diamondjo.worlddiamondjo.world/.../2020/10/SHAMPOO-FORMULATIONS-pdf-1.pdf1 GUIDELINE FORMULARY Kao...

SHAMPOO FORMULATIONS BY

KAO

1

GUIDELINE FORMULARY

Kao Corporation, S.A.Member of Kao Chemicals Europe

Puig dels Tudons, 10 -E-08210 – Barberà del Vallès

KCE REFERENCE: C-152

Tel. : +34-93-7399300Fax : +34-93-7399377

e-mail : [email protected] : www.kaochemicals-eu.com

“2 IN 1” ANTI-DANDRUFF SHAMPOO

VERY MILD

DESCRIPTION

Shampoo that prevents dandruff formation

Relieves the scalp, soothes redness and eliminates dandruff

For frequent use

Leaves hair soft and clean

COMPOSITION %

EMAL 270D (1) 13.5

AKYPO FOAM RL 40 5.0

LEVENOL H&B 2.0

AMIDET N 1.0Dimethicone (2) 0.5

TETRANYL U 0.5Hydroxypropyl Guar Hydroxypropyl TC (3) 0.1EDTA.Na4 0.2Acrylates/C10-30 Alkyl Acrylate Crosspolymer (4) 0.5Polyquartenium-10 (5) 0.2Zinc Pyrithione (6)

(50% solution) 2.0

DANOX PL-10 4.0CI 42090 (1‰ solution) 0.5Fragrance q.s.Preservative (Isothiazolinone type, 1.5% act) 0.05Triethanolamine q.s. (pH adjust = 6.0 – 7.0)

Sodium Chloride q.s.Deionized Water Up to 100%

(1) 13.5% of EMAL 270D (SLES at 70% a.m.) can be substituted by 35% of EMAL 227E (SLES at 27% a.m.).

(2) Dow Corning 200 350 CST supplied by Dow Corning

(3) Jaguar C-162 supplied by Rhodia Novecare

(4) Carbopol ETD 2020 supplied by Lubrizol

(5) Ucare LR 400 supplied by Amerchol

(6) Zinc Pyrion 48% micronized supplied by WeylChem/Evonik

mailto:[email protected]

http://www.kaochemicals-eu.com/

GUIDELINE FORMULARYKao Corporation S.A.(Member of KAO CHEMICALS EUROPE)


2REFERENCE :

UP-DATED: PRINTED :

C308 (C-091)

2010-09-092010-09-09

TECHNICAL CHARACTERISTICS

Kao Method

APPEARANCE (20ºC) : Blue Pearled Viscous Liquid KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : 12500 approx. (0.5% NaCl) KCSA-227

pH (100%) : 6.0 - 7.0 KCSA-014

STABILITY : Correct (1 month 40ºC/RT/5ºC)

RECOMMENDED OPERATIVE METHOD

Add to the Deionized Water EDTA.Na4, Polyquaternium-10, Hydroxypropyl Guar HydroxypropylTrimonium Chloride and Acrylate Polymer (Carbopol ETD 2020). Stir well after each additionuntil a homogeneous dispersion is obtained.

Add EMAL 270D, AKYPO FOAM RL 40 and LEVENOL H&B stirring after each addition until total homogeneity.

Mix the silicone (Dimethicone) with AMIDET N and, once it is homogeneous, add to previous mixture.

Add TETRANYL U, Zinc Pyrithione and DANOX PL-10. Stir well after each addition until a homogeneous mixture is obtained.

Add the other additives: preservative (soluble), perfume (15 minutes of agitation are usually needed to solubilize it), dye(s) (diluted in water) and other (extracts, etc.).

Adjust pH (it is recommended to use citric acid to reduce it and TEA if an increase is necessary)

and final desired viscosity using Sodium Chloride.

COMPONENTS

EMAL 270D (Sodium Laureth Sulfate, 70% a.m.) : anionic character. Primary surfactant, highly foaming. Good detergentproperties.

AKYP FOAM RL 40 (Sodium Laureth-5 Carboxylate, 60% a.m.): crypto-anionic character, it combines the propertiesO

of the anionic and non-ionic surfactants. Mild foam-booster for Personal Care products. Produces a rapid foam andimproves the foam behaviour of cleansing products when used as co-surfactant.

LEVENOL H&B (Glycereth-2 Cocoate, 100% a.m.): non-ionic character. Extra-mild surfactant, with emulsifying

properties. Skin emollient and moisturizing agent .Foam booster and thickening agent. Ecological product. It doesn’t need

any risk or safety warnings on its label. In hair rinse application increases the conditioning effect of the cationic component,

giving smoothness. % of use in Hair Rinse = between 0.1 - 2%

AMIDE N (PEG-4 Rapeseedamide, 95% a.m.): non-ionic character. Nitroso-amines free thickener. It increases theT

foam volume and improves the quality of it. It reduces the irritation potential of the anionic surfactants on the skin. Multi-functional agent. Previous name : AMINOL N

TETRANYL U (Undecylenamidopropyltrimonium Methosulfate, 50% a.m.): cationic character. Fungicide and bactericide effect. Water soluble at room temperature. Compatible with other surfactants.

DANOX PL-10 (pearling concentrate, 52% dry matter): anionic and non-ionic character. Nitroso-amines free product (its

composition doesn’t contain any Nitrogen derivative). It allows modifying the final appearance of the formula, providing it

with a beautiful pearled appearance. No heating is needed. Ecological product. Common use percentage: 3 - 10 %.

The information and recommendations in this publication are to the best of our knowledge reliable. However, nothing herein is to be construed asa warranty or representation. Users should make their own tests to determine the applicability of such information or the suitability of anyproducts for their own particular purpose.Statements concerning the use of the products described herein are not to be construed as recommending the infringement of any patent andno liability for infringement arising out of any such use is assumed.

1

GUIDELINE FORMULARY




Tel. : +34-93-7399300 e-mail : [email protected] : +34-93-7399377 Web : www.kaochemicals-eu.com

ANTIDANDRUFF & CONDITIONER SHAMPOO

DESCRIPTION


Additional effect on the hair: conditioning

After its application, combing becomes easier (wet - dry conditions)

It provides shine and anti-staticity to the hair

COMPOSITION %

EMAL270D (1) 15.0

EMAL 40TE 6.0

AMIDET B-112 2.0

EMANON HE 0.8

BETADET HR 5.0

TETRANYL CO-40 0.5Hydroxypropyl Cellulose 0.2ZnPt (50% solution) q.s.

TETRANYL U 0.5

DANOX P-15 3.0Preservative, perfume, dye(s) q.s.Additives q.s.NaOH (20% solution) q.s. (pH adjust = 5.0 – 6.0)

NaCl q.s. (viscosity adjust, < 1.0%)

Deionized Water Up to 100%

(1) 15% of EMAL 270D (SLES at 70% a.m.) can be substituted by 40% of EMAL 227E (SLES at 27% a.m.).


Kao Method

APPEARANCE (20ºC): Opaque Viscous Liquid KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs): 5000 approx. KCSA-227

pH (100%): 5.0 - 6.0 KCSA-014

DRY MATTER (%): 21 approx. KCSA-092

STABILITY: Correct (1 month 40ºC/RT/5ºC)





2REFERENCE:

UP-DATED: PRINTED :

C-90O – XT01-I / CS-504:KCC6/2

2010-09-092010-09-09


Sprinkle the Hydroxypropyl Cellulose over the water, avoiding lumps formation. Stir till complete incorporation.

Add the other components, keeping the above mentioned order until DANOXP-15, and stirring after each addition until total homogeneity.

Add the other additives: preservative (soluble), fragrance (15 minutes of agitation are usually needed to solubilize it), dye(s) (diluted in water), others (extracts, etc).

Adjust pH (it is recommended to use diluted sodium hydroxide to increase it and citric acid if a pH decrease is necessary).

Adjust the final desired viscosity using Sodium Chloride (usually < 0.5%).

COMPONENTS

AMIDET B-112 (Cocamide DEA, 100% organic matter): non-ionic character. Thickening agent. Its use allows reducing

the quantity of sodium chloride needed to adjust viscosity in the final formula. It improves the quality of the foam and avoids

the excessive degreasing effect of the anionic surfactants on the skin.

DANOX P-15 (pearling concentrate, 40% dry matter): anionic and non-ionic character. It modifies the final appearance of the formula, giving a beautiful pearled appearance. Use %: 3 - 10 %.

EMAL270D (Sodium Laureth Sulfate, 70% a.m.): anionic character. Primary surfactant, highly foaming. Good detergent properties.

EMAL40TE (TEA Lauryl Sulfate, 40% a.m.): anionic character. Primary surfactant, highly foaming. Good detergent properties.

EMANON HE (PEG-7 Glyceryl Cocoate, 100% a.m.): non-ionic character. Emollient for the skin and hair. It provides shine and smoothness to the hair.

TETRANYL CO-40 (Dioleoylethyl Hydroxyethylmonium Methosulfate, 80% a.m.): cationic character. Conditioning

surfactant, under liquid form. It provides smoothness, shine and anti-static properties to the hair, making easy to comb it. It

doesn't present cumulative effect. Environmentally friendly cationic surfactant.

TETRANYLU (Undecylenamidopropyltrimonium Methosulfate, 50% a.m.): cationic character. Fungicide and bactericide effect. Water soluble at room temperature. Compatible with other surfactants.

The information and recommendations in this publication are to the best of our knowledge reliable. However, nothing herein is to be construedas a warranty or representation. Users should make their own tests to determine the applicability of such information or the suitability of anyproducts for their own particular purpose.Statements concerning the use of the products described herein are not to be construed as recommending the infringement of any patent andno liability for infringement arising out of any such use is assumed.

1

GUIDELINE FORMULARY




Tel. : +34-93-7399300Fax : +34-93-7399377


ANTI-DANDRUFF SHAMPOO

DESCRIPTION

Healthy scalp without dandruff

For normal greasy hair

Daily use

COMPOSITION %

EMAL 270D (1) 23.0

BETADET HR-50K (2) 10.0

DANOX P-15 3.0

AMIDET B-112 1.0

EMANON HE 0.8Climbazol 0.5Preservative (Isothiazolinone type, 1.5% a.m.) 0.05Dye(s) q.s.Fragrance q.s.Citric Acid q.s. (pH adjust= 6.0 – 7.0)


(1) 23% of EMAL 270D (SLES at 70% a.m.) can be substituted by 60% of EMAL 227D (SLES at 27% a.m.).

(2) 10% of BETADET HR-50K (CAPB at 40% a.m.) can be substituted by 13.3% of BETADET HR (CAPB at 30% a.m.).


Kao Method

APPEARANCE (20ºC) : Pearled Viscous Liquid KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : 8000 approx. KCSA-227

pH (100%) : 6.0 - 7.0 KCSA-014

DRY MATTER (%) : 25 approx. KCSA-092






2REFERENCE :

UP-DATED: PRINTED :

2010-09-09

2010-09-09


Heat Deionized Water till 45ºC approx. and add EMAL 270D. Stir until complete transparency.

Add BETADET HR-50K to the previous mixture.

In another vessel mix up Climbazol (powder) with AMIDET B-112 and EMANON HE and heat slightly to help the solubilization of Climbazol. Add this mixture to the previous one.

Continue with the addition of DANOX P-15 stirring well until a homogeneous product is obtained.

Add the other additives: preservative (soluble), perfume (15 minutes of agitation are usually needed to solubilize it), dyes (diluted in water) and other (extracts, etc.).

Adjust pH (it is recommended to use citric or lactic acid to reduce it and diluted sodium hydroxide if an increase is necessary).

Adjust the final desired viscosity using Sodium Chloride.

COMMENTS

If high conditioning effect is desired, other type of components can be added (extracts, protein hydrolizates, cationic polymers, silicones, etc.), always following the manufacturer’s indications.

COMPONENTS

AMIDE B-112 (Cocamide DEA, 100% organic matter): non-ionic character. Thickening agent. Its use allows reducingT

the quantity of sodium chloride needed to adjust viscosity in the final formula. It improves the quality of the foam and avoids the excessive degreasing effect of the anionic surfactants on the skin.

BETADE HR-50K (Cocamidopropyl Betaine, 48% dry matter): amphoteric character. Secondary surfactant. ItT

decreases the irritation level of the anionic surfactants on the skin, improving volume and quality of the foam. Additional thickening affect.

DANOX P-15 (pearling concentrate, 40% dry matter): anionic and non-ionic character. It modifies the final appearance of the formula, giving a beautiful pearled appearance. Use %: 3 - 10 %.

EMAL 270D (Sodium Laureth Sulfate, 70% a.m.): anionic character. Primary surfactant, highly foaming. Good detergent properties.

EMANO HE (PEG-7 Glyceryl Cocoate, 100% a.m.): non-ionic character. Emollient for the skin and hair. It providesN

shine and smoothness to the hair.

Climbazol: anti-dandruff agent. It acts specifically against Malssezia furfur, one of the dandruff precursors. Recommended use less than 1 %.


1

GUIDELINE FORMULARY




Tel. : +34-93-7399300Fax : +34-93-7399377


ANTIDANDRUFF SHAMPOO

VERY MILD

DESCRIPTION



Hair is left healthy and perfectly clean

Safe for everyday use

COMPOSITION %

EMAL 227E (1) 25.0


BETADET THC-2 5.0

TETRANYL U 1.0Salicylic Acid 0.3Piroctone Olamine 0.5Dye(s) q.s.Fragrance q.s.Preservative (Isothiazolinone type, 1.5% act.) 0.05Lactic Acid q.s. (pH adjust = 5.5 – 6.0)


(1) 25% of EMAL 227E (SLES at 27% a.m.) can be substituted by 9.5% of EMAL 270D (SLES at 70% a.m.).


Kao Method

APPEARANCE (20ºC) : Clear Yellowish Viscous Liquid KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : 5500 approx. (1% NaCl) KCSA-227

pH (100%) : 5.5 - 6.0 KCSA-014

DRY MATTER (%) : 13.5 approx. KCSA-092

CLOUD POINT (ºC) : + 4 KCSA-246






2REFERENCE :

UP-DATED: PRINTED :

C06001

2010-09-092010-09-09


Add to the Deionized Water EMAL 227E, then dissolve Salicylic Acid and Piroctone Olamine.When the mixture is clear, add each component keeping the above-mentioned order and stirringafter each addition until total homogeneity.

Add the other additives: preservative (soluble), perfume (15 minutes of agitation are usuallyneeded to solubilize it), dye(s) (diluted in water) and other (extracts, etc.).

Adjust pH (it is recommended to use citric or lactic acid to reduce it and diluted sodium hydroxideif an increase is necessary)


COMMENTS


COMPONENTS


of the anionic and non-ionic surfactants. Mild foam-booster for Personal Care products. Produces a rapid foam and improves the foam behaviour of cleansing products when used as co-surfactant.

BETADE THC-2 (Disodium Cocoamphodiacetate, 40% a.m.): amphoteric character. Very mild co-surfactant. ItT


EMAL 227E (Sodium Laureth Sulfate, 27% a.m.): anionic character. Primary surfactant, highly foaming. Good detergent properties.

TETRANYL U (Undecylenamidopropyltrimonium Methosulfate, 50% a.m.): cationic character. Fungicide and bactericide effect. Water soluble at room temperature. Compatible with other surfactants.


GUIDELINE FORMULARY


Puig delsTudons,10 -E-08210 - BarberàdelVallès

1


Tel.: +34-93-7399300Fax: +34-93-7399377

e-mail: [email protected]: www.kaochemicals-eu.com

ANTI-DANDRUFF SHAMPOO

VERY MILD

DESCRIPTION



For frequent use


It contains natural EO free thickener

COMPOSITION %

EMAL270 D(1)

AKYPOFOAM RL 40

LEVENOLH&B

DANOXPL-10

EXCEPARLLM-LC

TETRANYL UDimethicone(2)

Hydroxypropyl Guar Hydroxypropyl TC (3)

EDTA.Na4

Polyquaternium-10(4)

Zinc Pyrithione(5) (50%)CI 42090 1‰PerfumePreservative (Isothiazolinone type, 1.5% act)

Sodium Chloride DeionizedWater

14.0

5.0

2.5

4.0

1.5

0.5

0.50.10.20.22.00.5q.s.q.s.q.s.

Up to 100%

(1) 14% of EMAL 270D (SLES, 70%) can be replaced by 36,3% of EMAL 227E (SLES, 27%)

(2) Dow Corning 200 350 cst supplied by Dow Corning

(3) Jaguar C-162 supplied by Rhodia

(4) UcareTM LR 400 supplied by Amerchol(5) Zinc Pyrion 48% micronized supplied by WeylChem/Evonik




KCE REFERENCE : C-211

2PREVIOUS: C08018_C-152/Mv2

UP-DATED: 2012-04-25PRINTED: 2012-04-25


Kao Method

APPEARANCE (20ºC) : Blue Pearled Viscous Gel KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : 17.000 approx. (0.1% NaCl) KCSA-227

pH (100%) : 6.0 - 7.0 KCSA-014

STABILITY : Correct 1 months 40ºC/RT/5ºC/cycles


Add EDTA.Na4 to the water, Polyquaternium-10 and Hydroxypropyl Guar Hydroxypropyl Trimonium Chloride. Stir well after each addition until a homogeneous dispersion is obtained.

Add AKYPOFOAM RL 40, EMAL270D, LEVENOLH&B and EXCEPARLLM-LC stirring after each addition until total homogeneity.

Add Silicone (Dimethicone), TETRANYLU, Zinc Pyrithione and DANOXPL-10. Stir well after each addition until a homogeneous mixture is obtained.


Adjust pH (it is recommended to use citric acid to reduce it and TEA if an increase is necessary) and final desired viscosity using sodium chloride.

COMPONENTS

EMAL 270D (Sodium Laureth Sulfate, 70% a.m.): anionic character. Primary surfactant, highly foaming. Good detergentproperties.

AKYPO FOAM RL 40 (Sodium Laureth-5 Carboxylate, 60% a.m.): crypto-anionic character, it combines the properties of

the anionic and non-ionic surfactants. Mild foam-booster for Personal Care products. Produces rapid foam and improves the

foam behaviour of cleansing products when used as co-surfactant.



any risk or safety warnings on its label. In hair rinse application increases the conditioning effect of the cationic component,giving smoothness. % of use in Hair Rinse = between 0.1 - 2%

EXCEPARL LM-LC (Lauryl Lactate, 100% a.m.): non-ionic character. Natural EO free liquid thickener. It is a clear,

odourless and colourless liquid, which is easy to handle and that can be processed at room temperature. % of use =

between 0.3 - 3%

TETRANYL U (Undecylenamidopropyltrimonium Methosulfate, 50% a.m.): cationic character. Fungicide and bactericideeffect. Water soluble at room temperature. Compatible with other surfactants.

DANOX PL-10 (Pearling Concentrate, 52% dry matter): anionic and non-ionic character. Nitroso-amines free product (its



The information and recommendations in this publication are to the best of our knowledge reliable. However, nothingherein is to be construed as a warranty or representation. Users should make their own tests to determine the applicabilityof such information or the suitability of any products for their own particular purpose.Statements concerning the use of the products described herein are not to be construed as recommending theinfringement of any patent and no liability for infringement arising out of any such use is assumed.

1

GUIDELINE FORMULARY


Puig delsTudons,10 -E-08210 – BarberàdelVallès


Tel. : +34-93-7399300Fax : +34-93-7399377


CLEAR ANTIDANDRUFF SHAMPOO

WITH TRIKENOL

DESCRIPTION

Clear shampoo

It contains glycerine and natural oils

It provides cleansing, moisturising and anti-aging protection

COMPOSITION %

EMAL270 D (1) 13.5AKYPOFOAM RL 40 5.0

LEVENOLH&B 2.0

AMIDETN 1.5Trikenol 0.5Silicone polyether copolymer (2) 0.5Hydroxypropyl Guar HydroxypropyltrimoniumChloride (3) 0.2

EDTA.NA4 0.2Sodium Chloride 1.2Sodium Hydroxide (10% solution) q.s.Preservative (4) q.s.


(1) 13.5% of EMAL 270D (SLES at 70% a.m.) can be substituted by 35% of EMAL 227E (SLES at 27% a.m.)

(2) Dow corning 193 supplied by Dow Corning


(4) IsocilTM PC supplied by Lonza


Kao Method

APPEARANCE (20°C) : Clear Viscous Liquid KCSA-258

VISCOSITY BROOKFIELD (20°C, cPs) : 5000 KCSA-227

pH (100%) : 5.5 KCSA-014






REFERENCE : C08014 – AT-4

UP-DATED : 2013-01--25PRINTED : 2012-04--25

2


Heat the water up to 60ºC. Add EDTA.Na4 and JaguarC-162. Stir well after each addition until a clear solution is obtained.

Add EMAL 270D, AKYPO FOAM RL 40 and LEVENOLH&B. Stir well after each addition until the mixture is homogeneous.

After complete homogenization cool down to 40ºC.

Mix Dow corning 193 with AMIDETN and once it is homogeneous, add to previous mixture.

Add Trikenol.

Add preservative and perfume (15 minutes of agitation are usually needed to solubilize it).

Adjust pH to 5.5 with Sodium Hydroxide.

COMPONENTS



the anionic and non-ionic surfactants. Mild foam-booster for Personal Care products. Produces a rapid foam and improves

the foam behaviour of cleansing products when used as co-surfactant.




AMIDET N (PEG-4 Rapeseedamide , 95% a.m. ): non-ionic character. Nitroso-amines free thickener. It increases thefoam volume and improves the quality of it. It reduces the irritation potential of the anionic surfactants on the skin. Multi-functional agent. Previous name : AMINOL N


1

GUIDELINE FORMULARY




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COLOR & CARE SHAMPOO

SLES-FREE

DESCRIPTION

SLES free shampoo

It offers long lasting color vibrancy and intensive care

COMPOSITION %

AKYPOFOAM RL40 15.0BETADET S-20 9.0

AMIDET APA-22 1.5

Silicone Quaternium-18 (1) 1.0

PEG-150 Distearate(2) 0.4

Carbomer (3) 0.3

Polyquaternium-10 (4) 0.15Preservative q.s.


(1) SilsoftQ supplied by Momentive

(2) AculynTM 60 supplied by RHOM & HAAS / ISISA

(3) Carbopol Ultrez 21 produced by Noveon

(4) UcareTM JR-30M produced by Amerchol Impex Química


Kao Method

APPEARANCE (20ºC) : Hazy Gel KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : 16000 approx KCSA-227

pH (100%) : 5.5 approx KCSA-014






2REFERENCE:

UP-DATED: PRINTED :

C09010 – D1/B9

2010-09-092010-09-09


Heat the water up to around 60ºC. Add Polyquaternium-10.

Add BETADETS-20 and AKYPOFOAM RL 40 until completehomogenization.

Heat up until 80ºC and add AMIDETAPA-22. Once it is complete melted, cool down until the temperatures is around 60ºC and add PEG-150 Distearate.

Cool down the temperature until 23ºC and add Silicone and Carbomer previously mixed with water.

Adjust pH (it is recommended to use Citric or Lactic Acid to reduce it and diluted Sodium Hydroxide if an increase is necessary).

Add the other additives: preservative (soluble), fragrance (15 minutes of agitation are usually needed to solubilize it), dyes (diluted in water) and other (extracts, etc.).

COMPONENTS




BETADET S-20 (Lauryl Hydroxysultaine, 38% a.m.): amphoteric character. Very mild co-surfactant. It decreases the

irritation level of anionic surfactants, improving the quality of the foam and performing also as a thickener. It improves the

stability of the formula at extreme pH’s and low temperature.

AMIDET APA-22 (Behenamidopropyl Dimethylamine, 100% a.m.): non-ionic character. High conditioning surfactant atacid pH, with substantive properties. It provides smoothness and anti-static effect to the hair. It also acts as a thickener in

shampoo formulations.


1

GUIDELINE FORMULARY




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CONDITIONER

ANTI-AGING

DESCRIPTION

Anti-aging conditioner

It provides conditioning and smoothing effect

It contains keratin, polymers and alcohols

COMPOSITION %

KALCOL® 6850 4.4

AMIDET® APA-22 2.2

LEVENOL® H&B 0.5

Keratin (1) 1.0

Lactic Acid 0.6

Avocado Oil 0.5

Polyquaternium-10(2)

0.3

D-Panthenol (3) 0.2

Preservative q.s.

Perfume q.s.


(1) KeratecTM IFP PE produced byCRODA.(2) UcareTM JR-30M produced by Amerchol ImpexQuímica(3) Provit® 50 produced byBASF.


Kao Method

APPEARANCE (20°C) : White Cream KCSA-258

VISCOSITY BROOKFIELD (20°C, cPs) : 4000- 6000 KCSA-227

pH (100%) : 4.0 approx. KCSA-014






REFERENCE : C11003– CD-2/B2

UP-DATED : 2011-06-17PRINTED : 2011-06-17

2


Heat the water up to around 80ºC. Add Lactic acid.

Add AMIDET® APA-22 and stir until completehomogenization.

Add Polyquaternium-10 and KALCOL® 6850P. Stir for 30 minutes.

Mix Avocado Oil with LEVENOL® H&B and add it to the previous mixture.

Cool down the temperature until 50-55ºC. Mix water (≈10% of the total water) with Keratin at 30ºC and once it is homogeneous add to previous mixture.

Add preservative (soluble), perfume (15 minutes of agitation are usually needed to solubilize it).

Adjust pH if it is necessary.

COMPONENTS

KALCOL 6850 (Cetearyl Alcohol, C1618:50/50 approx., 100% a.m.): non-ionic character. Co-emulsifier and thickener.Low substantive conditioning properties. Typical % of use = between 1 - 5%.

AMIDET APA-22 (Behenamidopropyl Dimethylamine, 100% a.m.): non-ionic character. High conditioning surfactant at

acid pH, with substantive properties. It provides smoothness and anti-static effect to the hair. It also acts as a thickener in






1

GUIDELINE FORMULARY




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CONDITIONING SHAMPOO

DAILY USE

DESCRIPTION

Mild shampoo

Improves hair feeling

Slight conditioning properties

Reduces fly away effect from combing

COMPOSITION %

EMAL227E (1)28.5

AKYPORLM 100 2.85

BETADET HR 10.0

AMIDET N 2.1

AMIDET APA-22 0.5NaOH (50% solution) 0.24Perfume q.s.Preservative q.s.Additives q.s.NaOH (10% solution) q.s.Sodium Chloride q.s. (viscosity adjust)

Deionized Water Up to 100

(1) 28.5% of EMAL 227E (SLES at 27% a.m.) can be substituted by 11% of EMAL 270D (SLES at 70% a.m.)

(2) 10.0% of BETADETHR can be substituted by 7.15% of BETADET HR-50K


Kao Method

APPEARANCE (20ºC) : Clear Viscous Liquid KCSA-258

VISCOSITY BROOKFIELD (20ºC, cPs) : 7400 approx.(4% NaCl)(2) KCSA-227

pH (as it is) : 6.0 - 7.0 KCSA-014

CLOUD POINT (ºC) : -2 KCSA-246

DRY MATTER (%) : 17 KCSA-092

STABILITY TEST : Correct 1 month 40ºC/RT/5ºC

(2) Viscosity is highly dependant on speed and spindle.





2REFERENCE:

UP-DATED: PRINTED :

C07004 (C-073)

2010-09-092010-09-09


Add to the 85% of the Deionized Water needed in the formula, AKYPORLM 100 and neutralizewith Sodium Hydroxide (0,12% of concentrated NaOH at 100%). Stir until complete transparency.

Continue with the addition of EMAL 227E and AMIDET N and stir after each addition until themixture is homogeneous.

In another vessel add 10% of the Deionized Water and BETADET HR, heat up to 80ºC and add

AMIDETAPA-22. When the mixture is clear add it to the previous one.

Adjust pH (it is recommended to use diluted sodium hydroxide to increase it and citric or lacticacids if a pH decrease is necessary).

Continue with the addition of the rest of components. Homogenize after each addition.

Add preservative and perfume.

Adjust viscosity by using NaCl.

COMMENTS

If high conditioning effect is desired, other type of components can be added (extracts, protein hydrolizates, cationic polymers, etc) taking always under account supplier advices.

If EMAL 270D is used (70% a.m.), it is recommended to heat Deionized Water up to 45ºC approx. before adding it, and afterwards to continue with the other components.

If a pearled product is desired, DANOXP-15 or DANOXPL-10 can be added (3-5%).

COMPONENTS

AKYPO RLM 100 (Laureth-11 Carboxylic acid, 95 % a.m.): crypto-anionic character, it combines the properties of theanionic and non-ionic surfactants. Foaming co-surfactant, with solubilizing properties and very mild for the skin.

AMIDET APA-22 (Behenamidopropyl Dimethylamine, 100% organic matter): non-ionic character. High conditioning

surfactant at acid pH, with substantive properties. It provides smoothness and anti-static effect to the hair. It also acts as a

thickener in shampoo formulations.


BETADETHR (Cocamidopropyl Betaine, 35% dry matter) : amphoteric character. Secondary surfactant. It decreases the

irritation level of the anionic surfactants on the skin , improving level and quality of the foam. Additional thickening affect.

EMAL 227E (Sodium Laureth Sulfate, 27% a.m.) : anionic character. Primary surfactant, highly foaming. Good detergentproperties.


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EASY COMBING

DESCRIPTION

Hair easy to comb

Very mild formulation

Highly foaming

COMPOSITION %

EMAL 270D (1) 12.0

BETADET HR 3.0

BETADET S-20 4.0

LEVENOL H&B 1.5

TETRANYL C0-40 0.5

DANOX PL-10 3.0Dye(s) q.s.Preservative q.s.Fragrance q.s.Sodium Chloride q.sNaOH (10% solution) q.s. (pH adjust = 6.0 – 6.5)


(1) 12% of EMAL 270D (SLES at 70% a.m.) can be substituted by 31.7% of EMAL 227E (SLES at 27% a.m.).


Kao Method

APPEARANCE (20ºC) : White Pearled Liquid KCSA-258


pH (100%) : 6.0 - 6.5 KCSA-014







2REFERENCE :

UP-DATED: PRINTED :

C402.001

2010-09-092010-09-09


Disperse EMAL270D into water at 45-50ºC to facilitate its incorporation.

Add BETADETHR, BETADETS-20, LEVENOLH&B and TETRANYLCO-40 in this order until clear.

Add the pearlizing agent DANOXPL-10 until fullydispersed.


Adjust pH (it is recommended to use citric or lactic acid to decrease it, diluted Sodium Hydroxide if an increase is necessary).

Adjust the final viscosity using Sodium Chloride until desired level.

COMMENTS

In case of using EMAL 227E, there is no need to heat the initial water at 45-50ºC.

COMPONENTS

BETADE HR (Cocamidopropyl Betaine, 35% dry matter) : amphoteric character. Secondary surfactant. It decreasesT

the irritation level of the anionic surfactants on the skin , improving level and quality of the foam. Additional thickening affect.

BETADE S-20 (Lauryl Hydroxysultaine, 38% a.m.): amphoteric character. Very mild co-surfactant. It decreases theT

irritation level of anionic surfactants, improving the quality of the foam and performing also as a thickener. It improves the stability of the formula at extreme pH’s and low temperature.

DANOX PL-10 (pearling concentrate, 52% dry matter) : anionic and non-ionic character. Nitroso-amines free product (its











Additives: other conditioning agents like proteins or silicones or derivatives, cationic polymers, etc.

Fragrance : in accordance with the idea of a conditioning product. It can affect to the final viscosity of the formula. Add it always at low temperature. (<35 - 40ºC). Use % = between 0.1 - 0.5%.


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MILD

DESCRIPTION

Mild shampoo



Reduces fly away effect from combing

COMPOSITION %

EMAL227E (1)32.0

BETADET S-20 8.0

LEVENOL H&B 2.0

AMIDET APA-22 0.5

Perfume q.s.Preservative q.s.Additives q.s.Citric Acid q.s. (pH adjust = 6.0 – 7.0)

Sodium Chloride q.s. (viscosity adjust)



TECHNICAL CHARACTERISTICSKao Method


VISCOSITY BROOKFIELD (20ºC,cPs) : 3700 (0% NaCl) KCSA-227

pH (100%) : 6.0 - 7.0 KCSA-014

CLOUD POINT (ºC) : - 12 KCSA-246







2REFERENCE: UP-DATED:

PRINTED :

C407

2005-03-03

2005-03-03


Add EMAL227E to the Deionized Water and stir the mixture until homogenous.

Add BETADETS-20 and LEVENOLH&B. Homogenize after each addition.

AMIDETAPA-22 could be added after heating the surfactant base up to 60ºC min. or by

melting it with one of the components.

Below 40ºC add the other additives: preservative (soluble), perfume (15 minutes of agitation are

usually needed to solubilize it), dyes (diluted in water), other (extracts, etc).

Adjust pH (it is recommended to use citric or lactic acid, and diluted sodium hydroxide if an

increase is necessary).

Adjust the final desired viscosity using sodium chloride.

COMMENTS

If high conditioning effect is desired, other type of components can be added (extracts, protein

hydrolizates, cationic polymers, etc) taking always under account supplier advises.

If EMAL 270E is used (70% a.m.), it is recommended to heat deionised water up to 45ºC

approx. before adding it, and afterwards to continue with the other components.

If a pearled product is desired, DANOXP-15 or DANOX PL-10 can be added(3-5%).

COMPONENTS

EMAL 227E (Sodium Laureth Sulfate, 27% a.m.) : anionic character. Primary surfactant, highly foaming. Good detergent

properties.




LEVENOL H&B (Glycereth-2 Cocoate, 100% a.m.): non-ionic character. Extra-mild surfactant, with emulsifying properties.

Skin emollient and moisturizing agent .Foam booster and thickening agent. Ecological product. It doesn’t need any risk or

safety warnings on its label. In hair rinse application increases the conditioning effect of the cationic component, giving

smoothness. % of use in Hair Rinse = between 0.1 - 2%

AMIDET APA-22 (Behenamidopropyl Dimethylamine, 100% a.m.): non-ionic character. High conditioning surfactant atacid pH, with substantive properties. It provides smoothness and anti-static effect to the hair. It also acts as a thickener inshampoo formulations.

The information and recommendations in this publication are to the best of our knowledge reliable. However, nothing herein is to be construed

as a warranty or representation. Users should make their own tests to determine the applicability of such information or the suitability of any

products for their own particularpurpose.

Statements concerning the use of the products described herein are not to be construed as recommending the infringement of an y patent and

no liability for infringement arising out of any such use is assumed.

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MILD & ECO-FRIENDLY

DESCRIPTION

High concentrated, unpreserved raw materials

Low irritancy and high performance formula

Good eco-toxicological profile

Easy combing and detangling effect

Rich and creamy foam and improved smoothness

COMPOSITION %

EMAL 270D (1) 14.5


AMIDET N 2.0

LEVENOL H&B 2.0

AMIDET APA-22 0.4

Panthenol (50% solution) 0.5Fragrance (2) 0.5Hydroxypropyl Guar Trimonium Chloride (3) 0.3Tocopheryl Acetate 0.2NaCl q.s.Citric Acid (50% solution) q.s.Preservative (4) 0.05CI 47005 (1/1000) 0.8CI 42090 (1/1000) 0.4Deionized Water Up to 100%

(1) 14.5% of EMAL 270D (SLES at 70% a.m.) can be substituted by 37.6% of EMAL 227E (SLES at 27% a.m.).

(2) REFINEMENT SK122420 supplied by KAO-Fragrances


(4) Miracare SR 1393 supplied by Thor


Kao Method

APPEARANCE (20ºC) : Clear Green Liquid KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : 6000 – 10000 KCSA-227

pH (100%) : 5.5 - 6.0 KCSA-014






2REFERENCE :

UP-DATED: PRINTED :

C08001/SH-1/2

2010-09-092010-09-09


Add EMAL 270D and AKYPO FOAM RL 40 to water (95% of it) at 50ºC.

Melt AMIDET APA-22 together with AMIDET N and LEVENOL H&B at 80ºC in a separate vessel. Add it to the main batch and mix it until getting a homogeneous and transparent solution.

Add the cationic guar polymer dissolved in the rest of the water.

Cool down to room temperature and add the rest of ingredients.

Adjust pH to 5.5-6.0 with Citric Acid.

Adjust viscosity to 6000-10000 with NaCl.

COMMENTS

Composition based on “Basic Formula” concept (system designed to easily formulate a range of liquid personal care products).

Conditioning effect is achieved when AMIDET APA-22 (eco-friendly conditioner) is added.

COMPONENTS


of the anionic and non-ionic surfactants. Mild foam-booster for Personal Care products. Produces a rapid foam and improves the foam behaviour of cleansing products when used as co-surfactant.

AMIDE APA-22 (Behenamidopropyl Dimethylamine, 100% a.m.): non-ionic character. High conditioning surfactant atT

acid pH, with substantive properties. It provides smoothness and anti-static effect to the hair. It also acts as a thickener in shampoo formulations.




REFINEMENT SK 1224240 (allergen-free fragrance) fruits such as apple, pear and peach play with smooth rose and jasmine on a bed of musk, cedar wood and vanilla (No allergen labelling at 0.5% in wash-off products).






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NORMAL HAIR

DESCRIPTION



Reduces fly-away effect from combing

COMPOSITION %

EMAL 227E (1) 38.0

BETADET HR 10.0

BETADET S-20 3.94

EMANON EV-E 2.0

PEG-12 Dimethicone (2) 0.5

DANOX PL-10 3.0

Guar Hydroxypropyl Trimonium Chloride(3)

0.3

Fragrance (4) 0.4

Preservative (5) 0.05

NaOH (10% solution) q.s. (pH adjust = 6.0 – 7.0)

Sodium Chloride q.s. (0.8 % approx)



(2) Dow Corning 193 Fluid supplied by Dow Corning


(4) Ultrafresh SK130209 supplied by KAO-Fragrances

(5) Isocil PC supplied by Lonza


Kao Method

APPEARANCE (20°C) : White Pearled Viscous Liquid KCSA-258

VISCOSITY BROOKFIELD (20°C, cPs) : 10000 approx. KCSA-227

pH (100%) : 6.0 - 7.0 KCSA-014







REFERENCE : C08011 UP-

DATED : 2010-03-31PRINTED : 2010-03-31

2


Add Guar Hydroxypropyl Trimonium Chloride to the Deionized Water and stir until a homogeneous dispersion is obtained.

Add EMAL 227E, BETADET HR, BETADET S-20, and EMANON EV-E. Homogenize after each addition.

Add PEG-12 Dimethicone and DANOX PL-10. Homogenize after each addition.

Add the rest of additives: preservative (soluble), perfume (15 minutes of agitation are usually needed to solubilize it), dye(s) (diluted in water), other (extracts, etc).

Adjust pH (it is recommended to use citric or lactic acid, and diluted sodium hydroxide if an increase is necessary).


COMMENTS - APPLICATION

If high conditioning effect is desired, other type of components can be added (extracts, protein hydrolizates, cationic polymers, etc) taking always under consideration supplier advises.

If EMAL 270D is used (70% a.m.), it is recommended to heat Deionized Water up to 45°C approx. before adding it, and afterwards to continue with the other components.

Different viscosity levels can be achieved using variable NaCl quantities.

Compared to similar products used as refatting and solubilizing agents as well, like PEG-6-Caprylic/Capric Glycerides, EMANON EV-E has an outstanding effect on the foam (speedformation, volume and creaminess).

EMANON EV-E improves conditioning effect and combing force as well, reducing the strength that has to be applied to comb a tress.

COMPONENTS


EMANO EV-E (Glycereth-7 Caprylate/Caproate, 100% a.m.): non-ionic character. Vegetable based, liquid product.N

Excellent emulsifier and solubilizer for hydrophobic materials, with HLB 17. Suitable for both rinse-off and leave-on products in hair and body applications. Key ingredient to achieve high foam ability and smooth feeling.

BETADE HR (Cocamidopropyl Betaine, 35% dry matter): amphoteric character. Secondary surfactant. It decreases theT

irritation level of the anionic surfactants on the skin, improving level and quality of the foam. Additional thickening affect.




composition doesn’t contain any Nitrogen derivative). It allows modifying the final appearance of the formula, providing itwith a beautiful pearled appearance. No heating is needed. Ecological product. Common use percentage: 3 - 10 %.


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HAIR CARE

DESCRIPTION

Mild shampoo

Improves combing

Highly foaming

COMPOSITION %

EMAL227E (1)42.0

AKYPORLM 45CA 1.74

BETADET THC-2 4.0Hydroxypropyl Guar Hydroxipropyltrimmonium Chloride (2) 0.3PEG-150 Disterate (3) 0.75Dye(s) q.s.Preservative q.s.Fragrance q.s.Sodium Chloride q.s.Citric Acid (10% solution) q.s. (pH adjust= 6.0 – 7.0)


(1) 42% of EMAL227E (SLES at 27% a.m.) can be substituted by 15.9% of EMAL270D (SLES at 70% a.m.).

(2) JaguarC-162 supplied by Rhodia

(3) Aculyn60 supplied by Rohm & Haas Company Inc.


Kao Method



pH (100%) : 6.0 - 7.0 KCSA-014

CLOUD POINT (ºC) : - 4 KCSA-246







REFERENCE:

UP-DATED: PRINTED:

C308 (C-091)

2010-09-092010-09-09

2


Add Hydroxypropyl Guar Hydroxypropyltrimonium Chloride to the water and disperse it. Then add some citric acid until a clear solution is obtained.

In a separate vessel heat the EMAL227E up to 55ºC and then add and disperse PEG-150 Distearate. Continue with the addition of this solution to the previousone.

Add each one of the remaining surfactants, AKYPORLM 45CA and BETADETTHC-2, in the above-mentioned order and stir after each addition.

Adjust pH (it is recommended to use diluted sodium hydroxide to increase it and citric or lactic acids if a pH decrease is necessary).

Add the other additives: preservative (soluble), fragrance (15 minutes of agitation are usually needed to solubilize it), dye(s) (diluted in water) and other (extracts, etc.).


COMMENTS

If EMAL 270D is used, it is recommended to use a separate vessel. Add it to 30% of the totalwater, while stirring and heat up until 45ºC. Once solved disperse PEG-150 Distearate in thesolution. Continue as described in the above operative method adding this blend to the mainvessel, where Hydroxypropyl Guar Hydroxypropyltrimonium Chloride has been already dispersedand acidified in the remaining water.

If a white pearled appearance is desired, a mild pearled base can be added as for example

DANOXPL-10 (3% approx.).

COMPONENTS

AKYPO RLM 45CA (Laureth-6 Carboxylic acid, 95 % a.m.): crypto-anionic character, it combines the properties of theanionic and non-ionic surfactants. Foaming co-surfactant, with solubilizing properties and very mild for the skin.

BETADET THC-2 (Disodium Cocoamphodiacetate, 40% a.m.): amphoteric character. Very mild co-surfactant. It

decreases the irritation level of the anionic surfactants on the skin, improving volume and quality of the foam. Additionalthickening affect.

EMAL 227E (Sodium Laureth Sulfate, 27% a.m.): anionic character. Primary surfactant, highly foaming. Good detergentproperties.


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HAIR CARE

DESCRIPTION

Mild shampoo

Improves combing

Highly foaming


COMPOSITION %

EMAL270D (1)16.2

BETADET THC-2 4.0

AKYPORLM 45CA 1.7

EXCEPARL LM-LC 1.5Hydroxypropyl Guar Hydroxipropyltrimmonium Chloride (2) 0.3Tocopheril Acetate (3) 0.2Dye(s) q.s.Preservative q.s.Perfume q.s.Sodium Chloride q.s.Citric Acid (10% solution) q.s. (pH adjust= 6.0 – 7.0)


(1) 16,2% of EMAL270D (SLES at 70% a.m.) can be substituted by 42% of EMAL227E (SLES at 27% a.m.).

(2) JaguarC-162 supplied by Rhodia

(3) DermofeelE74A produced by Dr. Straetmans


Kao Method

APPEARANCE (20ºC) : Clear Liquid KCSA-258


pH (100%) : 6.0 approx. KCSA-014

STABILITY : Correct (1 month 40ºC/RT/5ºC/cycles)





REFERENCE:

UP-DATED: PRINTED:

C11002_C-169A

2011-05-142011-05-14

2


Add to the Deionized Water, Hydroxypropyl Guar Hydroxypropyltrimonium Chloride and stir well until a homogeneous dispersion is obtained.

Add AKYPO RLM 45CA, BETADETTHC-2, EXCEPARLLM-LC and EMAL 227E stirring after each addition until total homogeneity

Adjust pH (it is recommended to use diluted sodium hydroxide to increase it and lactic acids if a pH decrease is necessary).



COMPONENTS







between 0.3 - 3%


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Silicone-free

DESCRIPTION

Repairing shampoo

Silicone free formula

COMPOSITION %

EMAL 270D 18.6AMIDET N 1.0

BETADET S-20 3.0

BETADET THC-2 1.6

KAO SOFCARE GP-1 0.75

SOFCARE KG-101E 0.8

DANOX PL-10 4.0Preservative q.s.Fragrance q.s.Sodium Chloride q.s.Citric Acid (10% solution) q.s. (pH adjust= 5.0 – 6.0)


(1) 18.6% of EMAL270D (SLES at 70% a.m.) can be substituted by 48.2% of EMAL227E (SLES at 27% a.m.).


Kao Method

APPEARANCE (20ºC) : White Pearled Gel KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : 5500 KCSA-227

pH (100%) : 5.5 KCSA-014






REFERENCE:

UP-DATED: PRINTED:

C15007-U-050814B

2014-03-032014-03-03

2


Heat the water up to 70ºC and add the following ingredients: BETADET® S-20, BETADET® THC-2 and SOFCARE® KG-101E and then stir until completehomogenization.

Cool down the temperature until 40-35ºC.

Add each one of the remaining ingredients, EMAL® 270D, AMIDET® N, KAO® SOFCARE GP-1and DANOX® PL-10 and stir until complete homogenization after each addition.

Add the other additives: preservative (soluble), fragrance (15 minutes of agitation are usually needed to solubilize it), dye(s) (diluted in water) and other (extracts, etc.)


COMPONENTS

AMIDET N (PEG-4 Rapeseedamide , 95% a.m. ): non-ionic character. Nitroso-amines free thickener. It increases the

foam volume and improves the quality of it. It reduces the irritation potential of the anionic surfactants on the skin. Multi-

functional agent.





decreases the irritation level of the anionic surfactants on the skin, improving volume and quality of the foam. Additional

thickening affect.




KAO SOFCARE GP-1 (PPG-3 Caprylyl Ether, 100% a.m) non-ionic character. Clear transparent liquid at room

temperature. Multi-functional conditioning agent that imparts similar characteristics to those of silicones, such as feel andfunctionality. It improves foam generation and hair shine.

SOFCARE KG-101E (cross-linked quaternary copolymer, Polyquaternium-52, 40% cationic a.m.): cationic character.

Provides a slippery feeling on hair during application and rinsing, leaving the hair smooth and detangled. Improves hair

conditioning by reducing combing forces.


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SLES-FREE

DESCRIPTION

Mild formulation with conditioning properties

Good foaming in the presence of sebum

Sulphate-free formula

COMPOSITION %

BETADET HR 37.1SUCCIDET S-30UK 19.3

AKYPOFOAM RL 40 10.0

AMIDETN 4.1PEG-12 Dimethicone (1) 2.0Polyquaternium-37 (2) 2.0Preservative q.s.Citric Acid (50% solution) q.s.

Deionised water Up to 100%

(1) XIAMETEROXF-0193 FLUID (INCI: PEG-12 Dimethicone), supplied by DOW.

(2) (INCI: Polyquartenium-37), supplied by Bonderalia.


Kao Method

APPEARANCE (20ºC) : Clear Liquid KCSA-258


pH (100%) : 5.5 KCSA-014






REFERENCE:

UP-DATED: PRINTED:

C14006 / (C-215C)

2015-07-172017-04-21

2


Add to the Deionised water the Polyquaternium-37 and stir until the solution is clear.

Add BETADETHR, AKYPOFOAM RL 40, SUCCIDETS30 UK and AMIDETN and stir after each addition until complete.

Add PEG-12 Dimethicone and stir until complete homogenization.

Adjust pH (it is recommended to use citric or lactic acid to reduce it and diluted sodium).

Adjust the final desired viscosity using AMIDETN.

COMPONENTS




AMIDET N (PEG-4 Rapeseedamide, 95% a.m.): non-ionic character. Nitroso-amines free thickener. It increases the foamvolume and improves the quality of it. It reduces the irritation potential of the anionic surfactants on the skin. Multi- functionalagent. Previous name : AMINOL N.

BETADET HR (Cocamidopropyl Betaine, 35% dry matter): amphoteric character. Secondary surfactant. It decreases theirritation level of the anionic surfactants on the skin, improving level and quality of the foam. Additional thickening affect.

SUCCIDET S30 UK (Disodium Laureth Sulfosuccinate, 31% a.m.): anionic character. Very mild surfactant with foamingproperties. Used as co-surfactant in baby cleansers.

The information and recommendations in this publication are to the best of our knowledge reliable. However, nothing herein is to be construedas a warranty or representation. Users should make their own tests to determine the applicability of such information or the suitability of anyproducts for their own particular purpose.

Statements concerning the use of the products described herein are not to be construed as recommending the infringement of any patent andno liability for infringement arising out of any such use is assumed.

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SHINY & SILKY

DESCRIPTION

Contains gentle conditioners to help untangle knots and tangles to make the hair easier to comb.

Restores dry and damaged hair, leaving it healthy, shiny,tangle free and manageable.

COMPOSITION %

EMAL 227E 37.0AKYPORLM 45CA 3.3

BETADET HR 10.0

AMIDET N 2.0

KAO SOFCARE GP-1 1.5Polyquaternium-10(1) 0.3Preservative(2) 0.5Silicone(3) 1.25Sodium Chloride q.s.Sodium Hydroxide (10% solution) q.s. (pH adjust= 5.0 – 5.5)


(1) UCARE™ Polymer JR-400 (INCI: Polyquaternium-10), supplied by Dow.(2) Microcare® SB (INCI: Blend of chlorinated and non-chlorinated isothiazolinones and benzyl alcohol), supplied

by THOR(3)Mirasil®ADME-P(INCI:Water(and)Amodimethicone(and)Trideceth-6(and)Methylchloroisothiazolinone),

supplied by Bluestar Silicones


Kao Method

APPEARANCE (20ºC): Clear Viscous Liquid KCSA-258


pH (100%): 5.0 - 5.5 KCSA-014







REFERENCE:

UP-DATED: PRINTED:

C15001- B2-A

2015-05-082015-05-08

2


At room temperature, dissolve the Polyquaternium-10 in water.

Once it is dispersed, add the remaining ingredients and stir until complete homogenization after each addition.

Adjust pH to 5.0-5.5 with Sodium Hydroxide.


COMMENTS

EMAL227E (SLES at 27% a.m.) can be substituted by EMAL270D (SLES at 70% a.m.).


DANOXPL-10 (3% approx.).

KAO SOFCAREGP-1 repairs damaged hair by adsorbing onto the hair surface; improves shine, manageability and volume.

COMPONENTS



EMAL227E (Sodium Laureth Sulfate, 27% a.m.): anionic character. Primary surfactant, highly foaming. Good detergent properties.

KAO SOFCARE GP-1 (PPG-3 Caprylyl Ether, 100% a.m.) non-ionic character. Clear transparent liquid at room

temperature. Multi-functional conditioning agent that imparts similar characteristics to those of silicones, such as feel and functionality. It improves foam generation and hair shine.

BETADETHR (Cocamidopropyl Betaine, 35% dry matter): amphoteric character. Secondary surfactant. It decreases the irritation level of the anionic surfactants on the skin, improving level and quality of the foam. Additional thickening affect.


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CREAMY & SOFT SHAMPOO

DESCRIPTION

Outstanding creamy and soft foam

Useful for normal and/or damaged hair

Sulfate-free

Easily rinsed

COMPOSITION %

AKYPO® FOAM LM 25 28.0

BETADET® HR 19.2

KAO SOFCARE®GP-1 0.6

KAOPAN®TW-IS399S 0.5

Perfume DEEP SHINE SS151160(1) 0.5

Polyquaternium-37(2) 5.0

Silicone Quaternium-16(3) 2.4

Preservative(4) 0.2

Citric acid e.q.


(1) Kao Fragrance

(2) Syntran® PC 5320, supplied by Interpolymer(3) Dow® Corning CE-7114 silicone, supplied by Dow Corning(4) Microcare® SB, supplied by Thor


Kao Method

APPEARANCE (20ºC) : White viscous gel KCSA-258

BROOKFIELD VISCOSITY (20ºC, cPs) : ≈ 17400 KCSA-227

pH (as it is) : 5.0-5.5 KCSA-014





REFERENCE: C17009/CH-2

UP-DATED: 2018-04-06PRINTED: 2018-04-06

2


Solubilize the Polyquaternium-37 with water at room temperature

After complete solubilization, add the AKYPO® FOAM LM 25 and BETADET® HR. Stir after

each addition until the mixture is homogeneous.

Add KAO SOFCARE® GP-1.

Continue with the addition of Silicone Quaternium-16.

Adjust pH with citric acid to 5.0 - 5.5

Add preservative and fragrance.

Add KAOPAN® TW-IS399S to adjust viscosity.

COMPONENTS

AKYPO FOAM LM 25 (Potassium Laureth-4 Carboxylate, 60% a.m.): anionic character. Primary surfactant. Offers a soft

and creamy foam, very stable and with special texture. Very mild and easy to thicken surfactant. Specially designed for

sulfate-free formulations.



temperature. Multi-functional conditioning agent that imparts similar characteristics to those of silicones, such as feel and

functionality. It improves foam generation and hair shine.

KAOPAN TW-IS399S (PEG-160 Sorbitan Triisostearate, 75% a.m.): non-ionic character. Liquid thickener for any type of

cleansing surfactant systems. Specially designed to increase viscosity of sulfate-free formulations. Processable at room

temperature.


1

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EXTRA MILD SHAMPOO

CLEAR OR PEARLED

DESCRIPTION

Extra mild shampoo

Specially recommended for babies and children

Good ratio price / quality

COMPOSITION

CLEAR PEARLED% %

EMAL 270D (1) 12.0 12.0

LEVENOL H&B 2.0 2.0

BETADET S-20 7.5 7.5

AMIDET N 1.0 1.0

DANOX PL-10 - 3.0

Perfume (2) 0.3 0.4EDTA.Na2 0.05 0.05Preservative q.s. q.s.Additives q.s. q.s.Citric Acid q.s. q.s. (pH adjust: 6.0 –7.0)

Sodium Chloride q.s. q.s. (viscosity adjust)

Deionized Water Up to 100% Up to 100%

(1) 12% of EMAL 270D (SLES at 70% a.m.) can be substituted by 31.5% of EMAL 227E (SLES at 27% a.m.).

(2) HEAD PS 92724 supplied by KAO-Fragrances


CLEAR PEARLED Kao Method

APPEARANCE (20ºC) : Clear Viscous Pearled KCSA-258Liquid Viscous Liquid

VISCOSITY BROOKFIELD (20ºC,cPs) : 3000 approx. 10000 approx. KCSA-227

pH (100%) : 6.0 – 7.0 6.0 – 7.0 KCSA-014

DRY MATTER (%) : 15 approx. 17 approx. KCSA-092

STABILITY : Correct Correct (1 month 40ºC/RT/5ºC)





2REFERENCE :

UP-DATED: PRINTED :

C308 001

2010-09-092010-09-09


Heat the Deionized Water up to 45ºC approx. in order to dissolve quicker EMAL 270D. When themixture is clear, add each component keeping the above mentioned order and stirring after eachaddition until total homogeneity.

Add the other additives: preservative (soluble), perfume (15 minutes of agitation are usuallyneeded to solubilize it), dyes (diluted in water), other (extracts, etc.).

Adjust pH (it is recommended to use citric or lactic acid, and diluted sodium hydroxide if anincrease is necessary)

Adjust the final desired viscosity using sodium chloride

COMMENTS

If high conditioning effect is desired, other type of components can be added (extracts, protein hydrolizates, cationic polymers, etc.), taking always under account supplier advises.

COMPONENTS




irritation level of anionic surfactants, improving the quality of the foam and performing also as a thickener. It improves thestability of the formula at extreme pH’s and low temperature.





properties. Skin emollient and moisturizing agent .Foam booster and thickening agent. Ecological product. It doesn’t needany risk or safety warnings on its label. In hair rinse application increases the conditioning effect of the cationic component,



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FORTIFYING SHAMPOO

VERY MILD

DESCRIPTION

Shampoo that prevents hair loss and fortifies the hair

For frequent use


COMPOSITION %

EMAL 270D (1) 14.3

AKYPO SOFT 100 BVC 5.7

BETADET S-20 5.0

LEVENOL H&B 2.0Hair Loss Prevention (2) 2.0Hydrolyzed Pea Protein (3) 2.0Fragrance q.s.Preservative (Isothiazolinone type, 1.5% act) 0.05pH control q.s. (pH adjust= 5.5 – 6.0)


(1) 14.3% of EMAL 270D (SLES, 70% a.m.) can be replaced by 37% of EMAL 228HP (SLES, 27% a.m.).

(2) Hair Loss Prevention supplied by Greentech (Impex Química, Azelis Group)

(3) Promois WJ supplied by Seiwa Kasei (Impex Química, Azelis group)


Kao Method


VISCOSITY BROOKFIELD (20ºC,cPs) : 7000 approx. (2.5% NaCl) KCSA-227

pH (100%) : 5.5 - 6.0 KCSA-014

STABILITY : Correct 2 months 40ºC/RT/5ºC/-5ºC





REFERENCE : C08014/HL-1

UP-DATED: 2008-06-20PRINTED : 2010-01-26

2


Add to the Deionized Water each component in the order indicated. Stir until the mixture is homogeneous after each addition.


Adjust pH (it is recommended to use diluted citric acid to reduce it and diluted NaOH if an increase is necessary) and final desired viscosity using Sodium Chloride.


If high conditioning effect is desired, other type of components can be added (cationic polymers, silicones, etc) taking always under consideration supplier advises.

Different viscosity levels can be achieved using variable NaCl quantities.

COMPONENTS


AKYP SOFT 100 BVC (Sodium Laureth-11 Carboxylate 70 % a.m.): crypto-anionic character, it combines theO

properties of the anionic and non-ionic surfactants. Foaming co-surfactant, with solubilizing properties and very mild for theskin.







Hair Loss Prevention (Water, Propylene Glycol, Thymus Vulgaris Extract, Zea Mays (Corn) Gluten Protein, Calcium

Panthothenate, Pyridoxine Hudrochloric): hydroglycolic extract. It is used to stop hair loss by revitalizing dermal papilla cells.

It supplies energy and nourishing elements and decreases hyper-seborrhoea.


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FORTIFYING SHAMPOO

HAIR LOSS PREVENTION

DESCRIPTION

Mild shampoo

Improves combing

Highly foaming

COMPOSITION %

EMAL 270D(1)14.3

AKYPOSOFT 100 BVC 5.7

BETADET S-20 5.0

LEVENOL H&B 2.0Hair Loss Prevention Additive(2) 2.0Promois WJ(3) 2.0pH modifier q.s.NaCl 2.5Preservative 0.05


(1) 14.3% of EMAL 270D (SLES at 70% a.m.) can be substituted by 37% of EMAL 227E (SLES at 27% a.m.)

(2) Hair Loss Prevention Additive supplied by GreenTech

(3) Promois WJ supplied by Seiwa Kansei


Kao Method



pH (100%) : 6 approx KCSA-014






REFERENCE: C08014 – HL1

UP-DATED: 2013-09-19PRINTED: 2013-09-19

2


Add to the deionised water each component in the above-mentioned order and stir after eachaddition until total homogenization. If EMAL 270D is used, it’s recommended to heat the water upto 60ºC to help incorporate the product. After the addition, no more heating is needed.

Adjust pH and viscosity

COMPONENTS


AKYPO SOFT 100 BVC (Sodium Laureth-11 Carboxylate 70 % a.m.): crypto-anionic character, it combines the

properties of the anionic and non-ionic surfactants. Foaming co-surfactant, with solubilizing properties and very mild for the

skin.




LEVENOL H&B (Glycereth-2 Cocoate, 100% a.m.): non-ionic character. Extra-mild surfactant, with emulsifying properties.

Skin emollient and moisturizing agent .Foam booster and thickening agent. Ecological product. It doesn’t need any risk orsafety warnings on its label. In hair rinse application increases the conditioning effect of the cationic component, giving

smoothness. % of use in Hair Rinse = between 0.1 - 2%


GUIDELINE FORMULARY


Puig delsTudons,10 -E-08210 - BarberàdelVallès

1


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e-mail: [email protected]: www.kaochemicals-eu.com

FORTIFYING SHAMPOO

VERY MILD

DESCRIPTION

Mild shampoo

For frequent use

Highly foaming


COMPOSITION %

EMAL270 D(1)14.3


BETADETS-20 5.0

LEVENOL H&B 2.0

EXCEPARL LM-LC 1.5Hair Loss Prevention (2) 2.0Hydrolysed Pea Protein (3) 2.0Sodium Chloride q.s.Perfume q.s.Preservative q.s.


(1) 14,3% of Emal 270D (SLES, 70%) can be replaced by 37,1% of Emal 227E (SLES, 27%)

(2) Hair Loss Prevention supplied by Greentech (Impex Química, Azelis Group)

(3) Promois WJ supplied by Seiwa Kasei (Impex Química, Azelis group)


Kao Method

APPEARANCE (20ºC) : Clear Gel KCSA-258


pH (100%) : 5.5 KCSA-014






REFERENCE: C-11002_C-161A

UP-DATED: 2012-05-14PRINTED: 2012-05-14

2


Add to the Deionized Water each component in the order indicated. Stir well after each addition until a homogeneous dispersion is obtained.


Adjust pH (it is recommended to lactic acid to reduce it and diluted NaOH (if an increase is necessary) and final desired viscosity using sodium chloride.

COMPONENTS




skin.









between 0.3 - 3%

The information and recommendations in this publication are to the best of our knowledge reliable. However, nothingherein is to be construed as a warranty or representation. Users should make their own tests to determine the applicabilityof such information or the suitability of any products for their own particular purpose.Statements concerning the use of the products described herein are not to be construed as recommending theinfringement of any patent and no liability for infringement arising out of any such use is assumed.

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HAIR CONDITIONER – LEAVE ON

SPRAY APPLICATION

DESCRIPTION

No rinse needed

Improves combing

Improves hair manageability

COMPOSITION %

TETRANYL CO-40 1.7LEVENOL H&B 0.5Propylenglycol 2.0Polysorbate-80 0.5Dye(s) q.s.Preservative q.s.Fragrance q.s.NaOH (10% solution) q.s. (pH adjust = 4.5 approx)



Kao Method

APPEARANCE (20ºC) : Opaque White Liquid KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : < 100 KCSA-227

pH (100%) : 4.7 approx. KCSA-014


STABILITY : Correct (2 months 40ºC/RT/5ºC)





REFERENCE:

UP-DATED: PRINTED:

C10001 (C-007/5A)

2010-09-092010-09-09

2


Add Deionized Water to the main vessel.

In a separate vessel, mix Propylenglycol, Polysorbate-80 and TETRANYLCO-40. This mixture has a milky appearance.

Add previous mixture to the water under stirring and add LEVENOLH&B afterwards.


Adjust pH (it is recommended to use diluted sodium hydroxide to increase it and citric or lactic acid if a pH decrease is necessary).

COMMENTS

Operative method is highly influencing on the final formula stability. It has to be kept as similar as the one above described.

COMPONENTS






surfactant, under liquid form. It provides smoothness, shine and anti-static properties to the hair, making easy to comb it. Itdoesn't present cumulative effect. Environmentally friendly cationic surfactant.


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HAIR CONDITIONER

DESCRIPTION

Hair becomes smooth and easy to comb

Good fly-away control

Fulfill EU Ecolabel criteria

COMPOSITION %

KALCOL 6850 4.5

QUARTAMIN BTC-131 2.5

TETRANYL CO-40 1.3

Quaternium-80 (1) 1.0

Panthenol (50% solution) 0.5

Tocopheryl Acetate 0.3

Methoxy PEG/PPG-7/3 Aminopropyl Dimethicone(2)

0.5

Perfume (3) 0.5


Sodium Hydroxide (10% solution) q.s.


(1) Abil Quat 3272 supplied by Evonik-Goldshmidt

(2) Abil Soft AF-100 supplied by Evonik-Goldshmidt

(3) FRUCTAPLUS SK122422 supplied by Kao Fragrances

(4) Miracare PM5 supplied by Thor


Kao Method

APPEARANCE (20ºC) : White Viscous Emulsion KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : > 6700 KCSA-227

pH (100%) : 4.0 - 4.5 KCSA-014






2REFERENCE:

UP-DATED: PRINTED :

2010-09-09

2010-09-09


Heat water up to 80ºC and add TETRANYLCO-40, Methoxy PEG/PPG-7/3 Aminopropyl

Dimethicone and KALCOL6850. Stir at high speed rate during 30 minutes.

Cool down to 65ºC. Add QUARTAMINBTC-131 and Quaternium-80. Again, homogenize during 30 minutes at high speed rate. Add preservatives.

Cool down to 40ºC at low speed rate at a cooling rate of 0.5ºC/minute.

Add the rest of ingredients.

Adjust pH with Sodium Hydroxide to 4.0 - 4.3

COMMENTS

TETRANYLCO-40 and QUARTAMINBTC-131, are eco-friendly products (eco-labelled products).

Outstanding combing force reductions are obtained when combining both products

These two surfactants can efficiently emulsify hydrophobic silicones, improving sensorial attributes.

COMPONENTS


QUARTAMIN BTC-131 (Behenoyl PG-Trimonium Chloride, 70% a.m.): cationic character. Conditioning surfactant. It

provides smoothness, shine and anti-static properties to the hair, making easy to comb it. It doesn't present cumulative

effect. Environmentally friendly cationic surfactant.




FRUCTAPLUS SK122422 (Allergen-free fragrance) fresh lemon and fruit complex of apple, peach and exotic fruits blend

well with cyclamen, rose and jasmine. The all is wrapped by warm sandalwood (No allergen labelling at 0.5% in wash-off

products).


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HAIR CONDITIONER

NORMAL HAIR

DESCRIPTION

Conditioning and smoothing product for the hair


Hair becomes shiny and with anti-static properties

After its application combing becomes easier (wet - dry conditions)

Easily rinsed

Non cumulative

COMPOSITION %

TETRANYL CO-40 0.94

AMIDET APA-22 0.61

KALCOL 6850 2.5Isopropyl Myristate 0.5

Lactic Acid (90% solution) 0.15

Preservative (1)0.2

Fragrance q.s.


(1) Glydant Plus supplied by Lonza


Kao Method


BROOKFIELD VISCOSITY (20ºC, cPs) : 9500 KCSA-227

pH (100%) : 4.0 - 4.3 KCSA-014





REFERENCE :

UP-DATED : 2010-03-31PRINTED : 2010-03-31

2


Start with the 50% of the water needed in the formulation. Heat it up to 60ºC and add Lactic Acid.

Add AMIDET APA-22 and KALCOL 6850 pre-melted together at 80ºC.

Continue with the addition of TETRANYL CO-40 and Isopropyl Myristate. Stir at 250 rpm during 30 minutes.

Add the rest of the water at room temperature (25ºC approx.) and stir at around 150 rpm.

Add preservative, fragrance and dye(s) at temperature below 40ºC.

Adjust pH with Lactic Acid to 4.0 - 4.3.

COMMENTS

TETRANYL CO-40 and AMIDET APA-22 are eco-friendly surfactants.

Lactic Acid is the acid recommended to acidify AMIDET APA-22 and assure its best stability and performance.

Final viscosity of the product can be increased adding more quantity of KALCOL 6850.

Isopropyl Myristate is an emollient for the skin and hair. It gives shine and smoothness.

Other additives (silicones, cationic polymers, natural extracts, etc) can be added to this basic hair conditioner composition, if some additional benefits want to be claimed.

COMPONENTS


acid pH, with substantive properties. It provides smoothness and anti-static effect to the hair. It also acts as a thickener inshampoo formulations.

KALCOL 6850P (Cetearyl Alcohol, C1618:50/50 approx., 100% a.m.): non-ionic character. Co-emulsifier and thickener.Low substantive conditioning properties. Typical % of use = between 1 - 5%.


surfactant, under liquid form. It provides smoothness, shine and anti-static properties to the hair, making easy to comb it. Itdoesn't present cumulative effect. Environmentally friendly cationic surfactant.


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HAIR CONDITIONER

(Normal Hair)

DESCRIPTION

Conditioning and smoothing product for the hair


Hair becomes shiny and with anti-static properties

After its application combing becomes easier (wet - dry conditions)

Easily rinsed

Non cumulative

COMPOSITION %

TETRANYL CO-40 0.94

AMIDET APA-22 0.61

KALCOL 6870P 2.5

Isopropyl Myristate (1) 0.5

LEVENOL H&B 0.5

Lactic acid (90%) 0.15


Fragrance e.q.

Deionised water Up to 100

(1) Waglinol 6014 supplied by Lasem

(2) GlydantTM PLUS supplied by Lonza


Kao Method

APPEARANCE (20ºC) : White viscous emulsion KCSA-258

BROOKFIELD VISCOSITY (20ºC, cPs) : 5000 - 6000 KCSA-227

pH (as it is) : 4.0 - 4.5 KCSA-014





REFERENCE: C11016-B 2

UP-DATED: 2011-06-30

PRINTED: 2011-06-30


Start with the 50% of the water needed in the formulation. Heat it up to 60ºC and add lactic acid.

Add AMIDETAPA-22 and KALCOL6870P pre-melted together at 80ºC.

Continue with the addition of TETRANYLCO-40 and Isopropyl Myristate. Stir at 250 rpm during 30 minutes.

Cool down to 30ºC (if possible, at 0,5ºC/min)

Add the rest of the water at room temperature (25ºC approx.) and stir at around 150 rpm.

Add LEVENOLH&B, preservative, fragrance and dye(s) at temperature below 40ºC.

Adjust pH with lactic acid to 4.0 - 4.5.

COMMENTS

TETRANYLCO-40 and AMIDETAPA-22 are eco-friendlysurfactants.

Lactic acid is the acid recommended to acidify AMIDETAPA-22 and assure its best stability and performance.

Final viscosity of the product can be increased adding more quantity of KALCOL6870P

Isopropyl Myristate is an emollient for the skin and hair. It gives shine and smoothness.

Other additives (silicones, cationic polymers, natural extracts, etc) can be added to this basic hair conditioner composition, if some additional benefits want to be claimed.

COMPONENTS




KALCOL 6870P (Cetearyl Alcohol, C1618:75/25 approx., 100% a.m.): non-ionic character. Co-emulsifier and thickener.Low substantive conditioning properties. Typical % of use = between 1 - 5%.








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HAIR CONDITIONER

BASIC HAIR CARE

DESCRIPTION

Specially designed for natural hair



COMPOSITION %

DANOXHC-30 4.7Preservative (1) 0.2Fragrance(2) 1.0Lactic Acid (10% solution) q.s. (pH adjust= 3.5 – 4.0)

Deionised Water Up to 100%

(1) Glydant® Plus (INCI: DMDM Hydantoin (and) Iodopropynyl Butylcarbamate), supplied by Lonza.

(2) SMOOTH HAIR SS148692 supplied by KAO-Fragrances.


Kao Method

APPEARANCE (20ºC): White Viscous emulsion KCSA-258


pH (100%): 3.5 - 4.0 KCSA-014







REFERENCE:

UP-DATED: PRINTED:

C15001-Hair conditioner

2015-05-072015-05-07

2


Heat water up to 75ºC and add DANOX HC-30.

Homogenize at high speed rate, stirring during 30 minutes.

Cool down to room temperature at low speed rate.

Add the rest of the ingredients below 40ºC. Stir until homogeneous after each addition.

Adjust pH to 3.5-4.0 with Lactic Acid.

COMMENTS

DANOX® HC-30 provides excellent detangling and high reduction of combing forces, improved hair smoothness and good control of fly-away.

If higher viscosities are needed, it is recommended to change the process by using 50% of the water initially and the rest to cool down the product.

COMPONENTS

DANOX HC-30 (surfactant blend, 100% d.m., 33% cationic a.m.): cationic and non-ionic character. It´s based on a

synergistic combination of cationic surfactants and fatty alcohol that allows single-step formulation providing an excellent performance in hair conditioning formulations. It provides smoothness and anti-static properties to the hair. Environmentally

friendly cationic blend.


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HAIR CONDITIONER

SMOOTHING

DESCRIPTION

Specially designed for damaged hair

Hair becomes smooth and silky, easy to comb

Good fly-away control and improved softness

COMPOSITION %

DANOXHC-30 4.0Dimethicone (60000cSt) (1) 1.0Cetyl Hydroxyethylcellulose (2) 0.015Preservative(3) 0.5Lactic Acid (10% solution) q.s. (pH adjust= 3.5 – 4.0)


(1) XIAMETER® PMX-200 SILICONE FLUID 60000cSt, supplied by Dow Corning.

(2) NATROSOL® Plus 331, supplied by Ashland.

(3) Microcare® SB (INCI: Water (and) Sodium Benzoate (and) Potassium Sorbate), supplied by Thor.


Kao Method



pH (100%): 3.5 - 4.0 KCSA-014







REFERENCE:

UP-DATED: PRINTED:

C15007-C6

2015-05-072015-05-07

2


Disperse Cetyl Hydroxyethylcellulose in water at room temperature.

Heat the mixture up to 75ºC , add DANOXHC-30 and homogenize.

Add Dimethicone and homogenize at high speed rate, stirring during 30 minutes.




COMMENTS



COMPONENTS


synergistic combination of cationic surfactants and fatty alcohol that allows single-step formulation providing an excellent performance in hair conditioning formulations. It provides smoothness and anti-static properties to the hair. Environmentally



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HAIR CONDITIONER

NOURISHING

DESCRIPTION

Specially developed to reduce and repair dry and stressed hair.

Hair becomes smooth and silky, easy to comb

Good fly-away control and improved softness

COMPOSITION %

DANOXHC-30 4.0Dimethicone (60000cSt) (1) 1.0

KALCOL 6098 0.6

KALCOL 8098 0.9Lactic Acid (10% solution) q.s. (pH adjust= 3.5 – 4.0)



(1) XIAMETER® PMX-200 SILICONE FLUID 60000cSt, supplied by Dow Corning.

(2) Microcare® SB (INCI: Water (and) Sodium Benzoate (and) Potassium Sorbate), supplied by Thor.


Kao Method

APPEARANCE (20ºC): White Viscous Emulsion KCSA-258


pH (100%): 3.5 - 4.0 KCSA-014

DRY MATTER (%): 6.5 approx. KCSA-092

STABILITY TEST: Correct (1 month 40ºC/RT/5ºC)





REFERENCE: C15007-C-3

UP-DATED: 2015-05-07PRINTED: 2015-05-07

2


Heat water up to 75ºC.

In a separate vessel, melt DANOXHC-30, KALCOL6098, KALCOL8098 and Dimethicone. Once it is homogeneous, add the mixture to the main vessel.





COMMENTS



COMPONENTS


synergistic combination of cationic surfactants and fatty alcohol that allows single-step formulation providing an excellent

performance in hair conditioning formulations. It provides smoothness and anti-static properties to the hair.

Environmentally friendly cationic blend.

KALCOL 6098 (Cetyl Alcohol, 100% a.m.): non-ionic character. Co-emulsifier and thickener. Low substantiveconditioning properties. Typical % of use = between 1 - 5%.



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HAIR CONDITIONER

DAMAGED HAIR

DESCRIPTION

Specially designed for damaged hair

Hair becomes smooth and silky.

Facilitates detangling and provides fly-away control.

COMPOSITION %

DANOX HC-30 5.0

KAO SOFCARE GP-1 0.5Dimethicone (60000cSt)(1) 1.0Preservative(2) 0.5Lactic Acid (10% solution) q.s. (pH adjust= 3.5 – 4.0)


(1) Mirasil® DM 60000 (INCI: Dimethicone (60000cSt) ), supplied by BluestarSilicones.

(2) GlydantTM PlusTM (INCI: DMDM Hydantoin (and) Iodopropynyl Butylcarbamate), supplied by Lonza.


Kao Method

APPEARANCE (20ºC): White Viscous Emulsion KCSA-258


pH (100%): 3.5 - 4.0 KCSA-014

DRY MATTER (%): 6.5 approx. KCSA-092

STABILITY TEST: Correct (1 month 40ºC/RT/5ºC)





REFERENCE:

UP-DATED: PRINTED:

C15001- B1-A

2015-05-082015-05-08

2


Heat water up to 75ºC. Add DANOX HC-30 and stir for 30 minutes at high speed rate.

Add Dimethicone and homogenize at high speed rate, stirring during 30 minutes.

Cool down at 0.3ºC/min at a low stirring speed.

Add KAO SOFCARE GP-1 below 55ºC.

At room temperature add the preservative and the additives.


COMMENTS



KAO SOFCARE GP-1 repairs damaged hair by adsorbing onto the hair surface; improves shine, manageability and volume.

COMPONENTS


synergistic combination of cationic surfactants and fatty alcohol that allows single-step formulation providing an excellentperformance in hair conditioning formulations. It provides smoothness and anti-static properties to the hair. Environmentally


KAO SOFCARE GP-1 (PPG-3 Caprylyl Ether, 100% a.m) non-ionic character. Clear transparent liquid at room




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HAIR CONDITIONER

DAMAGED HAIR

DESCRIPTION




COMPOSITION %

TETRANYLL6-30 8.0Preservative (1) 0.2Lactic Acid q.s. (pH adjust= 3.5 – 4.5)




Kao Method



pH (100%): 3.5 - 4.5 KCSA-014







2REFERENCE:

UP-DATED: PRINTED :

C15001 L / T-2

2015-10-072015-10-07


Heat water up to 70ºC and add TETRANYL L6-30.




Adjust pH at 3.5-4.5 with Lactic Acid.

COMMENTS

TETRANYL® L6-30 is an eco-friendlysurfactant.

Final viscosity of the product can be increased by adding KALCOL6850.

Other additives (silicones, cationic polymers, natural extracts, etc.) can be perfectly added in

combination with TETRANYL L6-30.


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HAIR CONDITIONER

NORMAL HAIR

DESCRIPTION




COMPOSITION %

TETRANYLL6-30 5.0Preservative (1) 0.2Lactic Acid q.s. (pH adjust= 3.5 – 4.5)




Kao Method



pH (100%): 3.5 - 4.5 KCSA-014







2REFERENCE:

UP-DATED: PRINTED :

C15001 L / T-1

2015-10-072015-10-07


Heat water up to 70ºC and add TETRANYL L6-30.




Adjust pH at 3.5-4.5 with Lactic Acid.

COMMENTS

TETRANYL® L6-30 is an eco-friendlysurfactant.

Final viscosity of the product can be increased by adding KALCOL6850.

Other additives (silicones, cationic polymers, natural extracts, etc.) can be perfectly added in

combination with TETRANYL L6-30.


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HIGH FOAMING SULFATE-FREE

SHAMPOO

DESCRIPTION

Sulfate-free shampoo

Mild and high foaming

Improves hair condition

COMPOSITION %


BETADET S-20 11.6

RHEODOL TW-IS399C 1.0

KAO SOFCARE GP-1 0.6Perfume DEEP SHINE SS151160 (1) 0.5Polyquaternium-37 (2) 5.0Silicone Quaternium-16 (3) 2.4Preservative (4) 0.5Citric Acid (50% solution) q.s (pH adjust = 5.0-5.5)

Deionized water Up to 100%

(1) Kao fragrance

(2) Syntran PC 5320, supplied by Bonderalia

(3) Dow Corning 5-7113 Silicone Quat Microemulsion, supplied by Dow Corning

(4) Microcare SB, supplied by Thor


Kao Method

APPEARANCE (20ºC) : Yellowish clear viscous liquid KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : 1200 - 1500 KCSA-227

pH (100%) : 5.0 - 5.5 KCSA-014






2REFERENCE :

UP-DATED: PRINTED :

C15008/20-41

2016-03-312016-03-31


Charge DeionizedWater.

Add Polyquaternium-37, stirring until total homogeneity.

Add BETADET S-20, stirring until total homogeneity.

Add AKYPO FOAM RL 40, stirring until total homogeneity.

Add KAO SOFCARE GP-1, stirring until total homogeneity.

Add LEVENOL H&B and Silicone Quaternium-16. Stir after each addition until total homogeneity.

Prepare a solution of max. 75% RHEODOL TW-IS399C in water, and add the equivalent quantity.

Add perfume and preservative. Stir after each addition until homogeneous.

Adjust pH to 5.0 - 5.5 with citric acid 50%.

COMPONENTS


of the anionic and non-ionic surfactants. Mild foam-booster for Personal Care products. Produces a rapid foam andimproves the foam behaviour of cleansing products when used as co-surfactant.



RHEODOL TW- IS399C (PEG-160 Sorbitan Triisostearate 100% a.m.): non-ionic character. Multi purposes thickening

agent for body/facial wash, shampoo and hair conditioner, etc. Gives higher viscosity with less dosage. Super resistant to

hydrolysis and good compatibility for any formulation. Very suitable for sulfate-free cleansing formulations.





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LEAVE-IN CONDITIONER

TRANSPARENT

DESCRIPTION

Light conditioning for hair

No rinse needed

Easy to apply

COMPOSITION %

OXIDET DMCLD 1.0GLC-99% 1.0AMIDET APA-22 0.5

Lactic Acid 90% 0.12KAO SOFCARE GP-1 0.5D-Panthenol 50% (1) 0.5Hydroxypropyl Guar Hydroxypropyl Trimonium Chloride (2) 0.3Benzophenone-4 (3) 0.25Preservative q.sFragrance q.sLactic Acid (50% solution) q.s (pH adjust = 3.5 – 4.0)


(1) Provit® 50, supplied by BASF(2) Jaguar® C-162, supplied by Rhodia(3) Uvinul® M40, supplied by BASF


Kao Method

APPEARANCE (20ºC) : Transparent Liquid KCSA-258


pH (100%) : 3.5 - 4.0 KCSA-014

CATIONIC ACTIVE MATTER (%) : 0.6 approx KCSA-003

STABILITY : Correct (2 months 40ºC/RT/5ºC/cycles)





REFERENCE:

UP-DATED: PRINTED:

C15001/C-241 A/2

2015-10-192015-10-19

2


Heat water up to 80ºC and disperse Jaguar C-162.

Add the Lactic Acid and then AMIDETAPA-22 under stirring, avoiding air incorporation.

Once the mixture is clear, add OXIDETDMCLD under stirring.

Stir until homogeneous and start to cool down to room temperature.

Below 40ºC, add Panthenol 50%, KAO SOFCAREGP-1, Glycerine (GLC 99%) and Benzophenone-4. Homogenize well after each addition.

Adjust pH to 3.5 – 4.0 with Lactic Acid 50%.

COMMENTS

FINDETARH/52 (PEG-40 Hydrogenated Castor Oil) can be added in formulation to increase the fragrance solubility.

COMPONENTS







GLC 99% (Glycerine): solvent. Emollient to the skin and hair. Normal % of use between 0.5 and 4%.

OXIDET DMCLD (Cocamine Oxide, 30% a.m.): non-ionic/cationic character (depending on the pH). Stable at acidic and alkaline media. Conditioning and solubilizing agent. Foam booster




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LEAVE-IN CONDITIONER

TRANSPARENT

DESCRIPTION

Light conditioning for hair

No rinse needed

Easy to apply

COMPOSITION %

AMIDET APA-22 0.5Lactic Acid 90% 0.12OXIDET DMCLD 1.0

GLC-99% 1.0FINDET ARH/52 0.4PEG-14 Dimethicone (1) 0.5D-Panthenol 50% (2) 0.5Preservative (3) 0.2Fragrance (4) 0.4Benzophenone-4 (5) 0.25Hydroxypropyl Guar Hydroxypropyl Trimonium Chloride (6) 0.3Lactic Acid (50% solution) q.s (pH adjust = 3.5 – 4.0)


(1) Abil B-8843 supplied by Evonik(2) Provit® 50 supplied by BASF(3) Glydant® Plus supplied by Lonza(4) LOTUS SK 138721 supplied by KAO-Fragrances(5) Uvinul® M40 supplied by BASF(6) Jaguar® C-162 supplied by Rhodia


Kao Method

APPEARANCE (20ºC) : Transparent Liquid KCSA-258


pH (100%) : 3.5 - 4.0 KCSA-014

CATIONIC ACTIVE MATTER (%) : 0.6 approx KCSA-003


STABILITY : Correct (2 months 40ºC/RT/5ºC/cycles)





REFERENCE:

UP-DATED: PRINTED:

C504/T1

2014-03-072014-03-07

2


Heat water up to 80ºC and disperse Jaguar C-162.

Add the Lactic Acid and then AMIDETAPA-22 under stirring, avoiding air incorporation.

Once the mixture is clear, add OXIDETDMCLD under stirring.

Stir until homogeneous and start to cool down to room temperature.

Below 40ºC, add Panthenol 50%, the silicone, Glycerine (GLC 99%) and Benzophenone-4. Homogenize well after each addition.

Melt FINDETARH/52 and mix with the perfume until it is completely dissolved. Then add the mixture to the main vessel and once it is homogeneous, add the preservative and adjust pH.

COMPONENTS





OXIDET DMCLD (Cocamine Oxide, 30% a.m.): non-ionic/cationic character (depending on the pH). Stable at acidic and alkaline media. Conditioning and solubilizing agent. Foam booster




MICELLAR SHAMPOO

Silicone-Feel

Daily use

COMPOSITION %

AKYPO® FOAM LM 25 16.1

BETADET® S-20 13.2

AKYPO® SOFT 100 BVC 5.0

KAO SOFCARE® GP-1 1.0

KAOPAN® TW-IS399S 0.8

Polyquaternium-7(1) 1.0

Parfum MICELLES SS159386(2) 1.0

Preservative(3) 0.5

Citric acid (10%) q.s (pH adjust = 5.0-5.5)

Deionized water up to 100

(1) MerquatTM 550 PR from Lubrizol supplied by Quimidroga(2) Kao fragrance

(3) Microcare® SB from Thor

TECHNICAL CHARACTERISTICS Kao Method

APPEARANCE (20°C): Clear viscous liquid KCSA-258

VISCOSITY BROOKFIELD(20°C, cP): Approx. 8,000 KCSA-227

pH (as it is): 5.0 - 5.5 KCSA-014

STABILITY TEST: Correct (1 months 40ºC/RT/5ºC)

C-306

DESCRIPTION

Mild shampoo

KAO CHEMICALS EUROPEwww.kaochemicals-eu.com


COMPONENTS

AKYPO® FOAM LM 25 (Potassium Laureth-4 Carboxylate, ≈ 60% a.m.): anionic character. Primary surfactant.

Offers a soft and creamy foam, very stable and with special texture. Very mild and easy to thicken surfactant.

Specially designed for sulfate alternatives formulations.

BETADET® S-20 (Lauryl Hydroxysultaine, ≈ 38% a.m.): amphoteric character. Very mild co-surfactant. It

decreases the irritation level of anionic surfactants, improving the quality of the foam and performing also as

a thickener. It improves the stability of the formula at extreme pH’s and low temperature.

AKYPO® SOFT 100 BVC (Sodium Laureth-11 Carboxylate ≈ 70 % a.m.): crypto-anionic character, it combines

the properties of the anionic and non-ionic surfactants. Foaming co-surfactant, with solubilizing properties

and very mild for the skin.

KAO SOFCARE® GP-1 (PPG-3 Caprylyl Ether, ≈ 100% a.m.) non-ionic character. Clear transparent liquid at

room temperature. Multi-functional conditioning agent that imparts similar characteristics to those of silicones,

such as feel and functionality. It improves foam generation and hair shine.

KAOPAN® TW-IS399S (PEG-160 Sorbitan Triisostearate, ≈ 75% a.m.): non-ionic character. Liquid thickener for

any type of cleansing surfactant systems. Specially designed to increase viscosity of sulfate-free formulations.

Processable at room temperature.

Enriching lives,in harmony withnature.


• Charge deionized water and dissolve Polyquaternium-7 until it is completely dissolved.

• Add BETADET® S-20, stirring until total homogeneity.

• Add AKYPO® FOAM LM 25, stirring until total homogeneity.

• Add KAOSOFCARE® GP-1, stirring until the solution is completely clear.

• Add a premixture of AKYPO SOFT 100 BVC with parfum.

• Add KAOPAN® TW-IS399S to increase viscosity and stir until complete incorporation.

• Adjust pH with citric acid 10%.

• Add preservative. Stir until complete homogeneous.

The information and recommendations in this publication are to the best of our knowledge reliable. However, nothing herein is to be

construed as a warranty or representation. Users should make their own tests to determine the applicability of such information or the

suitability of any products for their own particular purpose.

Statements concerning the use of the products described herein are not to be construed as recommending the infringement of any

patent and no liability for infringement arising out of any such use is assumed.

Ref. C18015/Sh Mic 4.4

(Edited march 2019. EU version)

MICELLAR SHAMPOO

Kao Corporation, S.A.

Puig dels Tudons,10E-08210 Barberà delVallès

(Barcelona) Spain

Tel.: +34 937 399 300

Fax: +34 937 399 377

e-mail: [email protected]

Kao Chemicals GmbH

Kupferstrasse, 1D-46446 Emmerich,Germany

Tel.: +49 (0) 2822 711-0

Fax: +49 (0) 2822 711-201

e-mail: [email protected]



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NEUTRALIZING SHAMPOO

POST-STRAIGHTENING TREATMENT

DESCRIPTION

Mild shampoo

Improves combing

Balances hair pH after application of a relaxing cream.

COMPOSITION %

EMAL 40TE 35.0BETADET HR 15.0

AMIDET N 4.0Phenolphthalein (1/300) 1.0Sodium Chloride 0.6Poliquaternium-10 (1) 0.3Preservative (2) 0.05Citric Acid (10% solution) q.s. (pH adjust = 5.0 – 6.0)


(1) Ucare LR-400 supplied by DOW Chemicals



Kao Method



pH (100%) : 5.5 approx. KCSA-014






REFERENCE:

UP-DATED: PRINTED:

C08014/NSH

2010-09-092017-04-24

2


Add EMAL40 TE into water and stir until clear.

Add BETADETHR and stir until clear.

Add Ucare slowly over the previous mixture and stir until a homogenous blend is obtained

Continue with the addition of AMIDETN and Phenolphthalein, stir after each addition until the mixture is homogeneous.



Adjust viscosity by using NaCl.

COMMENTS It is recommended to add some conditioning agents like silicones and cationic polymers to

improve hair condition. Other additives (proteins, natural extracts, etc) can be added to thishair conditioner composition, if some additional benefits want to be claimed

COMPONENTS

AMIDETN (PEG-4 Rapeseedamide, 95% a.m.): non-ionic character. Nitroso-amines free thickener. It increases the foamvolume and improves the quality of it. It reduces the irritation potential of the anionic surfactants on the skin. Multi- functionalagent. Previous name : AMINOL N


EMAL 40TE (TEA Lauryl Sulfate, 40% a.m.): anionic character. Primary surfactant, highly foaming. Good detergentproperties.


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PEARLED SHAMPOO

MILD CONDITIONING

DESCRIPTION

Very mild shampoo

Slightly conditioning properties

Advisable for all the family

Good ratio price-quality

COMPOSITION %


EMAL 227E (1) 25.0

BETADET S-20 5.0

LEVENOL H&B 2.0

AMIDET A 15 1.0

QUARTAMIN AB 0.5D-Panthenol (50% solution) 0.5

DANOX PL-10 3.0Perfume (2) 0.6Preservative q.s.Additives q.s.Citric Acid q.s. (pH adjust = 5.5 - 6.5)


Deionized water Up to 100%


(2) HEAD PS 92724 supplied by KAO-Fragrances


Kao Method

APPEARANCE (20ºC) : White Pearled Viscous Liquid KCSA-258


pH (100%) : 5.0 - 6.0 KCSA-014







2REFERENCE :

UP-DATED: PRINTED :

C308001

2010-09-092010-09-09


Add to the deionized water each component, keeping the abovementioned order and stirring after each addition until total homogeneity.

Disperse QUARTAMIN AB in part of the water (10%) at 65ºC, and add it to the rest of the formulation. By doing this it is not necessary to heat the entire product.

Add the other additives: preservative (soluble), perfume (15 minutes of agitation are usually needed to solubilize it), dyes (diluted in water), other (extracts, etc).

Adjust pH (it is recommended to use citric or lactic acid, and diluted sodium hydroxide if an increase is necessary).


COMMENTS

If high conditioning effect is desired, other type of components can be added (extracts, protein hydrolizates, cationic polymers, etc), taking always supplier advises.

If EMAL 270D is used (70% a.m.), it is recommended to heat Deionized Water up to 45ºC approx. before adding it, and afterwards to continue with the other components.

Maximum viscosity is 4500 cPs. If higher viscosity is needed, a suitable thickener should be added or AMIDET A 15 should be increased. Do not add more NaCl because viscosity drops.

COMPONENTS

AKYP SOFT 100 BVC (Sodium Laureth-11 Carboxylate 70 % a.m.): crypto-anionic character, it combines theO

properties of the anionic and non-ionic surfactants. Foaming co-surfactant, with solubilizing properties and very mild for the skin.

AMIDE A 15 (Trideceth-2 Carboxamide MEA, 95% a.m. ): non-ionic character. Previous name : AMINOL A-15. .VeryT

effective thickener and foam booster for cosmetic products. Levelling agents for hair colouring shampoos and hair colours. Product mild for the skin.






EMAL 227E (Sodium Laureth Sulfate, 27% a.m.) : anionic character. Primary surfactant, highly foaming. Good detergentproperties.




QUARTAMI AB (Behentrimonium Chloride, 82% a.m.): cationic character. High conditioning surfactant, withN

substantive properties. It provides smoothness, shine and anti-static effect to the hair.


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PROFESSIONAL SHAMPOO

DESCRIPTION

Mild shampoo

Easy rinse

Good cleansing properties

COMPOSITION %

EMAL 270D (1) 17.0

AKYPO RLM 100 2.7

AMIDET A 15 2.0

NaOH (50% solution) 0.32

Perfume q.s.

Preservative q.s.Additives q.s.NaOH (10% solution) q.s.



(1) 17% of EMAL 270D (SLES at 70% a.m.) can be substituted by 44% of EMAL 227E (SLES at 27% a.m.).


Kao Method


VISCOSITY BROOKFIELD (20ºC, cPs) : 2000 approx. (2.7% NaCl) KCSA-227

pH (100%) : 6.0 - 7.0 KCSA-014

DRY MATTER (%): 17 KCSA-092






2REFERENCE :

UP-DATED:

PRINTED :

C08001 (CG-005/ TN-1006)

2010-09-09

2010-09-09


Add EMAL 270D slowly to the water while stirring and continue with the stirring until complete

transparency. To facilitate this process, water can be heated up to 40-45ºC before adding

EMAL 270D.

Continue with the addition of AKYPO RLM 100 and AMIDET A15 and stir after each addition

until the mixture is homogeneous.

Adjust pH (it is recommended to use diluted sodium hydroxide to increase it and citric or lactic

acids if a pH decrease is necessary).

Continue with the addition of the rest of components. Homogenise after each addition.


Adjust viscosity by usingNaCl.

COMMENTS

If high conditioning effect is desired, other type of components can be added (extracts, protein

hydrolizates, cationic polymers, etc) taking always under account supplier advices.

If a pearled product is desired, DANOX P-15 or DANOX PL-10 can be added (3-5%).

COMPONENTS

AKYPO RLM 100 (Laureth-11 Carboxylic acid, 95 % a.m.): crypto-anionic character, it combines the properties of the

anionic and non-ionic surfactants. Foaming co-surfactant, with solubilizing properties and very mild for the skin.

AMIDE A 15 (Trideceth-2 Carboxamide MEA, 95% a.m.): non-ionic character. Previous name: AMINOL A-15. .VeryT

effective thickener and foam booster for cosmetic products. Levelling agents for hair colouring shampoos and hair colours.

Product mild for the skin.

EMA 270D (Sodium Laureth Sulfate, 70% a.m.): anionic character. Primary surfactant, highly foaming. Good detergentL

properties.

The information and recommendations in this publication are to the best of our knowledge reliable. However, nothing herein is to be construed as

a warranty or representation. Users should make their own tests to determine the applicability of such information or the suitability of any products

for their own particular purpose.

Statements concerning the use of the products described herein are not to be construed as recommending the infringement of any patent andno liability for infringement arising out of any such use is assumed.

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REGULAR SHAMPOO

NORMAL HAIR

DESCRIPTION


Reduces fly-away effect from combing

Contains silicone for improved shine and velvety touch

COMPOSITION %

EMAL227E (1) 38.0

BETADET HR 10.0

EMANON EV-E 2.0

PEG-14 Dimethicone(2)

1.0

Perfume q.s. (it can affect final viscosity)

Preservative q.s.

NaOH (10% solution) q.s. (pH adjust = 6.0 – 7.0)

Sodium Chloride q.s. (3.- 3.5% approx. ; Viscosity adjust)



(2) ABIL B 8843 supplied by Evonik Industries


Kao Method

APPEARANCE (20°C) : Clear Viscous Liquid KCSA-258

VISCOSITY BROOKFIELD (20°C, cPs) : 2000 - 4000 KCSA-227

pH (100%) : 6.0 - 7.0 KCSA-014







REFERENCE:

UP-DATED: PRINTED:

C10009

2010-09-072010-09-07

2


Add EMAL227E to the Deionized Water and stir the mixture until homogenous.

Add BETADETHR and EMANONEV-E. Homogenize after each addition.

Add the silicone (PEG-14 Dimethicone).

Add the rest of additives: preservative (soluble), perfume (15 minutes of agitation are usually needed to solubilize it), dye(s) (diluted in water), other (extracts, etc).

Adjust pH (it is recommended to use diluted sodium hydroxide, and citric or lactic acids if a pH decrease is necessary).



If high conditioning effect is desired, other type of components can be added (extracts, proteinhydrolizates, cationic polymers, etc) taking always under consideration supplier advices.

If EMAL 270D or EMAL 270E are used (70% a.m.), it is recommended to heat DeionizedWater up to 45°C approx. before adding it, and afterwards to continue with the othercomponents.

Different viscosity levels can be achieved using variable NaCl quantities. If a pearled product is

desired, DANOXPL-10 a concentrated pearling agent can be added (3-5%).

EMANON EV-E may improve conditioning effect and combing force as well, reducing thestrength that has to be applied to comb a tress.

COMPONENTS


EMANON EV-E (Glycereth-7 Caprylate/Caprate, 100% a.m.): non-ionic character. Vegetable based, liquid product.

Excellent emulsifier and solubilizer for hydrophobic materials, with HLB 17. Suitable for both rinse-off and leave-on

products in hair and body applications. Key ingredient to achieve high foam ability and smooth feeling.



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SHAMPOO “2 IN 1”

DESCRIPTION

Shampoo for normal hair

Hair becomes easier to comb

Highly foaming


COMPOSITION %

EMAL270D (1) 8.6

AKYPOFOAM RL 40 4.7

BETADET SHR 6.8

AMIDET APA-22 0.5

DANOX PL-10 4.0

Polyquartenium-10 (2) 0.2

PEG-12 Dimethicone (3) 0.5

Ethyl Panthenol 0.2

D-Panthenol (50% solution) 0.2

Perfume (4) 0.5




(2) Ucare Polymer LR-400 supplied by Amerchol

(3) Dow Corning DC 193 supplied by Dow Corning

(4) PPES-37341-H-DPG supplied by KAO-Fragrances



Kao Method

APPEARANCE (20ºC) : White Pearled Viscous Liquid KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : 8000 - 10000 KCSA-227

pH (100%) : 6.0 - 7.0 KCSA-014

STABILITY : Pending (1 month 40ºC/RT/5ºC)





REFERENCE:

UP-DATED: PRINTED:

C10001 (C07004 video)

2010-09-092010-09-09

2


Charge 90% approx. of the water in the vessel and add Polyquaternium-10.

Add EMAL® 270D and AKYPO® FOAM RL 40. Stir after each addition until the mixture iscompletely homogenous.

In a separate vessel, charge 8% of Deionized Water, BETADET® SHR and AMIDET® APA-22.Heat up till 80ºC. Once the mixture is clear add it to the previous mixture and stir until the productis clear.

Add the rest of ingredients in the indicated order. Stir after each addition until the mixture iscompletely homogenous.

Add DANOX® PL-10, preservative (soluble) and perfume (15 minutes of agitation are usuallyneeded to solubilize it)

Adjust pH (it is recommended to use diluted citric or lactic acid to decrease it or diluted sodiumhydroxide to increase it if necessary).

Adjust viscosity with NaCl.

COMPONENTS





BETADET SHR (Cocamidopropyl Hydroxysultaine, 44% a.m.): amphoteric character. Very mild co-surfactant. Itdecreases the irritation level of anionic surfactants, improving the quality of the foam and performing also as a thickener.








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SHAMPOO

AFTER PERM

DESCRIPTION

Highly nourishing

Leaves hair conditioned and easy to comb

COMPOSITION %

EMAL 227E (1) 43.0


LEVENOL H&B 1.5

AMIDET N 2.0

QUARTAMIN BTC-131 0.2Dye(s) q.s.Preservative q.s.

Fragrance q.s.Thickener q.sCitric Acid (10% solution) q.s. (pH adjust = 6.0 – 7.0)


(1) 43.0% of EMAL 227E (SLES at 26.5 a.m.) can be substituted by 16.6% of EMAL 270D (SLES at 70% a.m.).

TECHNICAL CHARACTERISTICSKao Method

KCSA-258APPEARANCE (20ºC) :

VISCOSITY BROOKFIELD (20ºC,cPs) :

pH (100%) :

DRY MATTER (%) :

CLOUD POINT (ºC) :

STABILITY :

Clear Viscous Liquid

4100 approx. (initial)

7200 approx. (after 1 month at RT)

6.0 - 7.0

18 approx.

-2

Correct

KCSA-227

KCSA-014

KCSA-092

KCSA-246

(1 month 40ºC/RT/5ºC)





REFERENCE : C07004 UP-

DATED : 2010-03-31PRINTED : 2010-09-02

2


Add EMAL227E into water until completely dissolved.

Add AKYPO SOFT 100 BVC and stir until clear

In a separate vessel, mix LEVENOL H&B, AMIDET N and QUARTAMIN BTC-131. Heat up to 50ºC and stir until clear. Add this mixture to the previous one.

Add the other additives: preservative (soluble), fragrance (15 minutes of agitation are usually

needed to solubilize it), dyes (diluted in water) and other (extracts, etc.).

Adjust pH (it is recommended to use citric or lactic acid to decrease it, diluted sodium hydroxide if

an increase is necessary).


COMMENTS

In case of using EMAL 270D, it’s recommended to heat the initial water at 45-50ºC to facilitate

its incorporation.


DANOX PL-10 (3% approx.).

COMPONENTS

AKYP SOFT 100 BVC (Sodium Laureth-11 Carboxylate and Laureth-10, 70 % a.m.): crypto-anionic character, itO

combines the properties of the anionic and non-ionic surfactants. Foaming co-surfactant, with solubilizing properties and very mild for the skin.




LEVENO H&B (Glycereth-2 Cocoate, 100% a.m.): non-ionic character. Extra-mild surfactant, with emulsifyingL



QUARTAMI BTC-131 (Behenoyl PG-Trimonium Chloride, 70% a.m.): cationic character. Conditioning surfactant. ItN

provides smoothness, shine and anti-static properties to the hair, making easy to comb it. It doesn't present cumulative effect. Environmentally friendly cationic surfactant.

Additives: other conditioning agents like proteins or silicones or derivatives , cationic polymers , etc.

Fragrance: in accordance with the idea of a conditioning product. It can affect to the final viscosity of the formula. Add it always at low temperature. (<35 - 40ºC). Use % = between 0.1 - 0.5%.

The information and recommendations in this publication are to the best of our knowledge reliable. However, nothing herein is to be construedas a warranty or representation. Users should make their own tests to determine the applicability of such information or the suitability of any

products for their own particular purpose.Statements concerning the use of the products described herein are not to be construed as recommending the infringement of any patent andno liability for infringement arising out of any such use is assumed.

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SHAMPOO

ANTI HAIR LOSS

DESCRIPTION

Enriched with vitamins and minerals

Prevents and visibly improves hair loss

COMPOSITION %

EMAL227 E (1)29.6

BETADET S-20 7.5

DANOX PL-10 4.0

LEVENOL H&B 2.0

AKYPOFOAM RL40 3.3

AMIDET N 2.1GLC 99% 1.0Polyquaternium-10 (2) 0.3Tocopherol (3) 0.2Dimethicone (4) 0.5Apigenin+Oleanolic Acid+Biotinoyl Tripeptide-1(5) 1.0Borago officialis 0.2Perfume q.s.Preservative q.s.


(1) 29.6% of EMAL 227E (SLES at 27% a.m.) can be substituted by 11.4% of EMAL 270D (SLES at 70% a.m.).

(2) UcareTM JR-30M supplied by Amerchol.(3) Vitamine E Acetate produced by Basf

(4) Dow Corning 200F 350cst supplied by Dow Corning

(5) ProcapilTM supplied by Croda


Kao Method

APPEARANCE (20°C) : Pearl Viscous Gel KCSA-258


pH (100%) : 6.0 approx. KCSA-014






REFERENCE: C08018 – Z/3

UP-DATED: 2012-04-25PRINTED: 2012-04-25

2


Heat the water up to 70ºC. Add Polyquaternium-10.

At room temperature add BETADET® S-20, AKYPO® FOAM RL40, EMAL® 227E and GLC 99%. Stir well after each addition until a homogeneous dispersion is obtained.

Mix AMIDET® N with LEVENOL® H&B, Borago officialis, Tocopherol and Dimethicone at room temperature. Once it is homogeneous add to previous mixture.

Heat 5% of the water up to 30ºC and add ProcapilTM. Once it is homogeneous add to the previous mixture.

Add DANOX® PL-10.



COMPONENTS











AMIDETN (PEG-4 Rapeseedamide, 95% a.m.): non-ionic character. Nitroso-amines free thickener. It increases the foam

volume and improves the quality of it. It reduces the irritation potential of the anionic surfactants on the skin. Multi-

functional agent. Previous name : AMINOL N



composition doesn’t contain any Nitrogen derivative). It allows modifying the final appearance of the formula, providing it with

a beautiful pearled appearance. No heating is needed. Ecological product. Common use percentage: 3 - 10 %.


1

GUIDELINE FORMULARY




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SHAMPOO

SHAMPOO FOR GRAY HAIR

DESCRIPTION

Shampoo for gray hair

It provides vitamins, nutrients and moisture to aging hair

It contains bluing tints that eliminate the yellowing effect

COMPOSITION %

EMAL227E (1)29.6

AKYPOFOAM RL40 6.6

BETADET HR 13.2

EMANON EV-E 2.2

AMIDET N 1.5Dimethicone (2) 0.5Hydroxypropyl Guar Hydroxypropyl Trimonium Chloride (3) 0.2Benzophenone-4 (4) 0.2Polyquaternium-10 (5) 0.1Tocopherol (6) 0.1Sodium Chloride q.s.Perfume q.s.Dye(s) (7) 0.2Preservative q.s.



(2) Dow Corning 200F 350CST supplied by Dow Corning

(3) Jaguar C-162 produced by Rhodia

(4) Uvinul M40 produced by BASF

(5) UcareTM JR-30M supplied by Amerchol

(6) Vitamine E acetate produced by BASF

(7) CI 60730


Kao Method

APPEARANCE (20°C) : Blue clear gel KCSA-258

VISCOSITY BROOKFIELD (20°C, cPs) : 15000 approx KCSA-227

pH (100%) : 5.5 approx. KCSA-014






REFERENCE:

UP-DATED: PRINTED:

C08018-SS-6/B

2011-04-252011-04-25

2


Heat the Water up to around 70ºC. Add Polyquaternium-10 and Hydroxypropyl Guar Hydroxypropyl Trimonium Chloride.

Add BETADET® HR, AKYPO® FOAM RL40, EMAL® 227E and EMANON® EV-E until complete homogenization.

Mix AMIDET® N with Dimethicone and Benzophenone-4. Once it is homogeneous add to previous mixture.

Cool down until room temperature.


Adjust pH (it is recommended to use Citric or Lactic Acid to reduce it and diluted Sodium Hydroxide if an increase is necessary)

Adjust the final desired viscosity using NaCl.

COMPONENTS





AMIDETN (PEG-4 Rapeseedamide, 95% a.m.): non-ionic character. Nitroso-amines free thickener. It increases the foamvolume and improves the quality of it. It reduces the irritation potential of the anionic surfactants on the skin. Multi-functional agent. Previous name : AMINOL N


EMANON EVE (Glycereth-7 Caprylate/Caprate, 100% a.m.): non-ionic character. Vegetable based, liquid product.

Excellent emulsifier and solubilizer for hydrophobic materials, with HLB 17. Suitable for both rinse-off and leave-on

products in hair and body applications. Key ingredient to achieve high foamability and smooth feeling.


1

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SCALP TREATMENT SHAMPOO

VEGETABLE EXTRACT

DESCRIPTION



Anti-dandruff agent from natural origin

Safe for everyday use

COMPOSITION %

EMAL227E (1)25.0

AKYPOFOAM RL 40 5.0

BETADET THC-2 5.0Trikenol™ Botanical complex 0.5

EDTA.Na4 0.1Dye (s) q.s.Fragrance q.s.Preservative (Isothiazolinone type, 1.5% act) 0.05Lactic Acid q.s. (pH adjust= 5.5 – 6.0)

Sodium Chloride q.s.




Kao Method


VISCOSITY BROOKFIELD (20ºC,cPs) : 3.200 approx. (1.75% NaCl) KCSA-227

pH (100%) : 5.5 - 6.0 KCSA-014

CLOUD POINT (ºC) : + 6 KCSA-246







REFERENCE:

UP-DATED: PRINTED:

C06001/AC-1

2010-09-092010-09-09

2


Add to the Deionized Water EDTA.Na4 and stir until clear. Then add EMAL 227E and once themixture is homogeneous dissolve TrikenolTM. When the mixture is clear add each component,keeping the above-mentioned order and stirring after each addition until total homogeneity.

Add the other additives: preservative (soluble), perfume (15 minutes of agitation are usuallyneeded to solubilize it), dyes (diluted in water) and other (extracts, etc.).

Adjust pH (it is recommended to use citric or lactic acid to reduce it and diluted sodium hydroxideif an increase is necessary)

Adjust the final desired viscosity using sodium chloride.

COMMENTS


COMPONENTS






EMAL227E (Sodium Laureth Sulfate, 27% a.m.) : anionic character. Primary surfactant, highly foaming. Good detergentproperties.

Trikenol™: is a synergistic complex of two botanical ingredients: Manuka concentrate and willow extract enriched with salicylic compounds, developed to offer an effective anti-dandruff active from natural origin.


1

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SHAMPOO

FOR COLOURED HAIR

DESCRIPTION

Shampoo for coloured hair

Cleanses without stripping, fading or dulling colour

Improves colour shine


COMPOSITION %

EMAL 227E (1) 22.2

BETADET THC-2 7.5

AMIDET APA-22 2.0

AKYPO RLM 100 3.3

DANOX PL-10 4.0


Cationic Amino Quaternized Silicone Terpolymer (3) 1.0

PEG-150 Pentaerythrityl Tetrastearate (4) (45% solution) q.s.

Fragrance q.s.

Preservative q.s.



(2) Ucare Polymer JR-30M supplied by Amerchol

(3) Silsoft Q supplied by Momentive

(4) Crothix Liquid supplied by Croda


Kao Method

APPEARANCE (20°C) : White Pearled Emulsion KCSA-258

VISCOSITY BROOKFIELD (20°C, cPs) : 10.000 approx. KCSA-227

pH (100%) : 5.0 - 6.0 KCSA-014







PREVIOUS : C08018 UP-

DATED : 2010-03-31PRINTED : 2010-03-31

2


Heat the water up to around 70ºC. Add Polyquartenium-10. Stir till clear.

Once the mixture is clear, add EMAL® 227E and BETADET THC-2 until complete homogenization.

Heat up to 80ºC and add AMIDET® APA-22 under stirring. Add AKYPO® RLM 100.

Cool down and add silicone and DANOX® PL-10 at temperature below 40ºC.

Adjust pH (it is recommended to use diluted citric or lactic acid to decrease it or diluted sodium hydroxide to increase it if necessary).

Add preservative (soluble), perfume (15 minutes of agitation are usually needed to solubilize it) and adjust the viscosity with PEG-150 Pentaerythrityl Tetrastearate (45% solution)

COMPONENTS


BETADE THC-2 (Disodium Cocoamphodiacetate, 40% a.m.): amphoteric character. Very mild co-surfactant. ItT



acid pH, with substantive properties. It provides smoothness and anti-static effect to the hair. It also acts as a thickener in shampoo formulations.

AKYP RLM 100 (Laureth-11 Carboxylic Acid, 95 % a.m.): crypto-anionic character, it combines the properties of theO

anionic and non-ionic surfactants. Foaming co-surfactant, with solubilising properties and very mild for the skin.

DANOX PL-10 (Pearling concentrate, 52% dry matter): anionic and non-ionic character. Nitroso-amines free product (its




1

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SHAMPOO

ANTI AGING SHAMPOO

DESCRIPTION

Shampoo for mature, weakened and lifeless hair

It contains Keratin

COMPOSITION %

EMAL227E (1)29.6

BETADET S-20 14.0

SUCCIDETS 30 UK 10.5

DANOX PL-10 4.0

GLC 99% 2.0LEVENOL H&B 1.5Keratin(2) 0.5Polyquaternium-10 (3) 0.3Tocopherol (4) 0.2Ascorbyl Palmitate(5) 0.2Tocopheryl acetate + sunflower oil(6) 0.1Preservative q.s.



(2) KeratecTM IFP produced by CRODA.

(3) UcareTM JR-30M produced by Amerchol Impex Química.

(4) Vitamine E acetate produced by BASF.

(5) Dermofeel Ascorbyl Palmitat produced by Dr. Straetmans.

(6) Dermofeel E74A produced by Dr. Straetmans.


Kao Method

APPEARANCE (20°C) : White Pearl Gel KCSA-258


pH (100%) : 6.0 approx. KCSA-014






REFERENCE: C08018-X1.6

UP-DATED: 2011-04-25PRINTED: 2011-04-25

2


Heat the water up to around 60ºC. Add Polyquaternium-10.

Add BETADET® S-20, EMAL® 227E and SUCCIDET® S30 UK until completehomogenization.

Mix LEVENOL® H&B with GLC 99%, Ascorbyl Palmitate and Tocopheryl Acetate. Once it is homogeneous add to previous mixture.

Mix Keratin with 10mL water and warm to 30ºC. Add it to previous mixture.

Add the other ingredients: Tocopherol and DANOX® PL-10.

Adjust pH (it is recommended to use Citric or Lactic Acid to reduce it and diluted Sodium Hydroxide if an increase is necessary)


COMPONENTS





SUCCIDET S 30UK (Disodium Laureth Sulfosuccinate, 31% a.m.): anionic character. Very mild surfactant with foamingproperties. Used as co-surfactant in baby cleansers.









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SHAMPOO “2 IN 1”

DESCRIPTION

Easy handling, high concentrated, unpreserved raw materials

Low irritation and high performance formula (Good ecotox. profile)

Improved wet combing and detangling effect, smoothness and shine

Meets EU Ecolabel Criteria

COMPOSITION %

EMAL270D (1)17.4

DANOXPL-10 4.0


AMIDETN 2.0

LEVENOLH&B 1.5

AMIDET APA-22 0.25Dimethiconol + TEA Dodecylbenzene Sulfonate (2) 1.0Fragrance (3) 0.5Panthenol (50% solution) 0.5Guar Hydroxypropyl Trimonium Chloride (4) 0.25CI 47005 (1/1000) 0.4CI 42090 (1/1000) 0.2Tocopheryl Acetate 0.2NaCl q.s.Lactic Acid (90% solution) q.s.Preservative (5) 0.05



(2) Dow Corning 1784 emulsion supplied by Dow Corning

(3) GREEN APPLE SK122421 supplied by KAO-Fragrances


(5) Microcare SR 1393 supplied by Thor


Kao Method

APPEARANCE (20ºC) : Pearled Green Viscous Liquid KCSA-258


pH (100%) : 5.5 - 5.8 KCSA-014






2REFERENCE:

UP-DATED: PRINTED :

C08001/21/B

2010-09-092010-09-09


Mix water with EMAL270D at 50ºC. Once EMAL270D is dissolved, add cationic guar polymer. Mixture becomes turbid.

Add AKYPOSOFT 100 BVC and LEVENOLH&B

Melt AMIDETAPA-22 together with AMIDETN (at 80ºC). Once melted, incorporate it to the above blend (always at 50ºC).

Allow to cool down to room temperature and add one by one the rest of the components.

Add Lactic Acid to adjust pH below 6, and NaCl to adjust desired viscosity.

COMMENTS

Composition based on “Basic Formula” concept (system designed to easily formulate a range of liquid personal care products).

Conditioning effect is achieved when AMIDETAPA-22 (eco-friendly conditioner) is added.

COMPONENTS



skin.













GREEN APPLE SK122421 (allergen-free fragrance) beautiful green apple accord enriched by green elements as well assoft peach, white jasmine and musk (No allergen labelling at 0.5% in wash-off products).


1

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SHAMPOO

AFTER-SUN

DESCRIPTION

Moisturizing and protective shampoo for dry hair

Suitable for hair exposed to the sun, sea and swimming

It contains vitamin C and UV filter

COMPOSITION %

EMAL227E (1)33.3

AKYPOFOAM RL40 5.0

BETADET HR 6.66

AMIDET N 1.0Dimethicone (2) 0.5GLC 99% 3.0Carbomer (3) 0.2Guar Hydroxypropyltrimonium Chloride (4) 0.3Ethylhexyl Methoxycinnamate (5) 2.0Lecithin (6) 0.4Fragrance q.s.Preservative q.s.NaOH (50% solution) q.s. (pH adjust = 6.5 – 7.0)



(2) Dow Corning 200F 350CST supplied by Dow Corning

(3) Carbopol Ultrez 21 supplied by Noveon

(4) Jaguar C-17 supplied by Amerchol

(5) Covasorb supplied by Sensient

(6) Vamothin SBXT supplied by Gentec/Cargill


Kao Method


VISCOSITY BROOKFIELD (20ºC,cPs) : 7000 approx KCSA-227

pH (100%) : 6.5 approx KCSA-014






REFERENCE:

UP-DATED: PRINTED:

C08018/S-1A

2010-09-092010-09-09

2


Mix water with Guar Hydroxypropyltrimonium Chloride. Stir till clear.

Add AKYPO® FOAM RL40, BETADET® HR, EMAL® 227E, and GLC 99%. Stir well after each addition until a homogeneous dispersion is obtained.

Mix AMIDET® N with Dimethicone and Lecithin, once it is homogeneous add to previous mixture.

Mix Carbomer with 27% of total water and once it is homogeneous add to previous mixture.

Add the other additives: UV filter (Ethylhexyl Methoxycinnamate), preservative (soluble),perfume (15 minutes of agitation are usually needed to solubilize it), dye(s) (diluted in water)and other (extracts, etc.).

Adjust pH (it is recommended to use NaOH to reduce it).

COMPONENTS


AMIDETN (PEG-4 Rapeseedamide, 95% a.m.): non-ionic character. Nitroso-amines free thickener. It increases the foamvolume and improves the quality of it. It reduces the irritation potential of the anionic surfactants on the skin. Multi- functionalagent. Previous name : AMINOL N







1

GUIDELINE FORMULARY




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SHAMPOO FOR COLOURED HAIR

SULFATE FREE

DESCRIPTION

Shampoo for coloured hair

Cleanses without stripping, fading or dulling colour

Improves colour shine


COMPOSITION %

AKYPOFOAM RL40 15.0

BETADET S-20 9.0

AMIDET APA-22 1.5

Cationic Amino Quaternized Silicone Terpolymer (1) 1.0


DANOX PL-10 4.0

Carbomer (3) 0.3

PEG-150 Distearate (4) 0.4

Perfume q.s.

Preservative q.s.

Lactic Acid q.s. (pH adjust = 5.5 approx.)


(1) SilsoftQ supplied by Momentive

(2) Ucare Polymer JR-30M supplied by Amerchol

(3) Carbopol Ultrez 21 supplied by Noveon Consumer Specialities

(4) Aculyn 60 supplied by Rohm & Haas


Kao Method

APPEARANCE (20°C) : White Pearled Viscous Liquid KCSA-258


pH (100%) : 5.5 approx. KCSA-014






REFERENCE: C09010

UP-DATED: 2010-03-31PRINTED: 2010-03-31

2


Heat the water up to around 70ºC. Add Polyquartenium-10 to the Deionized Water and stir until a

clear solution is obtained.

Add AKYPOFOAM RL40, BETADETS-20 and AMIDETAPA-22. Homogenize after each

addition.

Cool down below 40ºC. Add Silicone, Carbomer dispersed in water (30% of water), PEG-150

Distearate and DANOX PL-10

Add the rest of additives: preservative (soluble), perfume (15 minutes of agitation are usually needed to solubilize it), dyes (diluted in water), other (extracts, etc).

Adjust pH (it is recommended to use citric or lactic acid, and diluted sodium hydroxide if an

increase is necessary).

Adjust the final desired viscosity using PEG-150 Distearate.

COMPONENTS


the anionic and non-ionic surfactants. Mild foam-booster for Personal Care products. Produces a rapid foam and improvesthe foam behaviour of cleansing products when used as co-surfactant.




AMIDET APA-22 (Behenamidopropyl Dimethylamine, 100% a.m.): non-ionic character. High conditioning surfactant atacid pH, with substantive properties. It provides smoothness and anti-static effect to the hair. It also acts as a thickener in


DANOX PL-10 (pearling concentrate, 52% dry matter): anionic and non-ionic character. Nitroso-amines free product (itscomposition doesn’t contain any Nitrogen derivative). It allows modifying the final appearance of the formula, providing itwith a beautiful pearled appearance. No heating is needed. Ecological product. Common use percentage: 3 - 10 %.


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Transparent

DESCRIPTION

Repairing shampoo

Silicone free formula

COMPOSITION %

EMAL 270D 16.4AKYPORLM 45CA 4.2

BETADET HR 8.3

AMIDET N 1.5

KAO SOFCARE GP-1 0.6

QUARTAMIN AB 0.6Polyquaternium-7 1.1Polyquaternium-10 0.4Preservative q.s.Fragrance q.s.Citric Acid (10% solution) q.s. (pH adjust= 5.0 – 6.0)


(1) 16.4% of EMAL270D (SLES at 70% a.m.) can be substituted by 42.5% of EMAL227E (SLES at 27% a.m.).


Kao Method

APPEARANCE (20ºC) : Clear transparent gel KCSA-258

VISCOSITY BROOKFIELD (20ºC,cPs) : 7000 KCSA-227

pH (100%) : 6 KCSA-014






REFERENCE:

UP-DATED: PRINTED:

C13001(SH2)

2015-03-072015-03-07

2


Heat the water up to 70ºC and add the following ingredients: BETADET® HR, QUARTAMIN® AB, polyquaternium-10 and polyquaternium-7 and then stir until complete homogenization.

Cool down the temperature until 40-35ºC.

Add each one of the remaining ingredients, EMAL® 270D, AKYPO® RLM 45CA, AMIDET® N and KAO® SOFCARE GP-1 and stir until complete homogenization after each addition.

Add the other additives: preservative (soluble), fragrance (15 minutes of agitation are usually needed to solubilize it), dye(s) (diluted in water) and other (extracts, etc.)


COMPONENTS

AMIDET N (PEG-4 Rapeseedamide , 95% a.m. ): non-ionic character. Nitroso-amines free thickener. It increases the

foam volume and improves the quality of it. It reduces the irritation potential of the anionic surfactants on the skin. Multi-

functional agent.


BETADETHR (Cocamidopropyl Betaine, 35% dry matter) : amphoteric character. Secondary surfactant. It decreases the

irritation level of the anionic surfactants on the skin , improving level and quality of the foam. Additional thickening affect.


KAO SOFCARE GP-1 (PPG-3 Caprylyl Ether, 100% a.m) non-ionic character. Clear transparent liquid at roomtemperature. Multi-functional conditioning agent that imparts similar characteristics to those of silicones, such as feel and


QUARTAMIN AB (Behentrimonium Chloride, 82% a.m.): cationic character. High conditioning surfactant, withsubstantive properties. It provides smoothness, shine and anti-static effect to the hair.


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