33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited.

34 The commercial grade of calcium nitrate fertilizer, when consisting mainly of a dou-ble salt (calcium nitrate and ammonium nitrate) containing not more than 10 per-cent ammonium nitrate and at least 12 per-cent water of crystallization, is not subject to the requirements of this subchapter.

35 Antimony sulphides and oxides which do not contain more than 0.5 percent of ar-senic calculated on the total mass do not meet the definition of Division 6.1.

37 Unless it can be demonstrated by testing that the sensitivity of the substance in its frozen state is no greater than in its liquid state, the substance must remain liquid during normal transport conditions. It must not freeze at temperatures above ¥15 °C (5 °F).

38 If this material shows a violent effect in laboratory tests involving heating under confinement, the labeling requirements of Special Provision 53 apply, and the mate-rial must be packaged in accordance with packing method OP6 in § 173.225 of this sub-chapter. If the SADT of the technically pure substance is higher than 75 °C, the technically pure substance and formula-tions derived from it are not self-reactive materials and, if not meeting any other hazard class, are not subject to the re-quirements of this subchapter.

39 This substance may be carried under pro-visions other than those of Class 1 only if it is so packed that the percentage of water will not fall below that stated at any time during transport. When phlegmatized with water and inorganic inert material, the content of urea nitrate must not ex-ceed 75 percent by mass and the mixture should not be capable of being detonated by test 1(a)(i) or test 1(a)(ii) in the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter).

40 Polyester resin kits consist of two com-ponents: A base material (Class 3, Packing Group II or III) and an activator (organic peroxide), each separately packed in an inner packaging. The organic peroxide must be type D, E, or F, not requiring tem-perature control. The components may be placed in the same outer packaging pro-vided they will not interact dangerously in the event of leakage. The Packing Group assigned will be II or III, according to the classification criteria for Class 3, applied to the base material. Additionally, unless otherwise excepted in this subchapter, pol-yester resin kits must be packaged in spec-ification combination packagings based on the performance level of the base material contained within the kit.


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41 This material at the Packing Group II hazard criteria level may be transported in Large Packagings.

43 The membrane filters, including paper separators and coating or backing mate-rials, that are present in transport, must not be able to propagate a detonation as tested by one of the tests described in the UN Manual of Tests and Criteria, Part I, Test series 1(a) (IBR, see § 171.7 of this sub-chapter). On the basis of the results of suitable burning rate tests, and taking into account the standard tests in the UN Manual of Tests and Criteria, Part III, sub-section 33.2.1 (IBR, see § 171.7 of this sub-chapter), nitrocellulose membrane filters in the form in which they are to be trans-ported that do not meet the criteria for a Division 4.1 material are not subject to the requirements of this subchapter. Pack-agings must be so constructed that explo-sion is not possible by reason of increased internal pressure. Nitrocellulose mem-brane filters covered by this entry, each with a mass not exceeding 0.5 g, are not subject to the requirements of this sub-chapter when contained individually in an article or a sealed packet.

44 The formulation must be prepared so that it remains homogenous and does not separate during transport. Formulations with low nitrocellulose contents and nei-ther showing dangerous properties when tested for their ability to detonate, deflagrate or explode when heated under defined confinement by the appropriate test methods and criteria in the UN Man-ual of Tests and Criteria (IBR, see § 171.7 of this subchapter), nor classed as a Division 4.1 (flammable solid) when tested in ac-cordance with the procedures specified in § 173.124 of this subchapter (chips, if nec-essary, crushed and sieved to a particle size of less than 1.25 mm), are not subject to the requirements of this subchapter.

45 Temperature should be maintained be-tween 18 °C (64.4 °F) and 40 °C (104 °F). Tanks containing solidified methacrylic acid must not be reheated during trans-port.

46 This material must be packed in accord-ance with packing method OP6 (see § 173.225 of this subchapter). During transport, it must be protected from direct sunshine and stored (or kept) in a cool and well-ven-tilated place, away from all sources of heat.

47 Mixtures of solids that are not subject to this subchapter and flammable liquids may be transported under this entry without first applying the classification criteria of Division 4.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Except when the liquids are fully absorbed in solid material contained in sealed bags, for single packagings, each

packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Small inner packagings consisting of sealed packets and articles containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed onto a solid material are not sub-ject to this subchapter provided there is no free liquid in the packet or article.

48 Mixtures of solids that are not subject to this subchapter and toxic liquids may be transported under this entry without first applying the classification criteria of Divi-sion 6.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. This entry may not be used for solids containing a Packing Group I liquid.

49 Mixtures of solids that are not subject to this subchapter and corrosive liquids may be transported under this entry without first applying the classification criteria of Class 8, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level.

50 Cases, cartridge, empty with primer which are made of metallic or plastic cas-ings and meeting the classification criteria of Division 1.4 are not regulated for domes-tic transportation.

51 This description applies to items pre-viously described as ‘‘Toy propellant de-vices, Class C’’ and includes reloadable kits. Model rocket motors containing 30 grams or less propellant are classed as Di-vision 1.4S and items containing more than 30 grams of propellant but not more than 62.5 grams of propellant are classed as Di-vision 1.4C.

52 This entry may only be used for sub-stances that do not exhibit explosive prop-erties of Class 1 (explosive) when tested in accordance with Test Series 1 and 2 of Class 1 (explosive) in the UN Manual of Tests and Criteria, Part I (incorporated by reference; see § 171.7 of this subchapter).

53 Packages of these materials must bear the subsidiary risk label, ‘‘EXPLOSIVE’’, and the subsidiary hazard class/division must be entered in parentheses imme-diately following the primary hazard class in the shipping description, unless other-wise provided in this subchapter or through an approval issued by the Asso-ciate Administrator, or the competent au-thority of the country of origin. A copy of the approval shall accompany the shipping papers.


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49 CFR Ch. I (10–1–14 Edition) § 172.102

54 Maneb or maneb preparations not meet-ing the definition of Division 4.3 or any other hazard class are not subject to the requirements of this subchapter when transported by motor vehicle, rail car, or aircraft.

55 This device must be approved in accord-ance with § 173.56 of this subchapter by the Associate Administrator.

56 A means to interrupt and prevent deto-nation of the detonator from initiating the detonating cord must be installed between each electric detonator and the detonating cord ends of the jet perforating guns before the charged jet perforating guns are of-fered for transportation.

57 Maneb or Maneb preparations stabilized against self-heating need not be classified in Division 4.2 when it can be dem-onstrated by testing that a volume of 1 m3 of substance does not self-ignite and that the temperature at the center of the sam-ple does not exceed 200 °C, when the sample is maintained at a temperature of not less than 75 °C ±2 °C for a period of 24 hours, in accordance with procedures set forth for testing self-heating materials in the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter).

58 Aqueous solutions of Division 5.1 inor-ganic solid nitrate substances are consid-ered as not meeting the criteria of Division 5.1 if the concentration of the substances in solution at the minimum temperature encountered in transport is not greater than 80% of the saturation limit.

59 Ferrocerium, stabilized against corro-sion, with a minimum iron content of 10 percent is not subject to the requirements of this subchapter.

61 A chemical oxygen generator is spent if its means of ignition and all or a part of its chemical contents have been expended.

62 Oxygen generators (see § 171.8 of this sub-chapter) are not authorized for transpor-tation under this entry.

64 The group of alkali metals includes lith-ium, sodium, potassium, rubidium, and caesium.

65 The group of alkaline earth metals in-cludes magnesium, calcium, strontium, and barium.

66 Formulations of these substances con-taining not less than 30 percent non-vola-tile, non-flammable phlegmatizer are not subject to this subchapter.

70 Black powder that has been classed in ac-cordance with the requirements of § 173.56 of this subchapter may be reclassed and of-fered for domestic transportation as a Di-vision 4.1 material if it is offered for trans-portation and transported in accordance with the limitations and packaging re-quirements of § 173.170 of this subchapter.

74 During transport, this material must be protected from direct sunshine and stored

or kept in a cool and well-ventilated place, away from all sources of heat.

78 This entry may not be used to describe compressed air which contains more than 23.5 percent oxygen. Compressed air con-taining greater than 23.5 percent oxygen must be shipped using the description ‘‘Compressed gas, oxidizing, n.o.s., UN3156.’’

79 This entry may not be used for mixtures that meet the definition for oxidizing gas.

81 Polychlorinated biphenyl items, as de-fined in 40 CFR 761.3, for which specifica-tion packagings are impractical, may be packaged in non-specification packagings meeting the general packaging require-ments of subparts A and B of part 173 of this subchapter. Alternatively, the item itself may be used as a packaging if it meets the general packaging requirements of subparts A and B of part 173 of this sub-chapter.

101 The name of the particular substance or article must be specified.

102 The ends of the detonating cord must be tied fast so that the explosive cannot es-cape. The articles may be transported as in Division 1.4 Compatibility Group D (1.4D) if all of the conditions specified in § 173.63(a) of this subchapter are met.

103 Detonators which will not mass deto-nate and undergo only limited propagation in the shipping package may be assigned to 1.4B classification code. Mass detonate means that more than 90 percent of the de-vices tested in a package explode prac-tically simultaneously. Limited propaga-tion means that if one detonator near the center of a shipping package is exploded, the aggregate weight of explosives, exclud-ing ignition and delay charges, in this and all additional detonators in the outside packaging that explode may not exceed 25 grams.

105 The word ‘‘Agents’’ may be used instead of ‘‘Explosives’’ when approved by the As-sociate Administrator.

106 The recognized name of the particular explosive may be specified in addition to the type.

107 The classification of the substance is ex-pected to vary especially with the particle size and packaging but the border lines have not been experimentally determined; appropriate classifications should be verified following the test procedures in §§ 173.57 and 173.58 of this subchapter.

108 Fireworks must be so constructed and packaged that loose pyrotechnic composi-tion will not be present in packages during transportation.

109 Rocket motors must be nonpropulsive in transportation unless approved in ac-cordance with § 173.56 of this subchapter. A rocket motor to be considered ‘‘nonpropul-sive’’ must be capable of unrestrained


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burning and must not appreciably move in any direction when ignited by any means.

110 Fire extinguishers transported under UN1044 and oxygen cylinders transported for emergency use under UN1072 may in-clude installed actuating cartridges (car-tridges, power device of Division 1.4C or 1.4S), without changing the classification of Division 2.2, provided the aggregate quantity of deflagrating (propellant) explo-sives does not exceed 3.2 grams per cyl-inder. Oxygen cylinders with installed ac-tuating cartridges as prepared for trans-portation must have an effective means of preventing inadvertent activation.

111 Explosive substances of Division 1.1 Compatibility Group A (1.1A) are forbidden for transportation if dry or not desen-sitized, unless incorporated in a device.

113 The sample must be given a tentative approval by an agency or laboratory in ac-cordance with § 173.56 of this subchapter.

114 Jet perforating guns, charged, oil well, without detonator may be reclassed to Di-vision 1.4 Compatibility Group D (1.4D) if the following conditions are met: a. The total weight of the explosive con-

tents of the shaped charges assembled in the guns does not exceed 90.5 kg (200 pounds) per vehicle; and

b. The guns are packaged in accordance with Packing Method US 1 as specified in § 173.62 of this subchapter.

115 Boosters with detonator, detonator as-semblies and boosters with detonators in which the total explosive charge per unit does not exceed 25 g, and which will not mass detonate and undergo only limited propagation in the shipping package may be assigned to 1.4B classification code. Mass detonate means more than 90 percent of the devices tested in a package explode practically simultaneously. Limited propa-gation means that if one booster near the center of the package is exploded, the ag-gregate weight of explosives, excluding ig-nition and delay charges, in this and all additional boosters in the outside pack-aging that explode may not exceed 25 g.

116 Fuzes, detonating may be classed in Di-vision 1.4 if the fuzes do not contain more than 25 g of explosive per fuze and are made and packaged so that they will not cause functioning of other fuzes, explosives or other explosive devices if one of the fuzes detonates in a shipping packaging or in adjacent packages.

117 If shipment of the explosive substance is to take place at a time that freezing weather is anticipated, the water con-tained in the explosive substance must be mixed with denatured alcohol so that freezing will not occur.

118 This substance may not be transported under the provisions of Division 4.1 unless specifically authorized by the Associate

Administrator (see UN0143 or UN0150 as ap-propriate).

119 This substance, when in quantities of not more than 11.5 kg (25.3 pounds), with not less than 10 percent water, by mass, also may be classed as Division 4.1, pro-vided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter).

120 The phlegmatized substance must be significantly less sensitive than dry PETN.

121 This substance, when containing less al-cohol, water or phlegmatizer than speci-fied, may not be transported unless ap-proved by the Associate Administrator.

123 Any explosives, blasting, type C con-taining chlorates must be segregated from explosives containing ammonium nitrate or other ammonium salts.

125 Lactose or glucose or similar materials may be used as a phlegmatizer provided that the substance contains not less than 90%, by mass, of phlegmatizer. These mix-tures may be classified in Division 4.1 when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter) and approved by the Associate Administrator. Testing must be conducted on at least three pack-ages as prepared for transport. Mixtures containing at least 98%, by mass, of phlegmatizer are not subject to the re-quirements of this subchapter. Packages containing mixtures with not less than 90% by mass, of phlegmatizer need not bear a POISON subsidiary risk label.

127 Mixtures containing oxidizing and or-ganic materials transported under this entry may not meet the definition and cri-teria of a Class 1 material. (See § 173.50 of this subchapter.)

128 Regardless of the provisions of § 172.101(c)(12), aluminum smelting by-prod-ucts and aluminum remelting by-products described under this entry, meeting the definition of Class 8, Packing Group II and III may be classed as a Division 4.3 mate-rial and transported under this entry. The presence of a Class 8 hazard must be com-municated as required by this part for sub-sidiary hazards.

129 These materials may not be classified and transported unless authorized by the Associate Administrator on the basis of re-sults from Series 2 Test and a Series 6(c) Test from the UN Manual of Tests and Cri-teria (IBR, see § 171.7 of this subchapter) on packages as prepared for transport. The packing group assignment and packaging must be approved by the Associate Admin-istrator for Hazardous Materials Safety on the basis of the criteria in § 173.21 of this subchapter and the package type used for the Series 6(c) test.


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49 CFR Ch. I (10–1–14 Edition) § 172.102

130 ‘‘Batteries, dry, sealed, n.o.s.,’’ com-monly referred to as dry batteries, are her-metically sealed and generally utilize met-als (other than lead) and/or carbon as elec-trodes. These batteries are typically used for portable power applications. The re-chargeable (and some non-rechargeable) types have gelled alkaline electrolytes (rather than acidic) making it difficult for them to generate hydrogen or oxygen when overcharged and therefore, differentiating them from non-spillable batteries. Dry bat-teries specifically covered by another entry in the § 172.101 Table must be trans-ported in accordance with the require-ments applicable to that entry. For exam-ple, nickel-metal hydride batteries trans-ported by vessel in certain quantities are covered by another entry (see Batteries, nickel-metal hydride, UN3496). Dry bat-teries not specifically covered by another entry in the § 172.101 Table are covered by this entry (i.e., Batteries, dry, sealed, n.o.s.) and are not subject to requirements of this subchapter except for the following: (a) Incident reporting. For transportation

by aircraft, a telephone report in accord-ance with § 171.15(a) is required if a fire, violent rupture, explosion or dangerous evolution of heat (i.e., an amount of heat sufficient to be dangerous to packaging or personal safety to include charring of packaging, melting of packaging, scorch-ing of packaging, or other evidence) oc-curs as a direct result of a dry battery. For all modes of transportation, a writ-ten report submitted, retained, and up-dated in accordance with § 171.16 is re-quired if a fire, violent rupture, explosion or dangerous evolution of heat occurs as a direct result of a dry battery or bat-tery-powered device.

(b) Preparation for transport. Batteries and battery-powered device(s) containing batteries must be prepared and packaged for transport in a manner to prevent:

(1) A dangerous evolution of heat; (2) Short circuits, including but not lim-

ited to the following methods: (i) Packaging each battery or each battery-

powered device when practicable, in fully enclosed inner packagings made of non- conductive material;

(ii) Separating or packaging batteries in a manner to prevent contact with other batteries, devices or conductive mate-rials (e.g., metal) in the packagings; or

(iii) Ensuring exposed terminals or connec-tors are protected with non-conductive caps, non-conductive tape, or by other appropriate means; and

(3) Damage to terminals. If not impact re-sistant, the outer packaging should not be used as the sole means of protecting the battery terminals from damage or short circuiting. Batteries must be se-curely cushioned and packed to prevent

shifting which could loosen terminal caps or reorient the terminals to produce short circuits. Batteries contained in de-vices must be securely installed. Ter-minal protection methods include but are not limited to the following:

(i) Securely attaching covers of sufficient strength to protect the terminals;

(ii) Packaging the battery in a rigid plastic packaging; or

(iii) Constructing the battery with termi-nals that are recessed or otherwise pro-tected so that the terminals will not be subjected to damage if the package is dropped.

(c) Additional air transport requirements. For a battery whose voltage (electrical po-tential) exceeds 9 volts—

(1) When contained in a device, the device must be packaged in a manner that pre-vents unintentional activation or must have an independent means of preventing unintentional activation (e.g., packaging restricts access to activation switch, switch caps or locks, recessed switches, trigger locks, temperature sensitive cir-cuit breakers, etc.); and

(2) An indication of compliance with this special provision must be provided by marking each package with the words ‘‘not restricted’’ or by including the words ‘‘not restricted’’ on a transport document such as an air waybill accom-panying the shipment.

(d) Used or spent battery exception. Used or spent dry batteries of both non-recharge-able and rechargeable designs, with a marked rating up to 9-volt that are com-bined in the same package and trans-ported by highway or rail for recycling, reconditioning, or disposal are not sub-ject to this special provision or any other requirement of the HMR. Note that bat-teries utilizing different chemistries (i.e., those battery chemistries specifically covered by another entry in the § 172.101 Table) as well as dry batteries with a marked rating greater than 9-volt may not be combined with used or spent bat-teries in the same package. Note also that this exception does not apply to bat-teries that have been reconditioned for reuse.

131 This material may not be offered for transportation unless approved by the As-sociate Administrator.

132 This entry may only be used for uni-form, ammonium nitrate based fertilizer mixtures, containing nitrogen, phosphate or potash, meeting the following criteria: (1) Contains not more than 70% ammonium nitrate and not more than 0.4% total com-bustible, organic material calculated as carbon or (2) Contains not more than 45% ammonium nitrate and unrestricted com-bustible material.


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134 This entry only applies to vehicles pow-ered by wet batteries, sodium batteries, lithium metal batteries or lithium ion bat-teries and equipment powered by wet bat-teries or sodium batteries that are trans-ported with these batteries installed. For the purpose of this special provision, vehi-cles are self-propelled apparatus designed to carry one or more persons or goods. Ex-amples of such vehicles are electrically- powered cars, motorcycles, scooters, three- and four-wheeled vehicles or motorcycles, battery-assisted bicycles, lawn tractors, boats, aircraft, wheelchairs and other mo-bility aids. Examples of equipment are lawnmowers, cleaning machines or model boats and model aircraft. Equipment pow-ered by lithium metal batteries or lithium ion batteries must be consigned under the entries ‘‘Lithium metal batteries con-tained in equipment’’ or ‘‘Lithium metal batteries packed with equipment’’ or ‘‘Lithium ion batteries contained in equip-ment’’ or ‘‘Lithium ion batteries packed with equipment’’ as appropriate. Self-pro-pelled vehicles or equipment that also con-tain an internal combustion engine must be consigned under the entries ‘‘Engine, in-ternal combustion, flammable gas pow-ered’’ or ‘‘Engine, internal combustion, flammable liquid powered’’ or ‘‘Vehicle, flammable gas powered’’ or ‘‘Vehicle, flam-mable liquid powered,’’ as appropriate. These entries include hybrid electric vehi-cles powered by both an internal combus-tion engine and batteries. Additionally, self-propelled vehicles or equipment that contain a fuel cell engine must be con-signed under the entries ‘‘Engine, fuel cell, flammable gas powered’’ or ‘‘Engine, fuel cell, flammable liquid powered’’ or ‘‘Vehi-cle, fuel cell, flammable gas powered’’ or ‘‘Vehicle, fuel cell, flammable liquid pow-ered,’’ as appropriate. These entries in-clude hybrid electric vehicles powered by a fuel cell engine, an internal combustion engine, and batteries.

135 Internal combustion engines installed in a vehicle must be consigned under the en-tries ‘‘Vehicle, flammable gas powered’’ or ‘‘Vehicle, flammable liquid powered,’’ as appropriate. These entries include hybrid electric vehicles powered by both an inter-nal combustion engine and wet, sodium or lithium batteries installed. If a fuel cell engine is installed in a vehicle, the vehicle must be consigned using the entries ‘‘Ve-hicle, fuel cell, flammable gas powered’’ or ‘‘Vehicle, fuel cell, flammable liquid pow-ered,’’ as appropriate. These entries in-clude hybrid electric vehicles powered by a fuel cell, an internal combustion engine, and wet, sodium or lithium batteries in-stalled.

136 This entry only applies to machinery and apparatus containing hazardous mate-rials as in integral element of the machin-

ery or apparatus. It may not be used to de-scribe machinery or apparatus for which a proper shipping name exists in the § 172.101 Table. Except when approved by the Asso-ciate Administrator, machinery or appa-ratus may only contain hazardous mate-rials for which exceptions are referenced in Column (8) of the § 172.101 Table and are provided in part 173, subpart D, of this sub-chapter. Hazardous materials shipped under this entry are excepted from the la-beling requirements of this subchapter un-less offered for transportation or trans-ported by aircraft and are not subject to the placarding requirements of part 172, subpart F, of this subchapter. Orientation markings as described in § 172.312 (a)(2) are required when liquid hazardous materials may escape due to incorrect orientation. The machinery or apparatus, if unpackaged, or the packaging in which it is contained shall be marked ‘‘Dangerous goods in machinery’’ or ‘‘Dangerous goods in apparatus’’, as appropriate, with the identification number UN3363. For trans-portation by aircraft, machinery or appa-ratus may not contain any material forbid-den for transportation by passenger or cargo aircraft. The Associate Adminis-trator may except from the requirements of this subchapter, equipment, machinery and apparatus provided: a. It is shown that it does not pose a sig-

nificant risk in transportation; b. The quantities of hazardous materials do

not exceed those specified in § 173.4a of this subchapter; and

c. The equipment, machinery or apparatus conforms with § 173.222 of this sub-chapter.

137 Cotton, dry; flax, dry; sisal, dry; and tampico fiber, dry are not subject to the requirements of this subchapter when they are baled in accordance with ISO 8115, ‘‘Cotton Bales—Dimensions and Density’’ (IBR, see § 171.7 of this subchapter) to a density of not less than 360 kg/m3 (22.1 lb/ ft3) for cotton, 400 kg/m3 (24.97 lb/ft3) for flax, 620 kg/m3 (38.71 lb/ft3) for sisal and 360 kg/m3 (22.1 lb/ft3) for tampico fiber and transported in a freight container or closed transport vehicle.

138 This entry applies to lead compounds which, when mixed in a ratio of 1:1,000 with 0.07 M (Molar concentration) hydrochloric acid and stirred for one hour at a tempera-ture of 23 °C ±2 °C, exhibit a solubility of more than 5%. Lead compounds which, when mixed in a ratio of 1:1,000 with 0.07 M (Molar concentration) hydrochloric acid and stirred for one hour at a temperature of 23 °C ±2 °C, exhibit a solubility of 5% or less are not subject to the requirements of this subchapter unless they meet criteria as another hazard class or division. Lead compounds that have a solubility of 5% or


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less in accordance with this special provi-sion are not subject to the requirements of this subchapter that pertain to Marine Pollutants.

139 Use of the ‘‘special arrangement’’ proper shipping names for international ship-ments must be made under an IAEA Cer-tificate of Competent Authority issued by the Associate Administrator in accordance with the requirements in § 173.471, § 173.472, or § 173.473 of this subchapter. Use of these proper shipping names for domestic ship-ments may be made only under a DOT spe-cial permit, as defined in, and in accord-ance with the requirements of subpart B of part 107 of this subchapter.

140 This material is regulated only when it meets the defining criteria for a hazardous substance or a marine pollutant. In addi-tion, the column 5 reference is modified to read ‘‘III’’ on those occasions when this material is offered for transportation or transported by highway or rail.

141 A toxin obtained from a plant, animal, or bacterial source containing an infec-tious substance, or a toxin contained in an infectious substance, must be classed as Division 6.2, described as an infectious sub-stance, and assigned to UN 2814 or UN 2900, as appropriate.

142 These hazardous materials may not be classified and transported unless author-ized by the Associate Administrator. The Associate Administrator will base the au-thorization on results from Series 2 tests and a Series 6(c) test from the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter) on packages as prepared for transport in accordance with the re-quirements of this subchapter.

144 If transported as a residue in an under-ground storage tank (UST), as defined in 40 CFR 280.12, that has been cleaned and purged or rendered inert according to the American Petroleum Institute (API) Standard 1604 (IBR, see § 171.7 of this sub-chapter), then the tank and this material are not subject to any other requirements of this subchapter. However, sediments re-maining in the tank that meet the defini-tion for a hazardous material are subject to the applicable regulations of this sub-chapter.

145 This entry applies to formulations that neither detonate in the cavitated state nor deflagrate in laboratory testing, show no effect when heated under confinement, ex-hibit no explosive power, and are ther-mally stable (self-accelerating decomposi-tion temperature (SADT) at 60 °C (140 °F) or higher for a 50 kg (110.2 lbs.) package). Formulations not meeting these criteria must be transported under the provisions applicable to the appropriate entry in the Organic Peroxide Table in § 173.225 of this subchapter.

146 This description may be used for a ma-terial that poses a hazard to the environ-ment but does not meet the definition for a hazardous waste or a hazardous sub-stance, as defined in § 171.8 of this sub-chapter, or any hazard class, as defined in part 173 of this subchapter, if it is des-ignated as environmentally hazardous by another Competent Authority. This provi-sion may be used for both domestic and international shipments.

147 This entry applies to non-sensitized emulsions, suspensions, and gels consisting primarily of a mixture of ammonium ni-trate and fuel, intended to produce a Type E blasting explosive only after further processing prior to use. The mixture for emulsions typically has the following com-position: 60–85% ammonium nitrate; 5–30% water; 2–8% fuel; 0.5–4% emulsifier or thickening agent; 0–10% soluble flame sup-pressants; and trace additives. Other inor-ganic nitrate salts may replace part of the ammonium nitrate. The mixture for sus-pensions and gels typically has the fol-lowing composition: 60–85% ammonium ni-trate; 0–5% sodium or potassium per-chlorate; 0–17% hexamine nitrate or monomethylamine nitrate; 5–30% water; 2– 15% fuel; 0.5–4% thickening agent; 0–10% soluble flame suppressants; and trace addi-tives. Other inorganic nitrate salts may re-place part of the ammonium nitrate. These substances must satisfactorily pass Test Series 8 of the UN Manual of Tests and Cri-teria, Part I, Section 18 (IBR, see § 171.7 of this subchapter), and may not be classified and transported unless approved by the As-sociate Administrator.

149 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in § 173.150(b)(2) of this subchapter for inner packagings may be increased to 5 L (1.3 gallons).

150 This description may be used only for uniform mixtures of fertilizers containing ammonium nitrate as the main ingredient within the following composition limits: a. Not less than 90% ammonium nitrate

with not more than 0.2% total combus-tible, organic material calculated as car-bon, and with added matter, if any, that is inorganic and inert when in contact with ammonium nitrate; or

b. Less than 90% but more than 70% ammo-nium nitrate with other inorganic mate-rials, or more than 80% but less than 90% ammonium nitrate mixed with calcium carbonate and/or dolomite and/or mineral calcium sulphate, and not more than 0.4% total combustible, organic material calculated as carbon; or

c. Ammonium nitrate-based fertilizers con-taining mixtures of ammonium nitrate and ammonium sulphate with more than


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45% but less than 70% ammonium ni-trate, and not more than 0.4% total com-bustible, organic material calculated as carbon such that the sum of the percent-age of compositions of ammonium ni-trate and ammonium sulphate exceeds 70%.

151 If this material meets the definition of a flammable liquid in § 173.120 of this sub-chapter, a FLAMMABLE LIQUID label is also required and the basic description on the shipping paper must indicate the Class 3 subsidiary hazard.

155 Fish meal, fish scrap and krill meal may not be transported if the temperature at the time of loading either exceeds 35 °C (95 °F), or exceeds 5 °C (41 °F) above the ambi-ent temperature, whichever is higher.

156 Asbestos that is immersed or fixed in a natural or artificial binder material, such as cement, plastic, asphalt, resins or min-eral ore, or contained in manufactured products is not subject to the requirements of this subchapter.

159 This material must be protected from direct sunshine and kept in a cool, well- ventilated place away from sources of heat.

160 This entry applies to articles that are used as life-saving vehicle air bag infla-tors, air bag modules or seat-belt pretensioners containing Class 1 (explo-sive) materials or materials of other haz-ard classes. Air bag inflators and modules must be tested in accordance with Test se-ries 6(c) of Part I of the UN Manual of Tests and Criteria (incorporated by ref-erence; see § 171.7 of this subchapter), with no explosion of the device, no fragmenta-tion of device casing or pressure vessel, and no projection hazard or thermal effect that would significantly hinder fire-fight-ing or other emergency response efforts in the immediate vicinity. If the air bag in-flator unit satisfactorily passes the series 6(c) test, it is not necessary to repeat the test on the air bag module.

161 For domestic transport, air bag infla-tors, air bag modules or seat-belt pretensioners that meet the criteria for a Division 1.4G explosive must be trans-ported using the description, ‘‘Articles, py-rotechnic for technical purposes,’’ UN0431. See § 173.166(d)(1) of this subchapter for an exception regarding air bag inflators, air bag modules, or seat-belt pretensioners that are installed in a motor vehicle, air-craft, boat or other transport conveyance or its completed components, such as steering columns or door panels.

162 This material may be transported under the provisions of Division 4.1 only if it is packed so that at no time during transport will the percentage of diluent fall below the percentage that is stated in the ship-ping description.

163 Substances must satisfactorily pass Test Series 8 of the UN Manual of Tests

and Criteria, Part I, Section 18 (IBR, see § 171.7 of this subchapter).

164 Substances must not be transported under this entry unless approved by the Associate Administrator on the basis of the results of appropriate tests according to Part I of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this sub-chapter). The material must be packaged so that the percentage of diluent does not fall below that stated in the approval at any time during transportation.

165 These substances are susceptible to exothermic decomposition at elevated tem-peratures. Decomposition can be initiated by heat, moisture or by impurities (e.g., powdered metals (iron, manganese, cobalt, magnesium)). During the course of trans-portation, these substances must be shaded from direct sunlight and all sources of heat and be placed in adequately ventilated areas.

166 When transported in non-friable tablet form, calcium hypochlorite, dry, may be transported as a Packing Group III mate-rial.

167 These storage systems must always be considered as containing hydrogen. A metal hydride storage system installed in or intended to be installed in a vehicle or equipment or in vehicle or equipment com-ponents must be approved for transport by the Associate Administrator. A copy of the approval must accompany each shipment.

168 For lighters containing a Division 2.1 gas (see § 171.8 of this subchapter), rep-resentative samples of each new lighter de-sign must be examined and successfully tested as specified in § 173.308(b)(3). For cri-teria in determining what is a new lighter design, see § 173.308(b)(1). For transpor-tation of new lighter design samples for ex-amination and testing, see § 173.308(b)(2). The examination and testing of each light-er design must be performed by a person authorized by the Associate Administrator under the provisions of subpart E of part 107 of this chapter, as specified in § 173.308(a)(4). For continued use of approv-als dated prior to January 1, 2012, see § 173.308(b)(5). For non-pressurized lighters containing a

Class 3 (flammable liquid) material, its design, description, and packaging must be approved by the Associate Adminis-trator prior to being offered for transpor-tation or transported in commerce. In addition, a lighter design intended to contain a non-pressurized Class 3 mate-rial is excepted from the examination and testing criteria specified in § 173.308(b)(3). An unused lighter or a lighter that is cleaned of residue and purged of vapors is not subject to the re-quirements of this subchapter.

169 This entry applies to lighter refills (see § 171.8 of this subchapter) that contain a


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Division 2.1 (flammable) gas but do not contain an ignition device. Lighter refills offered for transportation under this entry may not exceed 4 fluid ounces capacity (7.22 cubic inches) or contain more than 65 grams of fuel. A lighter refill exceeding 4 fluid ounces capacity (7.22 cubic inches) or containing more than 65 grams of fuel must be classed as a Division 2.1 material, described with the proper shipping name appropriate for the material, and packaged in the packaging specified in part 173 of this subchapter for the flammable gas con-tained therein. In addition, a container ex-ceeding 4 fluid ounces volumetric capacity (7.22 cubic inches) or containing more than 65 grams of fuel may not be connected or manifolded to a lighter or similar device and must also be described and packaged according to the fuel contained therein. For transportation by passenger-carrying aircraft, the net mass of lighter refills may not exceed 1 kg per package, and, for cargo-only aircraft, the net mass of lighter refills may not exceed 15 kg per package. See § 173.306(h) of this subchapter.

170 Air must be eliminated from the vapor space by nitrogen or other means.

171 This entry may only be used when the material is transported in non-friable tab-let form or for granular or powered mix-tures that have been shown to meet the PG III criteria in § 173.127.

172 This entry includes alcohol mixtures containing up to 5% petroleum products.

173 For adhesives, printing inks, printing ink-related materials, paints, paint-related materials, and resin solutions which are assigned to UN3082, and do not meet the definition of another hazard class, metal or plastic packaging for substances of pack-ing groups II and III in quantities of 5 L (1.3 gallons) or less per packaging are not required to meet the UN performance package testing when transported: a. Except for transportation by aircraft, in

palletized loads, a pallet box or unit load device (e.g. individual packaging placed or stacked and secured by strapping, shrink or stretch-wrapping or other suit-able means to a pallet). For vessel trans-port, the palletized loads, pallet boxes or unit load devices must be firmly packed and secured in closed cargo transport units; or

b. Except for transportation by aircraft, as an inner packaging of a combination packaging with a maximum net mass of 40 kg (88 pounds). For transportation by aircraft, as an inner packaging of a com-bination packaging with a maximum gross mass of 30 kg when packaged as a limited quantity in accordance with § 173.27(f).

175 This substance must be stabilized when in concentrations of not more than 99%.

176 This entry must be used for formalde-hyde solutions containing methanol as a stabilizer. Formaldehyde solutions not containing methanol and not meeting the Class 3 flammable liquid criteria must be described using a different proper shipping name.

177 Gasoline, or, ethanol and gasoline mix-tures, for use in internal combustion en-gines (e.g., in automobiles, stationary en-gines and other engines) must be assigned to Packing Group II regardless of vari-ations in volatility.

198 Nitrocellulose solutions containing not more than 20% nitrocellulose may be transported as paint, perfumery products, or printing ink, as applicable, provided the nitrocellulose contains no more 12.6% ni-trogen (by dry mass). See UN1210, UN1263, UN1266, UN3066, UN3469, and UN3470.

200 Division 1.4G consumer fireworks may be certified for transportation by a DOT- approved Fireworks Certification Agency in accordance with the provisions of § 173.65 of this subchapter.

222 Shipments offered for transportation by aircraft may not be reclassed as ORM–D.

237 ‘‘Batteries, dry, containing potassium hydroxide solid, electric storage’’ must be prepared and packaged in accordance with the requirements of § 173.159(a) and (c). For transportation by aircraft, the provisions of § 173.159(b)(2) apply. This entry may only be used for the transport of non-activated batteries that contain dry potassium hy-droxide and that are intended to be acti-vated prior to use by the addition of an ap-propriate amount of water to the indi-vidual cells.

238 Neutron radiation detectors: a. Neutron radiation detectors containing

non-pressurized boron trifluoride gas in excess of 1 gram and radiation detection systems containing such neutron radi-ation detectors as components may be transported by highway, rail, vessel, or cargo aircraft in accordance with the fol-lowing:

(1) The pressure in each neutron radiation detector must not exceed 105 kPa abso-lute at 20 °C;

(2) The amount of gas must not exceed 12.8 grams per detector and the amount per outer packaging or per radiation detec-tion system must not exceed 51.2 grams;

(3) Each neutron radiation detector must be of welded metal construction with brazed metal to ceramic feed through as-semblies. They must have a minimum burst pressure of 1800 kPa; and

(4) Each neutron radiation detector must be packed in a sealed intermediate plas-tic liner with sufficient absorbent mate-rial to absorb the entire gas contents. Neutron radiation detectors must be packed in strong outer packagings that are capable of withstanding a 1.8 meter


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(6-foot) drop without leakage. Radiation detection systems containing neutron ra-diation detectors must also include ab-sorbent material sufficient to absorb the entire gas contents of the neutron radi-ation detectors. Absorbent material must be surrounded by a liner or liners, as appropriate. They must be packed in strong outer packagings unless neutron radiation detectors are afforded equiva-lent protection by the radiation detec-tion system.

b. Except for transportation by aircraft, neutron radiation detectors and radi-ation detection systems containing such detectors transported in accordance with paragraph (a) of this special provision are not subject to the labeling and placarding requirements of part 172 of this subchapter.

c. When transported by highway, rail, ves-sel, or as cargo on an aircraft, neutron radiation detectors containing not more than 1 gram of boron trifluoride, includ-ing those with solder glass joints, and ra-diation detection systems containing such detectors, where the neutron radi-ation detectors meet and are packed in accordance with the requirements of paragraph (a) of this special provision, are not subject to any other require-ments of this subchapter.

328 When lithium metal or lithium ion bat-teries are contained in the fuel cell system, the item must be described under this entry and the appropriate entries for ‘‘Lithium metal batteries contained in equipment’’ or ‘‘Lithium ion batteries con-tained in equipment’’.

332 Magnesium nitrate hexahydrate is not subject to the requirements of this sub-chapter.

335 Mixtures of solids that are not subject to this subchapter and environmentally hazardous liquids or solids may be classi-fied as ‘‘Environmentally hazardous sub-stances, solid, n.o.s,’’ UN3077 and may be transported under this entry, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Each transport unit must be leakproof when used as bulk packaging.

336 The use of UN1H1 drums, UN3H1 jerricans, and UN6HA1 composite pack-agings which meet the requirements of part 178 of the HMR at the Packing Group I or II performance level. These packagings are not required to: (1.) meet the venting requirements in § 173.24(g) or (2.) be marked with the hydrostatic pressure test marking specified in § 173.24a(b)(4). Shipment of packages under this special provision must be made by private or contract motor car-rier. Transportation of these packages also requires the door of each van trailer to be marked with ‘‘Warning trailer may contain

chemical vapor. Do not enter until vapors have dissipated.’’ The driver of the trans-port vehicle and the consignee(s) must be trained not to enter the transport vehicle until the ammonia vapors have dissipated, and the emergency response information on the shipping paper must indicate that the vehicle contains ammonia vapors. This training must be documented in training records required by § 172.704(d). Transport vehicles must be vented to prevent accu-mulation of vapors at a poisonous or flam-mable concentration.

337 Authorizes the use of regulated waste containers manufactured prior to October 1, 2006 to be marked with the alternative shipping name of Regulated medical waste, UN3291 and arrows that deviate as pre-scribed in § 172.312(a)(2) in that they may be black or white.

338 Life Saving appliances, self-inflating transported between an U.S. Coast Guard approved inflatable life raft servicing facil-ity and a vessel are only subject to the fol-lowing requirements: a. Prior to repacking into the life-saving

appliance, an installed inflation cylinder must successfully meet and pass all in-spection and test criteria and standards of the raft manufacturer and the vessel Flag State requirements for cylinders in-stalled as part of life-saving appliances, self-inflating (UN2990) used on marine vessels. Additionally, each cylinder must be visually inspected in accordance with CGA pamphlet, CGA C–6 (incorporated by reference, see § 171.7). A current copy of CGA pamphlet, CGA C–6 must be avail-able at the facility servicing the life-sav-ing appliance.

b. An installed inflation cylinder that re-quires recharging must be filled in ac-cordance with § 173.301(l).

c. Every installed inflation cylinder, as as-sociated equipment of the life-saving ap-pliance, must be packed within the pro-tective packaging of the life raft and the life raft itself must otherwise be in com-pliance with § 173.219.

d. The serial number for each cylinder must be recorded as part of the life-sav-ing appliance service record by the U.S. Coast Guard-approved servicing facility.

340 This entry applies only to the vessel transportation of nickel-metal hydride batteries as cargo. Nickel-metal hydride button cells or nickel-metal hydride cells or batteries packed with or contained in battery-powered devices transported by vessel are not subject to the requirements of this special provision. See ‘‘Batteries, dry, sealed, n.o.s.’’ in the § 172.101 Haz-ardous Materials Table (HMT) of this part for transportation requirements for nickel- metal hydride batteries transported by other modes and for nickel-metal hydride button cells or nickel-metal hydride cells


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49 CFR Ch. I (10–1–14 Edition) § 172.102

or batteries packed with or contained in battery-powered devices transported by vessel. Nickel-metal hydride batteries sub-ject to this special provision are subject only to the following requirements: (1) The batteries must be prepared and packaged for transport in a manner to prevent a dan-gerous evolution of heat, short circuits, and damage to terminals; and are subject to the incident reporting in accordance with § 171.16 of this subchapter if a fire, vio-lent rupture, explosion or dangerous evo-lution of heat (i.e., an amount of heat suffi-cient to be dangerous to packaging or per-sonal safety to include charring of pack-aging, melting of packaging, scorching of packaging, or other evidence) occurs as a direct result of a nickel metal hydride bat-tery; and (2) when loaded in a cargo trans-port unit in a total quantity of 100 kg gross mass or more, the shipping paper require-ments of Subpart C of this part, the mani-fest requirements of § 176.30 of this sub-chapter, and the vessel stowage require-ments assigned to this entry in Column (10) of the § 172.101 Hazardous Materials Table.

342 Glass inner packagings (such as am-poules or capsules) intended only for use in sterilization devices, when containing less than 30 mL of ethylene oxide per inner packaging with not more than 300 mL per outer packaging, may be transported in ac-cordance with § 173.4a of this subchapter, irrespective of the restriction of § 173.4a(b) provided that: a. After filling, each glass inner packaging

must be determined to be leak-tight by placing the glass inner packaging in a hot water bath at a temperature and for a period of time sufficient to ensure that an internal pressure equal to the vapor pressure of ethylene oxide at 55 °C is achieved. Any glass inner packaging showing evidence of leakage, distortion or other defect under this test must not be transported under the terms of this special provision;

b. In addition to the packaging required in § 173.4a, each glass inner packaging must be placed in a sealed plastic bag compat-ible with ethylene oxide and capable of containing the contents in the event of breakage or leakage of the glass inner packaging; and

c. Each glass inner packaging is protected by a means of preventing puncture of the plastic bag (e.g., sleeves or cushioning) in the event of damage to the packaging (e.g., by crushing).

343 A bulk packaging that emits hydrogen sulfide in sufficient concentration that va-pors evolved from the crude oil can present an inhalation hazard must be marked as specified in § 172.327of this part.

345 ‘‘Nitrogen, refrigerated liquid (cryogenic liquid), UN1977’’ transported in open cryo-

genic receptacles with a maximum capac-ity of 1 L are not subject to the require-ments of this subchapter. The receptacles must be constructed with glass double walls having the space between the walls vacuum insulated and each receptacle must be transported in an outer packaging with sufficient cushioning and absorbent materials to protect the receptacle from damage.

346 ‘‘Nitrogen, refrigerated liquid (cryogenic liquid), UN1977’’ transported in accordance with the requirements for open cryogenic receptacles in § 173.320 and this special pro-vision are not subject to any other require-ments of this subchapter. The receptacle must contain no hazardous materials other than the liquid nitrogen which must be fully absorbed in a porous material in the receptacle.

347 Effective July 1, 2011, for transportation by aircraft, this entry may only be used if the results of Test series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter) have dem-onstrated that any hazardous effects from accidental functioning are confined to within the package. Effective January 1, 2012, for transportation by vessel, this entry may only be used if the results of Test Series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental func-tioning are confined to within the package. Effective January 1, 2014, for transpor-tation domestically by highway or rail, this entry may only be used if the results of Test Series 6(d) of Part I of the UN Man-ual of Tests and Criteria (IBR, see § 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. Testing must be performed or witnessed by a person who is approved by the Associate Administrator (see § 173.56(b) of this subchapter). All successfully con-ducted tests or reassignment to another compatibility group require the issuance of a new or revised approval by the Associate Administrator prior to transportation on or after the dates specified for each author-ized mode of transport in this special pro-vision.

349 Mixtures of hypochlorite with an ammo-nium salt are forbidden for transport. A hypochlorite solution, UN1791, is a Class 8 corrosive material.

350 Ammonium bromate, ammonium bro-mate aqueous solutions, and mixtures of a bromate with an ammonium salt are for-bidden for transport.

351 Ammonium chlorate, ammonium chlo-rate aqueous solutions, and mixtures of a chlorate with an ammonium salt are for-bidden for transport.


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352 Ammonium chlorite, ammonium chlo-rite aqueous solutions, and mixtures of a chlorite with an ammonium salt are for-bidden for transport.

353 Ammonium permanganate, ammonium permanganate aqueous solutions, and mix-tures of a permanganate with an ammo-nium salt are forbidden for transport.

357 A bulk packaging that emits hydrogen sulfide in sufficient concentration that va-pors evolved from the crude oil can present an inhalation hazard must be marked as specified in § 172.327 of this part.

360 Vehicles only powered by lithium bat-teries must be assigned the identification number UN3171.

361 Capacitors with an energy storage ca-pacity of 0.3 Wh or less are not subject to the requirements of this subchapter. En-ergy storage capacity means the energy held by a capacitor, as calculated using the nominal voltage and capacitance. This entry does not apply to capacitors that by design maintain a terminal voltage (e.g., asymmetrical capacitors.)

362 This entry applies to liquids, pastes or powders, pressurized with a propellant that meets the definition of a gas in § 173.115. A chemical under pressure packaged in an aerosol dispenser must be transported under UN1950. The chemical under pressure must be classed based on the hazard char-acteristics of the components in the pro-pellant; the liquid; or the solid. The fol-lowing provisions also apply: (a) If one of the components, which can be

a pure substance or a mixture, is classed as flammable, the chemical under pres-sure must be classed as flammable in Di-vision 2.1. Flammable components are flammable liquids and liquid mixtures, flammable solids and solid mixtures or flammable gases and gas mixtures meet-ing the following criteria:

(i) A flammable liquid is a liquid having a flashpoint of not more than 93 °C (200 °F);

(ii) A flammable solid is a solid that meets the criteria in § 173.124 of this subchapter; or

(iii) A flammable gas is a gas that meets the criteria in § 173.115 of this subchapter.

(b) Gases of Division 2.3 and gases with a subsidiary risk of 5.1 must not be used as a propellant in a chemical under pres-sure.

(c) Where the liquid or solid components are classed as Division 6.1, packing groups II or III, or Class 8, packing groups II or III, the chemical under pres-sure must be assigned a subsidiary risk of Division 6.1 or Class 8 and the appro-priate identification number must be as-signed. Components classed as Division 6.1, packing group I, or Class 8, packing group I, must not be offered for transpor-tation and transported under this de-scription.

(d) A chemical under pressure with compo-nents meeting the properties of : Class 1 (explosives); Class 3 (liquid desensitized explosives); Division 4.1 (self-reactive substances and solid desensitized explo-sives); Division 4.2 (substances liable to spontaneous combustion); Division 4.3 (substances which, in contact with water, emit flammable gases or toxic gases); Division 5.1 (oxidizing sub-stances); Division 5.2 (organic peroxides); Division 6.2 (Infectious substances); or, Class 7 (Radioactive material), must not be offered for transportation under this description.

(e) A description to which Special provi-sion 170 or TP7 is assigned in Column 7 of the § 172.101 Hazardous Materials Table, and therefore requires air to be elimi-nated from the package vapor space by nitrogen or other means, must not be of-fered for transportation under this de-scription.

365 For manufactured instruments and arti-cles containing mercury, see UN3506.

(2) ‘‘A’’ codes. These provisions apply only to transportation by aircraft:


A1 Single packagings are not permitted on passenger aircraft.

A2 Single packagings are not permitted on aircraft.

A3 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with absorbent material in tightly closed metal recep-tacles before packing in outer packagings.

A4 Liquids having an inhalation toxicity of Packing Group I are not permitted on air-craft.

A5 Solids having an inhalation toxicity of Packing Group I are not permitted on pas-senger aircraft and may not exceed a max-imum net quantity per package of 15 kg (33 pounds) on cargo aircraft.

A6 For combination packagings, if plastic inner packagings are used, they must be packed in tightly closed metal receptacles before packing in outer packagings.

A7 Steel packagings must be corrosion-re-sistant or have protection against corro-sion.

A8 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with cushioning material in tightly closed metal recep-tacles before packing in outer packagings.

A9 For combination packagings, if plastic bags are used, they must be packed in tightly closed metal receptacles before packing in outer packagings.

A10 When aluminum or aluminum alloy construction materials are used, they must be resistant to corrosion.


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49 CFR Ch. I (10–1–14 Edition) § 172.102

A11 For combination packagings, when metal inner packagings are permitted, only specification cylinders constructed of metals which are compatible with the haz-ardous material may be used.

A13 Bulk packagings are not authorized for transportation by aircraft.

A14 This material is not authorized to be transported as a limited quantity or con-sumer commodity in accordance with § 173.306 of this subchapter when trans-ported aboard an aircraft.

A19 Combination packagings consisting of outer fiber drums or plywood drums, with inner plastic packagings, are not author-ized for transportation by aircraft.

A20 Plastic bags as inner receptacles of combination packagings are not authorized for transportation by aircraft.

A29 Combination packagings consisting of outer expanded plastic boxes with inner plastic bags are not authorized for trans-portation by aircraft.

A30 Ammonium permanganate is not au-thorized for transportation on aircraft.

A34 Aerosols containing a corrosive liquid in Packing Group II charged with a gas are not permitted for transportation by air-craft.

A35 This includes any material which is not covered by any of the other classes but which has an anesthetic, narcotic, noxious or other similar properties such that, in the event of spillage or leakage on an air-craft, extreme annoyance or discomfort could be caused to crew members so as to prevent the correct performance of as-signed duties.

A37 This entry applies only to a material meeting the definition in § 171.8 of this sub-chapter for self-defense spray.

A51 Irrespective of the quantity limitations specified in Column (9A) of the § 172.101 Table or § 175.75(c), the following aircraft batteries may be transported on passenger aircraft as cargo: a. Wet cell batteries, UN 2794 or UN 2795,

up to a limit of 100kg net mass per pack-age;

b. Lithium ion batteries, UN 3480, packages containing a single aircraft battery with a net mass not exceeding 35kg; and

c. Transport in accordance with this spe-cial provision must be noted on the ship-ping paper.

A53 Refrigerating machines and refrig-erating machine components are not sub-ject to the requirements of this subchapter when containing less than 12 kg (26.4 pounds) of a non-flammable gas or when containing 12 L (3 gallons) or less of ammo-nia solution (UN2672) (see § 173.307 of this subchapter).

A54 Irrespective of the quantity limits in Column 9B of the § 172.101 table, a lithium battery, including a lithium battery packed with, or contained in, equipment

that otherwise meets the applicable re-quirements of § 173.185, may have a mass exceeding 35 kg if approved by the Asso-ciate Administrator prior to shipment.

A56 Radioactive material with a subsidiary hazard of Division 4.2, Packing Group I, must be transported in Type B packages when offered for transportation by air-craft. Radioactive material with a sub-sidiary hazard of Division 2.1 is forbidden from transport on passenger aircraft.

A60 Sterilization devices, when containing less than 30 mL per inner packaging with not more than 150 mL per outer packaging, may be transported in accordance with the provisions in § 173.4a, irrespective of § 173.4a(b), provided such packagings were first subjected to comparative fire testing. Comparative fire testing between a pack-age as prepared for transport (including the substance to be transported) and an identical package filled with water must show that the maximum temperature measured inside the packages during test-ing does not differ by more than 200 °C (392 °F). Packagings may include a vent to per-mit the slow escape of gas (i.e. not more than 0.1 mL/hour per 30 mL inner pack-aging at 20 °C (68 °F) produced from grad-ual decomposition.

A82 The quantity limits in columns (9A) and (9B) do not apply to human or animal body parts, whole organs or whole bodies known to contain or suspected of con-taining an infectious substance.

A101 In addition to the applicable require-ments of § 173.185, the quantity of lithium metal in the batteries contained in any piece of equipment must not exceed 12 g per cell and 500 g per battery.

A105 The total net quantity of dangerous goods contained in one package, excluding magnetic material, must not exceed the following: a. 1 kg (2.2 pounds) in the case of solids; b. 0.5 L (0.1 gallons) in the case of liquids; c. 0.5 kg (1.1 pounds) in the case of Division

2.2 gases; or d. any combination thereof.

A112 Notwithstanding the quantity limits shown in Column (9A) and (9B) for this entry, the following IBCs are authorized for transportation aboard passenger and cargo-only aircraft. Each IBC may not ex-ceed a maximum net quantity of 1,000 kg: a. Metal: 11A, 11B, 11N, 21A, 21B and 21N b. Rigid plastics: 11H1, 11H2, 21H1 and 21H2 c. Composite with plastic inner receptacle:

11HZ1, 11HZ2, 21HZ1 and 21HZ2 d. Fiberboard: 11G e. Wooden: 11C, 11D and 11F (with inner lin-

ers) f. Flexible: 13H2, 13H3, 13H4, 13H5, 13L2,

13L3, 13L4, 13M1 and 13M2 (flexible IBCs must be sift-proof and water resistant or must be fitted with a sift-proof and water resistant liner).


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A189 Except where the defining criteria of another class or division are met, con-centrations of formaldehyde solution: a. With less than 25 percent but not less

than 10 percent formaldehyde, must be described as UN3334, Aviation regulated liquid, n.o.s.; and

b. With less than 10 percent formaldehyde, are not subject to this subchapter.

A191 Notwithstanding the Division 6.1 sub-sidiary risk for this description, the toxic subsidiary risk label and the requirement to indicate the subsidiary risk on the ship-ping paper are not required for manufac-tured articles containing less than 5 kg (11 pounds) of mercury.

A200 These articles must be transported as cargo and may not be carried aboard an aircraft by passengers or crewmembers in carry-on baggage, checked baggage, or on their person unless specifically authorized in § 175.10.

(3) ‘‘B’’ codes. These provisions apply only to bulk packagings. Except as otherwise provided in this subchapter, these special provisions do not apply to UN portable tanks or IBCs:


B1 If the material has a flash point at or above 38 °C (100 °F) and below 93 °C (200 °F), then the bulk packaging requirements of § 173.241 of this subchapter are applicable. If the material has a flash point of less than 38 °C (100 °F), then the bulk packaging requirements of § 173.242 of this subchapter are applicable.

B2 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized.

B3 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and DOT 57 portable tanks are not authorized.

B4 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized.

B5 Only ammonium nitrate solutions with 35 percent or less water that will remain completely in solution under all conditions of transport at a maximum lading tem-perature of 116 °C (240 °F) are authorized for transport in the following bulk pack-agings: MC 307, MC 312, DOT 407 and DOT 412 cargo tanks with at least 172 kPa (25 psig) design pressure. The packaging shall be designed for a working temperature of at least 121 °C (250 °F). Only Specifications MC 304, MC 307 or DOT 407 cargo tank motor vehicles are authorized for transpor-tation by vessel.

B6 Packagings shall be made of steel. B7 Safety relief devices are not authorized

on multi-unit tank car tanks. Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged.

B8 Packagings shall be made of nickel, stainless steel, or steel with nickel, stain-less steel, lead or other suitable corrosion resistant metallic lining.

B9 Bottom outlets are not authorized. B10 MC 300, MC 301, MC 302, MC 303, MC 305,

and MC 306 and DOT 406 cargo tanks, and DOT 57 portable tanks are not authorized.

B11 Tank car tanks must have a test pres-sure of at least 2,068.5 kPa (300 psig). Cargo and portable tanks must have a design pressure of at least 1,207 kPa (175 psig).

B13 A nonspecification cargo tank motor vehicle authorized in § 173.247 of this sub-chapter must be at least equivalent in de-sign and in construction to a DOT 406 cargo tank or MC 306 cargo tank (if con-structed before August 31, 1995), except as follows: a. Packagings equivalent to MC 306 cargo

tanks are excepted from the certifi-cation, venting, and emergency flow re-quirements of the MC 306 specification.

b. Packagings equivalent to DOT 406 cargo tanks are excepted from §§ 178.345–7(d)(5), circumferential reinforcements; 178.345– 10, pressure relief; 178.345–11, outlets; 178.345–14, marking, and 178.345–15, cer-tification.

c. Packagings are excepted from the design stress limits at elevated temperatures, as described in Section VIII of the ASME Code (IBR, see § 171.7 of this subchapter). However, the design stress limits may not exceed 25 percent of the stress for 0 temper at the maximum design tempera-ture of the cargo tank, as specified in the Aluminum Association’s ‘‘Aluminum Standards and Data’’ (IBR, see § 171.7 of this subchapter).

B14 Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be in-sulated with an insulating material so that the overall thermal conductance at 15.5 °C (60 °F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per de-gree Fahrenheit) temperature differential. Insulating materials must not promote corrosion to steel when wet.

B15 Packagings must be protected with non-metallic linings impervious to the lad-ing or have a suitable corrosion allowance.

B16 The lading must be completely covered with nitrogen, inert gas or other inert ma-terials.

B18 Open steel hoppers or bins are author-ized.

B23 Tanks must be made of steel that is rubber lined or unlined. Unlined tanks must be passivated before being placed in service. If unlined tanks are washed out with water, they must be repassivated prior to return to service. Lading in un-lined tanks must be inhibited so that the corrosive effect on steel is not greater than


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that of hydrofluoric acid of 65 percent con-centration.

B25 Packagings must be made from monel or nickel or monel-lined or nickel-lined steel.

B26 Tanks must be insulated. Insulation must be at least 100 mm (3.9 inches) except that the insulation thickness may be re-duced to 51 mm (2 inches) over the exterior heater coils. Interior heating coils are not authorized. The packaging may not be loaded with a material outside of the pack-aging’s design temperature range. In addi-tion, the material also must be covered with an inert gas or the container must be filled with water to the tank’s capacity. After unloading, the residual material also must be covered with an inert gas or the container must be filled with water to the tank’s capacity.

B27 Tanks must have a service pressure of 1,034 kPa (150 psig). Tank car tanks must have a test pressure rating of 1,379 kPa (200 psig). Lading must be blanketed at all times with a dry inert gas at a pressure not to exceed 103 kPa (15 psig).

B28 Packagings must be made of stainless steel.

B30 MC 312, MC 330, MC 331 and DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of § 173.24b(b) of this subchapter. Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 7.62 mm (0.300 inch) or the thickness required for a tank with a design pressure at least equal to 1.5 times the vapor pressure of the lading at 46 °C (115 °F). In addition, MC 312 and DOT 412 cargo tank motor vehicles must: a. Be ASME Code (U) stamped for 100% ra-

diography of all pressure-retaining welds; b. Have accident damage protection which

conforms with § 178.345–8 of this sub-chapter;

c. Have a MAWP or design pressure of at least 87 psig: and

d. Have a bolted manway cover. B32 MC 312, MC 330, MC 331, DOT 412 cargo

tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of § 173.24b(b) of this subchapter. Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 6.35 mm (0.250 inch) or the thickness required for a tank with a design pressure at least equal to 1.3 times the vapor pressure of the lading at 46 °C (115 °F). In addition, MC 312 and DOT 412 cargo tank motor vehicles must:

a. Be ASME Code (U) stamped for 100% radi-ography of all pressure-retaining welds;

b. Have accident damage protection which conforms with § 178.345–8 of this sub-chapter;

c. Have a MAWP or design pressure of at least 87 psig; and

d. Have a bolted manway cover. B33 MC 300, MC 301, MC 302, MC 303, MC 305,

MC 306, and DOT 406 cargo tanks equipped with a 1 psig normal vent used to transport gasoline must conform to Table I of this Special Provision. Based on the volatility class determined by using ASTM D 439 and the Reid vapor pressure (RVP) of the par-ticular gasoline, the maximum lading pres-sure and maximum ambient temperature permitted during the loading of gasoline may not exceed that listed in Table I.

TABLE I—MAXIMUM AMBIENT TEMPERATURE— GASOLINE

ASTM D439 volatility class Maximum lading and ambient temperature

(see note 1)

A ........................................................ 131 °F (RVP<=9.0 psia) B ........................................................ 124 °F (RVP<=10.0 psia) C ........................................................ 116 °F (RVP<=11.5 psia) D ........................................................ 107 °F (RVP<=13.5 psia) E ........................................................ 100 °F (RVP<=15.0 psia)

NOTE 1: Based on maximum lading pressure of 1 psig at top of cargo tank.

B35 Tank cars containing hydrogen cyanide may be alternatively marked ‘‘Hydrocyanic acid, liquefied’’ if otherwise conforming to marking requirements in subpart D of this part. Tank cars marked ‘‘HYDROCYANIC ACID’’ prior to October 1, 1991 do not need to be remarked.

B42 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105J. Each tank car must have a reclosing pressure relief device having a start-to-dis-charge pressure of 10.34 Bar (150 psig). The tank car specification may be marked to indicate a test pressure of 13.79 Bar (200 psig).

B44 All parts of valves and safety relief de-vices in contact with lading must be of a material which will not cause formation of acetylides.

B45 Each tank must have a reclosing com-bination pressure relief device equipped with stainless steel or platinum rupture discs approved by the AAR Tank Car Com-mittee.

B46 The detachable protective housing for the loading and unloading valves of multi- unit tank car tanks must withstand tank test pressure and must be approved by the Associate Administrator.


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B47 Each tank may have a reclosing pres-sure relief device having a start-to-dis-charge pressure setting of 310 kPa (45 psig).

B48 Portable tanks in sodium metal service may be visually inspected at least once every 5 years instead of being retested hydrostatically. Date of the visual inspec-tion must be stenciled on the tank near the other required markings.

B49 Tanks equipped with interior heater coils are not authorized. Single unit tank car tanks must have a reclosing pressure relief device having a start-to-discharge pressure set at no more than 1551 kPa (225 psig).

B52 Notwithstanding the provisions of § 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks.

B53 Packagings must be made of either alu-minum or steel.

B54 Open-top, sift-proof rail cars are also authorized.

B55 Water-tight, sift-proof, closed-top, metal-covered hopper cars, equipped with a venting arrangement (including flame ar-restors) approved by the Associate Admin-istrator are also authorized.

B56 Water-tight, sift-proof, closed-top, metal-covered hopper cars are also author-ized if the particle size of the hazardous material is not less than 149 microns.

B57 Class 115A tank car tanks used to trans-port chloroprene must be equipped with a non-reclosing pressure relief device of a di-ameter not less than 305 mm (12 inches) with a maximum rupture disc pressure of 310 kPa (45 psig).

B59 Water-tight, sift-proof, closed-top, metal-covered hopper cars are also author-ized provided that the lading is covered with a nitrogen blanket.

B61 Written procedures covering details of tank car appurtenances, dome fittings, safety devices, and marking, loading, han-dling, inspection, and testing practices must be approved by the Associate Admin-istrator before any single unit tank car tank is offered for transportation.

B65 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105A. Each tank car must have a reclosing pressure relief device having a start-to-dis-charge pressure of 15.51 Bar (225 psig). The tank car specification may be marked to indicate a test pressure of 20.68 Bar (300 psig).

B66 Each tank must be equipped with gas tight valve protection caps. Outage must be sufficient to prevent tanks from becom-ing liquid full at 55 °C (130 °F). Specifica-tion 110A500W tanks must be stainless steel.

B67 All valves and fittings must be pro-tected by a securely attached cover made of metal not subject to deterioration by

the lading, and all valve openings, except safety valve, must be fitted with screw plugs or caps to prevent leakage in the event of valve failure.

B68 Sodium must be in a molten condition when loaded and allowed to solidify before shipment. Outage must be at least 5 per-cent at 98 °C (208 °F). Bulk packagings must have exterior heating coils fusion welded to the tank shell which have been properly stress relieved. The only tank car tanks authorized are Class DOT 105 tank cars having a test pressure of 2,069 kPa (300 psig) or greater.

B69 Dry sodium cyanide or potassium cya-nide may be shipped in the following sift- proof and weather-resistant packagings: metal covered hopper cars, covered motor vehicles, portable tanks, or non-specifica-tion bins.

B70 If DOT 103ANW tank car tank is used: All cast metal in contact with the lading must have 96.7 percent nickel content; and the lading must be anhydrous and free from any impurities.

B76 Tank cars constructed before March 16, 2009, must have a test pressure of 20.68 Bar (300 psig) or greater and conform to Class 105S, 112J, 114J or 120S. Each tank car must have a reclosing pressure relief de-vice having a start-to-discharge pressure of 10.34 Bar (150 psig). The tank car specifica-tion may be marked to indicate a test pres-sure of 13.79 Bar (200 psig).

B77 Other packaging are authorized when approved by the Associate Administrator.

B78 Tank cars must have a test pressure of 4.14 Bar (60 psig) or greater and conform to Class 103, 104, 105, 109, 111, 112, 114 or 120. Heater pipes must be of welded construc-tion designed for a test pressure of 500 psig. A 25 mm (1 inch) woven lining of asbestos or other approved material must be placed between the bolster slabbing and the bot-tom of the tank. If a tank car tank is equipped with a non-reclosing pressure re-lief device, the rupture disc must be per-forated with a 3.2 mm (0.13 inch) diameter hole. If a tank car tank is equipped with a reclosing pressure relief valve, the tank must also be equipped with a vacuum relief valve.

B80 Each cargo tank must have a minimum design pressure of 276 kPa (40 psig).

B81 Venting and pressure relief devices for tank car tanks and cargo tanks must be approved by the Associate Administrator.

B82 Cargo tanks and portable tanks are not authorized.

B83 Bottom outlets are prohibited on tank car tanks transporting sulfuric acid in con-centrations over 65.25 percent.

B84 Packagings must be protected with non-metallic linings impervious to the lad-ing or have a suitable corrosion allowance for sulfuric acid or spent sulfuric acid in concentration up to 65.25 percent.


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49 CFR Ch. I (10–1–14 Edition) § 172.102

B85 Cargo tanks must be marked with the name of the lading in accordance with the requirements of § 172.302(b).

B90 Steel tanks conforming or equivalent to ASME specifications which contain solid or semisolid residual motor fuel anti-knock mixture (including rust, scale, or other contaminants) may be shipped by rail freight or highway. The tank must have been designed and constructed to be capable of withstanding full vacuum. All openings must be closed with gasketed blank flanges or vapor tight threaded clo-sures.

B115 Rail cars, highway trailers, roll-on/ roll-off bins, or other non-specification bulk packagings are authorized. Pack-agings must be sift-proof, prevent liquid water from reaching the hazardous mate-rial, and be provided with sufficient vent-ing to preclude dangerous accumulation of flammable, corrosive, or toxic gaseous emissions such as methane, hydrogen, and ammonia. The material must be loaded dry.

B116 The use of non specification, sift-proof dump or hopper type vehicles, and sift- proof roll-on/roll-off bulk bins, which must be covered by a tarpaulin, metal cover, or equivalent means is authorized for the transportation of spent bleaching earth by motor vehicle. The material is also be sub-ject to operational controls which include not exceeding a temperature of 55C (130F) at the time it is offered or during transpor-tation, not exceeding a transportation time of 24 hours, and drivers transporting spent bleaching earth must be trained in the properties and hazards of the spent bleaching earth. This training must be doc-umented in training records required by § 172.704(d).

B120 The use of flexible bulk containers conforming to the requirements in subpart R and subpart S of part 178 of this sub-chapter is permitted.

(4) IB Codes and IP Codes. These pro-visions apply only to transportation in IBCs and Large Packagings. Table 1 au-thorizes IBCs for specific proper ship-ping names through the use of IB Codes assigned in the § 172.101 table of this subchapter. Table 2 defines IP Codes on the use of IBCs that are assigned to specific commodities in the § 172.101 Table of this subchapter. Table 3 au-thorizes Large Packagings for specific proper shipping names through the use of IB Codes assigned in the § 172.101 table of this subchapter. Large Pack-agings are authorized for the Packing Group III entries of specific proper shipping names when either Special Provision IB3 or IB8 is assigned to that entry in the § 172.101 Table. When no IB code is assigned in the § 172.101 Table for a specific proper shipping name, or in § 173.225(e) Organic Peroxide Table for Type F organic peroxides, use of an IBC or Large Packaging for the mate-rial may be authorized when approved by the Associate Administrator. The letter ‘‘Z’’ shown in the marking code for composite IBCs must be replaced with a capital code letter designation found in § 178.702(a)(2) of this sub-chapter to specify the material used for the other packaging. Tables 1, 2, and 3 follow:

TABLE 1—IB CODES (IBC CODES)

IBC code Authorized IBCs

IB1 ....................... Authorized IBCs: Metal (31A, 31B and 31N). ......................... Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar

at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized. IB2 ....................... Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).

......................... Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized.

IB3 ....................... Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2).

......................... Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized, except for UN2672 (also see Special provision IP8 in Table 2 for UN2672).

IB4 ....................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B and 21N). IB5 ....................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B and 21N); Rigid plastics (11H1, 11H2, 21H1, and 21H2);

Composite (11HZ1and 21HZ1). IB6 ....................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B and 21N); Rigid plastics (11H1, 11H2, 21H1, and 21H2);

Composite (11HZ1, 11HZ2, 21HZ1, and 21HZ2). ......................... Additional Requirement: Composite IBCs 11HZ2 and 21HZ2 may not be used when the hazardous mate-

rials being transported may become liquid during transport. IB7 ....................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B and 21N); Rigid plastics (11H1, 11H2, 21H1, and 21H2);

Composite (11HZ1, 11HZ2, 21HZ1, and 21HZ2); Wooden (11C, 11D and 11F). ......................... Additional Requirement: Liners of wooden IBCs must be sift-proof.


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TABLE 1—IB CODES (IBC CODES)—Continued

IBC code Authorized IBCs

IB8 ....................... Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B and 21N); Rigid plastics (11H1, 11H2, 21H1, and 21H2); Composite (11HZ1, 11HZ2, 21HZ1, and 21HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexi-ble (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2).

IB9 ....................... IBCs are only authorized if approved by the Associate Administrator.

TABLE 2—IP CODES

IP Code h

IP1 ....................... IBCs must be packed in closed freight containers or a closed transport vehicle. IP2 ....................... When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a

closed freight container or a closed transport vehicle. IP3 ....................... Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant

liner. IP4 ....................... Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and

water-resistant liner. IP5 ....................... IBCs must have a device to allow venting. The inlet to the venting device must be located in the vapor

space of the IBC under maximum filling conditions. IP6 ....................... Non-specification bulk bins are authorized. IP7 ....................... For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1841, 2211, 2217, 2793 and 3314, IBCs are

not required to meet the IBC performance tests specified in part 178, subpart N of this subchapter. IP8 ....................... Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 31H2 and 31HZ1) that

have successfully passed, without leakage or permanent deformation, the hydrostatic test specified in § 178.814 of this subchapter at a test pressure that is not less than 1.5 times the vapor pressure of the contents at 55 °C (131 °F).

IP13 ..................... Transportation by vessel in IBCs is prohibited. IP14 ..................... Air must be eliminated from the vapor space by nitrogen or other means. IP15 ..................... For UN2031 with more than 55% nitric acid, rigid plastic IBCs and composite IBCs with a rigid plastic inner

receptacle are authorized for two years from the date of IBC manufacture. IP20 ..................... Dry sodium cyanide or potassium cyanide is also permitted in siftproof, water-resistant, fiberboard IBCs

when transported in closed freight containers or transport vehicles.

TABLE 3—IB CODES [Large packaging authorizations]

IB3 Authorized Large Packagings (LIQUIDS) (PG III materials only) 2

Inner packagings: Large outer packagings: Glass 10

liter.steel (50A).

Plastics 30 liter.

aluminum (50B).

Metal 40 liter.

metal other than steel or aluminum (50N).

rigid plastics (50H). natural wood (50C). plywood (50D). reconstituted wood (50F). rigid fiberboard (50G).

IB8 Authorized Large Packagings (SOLIDS) (PG III materials only) 2

Inner packagings: Large outer packagings: Glass 10 kg ........................................................... steel (50A). Plastics 50 kg ....................................................... aluminum (50B). Metal 50 kg ........................................................... metal other than steel or aluminum (50N). Paper 50 kg .......................................................... flexible plastics (51H). 1 Fiber 50 kg ............................................................ rigid plastics (50H).

natural wood (50C). plywood (50D). reconstituted wood (50F). rigid fiberboard (50G).

1 Flexible plastic (51H) Large Packagings are only authorized for use with flexible inner packagings. 2 Except when authorized under Special Provision 41.


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49 CFR Ch. I (10–1–14 Edition) § 172.102

(5) ‘‘N’’ codes. These provisions apply only to non-bulk packagings:


N3 Glass inner packagings are permitted in combination or composite packagings only if the hazardous material is free from hydrofluoric acid.

N4 For combination or composite pack-agings, glass inner packagings, other than ampoules, are not permitted.

N5 Glass materials of construction are not authorized for any part of a packaging which is normally in contact with the haz-ardous material.

N6 Battery fluid packaged with electric storage batteries, wet or dry, must con-form to the packaging provisions of § 173.159 (g) or (h) of this subchapter.

N7 The hazard class or division number of the material must be marked on the pack-age in accordance with § 172.302 of this sub-chapter. However, the hazard label cor-responding to the hazard class or division may be substituted for the marking.

N8 Nitroglycerin solution in alcohol may be transported under this entry only when the solution is packed in metal cans of not more than 1 L capacity each, overpacked in a wooden box containing not more than 5 L. Metal cans must be completely sur-rounded with absorbent cushioning mate-rial. Wooden boxes must be completely lined with a suitable material impervious to water and nitroglycerin.

N11 This material is excepted for the speci-fication packaging requirements of this subchapter if the material is packaged in strong, tight non-bulk packaging meeting the requirements of subparts A and B of part 173 of this subchapter.

N12 Plastic packagings are not authorized. N20 A 5M1 multi-wall paper bag is author-

ized if transported in a closed transport ve-hicle.

N25 Steel single packagings are not author-ized.

N32 Aluminum materials of construction are not authorized for single packagings.

N33 Aluminum drums are not authorized. N34 Aluminum construction materials are

not authorized for any part of a packaging which is normally in contact with the haz-ardous material.

N36 Aluminum or aluminum alloy construc-tion materials are permitted only for halo-genated hydrocarbons that will not react with aluminum.

N37 This material may be shipped in an in-tegrally-lined fiber drum (1G) which meets the general packaging requirements of sub-part B of part 173 of this subchapter, the requirements of part 178 of this subchapter at the packing group assigned for the ma-terial and to any other special provisions of column 7 of the § 172.101 table.

N40 This material is not authorized in the following packagings: a. A combination packaging consisting of a

4G fiberboard box with inner receptacles of glass or earthenware;

b. A single packaging of a 4C2 sift-proof, natural wood box; or

c. A composite packaging 6PG2 (glass, por-celain or stoneware receptacles within a fiberboard box).

N41 Metal construction materials are not authorized for any part of a packaging which is normally in contact with the haz-ardous material.

N42 1A1 drums made of carbon steel with thickness of body and heads of not less than 1.3 mm (0.050 inch) and with a corro-sion-resistant phenolic lining are author-ized for stabilized benzyl chloride if tested and certified to the Packing Group I per-formance level at a specific gravity of not less than 1.8.

N43 Metal drums are permitted as single packagings only if constructed of nickel or monel.

N45 Copper cartridges are authorized as inner packagings if the hazardous material is not in dispersion.

N65 Outage must be sufficient to prevent cylinders or spheres from becoming liquid full at 55 °C (130 °F). The vacant space (out-age) may be charged with a nonflammable nonliquefied compressed gas if the pressure in the cylinder or sphere at 55 °C (130 °F) does not exceed 125 percent of the marked service pressure.

N73 Packagings consisting of outer wooden or fiberboard boxes with inner glass, metal or other strong containers; metal or fiber drums; kegs or barrels; or strong metal cans are authorized and need not conform to the requirements of part 178 of this sub-chapter.

N74 Packages consisting of tightly closed inner containers of glass, earthenware, metal or polyethylene, capacity not over 0.5 kg (1.1 pounds) securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, not over 15 kg (33 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter.

N75 Packages consisting of tightly closed inner packagings of glass, earthenware or metal, securely cushioned and packed in outer wooden barrels or wooden or fiber-board boxes, capacity not over 2.5 kg (5.5 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter.

N76 For materials of not more than 25 per-cent active ingredient by weight, packages consisting of inner metal packagings not greater than 250 mL (8 ounces) capacity each, packed in strong outer packagings


349


together with sufficient absorbent mate-rial to completely absorb the liquid con-tents are authorized and need not conform to the requirements of part 178 of this sub-chapter.

N77 For materials of not more than two percent active ingredients by weight, pack-agings need not conform to the require-ments of part 178 of this subchapter, if liq-uid contents are absorbed in an inert mate-rial.

N78 Packages consisting of inner glass, earthenware, or polyethylene or other non-fragile plastic bottles or jars not over 0.5 kg (1.1 pounds) capacity each, or metal cans not over five pounds capacity each, packed in outer wooden boxes, barrels or kegs, or fiberboard boxes are authorized and need not conform to the requirements of part 178 of this subchapter. Net weight of contents in fiberboard boxes may not ex-ceed 29 kg (64 pounds). Net weight of con-tents in wooden boxes, barrels or kegs may not exceed 45 kg (99 pounds).

N79 Packages consisting of tightly closed metal inner packagings not over 0.5 kg (1.1 pounds) capacity each, packed in outer wooden or fiberboard boxes, or wooden bar-rels, are authorized and need not conform to the requirements of part 178 of this sub-chapter. Net weight of contents may not exceed 15 kg (33 pounds).

N80 Packages consisting of one inner metal can, not over 2.5 kg (5.5 pounds) capacity, packed in an outer wooden or fiberboard box, or a wooden barrel, are authorized and need not conform to the requirements of part 178 of this subchapter.

N82 See § 173.115 of this subchapter for clas-sification criteria for flammable aerosols.

N83 This material may not be transported in quantities of more than 11.5 kg (25.4 lbs) per package.

N84 The maximum quantity per package is 500 g (1.1 lbs.).

N85 Packagings certified at the Packing Group I performance level may not be used.

N86 UN pressure receptacles made of alu-minum alloy are not authorized.

N87 The use of copper valves on UN pressure receptacles is prohibited.

N88 Any metal part of a UN pressure recep-tacle in contact with the contents may not contain more than 65% copper, with a tol-erance of 1%.

N89 When steel UN pressure receptacles are used, only those bearing the ‘‘H’’ mark are authorized.

N90 Metal packagings are not authorized. N91 The use of a non specification sift-

proof, non-bulk, metal can with or without lid, or a non specification sift-proof, non- bulk fiber drum, with or without lid is au-thorized when transporting coal tar pitch compounds by motor vehicle or rail freight. The fiber drum must to be fab-

ricated with a three ply wall, as a min-imum. The coal tar pitch compound must be in a solid mass during transportation.

(6) ‘‘R’’ codes. These provisions apply only to transportation by rail.

R1 A person who offers for transpor-tation tank cars containing sulfur, molten or residue of sulfur, molten may reference the Sulfur Institute’s, ‘‘Molten Sulphur Rail Tank Car Guid-ance document’’ (see § 171.7 of this sub-chapter) to identify tank cars that may pose a risk in transportation due to the accumulation of formed, solid sulfur on the outside of the tank.

(7) ‘‘T’’ codes. (i) These provisions apply to the transportation of haz-ardous materials in UN portable tanks. Portable tank instructions specify the requirements applicable to a portable tank when used for the transportation of a specific hazardous material. These requirements must be met in addition to the design and construction speci-fications in part 178 of this subchapter. Portable tank instructions T1 through T22 specify the applicable minimum test pressure, the minimum shell thickness (in reference steel), bottom opening requirements and pressure re-lief requirements. Liquefied com-pressed gases are assigned to portable tank instruction T50. Refrigerated liq-uefied gases that are authorized to be transported in portable tanks are spec-ified in tank instruction T75.

(ii) The following table specifies the portable tank requirements applicable to ‘‘T’’ Codes T1 through T22. Column 1 specifies the ‘‘T’’ Code. Column 2 speci-fies the minimum test pressure, in bar (1 bar = 14.5 psig), at which the periodic hydrostatic testing required by § 180.605 of this subchapter must be conducted. Column 3 specifies the section ref-erence for minimum shell thickness or, alternatively, the minimum shell thickness value. Column 4 specifies the applicability of § 178.275(g)(3) of this subchapter for the pressure relief de-vices. When the word ‘‘Normal’’ is indi-cated, § 178.275(g)(3) of this subchapter does not apply. Column 5 references ap-plicable requirements for bottom open-ings in part 178 of this subchapter. ‘‘Prohibited’’ means bottom openings


350

49 CFR Ch. I (10–1–14 Edition) § 172.102

are prohibited, and ‘‘Prohibited for liq-uids’’ means bottom openings are au-

thorized for solid material only. The table follows:

TABLE OF PORTABLE TANK T CODES T1–T22 [Portable tank codes T1–T22 apply to liquid and solid hazardous materials of Classes 3 through 9 which are transported in

portable tanks.]

Portable tank instruction

(1)

Minimum test pressure

(bar) (2)

Minimum shell thickness (in mm-reference steel)

(See § 178.274(d)) (3)

Pressure-relief requirements (See § 178.275(g))

(4)

Bottom opening requirements

(See § 178.275(d)) (5)

T1 .................. 1 .5 § 178.274(d)(2) Normal .............................................. § 178.275(d)(2) T2 .................. 1 .5 § 178.274(d)(2) Normal .............................................. § 178.275(d)(3) T3 .................. 2 .65 § 178.274(d)(2) Normal .............................................. § 178.275(d)(2) T4 .................. 2 .65 § 178.274(d)(2) Normal .............................................. § 178.275(d)(3) T5 .................. 2 .65 § 178.274(d)(2) § 178.275(g)(3) ................................. Prohibited T6 .................. 4 § 178.274(d)(2) Normal .............................................. § 178.275(d)(2) T7 .................. 4 § 178.274(d)(2) Normal .............................................. § 178.275(d)(3) T8 .................. 4 § 178.274(d)(2) Normal .............................................. Prohibited T9 .................. 4 6 mm Normal .............................................. Prohibited for liquids. T10 ................ 4 6 mm § 178.275(g)(3) ................................. Prohibited T11 ................ 6 § 178.274(d)(2) Normal .............................................. § 178.275(d)(3) T12 ................ 6 § 178.274(d)(2) § 178.275(g)(3) ................................. § 178.275(d)(3) T13 ................ 6 6 mm Normal .............................................. Prohibited T14 ................ 6 6 mm § 178.275(g)(3) ................................. Prohibited T15 ................ 10 § 178.274(d)(2) Normal .............................................. § 178.275(d)(3) T16 ................ 10 § 178.274(d)(2) § 178.275(g)(3) ................................. § 178.275(d)(3) T17 ................ 10 6 mm Normal .............................................. § 178.275(d)(3) T18 ................ 10 6 mm § 178.275(g)(3) ................................. § 178.275(d)(3) T19 ................ 10 6 mm § 178.275(g)(3) ................................. Prohibited T20 ................ 10 8 mm § 178.275(g)(3) ................................. Prohibited T21 ................ 10 10 mm Normal .............................................. Prohibited for liquids.

§ 178.275(d)(2). T22 ................ 10 10 mm § 178.275(g)(3) ................................. Prohibited

(iii) T50 When portable tank in-struction T50 is indicated in Column (7) of the § 172.101 Hazardous Materials Table, the applicable liquefied com-pressed gas and chemical under pres-sure descriptions are authorized to be transported in portable tanks in ac-cordance with the requirements of § 173.313 of this subchapter.

(iv) T75. When portable tank instruc-tion T75 is referenced in Column (7) of the § 172.101 Table, the applicable re-frigerated liquefied gases are author-ized to be transported in portable tanks in accordance with the require-ments of § 178.277 of this subchapter.

(v) UN and IM portable tank codes/spe-cial provisions. When a specific portable tank instruction is specified by a ‘‘T’’ Code in Column (7) of the § 172.101 Table for a specific hazardous material, a specification portable tank conforming to an alternative tank instruction may be used if:

(A) The alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified);

(B) The alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified);

(C) The alternative portable tank has a pressure relief device as specified in the ‘‘T’’ Code. If a frangible disc is re-quired in series with the reclosing pres-sure relief device for the specified port-able tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pres-sure relief device; and

(D) With regard to bottom openings— (1) When two effective means are

specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or

(2) When three effective means are specified, the portable tank has no bot-tom openings or three effective means of closure; or

(3) When no bottom openings are au-thorized, the alternative portable tank must not have bottom openings.


351


(vi) Except when an organic peroxide is authorized under § 173.225(g), if a haz-ardous material is not assigned a port-able tank ‘‘T’’ Code, the hazardous ma-terial may not be transported in a portable tank unless approved by the Associate Administrator.

(8) ‘‘TP’’ codes. (i) These provisions apply to the transportation of haz-ardous materials in IM and UN Speci-fication portable tanks. Portable tank special provisions are assigned to cer-tain hazardous materials to specify re-quirements that are in addition to those provided by the portable tank in-structions or the requirements in part 178 of this subchapter. Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the § 172.101 Table.

(ii) The following is a list of the port-able tank special provisions:


TP1 The maximum degree of filling must not exceed the degree of filling determined by the following:

Degree of filling =+ −( )

⎛

⎝⎜⎞

⎠⎟97

1 α t tr f

.

Where:

tr is the maximum mean bulk temperature during transport, and tf is the tempera-ture in degrees celsius of the liquid dur-ing filling.

TP2 a. The maximum degree of filling must not exceed the degree of filling deter-mined by the following:

Degree of filling =+ −( )

⎛

⎝⎜⎞

⎠⎟95

1 α t tr f

.

Where:

tr is the maximum mean bulk temperature during transport,

tf is the temperature in degrees celsius of the liquid during filling, and

a is the mean coefficient of cubical expan-sion of the liquid between the mean tem-perature of the liquid during filling (tf) and the maximum mean bulk tempera-ture during transportation (tr) both in degrees celsius.

b. For liquids transported under ambient conditions a may be calculated using the for-mula:

α =−d d

d15 50

5035Where:

d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

TP3 The maximum degree of filling (in %) for solids transported above their melting points and for elevated temperature liquids shall be determined by the following:

Degree of filling = 95d

dr

f

⎛⎝⎜

⎞⎠⎟

.

Where: df and dr are the mean densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during transport respectively.

TP4 The maximum degree of filling for portable tanks must not exceed 90%.

TP5 For a portable tank used for the transport of flammable refrigerated liquefied gases or refrigerated liquefied oxygen, the maximum rate at which the portable tank may be filled must not exceed the liquid flow capacity of the primary pressure relief sys-tem rated at a pressure not exceeding 120 percent of the portable tank’s design pres-sure. For portable tanks used for the trans-port of refrigerated liquefied helium and re-frigerated liquefied atmospheric gas (except oxygen), the maximum rate at which the tank is filled must not exceed the liquid flow capacity of the pressure relief device rated at 130 percent of the portable tank’s design pressure. Except for a portable tank con-taining refrigerated liquefied helium, a port-able tank shall have an outage of at least two percent below the inlet of the pressure relief device or pressure control valve, under conditions of incipient opening, with the portable tank in a level attitude. No outage is required for helium.

TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment condi-tions (the conditions prescribed in CGA pam-phlet S–1.2 (see § 171.7 of this subchapter) or alternative conditions approved by the Asso-ciate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous ma-terial to be transported.

TP7 The vapor space must be purged of air by nitrogen or other means.

TP8 A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous mate-rial transported is greater than 0 °C (32 °F).

TP9 A hazardous material assigned to special provision TP9 in Column (7) of the § 172.101 Table may only be transported in a

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352

49 CFR Ch. I (10–1–14 Edition) § 172.102

portable tank if approved by the Associate Administrator.

TP10 The portable tank must be fitted with a lead lining at least 5 mm (0.2 inches) thick. The lead lining must be tested annu-ally to ensure that it is intact and func-tional. Another suitable lining material may be used if approved by the Associate Admin-istrator.

TP12 This material is considered highly corrosive to steel.

TP13 Self-contained breathing apparatus must be provided when this hazardous mate-rial is transported by sea.

TP16 The portable tank must be pro-tected against over and under pressurization which may be experienced during transpor-tation. The means of protection must be ap-proved by the approval agency designated to approve the portable tank in accordance with the procedures in part 107, subpart E, of this subchapter. The pressure relief device must be preceded by a frangible disk in ac-cordance with the requirements in § 178.275(g)(3) of this subchapter to prevent crystallization of the product in the pressure relief device.

TP17 Only inorganic non-combustible ma-terials may be used for thermal insulation of the tank.

TP18 The temperature of this material must be maintained between 18 °C (64.4 °F) and 40 °C (104 °F) while in transportation. Portable tanks containing solidified meth-acrylic acid must not be reheated during transportation.

TP19 The calculated wall thickness must be increased by 3 mm at the time of con-struction. Wall thickness must be verified ultrasonically at intervals midway between periodic hydraulic tests (every 2.5 years). The portable tank must not be used if the wall thickness is less than that prescribed by the applicable T code in Column (7) of the Table for this material.

TP20 This hazardous material must only be transported in insulated tanks under a ni-trogen blanket.

TP21 The wall thickness must not be less than 8 mm. Portable tanks must be hydrau-lically tested and internally inspected at in-tervals not exceeding 2.5 years.

TP22 Lubricants for portable tank fit-tings (for example, gaskets, shut-off valves, flanges) must be oxygen compatible.

TP24 The portable tank may be fitted with a device to prevent the build up of ex-cess pressure due to the slow decomposition of the hazardous material being transported. The device must be in the vapor space when the tank is filled under maximum filling conditions. This device must also prevent an unacceptable amount of leakage of liquid in the case of overturning.

TP25 Sulphur trioxide 99.95% pure and above may be transported in tanks without an inhibitor provided that it is maintained

at a temperature equal to or above 32.5 °C (90.5 °F).

TP26 The heating device must be exterior to the shell. For UN 3176, this requirement only applies when the hazardous material re-acts dangerously with water.

TP27 A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in § 178.275 of this sub-chapter, where the test pressure is 1.5 times the MAWP.

TP28 A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in § 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP.

TP29 A portable tank having a minimum test pressure of 1.5 bar (150.0 kPa) may be used provided the calculated test pressure is 1.5 bar or less based on the MAWP of the haz-ardous materials, as defined in § 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP.

TP30 This hazardous material may only be transported in insulated tanks.

TP31 This hazardous material may only be transported in tanks in the solid state.

TP32 Portable tanks may be used subject to the following conditions:

a. Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. The set to discharge for the spring loaded pressure relief device and the burst pressure for the frangible disc, as applicable, must not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar;

b. The suitability for transport in tanks must be demonstrated using test 8(d) in Test Series 8 (see UN Manual of Tests and Cri-teria, Part 1, Sub-section 18.7) (IBR, see § 171.7 of this subchapter) or an alternative means approved by the Associate Adminis-trator.

TP33 The portable tank instruction as-signed for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for trans-portation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent re-quirements for minimum shell thickness, maximum allowable working pressure, pres-sure-relief devices or bottom outlets are as-signed in which case the more stringent tank instruction and special provisions shall


353


apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter.

TP36 For material assigned this portable tank special provision, portable tanks used to transport such material may be equipped with fusible elements in the vapor space of the portable tank.

TP37 IM portable tanks are only author-ized for the shipment of hydrogen peroxide solutions in water containing 72% or less hy-drogen peroxide by weight. Pressure relief devices shall be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure. In addition, the portable tank must be designed so that internal surfaces may be effectively cleaned and passivated. Each tank must be equipped with pressure relief devices conforming to the following require-ments:

Concentration of hydrogen per peroxide solution Total 1

52% or less .............................................................. 11 Over 52%, but not greater than 60% ...................... 22 Over 60%, but not greater than 72% ...................... 32

1 Total venting capacity in standard cubic feet hour (S.C.F.H.) per pound of hydrogen peroxide solution.

TP38 Each portable tank must be insu-lated with an insulating material so that the overall thermal conductance at 15.5 °C (60 °F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahr-enheit) temperature differential. Insulating materials may not promote corrosion to steel when wet.

TP39 The portable tank instruction T4 prescribed may continue to be applied until December 31, 2018.

TP40 The portable tank must not be transported when connected with spray ap-plication equipment.

TP41 The portable tank instruction T9 may continue to be applied until December 31, 2018.

TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of § 173.24b(b) of this sub-chapter. Thickness of stainless steel for tank shell and heads must be the greater of 7.62 mm (0.300 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.5 times the vapor pressure of the hazardous material at 46 °C (115 °F).

TP45 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this sub-chapter. Thickness of stainless steel for port-able tank shells and heads must be the great-er of 6.35 mm (0.250 inch) or the thickness re-

quired for a portable tank with a design pres-sure at least equal to 1.3 times the vapor pressure of the hazardous material at 46 °C (115 °F).

TP46 Portable tanks in sodium metal service are not required to be hydrostatically retested.

(9) ‘‘W’’ codes. These provisions apply only to transportation by water:


W1 This substance in a non friable prill or granule form is not subject to the require-ments of this subchapter when tested in accordance with the UN Manual of Test and Criteria (IBR, see § 171.7 of this sub-chapter) and is found to not meet the defi-nition or criteria for inclusion in Division 5.1.

W7 Vessel stowage category for uranyl ni-trate hexahydrate solution is ‘‘D’’ as de-fined in § 172.101(k)(4).

W8 Vessel stowage category for pyrophoric thorium metal or pyrophoric uranium metal is ‘‘D’’ as defined in § 172.101(k)(4).

W9 When offered for transportation by water, the following Specification pack-agings are not authorized unless approved by the Associate Administrator: woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings.

W10 When offered for transportation by ves-sel, the use of Large Packagings (see § 171.8 of this subchapter) is prohibited.

W41 When offered for transportation by water, this material must be packaged in bales and be securely and tightly bound with rope, wire or similar means.

[Amdt. 172–123, 55 FR 52582, Dec. 21, 1990]

EDITORIAL NOTE: For FEDERAL REGISTER ci-tations affecting § 172.102, see the List of CFR Sections Affected, which appears in the Finding Aids section of the printed volume and at www.fdsys.gov.

Subpart C—Shipping Papers

§ 172.200 Applicability.

(a) Description of hazardous materials required. Except as otherwise provided in this subpart, each person who offers a hazardous material for transpor-tation shall describe the hazardous ma-terial on the shipping paper in the manner required by this subpart.

(b) This subpart does not apply to any material, other than a hazardous substance, hazardous waste or marine pollutant, that is—

(1) Identified by the letter ‘‘A’’ in col-umn 1 of the § 172.101 table, except


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