020613 - US Environmental Protection Agency · TCSTINO tna CERTIFICATION ' JUM H, VDlumt N 81 V...
313
020613
Transcript of 020613 - US Environmental Protection Agency · TCSTINO tna CERTIFICATION ' JUM H, VDlumt N 81 V...
020613
TCSTINO tna CERTIFICATION '
JUM H,
VDlumt N 81 V
TECHNICAL REPORTfor
Vlar & CompanyUSEPA Contract Laboratory Program
Sample Management Office300 N. Lee Street
Alexandria, VA 22314
:;H7i:B:. :;m' >Wi« HO.
ENVIRONMENTAL TESTIW Wrf CERTIFICATION CORPORATION
I
ifsC.K. Un.Ph.D,V/c* frtMtftnrircA inocptril/ont
02061-^
' \• iH RARITAN CENTER PARKWAY " EDISON, NJ M137 (101) 22B-JSCP
rETC TMT/N8 intf Cl"HTIflCATION '
"A
SECTION IV STANDARDS PACKET
CGCC3J020620
•ETC ENVIRONMENTALTESTING Mil CEHTIFICATION
Th« itindirdi in thii pickigt ipply to thi following iimplii:
ETC SAMPLE ttHBER ______£MQ SM>LE H*tflER
E47I8 C9417E47I9 C9418E4720 C94I9E4721 C9420£4722 C942IE4723 C9422E4724 C9423E4725 C9424E4726 C942SE4727 C9426E4728 C9427E4729 C942BE4730 C9429E473I C9430E4732 C943IE4733 C9432E4734 C9433E4M4 C9434E4745 C9435£4746 C9436E4747 C9437E4748 C9438£4749 C9439E4750 C9440E475I C944I£4752 C9442E4753 C9443E47S4 C9444£4755 C944SE47S6 C9446£4757 C9447£4756. C9446E4759 C9449£4760 C9450£5604 C947I£5605 C9472
t 156
QUANT RITORT
Operator I0i rtMS06f, Im.ant Till*. CMOS-lie 16.111-, Injected at. H40SOQ 16.00
D«,a File i >02nt)ii.lM Dilution Factor. 1,00Nane. O.G1695VSP,1500HKS,»»Mi*ci ETC SAMPLE,i:iCi695VSP,Vi:)A KlUiCTIOrVJ/B/fj^lDIIL
ID F'ilc i IWB2BTitle. IFB PUKGEABLE PRIORITY POLLUTANTS IDFILE, B31107, I), RLLast Calibration. B41I504 17.0V
CJonjiound R.Y. Scan* Area Cone Units
i) *BroMochloroMeth«ne 10,02 236 51402 250,00 ngS) Acrolein 4.61 8V 102 30,OH ng2) Acrolein 5,66 181 201 5V.27 ng2) Acrolein 7.26 157 18600 «i406,UU ng3) Acrylonitrile 8.04 177 2637? 563.9(3 ngA) l,2"l)ichloroeihane 12.98 Uiil 1471? 170.5H ng5) 1,1-Dichloroethane 10.66 250 SilBBO 189,00 ng6) Chloroethane <!.K1 82 8366 157.1V ng7) Chloroforn 1C,Of) 250 6MIS< 1.5, Hi ng7) ChloroPorn 12.HI BOS 70217 17V.77 rig7) Chloroform 15.2-1 36P. 442M 1111.7^ ng(5) l,l-Dii:hloro(?lhylene 9.S£ 215 411BV Itib.r.'w ng8> 1,1-Dichloroethylene ll.OK K69 39R72 172,IK ng9) l,2-'rr«n9'"(liKhlornethtilmm ?.S2 in1.. 11107 lt)V.,95 ng9) 1,2-trans-dichloroethylene 11,62 269 3V272 177,30 ng!•" Mtthylene chlorirte 6.«6 UV 1766U 1M.71 ng11 Methyl chloride 1,88 19 1441.0 176,7V. ng12) Methyl bpoiUrte 15.74 4.t 4777 150.7V, ng13) Trichlorofluoronethane U.7B 196 5533EI 153.30 ngIS) Vinyl chloride .;(t 57 9BS6 140.71 ng16) 2-Propanone 6,21 I'.SO lltl l,(jl nn16) 2-Propanone 7,34 IVi? 16111 ;!Orj,V), ng16) 2~['ropanone 6,54 170 103 1,31 rig16) 2-Propanone 8.97 Kill 15S l,9ti ng17) 2-Butanone 12,59 294 206 1,411 ng17) 2-Butanone 12.70 J02 23671 169.76 ng17) 2-Butanone 14.46 342 152 1.10 ngIB) Carbon diaull'ide tl.1V 1U1 38497 (11,17 ng19) *2~Brono-i-chlQropropane 19,32 467 B7903 250.00 ng20) Benzene 17,1)11 4150 BB099 161,40 ng21) Carbon tetrachloride 12,24 235 B77 3,1V ng21) Carbon tetrachloride 14,26 337 5324 19.3V ng21) Carbon tetrachloride 14.65 347 41559 151,34 ng22) 1,1,1-trichloroethane i 14,26 IJ37 42793 159,67 ng23) l,i,2-lrichloroith«ne 18,15 437 27646 161,03 ng24) 2-Chloroethylwinyl ethur 17.2II 464 21443 169.90 ng25) 1,2-Dichloropronane 16,56 396 30282 171.96 ng25) 1,2-Dichloropropane IB.12 436 7183 40,77 ng26) tnans-l,3-Dichloropropylene 16,63 403 43592 169,70 ng26) trant~l,3~Dichlaropropylene 18,12 446 41426 161,27 ng27) cis~l,3-Dichlor«propylen* 16,63 403 42592! 177.72 ng27) cia-M-DiclUoropropylene 1H.12 4'J6 41426 168,BV ng2E .Bronoforn 1U.04 434 1094 5,35 ng28) Brontforn 20.72 5UJ 3077? 150.47 ng29) DichlorobrodOMethane 15,24 36J! 49734 100,39 ng30) ChlorodibrotiOHethane 15.24 362 6B35 ' 24,1*4 ng
1 1 C 0 »•""'*' 1
Compound K.T. llcarit Area Clone U
30) cTl7r7dThr"o"iio"Me"t"h«ne 10.04 434 47679 160.34 ng31) Trichloro»th»lene 17, 41 41.U J50U1 160.6V ng22--, Viny acetate 14'95 35a IOSM lfl09'67 "931 \l,4-Dichlorobut*ne 83.85 «6U 105500 250 01. ng34) Chlorobtnzrne 25.32 6K1 83135 15i.95ng34) Chlorobenzene 26.68 656 101 -"ng' ™ » sa «='.«:',a-.?, % SSR a«338) Toluene 24,96 612 US .1? ng39) 2"le7anone 21,15 514 39229 269. OU ng39) a-H.x.nonf &•* S53 263 tB«.3V ng40) 4-Methyl-2-pentanone 21,15 514 39229 182.67 ng
S,4E) ortho-Xylene 30.61 757 82916 151.28ng4?) pptho-Xylme "•« 77B 179949 323/41 ng43) Heta.-and%ara-Xyl.ne 3061 7S7 82916 .36 n«,43) nnta-and-para-Xylene 31. 4J 770 179947 269.87 ng
* Conpound is ISTD
' VI W U (.) ,
,,59 020624
8.<!•J5K
Ijjj3* *
File >BBnBpk Rb 99
oeee-«»ee^
"ei>e;20BB-
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S NBS99
26
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u68
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98 4 QQ
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68 108 188 M6
1811• in.
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File >D2061 flCHj9SV$P,16etiHRS,»pEJC Sfll1PLE,QC1696YSP,VOR FRfiC Scan 304Bpk flb 85Ee 7= IP. 98 din.
8080-
:
4806-
0-
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Data File. )D2001..U1NaiiR. «U169SVSP,iSOOIHIS,tl)Misc. ETC SAMPLE,QC1695V8r',Vt)A FRACTION,5/B/H4,iOUL
Compound Noi 4Compound Nana. l,u-l)ichloroethaneScan Nunb«r. 3U4Retention Tine. 12,98 Min,Area. 44V1VConcentrationi 17H,5fl ng
r r- r*
1160
,•suKt?
1A
File >DBMBpk R|j 9910900.
8000
6600-
4066-'
2000;
Q.
s99
1 "
^S Rev/26 <54f **•
• 48
E I'ata BaseFull spectra of the HBS data sCai42.ee
67X"
a'e ' iae ' 168 ' aao ' 249 '
n 142win,-100
Jee*er*"•-20
«
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03
File >D2BBpk flb it
2600-
1600-
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080-
40(1-
e-
01 QC1694
41'N
' ' ' ' Vn
it>
1
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L l83 .12 y y ™ 22i «»/ k / / / s /
oa lia i4u ice J4u
an 62mln.-100
-60
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Data file. >D200inUlNane. C|C1675V6l>,lSOOHR!i,IDMint. ETU SAMPLE, «C1695V!UI1,Vl'lA f RAC',TION,S/£i/El4,10UL,
Uonpound No. 6Conpound Nanei Chloroethanebean NiiHtmr i B21Rptnntion Tine. 4.7.4 nin.Area. 83IJ6Concentration> 157.47 ng
1161
(j „ it U •* i.
J2062
§afl
M
£jj3
File >DBilS N*i Kev. E Data Baspf,ull spectra ol the HU-S data sran sivBpk ni. 99
180CB-•
8006-
6000
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oj
99
26
1 4 7L. fc. .""••i i i | i | i | i | i |
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j:' 91?. 68
96
98
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File .'•IiSeej QC169SYSP,lB8BHRS,«pETC: SflMPLE,90169SVSP,VOfl FRftC Scan 269Bpk flb 69?8 JP 11.62 din.
600B-
4000-
2000-
0-
4
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4
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Misc. ETC: SAMI'l.C^CU^SVJir.VOA FRACTION,S/8/B4,l(IUL.
Nvi r.'CiiMfiound Nine i 1,2-Ti'anf,-d'ichluropthyleneScan NuHbei . U6'.'Retention TiiiRi 11,62 nin.Area. 3927PConcentration. 1V7.'/.0 hg
02062762
§au&
J55
File MIBMS jy* "««• E "*•» Bas»>'ull bpectrii or thu NBi data scan 47RBph flh 99leeoo-
*000th
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99 ' L 4?5.001
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ei j'ia_a *T769eVSP,160iJHRS,»BETC SW1PLE,Qtl696VSPfVWl FRflC Sea
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Data file. > 1)200},. iUlNam. QCi675VBI',150UIII(:,i,1IiHIM.. I:TC 8AMPLt;,cici69Svar,voA FRACTION,«/B/Ei4,iouLCompound No: 10Confound Nanei Hethylene chlorideScan Nunber. ItiVRetention Tine. 6, 6 nin.Area. 1766UConcenti'ation; i'j4.74 rig
63 *20623
8rtM
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? Wli Hev. t Jitila Bagel1 ull spectra 01 the NBi data sir aS9 15P.RC
62
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Data File. )D200i..UiNane. QCi675VSl1,1500HI!!i,«Iihisci LITC C!Ahr'LL',QtC16V5Vfir,VOA (RAC:TlON,W8/B4,tlllll..
Conpound No. 15Confound Nanei Vinyl chloride*Scan Nuiibpi . li',1Retention Tine). 3.36 nin,Area. 9B26Concentration' 1411.71 ng
020623t«
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1 K*
an Iftt-loo'1•60
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26
File >»29»1 GCi6?KSP,15e9HR$,»BETC S"flfiPL"E,fitl69BySP,VlJfi FRflO Scan 159Bpk flb 8221 b^ ?.34 nin.
2800-
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eee-460-
0- J, , , , , , ,^, ,16(1 09 .,„ 1GJ: £00 !!(17 233X y 1J< / s x X^ <• / / s / X
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l)at,i File. > 1)2(1 111. >U1Nane . UiU6rcWI' , lUOOHRii , tl)hisc. . UTC aAMr'LE.CICtWSWjVtlA FRACTION, 5/B/84,10Ul,
Lonpoun.J No. 16
bean Nunher . 15?Retention TIMEM V.24. nin.rtrea. 16111Concentration. 205, 'jl nq
GdCC4;5(\206SO
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Data File. >1)19'?4..U1
Mis,(. . CTt: DAM'1. r,IU:lV73V!.il',V(.1fl I yiiA(.;TJCIN,S/l.!/t:l-1,) I1UI.
Cioi'ipiiiir.i.l No . i •!Coi'iimund N.ihei fiidiiiiriiinriuor(iht;1liaiit;Sttan Hui'iber • !33Rei(4ntioii IIMHI S.l'i'j Min,
Concentration! £'12.72 ntj
^ . f* 1 N -,
< w w o r* U
0206311166
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Data file! >l)2001,. .HI |Ni:i//,^V',)ll,120llllKS)<I)l,TC £iAI1['l.C,tiCU.95VeP,VOA I RACTXOII,5/8/84, tflUU
tcnpiiiinrt No. i?Coiipoudd Nanc> I'.-Elutdnaiibtic»n Nunbp( . 202Retention Tiiif. 12.VO nin,Area. i2' ?iConi.entration > i6?,V6 ng
p r * « It
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File JD2801 GC16S6VSP,16eatpi»IiETC Sf)HPLE,ac.l69eVSP,VOfl FRflC Scan «8Bpk fib 16768 '/ 17.88 tin.
16009-
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Mi'.x . nt aAMPl,f,W16r,W!U',V(lA I r!A(.'.linN,'J/8/fl4,l(iUl,
Conpound No. SOCqiifiaund N.KIWI l)en?.enfilican Nunher > 4311RetiTition Tint.'. I7.titl nin,Are,i. aQU'?VCiiiicontrfltiun i 161,16 ng
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Data File. !D£!001..1U
tlitr,. UTfi OAMPLCtCKlWSVai'^Oft n,'ftCT10M,'.i/8/84,10Ul.
Uonpound No. M!CoMpound Nane. Ti'ichloroethyUineScan Miinhni' . 01IIRetention Tine. ).','.41 nin.Area. uClil<iConcentration. I60,£)9nq
69
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file JD.2001 OC.169EVSP,16eeHR5;,<!LE,TO SflrtPLE,C(Cilt95V&P,VOfl FRflt Scan b21Bpk fib 14774 •« ,__ S .32 win.
.
12006-
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Conpounrl No. 11'1Conpuimcl Nai<ie. Chlorolit-nitint'3c.in NiH'ibHi . ;:iRt'tsntion Turn. 2S.22 nin,
Corn rntration, 1S1.VS ng
020633&
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MUvt-•'•I>
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f i l e MJKflEpN fll) 99
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File ,>D28Bpk fib ae0000-
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0-
01 QC.J696VSP,16e«IHRS,«I(?68 '
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Data File. >1)EOU1. .Ulriane. QC167SVW1,1500111!!.),Illfust. LTC; SAMm:,qcj6V5vaf',vcm TRACTION,r.,,'s/i:i4,iouL,Qonpound Nu. HI,Con|iounrl Nane. CthylheiucneScan (limber. 1>L>"Retention Tint. 27.U inn.ttrea. 113BS2UConcentration i ISS.OEi ng
$206351171
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File /MitrtS NJi» Kev, E Iidt'o Sfls*full spectra ci the NSi. dula $ran S31*Kpk flh 9999 '-L 0'<p.ofl nin.v looeo;) ^ cioo
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File >D206l QC169BVSP,1600HRS,«JFTC SflnPLE,Qt.lf96ys:P,V(!ifl FRflC Scan (592Bpk fib 17676 '.L M.I9 *in.
16000-
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400U
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0206371172
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Concentration^ I80,?i7ng
1173
n/""<:;0{, o u W J
02 633
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tic an MunbR,-1Retention Tine. 21,15 nin,Are*. 3922'.1Concentrationi 102,6V ng
CG3C54
1174
413HH
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Uoi.poiind Nu. 12Ciinpound Nane. ortho-Xylf.'neScan Nuhho,' , 7'j?Retention TIIUM 30,/a nin,Are.1*, i32VidConcentration. iSl.CBng
• 1175
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1
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Oat,'. File. >Df!001..UlNtne. QCU?SW,l8QOHI!:»,ilIiMint. ETC 8AMPU.',Qr;i69CVSI',VOA r'RACT10N,'../B/fM,10Ul.
Conpoun.1 No. nCoHpoorid ManeScan Nui<ibe< . 7VURetention Tine. 31.42 inn.ftre»i 17991VConcentration. 269,87 rig
^ 'J u u tl 0
020*411176
Toial Ion ChromotogramFilm >caa;
480008-448988-
400000-
320800-
208880-
840000-
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Data File. )Ca23J.iUiNane. QC1742VSP,12iSHRS,«Cdisc. ETC SAMPLE,BC1743VSP,yQA FRACTION,S/1B/84,10UL
Id File. DVFBLBTitle. IFB PURBEABUE PRIORITY POLLUTANTS IDFILE, 831107, D, RLLa»t Calibration. B40517 16.05
Operator ID. HM5066Qaunt Tine. 040518 13.07
r r r- r ri7\j ij U U tJ I
020642
1177
QUANT REPORT
Aerator ID. MMS066 Quant Tine. 840510 13.07Injected at. 840518 12.06
Data File. >C2231>.Ui Dilution Factor. 1.00Nan*. QC1748V8P,1215HRS,*CMisc. ETC SAMPLE,O.C1742VSP,VQft FRACTION,5/18/84,10UL
ID File. DVFBLBTitle. IFB PURCEABLE PRIORITY POLLUTANTS IDFILE, 631107, D, RLLast Calibration. 840517 16.05
Conpound R.T, Scan* Area Cone Units1) kBronochloronethane 8.42 189 21635 250,00 ng2) Acrolfin 5.55 115 43357 2130B.S7 ng?> Acrolein 6.58 140 156 76.67 ng2) Acrolein 6.98 152 101 49.64 ng3) Acrylonitrile 6,29 134 19671 775,07 ng3) Acrylonitrile 6.9i 150 226 8.90 ng4) 1,2-DJchloroethane 11.45 267 31406 170.73 ng5) 1,1-Dichloroethane 9,23 210 33689 16B.3S ng6) Chloroethane 3,22 55 11560 163,34 ng7) Chloroforn 9,20 209 4384 16,40 ng7) Chloroforn 10,71 248 43074 161,17 ng8) 1,1-Dichloroethylene 7,88 175 24566 161.89 ngB> i,i~Dichloroethylene 10,05 231 32734 215.71 ng9) 1,2-Trans-dichloroethylene 7,88 175 24566 138,08 ng> 1,2-Trans-dichloroethylene 10,05 231 32734 175,99 ng
,0) Methylene chloride 4,97 100 15948 143,89 ng11) Methyl chloride 1,55 IS 16544 129,16 ng12) Methyl bronide 2,13 27 13989 213,67 ngi3> Trichlorofluoronethane 7.10 155 41916 170,14 ng14) Dichlorodifluoronethane 2.52 37 11509 167,05 ng15) Vinyl chloride 2,56 38 19232 178,37 ng16) 2-Propanone 5.59 116 15638 161.22 ng16) S-Propanone 6,67 144 563 5,80 ng17) 2-Butanone 11,41 266 13171 133,12 ng17) 2-Rutanone 14,01 333 115 1.16 ng18) Carbon dlsulfide 6,52 140 55804 177,01 ng19) »8-BroMO~l-chloropropane 17,81 431 88418 850,00 ng20) Benzene 16.37 394 123819 177,77 ng21) Carbon tetrachloride 10.67 247 432 1.71 ng81) Carbon tetrachloride 18.65 898 7760 30.64 ng21) Carbon tetrachloride 13.04 308 47148 186,17 ng82) 1,1,1-trichloroethane 12,69 299 48838 SOB,02 ng23) i,l,8-Trichloroethane ' 16.64 401 31878 177,68 ng84) 8-Chloroethylvinyl ether 17,73 489 2695 235,67 ng2S> 1,8-Dichloropropane 15,01 359 38417 179,84 ng co85) 1,8-Dichloropropane 16.68 408 6871 29,26 ng <~26) trans-l,3-Dichloropropylene 15,38 367 47484 198.38 ng (386) trans-l,3-Dichloropropylene 16.64 401 48219 2Dl,5Bng (j87) ci»-i,3-Dichloropropylenis 15,38 367 47484 189,7? ng '")87) ci«-i,3-Dlchloropropylene 16,64 401 48S49 19S.7B ng Oot)> Bronoforn 16,53 398 1483 5.99 ng
j) fcronoforn 19,84 468 4SB96 180,70 ng29) Dichlorobrononethane 13,73 326 66135 181.37 ng30) Chlorodibrononethane 13.73 326 4971 16.98 ng30) Chlorodibrononethane 16.57 399 53197 181.12 ng3t) Trichloroethylene .15,91 382 388HS 179,03ng
Conpound R.T, Scant Area Cone Units
•0 Vinyl acetate 13.35 316 3823), 189,86 ngd.1) Vinyl acetate 14,59 348 1459 7.28 ng33) »l,4-Dirhlorobut«ne Si.80 534 83978 850,00 ng34) Chlorobenztne 83,90 588 110408 177,66 ng3?) 1,1,8,2-Tetrachlaroethane 81.53 587 48247 185,08 ng36) Ethylbenzene 25,65 633 155318 180,23 ng36) Ethylbenzene 88,58 707 60543 70,25 ng37) Tetrachloroethylene 21.57 588 64878 176,65 ng3R> Toluene 23,77 559 137710 182,80 ng39) 8-Hexanone 19,71 480 88194 807.83 ng39) 8-Hexanone 21.?6 580 19885 146,16 ng40) 4-Methyl-2-pentanone 19.71 480 20194 171.27 ng40) 4-Hethyl-a-penianone 21.?6 580 19885 180.80 ng41) Btyrene SB.36 703 77788 183.48 ng4?) ortho-Xylene 88,5? 707 82603 138.88 ng48) ortho-Xylene 89.14 783 177739 898,88 ng43) neta-and-para-Xylene 88,58 707 88603 148,88 ng43) neta~*nd-para-Xylene S9.14 783 177739 307,31 ng
* Conpound is ISTD
020644
1179 . *'
J!•\ gB1£hiH
File >IBn0BK RD 99* 100BB-
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eaee^•
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File >C2231 BC1742VSP,121EHRS,»CETC SflMPI.E,OC1742VSP,VOR FRflC Scan 210Bpk flb 6469 "/ . 9.23 .in.
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Data File. >C283ii.UlNane. fiC1742VSP,181SHRS,fCMisc. ETC SAMPLE,QCi748VSP,VOA FRACTION,5/18/84,10UL
Conpound No. 5Conpound Nane. 1,1-DichloroethaneScan Nunber. 810Retention Tine. 9,23 nin,Area. 33689Concentration. 168,35 ng
C« n n .••> c-««U\
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Data File. >C223)..UiNane. QC1742V8P,1815HR8,tCMisc. ETC SAMPLE,flC1748VSP,VOA FRACTION,5/18/84,10UL
Conpound No. 3Conpound Nanei AcrylonitrileScan Nunber. 134Retention Tine. 6.89 nin,Area. 19671Concentration. 775,07 ng
02064**
1 1 8 1
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File >£BI1S NBS Rev, E Hat a BajieFull jptclra of the NJPS data scan 2011Bpk WM99 „ °c^ ieit.ee «in.
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Data File. >CS?.3i»UiNane. qC174SVSP,181SHRS,*CMisc. ETC SAMPLE,QC1748V8P,VOA FRACTION,5/18/84,10UL
Conpound No. 4Conpound Nane. 1,2-DichJ.oroethaneScan Nunben 267Retention Tine. 11,45 nin,Area. 31406Concentration. 170,73 ng
020647
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42«SP(1215HRS,»CETC SR«PLE,aC1742VSP,VOfl FRRC Sctf> 3 .22
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Data File. >C823J..U1Nanei PC1748VSP,18i5HRS,»CMisc. ETC SAMPLE,qC1742VSP,VQA FRACTION,5/18/84,10UL
Conpound No. 6Conpound Nane. ChloroethaneBean Nunber. 55Retention Tine. 3.22 nin.Area. 11560Concentration. 163.34 ng
020648
83
uu
Iif»A
1
File >DBnBpk flb 99
10009-
0000;
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S.tCETC SRMPLE.6C1742VSP.VOR FRflC Sea10.71
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n 248• in.riee
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'4pe' ' ' ' ' 'B'O' ' ' ' ' ' 'lie' ' ' ' 160' ' ' ' ' '260
Data File. >C2831..U1Nane. QC1742VSP,i815HRS,*CHiBC . ETC SAMPLE,QC1748VSP,VQA FRACTION,5/iB/B4,10UL
Conpound No. 7Conpound Nane. ChJorofonnScan Nunber. 248Retention Tine. 10,71 nin,Area. 43074Concentration. 161,17 nq
02064n1184 '
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File >DBf1S NBS Rtv. E Data BaseFull iptctrtaf tht HB5 data Scan 919Bpk Ab 9999 V 9i9.ee «in.10000-
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6886-
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86
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File >C2231 flC1742VSP,121EHRS,»CETC Sfl(1PLE,ttC.1742VSP ,VOfl FRRC Scan 231Bpk Ab 59V V • 16.66 nin.
60001
5080-
4888-
3000-
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1 20 ' 4'0.H'l '1
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Data File. >C2231.«UiNane . QC1748VBP,iS15HRS,*C .
ETC 8AHPLE,QC174SWSP,VOA FRACTION, S/iB/84,10UL
Conpound No. 9Conpound Nane. 1,2-Trans-dichloroethyleneScan Nunben 831Retention Tine. 10,05 nin,Area . 38734Concentration. 175.99 ng
020650»*85
J5iwt?1i!
File >DBfl
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File >C2231 J)pl742VSP,1215HRS,»CETC SflHPLE,QC1742VSP,VOR FRRC Scan 100Bpk flb 4999 *2L *.»7 "tin.
5888-
4060:
380*
zeefrleee-
aj
84
1
1 SBj r,40 88
/
129 155 163 ... 211 262,,r x ^/ 8/eV x
;180
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;28
1 120 ' 160 ' 200 ' 240 '
Data File. >C8S31..U1Nane. QC1742VBP,1S1SHRB,»CMisc. ETC SAMPLE,QC1748VSP,VOA FRACTION,5/18/84.,10UL
Conpound No. 10Conpound Nane. Methylene chlorideScan Nunben 100Retention Tine. 4.97 nin.Area. 15948Concentration. 143,89 ng
",' ",
020651&
1186 f
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File >CBflBpk Ab 99
10008;
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S1 HJS Rev>9
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an 54•in.
?•68•"(0
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File >C2231 8C17«VSP,1215HRS,aCETC SRMPLE,BC1748VSP,VOR FRRC Scan 12Bpk Rb 22016 , 1.65 «in.i
20000-
16000-
12000-
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4000-Jl / 129 ' \ /' 2"2 286
-108-•60
-60
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Data File. >C2231.>U1Nane. RC1742VSP,12iSHRS,tCMisr. i ETC SAMPLE,qC1748V8P,WQA FRACTION,5/lB/B4,10UL
Conpound No. 11Conpound Nane. Methyl chlorideBean Nunber. 18Retention Tine. 1.55 nin,Area. 16544Concentration. 189,16 ng
02065»&
;87 r
s1££,21
1
File >BBNBpk flb 99
10080;
8000;
6000-
40Q0:
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S NBS Rev. E Data Ba99
6635 VI ^ 62
LL 1, k. L, , . r(0, i . , . i ,^i . . ,
uffill >pectra of the NBS data Scan™ 4774.08
123 136
is'e ' i^a ' 2^0 ' 240
4774• in.-100
•60
•60
MOt
•20
'•6
Flit >C22Bpk Ab 66
6ee0-
2000-
31 QC1742VSP,1215HRS,82
44 "^^ i 1 °2
J,l,r. I , f, t' ' ' V0 ' ' ' ' 'e'o' ' r
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134 153 211 s?„ < / / r
' 120 ' ' ' ' 16B ' ' ' ' 240' ' ' ' ' ' 240
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•20
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Data File. >C8831..U1Nine. QC1742VSP,181SHRS,ICHipc. ETC SAMPLE,OC174SWSP,VOA FRACTION,5/18/84,10UL
Conpound No. 13Conpound Nane. TrichlorofluoronethaneScan Nunber. 155Retention Tine. 7,10 nin,Area. 41916Concentrationi 170.14 ng
88
u
1J)«
13
File JBBf!»PK no 9918086;
8800;
6800-
400*.
2000-
S NfS Rfv. E Pata B«99
36 5"
j . J i.48 60 80
ise|ull spectra of the HBS data scan-J C900.0C
101
X" 120 128II fi -
2900• in.
|eeh60.'•49•-20
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<)•aeww
File >C2231 aCJ742VSP,1215HRS,tCETC SflMPLE,BC1742VSP,VOR FRRC Scan 37Bpk flb 11161 , 2.62 nin.
10000-
8000-
6000-
4008-
2000-A
62
*-w~
\
66X
60 ' 80
SB
101 104L f!f~~*~*"
LJeo•601• ft^
•201
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Data FHe. >C2231..UiNane. QC1748VSP,1215HRS,tCHisc. ETC SAMPLE,QC1748VSP,VQA FRACTION,5/lB/84,10UL
Conpound No. 14Conpound Nane. DichlorodlfluoronethaneScan Nunberi 37Retention Tine. 2.52 nin,Area. 11509Concentration. 167.05 ng
020654
1189
8H£•sMbs
FiU >D»NS Ws R»v. E Data BactFull ipectra of the NS& data" "' Sc.n 130Bpk flb 99
10808;•
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File >C2231 8C1742VSP,1215HRS,»CETC Sfl«PLE,8C1742VSP,VOfl FRRC Scan 38Bpk flb 11646 i . 2.66 win.
10000-
8008-
6000-
4PI«0-
0-
62
JJ ,J
85
l l01 .«« ,^» 220 2491. I X 132 V63 \ X
:
4
r*e•20
4*0 ' B'0 ' id0 ' U0 ' 288 ' 240
Data File. >C2231..U1Nane. QCi748VSP,181SHRS,*CMisc. ETC SAMPLE,QC1748VSP,VOA FRACTION,S/1B/84,10UL
Conpound No. 15Conpound Nane. Vinyl chlorideScan Nunben 38Retention Tine. 8.56 nin,Area. 19832Concentration. 178.37 ng
020655
1190 v *
ai^ ft£(1K
0
1
File >DBI1S NBS Rev- E Data BiseTull jpfctra of the NBS data Scan 90Bpk Ab 9999 71 90.06 *ln.
1BBBB-•
8006-
6000
4000;'
2600;
0
16
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[•lee•<e0
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File >C2231 flC1742VSP,1215HRS,eCETC SRMPLE,0C1742VSP,VOR FRHC Scan 116Bpk Ab 6422 / 6.69 mtn.
6888-f
4000-•
2000-'
"
JlJ
43\
i J120 162. 79 .x v . 169 196
ll / e ^\ t , i
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Data File. >C3231..UlNane. QCi748V8P,1315HRS,»CMisc. ETC SAMPLE,QCi748VSP,VQA FRACTION,5/18/84,10UL
Conpound No. 16Conpound Nane. 8-PropanoneScan Nunber > 116Retention Tine. 5,59 nin.Area. 15636Concentration. 161.82 ng
020653*<>
191
{jtit«Kfcl1
File >ms JtfS Rev. EBPK no 7777 »LleeeeS ^
.8000
6eeo;P4000;
2000;
»l J,,,67
, J,. . ,40
Pata BaseFull spectra of the NBS data scan 248eio.ec *in.riee
72X"
74
-e40.r460
Ve' " " ' 120" " ' ' 160 ' " " 200" ' ' ' " '
ft8w
File >C22Bpk flb 66
SaeO1
4000-
3000-
2080-
1000-
0-
31 aC1742V$E,1215HRS,iCETC SflNPLE,8CI742VSP,VDR FRRC Sea06 */ 11.41
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n 266• in.pieeio40
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Data File. >C2831..U1Nane> QC1742VSP,1815HR8,*CMisc. ETC SAMPLE,QC1748VSP,VQA FRACTION,S/1B/B4,10UL
Conpound No. 17Conpound Nane. 2-ButanoneScan Nunber > 866Retention Tine. 11.41 nin,Area. 13171Concentration. 133.18 ng
020657
1192 *"
s•\ ft11)PS£l1
File >J)WS NBS Rrv. E Da^BastFull spectra of tht NBS data Scan 366Bpk flb 99
0800;
6008;•
400*
2000;
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99
o« 6239 /
. i | . .,1
366.00
79
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File >C22Bpk Rb 23
2400«h
20000-16800-
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31 BC1742VSP,121E912
61
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91 127 129 J73 208i.../ ...NX / \.
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4'e ] e'a ' ide ' 160 ' 200
Data File. >C2231.,UiNane. BC1742VSP,1815HRS,*CMisc. ETC SAMPLE,QC1743VBP,VQA FRACTION,5/18/84,10UL
Conpound No. 80Conpound Nane. BenzeneScan Nunber. 394Retention Tine. 16,37 nin,Area. 183B19Concentration. 177.77 ng
02061193
J!rtI&I
File >DBnBpk Ab 99
10000;
8000;
6808-
4000:
2000;flj
S H>S"RiJ9
27/
lTI.'|l|30
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77X 96 97 M2
\X i''l'1'i'i ' I ' I''1*1!1' ''i ri'l'l"tee 90 100 lie
8014• in.-160
-69
•68
'•49
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6000-
480*
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ftn
Data File. >C8831..UlNane. QC1748VSP,1815HRS,ICMisc. ETC SAMPLE,QCi742VBP,VQA FRACTION,5/18/84,iOUL
Conpound No. 25Conpound Nane. 1,2-DichloropropaneScan Nunber. 359Retention Tine. 15.01 nin.Area. 36417Concentration. 179.?4 ng
r" "r7;Atw^w( -
i531194
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1BBBB-.
8000;P
699*
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S NBS Rev. E Data BaceFull spectra of tht NBS da199 „
60X
47
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62
L—0 80
99
,1100 120
52, Sc'n
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File >C2231 BC1742VSP,1215HRS,eCETC Sfl«PLE,8C1742VSP,VOfl F?0G Scan 302Bpk Ab 9114
"0800-
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4000"
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47S
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II40 60
*jr 16.91 nin.96""I
02fii'
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48
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Data File. >C223i..UlNane. «C1742VSP,121SHRS,»CMisc. ETC SAMPLE,QC1748V8P,VGA FRACTION,5/18/84,10UL
Conpound No. 31Conpound Nane. TrichloroethyleneScan Nunber. 382Retention Tine. 15.91 nin,Area. 38825Concentration. 179.03 ng
020 0
u
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File >DBI1S NBS Rev. E Data Baie^ull cpectra of the NBS data scan 2066Bpk Ab 9999 -JL eee6.ee «m,IBBBB;
8P0&-
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8800;
77S
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File >C2231 QC1742VSP,1215HRS,«CETC SfldPLE ,QC1742VSP,VOR FRRC Scan 588Bpk Rb 20604 'i L 23.90 «in.
20008;
16808;
12080;«
eeefr4808;
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77
51\ 74j X
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165 167, T N^"
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Data File. >C223J..UiNane. QC1748VSP,1815HRS,*CMisc. ETC SAMPLE,QC1748VSP,VOA FRACTION,S/iB/84,10UL
Conpound No. 34Conpound Nane. ChlorobenzeneScan Nunber. 588Retention Tine. 83,90 nin,Area. 110402Concentration. 177,66 ng
C- •* ."• i-i r.w u o I U
96
Flit >DBnBok flb 9
8900;
6090;
40eeJ•
2000;
S NBS Rev. E Data Ba»rJ99
7 j I j i
full spectra of the NBS data $c<nf 1677. e<
1B6
l 7
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JBO40
40
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40 00 120 160 200
1)ft
t/J
File >C2231 BC1742V$P,121!5HRS,iCETC SRMPLE,BC1742VSP,VOfi FRRC Scan 633Bpk Ab 26424 '/ 26.66 nin.
25080-
20000-
15008-
10000-
6000-
e-61 65
a, f ,. 4 VA TJ
106i . »..J, V" X
;iee-;00
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40
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' 4*0 ' e'0 ' 120 ' Ue ' 200
Data File. >C2?31..UlNane. QC1748VSP,l81SHRB,tCMisc. ETC SAMPLE,QC1742V6P,gQA FRACTION,S/1B/B4,10UL
Conpound No. 36Conpound Nane. EthylbenzeneScan Nunber. 633Retention Tine. 25.65 nin.Area. 155318Concentration. 180.S3 ng
0206G2*i-
1197
J File >DBflS NBS Rev. E Data Ba*eFull spectra of the NBS data Scan 9655BpK AO 9999 IS" 9600.ee Bin.
16000;
8*0**
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2000;
129/
94
" 59 ^ H728 ( / \\ ^.' ,. L L h 11, N.
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172
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40
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290
File >C22Bpk Ab 12
12000-
8000-
4008-
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31 8C1742VSP,1215HRS,«CETC SRMPLE,flC1742VSP,VO191
8.
<7 59
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L.,1 " '160
R .KJiRC seaJ2* 21.67
172
1 ' ' 200'
n 528• in.•100
40
48
•20
ft
Data File. >C2231..U1Nane. QC1742VBP,121SHRS,fCMisc. ETC SAMPLE,QC1748VSP,VOA FRACTION,5/18/84,10UL
Conpound No. 37Conpound Nane. TetrachloroethyleneScan Nunben 588Retention Tine. 81,57 nin,Area. 64878Concentration. 176,65 ng
0206G3ao98
J1VWK
E13
nie >J>BMBpk Ab 99
180B8-
8890-
600fr.
400*.
2000;
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S NBS Rev. E lata Baleful" " i
39 661 \
. J i Lt Ji --, , , , , , ,^, .,,,. .e,0,
1 spectra of the NBS data seaea9.ee
94X
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40
40
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n 559• in.
Jee40
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Data Flit. >C8S3i..UlNane. qci742VSP,18i5HRS,tCMlPC. ETC SAMPLE,QC1748VSP,VQA FRACTION,5/18/84,10UL
Conpound No. 38Conpound Nane. TolueneScan Nunber. 559Retention Tine. 22.77 nin.Area. 137710Concentration. 188,80 ng
-wo o I
99
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10880-
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600*.
4006;"
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1203• In.;100
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File >C2231 JH:i742VSP,1215HRS,eCETC SflnPtE,OC1742VSP,VOR FRRC Scan 520Bpk Rb 3624 ' 21.26 min.
300*
200ft;
1000;
SB
lit
'
BEX 1 133 V
i .1. -J. . 1 . / . S
•1BB
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Data File. >C?831..U1Nane. QCi742VSP,1815HRS,*CMisc.. ETC SAMPLE,QC174SYBP,VQA FRACTION,5/18/84,10UL
Conpound No. 39Conpound Nane. S-HexanoneScan Nunben 580Retention Tine. 81.86 nin,Area. 19865Concentration. 146.16 ng
200
dft1VKpQs
File >OBI1S NBS Reu9 E Data BaseFull spectra of the NBS data scan 1274Bpk Ab 9999 y
1BBBB;•
800*
6000;
406*"
2000;nj
,sII, i i, ,„40 88
96
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< tee' 102
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File >C22Bpk Ab 61
600*,
4000
3060-
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31 QC17467
2V.SJ>,1215HRS,oCETC SRHPLE,QC1742VSP,VOfl FRRC Sea19.71
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n 480• in.:iee«040
40
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40 80 120 160 200 240
Data File. >CS231..U1Nane. QC1748MSP,1815HRS,*CMisc. ETC SAMPLE,QC1748V8P,VQA FRACTION,S/1B/B4,10UL
Conpound No. 40Conpound Nane. 4-Methyl-£-pentanoneScan Nunber. 480Retention Tine. 19.71 nin,Area. 88194Concentration. 171.87 ng
0206G3
201
- HA
|w££a
File >DHIS NBS Rev. E Pata Ba.seF.un spectra of the NBS data scan 1615Bpk Ab 9999 "C 1616.00 «ln.leeoe-
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File >C2231 QC1742VSP,1215HRS,«C£TC SRHPLE,QC1742VSP,VQR FRRC Scan 703Bpk Ab 11127 IVJL 20.36 «tn.
1000*
000*
600*
400*
200*
161/
JI J. .1. j'j . _il
re
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riee.•ee40
40
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^ ' '4V • ' ' • '80' ' ' ' ' ' '120 ' ' ' ' ' '160' ' ' ' ' ' '200 '
Data File. >C223)..U1Nane. fiCi742VSP,1815HRS,*CMisc. ETC SAMPLE,QC1743VSP,VQA FRACTION,S/1B/84,10UL
Conpound No. 41Conpound Nane. StyreneScan Nunber. 703Retention Tine. 88.36 nin.Area. 777BBConcentration. 183,48 ng
020667
1202
^11i113
Flit >DBMBpk Rb 99
18BBB-
8000-
C00*
400e:200*:
S MS Rev.' E 'Sata"8«ePijll spectra of ih» HSS data scan99 '/ 1676.00
39\ 8» 77
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106[X
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1676• in.;1BB
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48
40
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40 80 120 160 200
U•a«
File >C2231 QCi742VSP,1215HRS,ftCETC SRMPLE,QC1742VSP,VOR FRRC Scan 707Bpk Ab 13133 , 20.62 »_in.
1200*•
m+•
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^
61 78
siN.,l 140
W-, ..................... .
106
f
il 2071 133 177 X
:it)o-<o40
40_
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Data File. >C2231..UlNane. QC1742VSP,181SHRS,ICMisc. ETC SAMPLE,«C1742VSP,VOA FRACTION,5/18/84,10UL
Conpound No. 48Conftound Nane. ortho-XyleneScan Nunber. 707Retention Tine. 28.52 nin.Area. 88603Concentration. 138,88 ng
020663&
1203
u-, u' ri
IM
I11
nu >DBMBpk Ab 99
IBBBO-
8000;
600*
400*
200*f.'
S NBS Rev. E Data Bast(99
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06
108
128 ' 160 288
1679• in.
;1B0
;60
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40
•20
Irt
File >C2831 QC1742VSP,121SHRS,»CEtC SAMPLE, QC1742VSP,VOfl FRRC Scan 723Bpk Ab 26666 , 29.14 nin.
25000-
20000
15000
19999
seee-a
61 77\
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147 207,. . / / . N.
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Data File. >CS831..UlNane. QC1742VSP,18iSHRS,»CMisc. ETC SAMPLE,QC1748VSP,VOA FRACTION,5/18/84,10UL
Conpeund No. 43Conpound Nane. neta-and-para-XyleneScan Nunben 723Retention Tine. 29.14 nin.Area. 177739Concentration. 307.31 ng
0206G3
1204
QUftNT REPORT
L rator ID. UU972B Quant Tine. U40S23 07.56Injected at. B40583 07.12
Data File. >E8819..U3 Dilution Factor. 1.00Nane. 50PPM 9TDMisc. SOI'PM STD B/N/A FRACTION,5/23/04,*K BTL*34
ID File. IFBENTitle. IFB P.E.QUANT ID FILE...,HWC.,831114Last Calibration. B40522 12,40
Conpound R.T, ScanO Area Cone Unite1) *d4-i,4-Dichlorobeniene 9.53 623 66637 40,00 UC/ML8) N-Nitrooodlnethylanine 4.15 35 63B29 47.07 UU/ML3) Aniline 6,84 546 134173 50,39 UG/ML4) bi«<2-Chloroethyl> ether 9,03 569 93921 49.42 US/MLS) 1,3,-Dichlorobenzene 9.43 618 81501 53.05 UU/ML5) 1,3,-Dichlorobenzene 9,57 620 83391 S4.8EI UG/rtL5) 1,3,-Dichlorobtnzene it), 07 668 79713 51.BQ UG/ML6) 1,4-Dichlorobenzene ?,43 612 81501 51,39 UG/ML6) 1,4-Dichlorobenzene 9,57 628 63391 52,53 UG/ML6) 1,4-Dichlorobenzene 10.07 6B£! 79713 50.26 UU/ML7) Benzyl alcohol 10.04 67V 8V52& 52.23 UG/ML7) Benzyl alcohol 10.44 722 37116 21,65 UU/ML8) 1,2-Uich'iorobenzene 9.43 612 81501 53,53 UG/MLP> 1,2-Dichlorobenzene 9.57 62B 83391 54.77 UI3/ML
1,2-Dichlorobenzene 10,07 60S 79713 58.35 UG/ML9) Phenol 6,06 550 125794 49.81 UU/Ml.
10) S-Chlorophenol 9,07 . 573 B1408 54,4(. UU/ML11) bis(2"Chioroi60propyl> ether 10,49 728 136601 43,83 UG/ML12) 2-MethyJ.phenol 10,44 728 82435 53.29 UG/MLiU) 2-Methylphenol 10.65 767 130474 84,35 Uli/hL13) 4-hethylphenol 10.03 67EJ 43881 18,00 UU/hL13) 4-Methylphenol 10,44 722 08435 33,6fc UU/nL13) 4-Methylphenol 10,85 767 130474 53,60 UU/ML14) dS-Aniline 8,80 543 118335 46,50 UU/ML15) *d8-Naphthalene 13,16 1080 195550 40,00 UG/ML16) N-Nitrosodi-n-propylanine 10,88 771 95333 48,12 UU/hL17) Hexachloroethane 10,69 778 23885 52,64 UG/ML18) Nitrobenzene 11,81 807 130492 46.91 UU/MLIB) Nitrobenzene 11.91 883 8777 1,00 UG/ML18) Nitrobenzene 12.37 933 88008 10,09 UG/rtL19) leophcrone 11,9i BBS 230713 49.30 UG/ML20) bit(2-Chlor*thoxy)nethane 12.68 967 124936 47.31 UG/ML81) 1,2,4-Trichlorobenzene ' 13.06 1009 73511 53,70 UG/ML221 Naphthalene 13,88 1026 8U0037 50.10 UU/ML83) 4-Ch'ioroaniline 13,55 1068 123Q68 48.38 UU/ML24) Hexachlorobutadiene 13.83 1093 40187 55.86 UG/ML85) 2-Methylnaphthalene 15,37 1861 220243 54,04 UG/ML26) 2-Nitrophenol 11,91 8B3 976 1,08 UU/ML86) 8-Nitrophenol 18.13 907 47367 52,85 UG/ML27) 2,4-Dinethylphenoi 18,37 933 93553 44.40 UU/MLar 2,4-Dichlorophenol 12,83 983 78635 54.5132.-' p-Chloro-n-cresol 1U.12 1234 09448 45.9630) Ben zoic acid 12.83 9B4 7954 B.84 UG/ML31) *dlO-Acenaphthalene IB,66 1628 105B9S 40.00 UU/ML32) Hexachlorocylopentadiene 16,10 1341 39559 52,34 UG/ML33) 2-Chloronaphthalene 16,86 1424 166821 53,44 UU/ML
1206
Conpound K,T. Scant Area Uonc. Units
3< , 2-Nitroaniline 17,30 1480 763Q2 51,37 UG/ML3*>. 8-NitroaniUne 18,70 itai 60080 40,37 UU/hL35) Dinethyl phthalate 10.15 1S64 246189 53.42 UCi/ML36) Acenaphthalene IQ.ib 1566 278582 53.76 Ufi/ML37) 2,6-Dlnltrotoluene IB.IS 1564 233 ,34 UG/ML37) 8,6-Dlnitrotoluene IB.33 1564 40303 48.90 UU/ML37) 2,6-Dinitrotoluene 18,66 1680 1048B 18.73 UG/ML37) 8,6-Dinitrotoluene 19,SO 1712 76289 92,56 UU/ML38) 3-Nltroaniline IB.70 1684 6008B 45.B7 UG/ML39) Acenaphthene 18,76 1631 184794 54.37 UG/ML40) Dibenzofuran 19,25 16.85 886574 54.88 UG/ML41) 2,4-Dinitrotoluene 18,33 1584 403Q3 85.85 UU/ML41) 2,4-Dinitrotoluene 19.50 1718 762B9 47.79 UU/ML42) Diethyl phthalate 80.38 180B 270706 58.16 UU/rtL43) Fluorene 80.33 1808 883886 58,95 UG/ML44) 4'Chlorophenyi pheny'l ether 80.48 1018 100107 56,50 UC/ML45) 4-Nitroaniline 20.61 1633 482X2 30.68 UG/ML46) N-Nitrosodiphenylanine £0.84 1358 157571 58.59 UU/ML47) 1,2-Dlphenylhydrazine 20,69 1864 320935 47,54 UU/ML40) 8,4,6-Trichlorophenol 16.39 1372 49315 58,83 UU/ML4B> 2,4,6-Trichlorophenol 16,40 1382 58736 55,67 UU/ML49) 2,4,5-Trichlorophenol 16.3V 1372 49315 4V.87 UG/rtL49) 8,4,S-Trichlorophenol 16,4Q 13B2 58736 58,613 UG/MLS3) d3-2,4-Dinitrophenol 10,9V 1654 8909 16,89 UG/rtL54) *dlO-Phenanthrene 23,1? 21 IS 206164 40.DO UG/rtL55) 4-Bronophenyl pheny'i ether 81.90 1974 77551 67.34 UiJ/rtL56 Hexachlorobenzene 82.27 2014 84584 67.60 UG/ML5V Phenanthren* 24.26 8123 873368 56.62 UU/ML57) Phenanthrene 22.40 2138 307044 65,85 UG/ML58) Anthracene 23,26 2123 273362 51,76 UG/MLSB) Anthracene 83,40 2138 307044 53.14 UU/ML,59) Dl-n-buty'l phthalate 85.42 8359 387699 60.73 UG/ML60) Pentachlorophenol 22.87 8080 8B44 16.71) UU/rtl.61) *dl8-Chry*ene 31.43 3015 £2185 40,00 UG/rtL6£!> Fluoranthene 86,96 3527 201884 37.67 UU/ML62) Fluoranthene 87.63 8600 179823 37.61 UU/ML63) Benzidine 87,50 25B6 1814 47,96 UU/hL64) P (irene 26,96 8527 201824 38,41 UU/ML64) Pyrene 27.63 8600 199883 38,14 UU/ML65) Butyl benzyl phthalate 30,08 8861 30315 46,49 UC/ML66) Benzo<a)anthracene 31,37 3009 46194 45,52 UC/ML66) Benzo(a)anthracene 3i,SU 3023 40488 39,69 UU/rtL67) Chrytene 31.37 300V 46194 53,66 UU/ML67) Chryeene 31.50 3083 404B8 47,03 UU/ML68) 3,3'-Dichlorobenzidine , 31.45 3017 3727 71.54 UG/ML6V) bi6(2"Ethylhexyl)phth«late 31.93 3070 81960 46.84 UG/hL ^71) Benzo<b)fluoroanthene 34,54 33SS 19429 100,95 UG/ML {.,71) Benzo(b)flworoanthene 34.59 3361 137B1 71.60 UC/ML ,,71) Benzo(b)fluoroanthene 35,40 344V 1243V 64,63 UU/ML (. j78) Benzo<k)fluoranthene 34,54 3355 19429 100.95 UG/ML ,•-.72) Benzo<k)fluoranthent 34,5V 3361 13781 71,60 UG/ML O72) BenzoUmuoranthene 3?>,40 344V 1843V 64,63 Uli/rtL73) Benzo(a)pyrene 34.54 3355 194SV 40,16 UU/ML73 ;Uenzo(a)pyrene 34.S? 3361 137B1 28,49 UU/ML73) Benzo(a)pyrene 35.40 3449 12439 85.71 UG/ML74) lndeno(i,2,J-c,d)pyrene 38.69 3801;) 11156 110.57 UCJ/dL74) Indeno(i,2,3-c.,d)pyrene 39.54 3901 5808 51,56 UG/ML7B) »ibenzoU,h)antnrscene 38,78 381EJ 7368 100,33 UU/nL
1207
Conpound H.T. Scan* Area Cone Units
74 ^ Benzo<flhi)perylene 38.69 3808 11155 98.88 UG/ML76) Benzo(ghi>perylene 39,54 3901 5202 45.83 UU/ML77) *diO~Phenanthrene 83,19 2115 206184 40,00 UG/ML85) *dl2~Chrysene ' 31,43 3015 831B5 40,00 UU/ML
* Conpound is I3TD
020673^
1208
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Data File. )E-:2819>.U3Nane. 50PPM CTUMisc. SOPPM STI) B/N/A FRACTION,5/23/04,»U B1L*34
Conpound No. VConpound Nane. PhenolScan Nunben 550Retention Tine. B.86 nin.Area. 12S9V4Concentration. 4V,Bi UU/ML
020674%*
1209
File >E2219 60PPM STD BOPPM S T D ™ i / R Scan 569Bpk Ab 2<?'fl 7 9.03 »ln' iee
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Data File. >b:£2lVi .U3Nane. 50PPM STDMisc. SOPHM STD B/N/A FRACTION,S/23/84,*E BT1434
Conpound No. 4Conpound Nane. bis(8~Chloroethyl) etherScan Nunber. 569Retention Tine. 9.03 nin,Area. 93921Concentration. 49.42 UG/ML
020675^
1210
File >E2219 6BPPM STB B*Pf(1 STD B7R ^ 62eBpk Ab 26912 tfjOT a In
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Uonpound No. 6Conpound Nane. 1,4-Dichlorobenzenetican Nunber. 6UURetention Tine. V.57 nin,Area. B33VXConcentration. S2.5B UU/ML
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020673
1 2 1 1
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Conpound No. 18Conpuund Nane. 2-MethylphenolScan Nunber i 78<iRetention Tine. 10,44 nin,Area. 8843SConcentration. 53.29 UG/ML
0206771 2 1 2 &
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Conpound No. 13Conpound Nane. 4-Methylphenoltic in Nunber. 767Retention Tine. 10,85 nin,Area. 130474Concentration. 53,60 UU/ML
Ci, r* <- ". OO w U J W
020673
1213
11w
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Conpound No. 28Conpound Nane. NaphthaleneScan Nunber. 1086Retention Tine. 13,22 nin.Area. 200037Concentration. SO.10 UG/ML
.0'*
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Conpound No. 27Conpound Nane. 2,4-DinethylphenolScan Nunben 933Retention Tine. 12,37 nin.Area. 93552Concentration. 44,40 UG/ML
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Data File. >EE217..U3Nane. SOPPM OTDMisc. SOPPM STD ll/N/ft FRACTION,S/S3/B4,IE BTL434
Conpound No. 42Conpound Nane. Diethyl phthalateScan Nunber. 1000Retention Tine. 20,3(1 nin,Are). 270706Concentration. 52,16 UG/ML
0206 2
217
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LData File. >E2819..U3Nane. 50I>PM STDMisc:. SOPPM STD B/N/A FRACTION,5/83/84,IE BTL»34
Conpound No. 6C.'Conpound Nane. bii(2-Ethylhexyl)phthalateScan Nunber. 3071Retention Tine. 31.93 nin,Area. t'1761)Concentration. 46.84 UG/ML
Cr- nnf^QJOwJ.>
020683
1218
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Data File. >E8191..U3Nane. SOPPM STDMisc. SOPPM STD BTLIli
Id File. IFBENTitle. IFB P,E,QUANT ID FILE,,.,WWC,,831114Last Calibration. 640523 12.46
Operator ID. UW998BQaunt Tine. B40S88 12.55
219
QUANT REPORT
Curator ID. WW9988 Quant Tine. B40S22 12.55Injected at. B40S22 04.03
Data File. >E2191..U3 Dilution Factor. 1,00Nane. SOPPM STDMisc. SOPPM STD BTLtli
ID File. IFBENTitle. IFB P.E.QUANT ID FILE....MUC.,631114Last Calibration. 840528 18.48
Conpound R.T. Scant Area Cone Units
1) *d4-l,4-Dichlorobenzene 9.47 614 41189 40.00 UC/ML8) N-Nitrosodinethylanine 4.OB 85 40688 46.78 UG/ML3) Aniline B.7B 538 66337 58.53 UG/ML4) bis<2-Chloroethyl) ether 8,97 559 60833 Si'.B6 UG/ML5) 1,3,-Dichlorobenzene 9.36 602 47697 50.30 UG/ML5) 1,3,-Dichlorobenzene 9.58 619 49345 58.04 UG/ML5) 1,3,-Dichlorobenzene 10.01 673 47455 50.04 UG/ML6) 1,4-Dichlorobeniene 9,36 602 47697 48,73 UG/ML6) 1,4-Dichlorobenzene 9,58 619 49345 50.41 UC/ML6) 1,4-Dichlorobenzene 10.01 673 47455 48.46 UG/ML7) Benzyl alcohol 9,96 670 5B182 55.00 UG/ML7) Benzyl alcohol 10.36 713 81699 80,51 UG/ML8) 1,2-Dichlorobenzene 9,36 602 47697 50,75 UG/MLB) i,a-Dichlorobenzene 9,52 619 49345 52.51 UG/MLP* 1,2-Dichlorobenzene 10.01 673 47455 50.50 UG/ML
Phenol 8,79 539 79664 51.08 UG/ML10) 2-Chlorophenol 9.00 563 47014 50.96 UG/MLii) bis<2-Chloroisopropyl) ether 10.44 780 98586 50.52 UG/MLU) bis<8-Chloroisopropyl> ether 10.49 785 13054 6,69 UG/ML18) 2-Methylphenol 10.36 713 50349 58.74 UG/ML18) 2-MethylphenoI 10,80 759 80156 83,96 UG/ML13) 4-Methylphenol 9.96 670 87582 18.36 UG/ML13) 4-Methylphenol 10.38 713 50349 33.51 UG/ML13) 4-Methylphenol 10.80 759 80156 53,35 UG/ML14) dS-Aniline 8,73 533 63401 53,19 UG/ML15) *d8~Naphthalene 13,18 1013 181891 40,00 UG/ML16) N-Nitrosodi-n-propylanine 10.84 763 61908 50,36 UG/ML17) Hexachloroethane 10,84 763 13070 46,62 UG/MLIB) Nitrobenzene 11,16 798 86661 50,82 UG/ML19) Isophorone 11.87 876 158631 52.66 UG/ML20) bis(2-Chlorethoxy)nethane 18.63 959 81691 49.87 UG/ML21) 1,8,4-Trichlorobenzene 13,08 1002 48605 50,18 UG/ML28) Naphthalene 13,18 1019 176978 51,04 UG/ML23) 4-Chloroaniline ' 13,50 1054 66644 54,56 UG/ML24) Hexachlorobutadiene 13,79 1066 82865 51,84 UG/ML25) 8-Methylnaphthalene 15.38 1853 131847 58.16 UG/ML26) 2-Nitrophenol 12.09 900 87870 49.56 UG/ML87) 8,4-Dinethylphenol 12.33 986 62818 47.61 UG/ML28) 2,4-Dichlorophenol 12.78 975 48826 ' 51,86 UG/ML89) p-Chloro-n-cresol 15,07 1886 66962 55.50 UG/ML30) Benzole acid 18.76 973 88130 46.97 UG/ML ,? " *diO-Acenaphthalene 18.68 1613 74718 40,00 UG/ML1"3*, 2-Chloronaphthalene 16,81 1416 106457 48,34 UC/ML34) 8-Nitroaniline 17,33 1473 55047 58.4634) 2-Nitroaniline 18,65 1617 48641 46,36 U35) Dlnethyl phthalate 18,10 1SS7 169427 58.12 UG/ML
" 1220
Conpound R , T , Scant Area Cone Units
3r Acenaphthalene 18.12 1SS9 173SS9 48.53 UC/MLi ' 2,6-Dinttrotoluene 18.29 1577 30110 51.78 UC/ML37) 2,6-Dinitrotoluene 18.61 1612 6820 11.73 UG/ML37) 2,6-Dlnitrotoluene 19.46 1705 58918 101,32 UC/ML38) 3-Nltroanlline 16,65 1617 46641 52,68 UG/ML39) Acenaphthene 13,78 1624 119979 50.03 UG/ML40) Dibenzofuran 19.21 1678 186892 50.67 UG/ML41) 2,4-Dinitrotoluene 18.29 1577 30110 86,73 UG/ML41) 2,4-Dinitrotoluene 19.46 1705 SB918 58.31 UG/ML48) Diethyl phthalate 80,35 1608 194398 53,08 UG/ML43) Fluorene 80,26 1795 153113 51,32 UC/ML44) 4-ChUrophenyl phenyl ether 80.37 1605 68B3S 50,26 UG/ML45) 4-Nltroaniline 20.56 1828 43065 55.93 UG/ML46) N-Nitrosodiphenylanlne 20.79 1851 111817 58.89 UG/ML47) 1,8-Diphenylhydrazine 20,85 1857 846945 51,64 UG/ML
- - • - •-••----—--i 4A 33 1363 33866 49,95 UG/ML, - p ,
46) 8,4,6-TrichlorophenoI 16.33 1363 w»o -48) 2,4,6-Trichlorophenol 16.43 1374 35367 53,11 .UU/ML49) 2,4,5-Trichlorophenol •16,3; S 1363 *«» 50,07 UG/ML49) 2,4,5-Trichlorophenol 16 .43 1374 *wy 51, 83 UG/MLS3) d3-8,4-Dinitrophenol 18.93 1647 iww s UG/ML54) *dlO-Phen«nthrene '•3.16 2109 »/o/«55) 4-Bronophenyl phenyl ether 81 .86 1968 49B« B/hL56) Hexachlorobenzene -a.-5 --y0 '0939 50|27 UG/ML57) Phenanthrene «•« "»' 22S72B 56i/)7 UG/ML57) Phenanthrene -3.37 B"* «YW9 44.39 UC/MLSB) Anthracene ".« |»' 22S72B 49|B6 UC/NLSB) Anthracene »-»' -"J. «W4 51.88 UG/ML5 Di-n-butyl phthalate 85.38 8352 awvw a60' Pentachlorophenol « 36 3006 10560 40. 00 UG/ML61) *Ul8-Chr»MM 26908518 149649 61. 98 UG/ML68) Fluoranthene 86- »« «» »"464g6 60|SO UG/ML68) Fluoranthene g-JJ |592 "^ U6.1S UG/ML
"' -°* • b MK n-66) Benzo(a)anthracene 31.3,. 3001 ««/ 8? UG/ML66) Benzo(a)anthracene 31383001 83297 59.48 UG/ML"> Chr>^ene 31 45 3015 80888 51. 75 UC/ML67) Chrysene "l'l= j3^ i359 57,27 UG/ML68) 3,3'-Dichlorobenzidine 31.39 J«uv wy69) b'ls<2-Ethylhtxyl)phthalate 31.68 3062 10719 «71) Benzo(b)fluoroanthene % BB 33B4 5504 68 79 UG/ML71) Benzo(b)fluoroanthene 34.55 3354 ^u, G/ML78) Benzo(k)fluoranthene 34 48 3347 BO/Y72) Benzo<k>nuoranthene . 3455 3354 5504 ^ ^73) Benzo(a)pyrene M-« »*^ 5504 24.98 UG/ML73) BenzoUlpyrene .;"•« j"* 2661 57,91 UG/ML74) lndeno(i,2,3-c,d)pyrene JB.61 3798 ««
'74) Indeno(i,8,3-c,d)pyrene E'SfJam ITlV 51,46 UG/ML75) Dibenzo(a,h).nthracene 36. 69 3807 im 51, 47 UC/ML76) Benzo(qhi)perylene 38.6i d/'yu « 53,06 UG/ML/ JUVtf «/ ,76) Benzo(ghi)perylene 39.4/ JUVtf «/7"v *diO-Phenanthrene 23. ib <SIUT i'«'*
0206S5* Conpound is ISTD
1 • 1221
3A> Acenaphthalene 16,12 1559 173559 48,53 UG/MLi ' 8,6-Dinitrotoluene 18.29 1577 30110 51,78 UC/ML37) 2,6-Dinitrotoluene 18,61 1612 6820 11,73 UG/ML37) 2,6-Dlnitrotoluene 19.46 1705 58918 101.38 UG/ML38) 3-Nitroanillne 16,65 1617 46641 58,68 UG/ML39) Acenaphthene 18,78 1624 119979 50,03 UC/ML40) Dibenzofuran 19,81 1678 1B6B92 50,67 UC/ML41) 2,4-Dinitrotoluene 18,29 1577 30110 26,73 UG/ML41) 2,4-Dinitrotoluene 19,46 1705 58918 58,31 UG/ML48) Diethyl phthalate 80,35 1802 194398 53.08 UG/ML43) Fluorene 80,88 1795 153113 51,38 UG/ML44) 4-Chlorophenyl phenyl ether 20,37 1805 62835 50,86 UG/ML45) 4-Nltroaniline 20,58 1B8B 43065 55.93 UG/ML46) N-Nitrosodiphenylanlne 80,79 1851 111817 58,89 UG/ML47) 1,8-Diphenylhydrazine 80,65 1B57 846945 51,64 UC/ML48) 8,4,6-Trichlorophenol 16,33 1363 33266 49,95 UC/ML48) 2,4,6-Trichlorophenol 16,43 1374 35367 53,11 UG/ML49) 2,4,5-Trichlorophenol -16.33 1363 33866 47, 10 UG/ML49) 2,4,5-Trichlorophenol 16,43 1374 35367 50,07 UG/ML53) d3-8,4-Dinitrophenol 16,93 1647 19993 51,83 UC/ML54) *dlO-Phenanthrene 23.16 8109 176735 40.00 UG/ML55) 4-Bronophenyl phenyl ether 81,66 1968 49862 50,51 UG/ML56) Hexachlorobenzene 88,83 8008 54361 50.78 UG/ML57) Phenanthrene 83.23 8117 800939 50,27 UC/ML57) Phenanthrene 83,37 8138 285728 56,47 UG/ML58) Anthracene 83,83 8117 800939 44,39 UG/ML58) Anthracene 83.37 8138 225788 49.86 UG/ML? Di-n-butyl phthalate 25,38 8358 839944 51, 68 UG/ML60; Pentachlorophenol 22.88 8078 88214 46.98 UG/ML61) *di2-Chrysene 31,36 3006 10560 40,00 UG/ML62) Fluoranthene 86,90 8518 149849 61, 98 UG/ML68) Fluoranthene 27,58 8598 146486 60,50 UG/ML63) Benzldine 87,44 8577 1339 116,15 UG/ML64) Pyrene 86,90 2518 149849 68,60 UG/ML64) Pyrene 27. SB 8592 146486 61.36 UG/ML65) Butyl benzyl phthalate 89,96 8853 14564 51.15 UG/ML66) Benzo<a)anthracene 31.32 3001 83297 50.40 UG/ML66) Benzo(a)anthracene 31,45 3015 80888 43,89 UG/ML67) Chrysene 31,32 3001 83297 59.48 UG/ML67) Chrysene 31.45 3015 20288 51, 75 UG/ML68) 3,3'-Dichlorobenzidine 31.39 3009 1359 57.27 UG/ML6?) bls(8-Ethylhexyl)phthalate 31.88 3062 10719 50.80 UG/ML71) Benzo(b)fluoroanthene 34,48 3347 8079 92.16 UG/ML71) Benzo(b)fluoroanthene 34.55 3354 5504 68.79 UG/ML72) Benzo(k)fluoranthene 34.48 3347 807? 98.16 UG/ML72) Benzo(k)fluoranthene i 34,55 3354 5504 68,79 UG/ML73) Benzo(a)pyrene 34,48 3347 6079 36,66 UG/ML73) Benzo<a)pyrene 34,55 3354 5504 84,98 UG/ML74) IndenoU,2,3-c,d)pyrene 38.61 3798 8661 57,91 UG/ML74) IndenoU,8,3-c,d)pyrene 39,47 3892 8743 59.70 UG/ML75) Dibenzo(a,h)anthracene 38,69 3B07 1719 51,46 UG/ML76) Benzo(ghi)perylene 38, 61 3798 8661 51.47 UC/ML76) Benzo(ghi)perylene 39,47 3892 2743 53.06 UG/ML7"' *dlO-Phenanthrene 23,16 2109 176735 40.00 UG/ML
* Conpound is ISTD 02068°"
1221
V"fti
File >E2191Bpk Ab 13264
taeoe-1260*
1100*
teee*900*
eee*?ee*6000-
6600-
460*
300*
2800-
160*
0-
B0PPM STD B0PPM STD infican 7131 38 mln.
7?
51
63
] 65.... ..I.f.... ....,.
90jf
09
_}
jT
1 130 ' 90 ' 109 '
» WV
•90
68
•70
i*9
i5040
•30
:20-10
Data File. >E819i..U3Nane. SOPPM STDMisc. SOPPM STD BTH11
Conpound No. 12Conpound Nane. 2-MethylphenolScan Nunber. 713Retention Tine. 10,38 nin,Area. 50349Concentration. 58.74 UG/ML
o V222
w
File >E21Bpk Ab 19
1800*
1606*•
14000-
12000-
16000-
800*
6000;
4000-
2000;
e-4
91 B0PPH STB 60PPM STD s«206 ' 8.7
66
51 55 63tO 47 \ S \
0 ' 44' ' 4V 52 Sis' ' Ve 64I......L.,.,.,...,.,.6'e ' rfe ' A ' s'e' ' W ' e'e ' 92
an 5399 nin.i-iee
'.;
J60
•70
•«0
;50
40
•30
:20•16
- '-9
Data File. )E2191..U3Nane. SOPPM STDMisc. SOPPM STD BTHil
Conpound No. 9Conpound Nane. PhenolScan Nunber. S3?Retention Tine. 8.79 nin,Area. 79664Concentration. 51,02 UG/ML
,223
"
u1HW
File >E2191Bpk Ab 16261
iseee-14000-
iseee-1206*
1160*10000-
900*
eeee-7000-
600*
600*
400*306*
200*100*
0-
43 1
44 ' Ve
S0PPM STD
63
?
1 tfe1 ' B'6' ' V0' ' 64
S0PPM STD t»4n 5596 97 jnnln.
1 Ve' ' >'2' ' 'A1 ' 'e'e' ' eV ' 'e'e' ' Va
•90
•ee
76
•60
•60
40
30
r26
ie
Data File. >E2191..U3Nane. SOPPM STDMisc. SOPPM STD BTLtU
Conpound No. 4Conpound Nane. bis(2-Chloroethyl) etherScan Nunber. 55?Retention Tine. 8,?7 nin,Area. 60833Concentration. 51,86 UG/ML
0206831224 U4U
•§.5?iw
File >E21Bpk Ab 20
28006-
taeee-
nee*
14000;
12000
10000;
eeee-
6000;
4ee*
2000-
e-
91256
B0PPM STI B0PPM STB
'
Bl
43
1 166
p
163
e'o'S
'7
1' 76 '
79
,0?
90
1 ,[
.an 7590 .nin.r!00
,' 199
-90
•00
•70
|«e
jse
40
-30
Jfi0
•10
"•Q
Data File. >E819i..U3Nane. SOPPM STDMisc. SOPPM STD BTL«il
Conpound No. 13Conpound Nane. 4-MethylphenolScan Nunber. 75?Retention Tine. 10.80 nin,Area. 80156Concentration. 53,35 UG/ML .
1225
N •B'S" a o v t p a o t o i v*'i «-i ff> W f> •* M> T W Nfewu • N"3 I
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n.nCO \,mm -n . a ) d } a ) u ) Q ) O C b C w C b ( D C b
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.»f5
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' 1226
•88.00
•88.00
•34.00
•80.00
-2B.OO z J2O +»
1-28.00 NX
-24.00 S? o
-22.00 5 ?•g Q-S **1-20.00 | * oi
^ Onk O -nhlB.OO i £ U.
N BO-18.00 "c °
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I «C'-«-'"'
4>,000 <
928 92
L
REPORT! 5203,21 'CHAHHELt 1 PESTICIDES FOK IFB(
SAMPLE: SURR 0,0! INJECTED AT 9l43i37 ON M A Y 1 8 , 1984
I ESTD METHODl IFBP/3 SEGl C2640P SUBSQ/SAMPi \/ 1 BTLi I
SL-MDTH MV/MIN DELAY MIN-AR BUNCH( .500 .100 20.00 250 NO
SUP-UNK DVT ID-LVL REF-RTW 8RTH XDJL-F ISO( NO O.«0 250 .10 1.0 1,00 NO
ACTUAL RUN TIME) 39.917 MINUTES(
RT ITM FACTOR AREA UG/pKC NAME( V
23.28 23,28* 3.1B22E- 3 606 BB ,019 i tLlMPflUB"33,65 33,69* 1.3970E- 2 3579 BB ,500 IDIBUTYLCHLOREHDflTE
(TOTAL AREA > 4186 TOTAL UG^G " ,519
( PROCESSED DATA FILEi P0280 RAW DATA FILEl R0200
.228 »20693
229
-ai.oo•98.00
-84,00
-K.OO
•10,00 £
.a,oo g-28.00 S
-24,00
-22.00
-80,00 _TJ rl
fc B n•11,00 I *J *
"s o u•»•» n44,00
10.00
-f.OOO
4.000
-4.000
-a,ooo
REPORT) 5260 CHANNEL: I PESTICIDES FOR IFB
,. SAMPLE! SURR 0,5 INJECTED AT 17i55M9 OH MAY 22, 1984
( ESTD METHOD) IFBP/1 SEQi C2640P SUBSQ/SAMPl 'l/ 32 BTLi 32
SL-HOTH MV/MIH DELAY M1N-AR BUNCH( ,500 .100 20,00 250 NO
SUP-UHK DVT ID-LVL REF-RTU XRTW KDIL-F ISO( HO 0.00 250 .10 1,0 1,00 NO
ACTUAL RUN TIMEi 39.917 MINUTES(
RT ITM FACTOR AREA UG/LKG NAME(
23,32 23,38* 4.36I2E- 3 554 BO ,024 HIHDAHE29.73 I.OCOOE- 3 616 BO ,006
( 26,40 26,40* 5.4334E- 3 6303 BB ,342 *ALDRIM27,32 27,46 7.0639E-3 918 BB ,065 (HEPTACHLOR EPOX1DE28,55 26,47 8.1399E- 3 590 BB ,046 »A END03ULFAM
( 29,16 29,16* 9.9252E- 3 450 BB ,045 *DIELDRIN33,66 33,74 t,39?OC 8- 2399 BB ^^
J.Oflf-l .faf TOTAL AREA - 11632 TOTAL UC/LKG « .865
PROCESSED DATA FILEl POZ91 RAW DATA FIL E i R0294
V -' W I
230
03Tl TlS,
O DQM
s
•o «0 •.(*J U.uID U
8d
»Mft
I
KKI'imii O J I / , 1 1 CHANNEL I I PESTICtOea FOR. tFS
( 3IWLKI UUKK 0,09 INJECTED AT fli4flMl) QH flflY 30,1* """ ———— '(Mo.
K8TO nKTIIOfii I Ml IV I BEfli JJJtjjjOf- aUBSa/SflnP. I,' I STLt
3L-HOIH MV/M1H DELAY M1N-AR BUNCH,901) .100 20,00 290 NO
Slin-UHK 1)VT 1D-LVU REF-RTH XRTH X01L-F ISOHI) 0,00 2SO ,10 1,0 1,00 NO
flClUlU KUH T I fit' l J9.9I7 MINUTES
NT II M KuCrOK AREA UC
au,40 30,40* 3, I I26E- 2 2*1! SB .091 •CHOSiir3 »,•»•,' 3U.«/* 7.7I98E- i 2 7 1 B B ,209 - 1 'j;i,«8 3J.67 7.9I86E- 3 6319 flfl .500
mi HI. until < 6aa3 TOTAL uc,(p;G » .ao«D.IIH MI.EI posai RAU DATA FILE:
I
v. .» f« \
1232 020697
Vfr
*'* •.!
Hi
i
-88.00
•88.00
-84.00
-82.00
•80.00
•28.00
•28.00
•24.00
-22.00
•20.00
•18.00
•18.00
-14.00
•12.00
-10.00
•8.000
•8.000
-4.000
•2.000
i IA/D Count* ' 1233
11 1
8-jjjllm
8*W?.S•x O (U
S 4J aK B ..* TJ "S B • *
4i U.K! UK 00
•n OC C.H a.
• 030 (UP oc" B
a CB aH (C
a(0
C" " • '•)w >-• -> .'.< V*
0.20G93
REPORT! 5204,31 CHANNEL: I PESTICIDES FOR 1FBI
-, SAMPLE! PEST ST00.5 INJECTED AT 10i32iOO ON MAY 16, 1984
( E8TD METHOD! IFBP/3 SEQi C2640P SUBSQ/SAMPl \t 2 BTLi 2
SL-UDTH HV/HIN DELAY MIN-AR BUNCH( .500 .100 20.00 250 NO
SUP-UHK PVT ID-LVL REF-RTW KRTU XDIL-F ISO( HO 0.00 230 .It 1,0 1,00 NO
ACTUAL RUN TIHEl 39.917 MINUTES
RT ITH FACTOR AREA UGG NAME(
22,29 22,29* 2.8023E- 3 170424 BB 5.000 «ABHC23,07 23,07* 7.0B22E- 3 63434 BB 5,000 «B BHC
( 23,20 23,28* 3.1822E- 3 157124 BB 5,000 *LINDAHE23,96 23,96* 3.823IE- 3 130783 BB 5,000 ID BHC24,29 1 .OOOOE- 3 356 BB ,004
( 24,77 t, OOOOE- 3 276 BB • ,00325,37 25,37* 3.9090E- 3 125343 BB 5,000 *HEPTACHLOR26,38 26,38* 2.6053E- 3 191910 BB 5,000 *ALDRIN
( 27,23 1 , OOOOE- 3 020 BB ,90827.45 27,45* 3,423?t- 3 146039 60 5.000 «HEPTACHLOR EPOXIDE20,10 1, OOOOE- 3 345 BB ,003
( 28.47 20,47* 3.8312E- 3 130507 BB 5,000 «A ENDOSULFAN28,67 20,87* 5.5517E- 3 90062 BB 5.000.IDDE29,16 29,16*>r5KWBC= 3 ".»I07103 BB lO.OOO/JDIELDRIN
( 29,70 29,78* 7.2200E- 3 "" 69252 BB 5,000 «ENDRIN3(1,00 30,00* 6.5354E- 3 153013 BB 10,000 KB ENDOSULFAN+PPDDD30,51 30,51* 0.8020E- 4 56294 BB ,500 *ENDRIN ALDEHYDE
( 31.03 31,03* 1.2302E- 2 40644 BB 5,000 tDDT31,17 ' 31,1?* 7.6197E- 3 65619 BB 5,000 IENDOSULFAH SULFATE32,37 t. OOOOE- 3 423 BB ,004
( 32,72 1. OOOOE- 3 4163 BB ,042
TOTAL AREA - 1711953 TOTAL UG/{Q<C » 00,564(
PROCESSED DATA FILE) P02B1 RAW DATA FILE) R0281
,-• *•*
1234 020693
f !f I
•Jl•Btn
H|fl0-»• •• ll &•••••
«Mt ————————— rrm
•88.00
•88.00
•84.00
•82.00
•80.00
•28.00
•28.00
-24.00
•22,00 |
-20.00 |
•18.00
•18.00
•14,00
•12.00
10.00
Sen«i nnlmCULL
SCB
gi8*AiT adS^1 O
«a.13^scOB O•o OC C.M a
men• COo ru
!•• £T*
is
A/D Count!
Ktsi%nto
REPORT) 9262:II 'CHANNEL) 1 PESTICIDES FOR IFB(_. SAMPLE) PEST STD0.5 INJECTED AT 10i49i28 ONJ1AY 22, 1904
( ESTO METHOD! IFBP/1 SEQt C2640P SUBSGVSAHPl \f 26 BTLl 26
SL-UDTH MWniN DELAY • MIM-AR BUNCH( ,500 .100 80.00 250 HO
SUP-UNK DVT ID-LVL REF-RTM XRT« HDIL-F ISO( HO 0.00 250 .10 1,0 1,00 NO
ACTUAL RUN TIMEl 39.90B MINUTES(
RT ITH FACTOR AREA UG/LKC NAME(
22.33 22,33* 3.61B6E- 3 138176 BB 9.008 AABHC23,10 23,10* 1.2903E- 2 38913 BB 5,000 «B BHC
( 23,31 23,31* 4.3612E- 3 114649 BB 5,000 (L1NDANE23.99 23,99* 6.9059E- 3 71972 BB 5,000 *D BHC25.38 25.38* S.5024E- 3 90B69 BB 5,000 «HEPTACHLOR
( 26,38 26,38* 5.4334E- 3 92023 BB 5.000 VALDRIN27.30 I.OOOOE- 3 274 BB .00327.44 27.44* 7.0639E- 3 70783 BB 5,000 «HEPTACHLOR EPOX1DE
( 28.45 20,45* 8.1399E- 3 61426 BB 5,000 «A ENDOSULFAN28,85 28,05* 1.5503E- 2 32253 BB 9.000 (DDE29.13 29,13* 9.9252E- 3 50377 66 9,000 «DIELDRIH
C 29,75 29,75* 1.9232E- 2 25999 BB 5,000 «ENDR1N29.96 29.96* 2.4529E- 2 40768 BB 10.000 «B ENDOSULFAN+PPDDD30,46 30,46* 3.1126E- 2 16064 BB 5,000 *ENDRIN ALDEHYDE
( 30,99 30.99* 7.7198E- 2 6477 BB 5,000 «DDT31,12 31.12* 4.4607E- 2 11209 BB 5,000 «ENDOSULFAN SULFATE32,64 t.OOOOE- 3 2162 BB ,022
(TOTAL AREA - 863594 TOTAL UG/LKC • 60.024
( PROCESSED DATA FILEi P0289 RAW DATA FILE) R0289
020701.
•.«
«,7I
• " — S•*'" W.M -
Bll ————————————— ULM
•.74
1
| i 1 i 1 | 1 • i •
•
•88.00
•88.00
•84,00
•82.00
-80.00
-28.00
-28.00
-24,00
-22,00 |
•20.00 I
—— " 0N
'18.00
•14.00
•12.00
10.00
8.000
•6.000
•4.000
-2.000
-0.000
1 '237 85 "A/D Count!
v3<n <rtg'Pcog
i§£d)g*
s«CU ffl«BT» Oa4Ja ..B
•O rlB n4J U.uB Oti Og&«nolH CC
• 1r** 01U) r)UJ <nQ. iL
«lI=a10
r ' " ' I "iC J« i** 1
£1'ofinTO
REPORTi 5322.11 CHANNEL! 1 PESTICIDES FOR IFB
( SAMPLE! PEST 0.5 INJECTED AT 17i49i49 ON HAY 30, 1984
ESTD METHOD! IFBP/1 SEGi 12672P SUBSIVSAMPs V 2 BTLi 2
SL-UDTH MV/MIM DELAY MIN-AR BUNCH,500 .140 20,00 250 NO
SIIP-UNK DVT ID-LVL REF-RTW XRTUHO 0,00 250 .10 1,0
ACTUAL RUN TIME! 39.917 MINUTES
RT ITM FACTOR AREA
( 20,74 I,OOOOE- 3 265 6B22.28 22,28* 1.9368E- 3 2569156623.06 23,06* 4.9993E- 3 101466 BB
( 23,27 23,27* 2.1295E- 3 2358636623.95 23,95* 2.3853E- 3 212247 6624,28 1,OOOOE- 3 397 66
( 24.76 1,OOOOE- 3 369'BB25,35 25,35* 2.7975E- 3 183982 6625,69 1,OOOOE- 3 2157 66
( 26,37 26,37* 2.0689E- 3 245354 6627,29 1,OOOOE- 3 6702 BB27.44 27,44* 2.5182E- 3 £04779 68
( 28.08 1,OOOOE- 3 325 6620,16 t,OOOOE- 3 1069 6828,46 28,46* 2.6097E- 3 199737 68 LM-i-eST «A ENDOSULFAN
( 28,86 28,86* 2.8217E- 3 109256 66 1J6~*W «DPE tf.ty29,15 29,15* 3.1519E- 3 166843 66 WTT77 #DIELDR1N &*&"29,77 29,77* 4.6513E- 3 115053 BB JJlZrW «EHDRIH rfV«W
i 29.99 29.99* 4.1096E- 3 270002 66 2A4TW7 «B EHDQ3ULFAN+PPDOD //.Of30,50 30,50* 5.4987E- 3 105009 66 \J£+4*S~ 4ENDRIN ALDEHYDE S.VP.30,90 1,OOOOE- 3 1292 BB ,258
, 31.02 31,02* 4.9729E- 3 113971 BB \&<yK~,W\>T &'K31,16 31,16* 4.9097E- 3 110106 66 USrfTT «ENDOSULFAN SULFATE^' ?f31 ,56 1,OOOOE- 3 629 BB ,126
( 32,03 I,OOOOE- 3 17507 BB 3,50132,72 t.OOOOE- 3 ' 4925 BB ,98539.49 t.tOOOE- 3 722 BB .144
TOTAL AREA • 2755045 TOTAL U G K C • 1707,608
PROCESSED DHTA FILEl P0519 RAW DATA FILEi R0519 .,,V «**
ao \1238 020703
• 1239A/D Counts
•4.000
•2.000
4.000
§£a*
S
* REPORT: 5211 CHANHELl 1 PESTICIDES FOR IFB
* SAMPLE) CHLOR STD5.0 INJECTED AT 17iI8i37 ON MAY 18, 1984
ESTD METHOD! IFBP/1 SE8i C2640P SUBSQ/SAMPi 1^9 8TLi 9
* SL-UDTH MV/'MIN DELAY MIN-AR BUNCH.900 .100 20,00 250 NO
* SUP-UNK DVT ID-LVL REF-RTU «RTW KDIL-F ISONO 0,00 250 .10 1,0 1,00 NO
^ ACTUAL RUN TIME) 39,917 MINUTES
* RT ITM FACTOR AREA UG.'LKC NAME
, 21,31 1,OOOOE- 3 13069 66 .131v 22.73 1,OOOOE- 3 2019 66 .020
22.82 23,03 9.0530E- 4 1090 66 .010 «*B BIIO—.i 23.42 23,23 3.4897E- 4 1759 B8 .006 IUHP*HE-' 23,87 23,87* 4.5124E- 4 1546 68 .007 fP BHIT
24.01 .OOOOE- 3 514 BB ,005/ 24.23 ,OOOOE- 3 2783 BB .028v 24.39 ,OOOOE- 3 1179 BB ,012
24,55 ,OOOOE- 3 4629 BB .046, 24,84 .OOOOE- 3 45626 BB .456v 25,04 .OOOOE- 3 1822 BB ,016
25.18 ,OOOOE- 3 723 66 .007, 25.39 25,39* .0797E- 4 72898 BB ,297* 25,52 .OOOOE- 3 4917 66 ,049
25,82 ,OOOOE- 3 297 66 ,003/ 25.93 .OOOOE- 3 1626 BB ,016* 26,09 .OOOOE- 3 1874 BB ,019
26,24 ,OOOOE- 3 5286 66 ,053, 26,35 26,35* .7887E- 4 10021 BB ,026 WltWHW
26.59 .OOOOE- 3 4794 66 ,04626,69 ,OOOQE- 3 474 66 .005
/ 26,79 .OOOOE- 3 369 66 ,004' 26,91 ,OOOOE- 3 1290 BB ,013
27.23 ,OOOOE- 3 30287 66 .303, 27.37 .OOOOE- 3 764 BB ,006 _______
27,48 27,46* .7542E- 4 ' 1387 BB ,005 «Hk.nniHLOR CP04U4E27,66 ,OOOOE- 3 2152 BB ,022
i 27,75 ,OOOOE- 3 1746 66 ,01727,61 .OOOOE- 3 479 B6 ,00527.86 .OOOOE- 3 594 66 ,006
/ 27,96 ,OOOOE- 3 19640 66 ,19628,11 , OOOOE- 3 155638 BB 1,556 p - ~ • . ..28,23 , OOOOE- 3 2288466 ,229 I*'.* w •.« i,
, 28,37 ,OOOOE- 3 2468 66 ,0251 26,51 28,51* 4.1735E- 4 123287 68 .515 »6 FtKinqill F.BjJ
26,62 I.OOOOE- 3 93680 6B ,937 *.' 28,74 1.OOOOE- 3 1583 BB ,016 W
28,89 28,69* 6.1501E- 4 32551 BB ,200 "WlS.29.07 29.07* 5.00B4E- 4 5056 66 ,025 «trfrCU&JJL> . .
. 29,19 1,OOOOE- 3 865 BB ,009 '29,31 '" 3 3341 BB ,033
/ 29,59 I,OOOOE- 3 686 BB .00?
REPORT) 5211 (CONTINUED) PAGE) 2 PESTICIDES FOR IF8
' RT ITM FACTOR AREA UC kc NAME
/ 29.61 29.81* 7.4945E- 4 1597 66 .012 JFHI)PTtJv 29.91 1. OOOOE- 3 1740 66 ,017
30.08 30.08* 7.2330E- 4 1942 66 .014, 30.31 I.6000E- 3 17460 BB ,175 ____
30,42 30.42* 9.9564E- 4 1753 B8 ,017 •#tl1GMH HCTCFT0P30,6531.06 31,061131.82 31,22* 0.4472E- 4 60466 .006 •EHPOOUlFftll SULPATB31 ,3231,7032.0632.3632.5833.1133.3333.61 33.7634.87
,OOOOE- 3 35806 68 .358.3403E- 3 1405 66 ,019
.•OOOE- 3 321 66 .003,OOOOE- 3 4430 BB ,044,OOOOE- 3 831 66 ,008.OOOOE- 3 507 66 .005,OOOOE- 3 435 66 ,004.OOOOE- 3 343 6B ,003.OOOOE- 3 326 66 ,003,3970E- 2 271 66 ,030 8DI8UTYLCHLOREHDATE.OOOOE- 3 1102 BB ,011
TOTAL AREA » 755557 TOTAL UG$KG • 6,183
PROCESSED DATA FILE) P0287 RAW DATA FILE) R0287
1241 0
0,000
•88.00
•88.00
•84.00«ri
•82,00 ofTl
•80.00 >
•28.00 g
•28.00 N
•24.00 cq
•22.00
•20.00 _•D i-«
k •> *•? *"•Q ^S£&
1-14,00
—- ,n oJQ CC
10.00 tn..x5•a.ooo o£
•fl.000 a |
•4.000 Jin
1-2.000
1242A/DCounti 020707
(
' REPORT) 9210 CHANNEL! 1 PESTICIDES FOR IFB
SAMPLE! TOX STD5.0 INJECTED AT 16i30i17 ON MAY 18, 1984
ESTD METHOD! IFBP/1 SEQi C2640P SUeSQ/SAMPt \f 8 BTLl 8
SL-UDTH MV/MIN DELAY MIN-AR BUNCH.500 .100 20.00 250 NO
SUP-UNK DVT ID-LVL REF-RTU XRTU JiDIL-F ISOHO 0,00 250 ,10 1.0 1,00 NO
ACTUAL RUN TIME) 39.900 MINUTES
, 22.32 22.32* 3.0060E- 4 384 86 .001 «A6HC1 23.30 23,30* 3.4897E- 4 1596 66 .006 *LINDANE
23,61 1,OOOOE- 3 283 66 ,003, 25,14 1.OOOOE- 3 451 86 ,005*• 25,39 25.39* 4.0797E- 4 983 66 ,004 «HEPTACHLOR
26,21 I,OOOOE- 3 007 66 ,006, 26.40 26,40* 2.7887E- 4 855 66 ,002 «ALDRIN1 26,72 1,OOOOE- 3 42366 ,004
: 26,89 1, OOOOE- 3 2906 66 ,029. 27,13 1,OOOOE- 3 270 BB ,003
I 27,30 I,OOOOE- 3 344 66 ,003I 27.39 27,39* 3,7542E- 4 1619 66 ,006 »HEPTACHLOR EPOX1DE
, 27.69 t,OOOOE- 3 3103 66 ,031v 27.84 1.OOOOE- 3 1622 66 ,010 i
27.97 1.OOOOE- 3 1518 66 ,015 i, 28,11 t,OOOOE- 3 1045 66 ,010v 28,30 1,OOOOE- 3 3573 66 ,036
26,43 I.OOOOE- 3 598 6B ,006( 28.54 28,54* 4.1735E- 4 1815 60 ,000 «A ENDOSULFAHV 28,67 t.OOOOE- 3 523 66 ,005
28,74 t.OOOOE- 3 965 66 ,006, 28,88 28.88* 6.1501E- 4 1067 66 ,011 *DDEv 29.04 I.OOOOE- 3 10673 68 ,107 |
29.16 29.18* 5.00B4E- 4 1195 BB ,006 4DIELDRIN '., 29.30 I.OOOOE- 3 474 66 ,005v 29,43 1.OOOOE- 3 > 1604 66 ,018
29,51 1,OOOOE- 3 541366 ,054, 29,75 29.75* 7.4945E- 4 16715 66 ,125 «EHDRIN '•
29.99 29,99* 7.2330E- 4 681 66 ,005 «6 ENDOSULFAN+PPDDD ,30,03 1,OOOOE- 3 539 66 ,005 \
. 30,15 I,OOOOE- 3 1383 BB ,014 '30,27 1. OOOOE- 3 315266 ,032 «--'~.O j30,37 1,OOOOE- 3 12417 BB ,124 LJO^V30.48 30,48* 9.9564E- 4 3383 66 ,034 *ENDRIN ALDEHYDE !30.60 1.OOOOE- 3 1079 66 ,011 i30,68 t.OOOOE- 3 1137 66 ,011 ;
' 30.60 I, OOOOE- 3 2615 BB ,026 19/17 '*" '30,69 1,OOOOE- 3 707 BB ,007 \C.1J j31,00 31,00* I.3403E-3 771066 ,103 »DDT non7fl331,32 31,14 8.4472E- 4 6137 8B ,052 DENDOSULFAN SULFATEVfru *w31 ,55 1 ,OOOOE- 3 13380 66 ,134 !n t i o < ft ft fl AP •»
NI* '
31 ,95 1. OOOOE- 3 7207 68 ,072
REPORT) 5210 (CONTINUED) PAGEi 2 PESTICIDES FOR IF6
* RT ITM FACTOR AREA UG/LKC NAME
( 32.08 1. OOOOE- 3 3702 66 ,037k 32.29 1. OOOOE- 3 10743 66 .107
32.41 1. OOOOE- 3 1094 66 ,011, 32.51 .OOOOE- 3 749 66 ,007
32,6132.82
i 33.06v 33.26
33,48( 33.59 33,67
33,8134.16
34.6434.72
35,1335,26
i 36.30-• 36,95
,OOOOE- 3 11270 BB ,113,OOOOE- 3 7543 BB ,075.OOOOE- 3 2972 68 ,030,OOOOE- 3 1646 66 ,016,OOOOE- 3 2855 BB ,029.3970E- 2 3393 68 ,474 fiDIBUTYLCHLOREHDATE,OOOOE- 3 323 66 ,003,OOOOE- 3 7805 08 ,076
/ 34,33 .OOOOE- 3 2107 BB ,021OOOOE- 3 571 66 ,006OOOOE- 3 869 66 ,009OOOOE- 3 1783 66 ,016i 34,90
1 "•> '- OOOOE- 3 1609 86 ,016,OOOOE- 3 443 68 ,004OOOOE- 3 262 BB ,003,OOOOE- 3 635 BB ,006
37.23 1,OOOOE- 3 302 68 - .003/ 38,05 t.OOOOE- 3 1054 66 ,011
TOTAL AREA « 109672 TOTAL UGA.KG « 2,251
* PROCESSED DATA FILEi P0286 RAW DATA FILEl R0286
(
1244
f\ r- n • •«, i
020703
/ /
\
1245A/D Count!
88.00
88.00
84.00 S
•82.00 m;fecu u.
80.00 5 H
-28.00 z c
28.00 £ *
24.00 ft -•. "S22.00 I * g
20.00 *«S B f
tJ "•N BO
16.00 ? f
14.00 o• Tlin o
•12.00 P gU) EC
•10.00 o ..Tt 0)O r»H.ooo 5£
•6.000 u n
H.OOO g<n
•2.000
•o.ooo C-C-Ihii
•'. if •'•'• i
l
i
REPORT) 5294 CHANHELi 1 PESTICIDES FOR IFB(- SAMPLE) A1016 STD5.0 INJECTED AT 15t29i34 ON NAY 23, 1984
CfwULl ESTD METHOD! IFBP/1 SEQi C264OP SUBSQ/SAMP) I/ 58 BTLi 58
SL-KDTH MV/MIN DELAY MIN-AR 6UNCH( ,500 ,100 20,00 250 NO
SUP-UNK DVT ID-LVL REF-RTV KRTU KDIL-F ISOI HO 0.00 250 .10 1,0 1,00 NO
ACTUAL RUN TIME I 39.917 MINUTESI
21.0321.7022.1122.2922.9423.5523,8624.1324.4924,6024.6925.1825,4025.5625.8225.9626,0726.4326.5426.7827.0227.3827.4727.60
1. OOOOE- 31, OOOOE- 31, OOOOE- 3
22.291 3.J61B6E- 323.08 1.2983E- 2
t. OOOOE- 323.99 6.9859E- 3
1, OOOOE- 31, OOOOE- 3t, OOOOE- 31. OOOOE- 31, OOOOE- 3
25,40* 5.S024E- 31. OOOOE- 3t, OOOOE- 31. OOOOE- 31, OOOOE- 3
26,43* 5.4334E- 31. OOOOE- 31. OOOOE- 31. OOOOE- 3t. OOOOE- 3
27.47* 7.0639E- 3t, OOOOE- 3
2945 663769 BB3890 6618735 662448 663177 66'2824 6610996 BB305 BB3040 661911 6610637 6610230 663216 6610084 666325 663867 667600 662193 6611480 662169 86347 BB578 661265 66
,029,038,0391 678 wrtDHir1,318 «e-6tt€,032,197 <H> 8H6.,190,003.030,015.106,5fi3 KKEPTflCHLOR-,032,101,063,039,413 tftfcWHW,.022,115,022,003,041 »HEPTACHLOR EPOX1DE,013I
TOTAL AREA • 139631 TOTAL UC&XG • 3,102
1246 020711
ffjS-•"•"
JjfeIwB* ^
«.•——-—!
1
1
1
•t
X_-S
•88.00
•88.00
•84.00
•82.00
•80.00
•28.00
•28.00
•24.00
•22.00 g
-20.00 I
•18.00
•18.00
-14.00
12.00
10.00
-8.000
•8.000
•4.000
2.000(
n nnn
1 '247 1A/D Count!
i** xat>. Mx -0z cQ »M
01CO 2n65(!) 0>f (0Tt Oft.B ..B
•D itB Tl4J Ii.O•m OC C.H a0• oin oesU) CC•A ..CU Bru ri< LL
B ni-t CCtnen
,1 f> •AM' i!_ I
o rv
I
0207i*
I
REPORT) 5293 CHANNEL! 1 PESTICIDES FOR 1FB(-SAMPLE! A1221 STD5.0 INJECTED AT 14i39H3 ON MAY 23, 1984
( ESTD METHOD! IFBP/1 SEOi C2640P SUBSQ/SAMPi I/ 57 6TLi 57
SL-UDTH MV/MIN DELAY MIN-AR 6UNCH( ,500 ,100 20,00 250 NO
3UP-UNK DVT ID-LVL REF-RTU fiRTW KDIL-F ISO( NO 0,00 250 ,10 1,0 1,00 NO
ACTUAL RUN TIflEi 39,900 MINUTES(
RT 1TM FACTOR AREA UGiQKG NAME(
20.34 1,OOOOE- 3 3079 68 .03121.03 t,OOOOE- 3 4745 66 .047
( 21,78 1,OOOOE- 3 10698 68 ,10722,11 1,OOOOE- 3 6811 66 .06822,29 22,29* 3.6186E- 3 24543 66 .888 *f*HS
( 23,48 23,30 4.3612E- 3 487 BB ,021 ••LiHDA+IE'23,56 I,OOOOE- 3 331 66 ,00323,65 1,OOOOE- 3 2164 66 ,022
( 24,14 23,99 6.9859E- 3 1315 66 ,092 •P-OIIO124,90 1,OOOOE- 3 3053 BB ,03125,19 1.OOOOE- 3 1307 66 .013
( 25,42 25,4211 5.5024E- 3 569 66 ,031 »l'IEPT*OHfaOR25,83 I.OOOOE- 3 307 66 ,00327,61 27,46 7.0639E- 3 382 68 ,027 tllCPTHCtlLOR n
( 28,17 1.OOOOE- 3 336 BB ,003
TOTAL AREA = 60127 TOTAL UG^KG = 1,386
PROCESSED DATA FILE) P0300 RAU DATA FILE) R0300
1248 0207.13
x \
«.*
88.00
86.00
84.00 in• Tl Tt
H«," (n CQ(U U.
80.00 £H
•28.00 z £O 4J
28.00
I
g
24.00 Sr 01•s 03 W
22.00 I " ?
20.00 £ n> •anh 0) Tl
18.00 I tj "•S B U
1B.OO £
•14.00 o• CDSO)gin cc
•10.00 cu ..ro aiCU rl
•6.000 oi nn CC,000 I
to(-2.000
•0.000
1249A/D Counts _____
"020714
REPORT! 5292 CHANNEL! t PESTICIDES FOR IF6
-N SAMPLE) A1232.STD3.0 INJECTED AT 13i40iS5 ON MAY 23, 1984
( ESTD METHOD) IF6P/I SEQi CS JP SUBSQ/SAMPl \f 56 BTLl 56
SL-KDTH MV/MIN DELAY 'MIN-AR BUNCH( .500 .100 20.00 250 NO
SUP-UNK DVT ID-LVL REF-RTU XRTU HDIL-F ISO( HO 0.90 2SO .10 1,0 1.00 NO
ACTUAL RUN TlHEi 39.917 MINUTES(
RT ITM FACTOR AREA UG*L|G NAMEc20,3221,<1
C 21.7622.0822.27 22.27*
( 22.91 23,0623,9323.65 23.96
( 24,1124.5824.66
( 25,1625.38 25.38*25.54
( 25.6025.9426,05
.•OOOE- 3 1994 BB ,020
.flOOOE- 3 3336 66 .033
.OOOOE- 3 6466 BB .065
.OOOOE- 3 4727 BB .0473.6186E- 3 19619 BB .710 «ft*H£.2963E- 2 1129 66 ,147 «M)fTC,OOOOE- 3 1525 66 .015
6.9859E- 3 1217 68 .085 <H> BMC.OOOOE- 3 9372 BB ,094, OOOOE- .'J 1372 66 ,014,OOOOE- 3 657 BB .007,OOOOE- 3 9033 66 .090.S024E- 3 4873 66 .268 *HCPTflCm.OR,OOOOE- 3 1251 68 .013, OOOOE- 3 4681 66 ,047,OOOOE- 3 2709 66 ,027.OOOOE- 3 1351 BB .014
( 26,41 26.41* 5.4334E- 3 3628 66 .19726.52 1.OOOOE- 3 1423 86 .01426.76 1,OOOOE- 3 5427 BB .054
( 27.00 1.OOOOE- 3 1365 66 ,01427,36 t,OOOOE- 3 705 BB .00727.44 27,44* 7.0639E- 3 1862 66 ,132
( 27,57 t,OOOOE- 3 2790 BB ,02826,05 1,OOOOE- 3 1521 BB ,01526.15 1,OOOOE- 3 393 66 .004
( 26,89 28,09* 1.5503E- 2 252 BB .03929.16 29.16* 9.9292E- 3 443 BB ,044 »&ICLPnat
( TO.AL AREA - 99139, TOTAL UG^G * 2,243
PROCESSED DATA FILE: P0299 RAW DATA FILE) R0299
I
1250
\ i
•38.00
•88.00
.00 §
*.oo „,-$WM
•80.00 >
N.« g|1-28.00 $£
1-24,00 S o•x MS
1-22,00 I * g
1*0.001 «ak B Tl
18.00 J tl "•*s „ o
18,00 c"c.
14.00 o•
«•«> Isenccf-io.oo cu..
c&SH-ooo 3£hfl.ooo B!
rl CC
M.ooo I(n
1-2.000
•0.000T • •
• 1251A/D Count! ;V (
020718
REPORT) 5291' 'CHANNEL) 1 PESTICIDES FOR IFB
-s SAMPLE! A1242 STD5.0 INJECTED AT 12iS8i41 ON MAY 23, 1984
(' ESTD METHOD! IFBP/1 9EQiJg640P_ SU6SQ/SAMP) I/ 55 BTLi 55
SL-UDTH MV/MIN DELAY MIN-AR BUNCH( .500 ,t«0 20,00 250 NO
SUP-UNK DVT ID-LVL REF-RTW XRTM 8DIL-F ISO( HO 0.10 250 .10 1.0 1.00 NO
ACTUAL RUN TIME) 39.917 MINUTES
2121
( 222222
( 232324
( 242425
( 252525
( 252626
( 262627
( 272727
( 272828
( 282029
( 29
.03,76,11,29.94,55,88.13,60,68.18.40.56.02.96,07.43.54,78.02,38.46.58.78.06.17.77,91.17.01
2223
23
25
26
27
282929
,29*.08
,99
,40*
,43*
,46*
.40006-
.00006-,00006-,61866-.29836-,00006-,98596-,00006-,40006-,00006-.00006-,50246-,00006-.00006-.00006-,00006-,43346-,00006-,00006-.00006-,00006-.06396-.00006-,00006-.00006-
1,00006-1.00006-
,91* 1.55036-,17* 9.9292E-,81* 1.92326-
333323333333333333333333333232 i
235527593089
19061201431842295158982571126115945089524240227507329426360246095402323138030604613343250670S319405697349
BB6B686666BB66666666666666866666BBBBBB66666666BBBBBBBBBB66BB
.024,026,031,545 *A6MC "nf 4 M»s n.tf.. £D 1 WP— wTTW.032.160 j*n BMg,159.026,013,159,409 (IICPTHCMLOR,024.002,051,0291 346 ttflUii'RIM',025,099,023.014.217 »MEPTneHL8lll BPOKtPB •,046,003,025,007,003,063 *«*1 065 'iC> tCL&fHNt UO I wtnTwTTTTl
TOTAL AR6A * 129042 TOTAL UG^G • 3,113
PROCESSED DATA FILE) P0296 RAU DATA FILE! R0298
pC
• 1253A/D Count!
85w*
32So<m O
0,000
REPORT) 9281 CHANNEL) 1 PESTICIDES FOR IFB
SAMPLE! A 1248 STDS.O INJECTED AT 4)39)22 ON MAY 23, 1964
( ESTD METHOD! IFBP/1 869 i C2640P SUBSQ/SAMPt I/ 45 BTLl 45
SL-UDTH HV/MIN DELAY MIN-AR BUNCHC .300 ,100 20.00 250 HO
SUP-UNK DVT ID-LVL REF-RTU RRTW KDIL-F ISO( HO O.flO 250 .10 1,0 1.00 NO
ACTUAL RUN TIME! 39.917 MINUTESC
RT ITM FACTOR AR6A UG/LKG NAME
22.30 22.30* 3.6186E- 3 1371 BB .050 -flWHe->22.94 23.00 1.2983E- 2 608 BB .089 *B OHO
( 23,55 1, OOOOE- 3 3263 BB .03323.07 23,99 6.90596- 3 572 66 .040 tD DltC24.13 .OOOOE- 3 9168 BB ,092
( 24.60 ,10006- 3 1108 66 ,01125,18 .OOOOE- 3 11049 66 ,11025.40 29,40* .9024E- 3 6833 BB .376 »MEETReMLOR
( 29,56 , OOOOE- 3 3867 BB ,03925.62 .OOOOE- 3 15301 BB ,15325,96 .OOOOE- 3 9226 66 ,092
( 26.06 .OOOOE- 3 4203 BB ,04226,42 26,42* .4334E- 3 13648 66 ,742 Hhttttrftt26,54 .00006- 3 4130 BB ,041
( 26.78 .OOOOE- 3 21516 BB .21927,02 .OOOOE- 3 4464 66 .04527.37 .OOOOE- 3 5250 86 ,052
( 27.46 27,46* .06396- 3 9934 6B ,702 -»HEPTAtHLOR 'EPU27.58 .00006- 3 16762 BB ,16827,78 .00006- 3 1203 6B ,012
( 28.06 ,00006- 3 10067 BB .10128,17 .00006- 3 3600 BB .03828.32 .00006- 3 2065 66 .021
( 28.64 26,50 ,13996- 3 373 BB ,030 -tH ENCIOSULFHH28.78 .00006- 3 1909 BB ,01928.91 28,91* .99036- 2 2582 BB .400 WE-
( 29,04 ,10006-3 1929 BB .01929.17 29.17*9.92926-3 4627 BB .459 «*&>BUPR1H29.91 t. 00006- 3 1616 BB ,016
( 29,62 29,62*1.92326-2 , 2926 BB ,563 te30,16 29,99 2,49296- 2 292 66 ,072 tfl30,16 29,99 2,49296- 2 ,30,36 30.38* 3,11266- 2 419 GB .130 ICHUK1N HLfEHY*E
( 38. 98 1, «00«E- 3 1487 BB ,019 ________ ___31.20 31.20*4,46076-2 444 BB .196 *6NDOSULFAN~51JtF#ffi—32.06 1,00006-3 299 BB .003
( TOTAL AREA • 170011 TOTAL UG/LKG • 5,104
( PROCESSED DATA FILE) P0297 RAW DATA FILE) R0297 ^
' 1254 C "" 020713
• ssi 'O
Tl Tl<u... *ASI
"» ""REPORT, 5280 CHANNEL, .(. SAMPLE, A1254STD5.0 INJECTED AT 3,49,42 ON MAY 23, 1964
( 'ESTD METHOD, IFBP/I SEO, C2640P SUBSQ/SAMP, ., 44 BTL, 44
c -ms r?S ffiS H1MS!< -r -o -a REF:i«w
ACTUAL RUN TIKE. 39.908 MIHUTES
ITH HAHE
2857 6B. .0296110 BB ,43220450 BB ,2043096 BB ,031si56 66 > 052
. =*"•"»! ii J ——3 1383 BB ,014s5-—
1 SS Sili1 II ;g( S:S !:S!E' 55 B ..M( TOTAL AREA - 1BW76 TOTAL UG^<G - 1 8 , 1 1 1
PROCESSED DATA FILE, P0296 RAU DATA FILE, R0296
< ' "
1256so.
• 1257A/D Count!
N
Tl L.
*H
7• of» OH £
O
I
.-£
(.
EITP METHOD, IFBP/1 «•' M""1 MIIO'MW' •> » 8TU "
< S.-5JH .WHIN gig lift* BUNCH
REPORT, 5222 CMAHHEL, I KITIC10M FOR IF!
AI260 "D5.0 I"""" " """" °H "*Y "' ""
* VHK rs. "*c "EF:?T.M r«* «CTUW.'RUH HUE, 3».»I7 I1IMUTE8
« RT ITN FMTOR «RE« UC^B
01 93 t.noeiE- 3 -1" n >o<3• :« "
„«.: ";" :s! s™. «s20.12 30,08 7.2330E-4
*A 0*1 1 •OOOE- 3 1257 n
KB -. 17876 II
, SJ5B!! 31 •"••:»«!: 5 « :«»!'.JJ 00«E-3 niMM ,"S1 \.n I. OOOOE- 3 UI27IB ,l«as ii l.tOOOE- 3 931 ** '°'3ll tt tOOOE- 3 2il7 Bi -0»•." ioOE-3 377318 .03813 15 l.tOOOE-3 2»47 IB .2H»'» «OOIE-3 1H2«BI .<»»'77 I UOOE- 3 tl»t BB ••»»-, l i - 3 «77BB .M3
13 7S33,73
-u at I IOOOE- 3 749C3 BB .74iM'BI IIIIK-I 71»BB .017
'. _ ^ |§» « I IIOOE- 3 132BI BB .133»'l4 (OOK-3 17343 BI .173"•!: !«MIE-3 1141 BB .«!«' "olE-3 «3»M •«»
3 474 BB ,«OS
REPORT. 922! <COHTINUED) PAGE, 2 PE6TICIDE6 FOR 1FB
RY ITM FACTOR AREA UC^KC NAHEv f, .-31.74 MOtQE-3 3t« BI .*3I L'..
TOTAL AREA • *J4»I6 TOTAL UC,<LKC * «.2I7
PROCESSED DATA FILE, P028I RAU DATA FILEi R02M n
Initial Calibration Data • Volatile HSL Conpunds (Cg. i)
Case No- SfegP— . M Contract Lab. FTR C.orn _____ Contract Ho.
"'Instrunent Identifier, n ____________ Calibration Date. p/4/84_
Hininun RF for SPEC is 0.30
_ RF RF RFConpound RRT 45 160 360 RF 6PCC
Methyl chloride .163 ,414 .387 ,389 ,397 tMethyl bronide .273 .254 .129 .080 ,154Dichlorodifluoronethane .323 .030 .040 .040 .037Vinyl chloride ,337 .375 .369 .276 ,340Chlortethane .432 .287 ,259 .231 .259Hethylene chloride .653 .739 .469 .436 .555Trichlorofluoronethane .876 1.788 1.797 1.6B3 1,756l,Hichloroethylene .952 1,128 1,10? 1.099 1.1101,1-Dichhroethane 1.064 1.386 1,314 1.300 1.333 I1,2-Trans-dichloroethylene 1.069 1,128 1.061 1.043 1.077Chloroftrn 1.223 2.453 1.967 1.929 2.1161,2-Dichloroelhane 1.294 1.410 1.136 1,126 1,2241,1,1-trichloroethane .739 ,828 ,737 ,720 ,762Carbon tetrachloride ,756 ,820 .775 .746 .780Dichlorobrononethane .769 ,612 ,768 ,770 .7631,2-Dichloropropane .658 .525 .494 .482 .500Tran5-l,3-Dichloropropylene .872 .734 .736 .716 .730Trichloroethylene .901 .681 .572 .605 .619!Chlorodibrononethane .934 ,781 .606 .825 .805Beniene .924 1.673 1.541 1.480 1.5641,1,2-Trichloroethane .940 ,523 .476 .463 ,488 ,cis-l,3-Dich)oropronylene .936 .740 .691 .661 .697 ''2-Chloroethylvinyl ether .993 .424 .329 .323 .359 tBronoforn 1.S73 ,534 .566 ,623 ,581 *1,1,2,2-tetrJChloroethane .969 ,573 .557 .515 ,546 ITetrachloroethylene .969 ,672 .799 .732 .801Toluene ' 1.041 1.660 1.453 1.374 1,502Chlorobeniene 1,089 1.376 1.29S 1.213 1.296 . IEthylbeniene 1.166 3.176 1.932 1.777 1.9622-Propanone .727 ,539 .251 .354 .3612-Butanone 1,286 ,977 ,556 ,501 ,6'/8Carbon disulfide .619 2.337 2.342 2,241 2,3072-Hemnone ,976 ,J<9 .346 ,345 -m-4-n>thyl-2-nentanone ,910 .572 .475 .479 ,509 'Styrene 1,308 1,279 1,151 1,077 1.169Vinyl acetate .752 ' ,009 .045 ,035 ,030ortho-Xylene 1,316 1,360 1,230 1,304 1.298 (Conc=3B,150,308)
RRT - Average Relative Retention Tine
RF - Response Factor (subscript is the anount in nanograns) ,r&. f. ±**
RF - Ai/erage Response Factor t/'J
,.SPCC - Systen Perfornance Check Conpoundf, (those conpounds flagged Mith an t)
tIi.
I
Initial Ciilbritim liti • VilitiU Ha CiA»itids <P«,. 1)Cm MI. 6698- ftA ctnUKt u>. ETC porff) ___ cwtraci MI,.MirtMM Mntlfitr, C ___________ CrtliMilm Htn ?/iO/6«
tw »CC it
_ IF IF IF „Ml 45 ill Ml IF ttCC
Htthil ckliPlfc .111 1.548 1.241 1.274 1.142 IBtihfl krwidi .251 1.185 1.124 ,117 1,117lUMirrflfUiriMlkMi ,H2 1.IU 1,193 ,833 ,W6Vinjl rtliridi .'Ml 1.116 1.S71 l.C» 1.433QiUrHliim .371 .ttt .m .*W .HIn»ttjl«i chlwUi ,S82 I.W3 t,t3T ,t!9 1.K3TrtchltrofliirtMtkMi .141 1,171 I.IK 2.ZK 1.787l,HUhlir»t»HlM .735 1,187 1,113 1.377 1.4731,1-liChliTMtltMi 1,177 4.1M 2,533 1,276 1.D3 »l,2-TpMHickliriith|ltnR I,ITS 3,173 1.7K MBS 3.M7Chlirtfirn 1,175 5,177 5.*K 1,147 4,744l,MlchlirHttaM 1.J64 1,472 1,112 1.572 1,115l,i,t-tricUirottliiRt .712 .717 .717 .724 .726Ctrlin titrichUrUf .731 ,Mt .Ml .463 ,M4liCRUriir«MMthMB .772 .774 ,774 .717 .786t,2-liclilH»priBMtf ,M4 .113 .573 .STB .STBtPMi-i,3-llrtlK»»rtf»l«M ,H2 .774 .158 .771 .114rlcklirHth7ltM .074 .447 .S87 .$87 .414OHiridlkriMRflliini ,731 .777 ,744 .747 .744Hflim .717 2.114 1.871 1.843 1.723
.734 .531 .444 .471 .477.714 .157 .817 .118 .128
«Mr .777 .148 ,144 .131 ,1481 *•rmfir* 1.112 ,473 ,457 .715 .482 tl.l.Z.MilPKMtfMItm* .787 .754 .487 .475 .711 ITBtridiUriitkfliM .787 .777 .765 .717 .741TilNM I.MS 2.1J4 2.145 1.742 1,147Chl»p«blflIWl 1.174 1.471 1,427 1.515 1.411 tElkilktMtAt 1.174 2.M7 2.437 2.241 2.4122-r>i«ntw .454 2.73S 1,447 1.121 1,142MIIMIM 1.157 2.443 1.471 t.142 1.757drkiR ilnlfl«* ,748 2.477 2.725 2.122 2,442MtaiMMM .774 .417 .128 .132 .1444-tttth7l-2-*MUMM .714 .575 .451 .474 .M7•firm t.Ht 1.225 l.in i.m 1.172ViRflKiUti .771 '.145 .184 ,157 .147<Mki-XfUw_______ 1.3*1 1.774 1.747 t.4M t.718 (Cm-it.lSI.MI)
Iff- MlTI4jl llUliM (BTntlM TIM
If - (HBIRM FKIIT (ukwrlit ti tttt HIMI U Mniirtn)if - MWH. IHBNH F*ttir Cju
-fifCC - IfMtAttrflPMnM CktCk CMflMft IthlH CllfllMl flHfttf Ultk M I)
Qram« • 1260
Initial Callbratiin Data - ViliUlt H8L Cinpmds (Pg. 1)C»w Ni, ffoPD frth Ciniract Lab. pTC Corp.____ Cimrid Ni. ,<p.tv'0/"67_fiy'Intir»Awl Idmtlfliri C____________ Cillbratiin Uln 5/17/B<»
HlnintA IF fir SfCC U l.3«
_ IF IF IFMT 45 181 361 IF »CC
NUhfl chlirMt .185 1,634 1,381 1,424 1,481 In*th»> bnnldi ,255 .754 .761 .555 ,757Dichlirrimnrmthint .»! ,787 ,141 ,757 .774Vinjl chliridi ,315 1.147 1.376 1.173 1.244Gtiliridhani ,311 .839 .855 .741 .818Ittthrliri chliride ,588 1.818 1,145 .777 1.281TfiChlinfliirwtlhMi .843 3,178 2.BII 2.442 2.847i ,1-RichliriHhf 1m ,735 1.865 1.779 1,617 1.7541,1-DUhliruthani 1.197 2,478 2,277 2,182 2,312 *1,2-lranHichllMHhflini 1.174 2,252 2,137- 2,159 2,147Ctilirifirh 1,273 3,757 2,134 2,671 3,1881,2-nichlirnthlBf 1.361 2.332 2,113 2.132 2,1261,1,1-trichlirHthine ,711 ,527 ,725 ,737 ,664Ctrbtn tltrachltPid* ' ,733 ,743 ,681 .726 .716llchUribriAiMthint .771 1,161 1,111 1,123 1.1311,2-Dlchliripripani .844 ,424 .574 ,577 .616
i 1rani-l,3-DlchliriBnpfUne .861 .713 .425 .712 ,677Trkhlirilthjlwe ,873 ,427 .616 .575 .613ChltnditriAtMthmi .731 ,857 ,816 ,814 .131Hwtni .719 2,1(1 1.735 1.873 1,7671,1,2-TrichlirMthani ,735 ,525 ,476 ,472 ,478ri«-i,3-PlchUriprip|>ltnt ,735 ,734 ,676 .713 .7182-Chlirinhfliinyl ithir l.lll .169 ,121 JIB ,1321 »Krinifirn 1,181 .645 ,455 ,713 ,471 t1,1,2,2-Tttrachliriithant .787 ,723 ,456 ,659 ,681 *Tftrichliriithflinl ,771 1.178 1,176 ,775 1,183Tllilfll 1,145 2.454 2.248 2.147 2.251Ctilinbtnint 1,177 2,166 1,824 1,661 1.851 tElhrllMIMt 1.177 2.814 2.546 2.346 2,5452-Pripanont ,481 1,431 ,756 ,776 . 1,1212-litantnt 1,343 1,454 ,878 ,878 1,143Carbin diiilfidi ,772 3,727 3,518 3,483 3,6432-HBMnini .776 ,547 ,317 .351 ,4154-flMhyl-2ftntanini .114 .516 ,451 .514 ,471Styrni l.Jll' 1,377 1,244 1,146 1,263Vinyl acititf ,751 ,715 .457 .552 ,571irthi-Xflm 1.317 2.195 1,585 1,432 1,771 (Cinc>3B,iSI,3H)
Rl- diiragi Rilatlii litmtiin TiM
IF - Ittfinu Factir (uiicrlpt U thi iniint in
IF - Awagt Itnfinu FactirSfCC - SyitM firftrnanci Ctnck Ciiviindi (thm ctnpiindi flaggid ulth in I) 0 c.U ( <- p
i Vv
m. ' 1261
Initial Calibration Data - 6itiiiolatilt HSL Cinpinds IPg. 1) ttft
Nn g6jO Cmtract Lab. ETC Corp. _____ Cintnct Ho. 66-01-67*6. _
Idtntlfltf . PE/MB E _____ ' Calibratiin Put. 5/21/Bf
Tii 1. 81. Iteilmn NT U L2LHlniAin I? fir SPCC K £J£,
__ IF IF IFCinpund HIT 21 111 211 IF JPCC
N-mtriiidiMthfliitint ,-,432 ,873 ,737 .814 .675bis(2-Chlirifthyl) ithir ^ ,747 1,284 1.126 1,114 1.1722-Chltriphtnil ,752 ,751 ,761 .871 ,734 (Cinc«4l, 110,210)Phtnil ,727 1,542 1.589 1,515 1,545 (Cinc,>40, 110,200)1,3,-Pidiliribinimi .787 1,141 ,861 ,726 ,742M-tickUriBtnitni 1,115 1,171 ,881 ,867 .7471,2-tichlinbifliini 1.158 1,121 .717 ,831 ,923bi6(2-ChUni«ipripyl) ithir 1,104 2,202 1,711 1,198 1,737Htuchliriithinf ,624 .177 .171 ,12t .078N-NiiriiidH-prip|flinini ,824 ,413 ,401 ,353 ,389 tHitribmiKie .847 .585 .591 .531 ,549Ir.ophinne .713 .757 .746 .941 .9482-Mtriphwil .722 ,176 .174 ,181 .171 (Cinc'4l,llO,2H)2,4-PiMthylphtflOl ,740 .373 .398 .411 .401 (CincMO, 100,200)biit2"ChUrf1hi»y>«ttnani .763 .559 .553 ,471 .534J,4-Dichlcnph(nil .774 ,271 ,272 .256 ,273 (Cinc-40, 101,200)1,2,4-Trichliribtnzmt ,773 ,271 ,274 ,312 ,282
;Haphthaltni 1.105 1,175 1,179 1,145 1,146HmachliributadiKit 1.152 ,127 .137 .208 ,159p-Ctilin-ntmil 1.150 ,420 ,411 ,340 ,370 (Cinc«40, 100,200)Htuchltricylipintadiini ,860 .434 .324 ,271 ,343 I?,4,6-TrichUnptiinil ,878 ,384 ,391 ,357 ,377 (Cinc-40, 110,200)2-ChUnnaphlhilmt ,703 1,284 1.214 1.069 1,186tetnaphthalwe ,773 2,241 1,855 1,717 1,934DiMlhyl phthalati ,773 2,016 1,700 1,513 1,744?,6-Dinitr»tolitnt .783 .281 .354 ,257 ,277Acmiphlhmt 1,005 1,441 1.303 1,135 1,301?,4-Pinitr»phmol 1,020 ,161 ,171 ,155 ,169 I (CincMO, 110,200)2,4-tinitntilitni 1.046 ,582 ,573 ,571 ,5824-Nitnphinil 1,015 ,135 ,227 ,246 .203 I (CinC'40,111,200)Fliirini 1,070 1,820 1,563 1,467 1,6174-Chlinphmrl phinyl ithr 1,074 ,742 ,467 ,651 ,687Hithyl pMhalati 1,074 2.242 1.701 1,716 1.7534,6-Pinitri-i-criHl 1.115 ,067 .106 ,174 ,170 (Cinc'40,101,200)Piphwyliiiini - il,2-Diphtnrlnydr«!int 1,122 2.851 2,667 1,876 2,4664-Brintphinyl phmyl ithir ,745 ,263 .267 ,249 ,260
RtUti«i Ifitntiin Tint
IF - Inpintt Factir (ubicript U ihi aniint in nintgrms) n - <* ' jf1_, t'J"1**IF - Anra;c Rnpinit Factir
SPCC - Syittn Perfirnancf ChKk CiApundc I thin cinpiindt fliggK vith an I) 000 7!? 7-
Funix ' 1262
i I
Initial Calibratiin Pata • Stniiolatilt HSL CiApvnds (Pg. 2) ify? iCue Hi. 8640 Ciniract Lab. ETC Corp,____ Ciniract Hi.In?.trii*nt Idmtifiif, CC/HB E________ Calibratiin Pitt. 5/21/84
NinlAinlTf ii OJO ItailAin MT il L2L
HiniAMRFfir SPCC ii I IS
__ IF IF IFCinpnnd . IIT 21 110 200 IF
Htiichlinbtnitn*Pentichliriphmil ,765 .078 ,167 ,103 ,117 <C«nc«40,100,201)PhtninthrmftnthracifllDH-bitjl phthilittHuiran thinePyrmiPenzidintiitjl bitiiyl phthalateIcniilDintnrictntChryiwi3,3'-ticnliribtniidinibil(2-Ethflhliyl)phthlll1lDi-n-ictfl phthalatekniKblflitriMlntntknzilk)fl«iranthioitmiKDprrmiIndMi(l,2,3t,d)pKtntlibinii(a,h)anthricmitenitlghDptrylm*Anilinetrniiic acid .772 .171 .085 .031 .102 (CincMO,100,210)Btniyl ilcihil4-ChliroanilintPibtntifinnJ-ntthylnaphthalent2-flithylphmil 1,095 ,778 1,182 ,728 1,003 (Cinc-4l,'.IO,2IO)4-Methflphiflil 1,141 1,446 1.595 1,427 1.487 (CincMO,100,200)2-Nitrianllini3-Nitnaniline4-hitrianilint2,4,5-TrUhltnphtnil ,883 .431 .403 .340 .371 (CincMO, 100,211)
IRT - A»ragi Rilatiit Idtntiin tintRF - Ittpinit Factir (nbttript ii thi aniint in nanigraw) r o • \<}
IF - Aiir«gi Rnpinn Factir ,SPCC - Syitin Pirfirnanct Chick Cinpundt (thiH cinpiindt flaggid nith an t) 0^6 ' **
FMH IX " 1 263
Initial Calibratiin Data - 6eniiolatili H8L Ctnpundi (Pg. i) f8J
t»« Hi. 2MQ Contraci Lab. ETC Corp._____ Cintract Hi. 6B-01.-67A6
InitMMnt Idmtifitr. PJC/HB E________ hlibriiiin Dan. 6/04/84
Minium RRT it j.8,0. HaiiAin RlT ii L2L
KiniAun RF fir 8PCC ii 0.05
__ «F *F IFCinpiind IRT 20 111 200 TF ffCC
N-NltriiidiMthjlMiM .421 .446 ,519 .563 ,510bistJ-Chliriithyl) ithir ,948 .836 ,706 .700 .8142-Chliriphmil .951 .832 .818 .905 .852 <Cinc*40,100,2ll)Phcnil .131 .79? .753 1.17? 1.010 (Cinc'10,100,208)1,3,-PichliPtbMitM .789 1,006 .838 1.0(8 .7511,4-Dichliribnitni 1.105 1.022 .841 .976 .7531,2-DUhlinbtniini 1.058 1.002 .814 .988 .735bi5(2-ChloriUipropyl) ithir 1.105 .960 .621 1.263 1,021Huachliriithant ,824 .127 .125 ,115 ,122N-Hitritidi-n-pripylaAini ,825 .247 .274 .265 .262 tNitnbmmt .850 .447 .453 .456 .452Uinhtnnt ,903 ,655 ,710 .673 ,6662-Hitriphinil ,721 .144 .189 ,187 ,174 (Cinc>40,100,2IO)2,4-Dinethylphinil ,941 .313 .271 .266 .280 (Cinc-40,100,200)bit(2-ChlirilhiKy)AHhane .764 ,345 .374 ,369 ,3632,4-DicMinphinil ,775 .206 .271 ,258 ,252 (Conc>40,100,200)1,2,4-lruhliribitiiini ,793 .351 .331 .306 ,330Naphlhalini 1,005 1.156 1.102 1.013 1.071Hmachliribittdiini 1,152 ,221 .204 ,205 ,210p-Chlirnt-criiel 1,153 .210 .317 .284 ,270 (Cinc«40,100,200)Hf«achliricylipmiadiin( ,B62 .237 ,342 ,382 .320 t2,4,6-Trichlinpnintl .878 .366 .423 ,397 .395 (Cinc-40,100,200)2-Chlinnaphthaltni .903 1.201 1.136 1,076 1.144ftccnaphthalnie ,773 1.991 1.64? 1,707 1,915Dinithyl phthalati .774 1.722 1,683 1,578 1,6682,6-Binitritiluine ,783 W ,311 ,280 ,277Aciniphthme 1.005 1,357 1,261 1,160 1,261?,4-tlnitriphinol 1,019 ,141 ,174 ,194 ,070 » (Cinc>40,100,200)2,4-Dinitritiluint 1.046 ,393 .475 .412 ,4274-Nilnphinil 1.036 .139 .086 .106 ,078 t (CincMO,100,200)Fliirmi 1.090 1.322 1.365 1,303 1.3304-Chliripninfl phtnyl ithir 1.096 ,472 ,541 ,506 ,513Diithyl phthalati 1,094 1,329 1.503 1.335 1.389-1,6-Plnitri-o-cruol 1,113 ,069 ,177 ,176 ,141 (Ctnc'40,100,200)Dlphmylwini • '),f-tiphmylhydraiini 1.121 ,927 1.173 1,115 1.0714-BriAiphmyl phmyl ithir .945 .310 ,322 .323 .315
RRf - Aviragt Rilaliii litintiin Tin*r» ' * \RF - RitpinH Factir (ubicript U thi anovnt in niniqram) C Jw
IF - nviragi Riipinw Factor
6PCC - Syttin Pirfirnanci Chick Cinpiundt (thosi cinpundt flagged Mith an t)
FMn ix " 1264
Initial Calibratiin Data - Stnitolatile HSL Canpunds (Pg. 2) fft
Ho. 2&4Q Ciniract Lab. ETC CQPP. ____ Cintrtct Hi. 6.3-01-67*6Inctrmnt Idtntiflir. pg/MS E ________ Calibrattin Dati. 6/Q4/B4
MniAin RRT it I JO., HiilmA IRT ii 11L
HinlMA RF fir 8PCC U 1.05
_ IF IF IF _Cinpiind IRT 20 100 211 IF 8PCC
Huachlinbtnimi .961 .617 ,492 ,577 ,559Ptntachlinphinol ,786 ,064 ,073 ,102 ,086 ICincMO, 100,200)Phtnanlhrmi 1,103 1,007 1,011 .776 .77?ftnthricint 1.019 .749 1,011 .775 ,785DiTi-bilyl phthalati 1.09B ,311 ,603 ,453 ,51?Flmrtnthine .657 2.276 1.795 1.617 1,770Pyrmi .876 2.269 1.890 1.882 J.02IPtnzidlni .675 .067 ,101 .209 .126 tButyl binzyl phthalati ,756 ,368 .674 .716 .584Bffl7i(a>anthracini .996 1.205 1,353 1,337 1.278Chrytmi 1.003 1,367 1,257 1,24? 1.271•.',,3'"Dichlirit,tnzidlni 1.001 .042 .42? .434 ,302bii(2-Ethylhf»yl)plithalali 1.018 ,48? ,655 ,723 .622Wti-iciyl phthalati 1.076 ,51? 1,114 1,240 ,758Mnzi(b)flnro<nthini 1.110 1,168 1,311 1,345 1,271HcnzKOfluiranthini 1.102 ,694 1,082 1.175 1,050hnzKalpyrmf 1,129 .735 1.083 1.191 .770)ndmi(i,2,3-c,d)pynn( fl.251 .733 1.047 1.107 .763DibmztU,h)anthractni 1,255 ,302 ,881 ,714 ,67?l!raii(9hi)pirylint 1,284 ,4?? 1.138 1,126 .921Anilint - .926 .810 .741 1.353 .768licntiic acid ,777 ,040 ,136 ,117 ,094 (Conc=40,100,20o)Imzyl ilcihil 1.057 .526 .578 .783 .62?4-Chlirianilini 1.031 ,370 ,418 ,516 ,43?Pibinzifiran 1.032 1.684 1.746 1.69? 1.776MKthylnaphthalini 1.171 ,79? .816 .703 .8002-mthylphMil 1.100 ,646 ,661 ,731 ,67? (Cinc«40, 100,210)4-hPthylphwil 1,146 .811 1.154 .89? .955 (Cinc»40, 100,200)2-Nitrtanilint .932 .27? .455 .513 .4127,-Hitrianiline 1,103 ,423 ,465 .614 ,5084-Hitriinilini 1,106 ,046 ,205 ,18? ,1472,4,5-TrichUnphtnil .883 .342 .347 .395 ,361 (Cinc"40, 111,200)
i
RRT - Aviragi Rilatini Ritmtiin Tint ;
IF - RiipinM Factir (tibicript U thi aniint in nanigrani) " ^ •*"*'' i
IF - Avirage Ritpinii Fictir j
.SPCC - Systin Ptrfirninct Chick Cinpivnds (thitt cinpiindt flagged uilh an t) 02v • ,• 1265 96 r
FORh IX !
Calibration Check - Volatile HSl Conpunds (Pg i)
Case Hn-Pfa^Py^fA Contract Lib: ETC Corp. _____ Contract No 'Qrw »0
Instrunent Identifier. 2_ ____________ Calibration Date. S/4/Bfl
Standard File. >Pi994i .in _____ Date. 5/B/B4 TiAe. i 0 ISHRS
Haninun X D for CCC is 20 Hininun M for 5PCC is 0.300
Conpound RF RF U CCC SPCC
Methyl chloride .397 .375 5.S45 ttMethyl bnnide .154 .143 7.166Dichlorodifluironethane .037 .043 18,288Vinyl chloride .340 .321 5.720 IChliroethane ,259 .230 11,238Methylene chloride .555 .512 7,721Trichlorofluoronethane 1.756 1,692 3.6491,1-Dichloroethylene 1,110 1.066 3,764 I1,1-Dichloroethane 1,333 1.348 1,06) t*1,2-Trani-dichljroeihyUne 1.077 1,014 5.917Chloroforn 2.116 2,024 4.369 I1,2-Dichloroethane 1.224 1,165 4,6411,1,1-trtchloriethane ' .762 .671 11,836Carbon tetracnloride ,760 ,646 17.257Dichlorobrononethane .783 .731 6,6651,2-Dichloropropane ,500 ,476 4,967 Itrans-l,3-Dichloropropylene .731 ,663 6.376Trichloroethylene .619 ,558 9.714Chlorodibrgnonethane ,605 ,725 9.870Ben:ene 1,564 1,417 9.4101,1,2-Trichloroethane .468 .436 10.597cis>"l,3-Dichloropropylene .697 .632 9.3002-Chloroethylvinyl ether .359 .333 7.172 ItBronoforn .581 .465 19.912 It1,1,2,2-Tetrachloroethane .548 .503 8.125 tlTetrachloroethylene .601 .629 21.506Toluene 1.502 1.306 13.061 ICnlorobensene 1.296 1.148 11.396 ItEthylbenzene 1.962 1.760 10.2912-Propanone .361 .405 6.0662-Butanone .678 .563 16.918Carbon disulfide 2.307 2.414 4.6602-Heianone .345 ,309 10,4254-Methyl-2-pentanone .509 ,451 11.354Styrene 1.169 1.063 7.363Vinyl acetate .031 .102 241.356ortho-Xylene 1.298 ' 1.321 1,801
RF - Average Response Factor fron initial calibration F«rn IX
RF - Response Factor fron daily standard file
J D - Percent Difference
CCC - Calibration Cherk Conpounds (those conpovnds (tnose conpounds fltggtd Kith an t)
' SPCC - Systen Perfornance Check Conpounds (those conpounds flagged Hith tt)
FQRUX " 1266
Calioration Cnecu - volatile nSi Conpunds (Pg. U
C«e Noi.gf.VP" frfc Contract Lab. ETC Corp,____ Contract No. 61*0 M?) fro
Instrunent Identifier, D____________ Calibration Date. 5/4/FU
^ 6tandard File. >DgQOl. .Ul______ Date. 5/H/Bt _ Tine. ISODHKS
Maxinun I D for CCC is 8.0 Mininun RF for SPCC is OJOO
Conpound RF RF ID CCC SPCC
Methyl chloride .397 ,389 1.824 ttMethyl bronide .154 .129 16,246Dichlorodifluoronethane .037 • JJSO —,Vinyl chloride .340 ,266 (WAUtjJChliroethane .259 .227 TT517Methylene chloride .555 .477 14.032Trichlorofluoronelhane 1.756 1,495 14.8321,1-Dichlortethylene 1.110 1.113 .272 Ii,Bichloroethane 1.333 1.400 5.002 It1,2-Trans-dichloroethylene 1.077 1.061 1.500Chloroforn 2.116 2.113 .130 t1,2-Dichloroethane 1.224 1.214 .8311,1,1-trichloroethane ,762 .676 11.294Carbon tetrachloride .780 .656 15.934Dichlorobrononethane .783 ,785 ,2141,2-Dichloropropane .500 .478 4 467 Itrans"l,3-Dichloropropy)ene .730 .668 5,721Trichloroethylene .619 ,553 10,615Chlorodiorononethane .805 ,753 6.4VBBenzene 1.564 1.403 10.2??
; )l,l,2-Trichloroethane .488 .436 10.540ci$-i,3-Dichloropropylene .697 .654 6.1V42-Chloroethylnnyl ether ,359 ,336 5.613 ttBronofcrn ,581 ,486 16.394 It1,1,2,2-Tetrachloroethane ,546 ,532 2,962 I*Tetrachloroethylent ,801 ,567 26.6?5Toluene 1.502 1,290 14.121 tChlorobenzene 1.296 1.094 15.563 ItEthylbenzene 1.962 1.691 13.6412-Propanone .361 .435 14,1692-Butanone ,678 ,640 5.689Carbon disulfide 2.307 1,040 54,9082-Henanone ,ffl *&%]. ,346 JM-»<.y4-nethyl-2-pentanone .509 .516 1,484Styrene 1,169 1,051 10,102Vinyl acetate ,030 ,167 460,929ortho-Xylene 1.296 1.309 ,650............................. ........ p...... ........ ... ....
R? - Average Response Factor fron initial calibration Forn IX
RF - Response Factor fron daily standard file
X D - Percent Difference« • "iCCC - Calibration Check Conpounds (those conpounds (those conpounds flagged uith an t) r>'" u ,,* l
SPCC - Systen Perfornance Check Conpounos (thise conpounds flagged with II)
FWIX • 1267
lanprtuon ineo • vnatue tat, lanpunoa ug. n
Cintract Lab. ETC Corp.____ Cintract Ho.Instrunent Identifier. 2____________ Calibration 'tite. g/4/B4 j
Standard Fill. >paoi4..ui______ Date. S/9/B4 Tim, 1040 HOURS jHuintn X D fir CCC is .JO Mlninim RF fir SPCC ii 0,30p . '
CiApovnd RF RF X D CCC SPCC
Hethyl chliride .397 ,335 15,601 ttMethyl brinide ,154 ,126 16.677Dichlindifliirinithane ',037 ,031 17,846Vinyl chliride .340 ,272 19,907 tChlinethane ,25? ,211 18.353Methylene chltrid* .555 .717 27.341 iTrichlinfliiriMthine 1.756 1,674 3,5131,1-Dichliriethylene 1.110 1,039 6.402 t i1,1-Pichliritthane 1.333 1,343 ,741 «1,2-Trani-dichliriethylene 1.077 ,976 9.432Chlirifirn 2.116 2,089 1,264 t j1,2-Dichlirieihint 1,224 1,164 4,862 |1,1,1-trichlirifthane ,762 ,664 10,239Carbin tetnchloride ,760 ,662 15,161PichloribriAiACthani .783 ,768 1.9751,2-Dichlortpripini .500 ,452 9,73V t jiran«-l,3-Dichlonpnpyline ,730 .679 6.945 iTrichlortethyltne .41? ,523 15,487Chlindibnninethane ,805 .759 5.689Btnzcnc 1,564 1,400 10,532 • |
M^i,l,2-Trichlir»thane ,486 ,446 6.510 (cii-M-Dichliripnpylene ,697 ,650 6,6702-Chlcrietriylvinyl ether ,359 ,319 11,124 tlBriAiforn ,581 ,495 14.756 It1,1,2,2-Titrichliroethani .548 .542 1,169 tlTetMChlorotlhyltne .801 .654 16,311 lTilvene 1.502 1.362 7,314 t ,Chlirobenzene 1,296 1,186 B.415 tt !Ethylbinuni 1.962 1.B09 7.8392-Pripanine .361 ,362 5,094 i2-Butanine ,678 ,552 18,660Carbon disulfide 2.307 ..2,431 S.3B42-Htiinini f ? *3*M()> <4-Meihyl-2-ptnlinin( .50? ,455 11,453Styrine 1,16? 1,158 ,733Vinyl acetate ,030 .114 261,751irthi-Xylint 1,278 1.380 4.278
|T - Awigi leipinii Factir fnn initial cilibritiin FIFA IX
RF - Rtipinii Factir fnn daily itandard fill
X D - Pircint tiffirincc.p r " ' ' "\CCC - Calibritiin Check C«npi»nds (those cinpunds (thoti cinpiunds flaggtd xith in t) C j" '''*"
SPCC - SysTcA-Ptrfirnance Chick CiApiunds (thin cinpiindt flagged Kith tt)
F6RMX 020 3
• ' 1268
s \
Clwcli - ViUllU HR CinBindi (Pg. i)"•' j' Cinlrict Lib. ETC popp. ____ Cintrict Mi,
Umtlfltri P. ___________ G«Ubritiin Mil, ?/4/B4Btindard Fill, >Daoao. .ua ______ late. 5/10/64 TIM. >4iO HOUR9
ItaiiAMi I D fir CCC if _J| Minium IF fir BPCC It 1 .318
CMfimd IF IF II KCttCC
Mlhil rtlirlde .377 ,»4 17,874 ttHfttijl briAidi .154 .113 33.114llcklirritfliiriMthint .137 .112Vinyl chlirUt .340 .247ChliriithiAi ,25? .177MttNyltni chlirtdi .555 ,543 2,136TricMirifliirimthini 1.754 1.461 14.7731,1-DUhlirtitHylMe 1,110 ,771 18,710 t1,1-tichliruthine 1,333 1.350 1,243 ttl,2-Trans-<licl»lir lit hy line 1,177 .771 7,771Ctillrifirn 2,114 2.111 5.424 t1,2-licr.liriethMe 1,224 1,172 4.2341,1,1-trlchUritlhini .762 .435 14,588Cirbm tttrithliride ,700 .581 25,572llckliribrMMilhifii .783 .717 1,4571,2-Dlehliripnpihe ,510 .445 7,144 ttrani-l,3-Jichliniripyline .731 .447 1.552Jrichlinilhylme ,41? .513 18.738tfcltfidibrmmthMi .615 .701 12.844If nine 1.544 1,33? 14,4041,1,2-lrlchlirHtHifll ,488 .442 7,470ei»-i,3-lichliripnpylenr ,477 .433 9.2122-ChliriithyliiAyl ithir .35? .331 7,758 ttIriAifim ,581 .441 21,673 tt1,1,2,2-TilrKMirmMM .548 .484 11.335 ttUtnchlirHtkFlm .801 .557 3UIITililfii 1.512 1.212 /STlttT)tChliriiniiM 1.274 1,045 W4»r ttEthylbmzini 1,742 1.441 14,3512-rripMint .381 .513 34.4312-HtmiAi .478 .471 1.23?
„„ 2,117 2.224 1,416
I.4-tkthil-2-pntMini p ,50? .518 1.744ttyrmt 1.16? , 1.134 11,423Vinilicttiti .130 .111 237.700
1.X78 1.217 4.571
iT- Aiwage iMftnu Fictir frm inilial calliratlin Firn IXIF - MifHM Fictir friA dill* ili»<ar< fill r. ••
V **
ll" Percent Hftirinci.'CCC - C4libr»tlin Chick CiApindi (ttiiw ciAfinds (tniu ciAiimli fla||«d nith M t)8PCC - fiynin PirfirMKi CkKk CtflpiiAdt (ihm ciApiiNi flinrt Him O)
F8IHX • " 1269
I
\ 1
Ulikritiin Chick - Vilitili H8L Cinpindi (P(, 1)
Caw NII ftiPq-tvfr. CwtrKl Uki ETf? Cjirp . _____ Cwtract Hi.
""wtrmiM IdiMifltN C ___________ Wlkrittin liti, P/1Q/B4(tlMirl Flit, ;>C210Bi .Ml lltl, 5/11/B4 TiM,
fc«iAiA X I fir CCC Ii Jl HlnlAM IF fir If CC it yjiff if xt atom
Hf thyl CtilwHi 1.342 1.484 7.104 ItHuhyl krinldi l.ll? 1.151 14.8508lcDHri<miiriMtkMi .f74 1.184 17.134Vinyl cklirMt 1.413 1.483 17,383 tCMirMtkm .M .770 11.817Mttbilm chlirlM 1.513 1.541 1.441TrtcMtTiflnriMtkiAt 2.787 3,115 15.34?l.HicMiriUKyliM 1.473 1.716 12.175 tl.HicMirMlkiM 3.333 2.524 24.217 nl,MrinHlcnlir»thiIffii 3.447 1.476 31 .512Oilirifirn 4.744 5.439 11.011 Il,2-licnlirHthin« MIS 1.485 12.225MiMMcMwMthMi .724 .711 .747Cariin mricdUrldi .444 .450 1.771llchltMbriAWilhaM .784 .771 1.140l.MichliriprKiini .578 .574 .770 *trn«-l,HicklirifripfliM .814 .153 4.410IrlcMiriithflini .414 .(88 4.424QilirMllkriMMtkiH .744 .754 .784«zw» 1.723 1.871 1.4571,1,2-TrirtllflltNlM .477 .454 8.277tii-l,3-lictilirifripylwi .828 .TJh 4,727KMiritlkilitiiil tlhr .848 (M 147.718 ttIriMfirii .M2 \& 4,540 ttl,l,2,MitrKklirMihMi .713 ,417 3,743 ttTltrKhlwHthlllftt .741 l.lll 5.124TilNM 2.147 2,127 1.182 tCMifikMim 1.411 1,714 4.380 ttEtAylimziM 2.482 2,11? 4.8742-fnpMMi 1.142 1.157 24.2272-fctMtM 1.717 1.472 14,128brim UtilfU* 2.442 2,751 21.7212H(»Miw .144 .M2 17.1834-tHlk7l-2-t«itMiM .187 .424 14.1238iirtM 1.172 1.242 1.174Vinyl Klllll .84? .857 14.781
1711 '1.817 5.713
IK - mwm litf MM Ficttr frtn Inltlil ullkritln FKA IXIF - IntMM Ficlir frM fclly itttiiNl fillI ti • PrcMt llffirfKi
V rfW '<XC - Ulikritlm Ckick d«fIM<I (tkiM cufiiMi (1km cnfimdi flifiH with M I)in4i (tFHU • J27Q
~y»CC - IfitiA ftrfM-Mnn Ckicl dffini:i (tkm CMpimdi fli|(td Mlth tt)
C«libratiin Chick - Vilatlli H8L Cinpindi (Pg. 1)
Caw Ni.'gffifciaj, Cinlrict Lab. EJC, Corn.____ Cintrid Ni.Initrimt Mwtlflir, fi___________ Cillbritiin liti, S/i7,ZB4Standard Flit, >C2214. .ill______ Dili. 5/ 7/64 Tint. 1215HR8
HaiiAin XI fir CCC U JU Minium IF fir 8PCC Ii 0.301CiApiiml IF IF XI CCC8PCC
Ntttiil chlirMi 1.481 1,381 4,795 ttMlkyl briAidl .757 ,741 27.141ttchliridlflnriMtkint ,776 ,841 5,584Vinyl chliridi 1,246 1,376 12.038 tCklirilthlN .611 ,655 4.563N»thylMi chlirldt 1,281 1,145 18.370TricklinfliiriMtkini 2.847 2,800 1.6451,1-DlchliriithylMt 1.754 1.777 1.426 t1,1-tlchliritthwi 2,312 2,277 1.538 tt1,2-Trani-dlchloriithylwi 2,14? 2.137 .582CMirifirA 3.188 2.634 8.228 t1,2-llchlarilthani 2.126 2.013 5.2711,1,1-trlchliriilhini .444 ,725 7,227Carbin titrachlirldi ,714 ,480 5,075DlchliribrwiiAithani 1,131 1,110 2,0581,2-Dlckliripnpani ,404 ,574 1.721 ttrini-l,3-lichliniripylrii ,477 ,425 7,57?TrlchlirHthylmi .413 ,414 .477Chliridibrinmthint ,831 ,618 1,476feniiflt 1,76? 1.735 1,7711,1,2-Trlchliriiihmt .478 .476 .430cit-l,3-Dichliripripylnii ,7082-ChlirHthyUlnyl tthir ,132Brinifirn .4711,1,2,2-TitrKhlinithani ,481Titrichliriithylwi 1,183Tllimi 2.251Ckliribmmi 1,650Ethyliwzifti 2.545?-Pripinint 1,1212-lninini 1.143Ciriin diulfidi 3.4432-Otunint .4154-Methyl-2-piflianini ,470fitirmi 1,243,Vinyl acitati ,571irtbi-Xylmi 1.771
IF - Amage IHPHIM Fictir frin Initial callkratlin Firn IXIF - Inpinn Fictir frin daily itandarl fill
XI- Pircml Mffiritict C .>« - J *CCC - Calibritiin Chick Cinpiindi (tniH cinpiindt (thm cinpiindi fliggid nitn in t) non7^SSPCC - lyttM Pirfirnanci CtiKk CiApiini4! (thin cinpundi fliggH Kith tt) SO ^
F«N> • 1271
Calibration Check - Vilitile HSL Cinpinds (Pg, 1)
Can Hir-efrye- fry Cintrid lib. ETC Corp, ____ Cintract Hi.
"*\ Iniirwent Idmtifiir, C ____________ Cilibritiin Datu 5/17/B4Stindird Fill, >C2231. .Ul ______ Diti. 5/16/84 Tint.
Huinin X D fir CCC is _2! Mininin IF fir SPCC it U!»
IF »F ZD CCC SPCC
Hithyl chlirtdi 1,481 1,142 28,246 ttMethyl brinidi ,757 ,878 18,706DkchliridlflMMAtthine ,776 ,73? 7,173Vinyl chliridi 1.246 1,235 ,914 tChliriRthini ,818 ,742 7,255Htihflin* chliride 1,281 1,124 20,063TrichlirifliiriMthint 2.647 2,471 5,4801,1-DichlirnthyUne 1.754 1.577 10.064 t1,1-Dichlinethani 2,312 2,163 6,471 ttl,2-Tr«ni-dichlirnthyl«ne 2,149 2,111 2,226Chlirifirn 3.086 2,765 10,461 t1,2-Jichliriethane 2,126 2,116 5,1531,1,1-trichlirnthini .464 ,76? 15,56?Cirbin tttrichliridi ,716 ,741 3,427Dichlinbrinimthini 1,031 1,13? ,7621,2-tichliripnpane ,606 ,413 ,423 ttrini-l,3-tichliripnpyUne .477 ,746 10,212TrichliriUhylltie ,613 ,610 ,542ChliriiltbriAiAtthini .631 ,836 .422
i ) Itnzine 1.96? 1,745 1,2421,1,2-Trichlirnthine ,478 ,471 1,290cii-i,3-Dichliripripylent ,708 ,758, 7.0782-Chlirnthyliinyl ithir .032 (**$> 30,72? tlBrmfirn ,671 ,474' ,38? tt1,1,2,2-Tetrachlinethane ,681 ,6??' 2,825 ttTitrichliruthylenf 1,183 1,143 1,862Ttlimi 2,251 2,278 1,221 tChlinbinieni 1,851 1,826 1,300 ' ttEthylbmzwe 2,545 2,54? ,1282-PnpiniM 1,121 1,104 10,4332-Bitanini 1,143 ,844 26,047Ctrbin diiilfidi 3.443 3.582 1,4412-Htunine .405 ,32? 18.8004-Mf1hyl-2-pentinine ,470 .444 4,849etyrwe 1.243 1,287 1,701Vinyl acetate ,571 .411 5.145irthi-Xyltne 1,771 ' 1,439 7,414
RF - A«erigi Inpinii Fictir frin initiil calibration Firn IX
IF - Rinpinw Fictir fnn diily tundird flit
X D - Pircint Difference
CCC - Calibration Chick Cinpnndt (thost ciAf>nnd« (this* ctnpiind» flagged Kith in t)
""' SPCC - Syjtw Pwfirninci Check Cinpiindi (thin cinpiindi flagged »ith tt)
I
Fmnx 1272
\ \
Calibration Chick - Smiitlatilt HSL Cinpinds (Pi). I) • W
G«i Ml. 2640 Cintrict Lib. ETC Corp,____ Cintract Ni. 69-01-fe7<X5
mitrinmt Idmtifiir. CC/HS E________ dlibritlin Dm. 5/ai/B4Stllrfird Fill. >E219i. .U3_______ Dltl. 5/22/84 Tim. 4.00
Maiinin X D fir CCC ii _j£ MlnlAin IF fir SfCC Ii OJI5I
Cinplinf IF IF XD CCC SPCC
(HdtriiidiMttiylanini .675 ,774 9,229bii(2-Chlirnthyl) ithir 1,172 1.183 1,0012-Chltnpkmil .734 .714 2,191Phenol 1.S45 1,551 .272 I1,3,-tlchlinbmzmi .742 ,726 1.4781,4-Dichlinbmimi .947 ,740 1.351 t1,2-Dlchloroblfizini .723 ,723 ,122bit(2-ChtinUipripyl) tthtr 1,737 1,714 10.320Htuchlinithint .198 .016 12,381IHfltntidi-n-pripylinint .389 ,408 5,028 ttNitnbmzmi ,56? .572 .534Iiiphirine .740 1,100 6.3082-Hitriphenil .190 .184 3.290 I2,4-limthylphonil .411 .410 2,463bis(2-Chlirithiiy>Ai1hini ,534 ,539 ,6352,4-Dichliriphtnil ,273 ,262 3,441 t1,2,4-Trichlinbmzwii .282 .261 .313
."iphthilini 1.146 1,147 1.821taichltnbitidime .15? .151 4.896 I
p-Ghliri-rcrnil .391 ,442 13.143 tHtiKhliricylipintidlmi .343 ,283 17.387 tl2,4,6-Trichliriphinol .377 ,354 5.437 t2-ChlironaphthaliM 1,164 1,141 3,17?Actniphthilme 1,734 1,858 3,739tiMthyl Ihthalati 1.744 1,614 4,0282,4-linitntilimi .297 ,322 8,475Acmiphthtni 1.310 1.285 1.150 t2,4-Dinitnpkinil ,06? ,161 11.574 tt2,4-tinitrotilnni ,582 ,431 8,3784-Nitriphitiil .213 .211 3.771 tlFliirmi 1.617 1.43? 1.4044-CMiriphmyl phinyl ithir .487 .473 2.134Diilhyl phthiliti 1.953 2.081 6.5454,6-Dinltro-i-crml .090 .173 18.587Diphmylinine - I. Ill t1,2-Diphmylhydrizint 2.464 fc444 7.2184-Briniphtnyl phwyl Hhir .261 .226 13.135
IF - Auragi RnpinH Fictir frin initial calibritiin Firn IXIF - Ittpintt Fictir fron dally itindard fill
X D - Pircmt Bifftrmet C w v ^^ >•,:c - Cilikritiin Chick Cutpiindi (thou cinpoindi (thin cinpundi flagged uith in I)SPCC - Byttiti Pirfirnanci Chick Cinpundi (thm conpiondi flaggid Kith It)
FOMX . 020733
Calibntiin Chick - Bmiitlitilt H5L Cinpindi (Pg. 2)
_Cm Mi. 2640 Cntrict Lib, ETC Cora. ____ Cintrict Nn 6
iniuinmt Umtifltn PP/rig E ________ Cillbritlin Dili.Standard Fill. >E2191. iU3 ______ Dati. ?/aa/64 Tim. 4.00
MuiAiA 1C fir CCC ii _21 Ninlnin IF fir SPCC it 1.05.1,
C»npitn« _____ Tf IF XB CCC BPCC
Ktuchliribmzmi .264 ,246 7,477Ptntichliriphmil ,117 ,111 13.871 tPhtninthrmt i,H? ,?ll 9,840AnthraciM 1.075 1.022 4,911litrbityl phthalitl 1,154 1,064 6,161Fl.iranthlfil 1.782 2.3S2 18.668 t 'Pyrini 2,156 2.293 11,545BtnzUini ,111 .ill 25,234 ttBityl btniyl phthalati ,648 1,013 18,325NnzKDinthncmi 1.148 1,365 18.702dipimi 1.28? 1.537 17.2173,3'-Dlchlinbmtidini ,175 .113 35.315kti(2-Eihylhi»yl)phthalati ,518 ,672 29,613DiTi-ictyl phthalati ,568 ,481 16.244 t'Itnzitblfliininthini .782 .712 27,495fenziumiirinthmi .859 .487 20,023HfllKDpirmi .635 ,472 17,489 t.Indmi(l,2,3-c,d)pyrine .718 ,502 30,116)ibifizi(a,h)anthracmi ,541 ,430 21,46?8mzKthi)pirylmi ,42? ,518 19,237Aniline 1,54? 1,67? 7,115Imnicicid .102 ,106 81,42?Imiil ilcihil 1,113 1,132 11,7704-ChliriMilini ,508 ,571 12,402Diiwzifirin 1,770 2,101 .5642-Mithylnaphthalmi ,772 ,870 9,77?2-fltthylphinil 1,103 .979 2,3344-tHthylphMil 1.48? 1.55? 4,4852-MltriiniUni .532 ,589 11,8113-flttrnnilini ,508 .521 2,40?4-MltrnnlUnt .378 ,441 15,6232,4,5-Trichlirophwil ,371 .37? 3,238
IF - Awagi RiipinM Fictir fnn initial calibration Firn IXIF - Ittpintt Fictir fnn dilly itindard flit
X D - Ptrctnt DifftrmciJ& - Calibritiin Chick Ctnpiindt (tkm cinpiindt (thitt cinpiini'i flifgtd uith in t)SPCC - SyitM Pirfirmnct Chick Cinpoindi (thaw cinpiindt fliggH Mith It)
FOIBX - 1 2 7 4
Calibration Chick - SmiiiUtili HSL Cinpindi (Pg. 1) ,Can Hi. 3640 Cintrict Lib. ETC C^rp,____ Ctntnct Nn 6a-OJ-fe7<j?
.fliinntnt Idmtifiir, RC/fl9,..E________ Calibratim Dili. 5/21/B46tindard Fill. >Eaa05. .U3 ____ Dati. g/33/94 Tint, }9j20
Maiinin X D fir CCC ii _2i Mininin RF fir SPCC it fJ5J
ClApund TF IF XD CCC8PCC
H-NitriiidinithyUnini ,675 ,791 9,597bU<2-CMirnlhfl) ithir 1.172 1.178 .538 , f2-ChIinpninil .734 1.009 7.9B2, £>'Phmil 1.545 1.545 ,<m~M <1,3,-lichIinbMzini .742 ,788 (4JVT1,4-Dichliribmzint .747 1.115 7.188 t1,2-DichlinbmzMe .923 ,772 5,315kii(2-Chliriiupripyl) ithir 1,737 1,807 4,010HtiaclUintthini ,l?6 .101 3.140N-Nitrisidl-n-pripylinini .389 .400 2,814 ttHitnbwiztne ,569 ,555 2,358Iiiphinni ,948 ,723 2,6372-Nttnphmil ,170 ,202 6,214 t2,4-liAithylphmil ,411 ,382 4,507bU(2-Chlirithixy)Mthint .534 .514 3.7792,4-Dichlinphinil .273 .295 8,261 t1,2,4-TMchlinbmztnt .262 ,312 7,194Naphthaline 1,146 1,158 1,131
l jimchliribitidimt .159 ,165 4,281 tp-Chliri-n-crisil .390 ,358 8,189 IHtuchlincylipintiditni .343 .351 2.376 tt2,4,6-Trichliriphmil .377 .401 6,277 t2-Cbliriniphthilitie 1.166 1,345 13,396Aciniphthalmt 1.934 2,118 9.463ttntthyl phthalati 1,744 1,834 5,1532,6-DinitritiUmi ,297 ,301 1,145Acmiphthmt 1.300 1.424 7.556 t'2,4-Dlnitriphmil .06? .on 15,742 U2,4-Dinitntilimt ,582 ,565 2,7274-Nltnphinil .203 .125 38,525 UFliirni 1.617 1,671 3,34?4-Chliriphmyi phmyl ithir .687 .741 7,807Oiethyl phthalati 1.953 2.002 2,4974,6-Dinitri-itriiil .191 .07? 11,876hphnylanine - - 1.000 <1,2-tlphinylhydraiine 2.464 2,444 ,1744-Bnniphmyl phmyl tthir .240 ,278 14,478
RF - Aitrigt Inpinu Fictir frin initiil cilibritiin Firn IXIF - Inpinit Factir frin diily itandard flit
* •* "•X D • Pircmi Diff«met C 'j « *%'"'
v C - Cilibritiin Chttk Cinpundi (thiH cinpitndi (thin cmpiindi fliggid tilth in t) . n;'QSPCC - Eyum PrfirMnct Chick Cinpiindi (thm cinpiindi fliggid Nith tt) ^,,
\ ul'FMBX • 1275
\ \
(ICalibration Chick - Smiiilitilt HBL Cinpindt (Pg. 2) ^
C«n No. 3640 Cintract Lab. ETC, Cgr.p.____ Cintrict N». 6B-01-67t€''"itrimnt Itentiflin CC/r)S_E________ Calibration Date. 5/31/94
Standard Fill. jfi2205. . U3______ Datu 5/28/84 Tint. >9.30
HiiiiAin X D fir CCC U 20 HiniAtin IF fir SPCC ii JJ5J
Cinpund ___ TF RF X D CCC 9PCC
HiKlcKlinbmzmi .266 .320 20,303Pintichlinphmil ,117 ,098 16,057 tPhmanthrtnt 1.009 1,101 9,123
'Anthncme 1.075 1,233 14.727IH-b»tyl phthilate 1.156 1.320 14.170Fliinnthini 1.982 2,123 2.IB6 IPyrmi 2.056 2.161 5.124Kmzidint .181 ,062 23,340 Itlityl binzyl phthalitt ,B48 1.023 20.7078tnzi(i)inthricini 1,146 1,432 24,739Chrytme 1,289 1,495 15,?683,3'-DithHribmiidlnt ,175 ,141 19,275 .bii(2-Ethylhi«yl)phthalati ,518 .599 15,640Di-n-ictyl phthalati .588 .473 17.603 t,ImiKbmininthint .782 .817 16.102kmzitklfliirinthmi .859 ,673 21,653ImiKDpirmi .835 .667 20.0BB IIndinill,2,3-c,d)pyrini .718 .471 34.432>en:«(i,h)anthracmi ,541 .338 37.485.luKghilpirylmi .629 ,476 24.324Anilini 1.56? 1.665 7.385lenziic icid ,102 ,076 6,414Imiyl ilcihol 1.113 1.100 8,6754-Chlininilini .506 ,506 .34?Dibmzifirin 1.790 2,160 8,5632-Mtthylniphthalme ,772 ,882 11.2852-Mlthylphmil 1.013 1.007 .4524-Mtthylphmil 1,489 1.580 6.0802-Nitriiniline .532 ,571 7,2703-MUrunilint .508 .451 11.1314-Mitruniline ,398 .365 6,1?)2,4,5-Trichlinphmtl .391 .428 7.276
RF - Avtrigt Ritpinti Factir frin initial cilibritiin Firn IXW • Rtipontt Fictir frin diily itindird fill
X D • Ptrcmt Difformco . „ nr"u.J°""p. - Cilibritiin Chick Cinpiindt (thin ciAptvnds (thisi cinpundi flagged tilth in t) ^ ^ (>j
8PCC - Systin Pirfirmnct ChKk Conpiindi (thow cinpundi flagged xith tt)FORIX • 1276 0207W
•/;
Calibratiin Chick - Sinivolitlli MS). Cinpindi (Pg, 2) fl$CIH No. 364.0. ._ Contrict Lab. ETC Corp.____ Cintract No. 6a-oi-67tf£
'N
.iiitrmmt Idwiifiir. GC/MS E________ Callbrnlin Datu 5/31/84Standard Fill. >E821B. .1)3______ Ditt. 5/33/84 Tint, 3.30
Haxinun X D fir CCC it 20 Nininin RF fir SPCC it US!
Cinpiind IF RF XD CCC SPCC
Hnichlinbinzini .246 .335 25.934Pmtachloriphmil .117 .117 ,384 I •Phmanthrtne 1.0D9 1.117 10.193Anthracine 1,175 1,160 7.716Di-n-bityl phthiliti 1,156 1,237 6,9ftFluoranthene 1,982 1,610 17,272 t.Pyrmt 2,056 1,703 17,146Btnzidint ,181 ,078 3,704 tlBityl bttuyl phthalate ,848 ,839 1,122Itnzidlinthracmi 1,146 1.429 24.487Chrytini 1,289 1,328 2,9723,3'-Dichlinbmzidint ,175 ,223 27,672bis(2-Ethylht«yl)ph1hiliti ,518 ,61? 19.575Di-n-ictyl phthiliti ,588 ,708 20.341 tBmzilbmnninthtne .782 1.242 26.477lenzi(k)flnrinthini ,859 1,072 24Imzililpyrmi ,635 1,029/"23,28Indtn«(i,2,3-c,d)pyrme .718 1.1'•>binzi(i,h)inthricmi ,541 ,771 46,371tftnzilghilpirylmi ,629 1.014 61,170Anilini 1.569 1.335 14,930Binziic acid ,102 ,151 49,974Benzyl alcihil 1,013 ,761 24.3554-Chlirnnilini ,506 ,395 22.244Dibmzifvran 1.790 1.935 2,7762-Mithylnaphthiltne ,792 ,720 7,1712-Mtthylphinol 1,113 .787 21,4954-Hlthylphinol 1,489 ,767 47,1432-Nitriiniline ,532 .495 6.9683-Nitroanilini ,508 .257 49,3374-Nitrnnihni .378 .29? 24,6932,4,5-TrichUnphtnol ,391 ,422 7.836
RF - A«trigt RiipinH Fictor fnn initiil cillbratiin Firn IXRF - Riipinn Fictir frin daily itindird fill
C,, r • •' "}j U .1, >' ••'
,C - Calibration Chick Canpiindt (thm cinpunds IthiH conponndi fliggrt with an t)SPCC - Sytten Pirfirninci Chick Cinpiindi (thoii conpoindt fligged nith tt) 02074-J
FORBX ' 1278 ' '
Calibratiin Chick - Stnlulatile HSL Conpinds (Pg. 1)ifl
I"1** N" 2640 CintriCt Lab. ETC Cora,______ Cintract No. 6B-01-67t>g
InstriAMt Idmtlflir. C.C/MB E________ Calibratiin Date. 5/21/B4
Standard Fill. >E2238. .115______. Datu 5/34/94. Tint. 3.30
Haiinin X D fir CCC ii _2J Hininin RF fir SPCC If 1.051
TF IF XD cccsrccN-NitniidlAtthylinlni .875 .582 33,477kis(2-Chliriithyl> ithir 1.172 ,777 16,6052-ChlinphMll .734 .885 5,26?Phtnil 1.545 1,336 13,417 ti,3(->ichliribmzmi .742 ,754 1,3171,4-DlchUnbmzmt ,747 ,771 2,477 t1,2-Dichlinbmzmi .723 ,742 2,119bl«(2-Chloriinpripyl) tthir 1.737 1,570 7,632Htxachliritthani .078 .11? 11,717K-Nitniidi-n-pripylanini ,36? ,330 15,11? ttNitribmzini .54? ,500 12.056Irophirone .748 ,824 13,11?2-Nitriphinil ,170 .174 3,191 I2,4-DlAtthylphinil ,401 ,352 12,112bi«(2-Cnlirithizy>Mthant .534 .443 11.3522,4-Dichloriphmil .273 .282 3,595 I1,2,4-Trlchliribinimi ,282 ,311 11.238Naphthaline 1.144 1.143 ,291Hiiichlinbitadiint ,159 ,186 17,161 tp-Chliri-n-crtiol .390 .31? 18,265 IHtmchlincylipmtidimi ,343 ,4il 19,979 tt2,4,6-Trlchliriphinil ,377 ,404 7,033 t2-Chlinniphthilmt 1,166 1,311 10,556Actniphthiltnt 1,734 2,057 6,346Dintlhyl phthiliti 1.744 1,499 M.0382,6-Dlnitrililuint .297 .292 1.711
' Acmiphthmt i 311 1.357 4.393 t2,4-Dinitriphmil .16? ,062 10,145 tt2,4-Dinitritil«ine ,582 .491 15,4454-Nitriphinil .203 ,11? 41,475 ttFlliriDl 1,617 1,253 22,4954-Chlinphmyl phmyl tthtr .487 ,514 26,395Ditthyl phthalati 1.753 1.384 29.1534,6-Dinitri-i-crHiI .070 .081 7,665Dlphtnylanlnt - - 1,100 t1,2-Diphinylhydrizint 2,466 ' 1.74? 20,7664-lriniphmyI phmyl ithtr ,260 .308 10,563
IF - nurigi RupinH Factir frin initial cilibritiin Firn IXIF - Itipinit Fictir fnn daily itandard flit
r " '" ' "'t '}X D - Pwcint Dlff trtnci t - "- "CCC - Calibratiin Chick Cinpundi (thin cinpundt (those cinpimdt flagged nith an t) r\n ,1 1SPCC - Syitin Pirfirnmct Chick Cinpundi (thin cinpundi flagged with tl) )0
FORM X 1279
Calibration Chick • Stnliolatile 1151 Cinpunds (Pg. 2) ft»
C*si No. 3640 Contrict Lab. ETC Corp.____ Cintract No. 6a-Ol-67tV6
Initrmnt Idrntiflir. GC/HS E________ Calibration Datt. 5/21/84Standard Fill. ?E2332. .US______ Datt. 5/34/B4 Tint. 13.30
Naiinin X D fir CCC ii 20 Minlnin RF fir SPCC it I.ISO
Cinpiind IF RF XD CCC 8PCC
Htiachliribmztni ,266 ,328 23,313rentachlinphtnil ,117 .140 17,91? tPhminthrmi 1.00? 1.054 4,512Anthracmi 1.075 ,777 7,243DH-bityl phthalate 1,156 ,711 21,207Fluiranthmi 1,702 2,391 20,656 tPyrmi 2,056 2.405 16,974Ocnzidini .081 ,055 32,079 ttBityl bmzyl phthalate .848 ,671 16.482Benzilalanthracini 1.148 1,313 14,373Chryimt 1,28? 1.371 4.3423,3'-Dichlinbtfizldini ,175 ,204 16,774cit(2-Elhylhuyl)phthalati ,518 .611 10.030DH-ictyl phthalati .568 .712 2135£-ImzKblfleirianthini .732 1.173 "T9.450tenzi(k)fluorinthtni .859 ,786 6,2608mzi(i)pyrmt .835 .730 11.431 tIndmi(i,2,3-c,d)pyrini .718 .850 16,329Dibtnzi<a,h)anlhncine ,541 ,619 12.612KniolghDpirylene .629 .671 38.490Aniline 1.569 1.364 13.052Benziic icid .102 .116 3.271knzyl ilcihil 1.013 .834 17.5964-Chliroanilini .506 .426 15.780Dibmzifiran 1.771 1,701 14,5342-Hethylnapnthaline ,772 ,817 3.1462-Mtthylphmil 1.103 .852 14,9964-Mlthylphmil 1.469 1.291 13.3332-Nitnanilini .532 ,46? 8,0573-Nitnmiltne ,506 ,289 43.1544-Nitnmilini ,378 ,122 6>,2622,4,5-Trichlorophtnil .371 ,365 1.648
IF - Aiinge Responn Factir fnn initial cilibritiin Firn IX
RF - Rtipinit Fictir frin daily itindard fill
X D - Pircint Dlfftrmci
CCC - Calibratiin Chick Conpounds (thitt conpunds (thon cinpimde fliggtd «ith an t)
SPCC - Syitf* Pirfirninci Chick Cinpundi (thin cinpundt flaggid with tl)
\ \
Calibration Check - Siniiolatile HSL Conpinds (Pg. 1) rV<
Can Hi, 3640 Cintnct Lib. ETC Corn.____ Contract No. feB-Ol-67jjrj5
Instnnmt Identifiir. cc/HS F________ Calibration DMI> S/a^/84
Stindard Filt. j>E.aa4Si .US _____ Datu S/as/64 Tint, i.oo______
Maxinun X D for CCC it , .20 Hinlnin RF for SPCC ii _J_B
Cinpiind TF RF XD CCC »CC
(HltriiidimthylaAlni ,875 ,757 13,475bls(2"Chlintthyl) ithir 1,172 ,993 15,23?2-Chliriphmil ,734 ,876 5,765Phenol 1.545 1.390 10,152 ,t1,3,-Dichliribinzmi ,742 ,751 ,9761,4-Dichloribinzeni .74? ,756 ,727 t1,2-Dichlonbmzmi .723 .724 ,074bis(2-Chloriis«propyl> tther 1,737 1.456 16,205Htmhliriithani ,098 ,102 4,172N-Nitrttidi-n-pnpylanint ,389 .295 24,039 ttNitrobenzene .56? .486 14,436Itophirint .948 .620 13,5452-Hitriphniil .170 ,204 7,527 I?,4-Dintthylphtnil ,401 .324 17,159bii(2-Chlortthuy)nithane ,534 ,462 11,53?2,4-Dichloriphmol ,273 .298 7,325 t1,2,4-Trichliribmzme ,282 .332 17,737Naphthaline 1,146 1.147 .041Hiiachliribntadiine ,15? ,181 14,13? Ip-Chliro-n-cresol .391 ,332 14.734 tHiHchliricylipmtidiint ,343 .411 16.768 U2,4,6-Trichltrophtnol ,377 ,437 15,786 t2-Chlirmaphthilint 1.166 1.266 6.447Acmaphthilmt 1,734 1,722 ,434Dintthyl phthilati 1.744 1.528 12,3972,6-Dinitritilvmi ,297 ,324 B.874Acmiphthmi 1311 1.317 1,311 I2,4-Dinitnphinil ,04? .066 4.348 tt2,4-Dinitritilimt .582 ,467 19,8284-Nitriphtnil ,203 .136 33,115 ttFliorine 1,617 1,364 15,42?4-Ch)iriphinyl phmyl tthir .487 ,563 18,103Diithyl phthalati 1,753 1,527 21,8324,6-Dinitrt-i-criiil , ,l?0 .077 14.126Diphinylanine - - 0.001 I1,2-Diphinylhydrazint 2.466 < 2.06? 16,1004-Brintphtnyl phmyl tthir ,260 ,302 H.229
R~- Average Response Fictir frin initiil calibration Firn IXIF - Rnpinii Fictir frin daily itandard fill
X D - Pircmt Difftrtnci r " ™ " C) '••\j j u •CCC - Callbritlon Chick Cinpo«nds (those conpiinds (those cinpoinds flagged vlth in I)
SPCC - Systin Ptrfirntnci Chick Cinpundi (thin cinpmndi flagged nith It) UcU • 1°
F8RHX ' 1281 b
Calibration ChKk • Sfniiolatilt HSL Ccnpinds (Pg, 2)Hi' 3640 Contract Lib. ETC Corpj ____ Cintract Hi. 6
Inntnntnt Idmtifiir. pc./HS E _______ Cilibntiin Dm. 5/31 /B4_Standard Fill. )E324S. .US ______ Diti. 5/85/84... Tint. |iOO
Mix j nin X D fir CCC ii 30 Hlninun RF fir SPCC ii JJgO
CiApund TF RF XD CCC SPCC
Htuchlinbmzmi ,266 ,309 16,160PtntiChlirophmol .117 ,141 20.775 tPhtninthrmi 1.00? 1,054 4,473Anthricmt 1,175 1,148 2.475DH-bityl phthilate 1,156 1.005 11,077Fluoranthini 1.962 1.876 5.357 I'Pyrmi 2,056 1,731 6.HBBenzidln* ,181 ,157 73,775 ttBityl benzyl phthiliti ,848 ,721 15,136BcnziUlmthracmt 1,148 1,320 14,987Chryiine 1,289 1,225 5.013:',,3'-Dlchliribmzidini .175 .242 38.550bis(2-Ethylheiyl)phthalati .518 ,fi02 U.291Di-n-ictyl phthaltte .588 ,637 8,272 IBinzilblflnnanthine ,782 1.072 9,165hnzilklfluoranthme .659 ,720 7.167fentilDpyrmi ,635 .748 13.578 tIndeni(l,2,3-c,d)pyrint .718 ,775 35,731Dibtnzi(i,h)inihrictne ,541 ,843 55,707BmzitQhilpirylmt ,62? 1,057 68,15?Aniline 1,549 1.327 15.408Btnziic acid .102 ,173 86.782Bwzyl .alcohol 1,013 ,811 it,9134-Chlinanilint .508 .439 13.439Dibtnztftrin 1.971 1.814 1,8532-Hithylniphth«line .772 .616 2.7712-Ntthylphmil 1,003 ,857 14,5244-Htthylphmol 1,489 1.226 17.6792-Nitroanilihi .532 .541 1.4B53-Nitruniline .508 .338 33.4454-Nitriinllini ,378 .211 47.1502,4,5-Trichlonphmil .371 .387 1.218
IF - Aurage Response Fictir frin Initial cilibritiin Firn IX
RF - Rtipmii Fictir frin daily standard fill p - f ' 'J, ]_.v j w *
ID- Pircmt DlffirtnciCCC - Calibration Chick Cmpiunds (thoH cinpunds (thiii conpoinds flagged uith an t)
SPCC - Syttin Pirfirnmci Chick Cinpundi (ttiosi cinpoindi flagged with It)
FOIMX • 1282
Calibration Check - Smitolatile HSL Conpunds (Pg. 1) ^tf
Cas» No. f3640_... Contract Lab. ETC Corp ._____ Contract No. 6B-01-67(rg
1 Instmntnt Idintifitn GC/rlS E________ Calibration Dati. 6/04/84 •' "'
Standird Fill. >E2403i .1,14______ Dite. &/4/B4 Tint. 18.50
Naxinvn X D fur CCC ii _20 Mintnin RF fir SPCC is OJBO
Cinpoind TF RF XD CCC SfCC
N-Nitriiidinithylanini • ,510 ,504 1,187bis(2-Chlintthyl) tthir .814 .613 .1262-Chliriphmil .652 .604 5,615Phenol 1,110 .920 8.911 t.1,3,-Dlchliribinzmi .951 ,937 1.3121,4-Dlchlinbmztne .953 .724 3,062 I1,2-DichIonbmant ,735 ,710 2.673I,ic(?-Chloroiiopnpyl) ether 1.021 1.104 8.196Hixachlinethane .122 ,123 .140N-Nitrosidi-n-prtpylanine ,262 ,256 1.631 tlNitnbinzine .452 .430 4.670isophorine .666 ,649 5,3732-Nltriphmil ,174 .159 6.503 I2,4-Dlntthylphenol .280 .279 .206bii(2-Chlirithixy>nithane .363 ,356 1,711C,4-DUhliriphinol ,252 ,254 ,940 I1,2,4-Trichliribmztne ,330 .337 2,114Kjphthaline 1,071 1.084 ,655Hiuchlonbvtadimt ,210 ,209 .441 t
< I'-ChJori-n-criwl .270 .266 1.530 IHixichlincylopmtadlmi .320 .341 6.361 tt^,4,6-Trichlinphmol ,395 .390 1.369 I2-Chlirinaphthilmi 1,144 1.134 ,710Aceniphthilene 1,915 1,703 ,633Binethyl phthalati 1,668 1,663 .9532,6-tinitrotoluine ,277 .281 1.556Acmiphthmi 1.261 1.275 1,195 t!',4-Cinitrophonol ,070 ,053 24,268 It2,4-Dinitritolune ,427 .43? 2.8764-Nitrophmil ,078 ,061 20.931 ItFlvirmt 1.330 1,314 1,9634-Chliriphmyl phtnyl tthir .513 .518 1,167Diithyl phthilati 1,389 1.390 .1094,6-linitro-o-critol .141 .135 4.269DiphmyUnine - - 1.100 t1,2-Diphmylhydrizini 1.071 1.022 4.6024-Briniphmyl phinyl tthir .315 ,317 ,743
RF~~ Awragt Rtsponte Factor fnn initiil calibration Firn IXRF - Ritpinie Factor fron daily standard file
X D - Fircmt Difference p - '
Ore - Calibration Check Conpitndt (those conptunds (thin cinpttndi flagged with in t)
""/ SPCC - Sytten Pirfirninct Check Cinpimdi (lime cinfuunds fliggid with tt) 02U ' 4^
FBRU • 1283
Calibrititn Chick - Seniiilatile HSL Cinpvndc (Pg. 2) (*Jf'«e Hi, 3640 Contract Lab. ETC Corp,____ Cintrict Mo. 68-ni-67fr6
InMriAint Idontifiir. DC/MS E________ Calibration Ditt. 6/04/84
Standard File. >Eg402. .114______ Date. 6/4/B4 Tint. iBjJSO
Haxinim X D for CCC Is 20 Mininm RF fir 6PCC is 1.050
Cinpiund TF RF XD CCC 8PCC
Hmachlonbmzini .559 .547 2.151I'rntKhlinphinil .066 ,072 16.527 tPhmanthrme ,??9 .964 1.475Anthracene ,985 .764 2.180Di-n-bityl phthalati .519 ,421 16.931riviranthtne 1.971 2.03? 3.516 tPyrme 2.121 2.115 4.MlHenzldine .126 .074 41.303 ttButyl bmzyl phthalate ,566 .561 4.359Brniilalanthracine 1.298 1.30? .853Chrysene 1.291 1.262 2,2823,3'-Dlchlorobenzidine ,302 ,266 5,022bii(2-Ethylheiiyl)phthalaie .622 .654 5.131Hi-n-octyl phthalati .756 .715 4.427 tBenzi(b)fl«onanthme 1,271 1.262 .754)ien;i(k)fluoranthtnt 1.050 ,95? 8,713BenzotDpyrtnt ,770 .960 ,762 IIndeno(l,2,3-c,d)pyrmi .763 .776 1.405Dibenzi(i,h)anthracme .69? .655 6.276BenzotghDpirylini ,921. .934 1,466Aniline ,768 1.034 6.772)!en;iic acid ,0?4 .049 48.165Benzyl alcohol .629 ,616 1,638l-Hhlirtaniline .439 .40? 6,790Dibmzifurin 1,776 1,770 ,316Mlrthylnaphthaltne ,800 .787 1.6262-Hithylphenol .679 ,657 3,3204-MMhylphmol .755 .964 .9492-llilrianiline .412 ,433 4,920>NltroaniUne • ,508 ,473 6,8084-Nitrianiline ,147 .149 1,786^4,5-Trichlorophtnol .361 .358 .874
IF - Aterige Riiponie Fictir fnn initial Calibratiin Firn IXRF - Response Fictir frin daily standard file r • " " .".4\, j« *"X D - Pircint DifftrmctCCC - Calibration Chick Conpounds (thisi conpiunds (thisi cinpimds fliggid tilth in t)SPCC - Systin Perfirnanci Chick Cinpundi (those cinpoinds flaggid tilth It) 0207'iJ
FORn X
P.'o. tot 111, AHundfH, Vlf|iU4 22)1) • 70)/»7-2»90
ORGANIC! ANA1.YS5 DATA SHEET //vjr w./Uaorttory Nimei t;TIf Simple ID No, ________________.________ QC Report Noi ,______________________& lcM»iri«. __ ____„_____________ ConuiciNo., pfl-fll-BTAR 70.0. ,67B9Dm ReleiK AuthorUed By,_________________ Due Simple Received, ___________
YOLAmeS • PESTICIDESCONCENTRATION, LOW MEDIUM HICH (circle one) CONCENTRATION, LOW MEDIUM HICH (circle one)DATE EXTRACTED/PREPAREDi ______________ DATE EXTRACTED/PREPAREDiDATE ANALYZECPERCENT MOIST!CONC./DILUTION
PPlI CASf(2V) 107.02.1I3VI(4V)(6V)(7V)(10V)(11V)(13V)(I4VI(13V)(16V)1 'VI. ,lr)(29V)(30V)(32V)(33V)
(31V)mvi(43V)(46V)(47V)(4SV)(49V)(30V)(31V)(19V)(16V)(17V)(IIV)
I07-13-I71.43-216-23-9101.90-7107-06-271.33.673.34.379.00.379.34-979-00.)110-7 5- 16746.)73.33.413640-371.17.3
10061.02.610061.01.03
100-41.473.09-274.17.374-I3-979-25-273-27.*734M73-71.112MH127-IM101- 14-379-01.67J.OM6744-17I.93-373-13-0Mt*7l4101.10-1100-»2.J101-03-41330,20-7
IiJREiFACTORi
icrolelnicrylonltrllebenzeneurbon tetrtchlorldechlorobeiuene1,2-dichIoroethitttI.I.Utrlchloroetlune1,1-dlchlOfoethinel,l,2.irlchloroeihtnelil,2,2.teirichloroeihinechloroeihtne2>ctiloroeihylvinyl etherchlorolormUHllChlOfMthCIK
trim- 1 ,2-<Jlchlotoeth«ncl,2 JlchloropropiiKtrant. 1 ,3-dlcWoroprocenccli-I.S-dJcriloroeroptMethylbeiuenemethylene chloridechloromethwebromomtthinebromolormbroirtodlchlorornethAnelluorotrlchloromettuncdlchl or odlfluorome thineetilorodlbromometlanetetrichloroetheMtoluenevlchloroethenevinyl dUoriae•cetone2-buiinonecvbondliullldeI teunone*.methy|.2K>enunonenyrinevinyl tciutclotil nylenei
(circle one)3500555"JD55y10j"k$IOSID/£7
SLGSt.f33££g
1)%..20
•rA"7n(e
-llfl7
/**•(ano
JO407
DATE ANALYZED,PERCENT MOISTURElCONC./DILUT10N FACTOR.
>PPI CASf(I9P) 309.00.2 ildrlnIMP) 60-37.1 dleldrln(9IP) 37-74-9 chlordlm(92P) 90.29O 4,4'.DDT(93P) 72.33.9 *,4'.DDE(94P) 72-34.1 4.V.DDD(93P) 113-29.7 eC-eniloiullin(96P) 113.29.7 0 .endoiullin(97P) 1031.07-1 tnaoiullin lullne(9IP) 72-20.1 endrln(99P) 7421.93Ji endrln tliKhyile(IDOP) 76-44.1 heptichlor(IOIP) 1024.37.3 heoiichlor epoxlde(I02P) 319-144 <-BHC(I03P) 319-13-7 6 .BHC(ID4P) 319-16.1 S -BHC(I03P) 3H9-9 T.BHC (Undine)(I06P) 33469-21.9 PCB-1242(I07P) 1109749.1 PCB-1234(IOIP) 11 104-21-2 PCB-1221(IMP) 11UI.I6-3 PCB.1232(HOP) 12672-29.6 PCB.124I(HIP) 11096.12.3 PCb-1260(112P) 12674-11-2 PC6-10I6(IDP) 1001-35-2 touphem' Mean! column did not oonfin" cenfinwcl by lecond oaliun
DtOXWS
CONCENTRATK3N, LOW MEDIUM HICHDATE EXTRACTED/PREPAREDiDATE ANALYZED,PERCENT MOISTUREl VCONC.miLUTlON FACTOR.
e(circle one)0,020.03.0,090. o30, a 26,02.C.QZ~O.GA.0.04C.0\O.OIO.OiC.030.020.03o.oa.0,0%o.i0.2.0,2.c.a.a.?o.a0,1O.I
(circle one)
.., jkr .»M"
1285 J^.ni CASI (circle one)(I29B) 17*6-014 2,3,7,1-tetrtcrilorodlbeTaiHMlloiiln 0.12
u • not detected; c • cormted for bltnHk • kilo* detection l»_lt December 1MJ
UA ENVIRONMENTAL PROTECTION AGENCY - CLP Simple Mw_|cmem Oilice"JO, Ben 111, Akunori*, Virgin- Z2313 - 70)/337-2»90
OROAN1C5 ANALYSIS DATA SHEET
U. lory Nimei ETC Corp. ________ .„______ Cue No, _ ____ _______Ub Simple ID Not ______ ___ ______ _________ QC Report N«i ___________ _____________c«mple Mitrln, ______________________ ComrtclNo.i 68-01-6766, 67B| .6789.6790Dm Relcue AuthorUed Byi _ __________________ Due Simple Recelyedi _______________________
SEMWOLAme COMPOUNDS
CONCENTRATION. LOW MEDIUM HICH (circle one)DATE EXTRACTED/PREPAREDiDATE ANALYZEDi
PERCENT MOISTURElCONC./DILUTION FACTOR,
PPI(2IA)(22A)(24A)(3IA)(34A)(37A)(31A)(39A)t'
(63A)
(IB)(3B)(IB)(9B)(I2B)(IIB)(20B)(29B)(26B)(27B)(2IB)(33B)(36B)(37B)(39B)(40B)<«"*)( i(43B)Deceit
CASI88-06-239-30.795-37-J120.13.2103.67.911.73.3100.02.731.21.5334.32.117-16-3101.93.265-15-093-41.7101.39.495-95-413-32-992.17.3120-12-11II-74-I67.72.1111-44-491-31-795-30-1341.73-1106-46-791-94-1121- 14-2606-20-212246-7206-44-07003-72-3101.39-3
396)1- .12.9111.91.)
*tr 1913
(circle one)2,4,6- trlchlorophenol .5"p-diloro-m-creiol2* chloroohenol2,4Mllchloropr*nol2,4-dlmethylphenol2- nltrophenol4-nltrophenol2,Mlnltrooheiwl*,6 llnltro.2.methylphemlpentichloropheno!phenolbenzole add2-methybbenole-methylohenol2,*.Vtrlchlorophenolacenaphthenebtnzldlne1 ,2,lhtrlchloroberaeneheuchlorobenzcneheuchlorocthtnebli(2 hloroethyl)ether2<hloror-phthtlenel,2.dlehloroberaene1,3-dlchlwotwnitnel.tdchlorobeiuene3,3' lchlorobcnzldlne2,t41nltratoluene2,6-dlnltrololun*U-dJphenylhvdrulnelluorinthene4-chlofophetiyl phenyl ether*-tromochwyl phenyl etherbli (2-chloroUoproovl) etherbli (24hlaroethoiy) methane
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>_2189 SONG DFTPP . SONG DHPP B/N/A FRACTION
- 139 SUB NRM
File. >E21Q9 Scan t, 139 Retn, tine. 9.53M/i in1. n/z Int. «/z Int. _n/i___Int_._ _n/^_Int__
ToTo"T4"s_ "Vr«V"""".77 7aTTfl"""~79 "tV?" ?"o""lOO .00 254,90 38.08SI 10 59 12 92,05 .52 135.10 1.46 198,90 5,69 256.00 4,9252 00 326 98.95 3,60 141.00 1,84 804,00 1,62 857.90 .9656 05 1 55 96.05 .77 148,05 1.37 80S.OS 3.64 272.95 .SO57 05 4 08 9795 2,83 154.95 .64 206,05 16,51 874.OS 8,4965 OS 98 99 10 2 30 156.05 1.07 207.05 1.54 274.95 20,0169 00 64 46 101 00 1 88 167.00 3.18 207.95 .64 875.85 1.5274 00 4 52 105 10 97 168,00 1.07 816.85 3.07 276.9S .3875 00 8 13 107 00 12,47 174.95 ,63 881,00 5,90 895,95 8,8377 00 56 74 108 00 1,38 179,05 2.07 828,90 ,48 382.90 ,8477 90 4 31 109 90 30,84 179.93 1,03 884.00 8.44 364.85 1.0979 00 071 m 00 4.10 184.95 1.07 885.00 1.88 422,95 3,0760 00 1 74 117 OS 6,00 185,9S 9,65 887,00 8.80 441.00 9.678090 380 183 05 ,57 107.05 1.98 244.05 8.55 441.90 73,0482 00 81 12695 45,65 191,90 ,31 844.95 ,88 443.00 13,1483 00 75 128 OS 2.71 198.90 ,44 853.10 ,80 444,00 ,86BS.OS ,88 189,00 IB,46 196,00 2,55
1310
''(i
CC/HS 'EHfommet STAHOAM. _< ———————— 68-01-6790OieifluorotrlphinjrlphoiphiM 66-01-6789
68-01-6788CASE NO. WTMCTOX BTC Corp __ CONTMCT NO. 68-01-6766_INSTANT » _____ DATE _j£____4 ———— Tl« ______2RUN MKR P **°3 QC KMKT NO. . itVT-i ——— «W-TJT
TUht CHICK;
!_!
SI
MII
70
1?7117
775365
44111?
443
Ion Abundinei CrlttHi
n ' in of MII inlilt thin K of MII 19•in 19 nlitlvt ibundinetIni thin 21 of MII N10 . 601 Of Mil 19Blilt thin 11 of MII 111but ptik, 1001 nlitlvt ibundinetS • n of MM IN10 . 301 of MII 198grtittr thin 11 of Mil 19B1 m 'thin Mil 443
trtittr thin 4K of MII 19817 . 231 of Mil 442
S fttlitlvt Abundinct
jo.r0 fn UJT770 t o \ l4>H0(00.0
_-,t».l
/.*I3.>fclO.* (,7.fl«
In pirinthiili U 1 «n «•in pnnUnili d I •»» «2
CoMinti:
r*I/-'
311 020777
.T. ...«?... /r... .9... .f... .7. . ..<!»."'"""""
tt v_m """
«\ 1A:
CD <D Q CD Q (9 O(0
• 1312
- La _ . r
02077:
>E8203 SONG DFTPP SONG DFTPP B/N/A FRACTION
133 BUB NRh
File. >_2_03 Scan ». 133 Retn. tine. 9.55
n/i Int. n/z Int. M/Z Int. n/z Int. n/z Int,
50.00 11.90 83.00 .50 189,00 15,72 186,95 2,37 245,05 .6751,00 50.46 85,15 ,58 130,00 ,79 191,90 ,27 846,05 ,6258.00 8.46 85,95 .32 135,00 1.30 198.90 .58 8SS.OO 41.7054,95 .16 90,95 ,84 141,00 1.87 196,00 8,35 856,00 5,5656,05 1.44 98.05 .87 146,95 ,58 198,00 100.00 857.90 1.3057.05 3.66 93,05 3.29 147.95 1.89 198,90 5,57 278,95 ,7160,95 .18 96.05 .72 14B.9S .83 301.40 .17 873,95 2.9361,95 .05 99,05 8.15 158.65 ,86 803.90 1.78 874.95 28,0663.15 1.58 99.10 1.80 154.95 .54 80S.OS 3,98 875,95 8.4765,15 .51 101.00 1.2a 156,OS .89 806,05 17,36 876,95 .8469,10 57,70 103.90 ,6B 161,10 .40 .06.95 .81 295.95 3,6374.00 3.86 105,10 .80 164,90 ,12 210,75 ,84 323.00 1,3375.00 6,45 107.00 10.54 167.10 3,05 811.05 .29 364,85 1,8176,10 8,34 10B.10 1.49 168,00 1.87 216,85 3,77 372.00 ,4677,00 48.19 109.90 27.31 175,05 .6B 881,00 6,86 422,95 4.3778,00 3,36 111,00 3.47 178,95 8,15 822,90 ,65 423.95 .6179,00 2,65 117.05 5.35 179,95 1.14 224.00 10.15 441.00 13.8279.90 l.SS 123.05 .69 160.95 .45 825,00 8.18 441.90 98.1081.10 3,12 126.95 42.69 184,65 .83 826.90 8.79 442.90 17,3088,00 ,63 127.95 2.68 IBS.95 9.76 244.05 8.96 443,90 .96
1313
CC/MS KRFORMMICC STAHPARP
DteiflMrotrlphtnylphoipMiw 66-01-678968-01-6788
CASE NO. c3£40 ._ CONTRACTOR _ETC.Corp_ CONTMCT HQ.68-01-6766
INSTRUMENT ID __g___. DATE r/»3)g4 TIME Id SO ___KUNRUHKV PaalT QC WORT NO. I fe? 1 tW-TST ..iA«v<Je* TUKE CHECK;
•Ji
si68
19
70
127197
in199
275
365
441
442
443
Ion Abundinei CMtirli
30 • 601 of Mil in1m thin 21 of MII 69MII (9 r»Ut1»t ibundinetlist thin 21 of MII 1940 • 601 of MII 198Itn thin 11 of Mil 198bin ptik. 1001 rtlitlw ibundinet5 . fl of Mil 198
10 . 301 of MII inqrtittr thin 11 of Mil 198Itmthin Mil 443snitir thin 401 of Mil 19817 . 231 of Mil 442
1 Rthtlvt Abundinei
17.00 tf)}lttfl:i t >u<«•.?. 3-
/00,0
f.~l
><n/.3t<>£(pp.6/*.P • (Mil
1n pinnthtili U S Mil II.2ViIui 1n pinntnttli It I Mil 442.
1314 020730
IWffl )' IT I I j ' ' ' 'JlT
02C7Q11315
>E2_17 SONG BFTPP SONG DFTPP B/N/A FRACTION
• 136 SUB NRH
File, )E2817 Scan ». 138 Rttn. tine. 9.S3
M/I Int. n/i Int. n/z Int. n/* Int. n/z Int,50.00 13,64 86,OS ,40 187.95 3.01 185.95 9.95 245.8S .5151,00 57.01 91.05 .01 129,00 16,SS 187,05 2.27 855.00 37,7058,00 8,83 91,95 ,33 130.00 ,B6 198,00 ,3? 256,00 5.3955,05 .52 98.95 3.91 135,10 1,17 193,00 ,56 850.00 1,1756,15 1,13 95,95 .14 137.00 .35 196,00 2,21 873,OS ,6057,15 4,84 98.05 2.28 140,90 1,28 196,70 .20 873.95 3.1468,05 ,35 99.10 2.67 147,05 .51 197.90 100,00 274.95 80.7063.05 1,41 101,00 1.17 147.95 1.30 19B.90 5,74 275.95 2.1369.00 66.91 104.10 .47 1S5.05 .72 803.90 2,02 276.95 ,7970,10 ,14 105,00 .90 156,05 1,27 205,05 3,86 895.9S 3.3671.00 ,32 106,10 .11 160.90 .44 206.OS 10,83 383,00 1,1574,10 4,30 107,00 11,81 165,00 .19 810,75 ,25 333,85 ,3475,00 7.69 107.90 1.63 167,00 3.20 811.05 .85 364,8S 1.2S76.10 8,35 110,00 31,58 168.00 1.86 816.95 3.79 372.00 .S377,00 55.80 111.00 3.63 174,00 .23 221.00 5,98 422.95 3.S97B.OO 3.9B 116.15 .09 175,05 ,77 223,00 ,03 483.95 .3-79.00 3.13 117.05 5.73 176,OS .03 224.00 9.18 440.90 10,5080,00 1,98 121,95 ,33 177,OS ,30 825,00 1,95 441.90 BO.6081.00 3.42 122.95 .68 179.05 2.03 826.90 8.35 442.90 13.9988.00 ,69 124.95 .16 179.95 1.18 888,90 ,88 444.00 .7283.00 .81 126.95 45.70 1BS.OD .75 243,95 8.73
0207S21316
6C/MS KRFORHAMEE STANuARD
OtClfluorotrlphntflphpiphlM 66-01-678968-01-6788
CASE NO. A640 CONTRACTOR ETC Corp CONTRACT NO.68-01-6766DATE JT/AAISU T1H_ I330
W«IM«ER__________ QC REPORT NO. 1^7 . AHAtTJTTUNE CHECK!
•_/•SI68
1970
127197
in199
275365
441
442
443
Ion Abundinei CrltiHt
30 ' 601 of MM in
tut thin 21 of MII 19Mil 19 nlitlvt ibundinettin thin 21 of MII 1940 . (01 Of Mil 198
tut thin 11 of MII 198but otik. 1001 ntitlvt ibundinets . n of MII in10 • 301 of MII inqrtitir thin 11 of MM 198Ittt-thin MII 443grtitir thin 401 of Mil 19817 . 231 of Mil 442
1 Rtlitlva Abundinet
47,40 ( .1160,4
.1 I.Ml4>,o.3WO
*,3Al.O
tJtoS&>3I&0' MM
In pinnthnli It 1 MII M.In Mrtnthttli It S Mil 442.
Cawntii
Rt»1t1on Ditt 1/13- ., r. • n ;.,V w —' - v) w
1317 020783
N •t CQ«"»mC O C D C D C d C D C O C J i D O C Dn fn (p N< ) u) fl* n oj *•< fl)ulO"
K
iW
fe8
CDOS ,
U)Ni"V
«*xn O.m
) 0* CO N *0 U) ^«
• 1318 J20784
)_2-30 SONU DFTI'P 50NG DFTPP B/N/A FRACTION
142 SUB NRh
r.lei >E2_30 Scan », 142 Ratn, tine. 9.53
n/z Int. n/z Int. n/z Int. M/* Int. n/i Int.49.20 .16 91.OS .57 141.00 1.47 196.00 3,03 857,90 1.8B50,10 12.56 91.95 ,43 142,00 ,38 196,70 ,39 864,95 .4051,00 49.40 92.95 3,81 146,95 .69 198.00 100.00 273,05 1,1658,10 2,69 98.05 8,47 148,05 1,68 199.00 6,26 873.95 3,7055,05 ,13 93,90 2.59 148,95 ,22 201,50 ,10 875.05 21,01)55,95 1,90 101,10 1.38 154,05 ,17 203.90 2.30 876.OS 2.6157,05 3.57 103.10 ,86 153,05 .76' 205.05 4,85 876.BS 1.2261.05 .50 104.00 .79 156,05 1,85 206.05 13,03 296,05 3.9362,05 ,36 105.00 1.13 160,00 ,30 207.05 8.55 877.05 .3363,05 1,61 106,10 ,80 161,10 .79 208,05 .47 302.95 .1?64.95 ,90 107,00 11,35 166,00 ,33 211,15 ,67 323.00 2.0469.00 60.39 10B.OO 1.60 167,00 3,66 217.05 4,01 333.95 ,9671,10 ,00 110.00 27.62 167,90 1.64 821,10 6,06 352.00 ' ,3074,10 4.59 111,00 3,58 175.05 1,84 223.00 ,74 353.90 .5075,00 7,43 116.OS .40 175,95 .16 224,00 10.20 364.95 1.6876.10 8,27 116.95 5,64 176,85 .35 285.00 8,35 372.00 1,0277,00 50.05 183.05 .77 178.95 2.10 826.90 3,48 402,90 ,4973,00 3.65 18S.05 ,29 100.OS 1.39 287.00 ,47 480.95 .3079.00 2,68 186,95 41.95 180.95 ,50 843.05 ,20 421,95 ,3680,00 2,09 120,05 3,49 105,OS 1,15 244,OS 0,40 482.95 4.0881,00 3,57 129,10 16.60 10S.9S 9.79 845.15 1.02 483.95 .8788,00 .02 189,90 1.16 186,95 8.50 846,05 1,11 441.00 10,58'83.00 .67 135.00 1.00 188,95 .13 255,00 41,13 441.90 00.0385,05 .55 13S.90 ,08 198,00 .59 255,90 S.34 442.90 15.0486,05 ,33 137,10 ,81 198,90 .68 857,00 ,21 443.90 1,02
• 1319020785
jjt/MS KRfORMAItEt STANDARD
DteiflMorotr1ph«nj1phoiph1ni 66-01-678968-01-6788
CASE RO. _________ COHTMCIOR' ETC Corp COHTMCT HQ.68-01-6766
IRSTIttKHT ID J:.___ 'DATEWRIMtER__S___l3_
TUHtCHtCKi
IVilut \n pinnthiHt U S «" *';ZV.lMlRpinntnn1t1tfMti4tt>
13HO 02078
CASE RO. _______• OATS tbrtPe TIME
GC/MS KRFORMAHCt STANOARD
OiMfluorotrlpninjIphoiphliit 66-01-678968-01-6788
CONTRACTOR ETC Corp COMTRACT MQ.68-01-6766
QC REPORT HO. \t,8~\ AWLYJT
Ivitw In pannthitH 1t t MM *»•2vilin1iip«nnthMli1i>Mii442.
CoMnti:
1320 02078
OJ •-,'H§
5*7,3«cen
z3
3It.(X
zn
cu.L _1.•wh. 3
L
^
pg;jU)
ro
ir§"fl"aa.•n a
c o i 3 a > a > a > ' S ' 3 i < s a >.T. ...*?... .^ ... ,*f . . . .K* . . .T . . .f, . .^ .1*. *
w/? -
BS
U>
"Vs\(0OJ^"
u> — •5\ JIflN
^v__.—— —— —— PH
\$ f »-fCO' J
•-1
W '
jN / 1
j IVJ ,_•-__
1 —— <w r
J<r>. ""~
-5G 3 Q Q G O C 3 C D _ , O C iC n W r > < i U ) T r / ) O J «
• 1321
i-?T
a"t
;•
3
-
•S(1)•
05-OJ•N
.
•C3•"f
s.to
OS0f*
o-wTH
JDCO
T\e. >E2243 Scan *. 142 Retn. tine. 9.66
n/z Int. n/z Int. n/'i Int. n/'i Int. M/: Int.
49,20 .26 93.05 3.17 141.00 1.13 196.00 2.80 256.00 5.41SO.10 10..7S 96.15 .37 141,90 ,23 197.90 100,00 2S8.00 1.2S51.00 44.66 90,05 2,20 147.05 ,58 199.00 5.92 864.65 .2952.10 1,90 99,00 2,28 147,95 1.2S 201.30 ,24 265,05 ,2655,05 .35 101.00 1.40 155.15 .62 204.00 2.24 273.05 1.0?.53.95 1,81 104,00 ,55 155,95 1,12 205,05 4,05 273.95 3.3457.05 2.73 105.00 .72 IfcO.OO ,13 206,OS 17.07 874.95 22.0362.05 .26 106,10 ,05 161.00 .43 208.05 ,03 275.95 2.5763.05 1.40 107.00 10,42 165.10 .21 210.85 ,43 276,95 .Clfo64.95 .53 108.00 1.20 166.00 ,16 216,95 4,05 295,95 3.8269,00 58.99 110.00 85,85 166.90 8.87 217.95 ,15 296.75 .1274,00 3,28 111,00 3,16 160.00 1,69 281.00 6.29 322.90 1.3175,00 6,20 116,95 5,32 174,00 ,31 223,00 .67 333.05 .7376,00 1.73 117.95 .24 175.05 ,94 224.00 10.16 351,90 .1677,00 45,87 121,OS ,29 175.95 ,23 225,00 2.21 353,90 ,1770,10 2.92 123.85 .16 176,95 ,41 226.90 3,07 364.OS 1.4079,00 8.29 124.95 ,14 17B.9S 8.89 820.00 .13 372.00 .7000,00 1,65 126.95 41.21 180,05 1,40 220,91) .55 402.80 .2081.00 8,99 127.95 2,62 180.95 .71 248.98 .22 428.95 4.0081.90 .55 129.00 15.86 184.95 ,98 244.OS 9.05 423.85 .4502.90 .53 130.10 1,19 IBS.95 9.S3 244,95 .86 440.90 11.31OS,OS .45 134,00 ,15 186,85 2,41 245,95 ,81 441.90 87.0705,85 ,35 135.00 1.09 190.90 ,13 853,00 .10 442.90 15.93'1,05 .6491.95 .38
1322
. CC/MS PERFORHAHCE 5TAHOARC
Dtufluorotr1phir\y1phoiphlM 66-01-678968-01-6788
CASE HO. -Uo ' CONTRACTOR ETC Corp CONTRACT KQ.68-01-6766
HWRUttKT ID _E __ DATE t./4lfo _____ TIK IRUN MNICR "6*40 I QC REPORT HO. I 6H AHAIYSTTUht ChtCK;
In pinnthiili 1i I MII II.2vi1m 1n pinntlMili Ii I MIS 4«.COMdtli
«_•SI18
19
70127197
198199
275
3(5
441
442
443
Ion Abundinei Cr1tir1i
30 • 601 of MM 198lilt thin 21 of MM (9MM 69 rtlitlvt ibundinctlilt thin 21 of MM 1940 • (01 of MM 198 •Ittt thin 11 of MM 198but otik. 1001 rtlitln ibundinciS • K of MM 19810 • 301 of MM 198cjmttr thin 11 of MM 198Ittt'thin MM 443
irtittr thin 401 of MM 19817 . 231 Of Mil 442
1 Rtlitlvt Abundinei
_•(.->0 (o )1
tf.t,«* 1.3)144.50
100,0
_T,8do.6**b. US.Itt.rii A' (mM
(conclautd) Rl»U1on Ditt I/I)
1323020783
02019°
>_2401 SONG Ur'TPP SONG DFTPPUQ SUK NRM
50.15 12,72 90.10 2.22 148,10 1.45 192. IS ,49 246.15 .6951.15 51,24 99,10 2,44 149,10 ,30 193.05 .56 855.10 39,5952,15 8,05 101. _0 1,36 151,10 .09 196,15 2.64 256,10 5.2S55.05 ,15 104.05 .67 153.00 .46 196.05100,00 256.00 1.4056,05 1,74 105,05 .71 1S4.00 .21 199,00 5,78 265,10 .2557.15 3.81 107.15 11.42 155.20 .74 201.70 .20 273.15 .8968.05 .28 108.15 l.SB 156.10 1.33 204,10 2,05 274,15 2.9563,10 1,66 110.05 27,05 157.20 .07 205.10 3.76 275.05 20, SB65,20 ,85 111.05 3,54 ISO. OS ,07 806,10 10,79 276,05 2,4169.20 59,62 118,05 ,16 160.05 .29 207.10 ,08 277,05 ,9670,00 ,17 115.95 ,88 161.15 .74 808.10 ,13 296,15 3.1(173,00 ,03 117.10 6.17 165.05 .35 209.00 ,10 297,05 .1074,10 3.91 119.00 ,07 166.15 .35 810.30 ,88 303, 15 ,0975,10 7,78 122.10 ,34 167,05 3,37 210.90 ,44 323,15 1.1676.15 2.3B 123.10 .86 160. IS 1.64 217.05 4,01 334.15 ,4677,15 49,77 124.10 ,27 173.10 .22 210.05 .20 352. OS .1270,05 3.23 127.10 44.30 174,10 ,41 821,15 6,73 354,15 .1379,05 2,31 120.10 3,11 175.10 1,04 223. IS .74 365.10 1.1580.05 8, 04 129.00 17.52 176.00 .17 224.05 9,55 378,10 .4581.05 3,49 130,10 1,07 176.90 .23 225,05 2.01 403,10 ,2888,05 .76 135,15 1,00 179,00 8.11 227.10 3,00 423,10 3. SI)83, IS ,64 136.05 .20 100.10 1.40 220,00 ,00 424.10 .3586,05 .45 137,15 .SB 181.10 .53 229.10 ,4? 441. OS 0.7271,00 ,56 141, OS 1.S9 105.15 .90 831,00 .15 448. OS 65.5398,80 ,40 142,15 .52 106.15 9.48 843.05 ,33 443.05 11.3593.10 3,71 143,05 ,14 187,15 2.81 244.15 Q.SO 444. OS .5796.10 .25 147.10 ,00 191. OS .17 24S.OS ,76
1325 020791
f\:S
£££_____ivtui Juri Ctirorn-tograrn_______i^file >fiWT3 <)«.0-iiJt.O amu.
l en
220090
aeeeee
.Ndrlt! . Ui:i»*tf.' , rf.OHl)1..'. , * I)
1326
4 ' ' ' i' ' 'i.1 ' ' i1* ' ' '_\»' ' 'i'*' ' S/B' ' 'Vi' ' ';'.-:.'
Dots Fi'hs. .yi-WW. .Uldrlt! . Ui:i»*i i.e. CTC: C!
'Mid riife. iwrti.e ^T:i.t'.U,. !.r B PUKGCACLL I'KJOKITV I'OL.LU'lfiNT!1:! 'JDriLE, B_1107, Ii, ,:l.La-it lli, I i.l;.r a v i o n . f)-10'.,(:.-l 17.11V
Operatoc ID. HMlll6fcOflUni Tine.'. 040S00 08. SV
020792
uufiin ;;u'Oi;Tat ID. MUMiM. UUoivl TiiHf iiili'Jtiu ,;;,.'.,'
. .,,* Ifljrttteti at. ij nil 111 i.! II u. I.".lUta !"i'l.fe.,,j!D;>9_. .IU .uuuiin I'oUor . i.ln
MiSC. CTC OAn!1LC,QCl>«V,VW' ( V.iftCl'ILiii.l.'O.'fi-'i
ID I lie. BVIB2BTi'Uo. 1PB PURCI.ABLL PRIORITY I'OLLUTAUT'J IDt'lLU, .31107, D, HI.Last Calibration. 0<0'.,U4 17.0V
Compound l<.T. Gcairr AI-BA Cone. Unit'
i) HtbroMochloroneihane V.tlU -16 -154S 2r-l°;ou "fl
_T—ftiji"iiiHin'1 s.i?—~nn nrr " w./& ,u.. 'P) fiff-trr-mr- --frSM——rW————rTO~" V'.'.bB'ri'u ~
;TT~- ft-r,,)! inUri7~r—Cliiu'i ur-ii.1 rr
!'•••!16V- G
'.i IQTO
1.0) htthyirjr.B chliif j lib '•,•'J i i »V HOV _. ,l.i ,,.,
!H. T r olio,, iMi«. V . -1,.', ii'j'u
tir ...tTfi- '"07 H)':!—————rrS
) a-I'llltanf,riB ).;..:.Vu _1"j 4'a 13. "T.W nu1.V) SE-Bi'iihij-l-c.hiurcai'-.'ipiine i'<.!i!.', T'.J/J 'j04VO !.VjO.QI) in.
I- ••"•Ti •.,.. n'tT r u K? "iI. o iciiwIft-i'Uhliif uci (.,> i'i.'1'ier
_:,._ii ';'.,::! IQTOU _.o.oo ,.iM----—"•'••,'" ........ '•-••• ;:''_r.
"SVTIlV
1327 020793
QUANT REPORT
Operator ID, MMSU66 Muant Tine. U40SO? OV.4Q-^ Urtf Injected at, 840SOQ OB,21nv i Filch, M>lW-i .Ul Dilution Factor. .40Nane i qCtWikv,930HRS,»Dhiic^ ETC 8AHPLE,OCW3V,VQA FVRACTION,S/Q/B4
MfynID File, DVFBLSTitle, IFB Surrogates, VOA FRACTION, GC/MS D'aft Calibration! B40S09 07.31
Conpound K,T. Scant Are. Cone Units
1) ftBronochloronethane V.8B 216 21545 2SO.OO ngZ) d4 1,2-Dichlaroethane 12,76 890 46035 100,01) ng3) Di8-Brono-l-chloropropane 19,83 456 50490 850,00 ng5) *l,4-Dichlorot)utane 83,20 SS8 107011 250.00 ng6) d8 Toluene 23.97 570 160408 100.00 ng7) p-Bronofluorobenzene 89.19 718 9872S 100.00 ng
$ Conpound U ISTD
1328
ft •rtCm-"_«8 T,i»UU>(0 •-0
<fQ\m),tiss]Kt.ao>>
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Data File, >D1993Scan Nunben 717M t nunber . 1 of 3
Rec.t. 18607 Reg,*. 54105? Xref.t. 10534 Base .N«ne. Cyclotrisiloxane, hexanethyl- (BCI9CI)MW . 2S2.0S6 QIi 334 MF. C6H1S03S13
PBM Values.
Cloas IV Reliability value, 55K-value, 83dK-value. 26Flagged Ions. 0Tilt factor, 0
r.
1338 020303
X I1(1 ,•
Total Ion Chromatograrnlit >E2196 48.0-460,9 MU
Data Flit. >E21?S,.U3Nane. «Clfa78Mist. 1FB SArtl'LE 2640-QC167B B/N/A FRACTION,S/22/84,»E BTL»lb
Id Filo IFBEflTitle, XFtl P.t,QUANT ID KILE,., .UWC. .631114Last Calibration. E)40S_2 1_,4U
Uptrator ID. WH7928Q.vnt Tine. B41)522 15.10
208041339
Ul
... ... -,.*»,. :
QUANT KEPORT
nner.tor ID, UUW2B Uu*nt Tim* ' B'"1S22 lii'iUOperator ID, HWV/<!U Injtcted at. 840522 07.31AmFile, >E21VS,.U3 »"»'»n F«tor. 1.00
HU.! IFB6SAMPLE 2640-801678 B/N/A FRACTION,5/22/84,t_ BTL*1S
TiTl-,*IFB P.E.QUANT ID FILE. .. .MWC. .831114Last Calibration. 840522 12,48
Compound R - T . Scan* Area. Cone Units
9,46 61113.10 IQ09IQ.fal 1611 81216 40,00 UG/HL
tl) *d!2--Chry»en« 31.353003 17795 40.00UU/rtL77) *JiO%htn7nthP.n. 23,14 2106 191891 40,00 UC/ML
* Conpound is I8TD
.-••JO
1340 020805
Operator ID. WW9928 Quant Tine. 840522 12.07Injected at. 840522 07.31
Data File. >E2195,.U3 Dilution Factor. 1JONane. QC167B~\9C. IFB SAMPLE 2640-QC1678 B/N/A FRACTION,5/22/84,*E BTLtlS
ID File. IFBPSTitle. IFB SURR QUANT ID FILE....,WWC..831114,«ELast Calibration. 840522 10.26
Conpound R.T. Scant Area Cone Units
1) *d4-l,2~Dichlorobenzene 9.46 611 46010 40.00 UC/ML2) 2-Fluorophenol 6.52 290 12667 10.87 UG/ML5) dS-Nltrobenzene 11.08 788 21018 15.25 UG/ML6) *d8-Naphthalene 13.10 1009 125989 40.00 UG/ML7) Decafluorobiphenyl 11.77 864 13537 12.34 UG/MLB) 2-Fluorobiphenyl 16.59 1391 42475 19.35 UG/ML9) *dlO-Ac«naphthene 18.61 1611 31216 40.00 UG/ML10) * dlO-Phenanthrene 23.14 2106 191891 40,00 UG/ML11) 2,4,6-Tribrofiophenol 21.08 1BB1 10727 20.55 UG/ML12) di4~Terphenyl 28,22 2661 36240 23,00 UG/ML
# Conpound is ISTD
1341020801
H
4••(1 T.
•
1
_____ • —at^ •••••__HH__B_H||._IH| H| HHIHH| HHB| ^ 9 ^ ESS >^_________________________________i_______________________PI_l^^^^^^^^^^^^^"^^^^^*^^.^ ^ ^ ^ ^ ^ ^ ^ ^ ^ •"• ^ •
1 • • • i 1 • • • • 1
-88.00
•88.00
-84.00
-82,00
-90.00
-28.00
-28.00
-24,00
-22.00 11•20.00 a
•18,00 J
•18.00
-14,00
-12.00
-10,00
•8.000
•8.000
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1 1342 §A/D Counts
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( "v,REPORT, 5205 CHANNEL, 1 PESTICIDES FOR IFB
, SAMPLE! QC1677 INJECTED AT 12i29i07 ON MAY 18, 1984CW«
ESTD METHODi IFBP/1 SEQi CgJ^OP SUBSQ/SAMPi I/ 3 BTLi 3
^ SL-HDTH MV/MIN DELAY MIN-AR BUNCH,500 .100 20,00 2SO NO
* SUP-UNK DVT ID--VL REF-RTU KRTW fiDIL-F ISONO 0.00 250 .10 1,0 1,00 NO
*• ACTUAL RUN TIME! 39.908 MINUTES
^ RT 1TM FACTOR AREA UG^G NAME
/ 25.71 1.OOOOE- 3 543 BB ,005V 29.98 29,981 7..330E- 4 455 BB ,003 »6-E'Hae8ULr*.HiPPDIH>
30.43 30,48* 9.9564E- 4 316 BB ,003 tCHPRlH ftLD-liy&C./ 30,72 t .OOOOE- 3 298 BB ,003v 31.01 31,011 1.3403E- 3 268 BB .004 tPPT
31.15 31 . 15* 8.4472E- 4 264 BB ,002 'H.HUllJULrftll SU.Fnii:/ 33,28 I ,OOOOE- 3 375 BB .0041 33,65 33,67 I .3970E- 2 21624 BB 3,021 '/.DIBUTYLCHLOP.EHDATE
/ TOTAL AREA a 24143 TOTAL UG^G » 3,045
PROCESSED DATA FILEi P0282 RAW DATA FILE! R0282
c>H020803
loiai ion ChrornatogramFit* >C2230 40.9-2.S.0 4_u. aCl'i'4_Vlll30HRS ,»C r-IC SRnPL.,QC1742V,VOH F
1000800-
900006-
600000-
700000
600080-
50000»;
400000
380800-
200000
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Data File. >C?230..U1Nine. qci748V>,1130HRS,tCMisc. F.TC SAMPLE,QC1748V,VOA FRACTION,5/18/84
Id File. DVFBLBTitle. IFB PURGEABLE PRIORITY POLLUTANTS IDFILE, 831107, D, RLLast Calibration, 840517 16,05
Operator ID. MM5Q66Qaunt Tine. 840518 12,10 /
1344 v020803
QUANT REPORT
Operator ID. MM5066 Quant Tine.Injected at .
Data File. >C2230.<U1 Dilution Factor.Nane. QC1742V,1130HRS,*CMisc. ETC SAMPLE, QC1742V,VQA FRACTION, 5/18/84
ID File. DVFBI.BTitle. IFB PURGEABLE PRIORITY POLLUTANTS IDFILE, 831107, D,Last Calibration. 840517 16,05
Conpound R.T. Scan* Area
1) HtBronochloronethane
„)"— FVCroiein"«D croin*2 ) BtrulEn.li l3) ' rttryionitrtjie4) -^-2-Eiuhlui ut'llune5) l-)i PlLliluruHllraiie6) . ntilnrnptharH—
8) i,i Pt-hinroeiliyiuni.' •»9) i ,,_-3*HHii."diiulilUllIH)Uiyl{!flt>
10) Methylene chlorideUU — Methyl chUiride
-t*) — Trlulilui uPluiiMMHihime
16) 2-Propanone_<>-j — _. Pnponnnr17) l?-Butanone19) *3-Brono-l-chloropropaneSOJ — C-ntene
.TILL t|l)l 1r ir.hlnr orthnnr
34) — g-enuronTnyiuinui mimf____-. tpans 1,3 Diuhluru|ji upylene
aw — P-iuliluruUi'ununuiliane3m — Bti-iuruuiurunanBTirarrg »>H — •h'lUIIJ.oroethyxene3fl-_-Wtryl dUMTTe33) *i,4-Dichlorobutane.3_U — Ohlui ubeiumm35) —— *-, i,^,^•T^Jl^T.^^Ili•^Jl'ue^ll.^u-••_ * — CthylbBn«ene36 f F 1 ii y 1 it MTf f'l r
38) Toluene3W — a-HB>an»ny
4^H — 0<ypenp . 1545
A3J — netn anil-Bapj-XMlanR-.
8,50•a,B4•Wrtr-
B onJ-, 00-OvOA—IB° _5,01IMW-
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5.83
11.490-00
17.8507*9-•0.00—0 00OvW—Or-00'0-44—0,09
0., 00 -
9-rfr6—Jl. 00-21,85
n n n
M*1_L__22,78
— _i',30 •
29-. 14 -2QT-56 •297TTT"
192
— Bfl ——— 85—-t-8—
—— B—— e —-'-Bl1—— 0 ——— D—102— e—
• —— B ——— e——— 0 —— tt—123
269- . 0433—— B——— B —
n
—— 0 ——— B—— a ——— 0——— B ——— 0_—— 0 ——— 6—
Q
—— B—536598
—— 0 ——434—
—— B—560
m—— 9—
7G4789— 721? —
18274, , ,., 17J—
——— TOT-——— 135~———— B-———— 0———— e-——— B————— B—~~~ 0
2428. —— — 9-———— B————— -tt-—-—— B—
n3193
4 Ad
2797n
79587———— 9-———— B—
Q
———— 9————— B_———— 9———— e_———— 0————— D_———— 0————— 0_
Q
— —— 0-76104
—— 2g-0-———— B——— ______—— 2776————— B-14395
———— 9-—— 1841 '———— 9-
— 37+e-—— 3521
,57 12
840518 12,10840518 11.24
1,000
RL
Cone Unite
250.00 ng—— 99,80 nq ———— •
76,22 ng ~—— 63 . 42 ' ny —— ———— 0,00 -ill) ——— - ———— 0.00 -ny" —— — ___.—— IhOO .09 ——— _—— 0.00 -IK) ——
0 0 -wL__
25.93 ng—— Orflfl-iiir-—— 0,'BO nt)~—— 0.00 MM—— 0,00- ng -—— O-r-00 ng— _38.97 ng
—— R.flt ng -__33.47 ng
n fin nij250,00 ng ~~~
—— 0-.80 ag ——— _— u.ou ng — — -
n g n r,n
—— 0.00 ii t| —— _
—— 0.00 ng — _^_^
n no na— 0.00 ne|~: r-~-
—— ff i C ff " f) ~""~~~250.00 ng
- —— 3,90 nu —— .—— O i O O np —— J^- -. HP nn T;
21.02 ng ,_>—— 0.80 -nq —— —
g , j P nflTZTr6-r5jT,4li£31*
—— ft-Tfi-n __ _
QUANT REPORT
Operator ID. MM5066 . Quant Tine. 840605 19.23Injected at. 840S18 11.24
Data File, )C2230,>U2 Dilution Factor. i.DO--yiei QC1742V,1130HRS,»C,.»ci ETC SAMPLE,QC1742V,VQA FRACTION,5/18/84
ID File, DVFBLSTitle, IFB Surrogates, VQA FRACTION, GC/MS DLast Calibration. 840605 17.14
Conpound R.T, Scan* Area Cone Units
1) #BroMochloronethane 8.50 192 18274 250,00 ng2) d4 1,2-Dichloroethane 11.37 266 33157 100,00 ng2) d4 1,2-Dichloroethane 11.80 277 143 .43 ng3) *2-Brono-l-chlopopropane 17,85 433 79587 250,00 ng4) #i,4-Dichlorobutane 21.85 536 76104 250.00 ng5) dB Toluene 22.62 556 141491 100.00 ng5) d8 Toluene 23,13 569 112 ,08 ng6) p-Bronofluorobenzene 27.47 681 71041 100.00 ng
* Conpound is ISTD
1346
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Data File. >C2230.,U1Nane, QC1742V,1130HRS,»CMisc. ETC SAMPLE,QC1742V,VQA FRACTION,S/1B/B4
Conpound No, 10Conpound Nane, Methylene chlorideScan Nufibtr. 102Rttention Tina. 5.01 nin.Area. 2428Concentration, 25.93 nq
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Conpound No, 10Conpound Nan*. Methyl.ne chlorideScan Nunber, 100Retention Tin*, 4,97 nin.Area, 15948Concentration, 143,89 ng
C--1
1349 02osU
J>iAbBI3
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4
Data File. >C2230,,U1Nant, «C1742y,1130HR8,*CMisc.. ETC SAMPLE,QC1742V,VQA FRACTION,5/18/84
Conpound No, 38Conpound Nant, ToluentScan Nunbep, 560Retention Tine, 22.78 nin,Area, 14395Concentration, 2i,02ng
1350 020515
(I
S i_0 C_KS|86 TS(BLUNM *NOJ
»n-sinzoH
J
X
a9>M>
N»w
JgJML
1
j
ij
*\
fth•Jr•(i
<s<r>o*PICP '>JNXaain ji•« aum
c | > o ( > r > . v p i p f ( ( ) c > j « c p
•/o'OJ
CO2s-
UJUJ__>S
»-"vA.
w. _"\_,/~4)
V~"U)
O C D Q C k i C 9 O O S ( B Oc o c o y a T ^ a j a j ^ T NOJ »•< -i ti ft 1-1
• • 1351
CO•oN
•C5•«rl
"
•a)0,— .
CO>*H
C3•<M
C5•«in
T*
,®>
"
B
Cf r- «• a j^ _, vi U J.
N» i 4^ :
aa$VWk,
g
1
ni« >DBni NfS Rev. E lata BafjFull spectra of the HIS data ;C4l- 339BpK Ab »999 i»_ 639.60 Kin.10000-
,8000;
6000:
400e:,2000
e-
39 66
,,}%,, UU 94K'1 ' ' ' 'i_e ' ' ' ' ' 'tie ' ' ' ' ' aia
ri00i
•48
40
•40\.
:204
&ft
3
Filt >C2231 QC1742VSP,1215HRS,«£ETC SflNPLE,OC1742VSP,VOR FRBC Scan 559Bpk flb 26712 *-i 22.77 min.
25000-
20000-
15008-
10006:
S000-
e-
65
X i A .96
, < r >" •'•"''• Ve r~'1 e'e ' ' ' 120 ' i.e ' 200
;iuo
49
48
0„
•26n
Data File. >C2231..UiNane. QC1742VSP,1215HR5,*CMiF,n ETC SAMPLE,QC1742VSP,VQA FRACTION,5/18/84,10UL
Conpound No, 38Conpound Nana, TolueneBean Nunbtr. 559Retention Tins. 22.77 nin.Area. 137710Concentration, 182.20 ng
1352
I/J
Fil« >C2230 OC17<I2V_J138HRS,MC ETC Sflr1PLE,OC1742V,VOfl FRflCTI Scan 123Bpk flb 864 7 6.63 nin.
880-•
600-.
408-
208-
flu
56
f 91 130 160 19s! 1991 1 ' t X /1 1 1 1 ' V Ml 1 ' ( [
40-40•0
•20
j\' 8'0' ' ' ' ' i_0 ' ' ' 160" ''' 288 ' ' ' " -i. "
Data File. >C2230.>U1Nant, QC1742V,il3QHRS,*CMisc. ETC SAMPLE,OC1742V,VOA FRACTION,5/18/84
Conpound No. 16Conpound Nane, 2-PropanoneScan Nunben 123Retention Tine, 5.83 nin,Area, 3193Concentration, 38.97 ng
'353
co co co< <¥ ..!>.
ucoVI 'U)
o»1
\
I
V020S13
§01VK
m|3
Filt >CBI1S NBS Rev- E Data Ba.tFull spectra of tht NBJ data sc«n 90Bpk flb 9999 i 90.ee Mln.
1BBBB->
8000;
6000;
4060:•
2000;]
1666f f
59J i, 1 L~*~~
l-ioe•40
40^
J40•
;.«
la' ' ' ' ' ' V0' ' ' ' ' ' Ve' ' ' ' ' ' i_e' ' ' ' ' ' 160 ' ' ' ' ' 200
o"3,eaM
Filt >C2231 BC1742VSP,12I5HRS,tCETC SRMPLE,OC1742VSP,VOfl FRHC Scan 116Spk flb 6422 / 5.S9 njn.
6000-
4080-
2000-
-
43\
t ,i120 162i 79 -x -»_. 169 195
ll . / e ^^ / . f .
^
40
40«C
-•20A
'''''' V0' ' ' 'B'B' ' ' ' ' i_0' ' ' ' ' ' 'i_0'" -1 ' ' 208
PAta File. >C2231..U1Nane, QC1742VSP,121SHRS,*CMisc. ETC. SAMPLE,QC174PVSP,VOA FRACTION,5/18/84,10UL
Conpound No, 16Conpound Nane. 2-PropanoneScan Nunbep, 116Retention Tine. 5.59 nin.Area. 15636Concentration, 16i,22ng
e>j4
355
IU
(tKfc»W
1?1S
Filt >D8rBpk flb 991000B"
•6000-
600IH
4000-
2000-fr
j NBS Rev,99
29
. J ,,1 Ve
.£. Dafa Ba.tFuH/
\ «i X .6*0 '
cptctra at tht N-S data $c_24e.ee
ra74
•F ~"e'0 ' i.e ' 120
n £43• in.r40
40••40•-20
4
U
1Sfj
Filt >C2230 OC1742V,H30HRS,«C ET£ SflnPLE,QC1742V,VOfl FRflCTI Scan 269Bpk flb 2964 b,b 11.49 min.
3800-
2B08-
2080-
1S00-
ieee-609-
e-
544
ilk L . i . , , , i
•
10272 X s 124,, r Jr. x
;UI0
•80"
40
•40
;20
la' 40 60 80 1_0 1.0
Data File. >C2230..UlNane. QC1742V,1130HRS,tCMisc. ETC SAMPLE,QC1742V,VQA FRACTION,5/18/84
Conpound No. 17Conpound Nane. 2-ButanoneScan Nunben 269Retention Tine. 11,49 nin.Arna. 2797Concentration. 33.47 ng
. \
1356
o> •*cffln'2(D C D C D C D O a o a O l. • r i c h c o r - . v p i p ' r n f yu*M •
«H•* .
•«•CO
n\U)c
JK
I '>K
>N* UJ§ 1,r* ^3 fc:-Jn Z2i 03a 1M OJ N,S N\w \.
u*r.cC9n-.Hn
1 [* 1Uo
;\B \ ————————————————————————————————————^g's'g's'^'s's's1"_, * « 0) « W N « -i
*" • 1357,rt D.U-«
a,,,T,,,.TS/ «rl
'S• r<
tH
2\ i> ——— ,(B
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-
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«
.
.(0,r»
.
•sJs —— ::. — — .
N.10s —— '
•8
——— :"(.•"i5 v
. r ••-•-,W W U I
\ 1
K
Filt }.sns JtfS Rev, EBPK no nr 198B0-
6090-
6000:
4006;
2000;»J
" X,
J..57
, . 140
I>afa BfifeFull spectra of the NBS data Sc.r. 243eio.ec
72
74
mn.
0
40
48
•20
'e'e' ' ' ' ' ' ' 20 ' ' ' ' ' lie ' ' ' ' ' 260 ' ' ' ' ' ' "Filt >C2231 BC1742V|E;,1215HRS,»CETC SflMPLE ,OC1742VSP,VOfi FRflC Scan 266Bpk flb 5860 V u'41 ."_lr-
5000-4080-
3606-•
2600-
1000-
0-
43\
40±
D 72 ia»1 ^ "7" 1<1 1« ,D, 2B9 235
li,i j.li. XX T X, X
;iuu
40•40
•46
•20
80 120 160 2-0
w
Data File. )C2231.,U1Nane. QC1742VSP,1215HRS,»CMisc. ETC SAMPLE,QC1742VSP,VQA FRACTION,5/18/84,10UL
Conpound No, 17Conpound Nane, _-ButanoneScan Nunber. 266Retention Tine, 11.41 nin.Area. 13171Concentration, 133,12 ng
$206231358
tIVufl
1
U"3,1
«PK HO 77»7
8000
4000-
A.
IB 96 133S 45 73 / 119 S 163< . / . . .. l . ..( i .. /' 40 ' s'a
Filt >C2230 aC1742V,1130hRS,-C .Bpk flb 2066 '
2000J
1000;
0.
75
,L<L1 " "Ve" " " 'e'e' ' '
i?e 160tTC SfiMPLE,OC1742V. CB
134121 >
Mil ,,*-' .l h II-V. 11
1 128 ' lie
•71.00 n»n.
191
46
40
Ifl1 ' "aia" ' ' "FRHCTl scan 684
|gd69 Min./ '
192IU faU . 1,
40
•40
-0' ' ' 200' ' ' '
Filt >C2230 8C1742Y/1130HRS,«CBpk flb 9999
•6000-
•
4000;
0,,
ETC SHFIPLE.CIC 1742V »VQHNRM
176S0 n »/ ... »3» \
..../... ....__._ J,40 ' 80
. " r.. i1 i_e ' ice
FRHCTI g-ican 684* ?'.69 -in.
191, L
"
40•;40
1 ' ' _.e ' ' ' w
Data File. >C223Q /Scan Nunber, 684 [''Hit nunber , 1 of 3
Rec.t. 10607 Reg.t. 541059 Xref.t, 10534 Base , DBMS.DNane, Cyclotrisiloxane, htxanethyl- (BCI9CI)MM , 222,056 QI. 334 MF, C6H1BQ3S13
PBM Values.
Class IV Reliability value. 60K-valuei 88dK-ualue, 21Flagged Ion*. 0Tilt factor, 0
o •• r' "*•_, _ _• -• o
\ $0824359
Tnt-! Ion Ghrorn_tonrGfT!Filt >E2223 48.0-460.0 a*u. w^bY "» »»>'"•-'• «4.-uub«r
V 1000 20,00 , 3060 , 4000
laaaaa-
iseeae-146000;
120808-
laaeaa-
60600-•
00060-
4008*
2B0B0-
0-
1" S"Hc-•p•Sr
S °va J
i
i £-Of 1* :f 3
1
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{ t7 T!5 '
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Js i 11it -i tr 1_!, r -«5f 1 1
I 1 4\ } ?l . L;_L_-^-
1 'iV ' 'A1 ' aV ' 'A' ' '__' ' 's'61 ' '4.' '
Data File, >E2223, ,113Nane, QC1687Misc . IFII SAMPLE 2640-QC1687 B/N/A FRACTION,5/23/84,*!.: BTL»3I3
Id File. IFBENTitle, IFB P.E.OUANT ID FILE.,,.WWC..031114Last Calibration, 840522 12.48
Operator ID, UU9928Daunt Tine. 040523 20.40
s 020S251360
8.UANT REPORT
Operator ID. UU992Q Quant Tine. 840523 20.40Injected at. U40S23 19.30
~")ata File. )E2223..U3 Dilution I'actor, 1,00Nane. QC1687Misc. IFB SAMPLE 2640-QC16B7 B/N/A FRACTION,C/23/84,*E BTL138
ID File. IFBENTitle. I Ft P.E,QUANT ID FILE ....UUC..831114Last Calibration, 840522 12,48
Conpound R,T, Scant Area Cone Units
1) *d4-l,4-Dichlorobenzene 9,37 613 156349 40.00 UG/ML15) *d8~Naphthal«n« 13.02 1011 456409 40.00 UP/ML31) #diO-Acenaphthalene 18,49 160? 200522 40,00 UG/ML37) 2,6-Dinltrotoluene IB.49 1609 21712 (* y_-/ML54) ftdlQ-Phananthrene 23.02 2103 145190 40.00 UU/ML61) *diS-Chrysene 31,26 3003 31173 40,00 UU/ML77) *dlO~Phenanthrene 23,02 2103 14S1VO 40,00 UG/ML85) *di2-Chrystna 31.26 3003 31173 40.00 UU/ML
* Conpound is I3TD
020828361
b51ucj
1vuQn
Filt DBMS Ettitrif, tttrachloro- (9C3J Scan/,96SSBpk flb 9999 ' 0.0«?*ln.
8000
40ae-
93r,|.|lri7l|iiVi|ilili'|Ml',l rii|iiii|llhi|il-Hviiin-M-i'ii'iiii-|irM|iiMlilM|M
129
80 4I 5, 92 »/ m,.,,,,.,,,,,i;,,,,,X,,JiI,.,..x... ..!.20 40 68 88 180 120 140 160 'Tl
Filt >E2223 OC1687.- IFB SAMPLE 264B-QC1687 B/N Sc*n 145Bpk flb 1626 *L^ SUB NRM WI09 nin.
1080-
0;
9469 ? "»
• • i i • p '' ''i » i|f ''T ' ' ' 'iifi |l
Z_ ' 4. ' 6B ' 80 ' 100 ' 120 140 160
Iff
Flit >E22'3 BC1687 IFB 5HMPLE Z64B-aG1687 B-'N Scan, 145Bpk flb 9999 NRM 6.0»7*in.
8600-•
4000-
0-
131
*7 94X 59 {
1, f ||
/
1a'e ' 4'0 ' 6'0 ' e'e' ' 100 ' 120 ' 140 ' 160t-
D,ita File. >E2223Scan Nunber. 145Hit nunber , i of 2
flc.ti 9655 Ret).«, 127184 Xref.», 6156 Base , DBMS.DNane, Ethene, tetrachloro- <9CI)MW , 163.875 QI. 655 MF> C2C14
PBM Values,
Class IV Reliability value, 89K-valuti 95dK-walu,i 27Flagged Ion*. 2 ,Tilt factor, 2
0208271362
n,«
p.a
mx ——————————————— ME:w*irHJ7«
II•.41tl8.M
».•-L
mm
11
•
i
| 1 1 ! * | 1 1 1 1
•38.00
-38.00
-34.00
-82.00
-30.00
-28.00
t"8.00
14.00
•22.00 }i•20.00 |
-18.00 1c.-18.00
•14.00
•12.00
•10.00
•6.000
•6.000
•4.000
•2.000
-0.000a ' S: n1 1363 1g *
A/D Counta
•»8-i -i
S'P"Us4 ..*sZ£O 4-Oa x
•<T
? (U.. OD-i in•n o
Q.4Ja ..
COT3 Heg n£ u.Ua u•n Ofife
(UoHIo_, ff
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!U)
.-•:>*U
020 23N
X «'
/.; ' REPORT) 9318. tl CHANNEL) 1 PESTICIDES FOR IFB
( SAMPLE! QCI670 INJECTED AT .11i44i49 ON MAY 30, 1964*-Mtt.-
E6TD METHOD i IFBP/1 SEQi D:jH.OP SUBSQ/SAMP i 1/2 BTLi 2
SL-UDTH MV/MIN DELAY M1N-AR BUNCH.100 20.00 290 NO
SUP-UNK DVT ID-LVL REF-RTW XRTW XD1L-F ISOHO 0.00 250 .10 1.0 1.00 HO
ACTUAL RUN TIME: 39,917 HINUTES
/ RT ITM FACTOR AREA UG^G NAME
( 20,26 1, OOOOE- 3 703 BB ,00720,69 1. OOOOE- 3 2451 BB ,02522,96 I. OOOOE- 3 822 BB ,008
( 25,65 t. OOOOE- 3 6389 BB ,06427.84 27,46 2.5I82E- 3 905 BB ,023 (HICPTACIILOR bHUXMUC28.20 I. OOOOE- 3 1411 BB ,014
( 28.47 26,471 2.6097E- 3 1466 BB ,038 K1 CtlDOQULFAtl28,73 28.86 2.8217E- 3 890 BB ,024 «OU_29.43 29,17 3.1919E-3 637 BB .020 tftlELBRlH30,17 30,01 4.1096E- 3 1062 BB ,044 '»D EHMOULFHIIiPPDCiD30,52 30,52* 9.4967E- 3 699 BB .036 tEHPKlH •ALDCIIVU6,30.72 t, OOOOE- 3 719 BB .007
( 30.99 30,99* 4.9729E- 3 362 BB ,018 HHW31 ,97 1, OOOOE- 3 14781 BB ,14833.03 1. OOOOE- 3 646 BB .006
( 33,25 1, OOOOE- 3 2437 BB .02433.62 33,68 7.9I26E- 3 1 09383 BB 14.985 XDIBUTYLCHLQRENbATE33.62 33,68 7.9I26E- .37.15 1, OOOOE- 3 926 BB ,009
( 39.40 1, OOOOE- 3 785 BB ,006
TOTAL AREA • 226997 TOTAL UG/Q<G - 15,505
I PROCESSED DATA FILE) P0582 RAW DATA FILE) R0582
1364
Total Ion ChromqtpgromFlit >D2016 40.0-266.0 a*u. t4riBYnST7 n.BTJK IFB SHnPCtT
tee 208 300 460 580 600 760 I
4'' P ra ife ae 24 28 _j_' ' "'.6.'_.
Data File, >D2016,iUlNane, E471BUMQ1, 1200 MRSMisc. IFB SAMPLE 264Q-C9417MS1, VOA FRACTION, 840509, D
Id File, 1WFB2BTitle, IFB PURGEABLE PRIORITY POLLUTANTS IDFILE, 831107, I), KLLast Calibration. 840504 17,07
Operator ID, RL9134gaunt Tine, 840509 16.02
1365 0208.TO
QUANT REPORT
Operator ID. RL9134 quant Tine, 84050V 16,02Injected at, 840509 15,22
•»ta File, >D2016,.U1 Dilution Factor. 1,01)iianc, E4718VMS1, 1200 HRSMisc. IFB SAMPLE 2640-C9417M81, UOA FRACTION, 840509, D
ID Flit. DVFB2BTitle. IFB PURCEABLE PRIORITY POLLUTANTS IDFILE, 831107, D, RLLa»t Calibration. 840504 17,07
Conpound R.T, Scan* Area Cone Units
1) *Bronochloronethane 10,03 228 58474 250,00 ng2) Acrolein 4,70 91 118 30,59 ng2) Acrolein 4,89 96 137 35.51 ng2) Acrolein 5,17 103 333 86.32 ng8) Acrolein 6,10 127 132 34,82 ng2) Acrolein 7.27 157 30673 7950,71 ng8) Acrolein 8,59 191 178 46,14 ng3) Acrylonitrilt 8,05 177 44695 040,00 ng3) Acrylonitrile 7.03 202 157 2.95 ng4) 1,2-Dichloroethane 12,99 304 44712 156,19 ng5) 1,1-Dichlorotthane 10,19 232 134 ,43 ng5) 1,1-Dichloroethane 10,89 250 S5538 178,05 ng6) Chloroethane 4,35 82 8395 138,57 ng7) Chloroforn 10,89 250 7227 14,60 ng7) Chloroforn 12,25 285 80111 161.85 ng7) ChloroForn 15.25 362 49042 99.OQ ng3) 1,1-Dichloroithyltne 9.57 816 4166? 160,55 ngB) i,l-Dichloro.thyl«ne 11.63 269 30970 150.15 ng8) l,i~l)ichloroethyltne 12.10 281 113 .44 ng9) 1,2-Trans-dichloroethylent 9.57 216 41669 165.37 ng9) i,2-1ran«~dichloroethyl«ne 11.63 269 38770 154.66 ng9) 1,8-Trans-dichloroethylent 12.10 281 113 .45 ng
10) Methylcne chloride 6.57 139 26655 806,76 ng11) Methyl chloride 1,82 17 13760 146,34 ng12) Mtthyl bronide 2.75 41 4176 115.85 ng13) Trichlorofluaromthane 8.7? 196 57706 140.5*3 ng14) Dichlorodifluoronethane 3.30 55 1331 155,83 ng15) Vinyl chloride 3.38 57 10085 126.83 ng16) 2-Propanon* 7.31 156 22061 247,37 ng16) 2-Propanon* 8,17 180 204 2,29 ng17) 2-Butanont 12.91 302 23897 150.59 ng17) 2-Butanon« 14,51 343 165 1,04 ngIB) Carbon ditulfide ' 8,20 181 78388 182,34 ng19) *2-Br»no-l-chloropropan» 19,33 467 96077 250,00 ng20) Benzent 17.86 489 95869 159.45 ng ...21) Carbon tttrachloride 12.25 285 1021 3.40 ng ."i21) Carbon tetrachloride 14.24 336 6044 20.16 ng >21) Carbon tatrachlor.ld* 14.63 346 44903 149,74 ng ( ;22) 1,1,1-trichloroethane 14.27 337 46599 159.22 ng . i23) 1,1,2-Trichloroethane 18.17 437 29904 159.51 ng c,j24) 2-Chloroethylvinyl ether 19.18 463 23071 167,40 ng25) 1,2-Dlchloropropane 16,57 396 31105 161,75 ngnt>) trans-i,3-Dichloropropylene 16.84 403 48521 172.98 ng <_6) tran»-i,3~Dichloropropylene 18.13 436 46181 164.64
27) cl9~l,3-Dichloropropylene 16.64 403 48521 181.1527) cU-i,3-Dichloropropylene 113,13 436 46181 172.41 ng
1366
Canpound R.T. Scant Area Cone Units
28) Bronoforn 18.05 434 1082 4.84 ng?B> Bronoforn 20.70 502 36273 162.41 ng'"'S Dichlorobronontthane 15.25 362 53880 178.96 ng-0) ChlorodibronoMtthane 15.21 361 7537 24.37 ng30) Chlorodibronontthane IB.05 434 53393 172.63 ng31) Trichloroethylenc 17.39 417 35813 150.54 ng32) Vinyl acetate 14,86 352 10233 893,95 ng32) Vinyl acetate 16.10 384 1891 165,20 ng33) *l,4-Dichlorobutane 23.23 567 108815 250,00 ng34) Chlorobenzene 25.33 621 90805 161.04 ng35) 1,1,2,2-Tetrachloroethana 22.95 560 44100 184.92 ng36) Ethylbenzene 27,08 666 140901 164.96 ng37) Tetrachloroithylene 22.95 560 50589 145,12ng38) Toluene 24,20 592 103624 158.47 ng39) 2-Hexanone 21.12 513 39043 259,76 ng39) 2-Hexanone 82.68 553 26597 176,96 ng40) 4-Methyl-2-pantanone 21,12 513 39043 176,40 ng40) 4-MBthyl-2-pentanone 22.68 553 26597 120.IV ng41) Styrene 29.03 716 1B3 ,36 ng41) Styrene 30.39 751 89756 176.35 ng42) ortho-Xylene 30,62 757 87532 154,95 ng42) ortho-Xylene 31,40 777 193053 341.74 ng42) ortho-Xylen- 38,76 B12 294 ,52 ng43) neta-and-para-Xylene 30.62 757 87532 127,38 ng43) neta-and-para-Xylene 31,40 777 193053 260,94 ng43) neta-and-para-Xylene 32,76 812 294 ,43 ng
* Conpound la I6TD
367 020832
QUANT l:t:PORl
Operator ID. RL9134 • Uuant line. -40510 12,,V.1Injected at. tl40SOl? 15.S3
!)ata File. >D2016>.U1 Dilution Factor. .-',11ine, E4718VMS1, 1200 MRS
Misc. 1FU SAMPLE 2640-C9417M81, VOA FRACTION, 840509, D
ID File. DVFBL&Title, IFB Surrogates, VOA FRACTION, GC/MS DLast Calibration. 840510 12.31!
Conpound K,T, Scant Area Cone Unit-;
1) *»roMOChloronethane 10,03 288 58474 850.00 ng2) d4 1,2-Dichloroethane 12.87 -111 83089 94,5- r,g3) *2-Brono-i~chloropropana 19.33 467 96077 250,00 ng5) *l,4-Dichlorobutane ifU.23 567 108815 250.01) ng6) dB Toluene 24,00 587 168722 96,44 nij6) d8 Toluene £4,47 S?7 110 ,06 ng6) dfl Toluene 24.70 610 104 .06 ng7) p-Bronofluorobenzeno 27,22 721 101322 97,31 ng
* Conpound is IBID
IK t'
1368 020333
s {
aH•'81tfisbs
File »DBMBpk Ab 9910089i
8000-
,000:4066
2806-
0J
S HBS- R99
86
(J
l |f
ev. E D|/
35/ 1_. L
4_' (1
ta BascFull
82t ,
'•' 'flb' ''
sptctra of the N~J data Seao 1 7 dn
96X
181
1 . . ^ , . , , , ..^ , . , . . .
i 917min,-180
I60
J40'
:28
4)
Data File, )D8016,.U1Nana. E471BVMS1, 1200 HRB(Use, IFB SAMPLE 8640-C9417MS1, VOA FRACTION, 840S09, D
Conpound No. BConpound N-ne. 1,1-DichloroethyleneScan Nunber . 816Retention Tine, 9,57 nin,Areat 41669Concentration. 160,55 ng
u
1w
Filt >D20Bpk Ab 74
6006-
4000-
2080-
e-
16 -4718VMS1. 12Pi
44/
J
ee HRS IFB SAMP
j
^ IL r-V.
96X
f-
Lt 2'64---9417MSl , V.P Sew9.57
137 161
lfl / /'l_0 ' 169 ' '
•> 216min.:100
0
1 8
e•20
<
0208341369
8•A•8M^
E§
File >DBNS HBS Rev. E Bat^BaseFull spectra of the NBS data scan 366BpK AD 99
1 68681
8006-
6008;
4966-
0-
99 , 366. 0Ci
39 // .ii
j,, IJL., ,j, ,,,,,,,,,.,.,.,,,,,,,,,.,,,79
46 68 129 160 288
min.
|e0
601.•46
•20
4(Bn
Filt >D2016 E47I9VMS1, l.flft, HRS IFB SAMPLE 2640-C9417MS1 , VQfi scan 429Bpk flb 17624 '/ 17.86 *in.
16000-
12066'
8900-;
4060-
Q-
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Data File, )D2016,.UlNane, E471BVMU1, 12011 MRSMisc.. Ir-D SAMPLE 2640-C9417M131, VOA FRACTION, 840509, D
Conpound No. 20Conpound Nane. Bnn;.eneScan Nunber. 429Retention Tine, 17.86 nin.Area, 9586VConcentration, 157,45 ng
1370 °20833
File >DBHBpk Ab 99iceeo
8660-
6806-
480fr;
2908;
0-
S NB» Rev. E H-t» B-seFull spectra of the NBS d^" 1>B <
x.
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* 59
h 'r 48 6
liM-i |-i MI i mi i.l.TnM. ,,,,,,.. in
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6_flS>-
48»fr
200fr
8- •! i i'ii iM'p ri'i'i i 1 1 1 1 1 1-.-. ,
j*aOO44 _>-xM ^
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40 60 88
95"
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99S 110.L,,,,,..,(l'......ih,,.l JW---.---iir--
136/iii . , ,
j-10068
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•40
•28
Ifl'"Ui" "Data File, )D2Q16,,U1Nane, E4716VM51, 1200 MRShist. IFU SAMPLE 2640-C9417MS1, VQA FRACTION, 840509, I)
Conpound No, 31Conpound Nane, TrichloroethyleneScan Nunber, 417Retention Tine, 17,39 nin.Area. 35813Concentration. 150,54 ng
0206331371
.- \\
|1j3
File >DBMBpK flb 99r 1B800"
8606-
-a.D;
4066
m±&
s'""NBi R*w. E B*ta BaseFull fpg-c99 ^
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Kill.196
0
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'•4f>
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Filt >J>20Bpk flb 15
168081
12008-
8800-
4006-
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16 E4718VMS1, 1200 HRS IFB SAHPI966 ' '<
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4*0 W ljl4s|i|i.M7iili|i|'l,|ii|i|'MV>ii"i'.,ii".|''i.|"i.)"ii|""i""j""i'" •56
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»»5 164
1^' , S60 60 160 i.e ue 1 0
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•60
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Data File. )D8016,,UlNane. E4718VMS1, 1200 HRSM16C, IFB SAMPLE 8640-C9417M31, VOA FRACTION, 840507, D
Conpound No, 34Conpound Nane. Ch'lorobenieneScan Nunber. 621Retention Tine. 85,33 nin.Area. 90805Concentration, 161.04 ng
1372 020837 [.
s i
§(41VM*__S1b3
File J-flBMS NBi R»«. C tut* BMVfFull sp-etr_ of th» NtS data Scan 839BpK flb 99
IOBOO-
aeoet>ee«>4068-
J
2098-
99 . ' ,
39 65
» i , "i/ i LJI L Jl ,. t0- >i-i"l-i f'l'i T"r rrr i i 'i-|-i48 88
839. 08
94,/
mri.;10Q«•60
•**
'•40
;20
!a' ' ' ' 128 " 'l6fl ' 2*6
File >D2616 E4716VMS1, 1206 MRSUFB SAMPLE 2640-C941?MSl , VOfl Sc»n 592Bpk Ob 16726 * _, 24.26 Kin.
Tla016600-
12866-
8080-
480
0-
44 66^^ \
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6
40
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Data File, )D8Q16,,U1Nane. E47KIVMB1, 1200 HRSMisc. IFU SAMPLE 2640-C9117MSJ,, VOA FRACTION, 640509, D
Conpound No. 3UConpound Nane. TolueneScan Nunber. 592Ratention Tine. 24.20 nin.Area. 103624Concentration, 158.47 ng
VJ '
1373 020833
ion unromgiogromFill* >E1U
240680
228000-
208000-
180080-
leeeee-140886-
128086-
160680-
88086-
68006-
40060-
28086-
8-
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Data File. >E8193..U3Nane. E4750MS1Misc. IFB SAMPLE 2640-C9440MS1 B/N/A FRACTION,S/28/B4,»E BTLtl3
Id File. IFBENTitle. IFB P.E,QUANT ID FILE.,..WWC,.831114Last Calibration. 840528 12.48
Operator ID. WW9928Qaunt Tine. 840582 13.49
J
• 1374 020S39
QUANT REPORT
Operator ID. WW9928 Quant Tine. 840522 13.4?Injected at. 840S22 05.47
Data File. >E81?3..U3 Dilution Factor. 1,00• -vie, E4750MS1,,j.sc. IFB SAMPLE 2640-C9440MS1 B/N/A FRACTION, 5/28/84, *E BTH13
ID File. IFBENTitle. IFB P. E, QUANT ID FILE ... ,WWC . ,831114Last Calibration. 840522 12.48
Conpound R.T. Scant Area Cone Units
i) *d4-l,4-Dichlorobenzene 9.45 618 44562 40.00 UG/MLS) 1,3,-Dichlorobenzene 9.50 617 10701 10.42 UG/ML6) 1,4-Dichlorobenzene 9,50 617 10701 10,09 UG/MLB) 1,8-Dlchlorobenzene 9,50 617 10701 10,51 UG/ML
10) 2-Chlorophenol 8.99 561 20006 20,01 UG/ML18) 8-Methylphenol 10.35 710 14818 14.38 UG/ML18) 2-Methylphenol 10,76 755 20058 19.39 UG/ML13) 4-Methylphenol 10,35 710 14812 9, 10 UG/ML13) 4-Methylphenol 10.76 755 20058 18,38 UG/ML15) *d8-Naphthalene 13,09 1010 123174 40.00 UG/ML16) N-Nitrosodi-n~propylanine 10,80 759 81611 17,38 UG/ML81) 1,8,4-Trichlorobenzene 18.99 999 10868 12,60 UG/ML26) 8-Nltrophenol 18.06 897 10151 17.78 UG/ML87) 2,4-Dinethylphenol 18,89 982 9837 7,41 UG/ML89) p-Chloro-M-cresol 15,04 1283 27751 28,65 UG/ML31) IdlO-Acenaphthalene 18,59 1611 79762 40.00 UG/ML37) 2,6-Dinitrotoluene 19,59 1611 7373 11.88 UG/ML"7> 8,6-Dinltrotoluene 19.43 1702 17973 88,95 UG/ML/> Acenaphthene 18,69 1681 46404 18,13 UG/ML41) 8,4-Dlnitrotoluene 19,43 1708 17973 14,95 UG/ML48) 2,4,6-Trichlorophenol 16.31 1361 13838 19.47 UG/ML48) 8,4,6-Trichlorophenol 16,40 1371 15987 82,40 UG/ML49) 2,4,5-Trichlorophenol 16,31 1361 13838 18.35 UG/ML49) 8,4,5-Trichlorophenol 16,40 1371 15987 81, 12 UG/ML51) 4-Nitrophenol 19.88 1679 3769 17.61 UG/ML54) #dlQ-Phenanthrene 83,14 8108 193183 40.00 UG/ML60) Pentachlorophenol 28,80 8071 11711 84,00 UG/ML61) KidiS-Chrysene 31,36 3006 86189 40.00 UG/ML62) Fluoranthene 27.56 8591 83577 13,96 UG/ML64) Pyrene 87,56 8591 83577 14,16 UG/ML77) mdlO-Phenanthrene 83,14 8108 1931B3 40,00 UG/ML85) *dia-Chrysene 31.36 3006 26189 40.00 UG/ML
* Compound is ISTD i
0208401375
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1006-
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6ae-400-
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Data File. >E2i?3..U3) Nane. E4750MS1
Misc. IFB SAMPLE 2640-C9440MS1 B/N/A FRACTION,5/88/84,*E BTL*13
Conpound No. 6Conpound Nane. 1,4-DlchlorobenzeneScan Nunber. 617Retention Tine, 9.50 nin.Area, 10701Concentration. 10.09 UG/ML
020S42
W
Bpk flb 5287 s'- !">."•5206-4888
4408'
4006-1
3600-)64
3200-1
e-i
2808-1 , , pse
24B8-
2008-
1608-
1288-
400-1111 73
92N
70-i-i~i~f~r-n~ri m^i i ilie ' 120
•70
ife3
Data File. >E2193,.U3) Nanei E4750M81
Misc. IFB SAMPLE a640-C9440MSi B/N/A FRACTION,5/88/84,*E BTL»13
Conpound No. 10Conpound Nane, 8-ChlorophenolScan Nunber. 561Retention Tinei 8.99 nin.Area. 20006Concentration. 80,01 UG/ML
1378 020843
\
u"ft1
Bpk"flb~S92
5600-5200-4800-
4400-4086-3600-
3200-2800-
2400-
2006-
1680-
1200-800.
•400-
e-
U3 ^
56
s'0 6'0 7
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79
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i53 .•46
;-30:
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Data File, )E8193..U3Nane. E4750MS1Misc. IFB SAMPLE 8640-C9440MS1 B/N/A FRACTION,5/28/64,*E BTLtlS
Conpound No. 16Conpound Nane. N-Nltrosodi-n-propylanineScan Nunber. 759Retention Tine. 10,80 nin,Area. 81611Concentration. 17.38 UG/ML
1379 Q20844
\\
u1ireM
Fil* >E2193 E475BMSJBpK AD 2751
2680-
2408>
2200-
2000'
ieee-1688-
1488-
1288-.
1000-•
800-
600-
408-
288-
fl»
74
IFB SfltlPLE 2640-C9448MS1 B/N fij n 999
146\
X" 109N
s'0 ' i&e 1 " '120" " ' " ' i40"
12'. mm.
,, . . .^, -• , ' • '|je
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•70I:*0jse'.r40l!-39
•20
;16
Data File. >E2193,.U3Nane. E4750MS1Mi5C, IFB SAMPLE 3640-C9440MS1 B/N/A FRACTION,5/22/84,*E BTL*13
Conpound No. 81Conpound Nane. 1,2,4-TrichlorobenzeneScan Nunber. 999Retention Tine. 18.99 nin,Area, 10868Concentration. 18,60 UG/ML
380 020845
)s {
i I
4&M
File >E21Bpk Rb 66
«see-seeo-5500.
seee-4588-
,1860-
3668-
3000-
2G00-
2088-
1580-
teee-590-
6-
93 "' *«"''•"38
7
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63
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J901
•78
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1-18
Data File. >E2193..U3.' Nane. E4750MS1
Misc. IFB SAMPLE 264Q-C9440MS1 B/N/A FRACTION,5/88/84,»E BTL»13
Conpound No. 89Conpound Nane. p-Chloro-n-cresolScan Nunber. 1283Retention Tine. 15.04 nin,Area. 27751Concentration. 28,65 UG/ML
020843381
un3M
File >E21Bpk Pb 16
10088
gaaa
8088
7088';
6000-
5060-;
4000-
3000-
2080-
1080-
0-
93 E47SeMSI IFB SflNPL- ' 2640-C944"eMSr" B/N ,s«a105 l-ij
76y
63c_a..........,....,..r............f
\ ,
n 16219 min.•180
H*Jee
•70
J60
i50!;40
•30
ifData File. >Eai?3..U3Nane. E475QMS1Misc. IFB SAMPLE 2640-C9440MS1 B/N/A FRACTION,5/22/84,*E BTL*13
' Conpound No. 39Conpound Nane. AcenaphtheneScan Nunber. 1681Retention Tine. 18,69 nin.Area. 46404Concentration. IB,13 UG/ML
020«47
\ \
\
u•ai/i
t ii* >t-iBpk flb 41
0
4688
3686
3200
2808-
2488-
2Q86-.
1600-
1200-
800'.
40e-
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63\
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191
20 ' 140 ' 16B
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Data File. >E8193..U3Nane. E4750MS1Misc. IFB SAMPLE 3640-C9440MS1 B/N/A FRACTION,5/22/84,*E BTLtiS
Conpound No. 41Conpound Nane. 2,4-DlnltrotolueneScan Nunber. 1702Retention Tine. 19.43 nin.Area. 17973Concentration. 14.95 UG/ML
,
0208,431383
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1868
ei EBB'
lt?B900 :1 fee
800-j I
B-70780-1
680
400-
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200-
108
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Data File, >E3193..U3' ) Nane. E4750MS1
Misc. IFB SAMPLE 2640-C9440MS1 B/N/A FRACTION,5/88/84,*E BTLtlS
Conpound No. SiConpound Nane. 4-NitrophenolScan Nunber. 1679Retention Tine. 19.82 nin.Area. 3769Concentration. 17,61 UG/ML
0208491384
V,1
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2666-
240B-
2280-
2000-
1800-
1608-
1400-
1208-
1000-
800-
688-
400-
200-
0-
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irjj *ni'irLL f. "tf-t.'f'JS'l'K-l J?'f) ,_£ift?6 a<i2<
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95X" 130
\
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' 'ide' ' '200' ' 'a.e' ' 240' ' 'aie'
« •>!> "7 ,T Mw i *6 nun.:106
90
J3rtT3W
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f50
H9;39
:29J-ie
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Data File. >E8193. .U3Nane. E4750MS1
iii»i!iiiii
Misc. IFB SAMPLE 8640-C9440MS1 B/N/A FRACTION,5/28/84,«E BTL*13
Conpound No. 60Conpound Nane. PentachlorophenolScan Nunber. 8071Retention Tine, 88.80 nin.Area. 11911Concentration. 84.00 UG/ML
385 02083°
I"'-S
M
rue /_tfi?o .•••--••• " * '""rut. _e*B-_»ittori_» »/M jigon 2691Bpk flb i364i .itisejian13000-
0126001
11680
5800-
4060'
3000-
2808-
8-
ie08 (-709000'
8008-1
7900
6000-
101
83
100
NO1000-
lee
•96
r20:
Data File. >E2193..U3Nane i E4750MS1Misc. IFB SAMPLE 2640-C9440MS1 B/N/A FRACTION,5/28/84,*E BTL*13
Conpound No. 64Conpound Nane. PyreneScan Nunber. 8591Retention Tine. 37.56 nin.Area. 83577Concentration. 14.16 UU/ML
386 020851
'"/x
1 ' 1}
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020852
REPORT! 5208,21 CHANNEL) I PESTICIDES FOR IFB(
SAMPLE! ES605 MSI INJECTED AT t4iS3)4l ON MAY 18, 1964Cos* SWOffi C94?&
( <'"|ESTD METHOD i IFBP/S SEQlC2$4JP SUBSQ/SAMPi \t 6 BTLi 6
SL-WDTH MV^MIN DELAY M1N-AR BUNCHI .500 JOO 20.00 250 NO
SUP-UNK DVT ID-LVL REF-RTW XRTU XD1L-F ISOI HO 0.00 250 .10 1,0 1,00 NO
ACTUAL RUN TIME, 39,917 MINUTES(
RT 1TI1 FACTOR AREA UC/LKC NAME(
20.77 1.OOOOE- 3 442 BB .00422.31 22,311 2.8023E- 3 3160 BB .089 ftABHC
( 23,30 23,301 3,1822E- 3 790219 BB 25,146 tLINDANE23.89 23,891 3.8231E- 3 40S2 BB .155 ND BHC24.75 t,OOOOE- 3 387 BB .004
( 25.38 29,381 3.9690E- 3 605239 BB 24.143 DHEPTACHLOR26.40 26,401 2.6053E- 3 850630 BB 22,161 IALDRIN27.24,27,49 3.4237E- 3 13227 BB ,453 HHEPTACHLQR EPOXIDE
( 29,11 1.OOOOE- 3 690 BB .00728,52 2B,S2» 3.8312E- 2 305 BB ,012 «A ENDQSULFAN26,69 28,891 S.S5I7E- 3 ,.j, 1171 BB ,.065 «DDE
( 29.13 29,18)1 3-JW8f- 3^J 533500 BB 49/&12 IDIELDR1H * jtf29,52 1,OOOOE- 3 3628 BB /V036
, 29.80 29,601 7.2200E- 3 353043 BB 25,490 (tENORIH0 ' 30.00 30,00* 6.5354E- 3 15117 BB ,986 KB EHDOSULFrtH+PPDDD
30,14 1,OOOOE- 3 BOS BB .00630.53 30,531 8.8820E- 4 1552 BB ,014 OENDRIM ALDEHYDE31.04 31,04*32.0532,7333,3433.71 33,711
,2302E- 2 292969 BB 36,041 I.DDT.OOOOE- 3 639 BB ,006,OOOOE- 3 13456 BB ,135,OOOOE- 3 531 BB ,005.3970E- 2 31149 BB 4,352 «DIBUTYLCHLQRENDATE
( TOTAL AREA » 3515914 TOTAL UG/LKG • 189,126
PROCESSED DATA FILE) P0284 RAW DATA FILE) R0284
389
s \
total Ion ChromotogromFile MJ2649 40.0-265.0
100 200
90866-
?8800-
C0008-
50090-
40000-
30000-
20000-
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( ' Data File, )1)1'>04II, .1.11None. _47iaWMW™. £1150 Hl.'liMisc, Ifli UAMI'l.li:' 2«,4l)-l;:V4lVM!:!IH, Wf, FKACTHiN, B4(lliUI, I)
id File, UVFB_»Title. Ifli PlIlUJC-.AlILt; PRJOfiin POLLUTANTS IDFILL, IMUOV, 1), Rl.Last C.ali.tir'<Hti.urn li-illVili-; i7.li','
Operator ID. RL9134Uaunt l''ine> Ei4ll5il. 11.58
r -v '
H90 020855
ii,-,e. n-iu'.,j i ji '..I-lli.VKIeil fit. llHH'ii. Xli.il.-i
Data File. ji»;-!iM«. ,m i/iluum. i amir . i.uli. 'jinn. -4710VMS2, ailS.O HKS
.il-.i: . ,11-H tiAMr'l.E 2640-C;941VMK!, VOA FRACTION, MO'SlO, 1)
11) File. DVFB2BTitle. IFB PUKKAULt: PRIORITY POLLUTANTS 1DF11.E, 031107, I), KLLast Calibration. U'lOSOfl 17.0V
Uonpound R.T. Scant Area Cone Units
i) *BronochJ.oronethane 10.04 22U 4'WO 250,011 nijIi) Acrolein 1,67 VII UIU .Vi.SlJ ny_> Acroiein 'J.M ill 2 36;* 11_,QU nij_) Acrolein S.41., nu 211 74. 41 ny2) AcrolPin 'J.64 11- 24i! 74,72 nga» Acrolein 5.UO uv it.li 4V,4u ny_) Hcroiein l-.4a l_5 147 41J,39 ngU) Hcroiein 6,77 H-! nil ;.._.4'« ny2) Acroifin V.36 l_9 17U M.76 nq_» Acryloni-tr:i..l,e B.lil 1711 401.'., BVU.iit ng4) i,2-lnctilorok)th,ine l-.OII SO-1 4t:_;57 17B.VS nuS) i,l'-Dichloroetlnne lli.VIl UCli 'I7C7'." lUl.'/l) ny6) Chloroethane 4.Ill B?, 7200 141.'.,7 ny7) Chlorot'orw ill '.'« _'.;u t.OEiti 14,6.1 ngV) Chloi-oforn i-.tfo MU'j 6VB71 168,80 nn7) Uhloroforn I'J.li. .bii -1U__li VV.7S ny8) 1,1-lij.cnloroethylene V.SB _l(j 3S1?V3 1-1 ,'.1U nijU) 1,1-Dichloroethylene 11.6U _7U 33956 iSS.ii'i ngV) i,_"'1ran9»-tlichlorof>thylene V.5CI 21.6 3_B93 H.-.U4 ny9) l,_-lranB--ichJ,oroettiyient( 11.«i« a'.'ll W91..1, 1(,0,.K ny
10) Methylene chloride 6.Wi 13'? 603S4 461."/Vnell) nethyl chlornie i-t't IB 147£!4 1B9.I11-1 ny12) Methyl tironiae 2.VE1 4H i:S3\.i C',3,V7 no13) -Irichlorofluorunethane U.W 1V7 49c/Vi liS.0.1 ny15) Vinyl chlorirtR 3.313 57 10168 ISE.ai;! n.j16) S-'l'ropanone 4.S6 Ul.: 117 l... r,yla) a-Propanone S.37 100 illl 1,-Sng16) a-Propan»ne Vi.9V 124 10- 1.4U ny16) 2-Propanone 7.44 161 XU27? H44.14 nyU>) 2-l'ropanone B.14 179 _SU a.41-; ng16) 2-Propanone 8,41 186 2S4 3,39 nrjl',1) 2-tiutanone 13,00 304 _24B4 168.84 ng17) 2-Butanone 15.10 3(.,fl I65i 1.2-1 ng17) 2-tiutanone i l!j.H4 37V1 2'jJ 1.711 ng111) Carbon disulfide 8.S5 IQi! 79373 17l3.t!2 nyIV) *l'.-Brono-l-chloropropane 19.20 466 114917 250.011 ng20) Benzene 17,96 489 132369 155.00 ng„),) Carbon tetraehloride !_.__ 205 777 _.ui ng21) Carbon tetrachloride 14.BB 337 4796 iU.iOncj_1) Larbon tetrachioride 14.4.'.' a4? a'JUUi 13'J.Uuny ,'a_) 1,1,1-trichJ.oroBthane' 14._U 337 AWVQ ISO.76 ny (",_,•'_'_) 1,1,2-l'richloroethtine ili.14 4'-6 Uli4VU li',V.7<i ng24) 2-Chlor»ethyl»inyl ether 19,19 463 F.II141 16S.34 ny35) 1,2-UiChloropropane 16.SU 'A'!t> HV077 l','l.«l,l ny<j) trans"l,;H)ichloropropylene ib.BC 4113 3i:il)?7 1M.3B ng
!U.t4 43i, ..iblilM i4'j.a_ng
3o, 020853 -
Ciofipound K , I . Ucan* Area lira i
27) cis-l,3~))ichloropropylene Kj.BU 403 3UQJ'7 160.63 no27) cis-l,_.-DKhioropropylene 1U..V-1 4.K, -blliM 182,1>U nyF__) BronoVorn 1U.02 133 1U93 S.SUnn.™) Bronoforn i'U.'/i 50 a 20017 141.V_ ng29) Dichlorobrononethane )S..26 36H 447IJ4 168.30 na29) Dichlorobrononethane 1V.4U 11.V 217 .OJ ny30) Chlorodibrononethane 15.22 361 62B3 22,VU ny30) Chlorodibrononethane ID.lit 434 43940 160.7-1 nej3D Trlchloroethylene 17.44 41U 297112 141.26 ng32) Vinyl acetate 13.93 _au aoiB 19V.4» ng32) Vinyl acetate 14.2H 337 343 33,90 ny32) Vinyl acetate 16.19 _Ub 82SS 222.B* ny33) *l,4-Dichlorobutane 23.24 567 1033313 250.00 ny34) Chlorobeniene 25,30 620 768t)l 14J.5'/ ny35) i,i,a,2-Tetrachloroethane 22.96 560 35935 158.66 ny36) Ethylbenzene 27,09 66. 1-OOU5 147,9S ny37) Tetrachloroethylene 22.96 S60 40667 122.U4 nrj3El) Toluene 24,ai S9't' V.OVfc 149.8U ny39) 2-Hexanone 21.17 514 36V1.3 2S8.61 nr,39) 2-HeKanone 22.69 553 29227 21)4.'/„ ny40) 4-Methyl-2-pentanone 21.17 514 36913 17S,62ng40) 4--Hethyl-li-pentanor,e -W.6V 55- li'/__7 139. II1- ng40) 4-Methyl-2-pentanone S3.74 1,80 4054 19.29 ng41) Styrene 3U.4U 7'.H 4U142 9r/,ftllny42) ortho-Xylene 27.133 6V.H, 101.1 .211 ng42) ortho-Xyiene eb.Bi '/O.1, 1611 .,..11 ng42) ortho-Xylene 29.12 Via US, ,77 nu42) ortho-Xylnne -U.M 751/ 7'J7U9 ill.iiV nyf) ortho-Xylene 31.45 7VO 165VHV 309.26 n?
l i) neta-and-para-Xylene ill,64 757 757B9 116. H ng43) neta-dnd-para-Xylene 31.4SI V7Q H,59IIV _54.23ny
* Conpound is I8TD
392 020857 '
Dpi .. ... •
!>,s t i . ., . >]l: • • . " • • •
Ml!
II) ».,,;-• -/•'.Tn '•• ,'••'• •La. ',.".... -." '
,u.in1 ..v;; "•''•"'•" -'" "" ""1) .!,:,„,„.. ..- - ".- •••""- ;§. ,,.. ,.„, ,-••„•..„ niu •;•; ,„,'•*' « • • - > . - • ' ••"•'"• "" •••"" . ,. .,-, .,.,(. iMVj'.' I:Ml «" "'•3) ::,.: i.:. ..." •.,.-.-.- -.•••"= , .,.,,. IU -;,;,.. ,'',11 uu „,
Miv riv,1,-, ',-? 21. '".•
1393 02085
uua
1(Stxt'tt£
i r , i B \niiMc MRJ I>B'.I , F lists JaseFul! spectr» «' fh^ M' S dat* "-•„•• il<"1DDK at ??
10890-
8000.
*i Add
4000i.
0-
2625 ,/"X f 4? 1
91P.08
V"
70 82,.,,',„.,../„„.,.,,„
38 Ve ' '& ' a'a '
161
•I'"""
inn.,rlOO-.j-88
1'•40.
ki100 120
"3,aaw
FiU >D204e E4718VMS2, 2l_£e HRS; IFB .AMPLE 264a-C9417MS2 , VClfi Scan £16Bpk fib 9140 7
8000-
6000--
Afatllt'.
2000-f
e- j
6_1
,,„ II
74\
>£1 40 tjg.
9.E8 min.
96
84 1 1'6j i o r *%J, / N
8t» 168 129
j.0
-rwr40•-0
-c
Dd16 r-lle. )D2ll40i .111Nane. hM7iSy,V,i;:, 2050 HR!;iMisc. Il-'li 8AI-1PI.,- 26411-C9417MCI2, VI.IA FRACTION, B4II510, 1)
Uucipuuncl No tlC impound Nane. 1,1-UichlorQethyleneiicati Nunber. ;j.\t,Retention Tine. 9.SB nin.urea. 35293Concentrfltion. 161,90 ng
020S5H
'Fil.- r,!-'f'°. ''"'- *#'>< ,•• i''IT,), ha-if.r uii ffttit rr.'~ of rno r-ie.-"~dji:.iiI F.L,|. iM, iii'S ' '•'U i ' I-' /•„•;,,.., • i, . i. -... , i
i p*t;\ .U'lfuV V. ,'1> I i '.- ,im l il« ' T^il '£ • """j<- I i-3,!L,,-J .--...iPv -i,..,.'')l)H,
sVCli-', «li'S*|..Hfts. JFE iK'"
V'- ,
,'ii:. .. J ..I,iri. .....''. ...,41,
I .'7 '••"•'"•••.. ..•• ' !u'c, i ys
i(«, -,.-, . . . . . i.,:ii-t.i . .ini:,.ii...... . ,,-..',.;,,'. ;.ii'.,» ,,,...i. .I.... :: iWi..;1. l' i'-.'.-'.'.!-!';1;.!.!'.'!-,.:-, Wf> I i.'i-.(:T:il.ii', i.i-1li'.,i il ,
Mt''U?.'l|. ...., i k l i i r . .,',•,)(., II. h.n, t.',l . ......'.I..'.1i:«rn. .si. i. .. ' . ni, • .1'...'..,. ill, in.
395
020860
(IJI-
.* «! IIt'. .n.pi* ',-•, I^ Im lU I
*•..>••.. .
v iii grip _
. . . .J . . ..."1 ••-.., ,.
'•I',,.... ,.,•.!, I'., ',:",',.:„.': '.'I'l-l i I I . i . "I I ll I I . i I '{ il'.". I t. . II
•\
11 /p,.--:fr.i •:.' fit'- 'it
II*._-•
IKfc .'Allfei'l.. .c.4u-C*^l,'M_^, VClH
I ;J HI'II,-
II...l ••.''.'
','l.lh I I.Vil.TU'li'l. ll-ill1", I II .
I,),,..,,, . .,11-
/"•"''
020S82
p:'•--L,'
i . LI..NU t«/iaVh._, -Wbt' MKi.-.lfli tHMfLt .'o U-C.'itll/I'Ui, VOH -..;i,r. ....,'flh .-V.I lr.._ -.I,.-': - - .
020683*
Total Ion ChromatogramFile >E21
240080-
220008-
280008-
180008-
160000-
140000-
120000-
88808-
68008-
40.08-
20000-
0-
94 40.0-450,0 *«u. E4750HS2 IFB SRMPLC 2640-C9448MS2TIC
.10,08 , 20,00 , 3000 , 4880
rL Myl 1 tl . l i , | [( , ————
Data File. )E2194..U3Nane. E4750MS2Misc. IFB SAMPLE 2640-C9440MS2 B/N/A FRACTION,5/22/84,*E BTL*14
Id File. 1FBENTitle. IFB P.E,QUANT ID FILE..,,WWC..831114Last Calibration. B40522 12,48
Operator ID. UW992BQaunt Tine. 840S22 14.05
1400
QUftNT REPORT
Operator ID. WW9928 . Quant Tine. 840S22 14.OSInjected at. 840522 06.39
fMta File. >E2194..U3 ' Dilution Factor. 1.00'\e> E47SOMS2
Misc. IFB SAMPLE 2640-C9440MS2 B/N/A FRACTION,S/22/84,*E BTH14
ID File. IFBENTitle. IFB P.E.QUANT ID FILE.,,,WWC.,831114Last Calibration. 840522 12.48
Conpound R.T. Scant Area Cone Units
1) *d4-l,4-Dichlorobenzene 9.47 617 45248 40,00 UG/MLS) 1,3,-Dichlorobenzene 9,51 622 11954 11,46 UG/ML6) 1,4-Dichlorobenzene 9,51 622 U9S4 11.10 UG/ML8) 1,2-Dichlorobenzene 9.51 622 11954 11.56 UG/ML
10) a-Chlorophenol 9.01 567 20151 19.85 UG/ML12) 2-Methylphenol 10.36 715 14989 14,27 UG/ML12) 2-Methylphenol 10.77 760 20589 19,60 UG/ML13) 4-Methylphenol 10.36 715 14989 9,07 UG/ML13) 4-Methylphenol 10.77 760 20589 12,46 UG/MLIS) *d8-Naphthalene 13.11 1015 127674 40,00 UG/ML16) N-Nltroaodi-n-propylanine 10.Bl 764 23233 17,96 UG/ML21) 1,2,4-Trichlorobenzene 13,01 1004 12509 14,00 UG/ML26) 2-Nitrophenol 12.07 902 10054 16,99 UG/ML27) 2,4-Dinethylphenol 12,30 927 11603 8.43 UG/ML29) p-Chloro-n-cresol 15,06 1228 27851 21,93 UG/ML31) *dlO-Acenaphthalene 18,60 1615 81796 40,00 UG/ML37) 2,6-Dinitrotoluene 18.60 1615 729B 11,46 UG/ML
>> 2,6-Dinitrotoluene 19,43 1706 20644 32,43 UG/ML39) Acenaphthene 18.69 1625 51073 19,45 UG/ML41) 2,4-Dinitrotoluene 19.43 1706 20644 16,74 UG/ML48) 2,4,6-Trichlorophenol 16.32 1366 14043 19.26 UG/ML48) 2,4,6-Trichlorophenol 16.41 1376 15910 21,82 UG/ML49) 2,4,5-Trichlorophenol 16.32 1366 14043 IB,16 UG/ML49) 2,4,5-Trichlorophenol 16,41 1376 15910 20,58 UG/ML51) 4-Nltrophenol 19.22 1683 4000 18,22 UG/ML54) KidlO-Phenanthrene 23,14 2111 199065 40,00 UG/ML60) Pentachlorophenol 22.80 2074 13081 25,58 UG/ML61) *dl2-Chrysene 31.38 3012 28024 40.00 UG/ML62) Fluoranthene 27.57 2S95 93883 14,62 UG/ML64) Pyrene 27,57 2595 93BB3 14.83 UG/ML77) *dlO-Phenanthrene 23.14 2111 199065 40,00 UG/ML8S) *dl2-Chrysene 31.38 3012 28024 40.00 UG/ML
* Conpound is ISTD i
J
. 14n]° 02086
.T <!».
U)<U '
O <S O CJN 05 •» (I,n « w w
1402
1 ii
r -C ,V •*
s
Ua.
File >E21Bpk lib 34
3200
2880
2408-
2800-
1600'
1208-r
808-
400'
8-
94 E47S0MS2 IFB SflMPL'E 2640-C9440MS2 B/N .568 <f\
111
75
50S
\... w ..... s'0 ' '100 ' i.0 ' Ue
If0 1In 622it. in.rlO«
:?0
r60
;70
:«e
.e
-39
:2er104}
Data Filei >E2194,.U3Nanei E4750MS2Misc. IFB SAMPLE 2640-C9440MS2 B/N/A FRACTION,5/22/84,»E BTL*14
Conpound No, 6Conpound Nane, 1,4-DichlorobenzeneScan Nunber. 622Retention Tine. 9,51 nin.Area. 11954Concentration. 11.10 UG/ML
t-..„.'
1403
X \
I . .File >E2S94 -4i'btfnS2 IFB SIMPLE 2&40-C944BMS2 B'H " "sfsarTssTBpk flb 5315 9.fl min.
S208 '*«•
4800-
4400
4080-
3600-j 6<*
3808-
aeee-8400-
2086-
1608
1288-
488-
0J
92N.>. i 20see-
•1073
40•39
^
Data File. >E3194.>U3Nane. E47SOMS2Misc. IFB SAMPLE 2640-C9440MS2 B/N/A FRACTION,5/22/84,*E BTLtl4
Conpound No. 10Conpound Nane. 2-ChlorophenolScan Nunber. 567Retention Tine. 9.01 nin.Area. 20151Concentration. 19,85 UG/ML
1404 02056:
File >E2194 H^BnsZ IFB SRHPLE 264B-C944BMS2 B'N sc_n 754Bpk Rb 6146.X ?e 18.81 m.in.
6880-6600-5200-4888-
4400-4808-3600-
3208-
2800-
2400-
2880-1600-
izee-6B0-100-
0-
^
58 " 'lol> 113
s'0 e'e 70 s'e 9'0 ie'e lie 120 ii
-ieo
Jjg
jee
•78
i6959
40
;30•*9
r19
ee
Data File. >E2194,.U3Nane. E4750MS2Misc. IFB SAMPLE 2640-C9440MS2 B/N/A FRACTION,5/22/84,»E BTLtl4
Conpound No. 16Conpound Nane. N-Nltrosodl-n-propylanineScan Nunber. 764Retention Tine. 10,81 nin,Area. 23233Concentration, 17,96 UG/ML
1405 020869
I:
\
•aftiW
File >E2194 Et75enS2Bpk fib 3161
300028802680-24802200-2008-
1880-
1600-1480-1286-1BBB-
800-
600-
400-
280-
0-
74X' 109
\
IFB SflMPLE 264e-C944BHS2 B/H SMirj
145\
"e.""""!..1"1111!..""1'1!*.1 1 168 ' ite
MI loot1 Bin.;108
•90
a
•70:<0
J58
r*0;38
r28' « a• "
-H3
Data File. >E2194.,U3Nane. E47SOMS2Misc. IFB SAMPLE 2640-C9440MS2 B/N/A FRACTION,5/22/84,*E BTL*14
Conpound No. 21Conpound Nane. 1,2,4-TrichlorobenzeneScan Nunber. 1004Retention Tine. 13.01 nin.Area. 12509Concentration. 14,00 UG/ML
1406 020570
X i
\
utidM
File >E21Bpk flb 66
6500
6808
S508-
seee-4508-
4808-
95C6-
3080-
2580-
2008-
1E08-
1880-686-
0-
94 E47S0MS2 IFB Sfl'MPfE £41 l
77/
51/
.3
1, ,,, L. n.iJ'l......... ............... M. - . III
t4JB-C94?BTIS2 B/N $CaY 15. e
142\
I I60 80 180 120 148
n 12236 niin.:i06e60
•70
<0
4j0
H0•38
:20r'0^
Data File. >E2194..U3Nane. E47SOMS2Misc. IFB SAMPLE 2640-C9440MS2 B/N/A FRACTION,5/28/84,»E BTL«14
Conpound No. 29Conpound Nane. p-Chloro-n-cresolScan NuMber. 1228Retention Tine. 15,06 Min,Area. 27851Concentration. 21,93 UG/ML
407 020671
If* .HHPLE -64e-t.944enS2 B/N lSS*!l 'lax?? m.]loeeflT
7008-3u'•aW
,3
,70
4898';
3 j I1!-303i566-
51
X
63X
76/
1 ".1II. i
!i2000: 63 . 1 .1
c. >*" ll::.,e
6'e
Data File. >E2194..U3Nane. E47SOMS2Misc. :FB SAMPLE 264U-C944QMS2 B/N/A FRACTION,5/22/84,*E BTL*14
Conpound No. 39Conpound Nane. AcenaphtheneScan Nunlier. 1625Retention Tine. 18.69 nin.Area. 51073Concen.'ration. 19.45 UG/ML
.""I
408 020S72
x \
I F i l e /E.194 E47S0Mt2 IFB SflMPLE 264&-C9440NS2 B/N .gfan 1706! BpK flb 4548 \y+*'i mm.I r ^^—_1 nn '
.I 44C.U-. . .
! * !i -199*-
! 3690ii
i 320ej 2800
i **%%•I|
, 1 688
, . - JU
666
: 46'C,>
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64
1 ' I ' ' '
89
^
8,'
3i
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1
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i
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19 :/
.0"" ' " ' i4e' " ' ' " jie'
II
70 ;
-*0 '|
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•S0
'•23 |
«
Data r:'.le. >E2194. .U3Nane. E^7SOMS2Misc. :f:;; SAMPLE 2640-C9440MS2 B/N/A FRACTION,5/22/34,*e BTLI-.HConpourn;; No. 41Conpound Nane. 2,4-DinitrotolueneiScan Nun&er. 1706Retention Tine. 19.43 nin.Area. 20644Concentration. 16,74 UG/ML
1409 0205$
if j, innp.t «Dt«i--»'»i«in*< »"'' ic.r ' t i!r-!'Vt7i-» 6S' '" 15.22 It'.:.';,k flb lliju- 139 rU->.MOB-::
hec908-3!
888-" lf-re]!700-;;<ii113!
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1
i1.1
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Data Tile. ,__i?i. .U3Nane. E47'.ti-,w_Misc. ir-tl In.'./uE 264Q-C9440MS2 ti/N/A FRACTION, 5/22/84, t£ BTLtU
CunptiUi'-.c :iu • 'iiCohpiiui.il I.^MW 4-NitrophenolScan NunGi'.i1 . iivO'JReter.t.on ".,,.. 19,22 nin.Are;.. iw.wConcer.tr a ,-;.„ . 1Q.22 UG/ML
1410 020874
Pi 2?:27CC""
£i?tiii&"
£4uu-.'
.:cc-2900-
isee-'
1-tOO-
-.203-;
239
D a \ in > . . ... w - ( -. mi 1 / "i > • vJ M, 't t '«/wi iwh..u. .;,•;:• .,,,;.. ,-i. -,4i)»C9440Msa U/N/A FRACTION, 5/22/34, *E
un,., AV,,,,. . .'u-rriucnior opt.enolSeal, hv.-.jt, . _ll'MRct.n,..-./.. , .,, -.-.•• --.til) Min,Ar 611, . *M ww.hConct-,, . .. ,..„„ ' W.S_ UG/ML
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411 020875
ikI
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Cn.-.|.. v. . -, »i
3,;.-; i.'.,. . .......A.' -. • ,...»..,"o,,.; .-.. .. . .•;. JjVi JU/ML
S i
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1413
I £|
020577 |
U.H-•.71 •
m.m
•Jf•.71 ••.M
I7JI +>-26.00 o Z
M.7B-2 -00 TT n
an
•33.00
•36.00
-34.00 gj
•32.00
•30.00
•28.00
-22.00•.71
1-20.00
.3
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iu ai*
o
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1414 iVDCounti 020S73
REPORT: 5209.21 CHANNEL i 1 PESTICIDES FOR IFB
SAMPLE! E5605 MS2 -INJECTED AT 15 ! 41 i 58 ON MAY 18, 1984
f. ESTD METHOD l IFBP/3 SEOi C2_4_>P SUBSQ/SAMPi 1/7 BTLl 7
SL-WOTH HV/MIN DELAY M1H-AR BUNCH( .500 ,100 20.00 250 NO
SUP-UNK DVT ID-UVL REF-RTU JiRTM KDIL-F ISO( HO 0.00 250 ,10 1,0 1,00. NO
ACTUAL RUN TIME! 39.906 MINUTES
RT ITtl FACTOR AREA UG/LKG NAMEI
20.76 1.OOOOE- 3 763 BB .00822.31 22.31* 2.8023E- 3 3143 BB ,086 tABHC
( 23.29 23,29* 3.1822E- 3 793550 BB 25.252 «LINDAHE23.89 23,89* 3,8231E- 3 3999 BB ,153 «D BHC24.75 1,OOOOE- 3 364 BB .004
( 23,36 25.38* 3.9890E- 3 630095 BB 25,133 NHEPTACHLOR26.39 26.39* 2.6053E- 3 872529 BB 22.732 ttALDRIN27,24 27.48 3.4237E- 3 13650 BB .467 HHEPTACHLQR EPOXIDE
t 28.11 1.OOOOE- 3 646 BB .00828.31 28,51* 3.83I2E- 3 297 BB .011 «A END03ULFAN28.89 28.89* 5.5517E- 3 ,y 1162 BB ,064 «DD£
( 29.17 29.17* f-jU* 3 "i 549399 BB 5#297 IDIELDR1N j -' *29.52 TTOOOOE- 3 t-l* 3527 BB ',03329.79 29.79* 7.220QE- 3 365095 BB 26.360 *ENDRIN
' 30.00 30.00* 6.5354E- 3 15553 BB 1,016 «B ENDOSULFAN+PPDDD30,14 1.OOOOE- 3 663 BB .00930.52 30.52* 6.8820E- 4 1307 BB ,012 «ENBR1H ALDEHYDE
( 31,04 31,04* I.2302E- 2 297338 BB 36,576 «DOT32,04 I.OOOOE- 3 252 BB .00332.73 t,OOOOE- 3 13305 BB ,133
( 33,33 1,OOOOE- 3 493 BB ,00533,70 33,70* 1.3970E- 2 29799 BB 4,163 »DIBUTYLCHLOREHDATE38,03 1.OOOOE- 3 1177 BB ,012
TOTAL AREfl • 3598529 TOTAL UC/LKG • 193,545
( PROCESSED DATA FILEt P0285 RAW DATA FILE) R0265
I
,.• ' I +•'{,'"
020S73 ,1415 ^
Total Ion ChromotogramFll. >C82_7 48.8-8*6.8 MU. E475gVHSi;.-8BHRSTiCTrB-SFmPTI72CTi)-ljy44ai15V
tee aee see 4 d e e tee ?ee eee 9ee
1280060-11180000-
leeeeee-900089-
933898-
709B00'
608800-
500000-
teeece-380000-
200000-
100000-
e- W-*-*__- JxAy_AA/VTJH_>J*Ar ^, .yn~ rf • r- ,,6 n^- , 2'4 • • • 2'e • • • 3-_ • • • 3-6
Data File. >C2227.,U1Nane. E47SOVMS1,22QOHRS,*CMisc. IFB SAMPLE,2640-C9440M81,VQA FRACTION,5/17/84
Id File. DYFBLBTitle. IFB PURGEABLE PRIORITY POLLUTANTS IDFILE, 831107, D, RLLast Calibration, B40S17 16.05
Operator ID, MM5066Baunt Tine. 840518 10,1?
020S30
P.'/
\(
QUANT REPORT
Operator ID. MM5066 Ouant Tine. 810518 10.19Injected at. 840518 00.14
D«ta Flit, >C2227..U1 Dilution Factor. 1.00Nil Me. E47SOVMS1,2200HRS,*CMisc. IFB SAMPLE,2640-C9440MS1,VQA FRACTION,5/17/84
ID File. DVFBI.BTitle, IFB PURGEABLE PRIORITY POLLUTANTS IDFILE, 831107, D, RLLast Calibration. 840517 16.05
Conpound R.T, Scan* Area Cone Units
1) UtRronochloronethane 8.37 186 18760 250,00 no2) Acrolein 5,58 116 1137 641.44 ng3> Acrylonitrile 6,24 133 19672 893,89 ng4) 1,2-Dichloroethane 11.40 266 42062 263,69 ngS) 1,1-Dichloroethane 9,19 209 31SB7 182,04 ng6) Chloroethane 3.17 54 11398 185,73 ng7) Chloroforn 9,19 209 3992 17,23 nq7) Chloroforh 10,66 247 39617 171.82 nq8) 1,1-Dichloroethylene 7,87 175 23050 175,17 nqi) 1,1-Dlchloroethylene 10.04 231 29940 227,54 ng9) 1,2-TranP-dlchloroethylene 7,87 175 23050 142,92 ng9) 1,2-Trans-dichloroethylene 10,04 231 29940 185,64 ng
10) Methylene chloride; 4,92 99 16676 173,51 ng11) Methyl chloride 1.51 11 14909 134.23 ngIi?) Methyl bronide 2.13 27 10953 192.94 ng13> Trichlorofluoronethane 7,09 155 37650 177,18 nq11) Dtchlorodifluoronethane 2.52 37 11376 190,43 ng15) Vinyl chloride 2,55 38 1B073 193,31 ng16) 2-Propanone 5,58 116 10B19 12B.63 ng17) 2-Butanone 11,36 265 9832 114.60 ng18) Carbon disulfide 6.47 139 49989 182.87 ng19) *2-Brono-i-chloroprop»ne 17.80 431 78970 250.00 ngSO) Benzene 16,36 394 107793 173,27 ng21) Carbon tetrachlorlde 10.66 247 432 1,91 ng2]) Carbon tetrachloride 12,64 298 6618 29,26 ng21) Carbon tetrachloride 13,03 308 39B66 176,25 ng2?) 1,1,1-trichloroethane 12,64 298 43725 206,53 ng23) 1,1,2-Trichloroethane 16.64 401 2900B 184,50 ng24) 2-Chloroethylvinyl ether 17,72 429 2465 241,35 ng25) 1,2-Dichloropropane 15.01 359 34098 176.12 ng25) 1,2-Dichloropropane 16.64 401 6144 39.10 ng26) trans-l,3-Dichloropropylene 15,32 367 43854 20S.14 ng26) trans-l,3-Dichloropropylene 16,64 401 43189 202,02 ng27) cis-l,3-DichloropropylenB 15,32 367 43854 196,18 ng27) cis-i,3-Dichloropropylene 16,64 401 43189 193.20 ng28) Bronoforn 16.56 399 1230 5.80 ng28) Bronoforn 19,24 468 41747 196,90 ng89) Dichlorsbronofi*thane 13,73 326 S596B 171,85 ng30) Chlorodibrononethane 13,69 325 4112 15,68 ng30) Chlorodibrononethane 16,56 399 46414 176.93 ng31) Trlchloroethylene 15,90 3B2 34363 177,41 ng33) *l,4-Dichlorobgtane 21.60 534 61394 250,00 ng.34) Chlorobenzene 23,89 568 96661 160,49 ng35) l,l,2,H-Tetrachloroethane 21,56 528 39865 180,19 ng36) Ethylhenzen* 25,64 633 137348 164.44 ng36) Ethylbeniene f4f7 2BlS1 707 S2463
Conpound R.T. Scan* Are* Cone Units
37) Tetrachloroethylene 21.56 528 60396 171.27 ng36) Toluene 22,77 559 120921 165.06 ng39) ?-Hexanone 19.66 479 27902 211.60 ng39) 2-Hexanone 21.25 520 15959 121,03 ng40) 4-Methyl-2-pentanone 19,66 479 27902 174,86 ng40) 4-Methyl-2-pentanone 21,35 520 15959 100.03 ng41) Styrene 26.36 703 67764 164,91 nq42) ortho-Xylene 27,38 683 316 .55 ng4?) ortho-Xylene 28,51 707 83183 144,29 ng42) ortho-Xylene 29,13 723 156149 270.86 ng42) ortho-Xylene 29,83 741 206 ,36 ng43) neta-»nd-p*r_-Xylene 26,51 707 63183 146,39 ng43) neta-and-para-Xylane 29,13 723 156149 278,55 ng
* Conpound IK ISTD
1418 020SS
QUANT REPORT
Operator ID. MMS066 Quant Tin*. 840518 14.41Injecved at. 640518 00.14
11 Data File. >C2227nUl Dilution Factor. .40Nanp, E4750VMS1,2200HRS,*CMac i IFB SAMPLE,2640-C9440MS1,VOA FRACTION,5/17/64
ID File, DVFBISTitle, IFB Surrogates, VOA FRACTION, GC/MS DL.IM Calibration, 840518 09.03
Cnnpound R.T, Scan* Area Cone Units_-,p»PWB_«-ll-IBiPt»«i-l«-,t-H-H.'B-P*l«l-'t""*«*«»«™«"««"""™^ •••»••«••« •*•*•*••« -»™-»™^^^W __B»^»"I--.™Wl-t ^Mn-l--««•«
1) IBronochlorociethans B.37 168 16760 250.00 ng2) d4 t,2-Dlchloroethane 11.2B 263 52677 144,82 ng3) d4 1,2-Dichloroethane 11.94 280 103 .29 ng3) *2-Brono-l-chloropropani9 17,80 431 76970 250.00 ng4) d6 Benzene 13,73 326 997 997.00 NO CALIB4) d6 Benzene 16,64 401 650 650,00 NO CALIB5) *l,4-Dlchlorohutane 21,80 534 81394 250.00 ng6) d8 Toluene 22,57 554 139934 85,84 ng7) p-Bronofluorobenzene S7.42 679 69560 82.56 ng
I Conpound is I3TD
1419
x i
8tlK£wM
tn23
£ftww
Filt >DDM!BpK Ab S?'
10000;
88(1 fr;-
6800-
4000:"
2060H
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35X*II TTT4P
i
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ill ' L M' - r - > \
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File >C2227 E<T76eVMSl,2200HRS,»ClFB Sfll1P-E,2640"Bpk Ab 7783
•6090-
f
4000-•
2000-
ti
44X.X
95
60/
47S 82
.k..M.JiL..,y....( .,.l1 - * ' ft'ft '
r
C9440MSJ ,VOfl , an 38213JJ70 Min.
hi................ifln ' lia
•100.•60
__; fl[tW
•_4A•-
•20
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(
t
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i
4'0 68 on ...
Data File, )CS227nUlN.nei E47SQVMS1,22I)OHRS,<»CMlsci IFB SAMPLE, 2640-C9440MS1, VOA FRACTION, 5/17/84
Conpound No.Conpound Nane.Scan Nunber .
31Trichloroethylene382
Retention Tine, 15,90 nin,Area. 34363Concentration. 177.41 no177.41 ng
1.42. f 020885
\ «
§PS1ffits1
nu >DOMBpk Ab 99
100001•
8008-•
6888-•
4800-
-60fr
<VJ
S NBS R»v. E D-ta laci&Mll sp.crra of Hit r4lli~d_U ss'_n99 'i_L 2066.00
77X"
51\ 74
1 ] "°^J. L^ . ji|. r rr -, i i | . -
114S
116
40 68 80 lae 120 140 160 160 20B
20«6»ln.•108
•«8-60
-40
•28
V(•N(-1gni/j
File >C2227 E475evnSl,22e9HRS,<|Cy;'BBpk Ab 17104 - .
16000
12600-
0000
_tnan.•TPPP
0-
77s
51\ 74| | X.
.1 J. .j., . JIJL.. T. ... ,„-,,, r
f
SflnPLE,264e-C944eHSl,YOfl Scan 58823.89 fiin.
•100
114S
132 167 207
... ..S, \ ^4»' ' '6*0' ' 'e'0' ' '100' ' 'i_e' 'Ue' ' '1,0' ' 'i_0' ' '200'
1Jee*e•48
•20
<
Data Fllei >C2227nUlNane. E4750VMSi,2200HRS,*CMisc. IFB SAMPLE,2640-C9440MS1,VOA FRACTION,5/17/84
Conpound No. 31Conpound Nane. ChlorobenzeneScan Nunber. 568Retention Tine, 23,89 nin,Area, 96661Concentration, 160,49 ng
,422
&
1
Library
nit >DBMBpk Ab 99
leeCO-
8000-
600fr
400*;
200fr
fl-
S -"NSrRPvrO.*. BMrful99 . »l
39 66
1 ' ' ' ' ' Ve' ' ' ' ' ' 'e'e' '
1 fp»ctra of tht NBS data $c-039.ee
94iX' ' ' ' '120 ' ' ' ' ' 'lea ' ' ' ' ' 'gee
n 939• in.-loo|60•
-60
0
•20
4JB5
File >C2227 E475eVI1Sl,22eeHRSr«CJFB SRMP-E, 2649-09449(181, VOB Scan 559Bpk Ab 28S»Z *-i-_ 28.7? "in.
20000-
16000-
12000-
8000-
4000-_
44 65
%Ni 1_LjLu.Ji___.._j
QD7O/ 117 131
;100-Jee'.;60
-40
-20
M" " ' ' " Ve" ' ' " Ve" ' ' ' ' tie " ' " Ue " ' " '-00 "
Data File, >C22?7..U1Nane. E4750VM8i,2200HRS,»CMisc., IFB SAMPLE,2640-C9440MS1,VOA FRACTION,5/17/64
Conpound No, 38Conpound Nane. TolueneScan Nunber. 559Retention Tine. 22.77 nin.Area. 120921Concentration, 165.06 nn
,423
8aHt?£
FU« >DBHBpk Ab 99
10000-
6808-
4000
2666;
J
S NBS Rev. C Bat99
39t
i L4V
52
L. j il
ABasrFull sptctra of the NBS data _c_/ 366.80
79
Ir | i ' i f i i i f i i i j i ( i j i i i | i f f j i i i f iaa i.e ise see
n 366«in.-iee
•
^I'ZB
t
File >C22Bpk Ab 80
20000;
12880-
0000-
4000-
0-
27 E4756VMS1 ,2280.224 '
HRS.*CIFB SflMPLE.264e-C9440MSl.VOfl Sea,8 16.36
44 SI JX. il | 91 127 129 173 206
ll .,,..4 y -V / N.40 80 120 160 208
n 394-in.;100
•88
«0
•40
•20
w
Data File, >C2327.,UtNane. E4750VMS1,22QOHRS,*CMisc. IFB SAMPLE,2640-C9440MS1,VOA FRACTION,5/17/84
Conpound No. 20Conpounri Nane, BenzeneScan Nunber. 394Retention Tine, 16.36 nin.Area. 107793Concentration. 173,27 ng
0208831424
Total Ion ChromotogramFile ,'E22
550000-
506008
468990.
460690-
350000-
300000-
250000-
200000-
150000-
163060-
50000-
0-
21 46.0-450.0 anu. -471SMS1 IFB SrtUhLt! _640-C941?HS1TIC
_^ ...... W ....... 2800 ....... 3000 ....... 4008
I
ll
I 6 ' 'l'2 '
1
111 . ,i.1 ' '-'0'' 'zV 'A' ''a'z'' -3.' ' Ve'1 VV
File. >I.',E221, .USNane. E4718MS1Misc. IFB SAMPLE 2640-C9417MS1 B/N/A FRACTION,5/_3/Q4,*E B1L*36
Id Pile. IFHENTitle. IFB P.E,QUANT ID FILE,,,,WWC,,031114Last Calibration. 840522 12.40
' Operator ID, WU99SBDaunt Tine. Q4Q521 12.06
1425 020583
'(i
QIJftNT REPORT
Operator II). WWV72U . Quant Tine. U10W-1 iii.ObInjected at. U40S24 09.24
Data Tile. >E22'_1. .U<5 Dilution Factor. 1.00'me. E471I3MS1
nisei IFB SAMPLE 2640-C9417MG1 B/N/A FRACTION,S/23/B4,*E BTL»36
ID File. IFBGNTitJe. IFB P.E.8UANT ID FILE,,.,WWC..031114Last Calibration. 840522 12.48
Conpound R.T, Scan* Area Cone Units
i) *d4-l,4»Dichlonobenzene 9.36 612 269511 40.00 UG/ML3) Aniline 8,90 561 145S .14 UU/ML.S) 1,3,-Dichlorobenzene 9,40 616 136796 22.01 UG/ML6) 1,4-Dichlorobenzene 9,40 616 136796 21,33 UU/ML7) Benzyl alcohol 10,27 711 55166 7,96 UG/ML8) 1,2-Dichlorobenzene 9,40 616 136796 2S.21 UG/ML9) Phenol 8,69 530 75904 9,37 UG/ML10) 2-Chlorophenoi 0,90 C61 152300 25.19 UU/ML12) 2-Methylphenol 10,26 710 126054 20,15 UG/ML12) 2-Methylphenol 10.6U 756 162765 £26,02 UG/ML13) 4-Methylphenol 10.26 710 126054 12.80 UG/ML13) 4-Methylphenol 10.60 756 162765 16.53 UG/ML15) *d8-Naphthalene 13.00 1Q09 030601 40,00 UG/ML16) N-Nitrosodi-n-propylanine 10,71 759 1S33CI1 18,23 UU/MLIB) Nitrobenzene 12.20 922 31996 2,71 UG/ML21) 1,2,4-Trichlorobenzene 12,90 99& 165182 28.4'i UG/ML26) 2-Nitrophenol 11,96 096 91275 23,70 UG/ML'•7) 2,4-Dinethylphenol 12,21 923 106697 11.92 UG/ML
cB> 2,4-Dichlorophenol 12,66 772 143136 25.32 UG/ML.29) p-Chloro-n-cresol 14,95 1222 158443 19,IB UG/ML31) *diO-Acenaphthalene 10.40 160G 393597 40,00 Uli/ML37) 2,6-Dinitrotoluene 18,48 160EJ 46010 15.08 UG/ML37) 2,6-Dinitrotoluene 19.32 1699 74743 24.411 UG/ML39) Acanaphthene 18,27 161U 354158 23.03 UG/ML41) 2,4-Dinitrotoluane 17.32 1699 74743 12.60 UG/ML48) 2,4,6-Trichlorophsnol 16,20 1359 102393 39.19 UU/ML48) 2,4,6-Trichlorophenol 16.87 1369 9566B 27.27 UG/ML49) 2,4,5-Trichlorophenol 16.20 1359 102393 87,52 UU/ML49) 2,4,5-Trichlorophenol •• 16.29 1369 95668 25,71 UG/ML.51) 4-Nitrophenol 19.12 1678 60B7 5.76 UG/ML54) HidlO-Phenanthrene 23,01 2103 2805BB 40,00 UG/ML59) Di-n-butyl phthalat* 25.27 2349 72229 9.84 UG/ML60) Pentachlorophenol 22,60 2067 22561 34-r3fellG/hL|.f.b61) fcdia-Chryaene , 31.25 3003 27893 40.0$ UG/ML62) Fluoranthene 27.44 2586 78207 18,23 UG/ML64) Pyrene 27,44 8586 7B207 12,41 UG/ML77) *dlO-Phenanthrene 23.01 2103 2B05B8 40.00 UG/ML85) *d!2-Chrysene 31,25 3003 27893 40.00 UG/ML
iK Conpound is 1STD
020590426
1
1)R1
File >E8a_lBpk Ab 33200
3.000
28006
24000-
2000fr.
16000-"
12006-
8000-•
e-
E47IBMS1 1FS JOnPtC a»4a-C9417MXI _/N . c«n 4 IVJf.W min.
(-100
1117B
50
1 6I,'l /,' 1as
l l I I I , .1,60 80 100 120 140
IH
i"11
;?09
i
I50
'-40
;59
•20
-10
-0
Data F'ile. >E2221..U5Nane. E471BMS1Miac. IfB SAMPLE 2640-C9417MS1 B/N/A FRACTION,5/23/84,»E BTL*36
Conpound No. 6Conpound Nane. 1,4-DichlorobenzeneBean Nunber. 61-Retenuon Tine, 9,40 nin,Area. 136796Concentration. 21,33 UG/ML
C.'-"-''"
020S81.,1427 • '
4AM
File >E2221 E4719CIS1Ipk Ab 23104
ecoeo-
2__ae
18000
16000-
14009;"
12666;
19986-
8080;•
6006-•
4000-
2600- 42 *? 51
f^M.45 56
65
6'\.1
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IFB Sfi'HPLE 264e-C9417MSl B/'JM. Scan 538'.L e.69 mm.N C100
.«
1
6B
71 95c.' 70 " 75' ' ' a'o1 ' ' SB' ' ' V0' ' ' ? V "
•98
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•78
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Data File. >E222i..UCNane, E4718MQ1Misc. IFB SAMPLE 2640-C9417M81 B/N/A FRACTIGN,S/23/B4,»ir. BTLI36
Conpound No. 9Conpound Naite. Phenoltic an Nunber , 538Retention Tine. 8.69 nin.Area. 95904Concentration. V.37 UG/ML
1428
I
S i
ft1R)n
File >E222l E4718MS1BpK Ab 35
32060-
28808-
Z4W«t-
20060-•
teeee-•
12088-
9900.
4660-
e-
449
S3
1 ll l'SB'
64
63
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ll
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92
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•70
;60
i58|4>?
•30
0
•10
'•0
Data l-ile.Nanei E4718MC1Misc. IFB SAhf'LE 8640-C9417M01 tl/N/A FRACTION,5/23/04,*(• BTl.43t,
Conpound No. IllConpound Nanei 2-ChlorophenolScan Nunben 561Retention Tinei 0.90 nin.Area i 152301)Concentration. 85,19 UG/ML
1429
X i
\
4Ai
Filt >E232Bpk Ab 393
3-B.&
3200*
28006
24006-'
26066-
1 £AQCk.lovwv-
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. ..iu<i~167
ie'e" ' " 'a'0' ' ' ' id0 '
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Data File, >E222i,,U5Nane. E471BHS1MiSC, IFB SAMPLE 2640-C9417M81 B/N/A FRACTION,S/23/B4,*E BTl,*36
Conpound No, 16Conpound Nane. N-Nitrosodi-n-propylanineScan Nunber. 759Retention Tine. 10.71 nin.Area. 1533B1Concentration. IB.S3 UG/ML
r>jX\j •>
,430 °20594
43ft
File >E2221 E4718MS1 IFBBpk Ab 36676
36000
32606
C800B-
26606-
16666-
12000-
4000-
a-
74
50
..j|,l,,|ii,.,, ................84
t ii r
SflMPLE 2640-C9417MS1 B/N ._<,ifl
1169
ll |
45
,1120 i4e ' iie ' i
r9<>enin,
l?e
[gg
•76
•46
40
•30
•16
Data File, )E2221,.U<;Nane. E471BMS1Misc. IFB SAMF'LE 2640-C9417MS1 B/N/A FRACTION,5/23/84,*E BTI..*36
Conpounil No, 81Conpound Nane. 1,8,4-TrichlorobenzeneScan Nunber. 99EJRetention Tine. 12,90 nin.Area, 165188Concentration. 28,41 UG/ML
431020595
I
File >E22Bpk Rb 34
32660
28000-
24000-
eeeee-
i.aaa-
12000
8000-
4006-
a-
Ii E4?iar121 ————————— I'FB SflMPLE 2-|848
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63
1 X, "ll 'l.l../....'i'1' -VM M I . M ^ M , , , 1<l9
89
^ 1
U£.9417H-i B/N sTI^ 14.?
14/
113 ,
C II
n 12225 nin,•1 80
?8z-40
•78
•*8i50r*e•36'
1:29::ie
Data File, >E8821,iUSNane. t:47iOMSlMisc. IFB SAMPLE 8640-C9417MQ1 B/N/A FRACTION,S/83/B4,»E F.ITL*36
Conpound No. 29Conpound Nane. p-Chloro--M-cresolScan Nunber, 1828Retention Tine, 14.95 Min.Area. 158443Concentration, 19.18 UG/ML
'132 02089
! £|
S i
File >i222l E^lSnSl IFB SflMPLE 2648-C941?MSl B'N s«jtpK flb 74888 10 •'
76000-66006-69009-
55666-5BBBO-
46060-
46606-
35060-
30680-26666-26888-
15600-
10600-5009-
9-
'
6351
" '"'J ''
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7 7 vs f Ts'o" ''"'lee'"1 '"i.e" '' i4e
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i"•5
76
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26
10
) Data File. >_2_21.iU5Nane, E4718M81Misc. 1I7B SAMPLE 2640-C9417MS1 B/N/A FRACTION,5/23/04,*t: BTL*36
Conpound No. 39Conpound Nane, AcenaphtheneScan Nunber: 1618Retention Tine. 18.57 nin.Area. 354158Concentration. 88,03 UG/ML
433 020897
File >E22Bpk flb 17
u«ae-
14000-
,200*
100.0-
80aO-
6606-
4800-
2000-
e-
31 E4716H51 '060 ''
•m
63
S!
||
L 1 ,68
IFB SfiMPLE .64e-C941?nSll6g.'*X_
89
N
'l ,.
90
1 HI86 186 1
fl Scanl?.32
1699ni in.:18B
r80•70i
i*0I8"'•4Q
•30
•23
:Y26 ' lie ' 168 ' iae
Data File. >E2221..USNane. E471BMS1Misc. IFB SAMPLE 264U-C9417MS1 B/N/A FRACTION,5/83/84,tit BTL*36
Conpound No. 41Conpound Nane. 2,4-DinitrotolueneScan Nunber, 1699Retention Tine, 19,32 nin,Ar*i. 74743Concentration. 18.60 UG/ML
020S93434
t
x \
&g4J
File >E2£BPK AD ui4oe1300-
1206
1106-
1660-
960-
600-
760-
600-see-400-
3Q6-
200-
1S8-
0-
.1 E4718MS.131 "2,
44X
IFB SfiMPLE 2M6-C9417MS1 B/N scan19.12139
c
...... ,,,0. ....... .e,0, . . . , .
109
V3'w/
/
" ide" " ' " "i.e" " ' " "
1678• in,166
e
_£)AHJo
•76
i«0J59
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30
:2er18
Data Filei >E83_1,,USNane, E471BMS1Mi&c. IPS SAMPLE 8640-C7417MS1 B/N/A FRACTIBN,5/23/B4,»t: B1L»?,6
Conpound-No. 51Conpound Nane. 4-NitrophenolScan Nunber. 167BRetention Tine. 19,12 nin,Area. 60B7Concentration, 5,76 UG/ML
020899435
,•
File >C3iBpk flb 17
16999-
14606
12066-
1 QflOCL
8606-
6006-.
4006-
2000-
e-
21 £47iansi IFB -AriPLC f528
41XI ?,6 w1 ll 1 1 /' • • ' ' • 's'e' '•''' 'lie' ' ' ' '
i_U--_9417MSl S/N scarV 25.27
223
,.., ,,,,,, ,. ,, ,.,,., |_, ,, .1'M "'" 8.e ' ' '
.949min,
rl«0
;90
r60•70
0
;S9
r*°tae
-80
-16
•«
Data Tile, >_2221,,USNane. E4718M81Misc. IFB SAMPLE 8640-W417MS1 B/N/A FRACTION,5/83/B4,»i: BTLt?.6
Conpound No. 59Conpound Nane. Di-n-butyl phthalateScan Nunber. 2347Retention Tine. 25.27 nin.Area. 78229Concentration. 9,84 UG/ML
020900436
•aM
File >E22IBpk flb 44:
4406-
••eefr
3499-
3288;
8866';
2466:
200*•
160fr
1200-•
QOCk.tfop-
400-
0.
———
>j £471 ens i91
44X
ITT-T-
181 l
f8'0 ' 126
ITB SflOPLf
165\.
36
. _b
1;1»u-i;y'
. . . . . . ' . ' . . . ..N
'171131 ""R/N" c;v,' ',c.t->B n .HIS
.02
' ' ' l40 '-l.
238
,
e ' ' ' '1
u'CO.'min.•180
j e
Jce
•70
J«0
J«o
J40
j.0
<e
•te
.40 '
iii
\iii1i.i
Data File, >E2221..USNane. E4718MS1Misc.. IFB SAMPLE 8640-C9417MS1 H/N/A FRACTION,5/83/84,*!• BTL»36
Conpound No. 60Conpound Nane, PentachlorophenolScan Nunber, 2067Retention Tine, 88.68 nin,Area, 28561Concentration. 31,30 UG/ML
020801** !-.• M37
x \
•\
*w
Filt >tZZBpk Ab 12
13866-
12000-
11000-
ieeee-»cee-8000-
7888-
6869-
B800-
4800-
3006-
2000'
leee-a-
Bf'C4Vl.MSr IPS SflMP-E 2»4"a-C9<t 17115,1 B/N ng, „247 . fe*<
101
44 IiX ee 1
f ',M'1 ' r1 6. ' 8'0 ' 100 ' 126 ' l'4'0 ' 160 ' I.. ' 201
i 2B86» nin.r!00
96
48
70
130
i50•40
iso-29
1'rt)i Data File. >E882i..US
M .' SSl'LE 2640-C9417MC1 B/N/A FRACTION,5/23/84,«E BTL»36
Conpound No. 64Conpound Nane. PyreneCcan Nunber, 2586Retention Tine, 27,44 nin.Area. 70207Concentration, 12.41 UG/ML
1438 020902
•Ji•Ji
*\s«• ——— HNVM
•Jl ——————————— MM.H•Ji •*
•J4
•Jl
1
————— __
, . . . . , . . . .
•
-88.00
•88.00
-34.00
•82.00
•30.00
•28.00
•28.00
•24.00
•22.00 '
•20.00 i
•18.00 j
•18.00
•14.00
•12.00
•10.00
•8.000
•9.000
4.000
•2.000
U.ooo1
| 1439 IA/DCounti
*. 3
Tl Tl
S?P(U U.
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Si 5!M EL <fcQ
S^T,ftffiO QXff^in .. s)CU O ti,r* n2_! ;aS^r« 0,.-•'" .1• JV
\
#020903
REPORT, 3266' " 'CHANNEL i I PESTICIDES FOR IFB
SAMPLE, £4725 MSI INJECTED AT 16i 17)08 ON MAV 22, 1984C.D-V*.
'-, ESTD METHOOl IFBP/! SEQl Cg__tflP SUBSQ/3AMP i I/ 30 BTL, 30
SL-MDTH MV/MIN DELAY M1N-AR BUNCH j( ,500 .100 20,00 2SO NO ;
3UP-UNK DVT ID-LVL REF-RTU HRTM f.DlL-F ISO( NO 0.00 250 .10 1,0 1,00 NO
ACTUAL RUN TIMEl 39.917 MINUTESI
RT ITM FACTOR AREA UG/LKC NAME(
20.80 1. OOOOE- 3 1297 BB ,01322,34 22,34* 3.6186E- 3 2513 BB ,091 DA6HC • ,
( 23.31 23,31* 4.3612E- 3 639466 BB 36.611 DLINDAME23,90 23,90* 6.9859E- 3 3447 BB ,241 *D OHO- ;24,76 1, OOOOE- 3 349 BB .003
( 25,39 25,39* 5.5024E- 3 620908 BB 34.165 *HEPTACHLOR j25,73 1, OOOOE- 3 405 BB ,004 !26,39 26,39* 5.4334E- 3 634301 BB 34,464 »ALDRIN ___ i.
( 27,23 27,47 7.0639E- 3 9880 BB ,698 *HCPTlHCMLUH kHUML»E ;28,09 I. OOOOE- 3 1503 BB ,015 ___ j28,49 23.49* 8.I399E- 3 1368 88 , 1 1 1 tA-ttHDUbULhHH
( 28,87 28,87* 1.5503E-2 693 BB ,107 *OTE~ I29,15 89,15* 9.9252E- 3 375978 BB 37,316 »DIELbRZN |29,49 I, OOOOE- 3 1528 BB ,015 j29,76 29,76* 1.9232E- 2 211969 BB 40,765 tEHBRIH I29,98 29,93* 2.4529E- 2 1065 BB ,261 KB" EHOCSOLFHMfPPCiC'Ii- L30.48 30,46* 3.1126E- 2 1491 BB . ..464 (htHURlH HLUtHVDt \j
( 31,00 31,00* 7.7198E- 2 51372 BB 39', fl'58 «DDT j'32,65 1. OOOOE- 3 5643 BB .056 '33,65 33,72 1.3970E-2 1494 BB ,209 XDIBUTYLCHLOREHDATE i
( " '•TOTAL HREA « 2766694 TOTAL UG/LKC » 225,271
( PROCESSED OATrt FILE I P0292 RAW DATA FILEl R0292
440 020904
Totql Ion ChromotogramFilt >C22
1306069-
1286600-
1100600-
1000668-906600-
660800-
700060-
600800-
568006-
400008-
380006-
200000-
100000-
0-
28 40.0--6E.0 MU. e47..VHS-,_-46HR8Xir_ SBHPLE.S'fi'ffl-CTflOT??188 2efl 300 4B0 60.0 600 798 806 9 0
S> - j. jyyn •j\7L_VLA_MA [_ f~ J\>\ A A. — I\-AA ———————————-i-- j ~ ~ J™ ,_' r-jij "I2V r 2V ' 2. ' ' ' 3. ' ' ' 36
Data File, >C228B,,UiNane. E47SOVMS8,8845HRB,»CMisc, IFB SAMPLE,8640-C9440MS2,VOA FRACTION,5/17/84
Id File. DVFBLBTitle, IFB PURGF.ABLE PRIORITY POLLUTANTS IDFILE, 831107, D, RLLast Calibration. 840517 16.05
Operator ID, MM5066Qaunt Tine, 840518 10,48
.-•a•• V1"
441 020505
QUANT REPORT
Operator IDi MM5066 Quant Tine. B40S1B 10.42Injected at. 840518 00.55
Data File. >C2228..U:l Dilution Factor. t orjNanp. E47SOVMSi»,224SHRS,»CMisc. IFB SAMPLE,2640-C9440MS8,VOA FRACTION,5/17/84
IP File. DVFBLBTil tie. IFB PURGEABLE PRIORITY POLLUTANTS IDFILE, 831107, D, RLLast Calibration* 840517 16iOS
Conpound R.T, Scant Area Cone Units
i) tBromochlnronethane 8.40 190 17083 250,00 nq2) Acroltin 5.64 119 931 SIB.75 ng2) Acralein 5.91 126 182 67.98 nq3) Acrylonitrile 6.26 135 19143 855.13 ng4) 1,2-Djchloroethane 11.42 868 44885 87B.93 nq5) 1,1-Dichloroethane 9.21 811 38961 106,74 ng6) Chloroethane 3.80 56 11688 187,84 ng7) Chloroforn 9,81 211 4121 17.48 ng7) Chloroforn 10.63 249 40745 172,84 ng8) 1,1-Dichlorotthylene 7.85 176 24000 179.31 ng8) 1,1-Dichloroethylene 10.03 832 31523 835.51 ngB) 1,1-Dichloroethylen* 10.61 847 187 .95 ng9) 1,8-Tranfi-dichloroethylene 7.85 176 84000 146,89 nq9) 1,8-Traris-dichloroethylene 10,03 838 31523 192.1Sng
10) MfithyJfne chloride 4,94 101 16568 169,47 ng11) Methyl chloride 1,53 13 15915 140,86ng1?) Methyl hronide 8.11 28 11797 804.29 ng13) Trichlorofluoronethane 7.08 156 29851 183,39 ng14) Diehlorodifluoronethane 2.50 3B 12253 801,64 ngIS) Vinyl chloride 2.54 39 19494 204.98 ng16) 8-Propanone 5.56 117 15105 176,55 ng17) 8-Butanone 11.38 867 17471 200.19ng18) Carbon disulfide 6.46 140 51448 185.08 ng19) *a-Brono-l-chloropro.pane 17.78 438 81353 850.00 ng20) Benzene 16.35 395 112555 175,63 nq21) Carbon tetrachloride 10.68 849 448 1,92 ng81) Carbon Tetrachloride 18,66 300 6681 29,53 ng21) Carbon tetrachloride 13,05 310 43087 184.65 ng82) 1,1,1-trichloroethane 12,66 300 45959 212.76 nq23) 1,1,2-Trichloroethane 16,66 403 30758 189,90 ng24) 2-Chloroethylvinyl ether 17.75 431 2784 864.60 nq85) 1,2-Dichloropropane 15.03 361 35880 178.59 ng25) 1,2-Dichloropropane ' 16.66 403 6660 33,77 ngR6> trans-l,3-Dichloropropylene 15,34 369 48577 193.33 ng86) trani5-l,3-Dichloropropylene 16.66 403 45425 806,86 nq87) clB-l,3-Dlchloropropylene 15.34 369 48577 1B4.B9 ng87) cis-l,3-Dichloropropylene 16.66 403 45485 197.86 ng28) Bronoforn 16.54 400 1330 6.09 ng2B) Bronoforn 19,26 470 44743 204,85 ng ,'89) Dichlorobrononethane 13,71 327 S91B8 176,40 ng ;30) Chlorodibrononethane 13,75 328 5180 19,17nq <.3(1) Chlorodibrononethane 16,54 400 49900 184.65 ng31) Trichloroethylene 15.92 384 36801 181.48ng , ,32) Vinyl acetate 13,36 318 3998 21,51 ng33) )T.l,4-DJchlorobutane 21,76 535 82528 250,01134) Chlorobtnjtn* . . . 23,88 589 97019 158,BE
Conpound R.T. Scant Area Cone Units35) 1,1,2,2-Tetrachloroethane 21,55 529 40851 182,11 ng36) Ethylbeniene 25.66 635 123079 145,33 ng36) Ethylben/ene 88.53 709 45580 53,82 ng37) Tetrachloroethylene 21,55 529 62588 175.04ng38) Toluene 22.75 560 182825 164,55 ng38) Toluene 83,29 574 US .15 ng39) 2-Hexanone 19,69 481 30231 226.11 ng39) 2-H»xanone 81.84 581 19574 146,40 nq40) 4~Methyl-2-pentanone 19,69 481 30831 186,87 ng40) 4-MethyI-2-pentanone 81,84 521 19574 121.00 nq41) Styrene 28.34 704 65878 158,07 ng42) ortho-Xylene 25.66 635 59395 101.61 ng48) ortho-Xylenp 26.75 663 105 .18 ng42) ortho-Xylene 27.64 6B6 159 .27 ng48) ortho-Xylene 88.53 709 72384 183,83 ng48) ortho-Xylene 89.18 724 157679 869,76 ng48) ortho-Xylene 29.85 743 127 ,88 ng43) neta-and-para-Xylene 28.53 709 723B4 187.35 ng43) neta-and-para-Xylene 89.18 724 157679 277.48 ng
* Conpound IT. IRTD
r ..vi
,4<3 °2°907
QUANT REPORT
Operator ID. MMS066 Quant Tine. 810518 14.46Injected at. 840518 00.55
Dat* File. >C2H28..U1 Dilution Factor. ,40N.ine>i E4750VMS8,2845HRS,*CMisc. IFB SAMPLE,2640-C9440MS8,VOA FRACTION,S/17/B4
IK) FiJe, DVFBLSTitle. IFB Surrogates, VOA FRACTION, GC/MS DLast Calibration, 840518 09,03
Conpound R.T. Scan* Area Cone Units
1) IBronochloronethane 8,40 190 19083 250,00 ng2) d4 1,8-Dichloroethane 11,31 265 54168 146,40 ng3) *2-Brono-l-chloropropane 17,78 432 B1353 250,00 ng4) d6 Benzene 16,68 402 560 560,00 NO CALIB5) *l,4-DichJorobutan<s 21,78 535 82528 250,00 ng6) tIB Tolwene 82.60 556 139449 84.37 ng7) p-Bronofluorobenzene 87.45 681 71671 83,92 ng
* Conpound i* ISTD
020903
8a$1t?E1/I
ru« >DONBpk Ab 99
10B00-•
8606-
6000
4600
. 2666--
0-
S NBS R»w. £ Data i.c»Full99
26 6024 / 47 X""x I s,,
In . r. i l l - 1,1 M'l '
a'e ' 40 ' 6
Sffctrt of fht H8S d.ta sc_^ 9i7.ee
96
^
82*X
i L i i , i u r1 e'a '
98
(101
\ t~* ****"\f\ f-r-
i 91?iln.•100
•66
•60
-46*
•20••e
ia'0 ' isa"File >C2228 £4750VHS2,2245HRS,*CIFB SIMPLE, 264B-C9448NS2,VOF) Scan 176Bpk Ab 4104 ^y 7.85 Bin.
400fr
3066-
2660-
IBfW-
43
12*0 ' 4'0
60"Xv
1 1 ll
96\
74f1 ...
96/
116.1 . /
•\ vv
;60
0•r»9L20w
«1 " 'V0' " ' ' a'0 ' ' id0 ' 120"
Data File, >C8228..U1Nane. E4750VMS2,2245HRS,*QMisc, IFB SAMPLE,2640-C9440M88,VOA FRACTION,5/17/84
Conpound No, 8Conpound Nane. 1,1-DichloroethyleneScan Nunber. 176Retention Tine. 7,85 nin.Area. 24000Concentration. 179,31 ng
020S03
1445
8£3ta£J
FiU >DBMBpk Ab 99
1600*
8006-
606*
400*"
200*
A.
S NBS R»tf. E H_t. ....Full ip.crr. of th* NSi d-U a,'» 9B 48M
60!
35 <7X X'Pi | , i rl'i MM'40 6
f
] 80 iae ise
^4974• in,-lev-66
?8-46
;20^
Filt >c'2_2TE47S0VhS2,S245hftS,iCIFB SflHPLE,.6'4e-cS44eriS_,V&A .s an 384Bpk Ab 7994 19 *2 min,
8600-
600B-*
4660-,
208fr.a.
95
6044 y\
8 " V01
47[In. .. 1
1 " '_
f
76 82, , X^ rf| 15 • ' ' ' • • ' 8'0 ''
. 116
LM.C, , , , , , , , ,100 126j i
„
i60;60"7*0
•20^n
Data File. )C282B.<U1Nane. E47SOVMSa,824SHRS,*CMisc. IFP SAMPLE,8640-C9440MS8,VQA FRACTION,5/17/84
Conpound No. 31Conpound Nane, TrichloroethyleneScan Nunber. 3B4Retention Tine. 15.98 nin,Area. 36801Concentration. 181.48 nq
1446 020910
8fl141W£•>Hjg19
Fu« MMBpk At) 99
1800*•
860*P
6000,•
4006-,
200*-0J
S NBS Rev. E Pata BassEi']99 'i_L
77y
61
S> ?i ^^J p ^ >y. .ifcjlvri 1)1
jr
1 spectra of the NBS data scan2066.60
114S
\ '»IL-— **4B ' ' 't'a' ' 'e'e' ' 'iea' ' 'isa' ' 'lie' ' ' o' ' 'lie' ' 'aea1"
2865• in.-100
_,
0••60L•40,•20•t0
ign
FU» >C22Bpk Rb 17
1600*
12098-
6000
6-
28 E4750VMS2,2245HRS,i|CLFB280 li
7?
SI
„ Ji li.p ,J|l
SRMPLE,2640-C9440MS2,VOfl Sea23.88
114/
149 167 207,. \ V X
n 589• in.-100
;80
r40•20
_t40 6B 8*0' ' '100' ' 'l_0' ' '140' ' 'M ' '180' ' '260'
Data File, >C228B..UiNane. E4750VMS2,2245HRS,*QMiBC. IFB SAMPLE,2640-C9440MS2,VOA FRACTION,5/17/84
Conpound No. 34Conpound Nane. ChlorobenzeneScan Nunber. 589Retention Tine. 23.88 nin.Area. 97019Concentration. 158.87 ng
,447 °20911 *
rile >DinBpK Ab 99
10BBB-
866*
666*
466*
266*0.
s"~HITRew. £ lata Sasjful" . ^
39 65
'l ' U)rr14Q 80
1 spectra of the HSS data sc*039.0V
94,/' 1.0 ' 160 ' 200
n 939pin.-IBB
40
0
;40
:2ia^
Fil» >C2228 E475eVI1S2,2245HRS,iJ.IFP SflMPLE,264B-C9~440MS2,VOfl Scan S60Bpk flb 22304 *-iv__ 22.75 din.
2006*
1600*
1200*
800B-
466*
*
44 65N \l i , ,
98
' • • ' • • '4. rrr' (j'0 '' " 120 " ' " '160 " '" 260
;
•;60
serZ0
•ai/j
Data File, )C2228,.U1Nane. E4750VMS2,2845HRS,fCMiBCi IFB SAMPIE,8640-C9440MS2,VOA FRACTION,5/17/84
Conpound No, 38Conpound Nane. TolueneScan Nunber. 560Retention Tine. P8.75 nin,Area. 188825Concentration. 164,55 nq
0209121448
§rt1wUt?a
fii« >D8nBpk Ab 99laeoe-
896*
6000-
400*
266*
S NBS R99
39
1, L' '413'
•v. E D.}
/
1.,. ,1
^B».»Full sp.ctr- of th* NSS d»t. ic»966.00
79
'a ' 1.0 ' 160 ' 200
n 3(6• in.-100^?9•60.r*9JM
U15;Agrew
Fil* >C2228 E47S0Vr1S2,224SHRS,-CIFB Sf)MPLE,2640-C9440MS2,VQfl Scan 395Bpk flb 21112 / 16.35 nip.r ' -i an
2006*
1606*
1266*
800*
400*ftt
93 12 >29 2B<. t... .f \.
•mftn. ^
V, j»
^
•40••2B
la'4'0' ' ' ' ' ' '80' ' ' ' 'li0' ' 160' ' ' ' ' ' 260 '
Data File. >C282BnUiNane. E475DVMS8,2245HRS,tC:Misc. IFB SAMPLE,2640-C9440MS2,VOA FRACTION,5/17/84
Conpound No. 80Conpound Nane. BenzeneScan Nunber. 395Retention Tine, 16,35 nin,Area. 112555Concentration, 175,63 nq
r .->
449 020913
Total Ion ChrornotograrnFilt >E2222 40.0-468.0 __u. ™
Data Filei >E2222. iU3Nane. E4718MS2Misc, IFB SAMPLE 8640-C9417MS2 B/N/A FRACTION, 5/83/1)4, IE HTL*37
Id File.Title, iru P.K. QUANT ID FILE. . . .WWC. .B3U14Last Calibration. 840522 12. 4Q
Operator ID. UU998BCltunt Tine, 840523 19,33
450
f. I lI '\ \
QUANT REPURT
Operator Il>. WW992H ' Quant Tine. U40--3 19.32Injected at. U40S_3 18.46
,"staFile. >E88-_.iU3 Dilution hactor , 1,00ne. E471BMS2
Misc. IFB SAMPLE 2640-C9417MS2 B/N/A FRACTION,5/83/84,« BTL»37
ID File. IFBENTitle. IFB P.E,QUANT ID FILE ....WWC..831114Last Calibration. 840582 18.48
Conpound R.T, Scant Area Cone Units
1) *d4-l,4-Dichlorobenzenn 9.39 616 163699 40.00 UC/ML5) 1,3,-Dichlorobenzene 9,43 621 79195 80.9-U&/ML6) 1,4-Dichlorobenzene 9,43 681 79195 80,33 UG/MLB) 1,2-Dichlorobenzene 9.43 681 79195 81.17 UU/nL9) Phenol 8,71 543 61168 9,84 UU/ML10) 8-Chlorophenoi 8.93 S66 90848 34.74 UU/ML12) 2-Methylphenol 10.30 716 75797 19.95 Uli/ML18) a-Methylphenol 10,71 761 97389 25.63 Uli/ML13) 4-Methylphenol 10.30 716 75797 12.67 UU/ML13) 4-Methyiphenol 10,71 761 97369 16,29 UiS/ML15) *dB-Naphthalene 13.03 1014 499914 40.00 UG/ML16) N-Nitrosorh-n-propylanine 10.75 765 94199 1B.60 UU/ML21) 1,8,4-Trichlorobenzene 18.94 1004 94187 26.90 UU/ML26) 8-Nitrophenol 12,00 902 574B4 24,79 UG/ML87) 8,4-Ihnethylphenol 18,84 988 55914 10,3EI Uli/ML88) 8,4-Dichlorophenol 12,69 97V Q6626 85.46 Uli/MLP9) p-Chloro-n-cresol 14.99 1880 89237 17.94 UG/nL
i )) *dlO-Acenaphthalene 13.51 1618 820616 40.00 UU/ML37) 8,6-Diniirotol.uene 18.51 1618 24971 14.54 UU/ML37) 8,6-Dinitrotoiuene 19,34 1703 37865 82,05 UU/hL39) Acenaphthene 10,60 16812 195500 27,61 UU/ML41) 2,4-lnnitrotoluene IV.34 1703 37865 11.39 UU/ML40) 8,4,6-Trichlorophenol 16,84 1364 58076 89,54 UG/ML40) 8,4,6-Frichlorophenol 16.33 1374 58934 _6,9E UG/rtL.49) 8,4,5-Tnchlorophenol 16.84 1364 50076 27,05 UB/ML49) 8,4,5-Trichlorophenol 16,33 1374 58934 85.38 UU/ML51) 4-Nitrophenoi 19,15 1688 8190 3.711 UU/ML54) DidlU-Phenanthrene 83,04 8107 143439 40.00 UU/nL60) Pentachlorophenol 88.71 8071 10083 EMM^JG/MU61) *di8~Chry»en* 31,87 3006 11414 40. OuUii/ML68) Fluoranthene 87.46 2590 35057 13,40 UG/ML64) Pyrene 27.46 8590 35057 13,59 UU/ML77) *dlO-f'henanthrtne , 23.04 2107 143439 40.00 UU/ML
* Conpound is ISTD
0209151451 «r
File >E32Bpk Ab 19
18000
16066
14000-
12666-
ieee*see*
c,aaa-
4aae-
2000-
e-
22 E4718MS2 IFF iflMPLE 264ii,-C,941?MS2 B/H440 'j
60s
61
IK s1 60
176/
85
llplC, | M , l l . l l . l l l l . . . . . . | . . . . .
11f
I.I. ..............80 100 120 140
&in 621nin.•100
8
1-60
:70<0
;5C
H9
•3B
{0
:>a
4
Data File. )E2228..U3Nane. E4718MSSMisc. IFB SAMf'LE 8640-C9417MU2 B/N/A FRACTION,5/83/84,tE BTL*37
Conpound No. 6Conpound Nane. 1,4-DichlorobenzeneScan Nunber. 621Retention Tine. 9,43 nin,Area. 791915Concentration. 20.33 UG/ML
020918 ! 4452 > •'
\
tiM
?"i"ie"">"_2~222 'E4716MS21 1FS SAMPLE 2646-C9417MS2 B/N Scan 642Bpk flb 14717 \ 8.71 »}n.
i4oee13000
12666
1100*
ieee*9000-
8600-
700*
600*
560*
460*
366*
2666-tee*
e-
66\
42 SE
/ sl 5' / «r,, V,i v45 50 55 66 6E
69UJ
76
71
X95
\\75 8'0 SB 9'0 9
'.99
e;•78
-«e
|?B
'•4*
;30
'9
•16
•e
Data Filei >_22_E, .U3Nane. E471BMS!!Misc. IFB SAMPLE 8640-C9417MS8 B/N/A FUACT10N,5/83/84,»E BTLK37
Conpound No. 9Conpound Nane. PhenolScan Nunber. 548Retention Tine. U.71 nin.Area. tllt2Concentration, 9.134 UG/ML
0209H1453 V
Fil* >-S2.2 E47lflMSi IFB ifiMPBpk flb 26936
26660
16000
16606
1400*
120e*
1000*
606*
6060-
4060-;
260*
*
64N,
63
l,f 1
65 9_X x
75
1, , ,lli. . . . . . . .'se' ' ' '6« V'0' ' ' 's'e' ' ' Ve
LC ._4Cl-.«417MS2 B/'N j jn .«(8V§3 (iiin.r r;100
160„.!.., ,,.„,,..,160 110 123 13(
?e
40
;76
i«o
i60r49•30
:20;16
<1
M
1 Data File. >E228i2,iU3
864Q-C9417HC8 B/N/A FRAt:TlQN,5/83/C4,*E BTL*37
Conpound Nu. 10Conpound Nacie. B-ChlorophenulScan Nunber. 566Retention Tine. B.93 nin,Area. 90IMt)Concentration, 24,74 UG/ML
.'•>*r .**v;
1454 *v
u•Sai5
File >E2222 ?F18flBpk Ab 23'
22999-
26666'
16066-
i see*14606'
•1200*
10000-
8006'',
600*
4006-
266*
*&*
________ LJUQ. -____,.,-,._50
._ 7B IFB SAMPLE 2.4.-.9417MS2 B'N $c<in 766'.
E8
' } , '
i1
i
71X
1 1 1
10. re
136\
V07 113
ll1
e'e ?'e e'e 9'. ia0 tie
/
mm.•103
0
40
•76
46|;50
e
•30
;26
16
^1.6 139
Data File, !E82E8..U3Nane. E471EJMS2hisc,. IFB SAMPLE 264Q-C94i7MSf! B/N/A FRACTION,5/23/84,*E BlLt37 '
Cnnpound No. 16Conpuund Nane. N-Nitrosodl-n-propylaninetic an Nunber, 765Retention Tints. 10,75 nin,Area. 941'/"/Concentrationi 18,60 UG/ML
0209191455 * "''
Data file. >li8228. .U3Nane. E4716MS8Mlsi:. IFB SAMPLE 2640-C9417MS2 B/N/A FRACTION,5/23/134,*E B1L*27
Conpound No, 81Conpound Nane. 1,2,4-TrichlorobenzeneScan Nunber, 1004Retention Tine, 12,94 nin,Area, 94127Concentration, 26,90 UG/ML
"'
02092v
1456
t
uft1
File >E332_ E4718MS2Bpk flb 20632
26000-
16666-
16060-.
1460*
1208*
1668*
800*
6608-
466*
aee*0
9-
1KB SflMPLE 26j(
77X'
51/
63\
, I6.
1 73
,(11. - , . ( - . i ,
8?
S 'i
fr
e'e ' i.e'
C9417MS2 B/N jcan14.99
142/
113
1228min.
•100
•SO
JtA•eg
•Tt)•
J.0J5R
r*0•36
;20
•16
1." ' 120" " ' ' " 140
Data Tile, )L'2282, ,U3Nane. E4718M32E4718M32U'B BAhPLE 8640-C9417MS2 B/N/A FRACTION, 5/83/84, »E BTL»37
Conpound No. 89Conpound Nane. p-C.hloro-n-cresolScan Nunber. 1888Retention Tine. 14.99 nin,Area. 89237Concentration. 17,94 UG/ML
020921
1457
•r iif i
File ,-.2222 E4718MS2 IFB SflMPLE 2640-C941?nS2 B/N .gi,Bpk Rb 41688 ll o
•»oeee-
36889-
32000-
28000-
24eee-
20060-
itaae-
12666-
8600-
4066-
9-
63SI
ft
87 98 '/6/ C • I1,
86 186 128 146
n 16226 nir>,:ioo;r|«0
•?9
i60
i58J46
fse
*e
•fl
Data File, >E2222,.U3Nane. E471BMQ2Misc. IFB SAMPLE 2640-C9417M88 B/N/A FRACTION,S/83/84,*E BTL*','J7
Conpound No, 39Conpound Nane. AcenaphtheneScan Nunber. 1622Retention Tine. 10.60 nin,Area. 195500Concentration, 87.61 UG/ML
020922 j1458 „ ••"• [;.
X \
u•aftw
fil? >E22BpK Ab 09
8006-
7000-
6006-'
600*
468*
3666-;
2B0*
1000-
22 E"4?6tl
(e'e
9MS2 "
63S
1
78
|s'e
IFB SfiMPLE i
99X
1
j"' 100" ••'••• t
646-C9417MS2 B'N ,j;_ar«a
19
_e" " ' "He ' 140
i 1703mir.,•166
41
•ee
•70
I*50
•46
-98
:29HO
Data File, >C2222..U3Nane, E471BMS2Misc. IFB SAMPLE 2640-C9417MS8 B/N/A FRACTION,5/83/84,»E BT1.437
Conpound No. 41Conpound Nane. 2,4-Dinitrotoiuan.Scan Nunber. 1703Retention Tine, 19.34 nin,Area. 37665Concentration. 11,39 UG/ML
020923ao
1459
S ,'
•
1I/I
IT.' >E2222 M/llffif|-Bpk flb 745 "—.
700
650
60S-56*
SB9-
45*
40*
35*30*
2se-280.
156 1106 156-
0J_-..
44
———— —— mr .MPLE 264e-C»41 1*1 2 B'N Jcar
139•— .
____ ——-n —— ar "^ — S51 " ' ' " ' i^e "'••• ig- '" r^-
1682min.•iea
•30
8
•70
*6
i56l_i A 1•4W
•96
-26
r18-e
' Data File i >t2222..U3Nane. E471QMS.Mi sci IFB SAMPLE 2640-C9417MS2 B/N/A FRACTION,5/23/84,*E BTH37
Conpound No. SiConpound Nane. 4'-Nj,trophenolBean Nunber. 16UCRetention Tine. 19.15 nin.Area. 81VOConcentration. 3.70 UG/ML
02092-11460
\
faM
File >E2222 'E1718MS2 " IFB SfiMPLE 2646-C94Ipk Ab 2267
2206-
260*
1890-
1608-
1406-
120*
100*
80*
606-
4O__-^ w>
206-
*
•
165\
44X
1 a'0 ' 1.0 ' i.e
.
17M__ B/N ,t,an-SSjTI
eg
'
2671i«tn,:18B
i"1•ee
•70
•60
;56
-40
30
J-28
r101
' 203 ' 246
Data File. >F.222t!. >U3Nane, C4718MC-Misc. IFB SAMPLE 8640-C9417MS2 B/N/A FRACTION,5/23/84,*E BTL»37
Conpound No. 60Conpound Nane, t'entachlorophenolScan Nunber, 2071Retention Tine, 28.71 nin.Area, 10883Concentration. 89,53 UC/ML
. 0209251461
X i
fw
FiT. >72l?2"'-WB«" '"" IFB SttMHLE 2-4---S4I7I1S2 B/N gj.rJpk Ab 6363 ^-
6600-
B690-
5260-4800-
440*400*
360*320*280*246*200*i.e*IZ0*890-
468-8-
•
10944 /
X 1 183 U/ I
"''" '"''"-'e' "''"Vie"'"' "1 'iAa •-• 'lie" ' lie ' 2
i 2698> min.•100
!*0
'•69
•?0
J.9
Jse"j A^»7
SP«e
0
8
d
Data File. >E2222i,U3Nane, E471BMS2Mi&c, IFB SAMPLE 2640-C941.VMS8 B/N/A FRACTION,S/23/84,»E BTH37
Conpound No. 64Conpound Nane. PyreneScan Nunber. 2590Retention Tine, 27.46 nin,Area. 35057Concentration. 13.59 UG/ML
', •'"
020923462
N "MCggH _ » ( s o j a j c o a i - J a j c o a )M «7. .. .T. ...<?... .1-. . . .1*. . . .H> . . . .T. . . .9. . . .«H. . . .V.
_ > D < S Q ) _ i _ i d ) _ > 0 ) < D Q ) a i Q i _ . « _i n a ) U ) < 8 i n < B i n _ i u ) a > i n a > u ) < - i nN r » < 0 < _ u > i a « < r p > < i > N ( \ i - i
1463
•JimmMM
HUM —
«,
M MJ•Jl
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(______
•88.00
-88.00
84.00
•82.00
•80.00
•28.00
•28.00
•24.00
^
•18.00 |
•18.00
•14.00
•12.00
•10.00
4.000
•fl.OOO
•4.000
•2.000
-0.000
| 1464 1" A/DCounti
Tl Tl
rim
inX TJ° t!n(U *0O fflIN niTl O
* a *•B1^ *B Tl T4J Ii. 5sO 0T^ O *C C, QM a. 5;
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020923. •
\
REPORT; 9267'" 'CHANNEL! 1 PESTICIDES FOR IFB(
SAMPLE) E4725 MS2 INJECTED AT 17i06i27 ON MAY 22, 1984
(•-•* ESTD METHOD! IFBP/t SEfll C2640p' SUBSQ/SAMPi I/ 31 BTLl 31
SL-HDTH MV/MIN DELAY MIN-AR BUNCH( .300 .100 20.00 250 NO
SUP-UNK DVT IO-LVL REF-RTH KRTM «DIL-F ISO( NO 0.00 250 .10 1,0 1,00 NO
ACTUAL RUN TlflEi 39.900 MINUTES
RT !TM FACTOR AREA UG/LKG NAME
2020202121222323242425252626272728Ofl-SB282929292931313233
.35
.80
.94,34.89,33,32,90.61,76,39.64.39.88.22.46.09.49.87.15,49,76,97.00,89.65,63
22.23,23.
29.
26,
27,QQ<0 i
28.29.
29.29,31,
33,
33*32*90*
39*
39*
__£__now
__-,__*f7w87*151
76*97*00*
72
11111346113151I71
1911271t1
. OOOOE-
.OOOOE-, OOOOE-, OOOOE-.OOOOE-.6186E-.3612E-•9859E-, OOOOE-.OOOOE-.5024E-.OOOOE-.4334E-. OOOOE-.OOOOE-
!oOOOE-4 *IO4P->« J Jvyft'*.5503E-.9252E-.OOOOE-.9232E-_BOOI7_>43_7b-.7198E-, OOOOE-.OOOOE-.3974E-
333333333333333
33233222338
6081136363944826
13334299528213648578
15192248084
7732257028
694457204572476QJ* Q7OD
23781504218
5462897134
1173230821
14619966776
BBBB68BBBBBBBBBBBBBBBBBBBBBBBBDOOP
BBOQHU68BBBBBBDOBDBBBBBBBB
,006,011,004,009,006,482
130,629,967.006.015
123.700.008
122.634,007,457,032,025,079,369
149,296,055
172,535oooi <C(JB
178,190,015,010,947
•tTBTnS.ILINDAHE(Kr-tRC1
•HEPTACHLOR
ttALDRIN
WEPTaCHLOR-
jW ETftOSULW
•DIELCiRIN
*ENDRIN4B CUDOCiLILrC*DDT
IN
rN-tWUiP
XDIBUTVLCHLORENDATE
TOTAL AREA • 10833076 TOTAL UG/LKG • 880.783
PROCESSED DATA FILE: P029.' RAU DATA FILE) R0293
1465
x
/I
