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    C.C.JENSEN A/S - Kim Kjr March 2005 1

    Transformer Lecture

    The Transformer and its Maintenance

    CJC V30 Transformer

    Oil Vacuum FiltrationUnit

    &

    Ion Exchange

    Filtration Units

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    Transformer Lecture

    The V30 Vacuum FilterInstalled at Rathkeale Power Station, Ireland

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    Transformer Lecture

    V30 Mo I Rana, Norway

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    Transformer Lecture

    V30 ProductionC.C.JENSEN A/S Svendborg

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    Transformer Lecture

    Hypothesis

    Oil

    O2

    Acids

    H O2

    Paper ageing:

    Water & acids

    acceleratesageing.

    Water is

    formed

    H O2

    Oil reclaiming

    Transformerrefurbishment

    Acids are formedby oxidation

    Source: L. Lundgaard, SINTEF Energiforskning AS

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    Transformer Lecture

    Ageing Factors

    Catalysts:

    Water.

    Copper.

    Oxygen.

    Accelerators:

    Heat.

    Ageing products.

    Dirt.

    Vibrations / overload.

    Electrical stress /voltage waves.

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    Transformer Lecture

    Ageing Processes

    Pyrolysis(heat)

    Hydrolysis(reactions with water)

    Oxidation(reactions with O2)

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    Transformer Lecture

    The Transformer and its MaintenanceWhen oil (CxHy) and O2 react chemically the oil starts to deteriorate (oxidize, age).

    Sludge: Reduces the break-down voltage. Reduces the cooling effect.

    Deteriorates the cellulose. Acts as catalyst for further

    oxidation.

    Acids: Create corrosion

    Acts as catalyst for further oxidation

    Water:

    Deteriorates the cellulose.

    Reduces the break-down voltage.

    Acts as catalyst for furtheroxidation.

    Gasses: Among others CO, CO2, O2, H2,

    CH4 , C2H4, C4H6, C6H8.

    During this reaction the following compounds are formed:

    The aging process dramatically increases the higherthe oil temperature is and if catalysts are present

    (sludge, water, acids, cupper).

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    Transformer Lecture

    Development in Transformer Design

    Source: Grestad Diag. & Rehab. AS - SDMyers.

    0,501979

    0,651977

    0,751975

    1,501960

    2,251945

    4,501930

    9,001915Ltrs of oil / kVaYear

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    Transformer Lecture

    Causes of Failure

    70 % of all failures happens on

    transformers older than 30 years.

    50 % of the failures originates in OLTC andlead-in bushings.

    15-20 % are due to reduced stability; waterand particles in the isolation.

    3-5 % due to far progressed ageing.

    10-15 % due to core mechanically

    weakened by twisting.

    Old constructions may have gas problemsdue to induction loss.

    Source: Grestad Diag. & Rehab. AS Doble og ZTZ

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    Transformer Lecture

    Lowering the Oxygen Concentrationslows Down Oxidation

    Depolymerisation of Cellulose. Accelerated Ageing (130 C)With/ Without P resence of Oxygen

    0

    100

    200

    300

    400

    500

    600

    700

    800

    900

    1000

    1100

    1200

    0 20 40 60 80 100 120 140 160 180 200

    Time [days]

    DP-value

    No OxygenOxygen

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    Transformer Lecture

    Ageing of Cellulose No Oxygen Present

    Ageing under a Nitrogen blanket. These curves are interesting because they showthe effect of no oxygen (same as having an efficient Nitrogen blanket). Pleasenote the relative speed of the ageing btw. 0% and 1% moisture. This change in

    reduction of DP is much more severe than from 1-2% moisture.Source: Roland Agnemo

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    Transformer Lecture

    Oxygen- affecting Transformer Life Length

    0,01

    0,10

    0,30

    1,00

    3,00

    10,00

    30,00

    100,00

    0,03

    Y

    ear

    90 110 130 150 170 190

    O C

    LowOcontent

    2HighOcontent

    2

    Source: Grestad Diag. & Rehab. AS . / SDMyers.

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    Transformer Lecture

    The Oxygen-Free TransformerDEOX - ASEA 1977 (today ABB)

    In the years 1976 & 1977 ASEA published articles about the oxygen-free transformer. It was tested

    on a transformer with rubber membrane and continuous degassed including filtration.

    Specification:

    Oxygen: < 300 l/l.

    Water: < 0,5 %.

    Particles: < 5 m.

    Gas-free oil: 200 N/m2,

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    Transformer Lecture

    Life Expectancy can be Calculated

    from Water Content and Temperature.

    yeare***A

    DPLifeExpected TEnd 273

    13350

    36524

    1000

    11

    Source: L. Lundgaard, SINTEF Energiforskning AS

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    Transformer Lecture

    The Model Facilitiates Analyses of Impactfrom Temperature and Water.

    20oC givesacceleration ofe2 = 7.4.

    Dry to wet givesacceleration ofe3 = 20.

    Wet and 20oC givesacceleration ofe2+3 = 7.4 x 20 = 148.

    Source: L. Lundgaard, SINTEF Energiforskning AS

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    Transformer Lecture

    Acid generation accelerates when water and oxygen arepresent. Acid in turn causes acid-hydrolysis.

    f

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    Transformer Lecture

    Gases

    generatedduring a

    FaultCombustible GasGeneration vs.approximate Oil

    DecompositionTemperature.

    T f L

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    Transformer Lecture

    The Transformer and its Maintenance

    Decomposition of celluloseCarbon dioxideCO2

    CarbonmonoxideCO

    ArcingAcethyleneC2H2

    Partial dischargesHydrogenH2

    EthyleneC2H4

    High oil temp.EthaneC2H6

    MethaneCH4

    Carbon dioxideCO2

    CarbonmonoxideCO

    Normal ageingMethaneCH4

    HydrogenH2

    ReasonGas

    Gas Analysis

    T f L

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    Transformer Lecture

    CO and CO2is produced through paper Ageing

    8% vann 0,5% vann

    CO / CO2:

    1/10 = normal oilageing

    1/1 = very hot

    2/1 = very veryhot

    1/5 = normalageingof paper

    water water

    CO2: More than 2,000 ppm is alarming!

    T f L t

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    Transformer Lecture

    CO / CO2 RatioCO/CO2 Ratio

    0

    0.5

    1

    1.5

    2

    2.5

    0 5 10 15 20 25

    Probability of failure [% ]

    CO/CO2ratio

    CO/CO2 Ratio

    CO/CO2 Ratio curve for

    recorded failures inCanada on conservatortype transformerswithout tap changerscommunicating with themain body.

    Acceptable dissolvedgas-in-oil concentrationlevels in power andinstrument transformersas function of age.

    2,500 transformers.

    Source: Lars Arvidsson.M.Duval, F.Langdeau,P.Gervais,G.Belanger.

    T f L t

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    Transformer Lecture

    Oil Regeneration & Reclaiming

    Will remove some moisture from paper.But with oil in the transformer themoisture transport takes time.

    Will remove some acids from paper.Oil acidity is reported to be stable and lowafter fluidex treatment (how many passes).

    Source: L. Lundgaard, SINTEF Energiforskning AS.

    T f L t

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    Transformer Lecture

    TransformerFeatures:

    Working at 20C 1 ton of paper 10 tons of oil 10 ppm water measured

    in oil

    Calculation:

    10 ppm of water 10 mg/kg 10 g/ton in 10 tons of oil:100 g of water.

    4,6% of 1 ton of paper 46 kg of water.

    100 g of water in oil and 46 kg ofwater in paper 99,8% of water incellulose.

    DegasserFeatures:

    Flow 1000 l/h Removal efficiency 100%

    Calculation:

    We can clean 24 tons in per 24

    hours - we have 10 g per ton, sowe can remove 240 g per 24hours.

    We have totally 46,100 g of waterin the transformer 46,100 g / 240

    g = it takes 192 days to remove allwater in this transformer.

    Transformer Lecture

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    Transformer Lecture

    Water in Oil Water in Cellulose Relation

    Log(Water ppm) = A B/TWhere A=7.09-7.42; B=1567-1670

    855777880100

    64859666390

    48445049180

    35533435870

    25524325560

    18017417950

    12412212240

    84838230

    55565320

    35363310

    2223200

    ShellGriffinCommenT (C)

    Transformer Lecture

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    Transformer Lecture

    The Transformer and its Maintenance

    20 CO

    30 CO

    50 CO

    70 CO

    90 C O

    Water in oil (ppm)

    Waterincellulose(W%)

    10

    8

    6

    4

    2

    00 20 40 60 80

    Oil/Cellulose Humidity Correlation- at different oil temperatures

    Transformer Lecture

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    Transformer Lecture

    Summarizing

    End-of-life of transformer =

    End-of-life of cellulose isolation.

    Heat, water, oxygen and ageingproducts are severely contributing

    to transformer ageing.

    The possibilities of reconditioningtransformers on site are good:

    drying,

    continuous degassing and

    regeneration.

    Transformer Lecture

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    Transformer Lecture

    Conclusion

    By lowering the Oxygenconcentration in the oil, theoxidation (degradation) of thecellulose is reduced.

    By removing water from the

    transformer the remaining lifetime is increased.

    By removing particles the breakdown voltage is increased.

    By reducing acidity levels thetransformer cellulose is betterprotected against ageingacceleration.

    Transformer Lecture

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    Transformer Lecture

    Highly efficientDeaeration

    &

    Drying of

    Power Transformer Oils.

    Vacuum Filtration Unit

    Transformer Lecture

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    Transformer Lecture

    V30 Vacuum Filter - Principle of Operation

    = Oil Inlet= Oil Outlet

    = Gas Outlet

    = Oil Drain

    AB

    C

    D

    A

    B

    C

    D

    Transformer Lecture

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    Transformer Lecture

    Transformer Lecture

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    Transformer Lecture

    V30 Efficiency of Water RemovalExample: 20 ppm in >> 6 ppm out

    The V30 will remove moisture down to 4 ppm given timeenough. The curve above shows the efficiency of full flowand minimum pressure of 2 mBar.

    Transformer Lecture

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    Transformer Lecture

    Water Removalon a very dry Transformer, Stubbekbing

    0

    1

    2

    3

    4

    5

    6

    06-06-03

    07-06-03

    08-06-03

    09-06-03

    10-06-03

    11-06-03

    12-06-03

    13-06-03

    time

    watercontent

    in/out[ppm]

    ppm in

    ppm out

    Transformer Lecture

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    Transformer Lecture

    Oxygen RemovalV30 StubbekbingO2 Concentration vs time.

    Stubbekbing, Denmark. 8000L oil in transformer.

    1307

    5870

    1940

    200580720

    20910

    0

    2000

    4000

    6000

    8000

    10000

    12000

    14000

    16000

    18000

    20000

    22000

    02-03-2003

    22-03-2003

    11-04-2003

    01-05-2003

    21-05-2003

    10-06-2003

    30-06-2003

    20-07-2003

    09-08-2003

    Time

    Oxygenconcentration

    inoil[ppm]

    V30 Stopped

    V30 Started

    V30 Started

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    Transformer Lecture

    0

    2000

    4000

    6000

    8000

    10000

    12000

    14000

    16000

    18000

    20000

    24-0

    7-1998

    01-1

    1-1998

    09-0

    2-1999

    20-0

    5-1999

    28-0

    8-1999

    06-1

    2-1999

    15-0

    3-2000

    23-0

    6-2000

    01-1

    0-2000

    09-0

    1-2001

    19-0

    4-2001

    28-0

    7-2001

    05-1

    1-2001

    13-0

    2-2002

    24-0

    5-2002

    01-0

    9-2002

    10-1

    2-2002

    20-0

    3-2003

    28-0

    6-2003

    06-1

    0-2003

    14-0

    1-2004

    Time

    Gasinoilconcentration[ppm]

    O2 Concentration INLET

    CO2 Concentration INLET

    V30Degasser

    Started

    Oxygen Removalwith V30, Ljusdal

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    Transformer Lecture

    0

    2

    4

    6

    8

    10

    12

    0

    1-12-1996

    3

    0-05-1997

    2

    6-11-1997

    2

    5-05-1998

    2

    1-11-1998

    2

    0-05-1999

    1

    6-11-1999

    1

    4-05-2000

    1

    0-11-2000

    0

    9-05-2001

    0

    5-11-2001

    0

    4-05-2002

    3

    1-10-2002

    2

    9-04-2003

    2

    6-10-2003

    Tid

    Koncentrationsforhold[O2ppm/CO2ppm

    ]

    0

    2000

    4000

    6000

    8000

    10000

    12000

    14000

    16000

    18000

    20000

    22000

    KoncentrationO2[ppm]

    O2/CO2

    O2 Concentration IND

    V30 Started

    Oxygen Content & Carbon Monoxide Generationi.e. Rate of Paper Degradation

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    Transformer Lecture

    V30 Advantages

    Removes OXYGEN from the transformer oil.Down to 200 ppm.

    Removes WATER from the transformer oil.

    Down to 4 ppm.

    Removes PARTICLES from the oil.Down to 0.4 micron.

    With an ion exchange filter ACID is removed.Down to 0.01 mg KOH/g.

    Transformer Lecture

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    Results using a V30 / Ion Exchange Filter

    months0.00500.0500 - 0.1500Tan delta@ 90

    C

    weeks170C95CBubble FormationTemp

    weeks200 2,000 ppm20,000 25,000 ppmOxygen

    months0.01 - 0.02 mg KOH/g0.10 - 0.25 mg KOH/gAcid

    days>75 kV35 - 60 KvBreakdown

    Voltage/2.5mm

    years4 ppm20 - 40 ppmWater in oil

    years0.6 - 1.1%2-7%Water in cellulose

    days11/814/10 - 16/13Particles, ISO

    Timeframe

    After filtrationTypical value for

    aged system

    ISO-standard. The old 5 my and 15 my standard.Source: EFFECT OF PARTICLES ON TRANSFORMER

    DIELECTRIC STRENGTH Working Group 12.17 - CIGRE

    Transformer Lecture

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    CJC V30 Safety Features

    High pressure alarm. In case the vacuum pump fails to keep the pressure below a preset value.

    In case the transformer starts gassing and the gas content of the oilincreases rapidly. Adjustable from 2-250 mBar (down to 500 ppm gas in oilincrease. A Buchholz relay can only detect free gas >70,000ppm H2 ).

    Low level alarm. In case the oil level inside the vacuum chamber falls below a preset value.

    Medium level stops the oil pump, low level stops the system.

    Vacuum pump low vacuum oil level alarm.

    Drip pan oil sensor. In the unlikely case of leakage. The system shuts itself off.

    Foam sensor that shuts vacuum off. Oil in (as foam) cannot leave the system.

    One way valve on vacuum pump. Air/fluids cannot enter only leave the system.

    All alarms on potential free relay.

    Transformer Lecture

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    Shut off valvesoperated bydifferential oil

    pressure monitoringsystem on inlet.

    Non return valve on

    outlet.

    Optional

    CJC V30Safety Features

    Transformer Lecture

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    V30 Vacuum FilterEarly Warning Systems

    1. Gassing alarm on V30 indication of a high thermal fault inthe transformer.

    2. Increased water in oil detection indication of a low thermalfault.

    3. Specific gasses produced high thermal fault moresensitive than gassing level. Direct online gasmeasurement. Hydrogen, Methane, Carbon Monoxide.

    4. Abnormal rise in oil temperature detects large scale

    heating.

    5. ComPosIT GSM datalogger. Alarm via sms. Data on WWW.

    Especially the gas sensor will yield important information and

    a very early warning for a possible fault.

    The CJC V30 Vacuum Filtration Unit equipped with standard as well as optional sensors will operate as an earlywarning system for the transformer. This includes:

    Transformer Lecture

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    Results obtained running a CJC V30

    for 5.5 Months on a Power Transformer.

    Data for the transformer:Distribution transformer

    40 MVA110/10.5 kV

    Oil: TR 25 A

    Oil weight: 20,000 kg

    Cooling system: OFAF

    Conservator: Open/Shared, no tap changer

    Produced by: Electroputere Craiova, 1970

    Filaret T3 Filaret, Bukarest, Romania

    The CJC V30 Vacuum Filter was startedup on 26/2-2004.

    Transformer Lecture

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    MoistureThis curve shows the saturation of the oil with terms of water.

    A curve which corresponds to the relative humidity in air.

    Water activity in oil [absolute water saturation of the oil]

    0.0000.020

    0.040

    0.060

    0.080

    0.100

    0.120

    0.140

    0.160

    0.180

    0.200

    0.220

    0.240

    0.260

    0.280

    0.300

    0.320

    0.340

    2004-02-13

    2004-02-23

    2004-03-04

    2004-03-14

    2004-03-24

    2004-04-03

    2004-04-13

    2004-04-23

    2004-05-03

    2004-05-13

    2004-05-23

    2004-06-02

    2004-06-12

    2004-06-22

    2004-07-02

    2004-07-12

    2004-07-22

    2004-08-01

    2004-08-11

    2004-08-21

    Time

    Wateractivity

    [%/100]

    aw [%/100]

    25 per. Mov. Avg. (aw [%/100])

    When the CJC V30 was first installed (26/2-2004) the saturation ofwater in oil was about 18%, now it has been lowered to below 6%.

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    Water Content in ppm

    0.00

    2.00

    4.00

    6.00

    8.00

    10.00

    12.00

    14.00

    16.00

    18.00

    20.00

    2004-02-

    23

    2004-03-

    04

    2004-03-

    14

    2004-03-

    24

    2004-04-

    03

    2004-04-

    13

    2004-04-

    23

    2004-05-

    03

    2004-05-

    13

    2004-05-

    23

    2004-06-

    02

    2004-06-

    12

    2004-06-

    22

    2004-07-

    02

    2004-07-

    12

    2004-07-

    22

    2004-08-

    01

    2004-08-

    11

    Time

    Waterinoil[ppm]

    ppm calculated

    20 per. Mov. Avg. (ppm calculated)

    From startup values of about 14-18 ppm we have now reached values down to 6ppm. When the unit was started the transformer had been shut down for a few

    days and the temperature was only 4 C. Hence the initial rise in water content.

    This curve shows when the saturation values have been converted into ppm.

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    Water ConcentrationWater content in oil [ppm] and oil temperature [C]

    0.00

    5.00

    10.00

    15.00

    20.00

    25.00

    30.00

    35.00

    40.00

    45.00

    50.00

    2004-07-09

    2004-07-11

    2004-07-13

    2004-07-15

    2004-07-17

    2004-07-19

    2004-07-21

    2004-07-23

    2004-07-25

    2004-07-27

    2004-07-29

    2004-07-31

    2004-08-02

    2004-08-04

    2004-08-06

    2004-08-08

    2004-08-10

    Time

    OilTemperature[C]

    0.00

    2.00

    4.00

    6.00

    8.00

    10.00

    12.00

    14.00

    16.00

    Watercontent[PPM]

    Oil temperature [C]

    ppm calculated

    30 per. Mov. Avg. (ppm calculated)

    30 per. Mov. Avg. (Oil temperature [C])

    Water concentration during the latest month. As can be seen fromthe curve the water content is still falling, but since the values are verylow the water removal rate has somewhat slowed. Note the daily

    fluctuations in oil temperature.

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    Accumulated Removed WaterAccumulated amount of water removed from the transformer insulation [Liters]

    0.0

    0.5

    1.01.5

    2.0

    2.5

    3.0

    3.5

    4.0

    4.5

    5.0

    200

    4-02-23

    200

    4-03-04

    200

    4-03-14

    200

    4-03-24

    200

    4-04-03

    200

    4-04-13

    200

    4-04-23

    200

    4-05-03

    200

    4-05-13

    200

    4-05-23

    200

    4-06-02

    200

    4-06-12

    200

    4-06-22

    200

    4-07-02

    200

    4-07-12

    200

    4-07-22

    200

    4-08-01

    200

    4-08-11

    Time

    Remove

    dWater(accumulated)

    [L]

    Accumulated Removed Water [L]

    This curve is calculated based on the known efficiency of the V30.

    So far about 4.5 Liters of water have been removed.

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    AcidOrganic acidity mg KOH/ g oil. The CJC V30 removes water from the oil. Since some acids

    are w ater so luble som acid is also removed f rom the transfo rmer.

    0.178

    0.118

    0.148

    0.1880.178

    0.2080.2040.21

    0

    0.05

    0.1

    0.15

    0.2

    0.25

    24-07-1998 06-12-1999 19-04-2001 01-09-2002 14-01-2004 28-05-2005

    Date

    TAN

    [mgKOH/g]

    Organic acidity mg KOH/g oil

    Startup of CJC V30

    From the curve it can be seen that the TAN has beenlowered since startup of the CJC V30 vacuum filter.

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    Water Removal on T3Water removal on T3, Filaret, Bucarest, Romania. 20000L oil. 40MVA.

    Water Content in oil at T=36 C.

    0.00

    2.00

    4.00

    6.00

    8.00

    10.00

    12.00

    14.00

    16.00

    2004-02-22

    2004-03-07

    2004-03-21

    2004-04-04

    2004-04-18

    2004-05-02

    2004-05-16

    2004-05-30

    2004-06-13

    2004-06-27

    2004-07-11

    2004-07-25

    2004-08-08

    2004-08-22

    Time

    WaterContent[ppm]

    The water content of the oil is highly

    temperature dependent due to the equilibrium

    with the transformer cellulose. The graph showsthe water content at 36 C. I.e. measurements

    taken each time the oil temperature was exactly

    36 C.

    As can easily be seen from the curve the V30

    has lowered the water content in the oil to

    roughly 6-7 ppm. Variations are caused by daily

    temperature fluctuations. A moisture reading at36 C when the temperature is rising (positive

    gradient, i.e. transformer heating up) tends to

    yield lower moisture contents than a reading

    when the temperature is falling (negative

    gradient, i.e. transformer cooling down).

    Measurements taken at a temperature of 36 C.

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    Water Removal on T3Other parameters that have been improved though only slightly are:

    Density: From 0.887 g/mL at startup to 0.884 g/mL on 2004-05-06(relative density at 20 C).

    Color: From deep low red at startup to low red on 2004-05-06.

    Inflammability: From 142 C at startup to 144 C on 2004-05-06.

    Breakdownvoltage: From 232 kV/cm at startup to 250 kv/cm on 2004-05-06.

    Dissipation factor(tan d) at 90 C [%]: From 16.9 at startup to 12.36 on 2004-05-06.

    Index of refraction: From 1.4904 at startup to 1.4883 on 2004-05-06.

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    Water Removal on T3Calculated data from the transformer degassing and drying monitoring:

    The average oil temperature is 36.4 C

    The CJC V30 has so far removed 4.48 L of water from the cellulosicinsulation

    That corresponds to 27.02 mL/day (7.2% of the total moisture)

    The output water content of the V30 is 3 ppm at the current input of 6ppm

    Based on estimations of the insulation mass, water measurements andwater in oil/water in cellulose equilibrium curves the total amount of water

    at startup was 61.92 L.

    Now 57.4 L remain. At the current rate of drying the CJC V30 will haveremoved 50% of the moisture in 3.1 years. 2.7 remaining.

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    Water Removal on T3The literature states that reducing the moisture by 50% will double the remaining life time ofa transformer.

    If the remaining life time of the transformer at startup was 15 years then removing 7.2 % of

    the moisture, assuming a linearity between water removal and life extension, will extend thelife time by:

    50% reduction = > 15 years life extension7.2% reduction = > 2.25 years life extension (achieved in 166 days)

    If we rate the price per MW at the Danish 1990 level (100,000 DKK per 1MW), then a new

    transformer of 40MW would cost 4,000,000 DKK or roughly 0.5 mio. EUROS.

    Interest levels in Europe are roughly 4%. Thus postponing an investment of 0.5 mio. EUROSby 2.25 years would mean a saving of 4% of 0.5 mio EUROS in 2.25 years.

    This corresponds to 45,000 EUROS.

    Thus by running only 166 days the V30 has savedthe transformer owner 45,000 EUROS.

    Thus the payback time for a V30 is far lower than

    166 days.