Post on 28-Feb-2018
SAFETY DATA SHEET
Product identifier
Product code: P1691Product Name: PICRIC ACID, CRYSTAL, REAGENT
Other means of identification
Synonyms: Picric acid, wetted with a minimum of 30% water to keep it stabilized1,3,5-Trinitrophenol2,4,6-Trinitrofenol [Dutch]2,4,6-Trinitrofenolo [Italian]2,4,6-Trinitrophenol2-Hydroxy-1,3,5-trinitrobenzeneAcide picrique [French]Acido picrico [Italian]Acidum picrinicumCarbazotic acidKyselina pikrova [Czech]MeliniteNitroxanthic acidPhenol trinitratePhenoltrinitratePicralPicronitric acidPikrinezuur [Dutch]Pikrinsaeure [German]Pikrynowy kwas [Polish]Trinitrophenol
CAS #: 88-89-1RTECS # TJ7875000CI#: Not available
Recommended use of the chemical and restrictions on use
Recommended use: Solvent. Explosive. Manufacture of matches. Colored glass. Mordant in textile andleather industries. In electric batteries. Rocket fuels. Dyes.
Uses advised against No information available
Supplier: Spectrum Chemical Mfg. Corp14422 South San Pedro St.Gardena, CA 90248(310) 516-8000
Order Online At: https://www.spectrumchemical.com
Emergency telephone number Chemtrec 1-800-424-9300Contact Person: Martin LaBenz (West Coast)Contact Person: Ibad Tirmiz (East Coast)
Revision Date: 05/29/2015 Revision Number: G1
Product code: P1691 Product name: PICRIC ACID,CRYSTAL, REAGENT
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Preparation Date: 05/29/2015
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Category 3Skin corrosion/irritation Category 2Serious eye damage/eye irritation Category 2ASkin sensitization Category 1Specific target organ toxicity (single exposure) Category 3
Label elements
Hazards not otherwise classified (HNOC)Not Applicable
Other hazardsCan explode on contact if water content is below 10%Do not allow this material to dry outMay form shock-sensitive mixtures on contact with metalsCan violently decompose at elevated temperatures
Hazard statementsToxic if swallowedCauses skin irritationCauses serious eye irritationMay cause an allergic skin reactionMay cause respiratory irritation
Danger
Flammable solids
Product code: P1691 Product name: PICRIC ACID,CRYSTAL, REAGENT
Flammable solids
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Category 1
Precautionary Statements - PreventionWash face, hands and any exposed skin thoroughly after handlingDo not eat, drink or smoke when using this productAvoid breathing dust/fume/gas/mist/vapors/sprayContaminated work clothing should not be allowed out of the workplaceUse only outdoors or in a well-ventilated areaKeep away from heat/sparks/open flames/hot surfaces. — No smokingGround/bond container and receiving equipmentUse explosion-proof electrical/ventilating/lighting/ .? /equipmentWear protective glovesWear eye/face protection
Precautionary Statements - ResponseSpecific treatment (see .? on this label)Specific treatment (see .? on this label)In case of fire: Use CO2, dry chemical, or foam to extinguish.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eyeirritation persists: Get medical advice/attention.IF ON SKIN: Wash with plenty of soap and waterTake off contaminated clothing and wash before reuseIf skin irritation or rash occurs: Get medical advice/attentionIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER ordoctor/physician if you feel unwell.IF SWALLOWED: Immediately call a POISON CENTER or doctor/physicianRinse mouth
Precautionary Statements - StorageStore locked upStore in a well-ventilated place. Keep container tightly closed
Precautionary Statements - DisposalDispose of contents/container to an approved waste disposal plant
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS-No. Weight % Trade SecretPicric Acid
88-89-188-89-1 100 *
4. FIRST AID MEASURES
First aid measuresGeneral Advice: Poison information centers in each State capital city can provide additional
assistance for scheduled poisons (13 1126)
Skin Contact: Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention. If skin irritation persists, call a physician.
Eye Contact: Flush eye with water for 15 minutes. Get medical attention.
Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Get medical attention. WARNING! It may be hazardous to the person providing aid to givemouth-to-mouth resuscitation when the inhaled or ingested material is toxic, infectious orcorrosive.
Ingestion: Toxic if swallowed. Do not induce vomiting without medical advice. Never give anything bymouth to an unconscious person. Immediate medical attention is required. Call a physician orPoison Control Center immediately.
Product name: PICRIC ACID,CRYSTAL, REAGENT
3 / 14Product code: P1691
Most important symptoms and effects, both acute and delayedSymptoms Causes serious eye irritation. Causes a strange visual effect call "yellow-tainted vision". May
cause corneal injury. Causes skin irritation. Yellow discoloration of skin. May cause allergicskin reaction. Possible burns of the skin and eyes. May cause irritation of respiratory tract. Maycause abdominal pain, nausea, vomiting, diarrhea. Possible corrosion and tissue destruction ofthe esophagus and digestive tract. Bright yellow stools. Thirst. Sweating. Bitter taste in mouth.May affect the cardiovascular system. Central nervous system effects. May cause headache.Dizziness. May affect the liver. It may affect the kidneys. It may affect the blood.
Indication of any immediate medical attention and special treatment neededNotes to Physician: Treat symptomatically
Protection of first-aidersFirst-Aid Providers: Avoid exposure to blood or body fluids. Wear gloves and other necessary protective clothing. Dispose ofcontaminated clothing and equipment as bio-hazardous waste
5. FIRE-FIGHTING MEASURES
Extinguishing MediaSuitable Extinguishing Media: Dry chemical. Carbon dioxide (CO2). Water spray mist or
foam.
Unsuitable Extinguishing Media: No information available.
Specific hazards arising from the chemical
Hazardous Combustion Products: Carbon oxides; Nitrogen oxides
Specific hazards: FlammableExplosive in presence of open flames and sparks, of shocks,of heat, of metals, of alkalisDry mixtures of picric acid and aluminum powder are inert,but addition of water causes ignition after a delay dependingupon the quantity addedFlammable solid when exposed to heat or flame.Picric acid and bases form explosives salts. Ammonia andmetals with picric acid give results similar to bases. Contactbetween picric acid and concrete floors leads to theformation of explosion-sensitive salts, such as calciumpicrate. Mixtures with uranium perchlorate are extremelypowerful explosives. It forms unstable salts with concrete,ammonia, and bases. Many of these are heat, friction, orimpact-sensitive. An explosive mixture results when theaqueous solution crystallizes. Keep Picric acid wet withwater. Do not let dry picric acid (crystals) form in container oron the cap threads of container. A severe explosion hazardwhen shocked or exposed to heat. Dried out material mayexplode if exposed to heat, flame, friction or shock; treat asan explosive. Keep material wet with water or treat as anexplosive. Explodes when heated to 300 C
Special Protective Actions for Firefighters
Specific Methods: Flood fire with large quantities of water. Cool contaningvessels with water jet in order to prevent pressure build-up,autoignition or explosion. Continue to cool containers untilwell after fire is out.
Product name: PICRIC ACID,CRYSTAL, REAGENT
4 / 14Product code: P1691
Special Protective Equipment for Firefighters: As in any fire, wear self-contained breathing apparatuspressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Use personalprotective equipment. Avoid contact with skin, eyes and clothing. Do not touch damagedcontainers or spilled material unless wearing appropriate protective clothing. Remove allsources of ignition. Use spark-proof tools and explosion-proof equipment. All equipment usedwhen handling the product must be grounded.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains.Prevent entry into waterways, sewers, basements or confined areas.
Methods and material for containment and cleaning up
Methods for containment Stop leak if you can do it without risk.
Methods for cleaning up Never allow spilled material to dry. Dampen with water without stirring. Neverattempt to sweep up dry material. . Use a spill response pad or pillow that isdampened with water to absorbed the spilled material. Collect the picric acid -containing waste in plastic or glass bottles for disposal. Place the pads/pillows in anappropriate impervious container with water added. Clearly identify the wastecontainer with "Picric Acid Waste" written on it. Wash area with soap and water.Clean contaminated surface thoroughly.
7. HANDLING AND STORAGEPrecautions for safe handling
Technical Measures/Precautions:Provide sufficient air exchange and/or exhaust in work rooms. Remove all sources of ignition. All equipment usedwhen handling the product must be grounded. Keep away from incompatible materials.
Safe Handling Advice:Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Do not breathe vapours/dust. Donot ingest. Avoid shock and friction. Keep away from heat and sources of ignition. Use only explosion-proofequipment. Do not use metal spatulas with removing or weighing out material. Remember, picric acid should neverbe allowed to dry out. Re-hydrate as needed to maintain wet paste. The water content should be at least 10%water by volume (recommended to be 30%). Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Technical Measures/Storage Conditions:Keep containers tightly closed in a cool, well-ventilated place. Keep wetted with a minimum of 30% water. Keepaway from heat and sources of ignition. Store away from incompatible materials. Do not store in metal containers.Store in a segrated and approved area.
Incompatible Materials:Oxidizing agents. Reducing agents. Metals. Alkalis. Copper. Lead. Zinc. Salts. Plaster. Concrete. Ammonia.Albumin. Gelatin. Uranium perchlorate.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parameters
National occupational exposure limits
Product name: PICRIC ACID,CRYSTAL, REAGENT
5 / 14Product code: P1691
United StatesComponents OSHA NIOSH ACGIH AIHA WHEEL
Picric Acid88-89-1
0.1 mg/m3 TWA = 0.1 mg/m3 TWA = 0.1 mg/m3 TWA None
CanadaComponents Alberta British Columbia Ontario Quebec
Picric Acid88-89-1
= 0.1 mg/m3 TWA = 0.1 mg/m3 TWA 0.1 mg/m3 TWA 0.1 mg/m3 TWAEV
Australia and MexicoComponents Australia Mexico
Picric Acid88-89-1
0.1 mg/m3 TWA = 0.1 mg/m3 TWA
Appropriate engineering controls
Engineering measures to reduce exposure: Use process enclosures, local exhaust ventilation, or otherengineering controls to keep airborne levels belowrecommended exposure limits. If user operations generatedust, fume or mist, use ventilation to keep exposure toairborne contaminants below the exposure limit.
Individual protection measures, such as personal protective equipment
Personal Protective Equipment
Eye protection: Goggles or Safety glasses with side-shields
Skin and body protection: Chemical resistant apron. Long sleeved clothing. Gloves.
Respiratory protection: Wear respirator with dust filter. Be sure to use an approved/certified respirator orequivalent.
Hygiene measures: Avoid contact with skin, eyes and clothing. When using, do not eat, drink or smoke.Wash hands before breaks and immediately after handling the product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Product name: PICRIC ACID,CRYSTAL, REAGENT
6 / 14Product code: P1691
9. PHYSICAL AND CHEMICAL PROPERTIES
10. STABILITY AND REACTIVITY
ReactivityHighly reactive with metals, alkalis.It may form shock-sensitive mixtures on contact with metals.Reactive with oxidizing agents, reducing agents.The product may undergo hazardous decomposition, condensation or polymerization, it may react violently with water to emit toxicgases or it may become self-reactive under conditions of shock or increase in temperature or pressure. Incompatible with copper, lead,zinc and other metals, salts, plaster, concrete, ammonia, oxidizing materials, reducing agents, albumin, gelatin, alkaloids(bases). Canreact vigorously with oxidizing materials. Dry mixtures of picric acid and aluminum powder are inert, but addition of water causes ignitionafter a delay depending upon the quantity added. Picric acid and bases form explosive salts. Contact between picric acid and concretefloors leads to the formation of explosion-sensitive salts, such as calcium picrate. Mixtures with uranium perchlorate are extremelypowerful explosives. It forms unstable salts with concrete, ammonia, and bases. Many of these are heat, friction, or impact-sensitive
Boiling point/range(°C/°F):Explodes at 300°C/ 572°F
Decomposition temperature(°C/°F):No information available
Formula:C6H2(NO2)3OH
Bulk density:No information available
Color:Yellow.
Specific gravity:1.763
Vapor pressure @ 20°C (kPa):No information available
Flammability:flammable solid
Density (g/cm3):No information available
Evaporation rate:No information available
Vapor density:7.9
Flash point (°C):150°C
VOC content (g/L):No information available
Physical state:Solid.
Odor threshold (ppm):No information available
Partition coefficient(n-octanol/water):1.44
Flashpoint (°C/°F):150°C/ 302°F
Viscosity:No information available
Odor:Odorless.
Miscibility:No information available
Solubility:Easily soluble in acetone.Soluble in hot water, diethyl ether.Partially soluble in cold water.Soluble in ethanol.Solubility in ethanol: 1 g/12 ml ethanol@ 25 deg. CSolubility in water: 1.27 x 10+4 mg/l @25 C; 1g/78 ml water @ 25 C; 1 g/15 mlboiling water.Solubility in Benzene: 1 g/10 ml @ 25deg. C.Solubility in Chloroform: 1 g/35 ml @ 25deg. C.Solubility in Ether: 1 g/65 ml @ 25 deg.C
Flash Point Tested according to:Closed cup
Lower Explosion Limit (%):No information available
Appearance:Crystals wetted with water, giving aconsistency of wet sand.
Upper Explosion Limit (%):No information available
TasteBitter.
Autoignition Temperature (°C/°F):300°C/ 572°F
pH:No information available
Molecular/Formula weight:229.11
Product code: P1691
Melting point/range(°C/°F):122.5°C/ 252.5°F
Product name: PICRIC ACID,CRYSTAL, REAGENT
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Chemical stabilityStability: Stable under recommended storage conditions. Keep picric acid wet with water. Do not allow
water to evaporate from product. An explosive misture results when the aqueous solutioncrystallizes. Do not let dry picric acid (crystals) form in container or on the cap threads ofcontainer. Dry picric acid is explosive. It can explode of water content is below 10%.
Possibility of Hazardous Reactions: Hazardous polymerization does not occur
Conditions to avoid: Heat. Ignition sources. Incompatible materials. Dry picric acid is explosive.
Incompatible Materials: Oxidizing agents. Reducing agents. Metals. Alkalis. Copper. Lead. Zinc. Salts.Plaster. Concrete. Ammonia. Albumin. Gelatin. Uranium perchlorate.
Hazardous decomposition products: Carbon oxides. Nitrogen oxides (NOx).
Other Information
Corrosivity: Corrodes on contact with metals
Special Remarks on Corrosivity: No information available
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Principal Routes of Exposure:Skin. Eyes. Inhalation. Ingestion.
Acute Toxicity
Component Information
Product Information
LD50/oral/rat =VALUE- Acute Tox Oral = 200mg/kg
LD50/oral/mouse =Value - Acute Tox Oral = No information available
LD50/dermal/rabbitVALUE-Acute Tox Dermal = No information available
LD50/dermal/ratVALUE -Acute Tox Dermal = No information available
LC50/inhalation/rat
Picric Acid - 88-89-1
LD50/dermal/rabbit = No information availableLC50/inhalation/rat = No information available
LD50/oral/mouse = No information available
LC50/inhalation/mouse = No infomation available
LD50/oral/rat = 200 mg/kg Oral LD50 Rat
Product code: P1691
Other LD50 or LC50information = No information available
Product name: PICRIC ACID,CRYSTAL, REAGENT
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LD50/dermal/rat = No information available
VALUE-Vapor = No information availableVALUE-Gas = No information availableVALUE-Dust/Mist = No information available
LC50/Inhalation/mouseVALUE-Vapor = No information availableVALUE - Gas = No information availableVALUE - Dust/Mist = No information available
Symptoms
Skin Contact: Causes severe skin irritation and possible burns. It may dye the skin yellow. It may babsorbed by the skin, particularly through broken skin. If it is absorbed through theskin and it can cause symptoms similar to those of ingestion.
Eye Contact: Causes severe eye irritation and possible burns. May cause corneal injury. Maycause a strange visual effect known as "yellow-tainted vision".
Inhalation Inhalation of mist may cause respiratory tract irritation with coughing and shortnessof breath. In normal use, Picirc acid is a wetted solid or solution that does not readilyform a vapor. This material has a low vapor pressure, so exposure to vapor is notlikely under normal handling conditions..
Ingestion Toxic if swallowed! May cause gastrointestinal tract irritation with bitter taste inmouth, abdominal pain, nausea, vomiting, hypermotility, diarrhea, malaise, thirst,increased sweating, bright yellow stools, yellow discoloration of skin, and possiblecorrosion and permanent tissue destruction of the esophagus and digestive tract.May affect behavior/central nervous system/nervous system (CNS depression,restlessness, anxiety, excitement, hyperactivity, vertigo, weakness, myalgia,headache, stupor, tremor, convulsions, loss of conciousness, coma), cardiovascularsystem (tachypnea, dysrhythmias, elevation in blood pressure, rapid pulse),metabolism (marked increases in metabolism and temperature, electrolyteabnormality), respiration (respiratory depression, hyperpnea, dyspnea),kidneys/urinary system (anuria, oliguria, polyuria, hematuria, albuminuria, renalleisons, hemorrhagic nephritis), liver (acute hepatitis, jaundice). High doses may alsoaffect the blood (destruction of red blood cells (hemolytic anemia), agranulocytosis,leukopnea). May also cause cyanosis (a bluish discoloration of the skin due todeficient oxygenation of the blood).
Aspiration hazard No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chronic Toxicity Skin: Prolonged or repeated skin contact may cause allergic or sensitizationdermatitis. May cause blistering and flaking of the skin, especially around the mouthand sides of nose.Eyes: Prolonged or repeated eye contact may cause cataracts, conjunctivitis.Prolonged or repeated skin and eye contact may also cause yellow staining ofskin/hair and eyes, and "yellow vision."Ingestion: Prolonged or repeated ingestion will cause symptoms similar to that ofacute ingestion.
Sensitization: May cause sensitization by skin contact
Mutagenic Effects: May affect genetic materialMutations in microorganismsExperiments with bacteria and/or yeast have shown mutagenic effects
Product name: PICRIC ACID,CRYSTAL, REAGENT
9 / 14Product code: P1691
Carcinogenic effects: Not considered carcinogenic
Components ACGIH -Carcinogens
IARC NTP OSHA HCS -Carcinogens
Australia - ProhibitedCarcinogenicSubstances
Australia - NotifiableCarcinogenicSubstances
Picric Acid Not listed Not listed Not listed Not listed Not listed Not listed
Reproductive toxicity No data is available
Reproductive Effects: No information availableDevelopmental Effects: No information availableTeratogenic Effects: No information available
Specific Target Organ Toxicity
STOT - single exposure Respiratory Tract.STOT - repeated exposure No information availableTarget Organs: Kidneys. Skin. Blood. Eyes. Liver.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity effects: No data available.
Persistence and degradability: No information available
Bioaccumulative potential: No information available
Mobility: No information available
13. DISPOSAL CONSIDERATIONS
Disposal Methods
Waste from residues / unused products:Waste must be disposed of in accordance with Federal, State and Local regulation.
Contaminated packaging:Empty containers should be taken for local recycling, recovery or waste disposal
Components RCRA - F SeriesWastes
RCRA - K SeriesWastes
RCRA - PSeriesWastes
RCRA - U Series Wastes
Picric Acid None None None None
14. TRANSPORT INFORMATION
DOTUN-No: UN1344Proper Shipping Name: Trinitrophenol, wettedHazard Class: 4.1
Product name: PICRIC ACID,CRYSTAL, REAGENT
10 / 14Product code: P1691
14. TRANSPORT INFORMATIONSubsidiary Risk: No information availablePacking Group: IERG No: 113Marine Pollutant No data availableDOT RQ (lbs): No information available
Symbol(s):
TDG (Canada)UN-No: UN1344Proper Shipping Name: Trinitrophenol, wettedHazard Class: 4.1Subsidiary Risk: No information availablePacking Group: IDescription: No information available
ADR
UN-No: UN1344Proper Shipping Name: Trinitrophenol, wettedHazard Class: 4.1Packing Group: ISubsidiary Risk: No information availableClassification Code: No information availableDescription: No information availableCEFIC Tremcard No: No information available
IMO / IMDGUN-No: UN1344Proper Shipping Name: Trinitrophenol, wettedHazard Class: 4.1Subsidiary Risk: No information availablePacking Group: IDescription: No information availableIMDG Page: No information availableMarine Pollutant No information availableEMS: F-BMFAG: No information availableMaximum Quantity: No information available
RIDUN-No: UN1344Proper Shipping Name: Trinitrophenol, wettedHazard Class: 4.1Subsidiary Risk: No information availablePacking Group: IClassification Code: No information availableDescription: No information available
ICAOUN-No: UN1344Proper Shipping Name: Trinitrophenol, wettedHazard Class: 4.1Subsidiary Risk: No information availablePacking Group: IDescription: No information available
IATA
Product name: PICRIC ACID,CRYSTAL, REAGENT
11 / 14Product code: P1691
14. TRANSPORT INFORMATIONUN-No: UN1344Proper Shipping Name: Trinitrophenol, wettedHazard Class: 4.1Subsidiary Risk: No information availablePacking Group: IERG Code: 3EDescription: No information available
15. REGULATORY INFORMATION
International Inventories
Components U.S. TSCA KOREA KECL Philippines(PICCS)
Japan ENCS CHINA Australia(AICS)
EINECS-No.
Picric Acid Present Present KE-34715
Present Present (3)-823
Present Present Present 201-865-9
U.S. Regulations
California Prop. 65: Safe Drinking Water and Toxic Enforcement Act of 1986.
Chemicals Known to the State of California to Cause Cancer:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)
Chemicals Known to the State of California to Cause Reproductive Toxicity:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)
Components Carcinogen Developmental Toxicity Male ReproductiveToxicity
Female ReproductiveToxicity:
Picric Acid Not Listed Not Listed Not Listed Not Listed
CERCLA/SARA
Components CERCLA - HazardousSubstances and theirReportable Quantities
Section 302 ExtremelyHazardous
Substances and TPQs
Section 302 ExtremelyHazardous
Substances and RQs
Section 313 -Chemical Category
Section 313 - Reportingde minimis
Picric Acid None None None None 1.0 % de minimisconcentration
U.S. TSCA
Components TSCA Section 5(a)2 - Chemicals With SignificantNew Use Rules (SNURS)
TSCA 8(d) -Health and Safety Reporting
Picric Acid Not Applicable Not Applicable
Canada
Pennsylvania RTK: Environmental hazard
Massachusetts RTK: Present
Pennsylvania RTK - Environmental Hazard List Present
New Jersey (EHS) List: 1946 500 lb TPQ
Pennsylvania RTK - Special Hazardous Substances Present
Picric Acid
Minnesota - Hazardous Substance List: Present
New Jersey - Discharge Prevention - List of Hazardous Substances: Present
California Directors List of Hazardous Substances: Present
Product code: P1691 Product name: PICRIC ACID,CRYSTAL, REAGENT
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New Jersey TCPA - EHS: =2500lbTQ
New Jersey RTK Hazardous Substance List: 1946
WHMIS hazard class:D1B Toxic materialsD2B Toxic materialsE Corrosive materialF Dangerously reactive material
Canada Controlled Products Regulation:This product has been classified according to the hazard criteria of the CPR (Controlled Products Regulation) and the MSDS containsall of the information required by the CPR.
Components WHMIS Ingredient Disclosure List -Picric Acid 1 %
Inventory
Components Canada (DSL) Canada (NDSL)Picric Acid Present Not Listed
Components CEPA Schedule I - Toxic Substances CEPA - 2010 Greenhouse Gases Subject to ManditoryReporting
Picric Acid Not listed Not listed
EU Classification
R-phrase(s)R 3 - Extreme risk of explosion by shock, friction, fire or other sources of ignition.R 4 - Forms very sensitive explosive metallic compounds.R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.
S -phrase(s)S28 - After contact with skin, wash immediately with plenty of waterS35 - This material and its container must be disposed of in a safe way.S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).S 1/2 - Keep locked up and out of the reach of children.S36/37 - Wear suitable protective clothing and gloves.
Components Classification Concentration Limits: Safety PhrasesPicric Acid T; R23/24/25
E; R3R4
No information S1/2 S28 S35 S36/37 S45
The product is classified in accordance with Annex VI to Directive 67/548/EEC
Indication of danger:T - ToxicE - Explosive.
Product code: P1691 Product name: PICRIC ACID,CRYSTAL, REAGENT
D1B D2B E F
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Picric Acid
16. OTHER INFORMATION
Preparation Date: 05/29/2015Revision Date: 05/29/2015Prepared by: Sonia Owen
Disclaimer: All chemicals may pose unknown hazards and should be used with caution. ThisSafety Data Sheet (SDS) applies only to the material as packaged. If this product iscombined with other materials, deteriorates, or becomes contaminated, it may posehazards not mentioned in this SDS. The physical properties reported in this SDS areobtained from the literature and do not constitute product specifications. Informationcontained herein does not constitute a warranty, whether expressed or implied, as tothe safety, merchantability or fitness of the goods for a particular purpose. SpectrumChemicals & Laboratory Products, Inc. assumes no responsibility for results obtainedor for incidental or consequential damages, including lost profits, arising from the useof these data. No warranty against infringement of any patent, copyright or trademarkis made or implied. It shall be the user's responsibility to develop proper methods ofhandling and personal protection based on the actual conditions of use. While thisSDS is based on technical data judged to be reliable, Spectrum assumes noresponsibility for the completeness or accuracy of the information contained herein.
End of Safety Data Sheet
Product code: P1691 Product name: PICRIC ACID,CRYSTAL, REAGENT
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Picric acid
2,4,6-trinitrophenol; 1,3,5-TrinitrophenolThe Picric is wetted with a minimum of 30% water to keep itstabilized
Picric Acid
C6H2(NO3)3OH
Not available.
TJ7875000
88-89-1
YY1271, P1691, P1145
Not available.
SPECTRUM LABORATORY PRODUCTS INC.14422 S. SAN PEDRO STREETGARDENA, CA 90248
CALL (310) 516-8000
SPECTRUM LABORATORY PRODUCTS INC.14422 S. SAN PEDRO STREETGARDENA, CA 90248
43 4
Material Safety Data SheetNFPA HMIS Personal Protective Equipment
Section 1. Chemical Product and Company Identification
Common Name/Trade Name
CatalogNumber(s).
CAS#
RTECS
CI#
Manufacturer
Synonym
Chemical Name
Chemical Family
IN CASE OF EMERGENCYCHEMTREC (24hr) 800-424-9300
Chemical Formula
Supplier
See Section 15.
Commercial Name(s) Not available.
TSCA TSCA 8(b) inventory: Picricacid
3
1
1
Health Hazard
Fire Hazard
Reactivity
Page Number: 1
Picric acid: ORAL (LD50): Acute: 200 mg/kg [Rat].
1) Picric acid 88-89-1 0.1 100
Toxicological Dataon Ingredients
Name
Section 2.Composition and Information on Ingredients
Exposure Limits
TWA (mg/m3) STEL (mg/m3) CEIL (mg/m3) % by WeightCAS #
Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Hazardous in case ofskin contact (sensitizer). Slightly hazardous in case of skin contact (permeator), of inhalation. Corrosive toeyes and skin. The amount of tissue damage depends on length of contact. Eye contact can result incorneal damage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dust willproduce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing.Severe over-exposure can produce lung damage, choking, unconsciousness or death. Inflammation of theeye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching,scaling, reddening, or, occasionally, blistering.
Section 3. Hazards Identification
Potential Acute HealthEffects
Continued on Next Page
Picric acid Page Number: 2
Slightly hazardous in case of skin contact (sensitizer).CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available.The substance may be toxic to kidneys, liver, skin, eyes.Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposureof the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skindestruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation orlung damage. Repeated exposure to a highly toxic material may produce general deterioration of health byan accumulation in one or many human organs.
Potential Chronic HealthEffects
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything bymouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medicalattention immediately.
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of waterfor at least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removingcontaminated clothing and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse.Thoroughly clean shoes before reuse. Get medical attention immediately.
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seekimmediate medical attention.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Get medical attention immediately.
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt orwaistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouthresuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouthresuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.
Not available.
Section 4. First Aid Measures
Eye Contact
Skin Contact
Serious Skin Contact
Inhalation
Serious Inhalation
Ingestion
Serious Ingestion
300°C (572°F)
Flammable.
These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
CLOSED CUP: 150°C (302°F).
Not available.
Explosive. Flammable solid.SMALL FIRE: Use DRY chemical powder.LARGE FIRE: Use water spray or fog. Cool containing vessels with water jet in order to prevent pressurebuild-up, autoignition or explosion. Do not fight fire. Evacuate surrounding areas.
Slightly flammable to flammable in presence of open flames and sparks, of heat.
Dry mixtures of picric acid and aluminum powder are inert, but addition of water causes ignition after a delaydepending upon the quantity added.Flammable solid when exposed to heat or flame.
Explosive in presence of open flames and sparks, of shocks, of heat, of metals, of alkalis.
Section 5. Fire and Explosion Data
Flammability of the Product
Auto-Ignition Temperature
Flash Points
Flammable Limits
Products of Combustion
Fire Hazards in Presence ofVarious Substances
Explosion Hazards inPresence of VariousSubstances
Fire Fighting Mediaand Instructions
Special Remarks onFire Hazards
Continued on Next Page
Picric acid Page Number: 3
Picric acid and bases form explosive salts. Ammonia and metals with picric acid give results similar tobases.Contact between picric acid and concrete floors leads to the formation of explosion-sensitive salts, such ascalcium picrate.Mixtures with uranium perchlorate are extremely powerful explosives.It forms unstable salts with concrete, ammonia, and bases. Many of these are heat, friction, orimpact-sensitive.An explosive mixture results when the aqueous solution crystallizes. Keep Picric acid wet with water. Donot let dry picric acid (crystals) form in container or on the cap threads of container.A severe explosion hazard when shocked or exposed to heat. Dried out material may explode if exposed toheat, flame, friction or shock; treat as an explosive. Keep material wet with water or treat as an explosive.Explodes when heated to 300 C.
Special Remarks on ExplosionHazards
Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Explosive. Explosive, class 1.4. Flammable solid. Corrosive solid. Poisonous solid.Stop leak if without risk. Do not touch damaged container or spilled material. Do not clean-up or disposeexcept under supervision of a specialist. Do not operate radio transmitters within 100 m of an electricdetonator. Do not get water inside container. Do not touch spilled material. Use water spray curtain todivert vapor drift. Use water spray to reduce vapors. Prevent entry into sewers, basements or confinedareas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Be careful that theproduct is not present at a concentration level above TLV. Check TLV on the MSDS and with localauthorities.
Section 6. Accidental Release Measures
Small Spill
Large Spill
Store in a segregated, approved and labeled area away from acute fire hazards and powerful oxidizingmaterials. Isolate from Organic materials. Do not store in metal containers. Keep container in a cool,well-ventilated area. Do not allow this material to dry out. Keep Picric acid wetted with a minimum of 30%water. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition(spark or flame).
Do not allow this material to dry out. Do not let dry picric acid (crystals) form in container or on the capthreads of container. Keep away from heat. Keep away from sources of ignition. Keep away from directsunlight or strong incandescent light. Ground all equipment containing material. Empty containers maycontain hazardous residue and pose a fire risk. Do not ingest. Do not breathe dust. Take precautionarymeasures against electrostatic discharges. Avoid shock and friction. In case of insufficient ventilation, wearsuitable respiratory equipment. If ingested, seek medical advice immediately and show the container or thelabel. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducingagents, metals, alkalis.
Section 7. Handling and Storage
Precautions
Storage
Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use processenclosures, local exhaust ventilation, or other engineering controls to keep airborne levels belowrecommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keepexposure to airborne contaminants below the exposure limit.
Splash goggles. Synthetic apron. Mist and dust respirator. Be sure to use an approved/certified respiratoror equivalent. Gloves (impervious).
Splash goggles. Full suit. Mist and dust respirator. Boots. Gloves. A self contained breathing apparatusshould be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient;consult a specialist BEFORE handling this product.
TWA: 0.1 (mg/m3) from OSHA (PEL) [United States]TWA: 0.1 (mg/m3) from ACGIH (TLV) [United States]TWA: 0.1 STEL: 0.3 (mg/m3) from NIOSH [United States]TWA: 0.1 STEL: 0.3 (mg/m3) [United Kingdom (UK)]
Consult local authorities for acceptable exposure limits.
Section 8. Exposure Controls/Personal Protection
Engineering Controls
Personal Protection
Personal Protection in Case ofa Large Spill
Exposure Limits
Continued on Next Page
Picric acid Page Number: 4
Not available.
Solid. (Crystals solid.)
Not available.
Not available.
122.5°C (252.5°F)
1.763 (Water = 1)
7.9 (Air = 1)
Not applicable.
The product is equally soluble in oil and water; log(oil/water) = -0.02
Not available.
See solubility in water, diethyl ether, acetone.
Easily soluble in acetone.Soluble in hot water, diethyl ether.Partially soluble in cold water.Soluble in ethanol.Solubility in ethanol: 1 g/12 ml ethanol @ 25 deg. CSolubility in water: 1.27 x 10+4 mg/l @ 25 C; 1g/78 ml water @ 25 C; 1 g/15 ml boiling water.Solubility in Benzene: 1 g/10 ml @ 25 deg. C.Solubility in Chloroform: 1 g/35 ml @ 25 deg. C.Solubility in Ether: 1 g/65 ml @ 25 deg. C
Not available.
Not available.
229.11 g/mole
Odorless.
Bitter.
Yellow.
Section 9. Physical and Chemical Properties
Physical state and appearance Odor
Taste
Color
Molecular Weight
pH (1% soln/water)
Boiling Point
Melting Point
Critical Temperature
Specific Gravity
Vapor Pressure
Vapor Density
Volatility
Odor Threshold
Water/Oil Dist. Coeff.
Ionicity (in Water)
Dispersion Properties
Solubility
The product is stable.
Non-corrosive in presence of glass.
Highly reactive with metals, alkalis.Reactive with oxidizing agents, reducing agents.The product may undergo hazardous decomposition, condensation or polymerization, it may react violentlywith water to emit toxic gases or it may become self-reactive under conditions of shock or increase intemperature or pressure.
Incompatible with copper, lead, zinc and other metals, salts, plaster, concrete, ammonia, oxidizing materials,reducing agents, albumin, gelatin, alkaloids(bases).Can react vigorously with oxidizing materials.Dry mixtures of picric acid and aluminum powder are inert, but addition of water causes ignition after a delaydepending upon the quantity added.Picric acid and bases form explosive salts.Contact between picric acid and concrete floors leads to the formation of explosion-sensitive salts, such ascalcium picrate.Mixtures with uranium perchlorate are extremely powerful explosives.It forms unstable salts with concrete, ammonia, and bases. Many of these are heat, friction, orimpact-sensitive.
Not available.
Incompatible materials, High temperatures, mechanical shock, ignition sources. Keep Picric acid wet withwater. Do not allow water to evaporate from product. An explosive mixture results when the aqueoussolution crystallizes. Do not let dry picric acid (crystals) form in container or on the cap threads of container.Dry picric acid is explosive. It can explode on impact if water content is below 10%. May formshock-sensitive mixtures on contact with metals.
Section 10. Stability and Reactivity Data
Stability
Instability Temperature
Conditions of Instability
Incompatibility with varioussubstances
Corrosivity
Special Remarks onReactivity
Continued on Next Page
Picric acid Page Number: 5
Corrodes metalsSpecial Remarks onCorrosivity
Polymerization Will not occur.
Absorbed through skin. Eye contact. Inhalation. Ingestion.
Acute oral toxicity (LD50): 200 mg/kg [Rat].
Very hazardous in case of skin contact (irritant), of ingestion.Hazardous in case of skin contact (sensitizer), of inhalation.Slightly hazardous in case of skin contact (permeator).
MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.May cause damage to the following organs: kidneys, liver, skin, eyes.
Not available.
Acute Potential Health Effects:Skin: Causes severe skin irritation and possible burns. It may dye the skin yellow. It may be absorbed bythe skin, particularly through broken skin. If it is absorbed through the skin and it can cause symptomssimilar to those of ingestion.Eyes: Causes severe eye irritation and possible burns. May result in corneal injury. May cause a strangevisual effect known as "yellow-tainted vision."Inhalation: Inhalation of mist may cause respiratory tract irritation with coughing and shortness of breath. Innormal use, Picirc acid is a wetted solid or solution that does not readily form a vapor. This material has alow vapor pressure, so exposure to vapor is not likely under normal handling conditions.Ingestion: Harmful if swallowed! May cause gastrointestinal tract irritation with bitter taste in mouth,abdominal pain, nausea, vomiting, hypermotility, diarrhea, malaise, thirst, increased sweating, bright yellowstools, yellow discoloration of skin, and possible corrosion and permanent tissue destruction of theesophagus and digestive tract. May affect behavior/central nervous system/nervous system (CNSdepression, restlessness, anxiety, excitement, hyperactivity, vertigo, weakness, myalgia, headache, stupor,tremor, convulsions, loss of conciousness, coma), cardiovascular system (tachypnea, dysrhythmias,elevation in blood pressure, rapid pulse), metabolism (marked increases in metabolism and temperature,electrolyte abnormality), respiration (respiratory depression, hyperpnea, dyspnea), kidneys/urinary system(anuria, oliguria, polyuria, hematuria, albuminuria, renal leisons, hemorrhagic nephritis), liver (acutehepatitis, jaundice). High doses may also affect the blood (destruction of red blood cells (hemolytic anemia),agranulocytosis, leukopnea). May also cause cyanosis (a bluish discoloration of the skin due to deficientoxygenation of the blood).Chronic Potential Health Effects:Skin: Prolonged or repeated skin contact may cause allergic or sensitization dermatitis. May causeblistering and flaking of the skin, especially around the mouth and sides of nose.Eyes: Prolonged or repeated eye contact may cause cataracts, conjunctivitis.Prolonged or repeated skin and eye contact may also cause yellow staining of skin/hair and eyes, and"yellow vision."Ingestion: Prolonged or repeated ingestion will cause symptoms similar to that of acute ingestion.
May affect genetic material (mutagenic)
Section 11. Toxicological Information
Routes of Entry
Toxicity to Animals
Chronic Effects on Humans
Other Toxic Effects onHumans
Special Remarks onToxicity to Animals
Special Remarks onChronic Effects on Humans
Special Remarks on otherToxic Effects on Humans
Not available.
Not available.
Possibly hazardous short/long term degradation products are to be expected.
The products of degradation are less toxic than the product itself.
Not available.
Section 12. Ecological Information
Ecotoxicity
BOD5 and COD
Products of Biodegradation
Toxicity of the Productsof Biodegradation
Special Remarks on theProducts of Biodegradation
Continued on Next Page
Picric acid Page Number: 6
Section 13. Disposal Considerations
Waste Disposal Waste must be disposed of in accordance with federal, state and local environmentalcontrol regulations.
DOT Classification CLASS 4.1: Flammable solid.
Not available.
UNNA: 1344 : Trinitrophenol, wetted with not less than 30% water, by mass PG: I
Section 14. Transport Information
Identification
DOT (Pictograms)
Special Provisions forTransport
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECSNo. 201-865-9).Canada: Listed on Canadian Domestic Substance List (DSL).China: Listed on National Inventory.Japan: Listed on National Inventory (ENCS).Korea: Listed on National Inventory (KECI).Philippines: Listed on National Inventory (PICCS).Australia: Listed on AICS.
44
3
3
1
1
CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC).CLASS D-2B: Material causing other toxic effects (TOXIC).CLASS E: Corrosive solid.CLASS F: Dangerously reactive material.
R3- Extreme risk of explosion byshock, friction, fire or other sourcesof ignition.R4- Forms very sensitive explosivemetallic compounds.R23/24/25- Toxic by inhalation, incontact with skin and if swallowed.
Section 15. Other Regulatory Information and Pictograms
Other Regulations
Other Classifications WHMIS (Canada)
DSCL (EEC)
HMIS (U.S.A.) Health Hazard
Fire Hazard
Reactivity
National Fire ProtectionAssociation (U.S.A.)
Health
Flammability
Reactivity
Federal and StateRegulations
Rhode Island RTK hazardous substances: Picric acidPennsylvania RTK: Picric acidMinnesota: Picric acidMassachusetts RTK: Picric acidMassachusetts spill list: Picric acidNew Jersey: Picric acidNew Jersey spill list: Picric acidCalifornia Director's List of Hazardous Substances: Picric acidTSCA 8(b) inventory: Picric acidSARA 313 toxic chemical notification and release reporting: Picric acid
CaliforniaProposition 65Warnings
California prop. 65: This product contains the following ingredients for which the State of California hasfound to cause cancer which would require a warning under the statute: No products were found.
California prop. 65: This product contains the following ingredients for which the State of California hasfound to cause birth defects which would require a warning under the statute: No products were found.
S28- After contact with skin, washimmediately with plenty of water.S35- This material and its container must bedisposed of in a safe way.S36/37- Wear suitable protective clothingand gloves.S45- In case of accident or if you feel unwell,seek medical advice immediately (show thelabel where possible).
Continued on Next Page
Picric acid Page Number: 7
jPersonal Protection Specific hazard
WHMIS (Canada)(Pictograms)
DSCL (Europe)(Pictograms)
TDG (Canada)(Pictograms)
ADR (Europe)(Pictograms)
Protective Equipment
Mist and dust respirator. Be sure to usean approved/certified respirator orequivalent. Wear appropriate respiratorwhen ventilation is inadequate.
Synthetic apron.
Splash goggles.
Gloves.
Major Uses: In synthesis of dyes; rocket fuel; sensitization of photographic emulsions; explosives; matches
Not available.
CALL (310) 516-8000
Notice to Reader
Verified by Sonia Owen.
Printed 8/26/2011.
Validated by Sonia Owen on 8/26/2011.
Other SpecialConsiderations
References
Section 16. Other Information
MSDS Code P3850
Continued on Next Page
Picric acid Page Number: 8
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product iscombined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop propermethods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.