Post on 20-Dec-2021
8 May 2014 By VPTS, PTTPM
HDPE
LLDPE
LDPE
Polyethylene Products
High pressure Tubular
Process
LyondellBasell Technology
Capacity 300,000 MTA
Gas Phase Process
Univation Technology
Capacity 400,000 MTA
Slurry Process
Mitsui Technology
Capacity 850,000 MTA
8 May 2014 By VPTS, PTTPM
HDPE Process Technology
Capacity : 850,000 MTA Catalyst : Zigler-Natta Comonomer : Propylene, Butene
InnoPlus HDPE : CX -Slurry Polymerization process by Mitsui Technology
Advantages :
• WIDE PRODUCT RANGE
• QUALITY UNIFORMITY
• Excellent products Quality
Film : Film impact strength , Tear Strength
Monofilament : High tenacity and processability
Blow molding : Stiffness, Environmental stress
cracking resistance (ESCR) • LOW ASH CONTENT
• LOW PRESS POLYMERIZATION
8 May 2014 By VPTS, PTTPM
InnoPlus LLDPE : Gas Phase Unipol process by Univation Technology
Advantages : • Broadest range of densities and melt indexes (MFI)
with both narrow and broad molecular weight distributions of product capabilities.
• Tougher, clearer, better-performing polyethylene resins especially Film Application. (Narrow MWD)
Capacity : 400,000 MTA Catalyst : Ziegler Natta, Metallocene Comonomer : Butene (C4), Hexene (C6)
LLDPE Process Technology
8 May 2014 By VPTS, PTTPM
LLDPE Classification
1. Catalyst types :
2. Co-monomer :
- C4 - Butene
- C6 - Hexene
- C8 - Octene
Co-monomer
Ziegler-Natta Metallocene
Introduction for LLDPE
8 May 2014 By VPTS, PTTPM
LDPE Process Technology
Capacity : 300,000 MTA
InnoPlus LDPE : LyondellBasell, Lupotech TS (Tubular Process)
Advantages :
• Provide good film surfaces and good optical film properties
• Products very low gel level
• High purity
8 May 2014 By VPTS, PTTPM
>>> InnoPlus HDPE Nomenclature
• General Structure HD 7000 F
Application
MFR range Article Application Article Application
F Film H Thermoform
J Injection JP, C Cap (Pass Organoleptic test)
B Blow molding
S Monofilament
Internal Code
Grade Name
Additive Package
8 May 2014 By VPTS, PTTPM
Example : InnoPlus LLDPE
C4 comonomer
- LL8420A
- LL7410D/D1/ D2
C6 comonomer
-LL9640U / UP
- LL9641U / UP
C6 comonomer/ metallocene
-LL7910A
- LL7810A -LL7835A
LL7410D
Polymer Type : LL = LLDPE
Grade Name
Application :
7 = Film, 8 = Injection, 9 = Rotational Molding
6 = wire & cable
Additive Package :
A = None Slip & Antiblock
D = With High Slip & Antiblock
D1 = With Low Slip & Antiblock
D2 = Very High Slip & Antiblock
G1 = Low gel with Low Slip & Antiblock
U = UV Stabilizer
UP = Power with UV stabilizer
Comonomer & Catalyst :
4 = C4-ZN, 6 = C6-ZN, 9,8 = C6-Metallocene
Melt Index :
MI for Injection
MI x 10 for film & Roto
>>> InnoPlus LLDPE Nomenclature
8 May 2014 By VPTS, PTTPM
InnoPlus LD2426K Melt Flow Rate :
D = 0.2-0.35
F = 0.6-0.9
H = 1.7-2.2
K = 3.4-4.6
T = 33-39
Density , eg. 0.924
Additive Package :
0 = None Slip & Antiblock
6 = With Slip & Antiblock
Internal code
Polymer Type : LD = LDPE
>>> InnoPlus LDPE Nomenclature
Grade Name
8 May 2014 By VPTS, PTTPM
Basic Properties Background
1. Melt Flow Rate (MFR) is the output rate (flow) in grams that occurs in 10 and a load of total mass of 2.16 kg at a temperature of 190°C (some use different weights and some even different “Load” @ 5 or 21.6 kg).
Key Basic Properties of InnoPlus Products
Low Molecular Weight High MFR
High Molecular Weight Low MFR
“MFR” refer to “Molecular weight” which affects on: 1. Properties 2. Melt Processability
8 May 2014 By VPTS, PTTPM
Basic Properties Background
Key Basic Properties of InnoPlus Products
2. Density is the mass per unit volume of plastic . Density is depend on “molecular chain orientation”
“High density - high melting point - high Stiffness - high strength.
“Low density” - high impact - high ESCR - Soft - Clarity
8 May 2014 By VPTS, PTTPM
“By Application”
- Film
- Injection & Masterbatch Carrier
- Blow Molding & Tube
- Monofilament
- Wire & Cable
- Foam & Bubble sheet
8 May 2014 By VPTS, PTTPM
“By Application”
- Film
- Injection & Masterbatch Carrier
- Blow Molding & Tube
- Monofilament
- Wire & Cable
- Foam & Bubble sheet
8 May 2014 By VPTS, PTTPM
“HDPE” Film Application
• Industrial film Industrial bag Liner film Plastic sheet
• General purpose film Shopping bag Disposal waste bag Re-sealable bag Bag-on-roll Industrial film
• Thin film Shopping bag Disposal waste bag Re-sealable bag Bag-on-roll Plastic glove
HDPE HD6000F HD7000F HD8000F
MFR 190, 2.16Kg 0.16 0.04 0.03
Density 0.956 0.956 0.950
Application Thin film General purpose
film
Wide film,
Industrial film
8 May 2014 By VPTS, PTTPM
LLDPE Grade LL7410A LL7410D LL7410D1 LL7410G1 LL7410D2 LL7420D LL7420D1 LL7810A*
MFR 190, 2.16Kg 1 1 1 1 1 2 2 1
Density 0.918 0.921 0.921 0.921 0.921 0.921 0.921 0.918
Slip/AB No High Low Low Very High High Low No
Remark Very low gel
mLL- High performance
“LLDPE” Film Application
*HVP Product
Packaging Film
Agricultural Film Frozen Food Film
Ice Bag
8 May 2014 By VPTS, PTTPM
LLDPE Grade LL7420A LL7428A LL7910A* LL7835A*
MFR 190, 2.16Kg 2 2.8 1 3.5
Density 0.918 0.921 0.918 0.920
Slip / AB No No No No
Remark mLL- Easy Processing
mLL- High performance
Stretch Wrap Film : Machine Wrap & Hand wrap
“LLDPE” Film Application
*HVP Product
8 May 2014 By VPTS, PTTPM
Blown Film : Air quench Blown Film : Water quench
Item Air quench Water quench
Antiblock/Slip content Low High
Recommend grade
LLDPE with D1 Series and G1
e.g. InnoPlus LL7410D1, LL7420D1, LL7410G1
LLDPE with D/ D2 Series e.g.
InnoPlus LL7410D, LL7410D2, LL7420D
Recommended Grade by Process
“LLDPE” Film Application
8 May 2014 By VPTS, PTTPM
Item Hand-Wrapping Machine-Wrapping
Recommend grade
InnoPlus LL7420A, LL7428A
Or Blend with InnoPlus LL7910A
InnoPlus LL7835A
“LLDPE” Film Application
Recommended Grade by Process
Cast Film
8 May 2014 By VPTS, PTTPM
Item High clarity High clarity & low gel
Recommend grade InnoPlus LL7410D1
LL7410G1
“LLDPE” Film Application
Recommended Grade by Process
Lamination Film
8 May 2014 By VPTS, PTTPM
LDPE LD2420D LD2420F
MFR 190 , 2.16Kg 0.27 0.75
Density 0.922 0.922
Slip/Antiblock No No
Application Heavy Duty film, Shrink film, Agriculture film
“LDPE” Film Application
Shrink Film Agricultural Film
8 May 2014 By VPTS, PTTPM
LDPE LD2420H LD2426H LD2420K LD2426K LD2026K
MFR 190, 2.16Kg 1.9 1.9 4.0 4.0 4.0
Density 0.924 0.924 0.924 0.924 0.920
Slip/AB No Yes No Yes Yes
Application General purpose film, Lamination film, Zip bag,
Light Duty Shrink film
“LDPE” Film Application
8 May 2014 By VPTS, PTTPM
22
“LLDPE” Film Application
Additive Content
InnoPlus LLDPE InnoPlus LDPE
GradeSlip
(ppm.)
Antiblock
(ppm.)
LL7410D 800 5,000
LL7410D1 700 700
LL7410G1 500 1800
LL7410D2 1,500 5,000
LL7420D 800 5,000
LL7420D1 800 1,500
GradeSlip
(ppm.)
Antiblock
(ppm.)
LD2426H 500 1000
LD2426K 600 1800
LD2026K 600 1500
8 May 2014 By VPTS, PTTPM
“By Application”
- Film
- Injection & Masterbatch Carrier
- Blow Molding & Tube
- Monofilament
- Wire & Cable
- Foam & Bubble sheet
8 May 2014 By VPTS, PTTPM
HDPE
HD1100J HD1600J HD2208J HD2218J HD2308J HD2408J
MFR 190, 2.16Kg
18 12 3.7 4.0 6 7
Density 0.958 0.958 0.961 0.954 0.962 0.964
Feature High flow Low flow / UV added
• High flow • Low flow
Masterbatch carrier Toys Housewares
Pallet Crate Garbage bin
“HDPE” Injection Application
8 May 2014 By VPTS, PTTPM
Properties Unit HD2218J HD2208J
MFR @ 2.16 kg/190 C g/10min 4 3.7
Density g/cm3 0.954 0.961
UV - Yes Yes
• UV stabilized resin • Suitable for outdoor durable application • Excellent mechanical properties (High impact resistance)
“HDPE” Injection Application
InnoPlus HD2218J
8 May 2014 By VPTS, PTTPM
“By Application”
- Film
- Injection & Masterbatch Carrier
- Blow Molding & Tube
- Monofilament
- Wire & Cable
- Foam & Bubble sheet
8 May 2014 By VPTS, PTTPM
• Drinking water bottle • Milk bottle • Beverage bottle
Food containers
HDPE
HD4200B HD5200B
MFR 190, 2.16Kg 0.67 0.45
Density 0.966 0.966
ESCR; 25% Igepal 25 30
Application Food Containers
“HDPE” Blow Molding Application
8 May 2014 By VPTS, PTTPM
“HDPE” Blow Molding Application
• Personal care container • Cosmetic bottle • Shampoo bottle • Detergent bottle • Lubricant oil containers
Chemical Containers
HDPE
HD6200B HD6600B
MFR 190, 2.16Kg 0.45 0.40
Density 0.962 0.957
ESCR; 25% Igepal 60 400
Application Chemical containers
/ Food container
8 May 2014 By VPTS, PTTPM
LDPE
LD2420D LD2420F LD2420H
MFR 190, 2.16Kg 0.27 0.75 1.9
Density 0.922 0.922 0.924
Slip/AB No No No
Application Cosmetic tube, small bottle
“LDPE” Blow & Tube Application
8 May 2014 By VPTS, PTTPM
“By Application”
- Film
- Injection & Masterbatch Carrier
- Blow Molding & Tube
- Monofilament
- Wire & Cable
- Foam & Bubble sheet
8 May 2014 By VPTS, PTTPM
Grade MFR
(g/10min) Density (g/cm3)
Characteristic Application
HD5000S 0.8 0.954 Excellent tenacity, good process
ability, high production rate Ropes, Fishing nets, Agricultural nets, Tarpaulins,
Woven sack HD5001S
0.8
0.954
Excellent thermal stability
“HDPE” Monofilament Application
8 May 2014 By VPTS, PTTPM
“By Application”
- Film
- Injection & Masterbatch Carrier
- Blow Molding & Tube
- Monofilament
- Wire & Cable
- Foam & Bubble sheet
8 May 2014 By VPTS, PTTPM
“LLDPE & LDPE” Wire & Cable Application
LLDPE LDPE
LL6420A LD2420H LD2420K
MFR 190C, 2.16Kg 1 1.9 4
Density 0.918 0.923 0.924
Application Base resin for PE Crosslinked
for Low voltage power cable.
Base resin for PE Crosslinked for Medium voltage power cable
8 May 2014 By VPTS, PTTPM
“By Application”
- Film
- Injection & Masterbatch Carrier
- Blow Molding & Tube
- Monofilament
- Wire & Cable
- Foam & Bubble sheet
8 May 2014 By VPTS, PTTPM
“LDPE” Foam and Bubble sheet Application
LDPE
LD2420H LD2426H LD2420K LD2426K LD2026K
MFR 190, 2.16Kg 1.9 1.9 4.0 4.0 4.0
Density 0.924 0.924 0.924 0.924 0.920
Slip/AB No Yes No Yes Yes
Application Foam application eg. Foam net, Thermal Insulators Foam, Cap
liner, Bubble sheet
8 May 2014 By VPTS, PTTPM
Thank You