Groundwater quality Baseline investigations in Estonia

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Groundwater quality Baseline investigations in Estonia

Andres Marandi

November 10th, 2011, Riga

Baseline conceptThe range of concentrations of a given element, species or chemical substance present in solution, being derived from natural geological, biological or atmospheric sources.

The range of concentrations of a given element, species or chemical substance present in solution, being derived from natural geological, biological or atmospheric sources

The natural baseline concentration varies spatially in relation to many factors such as geology and temporally with residents time

Baseline concept

Baseline conceptThe range of concentrations of a given element, species or chemical substance present in solution, being derived from natural geological, biological or atmospheric sources

The natural baseline concentration varies spatially in relation to many factors such as geology and temporally with residents time

Estonian geology

Historical data versus new data

No significant differences between "old" and "new" data

Distribution of TDS in CVAS

300 mg/l in north

16 g/l in south

Groundwater chemical types in CVAS

Buried valleys act as recharge areas for CVAS in N-Estonia

Recharge of modern precipitation is marked by d18O

• Intensive abstraction

• Depressione cone

Conceptual model for V2vr in NE-Estonia

Conceptual model for V2vr in NE-Estonia

Natural background

• low in SO4

• Variation in HCO3/Cl

• High in Na

• HCO3/Cl ~1

Natural background

Seawater intrusion

• Increase of Cl content during last 10 year

Sillamäe water supply well:

• Change in water type towards seawater

• HCO3 decreasing

• TDS increasing

Seawater intrusion

• Increase in HCO3 and Ca

Recharge from buried valleys

• HCO3/Cl increasing

• TDS decreasing

Recharge from buried valleys

• Stable isotope sampling of water (34S, 13C-DIC, 18O, 2H)

• gas isotopes sampling(13C-CH4)

• Radioactive isotope sampling (14C)

• Major ion sampling

Current activities in Estonia

Thank you for your attention!

Andres Marandi

andres.marandi@gi.ee