Background Report Reference

AP-42 Section Number: 9.5.3

Background Chapter: 4

Reference Number: 1

Title: Emission Testing at the Darlings Delaware Rendering Plant, Fresno, CA

Prepared by, Genesis Environmental Services Company

July 1990

AP42 Section - eeferenoe ReparcSect. Reference

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DARLINGS DELAWARE COMPANY e 7 3 7 KING GEORGE DRIVE, SUITE zoo

DALLAS, TEXAS 7 5 2 3 5

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DARLINGS DELAWARE COMPANY RENDERING PLANT

FRESNO. CALIFORNIA

EMISSION TESTING JULY 30 6 3 1 , 1 9 9 0

PREPARED BY: GENESIS ENVIRONMENTAL SERVICES CCUPANY

BALERSFIELD. CALIFORNIA 9 3 3 0 1 1 1 4 5 WEST COLUMBUS AVENUE

REPORT I 7 7 7 7 - 0 1 9 0

TEST CONOUCTEO 0 Y MICHAEL L . BAKALOR RESULTS VERFIED BY MICHAEL L . BAKALOR

OPERATIONS MANAGER

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section 1 - Introduction

section 2 - SlunplIng ProcedUr*a

Appandix

A-1 Coast to Coast .Result6

A-2 Chain of Custody

A-3 Raw Data

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Introduct ion

A t ths requast of W r . Wika Ko.wler O f Darlings Dalsnsrs Company. h ~ a i . Envircmmntal Services conductad a ssriam o f mmission taste at Darlings rmlanara's rendarlng plant. located a t 2354 F r u i t Avanue, Freeno, Cal i fornia.

The purpoaa of t h i o tamting waa to dotarmine if a apacif ic group of Comwunda ware present at various po in t sOUrCas i n the p lan t operation procaas. The four locations and t h s i r dascriptiona arm Scrubber $1. a 15K Environmntal Reesarch Cormration no t scrubbsr. Scrubber S Z , a 1OOK Stordbartz wat scrubbar and W u t a Hoat Incinsrator ( i n l e t and ou t la t ) , manufactursd by Spencer Bo i le r Wanufacturea.

The 1990 Annual Conplianca Test was conductad on July 30 k 31. 1990, by M r . nicha.1 0akalor. Mr. Patr ick Young and W r . Kavin Orton of Oenesis Environnuntal. Oarlings Dalsnara repreeentativs M r . Mike Koswler warn proaent during the taeting.

Tabla 1-1 is contians a summary of rasul ta frm Scrubbar sl oulat. Tabla 1-2 contain. a s u m y Of rmsulta from Scrubbar $2 out la t . Table 1-3 contains I Wumary o f rssu l ta P r m the Incinerator Outlet. Tabla 1-4 contains a s u m r y of resu l ts from tha Incinsrator i n l e t . Figure 1-1 contains calculat ions wed t o dstermins the resul ts. Tho fol lowing i a a a u m r y of t os ts perfornud a t Darlings Dslanare.

!&MLiLx v Trace Organics Single EPA 7-14 QWWS Fornaldohyde Single CAR0 Wathod 430 Mercaptans Single EPA 10-14 OCl l lS Aminao Single Qastac Datactor Tuba Organic Acids Single CAR0 Mathod 421 Cz-Cqo Hydrocarbons Single OC/FID

Qonseim Environmntal parfornud ths sample oo l lec t ion of the above l i s t a d constituente. Coast t o C o o t Analyt ical Servicas pmrformd analysis and sample t r a i n reagent preparation f o r the abova l i a t s d methods.

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TABLE 1-1 SUMMARY OF TEST RESULTS

SCRUBBER I 1 OUTLET

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- Acatona Banxana P-ButMone(MEK) Chlormthana chloroform Chloronmthana oichlorornthane EthylbanZen. Toluana 1.1.1-Trlchloroethana Trichlormthane(TCE) xylenes

!xaMk&w Propionic Acld

a C t - C l O

Ethan. Propane Butane

P m tanaa Haxanaa

C. H12 H.Xun.

IsObUtMO

Ca H14 H0XM.S

mmxm&wa Not Detactad -

9.1 ppm < 0.10 ppm < 0.10 porn < 0.10 ppm < 0.10 ppm < 0.10 DDm < 0.10 pPm < 0.10 ppm < 0.10 DDm < 0.10 pm < 0.10 ppm < 0.10 ppm

19.7 ppm

'< 1.0 ppm

NOTE: ~ 1 1 other conatituante not l i e t a d abova are deta i led l n Appendix A-1. were found to be not dat?ctad.

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TABLE 1-2 0UW)uRY OF TEST RESULTS

SCRUBBER 02 OUTLET - Acatone

Chloroethane chloroform Ch lormthene Dichlormsthana Ethylbenzana 4-M.thyl-2-Pentanone(YIBK) su ryne Toluene 1.1.1-Trichloroathane Xylenes - Propionic Acid

6 c* - c,p

Ethane Propana Butane

mntanae nexumm C. n14 naxanas CI I412 Hexanes CI nie neptanee Cv H14 Heptan.s C. ni8 O S t M W

Iaobutane

l4ucwmM

Farmaldehvdes

AoljM@ Not D.tactad

N o t Detected

< 0.10 pPm < 0.10 PPm < 0.10 ODm < 0.10 ppm < 0.10 ppm < 0.10 ppm < 0.10 ppm < 0.10 ppm < 0.10 am?

~ . . . . < 0.10 ppm < 0.10 porn < 0.10 nDm

11.8 ppm

1 10.0 p i < 10.0 ppm 1 10.0 DDm < 10.0 pPm 1 1.0 ppn < 1.0 PPm 1 1.0 PPm < 1.0 ppal 1 1.0 ppm

< 1 . 0 ppm

.. . . ,<

,. .

NOTE: A l l o t t :onstituenta not l i s t e d above arm detai Apwndix A-1, nsra found t o bm not detectad.

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mnzene 2-BUtMOne(YEK) Chloroform 1.2-Oichlorwthan* Ethyl benzene . Toluene Xylenes

!xm&AQm Propionic Acid

0.16 ppm < 0.10 nom < 0.10 Pm < 0.10 ppm < 0.10 D M I < 0.10 ppm < 0.10 P p n

08.8 porn

n s C. - C $ P

Ethane < 10.0 ppm Propma < 10.0 Ppm BUtMe < 10.0 ppm lsobutane < 10.0 Ppm Pentanem < 10.0 PPm H.XM*S < 10.0 Ppm C. H i 4 H.XM.0 < 1.0 p m C I H i 2 HeXMOS < 1 .O ppm CI wi6 Heptane. < 1 . 0 ppm c, H14 n.pt.nos < 1 .O opm ca n 1 8 Octanes < 1.0 ppm

lmXMmP3 Not Detected - AmillM N o t Detected

< 1.0 Pprn

NOTE: A l l other cpnetituente not l i e tad above ere detai led i n Appendix A-1, were found to b. not detected.

4

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Benzene Bromodichlormthan*

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TABLE 1-4 8UlOURY OF TEST RESULT8

INCINERATOR INLET

Chloroform Dichloromthans Ethylbmrene Styrene 1,1.2,2-TetrachloroOthan~ Toluena 1.1.1-TrichloroethMe xY1enee - Prooionic Acid

1.0 PPm < 0.10 ppm < 0.10 pw < 0.10 ppm

0.1s ppm < 0.10 ppm < 0.10 ppm < 0 . i o pPm < 0.10 ppm < 0.10 ppm < 0.10 ppm < 0.10 ppm < 0.10 ppm < 0.10 ppm

155.8 ppm

< 10.0 PPm < 10.0 nom < 10.0 Pw < 10.0 ppm < 10.0 pprn < 10.0 DDm < 1.0 p-w < 1.0 ppm < 1.0 o m < 1.0 ppm < 1.0 ppm

< 1.0 ppm

29.0 ppm

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NOTE: A l l other constituent. not 1iat.d above are d*t.i led i n Appendix A-1, *.re found t o be not detected.

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cubic Metera = Vm[atd) 8 0:028317

PPI4 v i udcu. m * W 8 .OOl MW -

ua/L I i T o t a l us8 1000

= ualcu. m cu. m

-1 mo 8 . Q U = ualcu. m CY. m

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Section 2.0

sampllno Procadurss,

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Section 2.0

Collection of Samples

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Tha sampling protucal used to collect the Tadlar bag sawlea follow orcadurea as outlined in CAR0 mathod 422 and eimailar CAR0 mthode.. Figure 2-1 contains a picture o f the Nutach S m l e train used and a detailed diagram o f that eomple train.

Thm sample train consisted of a rigid vacuum canister. aawle

a stainless steel* sample probe. pump mdula, Tygon aampls line. a 50 1it.r Tedly SMIDI. baa and

Each sample bag was identified with a lab number st thm baginning of aach test run, Appendix A-2 contalna the chain of cuetody sheat that all Samples were entered onto. Once tha sample train was assembled and leak checked. the sample bag w u purged With sample and evacuated twice beforo the actual sample waa collected. Sample collection consisted of a thirty minute collection time at a constant sample rate.

The following ie a list of proceduree followed for each empl. run:

1 . Stainless steel. sample probe clannod three t i m e with acetone and distilled water and drled with nitrogen.

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2. New Tygon eample line used on each test run. , ;. ' r: . . .. .. .'. . . .;.! . . . . 3. Now Tedlsr sample bag used on each teat run.

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4. ~ 1 1 non-replaceable stainless stsele connections cleanad three rims with acetone and dietillad watar.

5. Aftar the sample has been collacted tho Tedlar sample bag

sun1 ight. 1. placed in a black pla8tiC bag DrObCt from any

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Appendix A-1

Coast to Coast Resultm . .

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mt round

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VALERIC ACID bZ1 MlZ3lOI OR0 0. t l .

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PRWIOYIC ACID U1 MI1SlOl V I U D AT F w m W / a P I U PERfFWT nECOVERY

I W ~ I C ACID 611 MI13101 ORO S P I M AT F D W W / V I I ( E PERCENI RECOVERY

BUTVRIC ACID 421 M12alnl OaO 0 .1 t l . 1 V I U D AT 3.0 FOUND U l S P M E a.0 PEI)SENT RLrnVERI 13..

ISOVALERIC ACID b21 M/23/9a OR0 1.1 t l . 1 S P X M AT 3.0 FwlD W l S P I U 2 . 0 PERCEW RECOVERV 07.

VALERIC ACID b ~ i laiza/sa o(10 0.1 a1.2 S P I M AT a.0 FOUlD W/tPIKE 1.0 PERCENT RECOVERY 1w.

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Chain o f Cuatody

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