ChemInform Abstract: Preparation and Properties of 2,2-Bissilyl-1,3-dithia-2-silacyclopent-4-enes...

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Transcript of ChemInform Abstract: Preparation and Properties of 2,2-Bissilyl-1,3-dithia-2-silacyclopent-4-enes...

2001 organo-silicon compounds

organo-silicon compoundsS 0060

15 - 173Preparation and Properties of 2,2-Bissilyl-1,3-dithia-2-silacyclopent-4-enes and Related Compounds. — The synthesis of title compounds(III) (5 examples) by reaction of (Z)-ethenedithiolate (I) with appropriatedichlorosilanes (II) is described. The dithiasilole derivatives obtained formcharge-transfer complexes with tetracyanoethylene. — (TSUTSUI, SHINOBU;TAKAHASHI, MASAE; SAKAMOTO, KENKICHI; Chem. Lett. (2000) 12,1376-1377; Dep. Chem., Grad. Sch. Sci., Tohoku Univ., Aoba, Sendai 980,Japan; EN)

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